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1.
《Chemical Geology》2003,193(1-2):109-125
Ilmenite separates from the floor (LS), roof (UBS), and wall (MBS) sequences of the Skaergaard Intrusion were analyzed for major and trace elements using DCP-AES and ICP-MS techniques. In all three sequences, FeO progressively increases, and MgO and Al2O3 progressively decrease with differentiation. Although trace element abundances are, in general, higher in UBS ilmenite than in MBS and LS ilmenite, all three sequences have similar trends for trace element abundance vs. crystallization. Ba, Cs, Rb, Sr, Th, U, Y, and the REEs are excluded elements in ilmenite, and remained at low abundances during differentiation. Cr, Ni, Sc, and V are included elements in ilmenite and other mafic phases, and decreased during differentiation. V contents in ilmenite, however, do not decrease significantly until the upper part of the middle zone, suggesting that magnetite did not begin to affect the magma differentiation trend until much later than when it first appears in the intrusion. Hf, Nb, Ta, and Zr, which are strongly excluded elements in silicates, are included elements in ilmenite. The element ratios Zr/Hf, Y/Ho, Nb/Ta, and U/Th are relatively constant in Skaergaard ilmenite from different parts of the intrusion, suggesting that fluid transport did not significantly effect these elements during differentiation or post-solidification cooling. Calculated partition coefficients for ilmenite in the Skaergaard Intrusion are similar to those reported from previous studies of lunar and terrestrial basalts and kimberlites, and for most elements are significantly lower than those reported for ilmenite in rhyolitic magma. Similar Di's for Zr, Hf, Nb, and Ta suggest that ilmenite crystallization did not significantly affect Zr/Nb or Hf/Ta in the Skaergaard magma, but the ratios of Zr, Hf, Nb, or Ta to other high field strength elements, such as Th, U, Y, or the REEs, may have been altered by ilmenite fractionation.  相似文献   

2.
The Skaergaard Layered Series, Part VII: Sr and Nd Isotopes   总被引：2，自引：0，他引：2  
The initial isotopic ratios of strontium and neodymium in theSkaergaard Layered Series vary both vertically and laterally,on every scale from the intrusion as a whole down to coexistingminerals in a single rock. The magma that filled the Skaergaardchamber was contaminated to various degrees with the metamorphicrocks through which it rose and was never completely homogenizedafter being intruded. The contamination was most pronouncedin contact zones and aureoles around rare xenoliths. The greaterconcentrations of lithophile trace elements in the Upper BorderSeries was previously attributed to assimilation of buoyantfragments of gneiss that collected under the roof, but mostof the rocks of the Upper Border Series are isotopically indistinguishablefrom those of the Layered Series. It is doubtful, therefore,that this part of the intrusion assimilated much more of themetamorphic basement than did the rest of the magma. Similarly,the marked increase in the concentrations of excluded elementsin the upper part of the Layered Series is not matched by achange in the isotopic character of the rocks and cannot beattributed to a later influx of new magma. Analyses of mineralsseparated from rocks with exceptionally mafic or felsic modalcompositions revealed marked inhomogeneities in the isotopiccompositions of their constituent minerals. For example, coexistingplagioclase and pyroxene from closely associated anorthositesand pyroxenites have very different initial isotopic ratiosof both strontium and neodymium. The same is true of mafic andfelsic layers in modally graded gabbros. These differences areunrelated to the low-temperature alteration shown by oxygenisotopes. They must have been introduced when the original gabbrowas largely crystallized and underwent local metasomatic replacementby nearly mono-mineralic mafic and felsic assemblages. KEY WORDS: Nd isotopes; Skaergaard; Sr isotopes  相似文献   

3.
Liquid Immiscibility and the Evolution of Basaltic Magma   总被引：9，自引：0，他引：9  
This experimental study examines relationships between alternativeevolution paths of basaltic liquids (the so-called Bowen andFenner trends), and silicate liquid immiscibility. Syntheticanalogues of natural immiscible systems exhibited in volcanicglasses and melt inclusions were used as starting mixtures.Conventional quench experiments in 1 atm gas mixing furnacesproved unable to reproduce unmixing of ferrobasaltic melts,yielding instead either turbid, opalescent glasses, or crystallizationof tridymite and pyroxenes. In contrast, experiments involvingin situ high-temperature centrifugation at 1000g (g = 9·8m/s2) did yield macroscopic unmixing and phase separation. Centrifugationfor 3–4 h was insufficient to complete phase segregation,and resulted in sub-micron immiscible emulsions in quenchedglasses. For a model liquid composition of the Middle Zone ofthe Skaergaard intrusion at super-liquidus temperatures of 1110–1120°C,centrifugation produced a thin, silicic layer (64·5 wt%SiO2 and 7·4 wt% FeO) at the top of the main Fe-richglass (46 wt% SiO2 and 21 wt% FeO). The divergent compositionsat the top and bottom were shown in a series of static runsto crystallize very similar crystal assemblages of plagioclase,pyroxene, olivine, and Fe–Ti oxides. We infer from theseresults that unmixing of complex aluminosilicate liquids maybe seriously kinetically hampered (presumably by a nucleationbarrier), and thus conventional static experiments may not correctlyreproduce it. In the light of our centrifuge experiments, immiscibilityin the Skaergaard intrusion could have started already at thetransition from the Lower to the Middle Zone. Thus, magma unmixingmight be an important factor in the development of the Fe-enrichmenttrend documented in the cumulates of the Skaergaard LayeredSeries. KEY WORDS: liquid immiscibility; Skaergaard; layered intrusions; experimental petrology  相似文献   

4.
Plagioclase separates from the Layered Series (LS), Upper Border Series (UBS), and Marginal Border Series (MBS) of the Skaergaard intrusion were analyzed to examine major and trace element variations. In general, plagioclase from the LS, UBS, and MBS show similar trends in major elements vs. crystallization: SiO2, Na2O, and K2O progressively increase, and CaO and MgO progressively decrease with fractionation. No abrupt changes in the trends of major components of Skaergaard plagioclase during the differentiation of the intrusion are observed. Trace elements in plagioclase reflect changes in the Skaergaard magma and changes in plagioclase distribution coefficients with differentiation. Sr, Ga, and probably Ba are included elements in Skaergaard plagioclase, but were excluded from the other cumulus phases, and as a result systematically increased in the magma and plagioclase during differentiation. Be, Cs, Hf, Rb, Ta, U, and Zr, and the transition metals Co, Cr, Cu, Ni, Sc, V, and Zn were excluded elements in Skaergaard plagioclase, and remained low in plagioclase during differentiation. Changes in the abundances of these elements in plagioclase during differentiation reflect changes in their abundance in the magma. With the exception of the lower zone, which is enriched in the light rare earth elements, rare earth elements in LS plagioclase, in general, increase with differentiation of the Skaergaard intrusion, but decrease dramatically at the UZa/UZb boundary where abundant apatite first appears. Rare earth elements in UBS plagioclase followed a similar trend to LS plagioclase, except during the initial and final stages of differentiation. UBS plagioclase is much more enriched in rare earth elements during the final 20% of crystallization, except for Eu, which is similar in plagioclase from the two series. The observed trends suggest that the floor and roof sequences became isolated from each other and that the floor sequence may have been more reducing and the roof sequence more oxidizing during the final 20% of crystallization. As the Skaergaard magma ceased convection, or convected as isolated cells, during the final stages of differentiation, volatile elements may have accumulated in the UBS magma, resulting in an increase in ƒO2, and a decrease in Eu/Sm in UBS plagioclase. The observed trends of rare earth elements in plagioclase from the LS and UBS fit well with theoretical calculations that assume closed-system crystallization, and would be difficult to reconcile with any model requiring significant discharge of magma from the chamber during the final 20% of crystallization. The enrichment of light rare earth elements in plagioclase, suggests that the lower part of the intrusion re-equilibrated with a late, light rare earth element-rich fluid or melt. The recharge model proposed by earlier workers to explain anomalous Sr and Nd isotopes appears unlikely in light of the two to fourfold enrichment of light rare earth elements in these samples. Received: 1 October 1999 / Accepted: 14 May 2000  相似文献   

5.
Re-examination of the Skaergaard intrusion in the context ofits regional setting, combined with new data from explorationdrilling, has resulted in a revised structural model for theintrusion. It is modelled as an irregular box, c. 11 km fromnorth to south, up to 8 km from east to west, and 3·4–4km from the lower to the upper contact. The walls of the intrusionare inferred to follow pre-existing and penecontemporaneoussteep faults, and the floor and roof seem largely controlledby bedding planes in the host sediments and lavas, similar toregional sills. The suggested shape and volume are in agreementwith published gravimetric modelling. Crystallization alongall margins of the intrusion concentrated the evolving meltin the upper, central part of the intrusion, best visualizedas an ‘onion-skin’ structure inside the box. Thetotal volume is estimated to c. 280 ± 23 km3, of which13·7% are referred to the Upper Border Series (UBS),16·4% to the Marginal Border Series (MBS) and 69·9%to the Layered Series (LS). In the LS, the Lower Zone (LZ) isestimated to constitute 66·8%, the Middle Zone (MZ) 13·5%and the Upper Zone (UZ) 19·7%. The new volume relationshipsprovide a mass balance estimate of the major and trace elementbulk composition of the intrusion. The parental magma to theSkaergaard intrusion is similar to high-Ti East Greenland tholeiiticplateau basalts with Mg number c. 0.45. The intrusion representsthe solidification of contemporary plateau basalt magma trappedand crystallized under closed-system conditions in a crustalreservoir at the developing East Greenland continental margin. KEY WORDS: bulk composition; emplacement; mass proportions; Skaergaard intrusion; structure  相似文献   

6.
The Panzhihua gabbroic layered intrusion is associated withthe 260 Ma Emeishan Large Igneous Province in SW China. Thissill-like body hosts a giant Fe–Ti–V oxide depositwith 1333 million ton ore reserves, which makes China a majorproducer of these metals. The intrusion has a Marginal zoneof fine-grained hornblende-bearing gabbro and olivine gabbro,followed upward by Lower, Middle, and Upper zones. The Lowerand Middle zones consist of layered melanogabbro and gabbrocomposed of cumulate clinopyroxene, plagioclase, and olivine.These zones also contain magnetite layers. The Upper zone consistschiefly of leucogabbro composed of plagioclase and clinopyroxenewith minor olivine. Most rocks in the body show variable-scalerhythmic modal layering in which dark minerals, primarily clinopyroxene,dominate in the lower parts of each layer, and lighter minerals,primarily plagioclase, dominate in the upper parts. The oxideores occur as layers and lenses within the gabbros and are concentratedin the lower parts of the intrusion. Ore textures and associatedmineral assemblages indicate that the ore bodies formed by verylate-stage crystallization of V-rich titanomagnetite from animmiscible oxide liquid in a fluid-rich environment. The rocksof the Panzhihua intrusion become more evolved in chemistryupward and follow a tholeiitic differentiation trend with enrichmentin Fe, Ti, and V. They are enriched in light rare earth elementsrelative to heavy rare earth elements, and exhibit positiveNb, Ta, and Ti anomalies and negative Zr and Hf anomalies. Thesilicate rocks and oxide ores of the Panzhihua intrusion formedfrom highly evolved Fe–Ti–V-rich ferrobasaltic orferropicritic magmas. The textures of the ores and the abundanceof minor hydrous phases indicate that addition of fluids fromupper crustal wall-rocks induced the separation of the immiscibleoxide melts from which the Fe–Ti–V oxide ore bodiesin the lower part of the intrusion crystallized. KEY WORDS: magnetite; Fe–Ti-rich gabbro; layered intrusion; Panzhihua; SW China  相似文献   

7.
The Mokrsko Stream in the central Czech Republic is an oxic and slightly alkaline stream that drains a natural As geochemical anomaly. Although long-term monitoring has characterized the general seasonal trends in trace element concentrations (i.e., As, Mo, Cu, Zn) in this stream, little is known about solubility controls and sorption processes that influence diel cycles in trace element concentrations. Trace elements (including As species, Cu, Mn, Mo, Pb and Sb) and other parameters were monitored over two 24-h periods in unfiltered and filtered (0.1 μm) samples collected in August 2010 and June 2011. Copper and Pb were predominantly (>92% of the mass) associated with the particulate fraction (>0.1 μm). Arsenic, Mo and Sb were predominantly (>88% of the mass) in the “dissolved” (<0.1 μm) form. Particulate-associated elements displayed up to a factor of 13 differences between minimum and maximum concentrations, most likely due to increased streamflow related to rainfall events. Dissolved concentrations of the trace metal cations (Cu, Fe, Mn and Pb) were consistently low and displayed no diel trends. Dissolved As(V), Mo and Sb varied on a diel cycle, with increased concentrations (up to 36%) during the late afternoon and decreased concentrations during the nighttime. Diel trends in trace anionic elements are explained by temperature-dependent sorption, as the diel changes in pH during base flow were very small (0.07 std. units). Very low concentrations of As(III), which have been shown to vary in a diel cycle, were attributed to enhanced hydraulic exchange with As(III)-rich hyporheic water during rainfall events.  相似文献   

8.
An unusual quartz-bearing orthopyroxene-rich websterite xenolithhas been found in an alkali basaltic tuff at Szigliget, Bakony–BalatonHighland Volcanic Field (BBHVF), western Hungary. Ortho- andclinopyroxenes are enriched in light rare earth elements (LREE),middle REE and Ni, and depleted in Nb, Ta, Sr and Ti comparedwith ortho- and clinopyroxenes occurring in either peridotiteor lower crustal granulite xenoliths from the BBHVF. Both ortho-and clinopyroxenes in the xenolith contain primary and secondarysilicate melt inclusions, and needle-shaped or rounded quartzinclusions. The melt inclusions are rich in SiO2 and alkalisand poor in MgO, FeO and CaO. They are strongly enriched inLREE and large ion lithophile elements, and display negativeNb, Ta and Sr anomalies, and slightly positive Pb anomalies.The xenolith is interpreted to represent a fragment of an orthopyroxene-richbody that crystallized in the upper mantle from a hybrid meltthat formed by interaction of mantle peridotite with a quartz-saturatedsilicate melt that was released from a subducted oceanic slab.Although the exact composition of the slab melt cannot be determined,model calculations on major and trace elements suggest involvementof a metasedimentary component. KEY WORDS: quartz; mantle; silicate melt inclusion; SiO2-rich melt; subduction; Carpathian-Pannonian Region  相似文献   

9.
Some trace elements have the property that, although they areincompatible with most mineral phases in magmatic systems, theyare strongly concentrated in certain minor mineral phases. Theseminor phases, termed here ‘carrier-phases’, andtheir associated trace elements include platinum group elementsin base metal sulphide and chromite; chromium and vanadium inmagnetite; uranium group metals in zircon and monazite; andrare earth elements in monazite and xenotime. Carrier-phasesmay form only a small fraction of a source rock undergoing partialmelting and tend to be eliminated from the residue at an intermediatepoint in the partial melting history; conversely, those sameminor carrier-phases tend to precipitate late during fractionalcrystallization of a liquid produced in the above manner, butmay constitute a high proportion of the cumulate then forming.This paper explores the phase equilibria aspects of such processesin a simple system, outlining a nomenclature which is then usedin a mathematical treatment applicable to non-modal meltingand crystallization processes involving several crystal species.The treatment at this stage assumes constant individual crystal–liquiddistribution coefficients. Equations are developed, which areapplied in a companion paper to illustrate the behaviour thatcan be anticipated when carrier-phases play a significant rolein trace element location during melting and crystallization. KEY WORDS: uranium; thorium; platinum group elements; carrier-phase; trace element  相似文献   

10.
The Pan-African (572 Ma) Puttetti syenite (A-type granitoid)-pyroxenite association intrudes the high-grade metamorphic terrain of the Trivandrum Block, South India. Field evidence indicates the contemporaneous nature of syenitic and pyroxenitic liquids. The occurrence of a mixed-rock (~70% syenite and 30% pyroxenite) with an emulsion-like texture, and the occurrence of pyroxenite globules in syenite, is interpreted as relics of immiscible magmas. Both syenite and pyroxenite show similar mineral assemblage (with major minerals having overlapping compositions), but the relative proportions differ. Major element and trace element partitioning trends, parallel REE patterns, and similar Sr initial isotope compositions are in accord with behavior either predicted or measured for immiscible melts in experimental and/or natural systems. The more pronounced Eu anomalies and LREE/HREE ratios of syenite and pyroxenite (relative to the mixed-rock) is related to fractionation caused by immiscible separation. The proposed origin of the Puttetti pluton involves the intrusion of a magma whose bulk composition is that of the mixed-rock. This melt behaved immiscibly and split into two fractions, which produced the syenite and pyroxenite magmas.Editorial responsibility: T. Grove  相似文献   

11.
Sources and distribution of major and trace elements were investigated in the Plitvice Lakes, a pristine cascade hydrological system of sixteen karst lakes situated in a sparsely populated area of the central Croatia. Water and surface sediment samples from 17 locations, including springs, tributaries and lakes, were analyzed for the content of 22 elements by high-resolution inductively coupled mass spectrometry. Principal component analysis of the collected data set showed that different springs and tributaries displayed distinct multielemental compositions, reflecting primarily the differences in their corresponding geological backgrounds. It was shown that the springs situated in the Upper and Middle Jurassic dolomite bedrock represented the main source of several trace elements, including some toxic metals (Cd, Zn, Ni and Tl), to the Plitvice Lakes system. The concentrations of most of the trace elements (Mn, Fe, Al, Cd, Zn, Cu, Ni, Pb, Co, Cr and Tl) showed decreasing spatial trends in the downstream direction, from sources to the lakes. Such a distribution was interpreted to be a consequence of an efficient removal of the dissolved elements in the lentic parts of the system, mainly by co-precipitation with authigenic calcite and Mn oxides. Nevertheless, most of the elements in the lake sediments were highly correlated with Al, which indicated their prevalent association with terrigenic material. It was shown that the multicascade system of the Plitvice Lakes had an enhanced autopurification efficiency regarding the elimination of most of the trace metals from the aqueous phase.  相似文献   

12.
The Skaergaard Layered Series: I. Structure and Average Compositions   总被引：9，自引：6，他引：9  
Re-examination of the Skaergaard Layered Series in the lightof more extensive field work and sampling shows that the lithologiczones vary laterally as well as vertically, in both their bulkchemical composition and their mineralogical assemblages. Themargins of the zones differ from both the central part of theLayered Series and Marginal Border Series in being richer inFeO*, TiO2, K2, P2O2, and most excluded elements. Mafic mineralstend to be more abundant and more iron-rich, plagioclase ismore albitic and more strongly zoned, and apatite and biotiteare more abundant near the margins. When the average compositions of successive zones are compared,the abundances of most excluded components are seen to declineupward as far as Middle Zone then reverse their trends and increasethrough Upper Zone. P2O5 and K2O are negatively correlated inUpper Zones B and C, owing, perhaps, to separation of immisciblefelsic liquids from the iron-rich magma. No evidence has beenfound for introduction of a new batch of less differentiatedmagma. Layered rocks have an average composition that is more maficthan that of homogenous rocks at the same level. Blocks thatfell from the roof have the opposite relation; they are greatlyenriched in felsic components compared to the original compositionsof the Upper Border Series from which they came. Although some of the compositional variations may be consistentwith differing degrees of fractionation of trapped liquids,no consistent relation has been found between the degree offractionation and rates of crystal accumulation or cooling atthe walls. Contamination with the metamorphic wall rocks, eitherby assimilation or by hydrothermal fluids, seems to have hadonly local effects and cannot account for the large-scale variations.At least some of the compositional differences must have resultedfrom late-stage processes that redistributed certain componentsafter the intrusion reached advanced stages of solidification.  相似文献   

13.
在野外调研的基础上,对滇西“三江”地区临沧花岗岩基中勐库碱长花岗岩体的年代学、岩石学和地球化学开展了较系统的研究。结果显示,勐库岩体的锆石LA-ICP-MS U-Pb年龄为236.2±3.7 Ma,表明岩体应形成于中三叠世,而非前人认为的新生代。全岩主、微量元素,Sr同位素和锆石微量元素特征显示岩体属于S型花岗岩系列,来自于与临沧花岗岩基相类似的地壳沉积物源区的部分熔融,并经历了高程度的结晶分异作用。以勐库岩体为代表的碱长花岗岩与临沧花岗岩基形成时代一致,表明碱长花岗岩应为临沧花岗岩基的重要组成部分。除已报道的黑云母二长花岗岩类和黑云母花岗闪长岩类外,临沧花岗岩基还应包括较广泛分布的碱长花岗岩类。本文同时揭示,由于临沧花岗岩基中以勐库岩体为代表的碱长花岗岩并非早前认为的新生代岩体,“三江”南段特别是临沧地块前人划分的新生代岩体分布范围和规模可能需要重估。  相似文献   

14.
The late Archaean Panozero pluton in Central Karelia (BalticShield) is a multi-phase high-Mg, high-K intrusion with sanukitoidaffinities, emplaced at 2·74 Ga. The magmatic historyof the intrusion may be subdivided into three cycles and includesmonzonitic and lamprophyric magmas. Compositional variationsare most extreme in the monzonite series and these are interpretedas the result of fractional crystallization. Estimates of thecomposition of the parental magmas to the monzonites and lamprophyresshow that they are enriched in light rare earth elements, Sr,Ba, Cr, Ni and P but have low contents of high field strengthelements. Radiogenic isotope data indicate a low U/Pb, highTh/U, high Rb/Sr, low Sm/Nd source. The magmatic rocks of thePanozero intrusion are also enriched in H2O and CO2; carbonisotope data are consistent with mantle values, indicating afluid-enriched mantle source. The similarity in trace elementcharacter of all the Panozero parental magmas indicates thatall the magmas were derived from a similar mantle source. Thepattern of trace element enrichment is consistent with a mantlesource enriched by fluids released from a subducting slab. Nd-isotopedata suggest that this enrichment took place at c. 2·8Ga, during the main episode of greenstone belt and tonalite–trondhjemite–granodioriteformation in Central Karelia. Sixty million years later, at2·74 Ga, the subcontinental mantle melted to form thePanozero magmas. Experimental studies suggest that the monzoniticmagmas originated by the melting of pargasite–phlogopitelherzolite in the subcontinental mantle lithosphere at 1–1·5GPa. The precise cause of the melting event at 2·74 Gais not known, although a model involving upwelling of asthenosphericmantle following slab break-off is consistent with the geochemicalevidence for the enrichment of the Karelian subcontinental mantlelithosphere by subduction fluids. KEY WORDS: Archaean; sanukitoid; monzonite; Karelia; mantle metasomatism  相似文献   

15.
Minor phases which strongly concentrate selected trace elements,termed here ‘carrier-phases’, release relativelylarge amounts of those elements to the liquid phase when theyare eliminated during partial melting and glean relatively largeamounts of those elements when they first appear during progressivecrystallization. It is characteristic of such relationshipsthat concentrations of the selected trace elements in the bulkresidues of partial melting will rise to a peak somewhat beforethe last of the carrier-phase is eliminated during progressivemelting. In the liquids produced during equilibrium partialmelting a corresponding peak in the concentration of the traceelement occurs at the point where the carrier-phase is eliminated;the corresponding peak in trace element concentration in theliquids produced by accumulated perfect fractional melting isfound somewhat above that point. These peaks become more sharplyaccentuated as the distribution coefficient of the trace elementinto the carrier-phase increases. The highest trace elementconcentration in a partial melt liquid product is found in thesmall drop of liquid produced during perfect fractional meltingat the point where the carrier-phase is eliminated. Still higherconcentrations may be found in the first cumulates containingthe carrier-phase which precipitate during perfect fractionalcrystallization but the corresponding liquids do not containexceptionally high concentrations. Under favourable conditionsa large proportion of the available mass of a trace elementin a magmatic system may be transferred from the solid to theliquid phases or vice versa with only a small change in themass fraction of liquid in and energy content of the system.Within that range, separation of otherwise very similarly behavedtrace elements becomes possible. Further complexities ariseand the opportunities for separation increase when two carrier-phasescompete with differing success for the same group of trace elements. KEY WORDS: platinum; uranium; chromite; sulphide; distribution coefficient  相似文献   

16.
Petrographic analysis and geochemical mapping are used to characterizesector-zoned clinopyroxene oikocrysts from the Norra UlvöGabbro, Sweden. The sector zones are distinguished opticallyand by differences in TiO2 , Al2O3 , and incompatible traceelements. The oikocrysts grew with a branching morphology asevidenced by numerous triple points in a single oikocryst. Oikocrystsgrew from the center of domains outward and the growth withinindividual domains did not completely fill the space until theoikocryst had reached its full size. In some domains sectorzones are overgrown by growth zones that lack sectors. The lastcrystallization infilled channels that allowed late-stage liquidsto move through the oikocryst at the contacts with chadacrysts.Calculation of partitioning behavior of trace elements betweenadjacent sectors shows it to be regular and consistent withexperimental results. The data show that the CaTiAl2O6 componentgreatly enhances the solubility of most incompatible elementsin clinopyroxene. KEY WORDS: cumulate; layered intrusion; oikocryst; sector-zoned; trace elements  相似文献   

17.
Laser ablation microprobe data are presented for olivine, orthopyroxeneand clinopyroxene in spinel harzburgite and lherzolite xenolithsfrom La Palma, Hierro, and Lanzarote, and new whole-rock trace-elementdata for xenoliths from Hierro and Lanzarote. The xenolithsshow evidence of strong major, trace element and Sr isotopedepletion (87Sr/86Sr 0·7027 in clinopyroxene in themost refractory harzburgites) overprinted by metasomatism. Thelow Sr isotope ratios are not compatible with the former suggestionof a mantle plume in the area during opening of the AtlanticOcean. Estimates suggest that the composition of the originaloceanic lithospheric mantle beneath the Canary Islands correspondsto the residues after 25–30% fractional melting of primordialmantle material; it is thus significantly more refractory than‘normal’ mid-ocean ridge basalt (MORB) mantle. Thetrace element compositions and Sr isotopic ratios of the mineralsleast affected by metasomatization indicate that the upper mantlebeneath the Canary Islands originally formed as highly refractoryoceanic lithosphere during the opening of the Atlantic Oceanin the area. During the Canarian intraplate event the uppermantle was metasomatized; the metasomatic processes includecryptic metasomatism, resetting of the Sr–Nd isotopicratios to values within the range of Canary Islands basalts,formation of minor amounts of phlogopite, and melt–wall-rockreactions. The upper mantle beneath Tenerife and La Palma isstrongly metasomatized by carbonatitic or carbonaceous meltshighly enriched in light rare earth elements (REE) relativeto heavy REE, and depleted in Zr–Hf and Ti relative toREE. In the lithospheric mantle beneath Hierro and Lanzarote,metasomatism has been relatively weak, and appears to be causedby high-Si melts producing concave-upwards trace element patternsin clinopyroxene with weak negative Zr and Ti anomalies. Ti–Al–Fe-richharzburgites/lherzolites, dunites, wehrlites and clinopyroxenitesformed from mildly alkaline basaltic melts (similar to thosethat dominate the exposed parts of the islands), and appearto be mainly restricted to magma conduits; the alkali basaltmelts have caused only local metasomatism in the mantle wall-rocksof such conduits. The various metasomatic fluids formed as theresults of immiscible separations, melt–wall-rock reactionsand chromatographic fractionation either from a CO2-rich basalticprimary melt, or, alternatively, from a basaltic and a siliceouscarbonatite or carbonaceous silicate melt. KEY WORDS: mantle xenoliths; mantle minerals; trace elements; depletion; carbonatite metasomatism  相似文献   

18.
Numerical reconstructions of processes that may have operatedduring igneous petrogenesis often model the behaviour of importanttrace elements. The geochemistry of these trace elements maybe controlled by accessory mineral saturation and fractionation.Determination of the saturation point of accessory mineralsin granitoid rocks is ambiguous because assumptions about crystalmorphology and melt compositions do not always hold. An integratedapproach to identifying accessory mineral saturation involvingpetrography, whole-rock geochemical trends, saturation calculationsand mineral chemistry changes is demonstrated here for a compositionallyzoned pluton. Within and between whole-rock samples of the BoggyPlain zoned pluton, eastern Australia, the rare earth element(REE)-enriched accessory minerals zircon, apatite and titaniteexhibit compositional variations that are related to saturationin the bulk magma, localized saturation in intercumulus meltpools and fractionation of other mineral phases. Apatite isidentified as having been an early crystallizing phase overnearly the whole duration of magma cooling, with zircon (andallanite) only saturating in more felsic zones. Titanite andmonazite did not saturate in the bulk magma at any stage ofdifferentiation. Although some trace elements (P, Ca, Sc, Nb,Hf, Ta) in zircon exhibit compositional variation progressingfrom mafic to more felsic whole-rock samples, normalized REEpatterns and abundances (except Ce) do not vary with progressivedifferentiation. This is interpreted to be a result of limitationsto both simple ‘xenotime’ and complex xenotime-typecoupled substitutions. Our data indicate that zircon REE characteristicsare not as useful as those of other REE-rich accessory mineralsas a petrogenetic indicator. KEY WORDS: saturation; zircon; apatite; titanite; magma differentiation; trace elements; REE patterns  相似文献   

19.
Two coexisting series of strongly alkaline (basanite-tephritephonolite)and weakly alkaline (alkali basalt-trachyandesite-trachyte-rhyolite)lavas occur in the Cantal volcano (French Massif Central). Theparental magmas appear to be derived by variable degrees ofpartial melting of a common asthenospheric mantle source. Derivativetrachyandesites and feldspathoidbearing tephrites show depletionsand enrichments in trace elements which indicate that they havebeen generated by broadly similar fractionation processes, relatedto the removal of a mineral extract, from the parental alkalibasalts and basanites respectively, dominated by olivine, clinopyroxene,amphibole, apatite and titaniferous magnetite±plagioclase.In the most extreme differentiates (trachytes, rhyolites andphonolites) fractionation of zircon, sphene and alkali feldsparexerts a major control on the trace element characteristicsof the magmas. Sr-Nd-Pb isotopic data for the two magma series suggest theimportance of combined assimilation-fractional crystallizationprocesses (AFC) within the lower crust in their evolution. Modellingdemonstrates that the AFC process amplifies the original compositionaldifferences between the parent magmas. After 55% crystallizationin the strongly alkaline series and 65% in the weakly alkalineseries crustal contamination ceases, although fractional crystallizationcontinues beyond this point to produce the most evolved differentiates(phonolites and rhyolites). This may reflect progressive sealingof the lowercrustal magma reservoirs. The tendency of the magmasto follow over- or under-saturated evolutionary trends, producingrhyolitic and phonolitic residua respectively, appears to beestablished at the early stages of magmatic differentiation,reflecting inherent differences in the compositions of the parentalmagmas. KEY WORDS: alkaline magmas; Massif Central; Cantal; AFC; magmatic differentiation  相似文献   

20.
Mantle xenoliths in alkaline lavas of the Kerguelen Islandsconsist of: (1) protogranular, Cr-diopside-bearing harzburgite;(2) poikilitic, Mg-augite-bearing harzburgite and cpx-poor lherzolite;(3) dunite that contains clinopyroxene, spinel phlogopite, andrarely amphibole. Trace element data for rocks and mineralsidentify distinctive signatures for the different rock typesand record upper-mantle processes. The harzburgites reflectan initial partial melting event followed by metasomatism bymafic alkaline to carbonatitic melts. The dunites were firstformed by reaction of a harzburgite protolith with tholeiiticto transitional basaltic melts, and subsequently developed metasomaticassemblages of clinopyroxene + phlogopite ± amphiboleby reaction with lamprophyric or carbonatitic melts. We measuredtwo-mineral partition coefficients and calculated mineral–meltpartition coefficients for 27 trace elements. In most samples,calculated budgets indicate that trace elements reside in theconstituent minerals. Clinopyroxene is the major host for REE,Sr, Y, Zr and Th; spinel is important for V and Ti; orthopyroxenefor Ti, Zr, HREE, Y, Sc and V; and olivine for Ni, Co and Sc. KEY WORDS: mantle xenoliths; mantle metasomatism; partition coefficients; Kerguelen Islands; trace elements  相似文献   

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