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1.
Four groups of thermal springs with temperatures from 50 to 80 °C are located on the S–SW–W slopes of El Chichón volcano, a composite dome-tephra edifice, which exploded in 1982 with a 1 km wide, 160 m deep crater left. Very dynamic thermal activity inside the crater (variations in chemistry and migration of pools and fumaroles, drastic changes in the crater lake volume and chemistry) contrasts with the stable behavior of the flank hot springs during the time of observations (1974–2005). All known groups of hot springs are located on the contact of the basement and volcanic edifice, and only on the W–SW–S slopes of the volcano at almost same elevations 600–650 m asl and less than 3 km of direct distance from the crater. Three groups of near-neutral (pH ≈ 6) springs at SW–S slopes have the total thermal water outflow rate higher than 300 l/s and are similar in composition. The fourth and farthest group on the western slope discharges acidic (pH ≈ 2) saline (10 g/kg of Cl) water with a much lower outflow rate (< 10 l/s).  相似文献   

2.
Phytoplankton biomass, community and size structure, primary production and bacterial production were measured at shelf and continental slope sites near North West Cape, Western Australia (20.5°S–22.5°S) over two summers (October–February 1997–1998 and 1998–1999), and in April 2002. The North West Cape region is characterized by upwelling-favorable, southwesterly winds throughout the summer. Surface outcropping of upwelled water is suppressed by the geostrophic pressure gradients and warm low-density surface waters of the southward flowing Leeuwin Current. Strong El Niño (ENSO) conditions (SOI <0) prevailed through the summer of 1997–1998 which resulted in lower sea levels along the northwestern Australian coast and a weaker Leeuwin Current. La Niña conditions prevailed during the 1998–1999 summer and in April 2002. During the summer of 1997–1998, the North West Cape region was characterized by a shallower thermocline (nutricline), resulting in larger euphotic zone stocks of inorganic nitrogen and silicate over the continental slope. There was evidence for episodic intrusions of upper thermocline waters and the sub-surface chlorophyll maximum onto the outer continental shelf in 1997–1998, but not in 1998–1999. Pronounced differences in phytoplankton biomass, community size structure and productivity were observed between the summers of 1997–1998 and 1998–1999 despite general similarities in irradiance, temperature and wind stress. Phytoplankton primary production and bacterial production were 2- to 4-fold higher during the summer of 1997–1998 than in 1998–1999, while total phytoplankton standing crop increased by<2-fold. Larger phytoplankton (chiefly diatoms in the >10 μm size fraction) made significant contributions to phytoplankton standing crop and primary production during the summer of 1997–1998, but not 1998–1999. Although there were no surface signs of upwelling, primary production rates near North West Cape episodically reached levels (3–8 g C m−2 day−1) characteristic of eastern boundary Ekman upwelling zones elsewhere in the world. Bacterial production (0.006–1.2 g C m−2 day−1) ranged between 0.6 and 145 percent (median=19 percent) of concurrent primary production. The observed differences between years and within individual summers suggest that variations in the Leeuwin Current driven by seasonal or ENSO-related changes in the Indonesian throughflow region may have episodic, but significant influences on pelagic productivity along the western margin of Australia.  相似文献   

3.
El Chichón volcano (Chiapas, Mexico) erupted violently in March–April 1982, breaching through the former volcano–hydrothermal system. Since then, the 1982 crater has hosted a shallow (1–3.3 m, acidic (pH ∼ 2.2) and warm (∼ 30 °C) crater lake with a strongly varying chemistry (Cl/SO4 = 0–79 molar ratio). The changes in crater lake chemistry and volume are not systematically related to the seasonal variation of rainfall, but rather to the activity of near-neutral geyser-like springs in the crater (Soap Pool). These Soap Pool springs are the only sources of Cl for the lake. Their geyser-like behaviour with a long-term (months to years) periodicity is due to a specific geometry of the shallow boiling aquifer beneath the lake, which is the remnant of the 1983 Cl-rich (24,000 mg/l) crater lake water. The Soap Pool springs decreased in Cl content over time. The zero-time extrapolation (1982, year of the eruption) approaches the Cl content in the initial crater lake, meanwhile the extrapolation towards the future indicates a zero-Cl content by 2009 ± 1. This particular situation offers the opportunity to calculate mass balance and Cl budget to quantify the lake–spring system in the El Chichón crater. These calculations show that the water balance without the input of SP springs is negative, implying that the lake should disappear during the dry season. The isotopic composition of lake waters (δD and δ18O) coincide with this crater lake-SP dynamics, reflecting evaporation processes and mixing with SP geyser and meteoric water. Future dome growth, not observed yet in the post-1982 El Chichón crater, may be anticipated by changes in lake chemistry and dynamics.  相似文献   

4.
The extensive sea grass meadows in Torres Strait enable it to be a globally important habitat for the dugong, Dugong dugon, a marine mammal of cultural and dietary significance to Torres Strait Islanders and the basis for the substantial island-based fishery in the Torres Strait Protected Zone. Torres Strait sea grass communities are subjected to episodic diebacks which are now believed to be largely natural events. Information on dugong life history was obtained from specimens obtained from female dugongs as they were butchered for food by Indigenous hunters at two major dugong hunting communities in Torres Strait: Daru (9.04°S, 143.21°E) in 1978–1982 (a time of sea grass dieback and recovery) and Mabuiag Island (9.95°S, 142.15°E) in 1997–1999 (when sea grasses were abundant). Dugongs sampled in 1997–1999 had their first calf at younger ages (minimum of 6 cf. 10 years), and more frequently (interbirth interval based on all possible pregnancies 2.6±0.4 (S.E.) yr cf. 5.8±1.0 yr) than the dugongs sampled in 1978–1982. Pregnancy rates increased monotonically during 1978–1982, coincident with sea grass recovery. The age distribution of the female dugongs collected in 1997–1999 also suggested a low birth rate between 1973 and 1983 and/or or a high level of mortality for animals born during this period. These results add to the evidence from other regions that the life history and reproductive rate of female dugongs are adversely affected by sea grass loss, the effect of which cannot be separated from a possible density-dependent response to changes in dugong population size. Many green turtles in Torres Strait were also in poor body condition coincident with the 1970s sea grass dieback. The impacts of future sea grass diebacks need to be anticipated when management options for the traditional Torres Strait fisheries for dugongs and green turtles are evaluated.  相似文献   

5.
Side scan sonar records, sediment textural characteristics, and in-situ field observations were used to study gravelly and pebbly dunes and sorted bedforms on the inner shelf of Marettimo Island, along the northwestern Sicilian shelf. The dunes are composed of coarse sands, gravels and pebbles (D50: 2–16 mm), displaying a symmetrical shape with a wavelength in the range of 1–2.5 m and a height of 0.15–0.30 m. The bedforms are distributed in a patchy pattern in a depth range of 10–50 m, and are described for the first time on a Mediterranean inner shelf. Sorted bedforms are linear morphological features developed almost perpendicular to the coast in the eastern sector of the island between 15 and 50 m water depth. Bottom shear stresses required for sediment entrainment and the generation of the shallower dunes can be reached during strong storms (Hs=5–6 m; Tp=9–11 s), which are not common in the Mediterranean Sea. However, wave storm events recorded in the study area during the last 17 years are not able to generate the coarsest and deeper dunes, suggesting that the stirring mechanism for dune formation is associated with severe storms that have a recurrence interval of more than 17 years. The long-term stability of the coarse bedforms is supported by the permanence of sorted bedforms without significant morphological changes for long periods (>13 years). Therefore, it is shown that processes forming coarse bedforms can occur in tideless and moderate-energy settings like those of the Mediterranean continental shelves, although the morphological features are probably less dynamic and remain unaltered for longer periods than on higher-energy shelves.  相似文献   

6.
A recently extended and spatially rich English Channel sea level dataset has been used to evaluate changes in extreme still water levels throughout the 20th century. Sea level records from 18 tide gauges have been rigorously checked for errors and split into mean sea level, tidal and non-tidal components. These components and the interaction between surge and tide have been analysed separately for significant trends before determining changes in extreme sea level. Mean sea level is rising at 0.8–2.3 mm/year, depending on location. There is a small increase (0.1–0.3 mm/year) in the annual mean high water of astronomical tidal origin, relative to mean sea level, and an increase (0.2–0.6 mm/year) in annual mean tidal range. There is considerable intra- and inter-decadal variability in surge intensity with the strongest intensity in the late 1950s. Storm surges show a statistically significant weak negative correlation to the winter North Atlantic Oscillation index throughout the Channel and a stronger significant positive correlation at the boundary with the southern North Sea. Tide–surge interactions increase eastward along the English Channel, but no significant long-term changes in the distribution of tide–surge interaction are evident. In conclusion, extreme sea levels increased at all of the 18 sites, but at rates not statistically different from that observed in mean sea level.  相似文献   

7.
Tephra layers from archaeological sites in southern Italy and eastern Europe stratigraphically associated with cultural levels containing Early Upper Palaeolithic industry were analysed. The results confirm the occurrence of the Campanian Ignimbrite tephra (CI; ca. 40 cal ka BP) at Castelcivita Cave (southern Italy), Temnata Cave (Bulgaria) and in the Kostenki–Borshchevo area of the Russian Plain. This tephra, originated from the largest eruption of the Phlegrean Field caldera, represents the widest volcanic deposit and one of the most important temporal/stratigraphic markers of western Eurasia. At Paglicci Cave and lesser sites in the Apulia region we recognise a chemically and texturally different tephra, which lithologically, chronologically and chemically matches the physical and chemical characteristics of the Plinian eruption of Codola; a poorly known Late Pleistocene explosive event from the Neapolitan volcanoes, likely Somma–Vesuvius. For this latter, we propose a preliminary age estimate of ca. 33 cal ka BP and a correlation to the widespread C-10 marine tephra of the central Mediterranean. The stratigraphic position of both CI and Codola tephra layers at Castelcivita and Paglicci help date the first and the last documented appearance of Early Upper Palaeolithic industries of southern Italy to ca. 41–40 and 33 cal ka BP, respectively, or between two interstadial oscillations of the Monticchio pollen record – to which the CI and Codola tephras are physically correlated – corresponding to the Greenland interstadials 10–9 and 5. In eastern Europe, the stratigraphic and chronometric data seem to indicate an earlier appearance of the Early Upper Palaeolithic industries, which would predate of two millennia at least the overlying CI tephra. The tephrostratigraphic correlation indicates that in both regions the innovations connected with the so-called Early Upper Palaeolithic – encompassing subsistence strategy and stone tool technology – appeared and evolved during one of the most unstable climatic phases of the Last Glacial period. On this basis, the marked environmental unpredictability characterising this time-span is seen as a potential ecological factor involved in the cultural changes observed.  相似文献   

8.
We examine characteristics in the variability of sea surface temperature (SST) in the Yellow/East China Sea during the boreal winter (December–January–February) for the period 1950–2008 in observations. It is found that the mean SST in the Yellow Sea/East China Sea gradually increases during recent decades. A warming trend of a basin scale SST is significant in most of the regions in the Yellow/East Sea, which is well explained by the variability of the first empirical orthogonal function SST mode. We suggest one candidate mechanism that the North Pacific oscillation (NPO)-like sea level pressure play an important role to warm the Yellow/East China Sea. Anomalous anticyclonic circulation, which is the southern lobe of NPO-like sea level pressure over the North Pacific, causes a weakening of northerly mean winds over the Yellow/East China Sea during winter. This contributes to increase in the SST in the Yellow/East China Sea through the changes in the latent heat and sensible heat fluxes.  相似文献   

9.
Five weeks of hourly, 10-min time-exposure video images were used to analyze the meso–macro-tidal double-barred Truc Vert Beach, SW France, under intense wave forcing. The four storms experienced, one of which with an offshore significant wave height over 8 m, induced dramatic changes in the double sandbar system. The subtidal outer bar migrated offshore rapidly (up to 30–50 m/day) and its pre-existing crescentic pattern was wiped out. The seaward-protruding parts of the outer bar barely migrated offshore during the most intense storm, whereas a landward-protruding part was shed off. Over the entire study period, the outer-bar dynamics was dominated by alongshore-averaged changes rather than alongshore non-uniform changes, while the opposite was observed for the inner bar. In addition, the outer-bar dynamics was predominantly controlled by the time-varying offshore wave conditions, whereas the inner-bar dynamics was influenced largely by the tide-range variations. Our observations put forward the key role of morphological settings (the presence of a subtidal bar and its shape) and tidal range in governing inner-bar behaviour within a double sandbar dynamics, and provide strong support for previous suggestions that sandbars cannot be studied in isolation.  相似文献   

10.
The present work aimed at studying the origin of particulate organic matter in Guanabara Bay and in some rivers of the Guanabara basin by using elemental composition, isotopic ratios (δ13C and δ15N) and molecular markers (sterols) in samples collected in two periods (winter and summer). Elemental and isotopic compositions were determined by dry combustion and mass spectrometry, respectively, while sterols were investigated by GC–FID and GC–MS. Higher sterol concentrations were present in the north-western part of the bay in winter (5.10–23.5 μg L–1). The high abundance of algal sterols (26–57% of total sterols), the elemental composition (C/N=6–8) and the isotopic signatures (δ13C=−21.3‰ to −15.1‰ and δ15N=+7.3‰ to +11.1‰) suggested the predominance of autochthonous organic matter, as expected for an eutrophic bay, although seasonal variation in phytoplankton activity was observed. Coprostanol concentration (fecal sterol) was at least one order of magnitude higher in the particulate material from fluvial samples (4.65–55.98 μg L–1) than in the bay waters (<0.33 μg L–1). This could be ascribed to a combination of factors including efficient particle removal to sediments in the estuarine transition zone, dilution with bay water and bacterial degradation during particle transport in the water column.  相似文献   

11.
A field experiment to assess the effects of continuous nutrient addition on the macrobenthic community was carried out on an estuarine mudflat on the northeast coast of Brazil. The experiment began on 5 October 2005 and ended on 8 February 2006. Macrofauna was compared at approximately four-week intervals in triplicate plots with three levels (Control – C, Low Dose – LD and High Dose – HD) of weekly fertilizer additions for 17 weeks. Inorganic fertilizer (N–P–K) was applied on nine randomly defined quadrangular plots (4 m2 each). All measurements were calculated from species abundances. Multivariate analyses as well as the univariate indices (richness, abundance and Shannon–Wiener index) showed statistically significant differences between the enriched and control areas during the period of the experiment. The expected gradual response based on the succession model of Pearson and Rosenberg was not observed. The nutrient doses used were high enough to cause severe decreases in abundance, richness and evenness, and an increase in dominance.  相似文献   

12.
Saronikos Gulf (Greece) practically constitutes the sea border of the metropolitan city of Athens and the alongshore outskirts, and it receives the treated wastes of ∼4 million people from a point source that discharges on the sea bottom at ∼65 m water depth. Total organic carbon (TOC) was measured in 477 seawater samples collected in the Saronikos Gulf, during 10 cruises, from August 2001 to May 2004 and analyzed with the High Temperature Catalytic Oxidation method (HTCO). TOC concentrations ranged from 49 to 198 μmol C L−1 in agreement with other Mediterranean coastal waters. The highest TOC concentrations were found in the upper waters (0–75 m), whereas in the deeper parts of the Gulf (between 100 and 400 m) TOC concentrations were kept constantly low (49–70 μmol C L−1). A general pattern towards higher TOC concentrations during summer was also observed. Calculations of non-refractory (labile+semi-labile) organic material based on a one-dimensional (1D) conceptual model showed that it corresponds to 33% of the bulk TOC during summer and to 27% during winter. Bacterial production (BP) was measured at selected stations of ∼70–80 m depth using the [3H] leucine method. Depth integrated BP values varied from 2.8 to 10.9 mmol m−2 d−1, whereas extraordinary high integrated BP values (126 and 140 mmol m−2 d−1) were observed at the station over the treated sewage outflow. From the turnover time, τ, of the non-refractory TOC by bacteria it was implied that organic matter in the effluents is extremely labile (2–58 days). Moreover, τ values at the other sites showed that during summer non-refractory organic material resisted bacterial degradation (1–8 months), whereas during early spring it was easily degradable (20–50 days). The balance of TOC fluxes for the Inner Gulf for June and September 2003 showed that the Inner Gulf acts as a net producer of TOC during summer. Our results suggest that the presence of the Athens treated sewage outfall does not contribute to the observed summer accumulation of TOC in the Inner Gulf and other causes such as increased bacteria predation and/or nutrient limitation must be responsible.  相似文献   

13.
Nearshore currents of the southern Namaqua shelf were investigated using data from a mooring situated three and a half kilometres offshore of Lambert's Bay, downstream of the Cape Columbine upwelling cell, on the west coast of South Africa. This area is susceptible to harmful algal blooms (HABs) and wind-forced variations in currents and water column structure are critical in determining the development, transport and dissipation of blooms. Time series of local wind data, and current and temperature profile data are described for three periods, considered to be representative of the latter part of the upwelling season (27 January–22 February), winter conditions (5–29 May) and the early part of the upwelling season (10 November–12 December) in 2005. Differences observed in mean wind strength and direction between data sets are indicative of seasonal changes in synoptic meteorological conditions. These quasi-seasonal variations in wind forcing affect nearshore current flow, leading to mean northward flow in surface waters early in the upwelling season when equatorward, upwelling-favourable winds are persistent. Mean near-surface currents are southward during the latter part of the upwelling season, consistent with more prolonged periods of relaxation from equatorward winds, and under winter conditions when winds were predominantly poleward. Within these seasonal variations in mean near-surface current direction, two scales of current variability were evident within all data sets: strong inertial oscillations were driven by diurnal winds and introduced vertical shear into the water column enhancing mixing across the thermocline, while sub-inertial current variability was driven by north–south wind reversals at periods of 2–5 days. Sub-inertial currents were found to lag wind reversals by approximately 12 h, with a tendency for near-surface currents to flow poleward in the absence of wind forcing. Consistent with similar sites along the Californian and Iberian coasts, the headland at Cape Columbine is considered to influence currents and circulation patterns during periods of relaxation from upwelling-favourable winds, favouring the development of a nearshore poleward current, leading to poleward advection of warm water, the development of stratification, and the creation of potentially favourable conditions for HAB development.  相似文献   

14.
The retreat-making larvae of many lotic caddisflies build entirely new pupal cases with fine gravel and sand that they collect in the neighbourhood of the building place to fix it with silk to cobbles in swift flow (where finer sediments are generally rare). Previous field observations on Hydropsyche siltalai pupal cases illustrate that natural local resource limitations of the preferred grain fraction (2.5–3.15 mm) produced chained effects across other grain fractions, as the alternative use of more grains in the 1.6–2 mm fraction (an unlimited resource) induced an increased use of more grains in the 0.315–0.5 mm fraction (another unlimited resource). To examine the implications of these observations for H. siltalai, we used (1) mesocosms to created minor deviations in the availability of the natural grain size composition of the building material of pupal cases at otherwise carefully replicated natural stream habitat conditions and (2) recently developed technologies to assess many case characteristics so far ignored in studies of caddisfly cases. When the preferred coarser grains (2.5–3.15 mm) were unavailable, more grains with intermediate size (1.25–2.0 mm) were used (and not other, still available coarse grains) and fewer larvae built cases in groups, thereby not only loosing the benefits (lower costs for grain transport and silk) but also avoiding potential disadvantages associated with grouped cases (more aggressive encounters with conspecifics for rare building material, less flow exposure and thus reduced water renewal in the pupal chamber). Unavailability of 2.5–3.15-mm and 0.315–0.5-mm grains caused a reduction of larvae building in groups, more use of grains with intermediate size, changes of several other grain characteristics (e.g. number, circularity) and considerable investment into silk to maintain the case resistance. Finally, grain availability deviating most from that observed in nature (no grains of 2.5–3.15 mm and 1.6–2.0 mm) caused dramatic responses, as mortality increased so that fewer pupal cases were built, using typically more coarse grains so that many cases had an elevated resistance against crushing forces; in addition, many males had a retarded development, whereas female development was unaffected. Thus, the response of H. siltalai to any of the three types of grain limitations differed, illustrating an immense diversity to respond to grain-size shortage.  相似文献   

15.
The results are presented of an intensive study of phytoplankton assemblage carried out in the Berounka River above its confluence with the Vltava River (Czech Republic) in the period 2002–2007. The annual and interannual changes of phytoplankton development (based on high frequency of sampling) and their relation to hydrological conditions and concentrations of main nutrients are analysed. A marked decline of nutrient concentrations was observed during the period 1996–2007. The annual mean values of total P decreased from 0.43 mg L−1 to 0.16 mg L−1, those of N-NO3 from 4.6 mg L−1 to 1.5 mg L−1 and N-NH4 from 1.9 mg L−1 to 0.04 mg L−1. Despite this, the phytoplankton biomass remained at a high level. The seasonal mean values of chlorophyll-a ranged from 51.0 μg L−1 to 116.8 μg L−1 in the same time period. An obviously stronger relationship was found of the phytoplankton biomass and pattern of its development to the variation of flow rates than to the existing level of nutrient concentrations. A significantly decreasing relationship (R2 = 0.384, P < 0.001) of chlorophyll-a to flow rates and a significantly increasing relationship (R2 = 0.359, P < 0.001) of chlorophyll-a to water temperatures were found, based on monthly mean values for the seasonal period 2002–2007. The results obtained indicate a remarkable increase of phytoplankton biomass and its prolongated occurrence in watercourses, which can be expected due to the consequences of the predicted climate change (i.e. higher occurrence of summer droughts and low precipitation amounts accompanied by a substantial drop of flow rates, increase of air and water temperatures), as described in the respective scenarios for the territory of the Czech Republic. Simulations by the regional climate models HIRHAM and RCAO and emission scenario SRES indicated the increase of air temperature by 2.5–5 °C, decrease of precipitation amount by 6–25% and decline of flows by 14–43% in the Berounka River for the scenario period 2071–2100.  相似文献   

16.
A historical data set is used to describe the coastal transition zone off Northwest Africa during spring 1973 and fall 1975, from 17° to 26°N, with special emphasis on the interaction between subtropical (North Atlantic Central Waters) and tropical (South Atlantic Central Waters) gyres. The near-surface geostrophic circulation, relative to 300 m, is quite complex. Major features are a large cyclonic pattern north of Cape Blanc (21°N) and offshore flow at the Cape Verde front. The large cyclone occurs in the region of most intense winds, and resembles a large meander of the baroclinic southward upwelling jet. The Cape Verde frontal system displays substantial interleaving that may partly originate as mesoscale features at the coastal upwelling front. Property–property diagrams show that the front is an effective barrier to all properties except temperature. The analysis of the Turner angle suggests that the frontal system is characterized by large heat horizontal diffusion as a result of intense double diffusion, which results in the smoothing of the temperature horizontal gradients. Nine cross-shore sections are used to calculate along-shore geostrophic water-mass and nutrient transports and to infer exchanges between the coastal transition zone and the deep ocean (import: deep ocean to transition zone; export: transition zone to deep ocean). These exchanges compare well with mean wind-induced transports and actual geostrophic cross-shore transport estimates. The region is divided into three areas: southern (18–21°N), central (21–23.5°N), and northern (23.5–26°N). In the northern area geostrophic import is roughly compensated with wind-induced export during both seasons. In the central area geostrophic import is greater than wind-induced export during spring, resulting in net import of both water (0.8 Sv) and nitrate (14 kmol s−1), but during fall both factors again roughly cancel. In the southern area geostrophy and wind join to export water and nutrients during both seasons, they increase from 0.6 Sv and 3 kmol s−1 during fall to 2.9 Sv and 53 kmol s−1 during spring.  相似文献   

17.
Before the 1991–1992 activity, a large andesite lava dome belonging to the penultimate Pinatubo eruptive period (Buag ∼ 500 BP) formed the volcano summit. Buag porphyritic andesite contains abundant amphibole-bearing microgranular enclaves of basaltic–andesite composition. Buag enclaves have lower K2O and incompatible trace element (LREE, U, Th) contents than mafic pulses injected in the Pinatubo reservoir during the 1991–1992 eruptive cycle. This study shows that Buag andesite formed by mingling of a hot, water-poor and reduced mafic magma with cold, hydrous and oxidized dacite. Depending on their size, enclaves experienced variable re-equilibration during mixing/mingling. Re-equilibration resulted in hydration, oxidation and transfer of mobile elements (LILE, Cu) from the dacite to the mafic melts and prompted massive amphibole crystallization. In Buag enclaves, S-bearing phases (sulfides, apatite) and melt inclusions in amphibole and plagioclase record the evolution of sulfur partition among melt, crystal and fluid phases during magma cooling and oxidation. At high temperature, sulfur is partitioned between andesitic melt and sulfides (Ni-pyrrhotite). Magma cooling, oxidation and hydration resulted in exsolution of a S–Cl–H2O vapor phase at the S-solubility minimum near the sulfide–sulfate redox boundary. Primary magmatic sulfide (pyrrhotite) and xenocrystic sulfide grains (pyrite), recycled together with olivines and pyroxenes from old mafic intrusives, were replaced by Cu-rich phases (chalcopyrite, cubanite) and, partially, by Ba–Sr sulfate. Sulfides degassed and transformed into residual spongy magnetite in response to fS2 drop during final magma ascent and decompression. Our research suggests that a complete evaluation of the sulfur budget at Pinatubo must take into account the en route S assimilation from the country rocks. Moreover, this study shows that the efficiency of sulfur transfer between mafic recharges and injected magmas is controlled by the extent and rate of mingling, hydrous flushing and melt oxidation. Vigorous mixing/mingling and transformation of the magmatic recharge into a spray of small enclaves is required in order to efficiently strip their primary S-content that otherwise remains locked in the sulfides. Hydrous flushing increases the magma oxidation state of the recharges and modifies their primary volatile concentrations that cannot be recovered by the study of late-formed mineral phases and melt inclusions. Conversely, S stored in both late-formed Cu-rich sulfides and interstitial rhyolitic melt represents the pre-eruptive sulfur budget immediately available for release from mafic enclaves during their decompression.  相似文献   

18.
We observed a phytoplankton bloom downstream of a large estuarine plume induced by heavy precipitation during a cruise conducted in the Pearl River estuary and the northern South China Sea in May–June 2001. The plume delivered a significant amount of nutrients into the estuary and the adjacent coastal region, and enhanced stratification stimulating a phytoplankton bloom in the region near and offshore of Hong Kong. A several fold increase (0.2–1.8 μg Chl L−1) in biomass (Chl a) was observed during the bloom. During the bloom event, the surface water phytoplankton community structure significantly shifted from a pico-phytoplankton dominated community to one dominated by micro-phytoplankton (>20 μm). In addition to increased Chl a, we observed a significant drawdown of pCO2, biological uptake of dissolved inorganic carbon (DIC) and an associated enhancement of dissolved oxygen and pH, demonstrating enhanced photosynthesis during the bloom. During the bloom, we estimated a net DIC drawdown of 100–150 μmol kg−1 and a TAlk increase of 0–50 μmol kg−1. The mean sea–air CO2 flux at the peak of the bloom was estimated to be as high as ∼−18 mmol m−2 d−1. For an average surface water depth of 5 m, a very high apparent biological CO2 consumption rate of 70–110 mmol m−2 d−1 was estimated. This value is 2–6 times higher than the estimated air–sea exchange rate.  相似文献   

19.
A method for determining the cross-isotherm ocean transport from surface heat flux and ocean temperature data is derived. By computing the volume flux through the isotherm that extend from 19°E, 74°N to the eastern part of the Kola Peninsula, the flow through the western entrance of the Barents Sea south of 74°N is estimated. Using three different surface heat flux datasets, the inflow is found to range from 2.9 to 4.5 Sv in winter (October–March) and from 0.4 to 1.4 Sv in summer (April–September; 1 Sv=106 m3 s−1). The seasonal variations are stronger than indicated by results from direct current measurements, probably because the seasonal cycle of the surface heat fluxes is overestimated along the considered isotherm. The annual mean inflow ranges from 1.9 to 2.2 Sv during a cold period (1986–1988), and from 2.4 to 3.0 Sv during a warm period (1990–1992), close to reported observations.  相似文献   

20.
Spatio-temporal estimation of precipitation over a region is essential to the modeling of hydrologic processes for water resources management. The changes of magnitude and space–time heterogeneity of rainfall observations make space–time estimation of precipitation a challenging task. In this paper we propose a Box–Cox transformed hierarchical Bayesian multivariate spatio-temporal interpolation method for the skewed response variable. The proposed method is applied to estimate space–time monthly precipitation in the monsoon periods during 1974–2000, and 27-year monthly average precipitation data are obtained from 51 stations in Pakistan. The results of transformed hierarchical Bayesian multivariate spatio-temporal interpolation are compared to those of non-transformed hierarchical Bayesian interpolation by using cross-validation. The software developed by [11] is used for Bayesian non-stationary multivariate space–time interpolation. It is observed that the transformed hierarchical Bayesian method provides more accuracy than the non-transformed hierarchical Bayesian method.  相似文献   

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