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1.
The staurolite–biotite–garnet–cordierite–andalusite–plagioclase–muscovite–quartz metapelitic mineral assemblage has been frequently interpreted in the literature as a result of superimposition of various metamorphic events, for example, in polymetamorphic sequences. The assemblage was identified in schists from the Ancasti metamorphic complex (Sierras Pampeanas of Argentina) where previous authors have favoured the polymetamorphic genetic interpretation. A pseudosection in the MnNCKFMASH system for the analysed XRF bulk composition predicts the stability of the sub‐assemblage staurolite–biotite–garnet–plagioclase–muscovite–quartz, and the compositional isopleths also agree with measured mineral compositions. Nevertheless, the XRF pseudosection does not predict any field with staurolite, andalusite and cordierite being stable together. As a result of more detailed modelling making use of the effective bulk composition concept, our interpretation is that the staurolite–biotite–garnet–plagioclase–muscovite–quartz sub‐assemblage was present at peak metamorphic conditions, 590 °C and 5.2 kbar, but that andalusite and cordierite grew later along a continuous P–T path. These minerals are not in mutual contact and are observed in separate microstructural domains with different proportions of staurolite. These domains are explained as a result of local reaction equilibrium subsystems developed during decompression and influenced by the previous peak crystal size and local modal distribution of staurolite porphyroblasts that have remained metastable. Thus, andalusite and cordierite grew synchronously, although in separate microdomains, and represent the decompression stage at 565 °C and 3.5 kbar.  相似文献   

2.
Aluminous reaction textures in orthoamphibole-bearing rocks from the Froland area, Bamble, south Norway, record the prograde pressure–temperature path of the high-grade Kongsbergian Orogeny (c. 1600–1500 Ma) and the low–mid amphibolite facies overprint during the Sveconorwegian Orogeny (c. 1100–1000 Ma). The rocks contain anthophyllite/gedrite, garnet, cordierite, biotite, quartz, andalusite, kyanite, Cr-rich staurolite, tourmaline, ilmenite, rutile and corundum in a variety of parageneses. The P–T path is deduced from petrographic observations, mineral chemistry and zoning, geothermometry and (N)FMASH equilibria. The results indicate the sequence of metamorphic stages outlined below. (a) An M1 phase characterized by the presence of strongly deformed andalusite, gedrite and tourmaline. (b) An M2 phase with the development of kyanite after andalusite and the growth of staurolite associated with strong Na–Al–Mg zoning in orthoamphibole, indicating an increase in pressure (4 8 kbar) and temperature (500° 650°C). (c) Pressure decrease at high P (6–7 kbar) and high T (600–700 °C) during M3a with the production of cordierite ° Corundum between kyanite, staurolite and orthoamphibole and cordierite growth between corundum and orthoamphibole. (d) Temperature increase to 740 ± 60 °C and 7 kbar; static growth of garnet (M3b) at the metamorphic climax (peak T). The heat supply necessary to explain the temperature increase between the M3a and M3b phases is correlated with synkinematic enderbitic–charnockitic and basic intrusions in the Arendal granulite facies terrain. (e) M3b metamorphic conditions were followed by an initial isobaric cooling path (early M4) and late-stage pressure decrease (late M4). Early M4 conditions of 6–7 kbar and 550–600 °C, assuming PH2O < Ptotal are indicated by a retrograde talc–kyanite–quartz assemblage in late quartz–cordierite veins. Late M4 conditions of 3–4 kbar and 420–530 °C are inferred from a kyanite–andalusite–chlorite–quartz assemblage in vein-cordierite. The M1–M3 stages are interpreted as being the result of the same metamorphic P–T path, which was caused by both tectonic and magmatic thickening. A prolonged crustal residence time is proposed for the Bamble sector before uplift during the later stages of M4 occurred.  相似文献   

3.
The sequential growth of biotite, garnet, staurolite, kyanite, andalusite, cordierite and fibrolitic sillimanite, their microstructural relationships, foliation intersection axes preserved in porphyroblasts (FIAs), geochronology, P–T pseudosection (MnNCKFMASH system) modelling and geothermobarometry provide evidence for a P–T–t–D path that changes from clockwise to anticlockwise with time for the Balcooma Metamorphic Group. Growth of garnet at ～530 °C and 4.6 kbar during the N–S‐shortening event that formed FIA 1 was followed by staurolite, plagioclase and kyanite growth. The inclusions of garnet in staurolite porphyroblasts that formed during the development of FIAs 2 and 3 plus kyanite growth during FIA 3 reflect continuous crustal thickening from c. 443 to 425 Ma during an Early Silurian Benambran Orogenic event. The temperature and pressure increased during this time from ～530 °C and 4.6 kbar to ～630 °C and 6.2 kbar. The overprinting of garnet‐, staurolite‐ and kyanite‐bearing mineral assemblages by low‐pressure andalusite and cordierite assemblages implies ～4‐kbar decompression during Early Devonian exhumation of the Greenvale Province.  相似文献   

4.
The distribution and textural features of staurolite–Al2SiO5 mineral assemblages do not agree with predictions of current equilibrium phase diagrams. In contrast to abundant examples of Barrovian staurolite–kyanite–sillimanite sequences and Buchan‐type staurolite–andalusite–sillimanite sequences, there are few examples of staurolite–sillimanite sequences with neither kyanite nor andalusite anywhere in the sequence, despite the wide (~2.5 kbar) pressure interval in which they are predicted. Textural features of staurolite–kyanite or staurolite–andalusite mineral assemblages commonly imply no reaction relationship between the two minerals, at odds with the predicted first development (in a prograde sense) of kyanite or andalusite at the expense of staurolite in current phase diagrams. In a number of prograde sequences, the incoming of staurolite and either kyanite, in Barrovian sequences, or andalusite, in Buchan‐type sequences, is coincident or nearly so, rather than kyanite or andalusite developing upgrade of a significant staurolite zone as predicted. The width of zones of coexisting staurolite and either kyanite, in Barrovian sequences, or andalusite, in Buchan‐type sequences, is much wider than predicted in equilibrium phase diagrams, and staurolite commonly persists upgrade until its demise in the sillimanite zone. We argue that disequilibrium processes provide the best explanation for these mismatches. We suggest that kyanite (or andalusite) may develop independently and approximately contemporaneously with staurolite by metastable chlorite‐consuming reactions that occur at lower P–T conditions than the thermodynamically predicted staurolite‐to‐kyanite/andalusite reaction, a process that involves only modest overstepping (<15°C) of the stable chlorite‐to‐staurolite reaction and which is favoured, in the case of kyanite, by advantageous nucleation kinetics. If so, the pressure difference between Barrovian kyanite‐bearing sequences and Buchan andalusite‐bearing sequences could be ~1 kbar or less, in better agreement with the natural record. The unusual width of coexistence of staurolite and Al2SiO5 minerals, in particular kyanite and andalusite, can be accounted for by a combination of lack of thermodynamic driving force for conversion of staurolite to kyanite or andalusite, sluggish dissolution of staurolite, and possibly the absence of a fluid phase to catalyse reaction. This study represents an example of how kinetic controls on metamorphic mineral assemblage development have to be considered in regional as well as contact metamorphism.  相似文献   

5.
The Priest pluton contact aureole in the Manzano Mountains, central New Mexico preserves evidence for upper amphibolite contact metamorphism and localized retrograde hydrothermal alteration associated with intrusion of the 1.42 Ga Priest pluton. Quartz–garnet and quartz–sillimanite oxygen isotope fractionations in pelitic schist document an increase in the temperatures of metamorphism from 540 °C, at a distance of 1 km from the pluton, to 690 °C at the contact with the pluton. Comparison of calculated temperature estimates with one‐dimensional thermal modelling suggests that background temperatures between 300 and 350 °C existed at the time of intrusion of the Priest pluton. Fibrolite is found within 300 m of the Priest pluton in pelitic and aluminous schist metamorphosed at temperatures >580 °C. Coexisting fibrolite and garnet in pelitic schist are in oxygen isotope equilibrium, suggesting these minerals were stable reaction products during peak metamorphism. The fibrolite‐in isograd is coincident with the staurolite‐out isograd in pelitic schist, and K‐feldspar is not observed with the first occurrence of fibrolite. This suggests that the breakdown of staurolite and not the second sillimanite reaction controls fibrolite growth in staurolite‐bearing pelitic schist. Muscovite‐rich aluminous schist locally preserves the Al2SiO5 polymorph triple‐point assemblage – kyanite, andalusite and fibrolite. Andalusite and fibrolite, but not kyanite, are in isotopic equilibrium in the aluminous schist. Co‐nucleation of fibrolite and andalusite at 580 °C in the presence of muscovite and absence of K‐feldspar suggests that univariant growth of andalusite and fibrolite occurred. Kyanite growth occurred during an earlier regional metamorphic event at a temperature nearly 80 °C lower than andalusite and fibrolite growth. Quartz–muscovite fractionations in hydrothermally altered pelitic schist and quartzite are small or negative, suggesting that late isotopic exchange between externally derived fluids and muscovite, but not quartz, occurred after peak contact metamorphism and that hydrothermal alteration in pelitic schist and quartzite occurred below the closure temperature of oxygen self diffusion in quartz (<500 °C).  相似文献   

6.
A kilometre-scale shear zone is recognized in the Cambro–Ordovician schist of the Bossòst dome, a Variscan metamorphic and structural dome in the Axial Zone of the central Pyrenees. Non-coaxial deformation is recorded by rotated garnet and staurolite porphyroblasts following regional metamorphism M1, while coaxial conditions prevailed during later contact metamorphic M2 growth of andalusite and cordierite. Mineral compositions and bulk rock analyses show that garnet–staurolite–andalusite–cordierite assemblages are significantly enriched in Mg and Mn over the garnet–staurolite assemblage, which lacks sufficient Mg for cordierite to form. The garnet–staurolite assemblage preserves conditions during M1, estimated by AFM diagrams and P–T pseudosections to be 5.5 kbar and 580 °C, respectively. Pseudosections also indicate that staurolite is not a stable phase in cordierite–andalusite assemblages of M2, suggesting polyphase metamorphism and decompression along a clockwise P–T path for the staurolite–cordierite–andalusite assemblages. This concurs with proposed extensional tectonics along the regional shear zone. To cite this article: J.E. Mezger et al., C. R. Geoscience 336 (2004).  相似文献   

7.
Oxygen‐isotope compositions of kyanite, andalusite, prismatic sillimanite and fibrolite from the Proterozoic terrane in the Truchas Mountains, New Mexico differ from one another, suggesting that these minerals did not grow in equilibrium at the Al2SiO5 (AS) polymorph‐invariant point as previously suggested. Instead, oxygen‐isotope temperature estimates indicate that growth of kyanite, andalusite and prismatic sillimanite occurred at c. 575, 615 and 640 °C respectively. Temperature estimates reported in this paper are interpreted as those of growth for the different AS polymorphs, which are not necessarily the same as peak metamorphic temperatures for this terrane. Two distinct temperature estimates of c. 580 °C and c. 700 °C are calculated for most fibrolite samples, with two samples yielding clear evidence of quartz‐fibrolite oxygen‐isotope disequilibrium. These data indicate that locally, and potentially regionally, oxygen‐isotope disequilibrium between quartz and fibrolite may have resulted from rapid fibrolite nucleation. Pressures of mineral growth that were extrapolated from oxygen‐isotope thermometry results and calculated using petrological constraints suggest that kyanite and one generation of fibrolite grew during M1 at 5 kbar, and that andalusite, prismatic sillimanite and a second generation of fibrolite grew during M2 at 3.5 kbar. M1 and M2 therefore represent two distinct metamorphic events that occurred at different crustal levels. The ability of the AS polymorphs to retain δ18O values of crystallization make these minerals ideal to model prograde‐growth histories of mineral assemblages in metamorphic terranes and to understand more clearly the pressure–temperature histories of multiple metamorphic events.  相似文献   

8.
Eclogite boudins occur within an orthogneiss sheet enclosed in a Barrovian metapelite‐dominated volcano‐sedimentary sequence within the Velké Vrbno unit, NE Bohemian Massif. A metamorphic and lithological break defines the base of the eclogite‐bearing orthogneiss nappe, with a structurally lower sequence without eclogite exposed in a tectonic window. The typical assemblage of the structurally upper metapelites is garnet–staurolite–kyanite–biotite–plagioclase–muscovite–quartz–ilmenite ± rutile ± silli‐manite and prograde‐zoned garnet includes chloritoid–chlorite–paragonite–margarite, staurolite–chlorite–paragonite–margarite and kyanite–chlorite–rutile. In pseudosection modelling in the system Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O (NCKFMASH) using THERMOCALC, the prograde path crosses the discontinuous reaction chloritoid + margarite = chlorite + garnet + staurolite + paragonite (with muscovite + quartz + H2O) at 9.5 kbar and 570 °C and the metamorphic peak is reached at 11 kbar and 640 °C. Decompression through about 7 kbar is indicated by sillimanite and biotite growing at the expense of garnet. In the tectonic window, the structurally lower metapelites (garnet–staurolite–biotite–muscovite–quartz ± plagioclase ± sillimanite ± kyanite) and amphibolites (garnet–amphibole–plagioclase ± epidote) indicate a metamorphic peak of 10 kbar at 620 °C and 11 kbar and 610–660 °C, respectively, that is consistent with the other metapelites. The eclogites are composed of garnet, omphacite relicts (jadeite = 33%) within plagioclase–clinopyroxene symplectites, epidote and late amphibole–plagioclase domains. Garnet commonly includes rutile–quartz–epidote ± clinopyroxene (jadeite = 43%) ± magnetite ± amphibole and its growth zoning is compatible in the pseudosection with burial under H2O‐undersaturated conditions to 18 kbar and 680 °C. Plagioclase + amphibole replaces garnet within foliated boudin margins and results in the assemblage epidote–amphibole–plagioclase indicating that decompression occurred under decreasing temperature into garnet‐free epidote–amphibolite facies conditions. The prograde path of eclogites and metapelites up to the metamorphic peak cannot be shared, being along different geothermal gradients, of about 11 and 17 °C km?1, respectively, to metamorphic pressure peaks that are 6–7 kbar apart. The eclogite–orthogneiss sheet docked with metapelites at about 11 kbar and 650 °C, and from this depth the exhumation of the pile is shared.  相似文献   

9.
Porphyroblastic schists in the thermal aureole of the Victor Harbor Granite at Petrel Cove, in the southern Adelaide Fold Belt, South Australia, preserve a record of sequential cordierite, andalusite, staurolite, fibrolite, chlorite and muscovite growth (along with biotite+plagioclase+quartz+ilmenite) during progressive deformation. A P–T pseudo‐section appropriate to biotite‐saturated assemblages in KFMASH shows that the sequence of mineral reactions records increasing pressure of at least 1 kbar (from c. 3 to c. 4 kbar) during cooling from around 580 °C. Heating at pressures below c. 3 kbar is inferred for growth of early formed cordierite porphyroblasts, and is attributed in part to the thermal effects of granite emplacement, while the pressure increase is attributed to tectonic burial accruing from ongoing deformation. The ‘anticlockwise’P–T path is consistent with convergent deformation being focussed as a consequence of heating, as to be expected for a lithospheric rheology that is strongly temperature dependent.  相似文献   

10.
Metapelites from the southern aureole of the Vedrette di Ries tonalite (eastern Alps) were variably overprinted by contact and earlier regional metamorphic events during pre-Alpine and Alpine metamorphic cycles. In these rocks, starting from a primary garnet mica-schist (garnet stage), a complex sequence of transformations, affecting the site of the garnet, has been recognized. In the outermost part of the aureole, the primary garnet sites are occupied by nodules of kyanite (kyanite stage). Closer to the tonalite, kyanite is replaced by staurolite (staurolite stage), which in turn is pseudomorphed by muscovite (muscovite stage). The aggregates of kyanite do not overgrow garnet directly; they post-date a stage (fibrolite stage) represented by the pseudomorphic alteration of garnet into fibrolitic sillimanite plus biotite. A further sericite stage is likely to have occurred between the fibrolite and kyanite stages. Preservation of the sub-spherical garnet shape during all these transformations and persistence of mineralogical and textural relicts from earlier stages were favoured by the very low strain experienced by the rocks since the garnet stage. The textural sequence is in agreement with the metamorphic history of this part of the Austroalpine basement of the Eastern Alps: the garnet and fibrolite stages, and the coeval main foliation of the samples, are referred to the high-grade Hercynian metamorphism; the kyanite stage to the Eo-Alpine metamorphism; the staurolite and muscovite stages to the Oligocene contact metamorphism. It is suggested that kyanite growth as microgranular aggregates took place in polymetamorphic rocks where static, high- P /low- T  metamorphism overprinted high- T  assemblages that contained sillimanite or andalusite.  相似文献   

11.
The Ross of Mull pluton consists of granites and granodioritesand intrudes sediments previously metamorphosed at amphibolitefacies. The high grade and coarse grain size of the protolithis responsible for a high degree of disequilibrium in many partsof the aureole and for some unusual textures. A band of metapelitecontained coarse garnet, biotite and kyanite prior to intrusion,and developed a sequence of textures towards the pluton. InZone I, garnet is rimmed by cordierite and new biotite. In ZoneII, coarse kyanite grains are partly replaced by andalusite,indicating incomplete reaction. Coronas of cordierite + muscovitearound kyanite are due to reaction with biotite. In the higher-gradeparts of this zone there is complete replacement of kyaniteand/or andalusite by muscovite and cordierite. Cordierite chemistryindicates that in Zone II the stable AFM assemblage (not attained)would have been cordierite + biotite + muscovite, without andalusite.The observed andalusite is therefore metastable. Garnet is unstablein Zone II, with regional garnets breaking down to cordierite,new biotite and plagioclase. In Zone III this breakdown is welladvanced, and this zone marks the appearance of fibrolite andK-feldspar in the groundmass as a result of muscovite breakdown.Zone IV shows garnet with cordierite, biotite, sillimanite,K-feldspar and quartz. Some garnets are armoured by cordieriteand are inferred to be relics. Others are euhedral with Mn-richcores. For these, the reaction biotite + sillimanite + quartz garnet + cordierite + K-feldspar + melt is inferred. Usinga petrogenetic grid based on the work of Pattison and Harte,pressure is estimated at 3·2 kbar, and temperature atthe Zone II–III boundary at 650°C and in Zone IV asat least 750°C. KEY WORDS: contact metamorphism; disequilibrium  相似文献   

12.
The Meatiq basement, which is exposed beneath late Proterozoic nappes of supracrustal rocks in the Central Eastern Desert of Egypt, was affected by three metamorphic events. The ophiolite cover nappes show only the last metamorphic overprint. The M1 metamorphic event (T ≥750 °C) is restricted to migmatized amphibolite xenoliths within the Um Ba′anib orthogneiss in the structurally lowest parts of the basement. Typical upper amphibolite facies M2 mineral assemblages include Grt–Zn-rich Spl–Qtz±Bt, Grt–Zn-rich Spl–Ms–Kfs–Bt–Sil–Qtz and locally kyanite in metasedimentary rocks. The mineral assemblages Ms–Qtz–Kfs–Sil in the matrix and Sil–Grt in garnet cores indicate that peak M2 P–T conditions exceeded muscovite and staurolite stabilities. Diffusional equilibration at M2 peak temperature conditions caused homogeneous chemical profiles across M2 garnets. Abundant staurolite in garnet rims and the matrix indicates a thorough equilibration during M2 at decreasing temperature conditions. M2 P–T conditions ranged from 610 to 690 °C at 6–8 kbar for the metamorphic peak and 530–600 °C at about 5.8 kbar for the retrograde stage. However, relic kyanite indicates pressures above 8 kbar, preceeding the temperature peak. A clockwise P–T path is indicated by abundant M2 sillimanite after relic kyanite and by andalusite after sillimanite. M2 fluid inclusions, trapped in quartz within garnet and in the quartz matrix show an array of isochores. Steepest isochores (water-rich H2O-CO2±CH4/N2 inclusions) pass through peak M2 P–T conditions and flatter isochores (CO2-rich H2O-CO2±CH4/N2 inclusions) are interpreted to represent retrograde fluids which is consistent with a clockwise P–T path for M2. The M3 assemblage Grt–Chl in the uppermost metasedimentary sequence of the basement limits temperature to 460 to 550 °C. M3 temperature conditions within the ophiolite cover nappes are limited by the assemblage Atg–Trem–Tlc to<540 °C and the absence of crysotile to >350 °C. The polymetamorphic evolution in the basement contrasts with the monometamorphic ophiolite nappes. The M1 metamorphic event in the basement occurred prior to the intrusion of the Um Ba′anib granitoid at about 780 Ma. The prograde phase of the M2 metamorphic event took place during the collision of an island arc with a continent. The break-off of the subducting slab increased the temperature and resulted in the peak M2 mineral assemblages. During the rise of the basement domain retrograde M2 mineral assemblages were formed. The final M3 metamorphic event is associated with the updoming of the basement domain at about 580 Ma along low-angle normal faults.  相似文献   

13.
Kyanite replaces andalusite in a belt of Ordovician and Silurian pelitic rocks that form a narrow synform pinched between high-grade antiforms in NW Variscan Iberia. Kyanite occurs across the belt in Al-rich, black pelites in assemblages I: kyanite–chloritoid–chlorite–muscovite and II: kyanite–staurolite– chlorite–muscovite. In I, kyanite occurs in the matrix and in kyanite–muscovite aggregates that pseudomorph earlier andalusite porphyroblasts. The aggregates are found across the belt and can still be recognized in assemblage II and even in III: andalusite–staurolite–biotite–muscovite, this latter being a hornfelsic Silurian schist where kyanite is relic and staurolite occurs in the matrix, and is resorbed inside new massive pleochroic andalusite. KFMASH and MnKFMASH pseudosections have been constructed using Thermocalc for Al-rich and Al-poorer compositions from the belt. Chloritoid zoning in Al-rich rocks containing assemblage I, plus chloritoid–chlorite thermometry complemented with garnet–chlorite thermometry in Al-poorer lithologies, mean that the path is one of increasing pressure and temperature. Conditions prior to assemblage I, with earlier andalusite stable, are those of the andalusite–chloritoid– chlorite field as testified by chloritoid enclosed in andalusite porphyroblast rims. The passage from assemblage I to II implies a prograde path within the kyanite field. Assemblage III represents peak conditions, indicating a prograde staurolite-consuming reaction across a KFMASH field, leading eventually to a locally found andalusite–biotite–muscovite hornfels. The lowest pressure stages are recorded by cordierite–biotite in Al-poor pelites. Garnet-bearing MnKFMASH assemblages in Al-poorer pelites record conditions similar to assemblages II and III. The replacement of andalusite by kyanite in assemblage I is attributed to downdragging of andalusite-bearing rocks into a synform as testified by the strained andalusite porphyroblasts affected by a subvertical crenulation cleavage. Prograde metamorphism in the eastern contact of the belt is due to heat transferred to the belt from the ascending high grade antiform across the Vivero fault.  相似文献   

14.
Quartz‐rich veins in metapelitic schists of the Sanandaj‐Sirjan belt, Hamadan region, Iran, commonly contain two Al2SiO5 polymorphs, and, more rarely, three coexisting Al2SiO5 polymorphs. In most andalusite and sillimanite schists, the types of polymorphs in veins correlate with Al2SiO5 polymorph(s) in the host rocks, although vein polymorphs are texturally and compositionally distinct from those in adjacent host rocks; e.g. vein andalusite is enriched in Fe2O3 relative to host rock andalusite. Low‐grade rocks contain andalusite + quartz veins, medium‐grade rocks contain andalusite + sillimanite + quartz ± plagioclase veins, and high‐grade rocks contain sillimanite + quartz + plagioclase veins/leucosomes. Although most andalusite and sillimanite‐bearing veins occur in host rocks that also contain Al2SiO5, kyanite‐quartz veins crosscut rocks that lack Al2SiO5 (e.g. staurolite schist, granite). A quartz vein containing andalusite + kyanite + sillimanite + staurolite + muscovite occurs in andalusite–sillimanite host rocks. Textural relationships in this vein indicate the crystallization sequence andalusite to kyanite to sillimanite. This crystallization sequence conflicts with the observation that kyanite‐quartz veins post‐date andalusite–sillimanite veins and at least one intrusive phase of a granite that produced a low‐pressure–high‐temperature contact aureole; these relationships imply a sequence of andalusite to sillimanite to kyanite. Varying crystallization sequences for rocks in a largely coherent metamorphic belt can be explained by P–T paths of different rocks passing near (slightly above, slightly below) the Al2SiO5 triple point, and by overprinting of multiple metamorphic events in a terrane that evolved from a continental arc to a collisional orogen.  相似文献   

15.
High‐pressure kyanite‐bearing felsic granulites in the Bashiwake area of the south Altyn Tagh (SAT) subduction–collision complex enclose mafic granulites and garnet peridotite‐hosted sapphirine‐bearing metabasites. The predominant felsic granulites are garnet + quartz + ternary feldspar (now perthite) rocks containing kyanite, plagioclase, biotite, rutile, spinel, corundum, and minor zircon and apatite. The quartz‐bearing mafic granulites contain a peak pressure assemblage of garnet + clinopyroxene + ternary feldspar (now mesoperthite) + quartz + rutile. The sapphirine‐bearing metabasites occur as mafic layers in garnet peridotite. Petrographical data suggest a peak assemblage of garnet + clinopyroxene + kyanite + rutile. Early kyanite is inferred from a symplectite of sapphirine + corundum + plagioclase ± spinel, interpreted to have formed during decompression. Garnet peridotite contains an assemblage of garnet + olivine + orthopyroxene + clinopyroxene. Thermobarometry indicates that all rock types experienced peak P–T conditions of 18.5–27.3 kbar and 870–1050 °C. A medium–high pressure granulite facies overprint (780–820 °C, 9.5–12 kbar) is defined by the formation of secondary clinopyroxene ± orthopyroxene + plagioclase at the expense of garnet and early clinopyroxene in the mafic granulites, as well as by growth of spinel and plagioclase at the expense of garnet and kyanite in the felsic granulite. SHRIMP II zircon U‐Pb geochronology yields ages of 493 ± 7 Ma (mean of 11) from the felsic granulite, 497 ± 11 Ma (mean of 11) from sapphirine‐bearing metabasite and 501 ± 16 Ma (mean of 10) from garnet peridotite. Rounded zircon morphology, cathodoluminescence (CL) sector zoning, and inclusions of peak metamorphic minerals indicate these ages reflect HP/HT metamorphism. Similar ages determined for eclogites from the western segment of the SAT suggest that the same continental subduction/collision event may be responsible for HP metamorphism in both areas.  相似文献   

16.
Phase equilibrium modelling and monazite microprobe dating were used to characterize the polymetamorphic evolution of metapelites from the northern part of the Vepor Unit, West Carpathians. Three generations of garnet and associated metamorphic assemblages found in these rocks correspond to three distinct metamorphic events related to the Variscan orogeny, a Permian phase of crustal extension and the Alpine orogeny. Variscan staurolite‐bearing and Alpine chloritoid‐bearing assemblages record medium‐temperature and medium‐pressure regional metamorphisms reaching 540–570 °C/5–7.5 kbar and 530–550 °C/5–6.5 kbar respectively. The Permian metamorphic assemblage involves garnet, andalusite, sillimanite, biotite, muscovite, plagioclase and corundum and locally forms silica‐undersaturated andalusite‐biotite‐spinel coronas around older staurolite. The transition from andalusite to sillimanite indicates a prograde low‐pressure and medium‐temperature metamorphism characterized by temperature increase from 500 to 650 °C at ～3 kbar. As accessory monazite is abundant in the rocks, an attempt was made to derive its age of formation by means of electron microprobe‐based Th‐U‐Pb chemical dating. Despite the polymetamorphic nature of the metapelites, the monazite yielded uniform Permian ages. Microstructures confirm that monazite was formed in relation to the low‐pressure and medium‐temperature paragenesis, and the weighted average ages obtained for two different samples are 278 ± 5 and 275 ± 12 Ma respectively. The virtual lack of Variscan and Alpine monazite populations points to interesting aspects concerning the growth systematics of monazite in metamorphic rocks.  相似文献   

17.
Medium grade metapelites of the Torrox unit (Betic-Rif Belt, S Spain) contain mineral assemblages consisting of garnet (Grt), staurolite (St), cordierite (Crd), biotite, kyanite, sillimanite, andalusite, muscovite (Ms) and quartz (Qtz) and record complex reaction processes of cordierite growth through garnet and staurolite decomposition. The reaction textures, the chemical composition of the reactant and product phases, including Fe-Mg-Mn partitioning, and the results of equilibrium thermodynamic calculations indicate that these cordierite-bearing assemblages are largely deviated from equilibrium. Furthermore, the actual cordierite-forming reactions, as estimated from the assemblage and associated textures, conflict with the predictions of thermodynamically based petrogenetic grids for the model pelite system KFMASH, either those that predict the stable coexistence of cordierite + muscovite plus garnet or staurolite or those that do not foresee a field of stability for these types of assemblages. This conflict is explained in terms of cordierite growth (at ca. 575 °C and 2.5 kbar) through metastable reactions whose operation was conditioned by the relict persistence of higher pressure phases (garnet and staurolite) and phase compositions (e.g. muscovite and biotite) after fast decompression. This interpretation militates against the existence of a wide P-T range of stable coexistence at low P of Crd + Ms + Qtz ± Grt ± St in medium grade metapelites of normal composition (i.e. poor in Zn and/or Mn). The triggering of metastable cordierite-forming reactions and the preservation of even subtle disequilibrium features associated to them indicate that the rocks underwent fast near-isothermal decompression from ca. 12 kbar down to 2–3 kbar, then rapid cooling. These inferences agree with independent evidence indicating that termination of alpine metamorphism in the western Betic-Rif Belt was related to the extensional collapse of thickened crust and that the latter had consisted of a single, continuous event. Received: 6 August 1998 / Accepted: 9 February 1999  相似文献   

18.
We combine structural observations, petrological data and 40Ar–39Ar ages for a stack of amphibolite facies metasedimentary units that rims high‐P (HP) granulite facies felsic bodies exposed in the southern Bohemian Massif. The partly migmatitic Varied and Monotonous units, and the underlying Kaplice unit, show a continuity of structures that are also observed in the adjacent Blanský les HP granulite body. They all exhibit an earlier NE?SW striking and steeply NW‐dipping foliation (S3), which is transposed into a moderately NW‐dipping foliation (S4). In both the Varied and Monotonous units, the S3 and S4 foliations are characterized by a Sil–Bt–Pl–Kfs–Qtz–Ilm±Grt assemblage, with occurrences of post‐D4 andalusite, cordierite and muscovite. In the Monotonous unit, minute inclusions of garnet, kyanite, sillimanite and biotite are additionally found in plagioclase from a probable leucosome parallel to S3. The Kaplice unit shows rare staurolite and kyanite relicts, a Sil–Ms–Bt–Pl–Qtz±Grt assemblage associated with S3, retrogressed garnet?staurolite aggregates during the development of S4, and post‐D4 andalusite, cordierite and secondary muscovite. Mineral equilibria modelling for representative samples indicates that the Varied unit records conditions higher than ~7 kbar at 725 °C during the transition from S3 to S4, followed by a P?T decrease from ~5.5 kbar/750 °C to ~4.5 kbar/700 °C. The Monotonous unit shows evidence of partial melting in the S3 fabric at P?T above ~8 kbar at 740–830 °C and a subsequent P?T decrease to 4.5–5 kbar/700 °C. The Kaplice unit preserves an initial medium‐P prograde path associated with the development of S3 reaching peak P?T of ~6.5 kbar/640 °C. The subsequent retrograde path records 4.5 kbar/660 °C during the development of S4. 40Ar–39Ar geochronology shows that amphibole and biotite ages cluster at c. 340 Ma close to the HP granulite, whereas adjacent metasedimentary rocks preserve c. 340 Ma amphibole ages, but biotite and muscovite ages range between c. 318 and c. 300 Ma. The P?T conditions associated with S3 imply an overturned section of the orogenic middle crust. The shared structural evolution indicates that all mid‐crustal units are involved in the large‐scale folding cored by HP granulites. The retrograde P–T paths associated with S4 are interpreted as a result of a ductile thinning of the orogenic crust at a mid‐crustal level. The 40Ar–39Ar ages overlap with U–Pb zircon ages in and around the HP granulite bodies, suggesting a short duration for the ductile thinning event. The post‐ductile thinning late‐orogenic emplacement of the South Bohemian plutonic complex is responsible for a re‐heating of the stacked units, reopening of argon system in mica and a tilting of the S4 foliation to its present‐day orientation.  相似文献   

19.
浙西南八都杂岩早中生代泥质麻粒岩变质作用及构造意义   总被引：1，自引：0，他引：1  
遂昌-大柘泥质麻粒岩出露于华夏地块东北部的浙西南八都杂岩中,该岩石保留了典型的减压反应结构.但其变质演化特点、变质作用时代及构造意义目前尚不明确.通过系统的岩相学、矿物化学和同位素年代学分析,结果表明遂昌-大柘泥质麻粒岩记录了4个阶段的变质矿物组合,其中早期进变质阶段M1的矿物组合为石榴石+黑云母+石英;压力峰期变质阶段M2的矿物组合为石榴石+铝绿泥石+金红石+蓝晶石+刚玉+黑云母+石英±十字石,该矿物组合可能预示着岩石曾经历了超高压变质作用过程;峰期变质阶段M3的矿物组合为石榴石+黑云母+夕线石+石英±钾长石±斜长石±钛铁矿;峰后近等温降压M4-1阶段的矿物组合为石榴石+黑云母+夕线石+堇青石+石英+钛铁矿±尖晶石±斜长石±钾长石;M4-2阶段的矿物组合为石榴石+堇青石+夕线石+斜长石+黑云母+石英±钾长石.相平衡模拟结合传统地质温压计限定其峰期变质阶段的温压条件为T=780~810 ℃、P=8.0~9.2 kbar;峰期后近等温降压的M4-1阶段的温压条件为T=780~860 ℃和P=5.7~6.0 kbar,M4-2阶段的温压条件为T=~700 ℃和P=~4.4 kbar,具有典型的顺时针近等温减压型P-T轨迹特征.LA-ICP-MS U-Pb定年结果表明其麻粒岩相变质作用时代为233.5~238.9 Ma.变质作用历史说明浙西南地体可能卷入了古特提斯洋域内印支-华南-华北板块之间的俯冲-碰撞过程,并经历了早中生代的麻粒岩相变质作用后快速折返至地表.   相似文献   

20.
The Leverburgh Belt and South Harris Igneous Complex in South Harris (northwest Scotland) experienced high-pressure granulite facies metamorphism during the Palaeoproterozoic. The metamorphic history has been determined from the following mineral textures and compositions observed in samples of pelitic, quartzofeldspathic and mafic gneisses, especially in pelitic gneisses from the Leverburgh Belt: (1) some coarse-grained garnet in the pelitic gneiss includes biotite and quartz in the inner core, sillimanite in the outer core, and is overgrown by kyanite at the rims; (2) garnet in the pelitic gneiss shows a progressive increase in grossular content from outer core to rims; (3) the AlVI/AlIV ratio of clinopyroxene from mafic gneiss increases from core to rim; (4) retrograde reaction coronas of cordierite and hercynite+cordierite are formed between garnet and kyanite, and orthopyroxene+cordierite and orthopyroxene+plagioclase reaction coronas develop between garnet and quartz; (5) a P–T path is deduced from inclusion assemblages in garnet and from staurolite breakdown reactions to produce garnet+sillimanite and garnet+sillimanite+hercynite with increasing temperature; and (6) in sheared and foliated rocks, hydrous minerals such as biotite, muscovite and hornblende form a foliation, modifying pre-existing textures. The inferred metamorphic history of the Leverburgh Belt is divided into four stages, as follows: (M1) prograde metamorphism with increasing temperature; (M2) prograde metamorphism with increasing pressure; (M3) retrograde decompressional metamorphism with decreasing pressure and temperature; and (M4) retrograde metamorphism accompanied by shearing. Peak P–T conditions of the M2 stage are 800±30 °C, 13–14 kbar. Pressure increasing from M1 to M2 suggests thrusting of continental crust over the South Harris belt during continent–continent collision. The inferred P–T path and tectonic history of the South Harris belt are different from those of the Lewisian of the mainland.  相似文献   

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