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1.
We report the first precise U–Pb isotope data on cassiterite from the large Xianghualing tin-polymetallic deposit in the central Nanling district, South China. The results show that four separates from sample XF-51 have a relatively narrow range of 206Pb/238U apparent ages, varying from 152 to 157 Ma, and the three 206Pb/238U apparent ages yield a weighted average value of 156 ± 4 Ma (MSWD = 0.32). Separates from two other cassiterite samples do not have sufficient radiogenic Pb to generate a reliable 206Pb/238U age. Seven separates from the above three cassiterite samples define a well-constrained 238U–206Pb isochron corresponding to an age of 157 ± 6 Ma (MSWD = 34). A comparison of the U–Pb cassiterite ages with published Ar–Ar dates on muscovite from this deposit and K–Ar age data on biotite from the pluton genetically related to the tin mineralization in this area demonstrates that the U–Pb isotope system of cassiterite is a potential geochronometer. Combined with the Ar–Ar dates of muscovite from this deposit, we can constrain the absolute age of tin-polymetallic mineralization in Xianghualing at 154–157 Ma. The dates obtained in this study, consistent with the published geochronological results from other important deposits in this region, reveal that the large-scale tungsten–tin mineralization in the central Nanling region was predominantly emplaced during 150–161 Ma.  相似文献   

2.
The 40Ar/39Ar age of the productive stage of the ore-forming hydrothermal process at the large Tokur gold deposit is 122.4 ± 2.0 Ma. This estimate suggests a paragenetic relationship of this deposit with the nearly exposed Karaurak subvolcanic trachyrhyodacite intrusion, the U—Pb zircon age of which was previously estimated at 120 ± 5 Ma. The age of mineralization at the Tokur deposit is close to the time of formation of some other deposits in the Russian Far East localized in various structural units.  相似文献   

3.
Application of multiple chronometers (including U–Pb and 40Ar/39Ar geochronology and zircon and apatite (U–Th)/He thermochronology) to porphyry intrusions at the Bajo de la Alumbrera porphyry copper–gold deposit, Argentina, reveals a complex history of reheating that spans millions of years. Previous U–Pb geochronology, combined with our new 40Ar/39Ar data, shows that the multiple porphyritic intrusions at Bajo de la Alumbrera were emplaced during two episodes, the first at about 8.0 Ma (P2 and associated porphyries) and the second about a million years later (Early and Late P3 porphyries). Complex overprinting alteration events have obscured the earliest hydrothermal history of the deposit. By contrast, 40Ar/39Ar data reveal the close temporal relationship of ore-bearing potassic alteration assemblages (7.12 ± 0.13 Ma; biotite) to the emplacement of the P3 intrusions. Consistent with low closure temperatures, younger ages have been determined for associated hydrothermal alkali feldspar (6.82 ± 0.05 Ma and 6.64 ± 0.09 Ma). The temperature-sensitive Ar data also record an unexpected prolonged cooling history (to below 200°C) extending to 5.9 Ma. Our data suggest that the Bajo de la Alumbrera system underwent protracted cooling, after the collapse of the main hydrothermal system, or that one or more low-temperature (~100–200°C) reheating events occurred after emplacement of the porphyritic intrusions at Bajo de la Alumbrera. These have been constrained in part by our new 40Ar/39Ar data (including multidomain diffusion modeling) and (U–Th)/He ages. Single-grain (U–Th)/He ages (n = 5) for phenocrystic zircon from P2 and P3 intrusive phases bracket these thermal events to between 6.9 (youngest crystallization of intrusion) and 5.1 Ma. Multidomain modeling of alkali feldspar data (from both igneous and hydrothermal crystals) is consistent with the deposit cooling rapidly from magmatic temperatures to below about 300°C, with a more protracted history down to 150°C. We conclude that the late-stage low-temperature (150 to 200°C) thermal anomaly localized at Bajo de la Alumbrera resulted from radiation of heat and/or fluids sourced from deeper-seated magma bodies, emplaced beneath the deposit. To produce the observed thermal longevity of the porphyry system, magma bodies underlying the Bajo de la Alumbrera deposit must have been repeatedly replenished by new magma batches. Without replenishment, crystallization of the source magma will occur, and heat release will stop, leading to rapid cooling (in less than ten thousand years). The influx of deep-seated magma may have caused the development of late low-temperature hydrothermal alteration assemblages at Bajo de la Alumbrera, at the same time that mineralization formed at Agua Rica, some 25 km away. All available chronologic data for the Bajo de la Alumbrera deposit suggest that the hydrothermal system was active episodically over at least a three-million and possibly up to a four-million-year period. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

4.
Recent advances in U–Pb geochronology allow unprecedented levels of precision in the determination of geological ages. However, increased precision has also illuminated the importance of understanding subtle sources of open-system behavior such as Pb-loss, inheritance, intermediate daughter product disequilibria, and the accuracy of the model assumptions for initial Pb. Deconvolution of these effects allows a much richer understanding of the power and limitations of U–Pb geochronology and thermochronology. In this study, we report high-precision ID-TIMS U–Pb data from zircon, baddelleyite, titanite and apatite from the McClure Mountain syenite, from which the 40Ar/39Ar hornblende standard MMhb is derived. We find that excess 206Pb in zircon due to inclusions of high-Th minerals and elevated Th/U in titanite and apatite jeopardize the utility of the 238U–206Pb system in this rock. Strongly air-abraded zircons give dates that are younger than chemical-abraded zircons, which yield a statistically robust 207Pb/235U date of 523.98±0.12 Ma that is interpreted as the crystallization age. We explore the best method of Pbc correction in titanite and apatite by analyzing the U–Pb isotopes of K-feldspar and using 2-D and 3-D regression methods—the latter of which yields the best results in each case. However, the calculated compositions of Pbc for titanite, apatite and K-feldspar are different, implying that using a single Pbc correction for multiple U–Pb thermochronometers may be inaccurate. The U–Pb thermochronological results are used to predict a closure time for Ar in hornblende of 522.98±1.00 Ma. Widely cited K–Ar and 40Ar/39Ar dates overlap with the U–Pb date, and relatively large errors make it impossible to verify whether U–Pb dates are systematically ≤1% older than K–Ar and 40Ar/39Ar dates.  相似文献   

5.
Life spans and thermal evolution of hydrothermal systems are of fundamental metallogenic importance. We were able to establish the chronology and cooling history of the Zaldívar porphyry copper deposit (Northern Chile) by applying a combination of different isotopic dating methods in minerals with different closure temperatures, including 40Ar/39Ar geochronology and zircon fission track thermochronology, together with fluid inclusion thermometry and previous published U–Pb zircon geochronology. The hydrothermal mineralization in the Zaldívar deposit is genetically related to the Llamo Porphyry unit. Samples of igneous biotites from this intrusion yielded 40Ar/39Ar plateau ages between 35.5 ± 0.7 and 37.7 ± 0.4 Ma defining a weighted average of 36.6 ± 0.5 Ma (2σ). In contrast, one sample from the Zaldívar porphyry, one from the andesites, and two from the Llamo porphyry yielded considerably younger fission track ages of approximately 29 Ma with a weighted mean for all ages of 29.1 ± 1.7 Ma (2σ). Thermal and compositional constraints for the hydrothermal system in the Zaldívar deposit from fluid inclusions thermometry show that at least three fluid types broadly characterize two main hydrothermal episodes during the evolution of the deposit. The main mineralization and alteration event is characterized by high temperature (above 320°C) hypersaline fluids (salinity between 30 and 56 wt.% NaCl equivalents) coexisting with low-density gas-rich inclusions (salinity less than 17 wt.% NaCl equivalents) that homogenizing into the gas phase at temperatures above 350°C. The second episode corresponds to a low-temperature event which is characterized by liquid-rich fluid inclusions that homogenize into the liquid phase at temperatures ranging from 200°C to 300°C with salinities lower than 10 wt.% NaCl equivalents. The 40Ar/39Ar data (36.6 ± 0.5 Ma, weighted average) obtained from igneous biotites represent the minimum age for the last high-temperature (above 300°C) hydrothermal pulse. When compared with previously published U–Pb ages (38.7 ± 1.3 Ma) in zircons from the Llamo porphyry, a close temporal relationship between crystallization of the parental intrusion and the thermal collapse of the last high-temperature hydrothermal event is evident. Cooling took place from approximately 800°C (crystallization of the intrusive complex defined by zircon U–Pb ages) to below 300 ± 50°C (biotite 40Ar/39Ar closure temperature) within approximately 1.5 m.y. Because the thermal annealing of fission tracks in zircons occurs at temperatures of 240 ± 30°, the zircon fission track (ZFT) ages of 29.1 ± 1.7 Ma (2σ) mark the end of the thermal activity in the Zaldívar area, specifically the time when the whole area cooled below this temperature, well after the collapse of the main hydrothermal event in the Zaldívar porphyry copper deposit. This cooling age roughly coincides with the age defined for the emplacement of dacitic dikes at 31 ± 2.8 Ma (2σ) (published K–Ar whole rock), 5 km south of the Zaldívar deposit, in the Escondida area. This late magmatic pulse probably is responsible for high heat flow in the Zaldívar deposit as late as 29 Ma. There is no evidence that the low temperature hydrothermal pulse recognized by fluid inclusion studies is related to this thermal event. The zircon fission track cooling ages are interpreted to be related to the time lag required for complete relaxation of the perturbation of the isotherms in the geothermal field imposed by the intrusion of magmatic bodies, with or without any association with low temperature hydrothermal activity.  相似文献   

6.
In situ SHRIMP U–Pb dating of magmatic zirconolite (CaZrTi2O7) in the Golden Mile Dolerite from the Mt Charlotte gold deposit (Yilgarn Craton, Australia) has yielded the first robust emplacement age (2,680 ± 9 Ma) for the principle host-rock of gold mineralization in the Kalgoorlie district. In contrast, co-magmatic zircon gave ages from ~2.68 Ga to ~2.17 Ga, reflecting isotopic resetting of high-U and -Th crystals. In situ SHRIMP analysis of hydrothermal xenotime (YPO4), which co-exists with gold in alteration pyrite, provided a Pb/Pb isochron age of 2,655 ± 13 Ma. This date indicates that the youngest deposit in the Kalgoorlie district (Mt Charlotte) formed at ~2.65 Ga, and provides a new minimum age for the structurally older Golden Mile deposit. Our results indicate that gold mineralization at Mt Charlotte is ~50 million years older than indicated by recent 40Ar/39Ar dating and places new constraints on the timing of late-stage regional faulting (D4) in the province.  相似文献   

7.
Summary The northwest-striking Pfahl zone, Bavarian Forest, is a mylonitic shear zone that is associated with brittle-ductile deformation fabrics and a conspicuous hydrothermal quartz mineralization. Two granites from this shear zone yield U–Pb and Pb–Pb evaporation ages between 321–329 Ma and two granodiorites give concordant 238U–206Pb and 235U–207Pb ages of 325±3 Ma and 326±3 Ma, respectively. Zircon populations of the granitoids show sub-types clustering around S20, S10 (granite) and S22 to S24 (granodiorite) testifying different magma affinity. Compositional and isotopic characteristics indicate that the granites and granodiorites were coeval melts, but not differentiates of a single parent magma. The granodiorites were derived from a source with higher time-integrated 87Rb/86Sr and lower 147Sm/144Nd ratios than the granites. One granite body is transected by the shear zone but the main mass of the granite is largely undeformed. This finding suggests that granite intrusion predates the final stage of ductile deformation along the Pfahl shear zone.  相似文献   

8.
Host rocks to the Aitik Cu–Au–Ag deposit in northern Sweden are strongly altered and deformed Early Proterozoic mica(-amphibole) schists and gneisses. The deposit is characterised by numerous mineralisation styles, vein and alteration types. Four samples were selected for Re–Os molybdenite dating and 12 samples for U–Pb titanite dating in order to elucidate the magmatic/hydrothermal and metamorphic history following primary ore deposition in the Aitik Cu–Au–Ag deposit. Samples represent dyke, vein and alteration assemblages from the ore zone, hanging wall and footwall to the deposit. Re–Os dating of molybdenite from deformed barite and quartz veins yielded ages of 1,876±10 Ma and 1,848±8 Ma, respectively. A deformed pegmatite dyke yielded a Re–Os age of 1,848±6 Ma, and an undeformed pegmatite dyke an age of 1,728±7 Ma. U–Pb dating of titanite from a diversity of alteration mineral associations defines a range in ages between 1,750 and 1,805 Ma with a peak at ca. 1,780 Ma. The ages obtained, together with previous data, bracket a 160-Ma (1,890–1,730 Ma) time span encompassing several generations of magmatism, prograde to peak metamorphism, and post-peak cooling; events resulting in the redistribution and addition of metals to the deposit. This multi-stage evolution of the Aitik ore body suggests that the deposit was affected by several thermal events that ultimately produced a complex ore body. The Re–Os and U–Pb ages correlate well with published regional Re–Os and U–Pb age clusters, which have been tied to major magmatic, hydrothermal, and metamorphic events. Primary ore deposition at ca. 1,890 Ma in connection with intrusion of Haparanda granitoids was followed by at least four subsequent episodes of metamorphism and magmatism. Early metamorphism at 1,888–1,872 Ma overlapping with Haparanda (1,890–1,880 Ma) and Perthite-monzonite (1,880–1,870 Ma) magmatism clearly affected the Aitik area, as well as late metamorphism and Lina magmatism at 1,810–1,774 Ma and TIB1 magmatism at 1,800 Ma. The 1,848 Ma Re–Os ages obtained from molybdenite in a quartz vein and pegmatite dyke suggests that the 1,850 Ma magmatism recorded in parts of northern Norrbotten also affected the Aitik area.  相似文献   

9.
The Valhalla uranium deposit, located 40 km north of Mount Isa, Queensland, Australia, is an albitite-hosted, Mesoproterozoic U deposit similar to albitite-hosted uranium deposits in the Ukraine, Sweden, Brazil and Guyana. Uranium mineralisation is hosted by a thick package of interbedded fine-grained sandstones, arkoses and gritty siltstones that are bound by metabasalts belonging to the ca. 1,780 Ma Eastern Creek Volcanics in the Western Succession of the Mount Isa basin. Alteration associated with U mineralisation can be divided into an early, main and late stage. The early stage is dominated by laminated and intensely altered rock comprising albite, reibeckite, calcite, (titano)magnetite ± brannerite. The main stage of mineralisation is dominated by brecciated and intensely altered rocks that comprise laminated and intensely altered rock cemented by brannerite, apatite, (uranoan)-zircon, uraninite, anatase, albite, reibeckite, calcite and hematite. The late stage of mineralisation comprises uraninite, red hematite, dolomite, calcite, chlorite, quartz and Pb-, Fe-, Cu-sulfides. Brannerite has U–Pb and Pb–Pb ages that indicate formation between 1,555 and 1,510 Ma, with significant Pb loss evident at ca. 1,200 Ma, coincident with the assemblage of Rodinia. The oldest ages of the brannerite overlap with 40Ar/39Ar ages of 1,533 ± 9 Ma and 1,551 ± 7 Ma from early and main-stage reibeckite and are interpreted to represent the timing of formation of the deposit. These ages coincide with the timing of peak metamorphism in the Mount Isa area during the Isan Orogeny. Lithogeochemical assessment of whole rock data that includes mineralised and unmineralised samples from the greater Mount Isa district reveals that mineralisation involved the removal of K, Ba and Si and the addition of Na, Ca, U, V, Zr, P, Sr, F and Y. U/Th ratios indicate that the ore-forming fluid was oxidised, whereas the crystal chemistry of apatite and reibeckite within the ore zone suggests that F− and were important ore-transporting complexes. δ18O values of co-existing calcite and reibeckite indicate that mineralisation occurred between 340 and 380°C and involved a fluid having δ18Ofluid values between 6.5 and 8.6‰. Reibeckite δD values reveal that the ore fluid had a δDfluid value between −98 and −54‰. The mineral assemblages associated with early and main stages of alteration, plus δ18Ofluid and δDfluid values, and timing of the U mineralisation are all very similar to those associated with Na–Ca alteration in the Eastern Succession of the Mount Isa basin, where a magmatic fluid is favoured for this style of alteration. However, isotopic data from Valhalla is also consistent with that from the nearby Mount Isa Cu deposit where a basinal brine is proposed for the transport of metals to the deposit. Based on the evidence to hand, the source fluids could have been derived from either or both the metasediments that underlie the Eastern Creek Volcanics or magmatism that is manifest in the Mount Isa area as small pegmatite dykes that intruded during the Isan Orogeny.  相似文献   

10.
The Alligator Rivers Uranium Field (ARUF) includes the mined and unmined Jabiluka, Ranger, Koongarra and Nabarlek unconformity-related uranium deposits and several small prospects including the newly discovered King River prospect. Uranium mineralisation is hosted by a variety of metamorphosed Nimbuwah Domain lithologies that are unconformably overlain by the Kombolgie Subgroup, a basin package of unmetamorphosed arenites and mafic volcanics. All of the uranium deposits and prospects preserve an identical alteration assemblage that is subdivided into a distal and proximal alteration zone. The distal alteration zone comprises an assemblage of sericite and chlorite that replace albite and amphibole. In some cases, this alteration can be traced >1000 m from the proximal alteration zone that is dominated by uraninite, hematite, chlorite and sericite. Uranium precipitated in the basement as uraninite at 1680 Ma at around 200°C from a fluid having δ18Ofluid values of 3.0±2.8‰ and δDfluid values of ?28±13‰ VSMOW reflecting an evolved marine source. These geochemical properties are indistinguishable from those recorded by diagenetic illite and chlorite that were collected from the Kombolgie Subgroup sandstones across the ARUF. The illite and chlorite formed in diagenetic aquifers, and where these aquifers intersected favourable basement rocks, such as those containing graphite or other reductants, U was precipitated as uraninite. Therefore, it is proposed that the Kombolgie Subgroup is the source for fluids that formed the deposits. A post-ore alteration assemblage dominated by chlorite, but also comprising quartz±dolomite±sulfide veins cut the uranium mineralisation at all deposits and has historically been recorded as part of the syn-ore mineralisation event. However, these minerals formed anywhere between 1500 to 630 Ma from fluids that have distinctly lower δ18Ofluid values around 1.5‰ and lower δDfluid values around ?45‰ reflecting a meteoric water origin. Despite unconformity-related uranium deposits having a large alteration halo, they remain difficult to find. The subtle alteration of albite to sericite several hundred metres from mineralisation occurs in isolation of any increase in trace elements such as U and radiogenic Pb and can be difficult or impossible to identify in hand specimen. Whole rock geochemical data indicate that Pearce Element Ratio (PER) analysis and General Element Ratio (GER) analysis may vector into this subtle alteration because it does not rely on an increase in trace elements to identify proximity to ore. PER and GER plots, Al/Ti vs (2Ca + Na + K)/Ti, Na/Al vs (Na + K)/Al, K/Al vs (Na + K)/Al and (Fe + Mg)/Al vs (Na + K)/Al provide a visual guide that readily distinguish unaltered from altered samples. A plot of (Na + K)/Al and (Fe + Mg)/Al on the x-axis against the concentration of trace elements on the y-axis reveals that U, Pb, Mo, Cu, B, Br, Ce, Y, Li, Ni, V and Nd are associated with the most intensely altered samples. The lithogeochemical vectors should aid explorers searching for uranium mineralisation in a prospective basin environment, but exploration must first focus on the characteristics of the basin to assess its mineralisation potential. A holistic model that describes the evolution of the Kombolgie Subgroup from deposition through diagenesis to formation of the uranium deposits in the underlying basement rocks is presented and has application to other basins that are considered prospective for unconformity-related uranium deposits. The model outlines that explorers will need to consider the thickness of the sedimentary pile, its lithological composition relative to depositional setting, the depth to which the sediments were buried during diagenesis and the degree of diagenesis achieved, which may be time dependant, before deciding on the prospectivity of the basin.  相似文献   

11.
The Chelopech deposit is one of the largest European gold deposits and is located 60 km east of Sofia, within the northern part of the Panagyurishte mineral district. It lies within the Banat–Srednegorie metallogenic belt, which extends from Romania through Serbia to Bulgaria. The magmatic rocks define a typical calc-alkaline suite. The magmatic rocks surrounding the Chelopech deposit have been affected by propylitic, quartz–sericite, and advanced argillic alteration, but the igneous textures have been preserved. Alteration processes have resulted in leaching of Na2O, CaO, P2O5, and Sr and enrichment in K2O and Rb. Trace element variation diagrams are typical of subduction-related volcanism, with negative anomalies in high field strength elements (HFSE) and light element, lithophile elements. HFSE and rare earth elements were relatively immobile during the hydrothermal alteration related to ore formation. Based on immobile element classification diagrams, the magmatic rocks are andesitic to dacitic in compositions. Single zircon grains, from three different magmatic rocks spanning the time of the Chelopech magmatism, were dated by high-precision U–Pb geochronology. Zircons of an altered andesitic body, which has been thrust over the deposit, yield a concordant 206Pb/238U age of 92.21 ± 0.21 Ma. This age is interpreted as the crystallization age and the maximum age for magmatism at Chelopech. Zircon analyses of a dacitic dome-like body, which crops out to the north of the Chelopech deposit, give a mean 206Pb/238U age of 91.95 ± 0.28 Ma. Zircons of the andesitic hypabyssal body hosting the high-sulfidation mineralization and overprinted by hydrothermal alteration give a concordant 206Pb/238U age of 91.45 ± 0.15 Ma. This age is interpreted as the intrusion age of the andesite and as the maximum age of the Chelopech epithermal high-sulfidation deposit. 176Hf/177Hf isotope ratios of zircons from the Chelopech magmatic rocks, together with published data on the Chelopech area and the about 92-Ma-old Elatsite porphyry–Cu deposit, suggest two different magma sources in the Chelopech–Elatsite magmatic area. Magmatic rocks associated with the Elatsite porphyry–Cu deposit and the dacitic dome-like body north of Chelopech are characterized by zircons with ɛHfT90 values of ∼5, which suggest an important input of mantle-derived magma. Some zircons display lower ɛHfT90 values, as low as −6, and correlate with increasing 206Pb/238U ages up to about 350 Ma, suggesting assimilation of basement rocks during magmatism. In contrast, zircon grains in andesitic rocks from Chelopech are characterized by homogeneous 176Hf/177Hf isotope ratios with ɛHfT90 values of ∼1 and suggest a homogeneous mixed crust–mantle magma source. We conclude that the Elatsite porphyry–Cu and the Chelopech high-sulfidation epithermal deposits were formed within a very short time span and could be partly contemporaneous. However, they are related to two distinct upper crustal magmatic reservoirs, and they cannot be considered as a genetically paired porphyry–Cu and high-sulfidation epithermal related to a single magmatic–hydrothermal system centered on the same intrusion.  相似文献   

12.
Four of the major plutons in the vicinity of the Candelaria mine (470 Mt at 0.95% Cu, 0.22 g/t Au, 3.1 g/t Ag) and a dike–sill system exposed in the Candelaria open pit have been dated with the U–Pb zircon method. The new geochronological data indicate that dacite magmatism around 123 Ma preceded the crystallization of hornblende diorite (Khd) at 118 ± 1 Ma, quartz–monzonite porphyry (Kqm) at 116.3 ± 0.4 Ma, monzodiorite (Kmd) at 115.5 ± 0.4 Ma, and tonalite (Kt) at 110.7 ± 0.4 Ma. The new ages of the plutons are consistent with field relationships regarding the relative timing of emplacement. Plutonism temporally overlaps with the iron oxide Cu–Au mineralization (Re–Os molybdenite ages at ∼115 Ma) and silicate alteration (ages mainly from 114 to 116 and 110 to 112 Ma) in the Candelaria–Punta del Cobre district. The dated dacite porphyry and hornblende diorite intrusions preceded the ore formation. A genetic link of the metallic mineralization with the quartz–monzonite porphyry and/or the monzodiorite is likely. Both of these metaluminous, shoshonitic (high-K) intrusions could have provided energy and contributed fluids, metals, and sulfur to the hydrothermal system that caused the iron oxide Cu–Au mineralization. The age of the tonalite at 110.7 Ma falls in the same range as the late alteration at 110 to 112 Ma. Tonalite emplacement may have sustained existing or driven newly developed hydrothermal cells that caused this late alteration or modified 40Ar/39Ar and K/Ar systematic in some areas.  相似文献   

13.
Large volumes of silicic magma were produced on a very short timescale in the nested caldera complex of the SW Nevada volcanic field (SWNVF). Voluminous ash flows erupted in two paired events: Topopah Spring (TS, >1,200 km3, 12.8 Ma)–Tiva Canyon (TC, 1,000 km3, 12.7 Ma) and Rainier Mesa (RM, 1,200 km3, 11.6 Ma)–Ammonia Tanks (AT, 900 km3, 11.45 Ma; all cited ages are previously published 40Ar/39Ar sanidine ages). Within each pair, eruptions are separated by only 0.1–0.15 My and produced tuffs with contrasting isotopic values. These events represent nearly complete evacuation of sheet-like magma chambers formed in the extensional Basin and Range environment. We present ion microprobe ages from zircons in the zoned ash-flow sheets of TS, TC, RM, and AT in conjunction with δ18O values of zircons and other phenocrysts, which differ dramatically among subsequently erupted units. Bulk zircons in the low-δ18O AT cycle were earlier determined to exhibit ∼1.5‰ core-to-rim oxygen isotope zoning; and high-spatial resolution zircon analyses by ion microprobe reveal the presence of older grains that are zoned by 0.5–2.5‰. The following U–Pb isochron ages were calculated after correcting for the initial U–Pb disequilibria: AT (zircon rims: 11.7 ± 0.2 Ma; cores: 12.0 ± 0.1 Ma); pre-AT rhyolite lava: (12.0 ± 0.3 Ma); RM: 12.4 ± 0.3); TC: (13.2 ± 0.15 Ma); TS: (13.5 ± 0.2). Average zircon crystallization ages calculated from weighted regression or cumulative averaging are older than the Ar–Ar stratigraphy, but preserve the comparably short time gaps within each of two major eruption cycles (TS/TC, RM/AT). Notably, every sample yields average zircon ages that are 0.70–0.35 Ma older than the respective Ar–Ar eruption ages. The Th/U ratio of SWNVF zircons are 0.4–4.7, higher than typically found in igneous zircons, which correlates with elevated Th/U of the whole rocks (5–16). High Th/U could be explained if uranium was preferentially removed by hydrothermal solutions or is retained in the protolith during partial melting. For low-δ18O AT-cycle magmas, rim ages from unpolished zircons overlap within analytical uncertainties with the 40Ar/39Ar eruption age compared to core ages that are on average ∼0.2–0.3 My older than even the age of the preceding caldera forming eruption of RM tuff. This age difference, the core-to-rim oxygen isotope zoning in AT zircons, and disequilibrium quartz–zircon and melt-zircon isotopic fractionations suggest that AT magma recycled older zircons derived from the RM and older eruptive cycles. These results suggest that the low-δ18O AT magmas were generated by melting a hydrothermally-altered protolith from the same nested complex that erupted high-δ18O magmas of the RM cycle only 0.15 My prior to the eruption of the AT, the largest volume low-δ18O magma presently known.Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.  相似文献   

14.
The importance of geochronology in the study of mineral deposits in general, and of unconformity-type uranium deposits in particular, resides in the possibility to situate the critical ore-related processes in the context of the evolution of the physical and chemical conditions in the studied area. The present paper gives the results of laser step heating 40Ar/39Ar dating of metamorphic host-rock minerals, pre-ore and syn-ore alteration clay minerals, and laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS) U/Pb dating of uraninite from a number of basement- and sediment-hosted unconformity-related deposits in the Athabasca Basin, Canada. Post-peak metamorphic cooling during the Trans-Hudson Orogen of rocks from the basement occurred at ca 1,750 Ma and gives a maximum age for the formation of the overlying Athabasca Basin. Pre-ore alteration occurred simultaneously in both basement- and sandstone-hosted mineralizations at ca 1,675 Ma, as indicated by the 40Ar/39Ar dating of pre-ore alteration illite and chlorite. The uranium mineralization age is ca 1,590 Ma, given by LA-ICP-MS U/Pb dating of uraninite and 40Ar/39Ar dating of syn-ore illite, and is the same throughout the basin and in both basement- and sandstone-hosted deposits. The mineralization event, older than previously proposed, as well as several fluid circulation events that subsequently affected all minerals studied probably correspond to far-field, continent-wide tectonic events such as the metamorphic events in Wyoming and the Mazatzal Orogeny (ca 1.6 to 1.5 Ga), the Berthoud Orogeny (ca 1.4 Ga), the emplacement of the McKenzie mafic dyke swarms (ca 1.27 Ga), the Grenville Orogeny (ca 1.15 to 1 Ga), and the assemblage and break-up of Rodinia (ca 1 to 0.85 Ga). The results of the present work underline the importance of basin evolution between ca 1.75 Ga (basin formation) and ca 1.59 Ga (ore deposition) for understanding the conditions necessary for the formation of unconformity-type uranium deposits. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

15.
The Yaogangxian deposit in the central Nanling region, South China consists of vein-type ore bodies hosted in Cambrian to Jurassic strata and Mesozoic granitic intrusions. Wolframite and molybdenite are the dominant ore minerals intergrown with gangue minerals of quartz, feldspar, phlogopite, and muscovite. We have carried out molybdenite Re–Os and phlogopite and muscovite 40Ar/39Ar dating to better understand the timing and genesis of mineralization. Re–Os dating of eight molybdenite samples yielded model ages ranging from 152.0±3.5 to 161.1±4.5 Ma, with an average of 156.0 Ma. The Re–Os analyses give a well-defined 187Re/187Os isochron with an age of 154.9±2.6 Ma (MSWD=2.4). Hydrothermal phlogopite and muscovite display extremely flat 40Ar/39Ar age spectra. Phlogopite yields a 40Ar/39Ar plateau age of 153.0±1.1 Ma, whereas muscovite yields a plateau age of 155.1±1.1 Ma. Both 40Ar/39Ar ages are in good agreement with the Re–Os ages, placing the timing of tungsten mineralization at about 154 Ma. This age is consistent with the field relationships. Our new data, when combined with published geochronological results from other major deposits in this region, suggest that large scale W–Sn mineralization occurred throughout the central Nanling region in the Late Jurassic.  相似文献   

16.
 The Sesia-Lanzo Zone is a polymetamorphic unit containing Hercynian granulite relics overprinted by eclogite and greenschist facies metamorphism and deformation during the Alpine orogeny. Different parts of the unit record different stages on the P-T-deformation evolution, allowing multi-system isotopic studies to unravel the precise timing of the metamorphic history. New Rb–Sr white mica and U–Pb sphene data constrain the age of eclogite facies metamorphism and deformation to 60–70 Ma. This substantially alters the common view of early- to mid-Cretaceous eclogite facies metamorphism in this unit. The new results are more consistent with the established geotectonic framework for the Alpine orogeny, since they do not require a prolonged period of depressed geothermal gradient at a time when the region was in extension. It is also more concordant with recent studies of other units that demonstrate post-Cretaceous high-pressure metamorphism. Step-heated 40Ar–39Ar analysis of phengites yields good plateaux giving ages older than the corresponding Rb–Sr age. Such anomalously high ages indicate the presence of radiogenic argon-rich fluids in the grain boundary network under the fluid/pressure conditions acting during this high-pressure metamorphic event. The U–Pb sphene ages are variable in polymetamorphic rocks, and show inheritance of older Pb or sphene crystals into the high-pressure event. Two monometamorphic assemblages yield concordant ages at 66±1 Ma, reflecting crystallisation of the eclogite facies assemblage. The Gneiss Minuti Complex (GMC) lies structurally below the Eclogitic Micaschists, and its pervasive greenschist facies fabric yields tightly clustered Rb–Sr white mica ages at 38–39 Ma. This greenschist event did not affect the majority of the EMC. The 40Ar–39Ar ages of micas formed at this time were very disturbed, whereas micas surviving from an earlier higher pressure assemblage had their 40Ar–39Ar system reset. The greenschist event did not strongly affect U–Pb systematics in Hercynian age sphenes, suggesting that the GMC did not uniformly suffer an eclogite facies metamorphism during the Alpine cycle, but was juxtaposed against the EMC later in the orogeny. This model still requires that the locus of deformation and metamorphism (and possibly fluid flux) moved outboard with time, leaving the Sesia-Lanzo basement as a shear-bounded unreactive block within the orogenic wedge. Received: 12 October 1995/Accepted:25 June 1996  相似文献   

17.
A temperature–time path was constructed for high-temperature low-pressure (HT–LP) migmatites of the Bayerische Wald, internal zone of the Variscan belt, Germany. The migmatites are characterised by prograde biotite dehydration melting, peak metamorphic conditions of approximately 850 °C and 0.5–0.7 GPa and retrograde melt crystallisation at 800 °C. The time-calibration of the pressure–temperature path is based on U–Pb dating of single zircon and monazite grains and titanite separates, on 40Ar/39Ar ages obtained by incremental heating experiments on hornblende separates, single grains of biotite and K-feldspar, and on 40Ar/39Ar spot fusion ages of biotite determined in situ from sample sections. Additionally, crude estimates of the duration of peak metamorphism were derived from garnet zoning patterns, suggesting that peak temperatures of 850 °C cannot have prevailed much longer than 2.5 Ma. The temperature–time paths obtained for two areas approximately 30 km apart do not differ from each other considerably. U–Pb zircon ages reflect crystallisation from melt at 850–800 °C at 323 Ma (southeastern area) and 326 Ma (northwestern area). The U–Pb ages of monazite mainly coincide with those from zircon but are complicated by variable degrees of inheritance. The preservation of inherited monazite and the presence of excess 206Pb resulting from the incorporation of excess 230Th in monazite formed during HT–LP metamorphism suggest that monazite ages in the migmatites of the Bayerische Wald reflect crystallisation from melt at 850–800 °C and persistence of older grains at these temperatures during a comparatively short thermal peak. The U–Pb ages of titanite (321 Ma) and 40Ar/39Ar ages of hornblende (322–316 Ma) and biotite (313–309 Ma) reflect cooling through the respective closure temperatures of approximately 700, 570–500 and 345–310 °C published in the literature. Most of the feldspars' ages (305–296 Ma) probably record cooling below 150–300 °C, while two grains most likely have higher closure temperatures. The temperature–time paths are characterised by a short thermal peak, by moderate average cooling rates and by a decrease in cooling rates from 100 °C/my at temperatures between 850–800 and 700 °C to 11–16 °C/my at temperatures down to 345–310 °C. Further cooling to feldspar closure for Ar was probably even slower. The lack of decompressional features, the moderate average cooling rates and the decline of cooling rates with time are not easily reconciled with a model of asthenospheric heating, rapid uplift and extension due to lithospheric delamination as proposed elsewhere. Instead, the high peak temperatures at comparatively shallow crustal levels along with the short thermal peak require external advective heating by hot mafic or ultramafic material. Received: 7 July 1999 / Accepted: 28 October 1999  相似文献   

18.
Three major mineralization events are recorded at the Rožná uranium deposit (total mine production of 23,000 t U, average grade of 0.24% U): (1) pre-uranium quartz-sulfide and carbonate-sulfide mineralization, (2) uranium, and (3) post-uranium quartz-carbonate-sulfide mineralization. (1) K–Ar ages for white mica from wall rock alteration of the pre-uranium mineralization style range from 304.5 ± 5.8 to 307.6 ± 6.0 Ma coinciding with the post-orogenic exhumation of the Moldanubian orogenic root and retrograde-metamorphic equilibration of the high-grade metamorphic host rocks. The fluid inclusion record consists of low-salinity aqueous inclusions, together with H2O-CO2-CH4, CO2-CH4, and pure CH4 inclusions. The fluid inclusion, paragenetic, and isotope data suggest that the pre-uranium mineralization formed from a reduced low-salinity aqueous fluid at temperatures close to 300°C. (2) The uraniferous hydrothermal event is subdivided into the pre-ore, ore, and post-ore substages. K–Ar ages of pre-ore authigenic K-feldspar range from 296.3 ± 7.5 to 281.0 ± 5.4 Ma and coincide with the transcurrent reorganization of crustal blocks of the Bohemian Massif and with Late Stephanian to Early Permian rifting. Massive hematitization, albitization, and desilicification of the pre-ore altered rocks indicate an influx of oxidized basinal fluids to the crystalline rocks of the Moldanubian domain. The wide range of salinities of fluid inclusions is interpreted as a result of the large-scale mixing of basinal brines with meteoric water. The cationic composition of these fluids indicates extensive interaction with crystalline rocks. Chlorite thermometry yielded temperatures of 260°C to 310°C. During this substage, uranium was probably leached from the Moldanubian crystalline rocks. The hydrothermal alteration of the ore substage followed, or partly overlapped in time, the pre-ore substage alteration. K–Ar ages of illite from ore substage alteration range from 277.2 ± 5.5 to 264.0 ± 4.3 Ma and roughly correspond with the results of chemical U–Pb dating of authigenic monazite (268 ± 50 Ma). The uranium ore deposition was accompanied by large-scale decomposition of biotite and pre-ore chlorite to Fe-rich illite and iron hydrooxides. Therefore, it is proposed that the deposition of uranium ore was mostly in response to the reduction of the ore-bearing fluid by interaction with ferrous iron-bearing silicates (biotite and pre-ore chlorite). The Th data on primary, mostly aqueous, inclusions trapped in carbonates of the ore substage range between 152°C and 174°C and total salinity ranges over a relatively wide interval of 3.1 to 23.1 wt% NaCl eq. Gradual reduction of the fluid system during the post-ore substage is manifested by the appearance of a new generation of authigenic chlorite and pyrite. Chlorite thermometry yielded temperatures of 150°C to 170°C. Solid bitumens that post-date uranium mineralization indicate radiolytic polymerization of gaseous and liquid hydrocarbons and their derivatives. The origin of the organic compounds can be related to the diagenetic and catagenetic transformation of organic matter in Upper Stephanian and Permian sediments. (3) K–Ar ages on illite from post-uranium quartz-carbonate-sulfide mineralization range from 233.7 ± 4.7 to 227.5 ± 4.6 Ma and are consistent with the early Tethys-Central Atlantic rifting and tectonic reactivation of the Variscan structures of the Bohemian Massif. A minor part of the late Variscan uranium mineralization was remobilized during this hydrothermal event.  相似文献   

19.
The Chengchao and Jinshandian deposits in the southeast Hubei Province are the two largest skarn Fe deposits in the Middle–Lower Yangtze River Valley metallogenic belt (MLYRVMB), China. They are characterized by NW-striking orebodies that are developed along the contacts between the Late Mesozoic granitoid and Triassic carbonate and clastic rocks. New sensitive high-resolution ion microprobe and laser ablation inductively coupled plasma mass spectrometry zircon U–Pb dating of the mineralization-related quartz diorite and granite at Chengchao yield ages of 129 ± 2 and 127 ± 2 Ma, respectively, and those at Jinshandian of 127 ± 2 and 133 ± 1 Ma, respectively. These results are interpreted as the crystallization age of these intrusions. Hydrothermal phlogopite samples from the skarn ores at Chengchao and Jinshandian have the plateau 40Ar–39Ar ages of 132.6 ± 1.4 and 131.6 ± 1.2 Ma, respectively. These results confirm that both intrusions and associated skarn Fe mineralization were formed contemporaneously in the middle Early Cretaceous time. New zircon U–Pb and phlogopite 40Ar–39Ar ages in this study, when combined with available precise geochronological data, demonstrate that there were two discontinuous igneous events, corresponding to two episodes of skarn Fe-bearing mineralization in the southeast Hubei Province: (1) 140–136 Ma diorites and quartz diorites and 141–137 Ma skarn Cu–Fe or Fe–Cu deposits and (2) 133–127 Ma quartz diorites and granites and 133–132 Ma skarn Fe deposits. This scenario is similar to that proposed for the entire MLYRVMB. The intrusions related to skarn Fe deposits show obviously petrological and geochemical differences from those related to skarn Cu–Fe or Fe–Cu deposits. The former are quartz diorite and diorite in petrology and have similar adakitic geochemical signatures and in equilibrium with a garnet-rich residue, whereas the latter are petrologically granite and quartz diorite that are distinguishable from adakitic rocks and in equilibrium with a plagioclase residue. These features indicated that two episodes of magmatism and the formation of skarn Fe-bearing deposits in the southeast Hubei Province, MLYRVMB, might be associated lithosphere thinning induced by asthenosphere upwelling during the Late Mesozoic.  相似文献   

20.
The lead isotopic composition of 33 sulfide samples from orebodies of the Sukhoi Log deposit was studied by high-precession MC-ICP-MS with a precision of ±0.02% (±2SD from 120 analyses of the SRM 981 standard sample). The deposit is located in the Bodaibo gold mining district in the northern Baikal-Patom Highland. Gold mineralization is hosted in Neoproterosoic black slates. Variations of lead isotope ratios of the Sukhoi Log sulfides are generally typical of Phanerozoic deposits and ore fields. They are significant for 206Pb/204Pb (17.903–18.674), moderate for 208Pb/204Pb (37.822–38.457), and relatively narrow for 207Pb/204Pb (15.555–15.679). In the Pb-Pb isotope diagrams, the data points of pyrite and galena constitute a linear trend. The points corresponding to pyrite from metasomatic ore occupy the left lower part of the trend. Galena from late gold-quartz veins shows more radiogenic Pb, and corresponding data points are located in the upper part of the trend. According to the Stacey-Kramers model, the end points of the trend, which is regarded as a mixing line, have μ2 = 9.6 and μ2 = 13.2 and model Pb-Pb ages 455 and 130 Ma, respectively. The isotope characteristics of ore lead, their relationships in pyrite and galena, and the mixing trend of Pb isotopic compositions are clearly tied to two Paleozoic stages in the formation of the Sukhoi Log deposit (447 ± 6 and 321 ± 14Ma) and testify to the leading role of crustal sources, which are suggested as being the Neoproterozoic black-shale terrigenous-carbonate rocks.  相似文献   

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