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1.
我国铝土矿成因及矿层沉积过程 总被引：8，自引：3，他引：8
我国铝土矿床按最近作者等（1984,1985）的意见主要的是风化壳沉积型（Ⅰ型）,占我国铝土矿石储量98.83%,其次是红土型（Ⅱ型）,占我国矿石储量1.17%。前者又分三个亚型即Ⅰ1修文式--碳酸盐古风化壳沉积亚型,占Ⅰ型矿石储量83.2%,分布在山西、贵州、河南、四川、山东、河北、陕西、辽宁、江西、新疆等省（区）;Ⅰ2苹果式--碳酸盐古风化壳沉积--近代卡斯特堆积亚型,占Ⅰ型矿石储量13.04%,分布在广西、云南等省（区）;Ⅰ3乐山式--硅酸盐古风化壳沉积型,分布在四川、贵州北部、湖北、湖南等省。红土型（Ⅱ型）分布在福建、广东。是第三纪到第四纪玄武岩在近代气候条件下风化作用形成的三水铝石矿床。其成因已得到我国铝土矿床地质工作者的公认,与国外的意见也一致,本文不再讨论。但是我国对于古风化壳沉积型铝土。 相似文献
2.
The Songqi region, SW Henan, is an important bauxite province in China. The bauxite ore deposits occur unconformably on the top of Middle Ordovician argillaceous carbonates. The bauxite ores from the Songqi region are characterized by unusually high boron contents. In this paper, we report the mineralogical and chemical compositions of selected bauxite ores from the region. These new data, together with existing geochemical data of soils in the region, are used to evaluate the origin of boron enrichment in the bauxite ores. The compositional characteristics of tourmaline in the bauxite ores suggests that this mineral was likely derived from a meta-sedimentary protolith. Mass balance calculation reveals that tourmaline only accounts for a small portion of boron in the bauxite ores; the majority of boron in the ores must occur in other forms, possibly by ion absorption on the surfaces of diaspore and clay minerals. In the Songqi region, the Precambrian meta-sedimentary rocks are known to contain abundant tourmalines whereas the Cambrian–Ordovician argillaceous carbonates and the Upper Proterozoic shales are all enriched in boron in free ion state. We suggest that these rocks provided tourmaline and boron ion to the bauxite deposits in the region. Most known bauxite deposits in the Songqi region occur at the margins of boron-rich soil domains, suggesting that boron in soils is a potential exploration indicator for unknown bauxite deposits in this region. 相似文献
3.
The paper concerns issues of geology and metallogeny of the Russian Arctic, namely, (i) limits of the Russian oceanic Arctic in the context of the continental origin of territories under jurisdictional dispute; (ii) geology and tectonic history of the region; (iii) distribution of mineral deposits; (iv) outlook for diamond, PGE, Ni, rare metals, gold, and bauxite resources development.Advanced diamond exploration and development can be expected proceeding from geology of new potentially diamondiferous areas, the Phanerozoic history and composition of lithospheric mantle beneath the Siberian craton which were controlled by the Siberian superplume at the Permian–Triassic boundary, and from new exploration approaches adapted to the prospecting conditions of Arctic Siberia.According to the available knowledge of Ni and PGE mineralization in the Noril’sk region, it is reasonable to develop depleted ores and tailings (mining dumps at the Noril’sk and Talnakh deposits). However, the key solution consists in new large discoveries within the Dzheltula and Kharaelakh volcanic and plutonic complexes.Gold production enhancement may be associated with black shale-hosted Au-As mineralization in the northeastern Russian Arctic, but the problem is in the lack of efficient and environmentally safe dressing technologies for these ores.Most of rare metals in the area (Nb, Sc, Y, and other elements) are stored in the giant Tomtor field, which has a complex structure and history. A special technology designed for the Tomtor ores ensures more than 60% extraction of ore components.Good prospects for the bauxite potential are expected from the Timan district where bauxite may occur in Vendian and Early Carboniferous formations.It is suggested to include the development of the Russian Arctic as a priority target in the national economic strategy. 相似文献
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贵州云峰铝土矿中铀矿物的发现 总被引：1，自引：1，他引：0
有关铝土矿中铀富集的报道很多,但至今未见独立铀矿物存在的相关文献。本次研究采用岩相学观察、X衍射(XRD)、ICP-MS、电子探针(EPMA)、拉曼光谱分析等手段,对黔中典型的铝土矿——云峰铝土矿中的晶质铀矿进行了研究。研究发现该铝土矿床中,铀富集明显(w(U)(18×10~(-6)～62×10~(-6)),平均值35×10~(-6)),铀矿物大小呈微米至亚微米级,围绕锐钛矿边缘生长、或充填于高岭石微裂隙中、或散布于与黄铁矿密切相关的高岭石或硬水铝石中。铀矿物的主要组分为UO_2(w(UO_2)为52.2%～80.88%)和TiO_2(w(TiO_2)为1.85%～14.98%);电子探针面扫描显示铀矿物中钛分布不均匀;铀矿物的拉曼特征波长为442 cm~(-1)和454 cm~(-1),因此,初步推测铀矿物为晶质铀矿和含钛晶质铀矿。其形成过程大致如下,来源于下寒武统牛蹄塘组黑色岩系中的铀(U~(4+))在风化过程中氧化为U~(6+)、析出、被Al~-, Fe~-氧化物/氢氧化物吸附;在沉积和成岩过程中,随着三水铝石转变为勃姆石和硬水铝石、铁氧化/氢氧化物转变为黄铁矿,吸附的铀解吸、还原(U~(6+)至U~(4+))、最后形成铀矿物。 相似文献
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贵州大竹园是近年来取得重要找矿进展的大型铝土矿之一,黔北务正道地区也已被国家列入首批整装勘查区。为确保进一步找矿取得突破,迫切需要对大竹园铝土矿典型矿床及务正道铝土矿矿集区的成矿条件分析和成矿规律进行总结。本文通过含矿地层、构造、古气候、地貌和岩相古地理条件的分析,将大竹园组含矿岩系的分布、韩家店群成矿母岩的存在、基底黄龙组灰岩的溶蚀和向斜轴部构造的稳定延伸作为最重要的区域成矿要素,进而梳理出栗园－鹿池、张家院、大塘、新模、道真、桃园、安场和浣溪等向斜构造展布区作为整装勘查的主要目标,并分别建立了成矿模式,明确了重点勘查的找矿方向。通过2010年以来的整装勘查工作,目前已新增铝土矿资源量4.7亿吨,新发现3个超大型、4个大型和3个中型铝土矿,取得了显著的找矿效果。本文在找矿勘查实践基础上总结的成矿规律和成矿模式,为整装勘查提供了科学依据,也为今后的找矿提供了理论指导。 相似文献
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论我国铝土矿床类型及其红土化风化壳形成机制问题 总被引：3，自引：0，他引：3
中国铝土矿床98%以上为古风化壳型,少量属红土型.前者分六个亚型,即铝硅酸盐岩古风化壳原地残积（Ⅰa）;碳酸盐岩古风化壳准原地堆积（Ⅰb）、异地堆积（Ⅰc）以及异地沉积（湖水）（Ⅰd）;Ica古风化壳异地沉积（海相）;Ⅰf碳酸盐岩古风化壳准原地堆积（或沉积）-现代喀斯特堆积等六个亚型.ⅠⅠb、Ⅰc三亚型矿床在大气条件下就位,就位以后继续红土化,为此矿层很少层理;矿石中常有渗流管、渗流凝胶.Ⅰd、Ⅰe亚型在水体中沉积,有层理,无渗流管、渗流凝胶.所有铝土矿床的矿物组成及矿石结构、构造都是含铝岩石红土化风化作用易溶物淋失,难溶的钛、铝、铁质残留的风化壳铝土物质;无水体中结构、构造特征;δ18O‰及δD‰值证为风化物;除Ⅰc外均无动物化石及其碎屑. 相似文献
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[摘 要] 河南三门峡市贯沟铝土矿属喀斯特型铝土矿。研究区内地层发育相对完全,除上奥陶统、
志留系、泥盆系和下石炭统地层缺失外,从太古界到新生界均有出露。铝土矿层主要产出于中石炭系本
溪组下段。矿石以鲕粒和隐晶质结构为主,少量碎屑结构。矿物学分析显示,铝土矿矿石的主要组成矿
物有硬水铝石、锐钛矿、伊利石,另外,还包括少部分高岭石、锆石等。硬水铝石呈隐晶质结构组成矿石
的基质,少部分呈现细小的板状、长柱状形态。锐钛矿存在两种形态:第一种是锐钛矿与硬水铝石二者
同期形成;第二种锐钛矿以脉状穿插在硬水铝石组成的基质中,形成稍晚于硬水铝石。伊利石主要呈鳞
片状集合体形态组成矿石的基质。锆石主要分散在硬水铝石组成的基质中。进一步研究发现:硬水铝
石电子探针分析显示晶体中存在Fe、Si 和Ti 等其它元素,其主体呈隐晶质与锐钛矿密切共生,指示硬水
铝石主要为简单的成岩结晶成因。矿石中的锐钛矿和硬水铝石共生,互相包含和穿插,反映大量的锐钛
矿是成矿期或成岩期结晶形成。对风化作用中形成的伊利石主要由云母转化而形成,该过程中矿物结
构并未发生明显改变。 相似文献
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GEOEXPLORER is a knowledge-based system under development to support the prospecting and exploration of supergene deposits. As a new type of multi-stage expert systetn, GEOEXPLORER is not only able to deal with problems of searching for supergene deposits, but will also cover both the evaluation of the spatial occurrences and the economic values of the deposits considered. A first prototype of GEOEXPLORER has been developed for bauxite deposits. It is a rule-based system implemented in PROLOG and can be used to identify favorable areas for bauxite prospecting. This paper discusses this prototype of GEOEXPLORER. 相似文献
11.
安徽庐枞盆地矾山酸性蚀变岩帽形成时代及其地质意义 总被引：3，自引：1，他引：2
酸性蚀变岩帽是岩浆热液流体和围岩在近地表相互作用的产物,是斑岩-浅成低温热液成矿系统的重要指标。发育在长江中下游成矿带庐枞盆地内的矾山酸性蚀变岩帽产出面积较大( 20km~2)。前人对该酸性蚀变岩帽中的明矾石矿床的地质和地化特征进行了相关研究,但详细的年代学研究工作尚未开展。为精确厘定矾山酸性蚀变岩帽的形成时代,本文开展了明矾石~(40)Ar-~(39)Ar法和金红石原位U-Pb法定年。矾山酸性蚀变岩帽中明矾石共有三种类型:ⅠA型明矾石主要呈交代蚀变发生在热液蚀变早阶段,与石英、粒状黄铁矿或赤铁矿、少量金红石共生;ⅠB型明矾石形成于热液蚀变晚阶段,主要呈叶片状集合体充填在开放空间中,与石英、星点状赤铁矿、粒状金红石集合体共生,少量金红石和赤铁矿沿明矾石解理裂隙分布;Ⅱ型明矾石是表生明矾石,主要呈细粒集合体沿裂隙分布,与赤铁矿、高岭石、地开石共生。三类明矾石形成于不同环境下:ⅠA和ⅠB型明矾石形成于岩浆热液环境下,是大矾山明矾石矿区的主要产物;Ⅱ型细粒明矾石分布在矾山酸性蚀变岩帽的非明矾石矿区,是表生环境下的产物。ⅠA型明矾石的~(40)Ar-~(39)Ar定年的坪年龄为131±6Ma,代表了矾山酸性蚀变岩帽的形成时代。与Ⅱ型明矾石密切共生的金红石U-Pb定年结果为32. 7±4Ma,在该期间,整个盆地内无岩浆活动发生,该年龄反映了矾山酸性蚀变岩帽经历表生氧化作用的时间。明矾石和金红石定年结果分别对应岩浆热液和表生明矾石的形成时代。在利用明矾石进行找矿工作时需先明确明矾石成因,矾山酸性蚀变岩帽中深成明矾石是下一阶段的找矿研究的基础。 相似文献
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Karstic bauxite deposits are widespread in Central Guizhou Province, SW China, and high-grade ores are frequently sandwiched with overlying coal and underlying iron-rich layers and form a special “coal–bauxite–iron” structure. The Lindai deposit, which is one of the most representative karstic bauxite deposits in Central Guizhou Province, was selected as a case study. Based on textural features and iron abundances, bauxite ores in the Lindai deposit are divided into three types of ores, i.e., clastic, compact, and high-iron. The bauxite ores primarily comprise diaspore, boehmite, kaolinite, illite, and hematite with minor quartz, smectite, pyrite, zircon, rutile, anatase, and feldspar. The Al2O3 (53–76.8 wt.%) is the main chemical contents of the bauxite ore samples in the Lindai district, followed by SiO2, Fe2O3, TiO2, CaO, MgO, S, and P etc. Our geological data on the Lindai deposit indicated that the ore-bearing rock series and its underlying stratum have similar rare earth elements distribution pattern and similar Y/Ho, Zr/Hf, and Eu/Eu1 values; additionally, all ore-bearing rock samples are rich in MgO (range from 0.16 wt.% to 0.68 wt.%), and the plots of the dolomites and laterites lie almost on or close to the weathering line fit by the Al-bearing rocks in Zr vs. Hf and Nb vs. Ta diagrams; suggesting that the underlying Middle Cambrian Shilengshui Formation dolomite is the parent rock of bauxite resources in the Lindai district.Simulated weathering experiments on the modern laterite from the Shilengshui Formation dolomite in the Lindai bauxite deposit show that hydrogeological conditions are important for karstic bauxite formation: Si is most likely to migrate, its migration rate is several magnitudes higher than those of Al and Fe under natural conditions; the reducing inorganic acid condition is the most conducive to Al enrichment and Si removal; Fe does not migrate easily in groundwater, Al enrichment and Fe removal can occur only in acidic and reducing conditions with the presence of organic matter.The geological and experimental studies show that “coal–bauxite–iron” structure in Lindai deposit is formed under certain hydrogeological conditions, i.e., since lateritic bauxite or Al-rich laterite deposited upon the semi-closed karst depressions, Si can be continuously removed out under neutral/acidic groundwater conditions; the coal/carbonaceous rock overlying the bauxitic materials were easily oxidized to produce acidic (H2S, H2SO4, etc.) and reductant groundwater with organic materials that percolated downward, resulting in enrichment of Al in underlying bauxite; it also reduced Fe3+ to its easily migrating form Fe2+, moving downward to near the basal carbonate culminated in precipitating of ferruginous (FeS2, FeCO3, etc.) strata of the “coal–bauxite–iron” structure. Thus, the bauxitic materials experienced Al enrichment and Si and Fe removal under above certain hydrogeological conditions forming the high-quality bauxite. 相似文献
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《Journal of Asian Earth Sciences》2011,40(6):701-712
Most of the karstic bauxite deposits in China are enriched in REE, and the REE has commonly been considered to be adsorbed on the surface of clay or diaspore minerals as ion state. However, occurrence of REE minerals in the bauxite deposits has not been reported by far. In the Quyang bauxite deposit from Guangxi province, we find REE minerals. The minerals are parisite and churchite. Parisite is widely distributed in the ooids and matrix, inducing positive Ce anomaly of the ores; whereas, churchite is rare and occurred in the core of ooid. The compositions of the REE minerals show the Eu anomaly can change gently during the weathering, and the Eu anomaly analyses suggest that the REE in the ores are mostly derived from the underlying carbonates. The parisite is formed in an alkaline condition, while churchite in an acidic situation; the co-existence of the two minerals in the ores suggests the Permian environment for bauxite formation is complex with great change of pH value. Moreover, parisite is inferred to be formed earlier than the churchite. 相似文献
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豫某铝土矿勘查中重力异常显示,区域重力异常反映深部奥陶系顶面呈自西向东缓斜坡状起伏分布;对浅表干扰异常,通过上延过滤后,可以发现奥陶系顶界面的隆、凹起伏分布特征;虽铝土矿密度大于奥陶系灰岩密度,有较大密度差,但由于评价区似层状铝土矿厚度薄,斗状铝土矿虽厚度大,但体积小,重力异常不能直接反映铝土矿。含铝岩系厚度与铝土矿厚度总体上成正比,因此寻找厚大含铝岩系分布区可间接起到找矿的作用。比较含铝岩系密度值与奥陶系灰岩密度值可知,含铝岩系与奥陶系地层有一定的密度差,奥陶系灰岩密度相对较大,因此,局部重力高异常对应奥陶系隆起;对比己知见铝土矿钻井资料和上延后重力异常分布关系,发现铝土矿床大多分布在局部重力高异常以外的区域;通过上述分析,圈定了2个铝土矿找矿靶区,从而对铝土矿的调查评价有重要指导作用。 相似文献
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河南不同成因类型铝土矿的矿石特征 总被引：4，自引：0，他引：4
本文在对铝土矿石物质组成研究的基础上,运用电子显微镜(EM)对河南两类不同类型铝土矿床的矿石结构进行了观察研究。根据EM观察到的铝土矿石显微结构的不同形貌特征,划分出三种矿石结构类型:致密-隐晶结构、粒状镶嵌结构和粒屑结构。由此归结为两个成因类型:古风化壳异地堆积亚型和古风化壳原地堆积亚型的铝土矿床。 相似文献
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河南渑池铝土矿成矿区地球化学背景 总被引：3，自引：0，他引：3
[摘 要]地球化学元素的分布特征反映了元素矿化富集规律。本文在了解矿床地质背景及地球化学性质的基础上,通过对河南渑池地区水系沉积物地球化学测量数据的统计分析,着重研究铝土矿成矿区的地球化学背景,寻找地球化学找矿指标,希望对以后的勘察工作有所借鉴。研究区的铝土矿带位于石炭系本溪组地层中,且本溪组不整合覆盖于奥陶纪地层之上。与上层地层相比,矿层富含Al2O3、高场强元素(HSFS),尤其是硼元素。对水系沉积物地球化学数据进行分析,得出反映元素分布形态的地球化学图,结果表明,只有B 元素可以明确反应铝土矿的空间分布位置。矿床点一般沿硼元素高值区边界分布,表明B 元素可以作为河南渑池铝土矿成矿区的地球化学找矿指标。 相似文献
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在龙州地区首次发现早石炭世的堆积型铝土矿矿源层,提出广西堆积型铝土矿至少存在早石炭世和晚二叠世两个时代的矿源层。探索运用高密度电阻率法寻找古风化壳沉积型铝土矿的有效性试验工作。提交新发现矿产地4处,探获新增铝土矿(3341)资源量5 289.15万吨。重新厘定区域地层岩性及岩相特征,系统总结区内铝土矿矿床(点)的时空分布特征、控矿地质条件、成矿规律及找矿标志,建立了区域成矿模式和预测找矿模型,圈定成矿远景区5处,找矿靶区6处,开展区域矿产预测,初步评价了本区铝土矿资源潜力。为该地区下一步地质调查、矿产勘查规划和开发提供了丰硕的基础资料和有益参考。 相似文献
19.
Xuefei Liu Qingfei Wang Jun Deng Qizuan Zhang Silei Sun Jianyin Meng 《Journal of Geochemical Exploration》2010
The Dajia Salento-type bauxite deposit in western Guangxi is hosted within the Quaternary ferrallitic soil profile, and it formed via breaking up, weathering and oxidizing of Permian bauxite orebodies occurring as a semi-continuous layer in the upper Permian. Mineralogical analyses reveal that diaspore, hematite and kaolinite are the major minerals in bauxite ores with small amounts of anatase, chamosite, gibbsite, goethite, illite, zircon, quartz and pyrite. The ore texture and mineral assemblage reveal that the depositional/diagenetic environment of the Dajia bauxite was much close to phreatic environment. Both the ore texture and the morphology of zircon grains also indicate that most of the bauxitic soils were transported a short distance. Diaspore is suggested to be non-metamorphic in origin and mainly formed in a reducing condition of diagenetic environment, while kaolinite is the product of the in situ epigenetic replacement of alumina in diaspore by dissolved silica. Geochemical analyses indicate that Al2O3, Fe2O3, SiO2 and TiO2 are the main components of the bauxite ores and trace elements such as Zr, Hf, Nb, Ta, Th and U were enriched during the bauxitization process. Simultaneously, Zr vs. Hf and Nb vs. Ta show a high correlation. Geochemical indices such as Zr/Hf, Nb/Ta and Eu/Eu* (among others) denote that the magmatic rocks related to the Emeishan plume in western Guangxi and the carbonates in the underlying Maokou Formation provided the main sources of material for the bauxite ores. 相似文献
20.
嫩江-黑河地区多宝山岛弧多宝山矿集区新发现了晚三叠世二道坎大型银矿床,铜山矿床深部取得重大找矿突破;科洛-新开岭构造杂岩带新发现晚三叠世孟德河金矿床,三合屯金矿区外围深部也发现了金矿化;塔溪岩浆弧新发现了早白垩世宝泉小型铜矿床.这些矿床与区域圈定的化探异常较吻合,成矿规律较明显.依据新发现的铜金矿成果,总结了嫩江-黑河地区近年来取得的新近展,指出了下一步找矿方向和今后勘查工作部署建议,为即将实施的战略找矿行动勘查部署提供参考依据. 相似文献