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1.
Sukinda chromite valley is one of the largest chromite deposits of the country and produces nearly 8% of chromite ore. It greatly contributes towards the economic development but at the same time deteriorates the natural environment. It is generally excavated by opencast mining method. In the Sukinda mining area, around 7.6 million tons of solid waste have been generated in the form of rejected minerals, overburden material/waste rock and sub-grade ore that may be resulting in environmental degradation, mainly causing lowering in the water table vis-à-vis deterioration in surface and ground water quality. The study conducted in and around one of the chromite mine of the valley reveals that the concentration of hexavalent chromium is found in the water samples of ground and surface water, mine effluents and seepage water. Hexavalent Chromium (Cr+6) have been found varying between 0.02 mg/l and 0.12 mg/l in mine effluents and 0.03–0.8 mg/l in shallow hand pumps and 0.05 and 1.22 mg/l in quarry seepage. The concentration of Cr+6 in Damsal nalah, the main surface water source in the area, is found varying between 0.03 mg/l and 0.14 mg/l and a increasing trend, which is in the downstream of mining activities, has been observed. Leachate study clearly shows that the soil lying in the vicinity of mine waste dump shows highest concentration of Cr+6. Contaminant migration in ground water depends upon various geohydrological conditions of the area. The study shows that aquifer resistivity varies between 15 Ωm to 150 Ωm and aquifer depth varies from 4 m to 26 m below ground level. The ground water flow and mass transport models were constructed with the help of geo-hydrological and geophysical informations using Visual Modflow software. Contaminant migration and path lines for 20 years have been predicted in two layers model of ground water. The study provided an insight into the likely migration of contaminant in ground water due to leaching from overburden dump of chromite ore and will be helpful in making strategic planning for limiting the contaminant migration in the ground water regime in and around the mining areas.  相似文献   

2.
 Acidification is the most common water quality problem in lakes created from previous open cast lignite mines. Aeration of aquifers and dump materials from mining activities causes pyrite oxidation. Pyrite oxidation products are stored in pore water, minerals and at the exchange complexes of the aquifers and dump sediments. Rainfall runoff transports sediments on the dump slope into the lakes. Elutriation of these sediments whithin the lakes releases either acid-producing or acid-neutralizing agents. At a test site south of Leipzig, the annual erosion rates were quantified by water erosion models (RUSLE, EROSION 2D, PEPP) and field measurements. They ranged from 300 up to 900 tons per hectare. Hydrogen ion equivalent release or binding at the sediment elutriation was computed from laboratory analysis of the pore-water quality, ion exchange complex and mineral composition of the sediment. Two of the three investigated sediments contained 3 mmol (eq) acidity per 100 g dry sediment and revealed saturation with respect to jarosite, jurbanite and gypsum. In the third sediment, 6 mmol (eq) alkalinity per 100 g dry sediment was obtained. The annual net acidity influx was calculated to be about 0.5 million mol (eq) for the lake of the test site. Received: 2 November 1998 · Accepted: 26 January 1999  相似文献   

3.
选择北京平原区水文地质、环境地质等方面都比较典型的沙子营垃圾堆放场,建立了其水文地质模型。在充分收集资料、分析得出部分计算所需参数后,采用现场弥散实验、勘查取样测试等方法,求得了该含水层的弥散系数等参数;用二维非稳定流溶质运移方程对污染物在此含水层中的迁移扩散规律、速度和污染范围等进行了模拟计算;采用现场钻探、取样测试分析等方法,评价了该含水层的实际污染状况。实验模拟计算和现场调查结果表明:污染物在潜水含水层中的运移规律遵循二维非稳定流场中的溶质运移方程,污染物在潜水含水层中的运移速度约为86.25m/a,迁移扩散主要发生在地下水流向上,侧向扩散宽度极小,是地下水流向上的1/17。  相似文献   

4.
Tanneries located in an industrial development area of Ranipet (India) manufactured chromate chemicals during 1976?C1996. A large quantity of associated hazardous solid wastes has been stacked about 5-m high above ground level, spread over 3.5?ha inside one of the factory premises. The study area receives an average annual rainfall of 1,100?mm. The granitic formation in the northern part of Palar River catchment has high infiltration rates and has resulted in fast migration of the contamination to the water table. Chromium levels in the groundwater were found up to 275?mg/l. The available hydrogeological, geophysical and groundwater quality data bases have been used to construct a groundwater flow and mass transport model for assessing the groundwater contamination and it has been calibrated for the next 30?years. The migration has been found to be very slow, with a groundwater velocity of 10?m/year. This is the first field-scale study of its kind in this industrial area. The findings are of relevance to addressing the groundwater pollution due to indiscriminate disposal practices of hazardous waste in areas located on the phreatic aquifer. Further, it has been reported that the untreated effluent discharge adjacent to the chromium dump site is most influential in the migration of contaminants.  相似文献   

5.
Surface waters are subject to intense contamination with trace elements in ore mining areas. A complex study was performed for the state of waters and bottom sediments from the Bogachukha and Urup Rivers in the area of the abandoned tailing dump of the Urupsky Ore Mining. The impact exerted by the tailing dump on the concentration of elements in the water, suspended particulate matter, and bottom sediments of the rivers is evaluated. The major contaminants of surface waters and bottom sediments, as well as the forms of their element distribution are revealed.  相似文献   

6.
Solute transport and chemical neutralization (pH 3 to 7) within a shallow heterogeneous aquifer producing acid mine drainage (AMD) are examined at an abandoned surface coal mine in West Virginia. The aquifer is undergoing partial neutralization by mixing with alkalinity from a leaking sludge disposal pond, extending in preferential zones controlled by aquifer heterogeneity. Hydraulic heads interpolated from wells indicate leakage from a central alkaline (pH 7.1, 0.72 meq/L alkalinity) sludge pond is a principal source of recharge. Chemically-conservative sodium, added to AMD during treatment and leaked into the aquifer with the sludge, develops a dispersion plume over a restricted portion of the aquifer that correlates with pH, hydraulic head, and dissolved metals distributions. Concentrations of aluminum, iron, sulfate and acidity display higher concentrations downgradient from the pond as sludge alkalinity is consumed along flow paths. Before reaching springs, most dissolved iron is oxidized and hydrolyzed, likely precipitating in the aquifer as a ferric hydroxide or hydroxysulfate phase. The spatial pattern of iron and aluminum concentrations suggests accelerated oxidation caused by gas transport along the outer slopes of the spoil. Dissolved aluminum concentrations increase with total acidity, suggesting that dissolution of silicate minerals results from acidity released by iron hydrolysis. Neutralization reactions and higher pH are favored in more highly permeable portions of the spoil, where ferrihydrite and aluminum hydroxysulfate minerals (such as basaluminite) are supersaturated. In acid-producing zones at pH < 4.5, jurbanite is near equilibrium and an aluminum-sulfate phase with similar properties may limit aluminum concentrations, but become undersaturated in zones of advancing neutralization. At this particular site, ferrous iron produced by pyrite oxidation is almost completely oxidized over short transport distances, allowing hydrolysis of iron and aluminum should sufficient alkalinity be added to these acid waters.  相似文献   

7.
In Mexico, open dumps that are maintained by the municipality but provide no covering of waste are not uncommon. Further, disposal at these sites is often performed by burning. The aim of this study was to determine the leachate plume from an open dump located in a depositional deltaic environment, with arid climate, low rainfall and where the water table is about 2 m below the surface. The methodology comprised analysis of groundwater monitoring wells and geophysical and geochemical prospecting techniques. The 3D geoelectric interpretation shows a typical area of these depositional environments with low resistive values (10–20 Ω-m) associated with the presence of sands and clays interbedded. However, there is a very low resistivity zone associated with the dump’s impact which reaches values below 5 Ω-m, and it is located where the disposal and burning of wastes occurred. Another zone with values above 16 Ω-m appears as a limit for the advance of the saline. This is interpreted as a sandy lenses area. These sandy lenses with higher porosity transport aquifer’s water. Thus the dump is in direct contact by this conduct with clean groundwater. Piper diagrams constructed with the chemical data analysis reveal that the groundwater in the area corresponds to the chlorinated and/or sulfated sodium type, showing the impact caused by the dump. The monitoring well (NP8, on-site) with the highest dissolved solids content behaves anomalously and belongs to the more conductive zone according to the geoelectric profiles. The subsoil geochemical behavior is influenced by the seasonal water table variations provoking the dissolution of burned and unburned wastes, but the effects of slow flows in the direction of the regional flow are not discarded. Although the most impacted area within the dump is characterized to a depth of 10 m, there is a slow flow in the direction of the regional flow that has been moving pollutants out of the dumpsite during its almost 20 years of operation. The results of this study provide valuable information for the authorities to carry out an appropriate restoration project.  相似文献   

8.
Solute transport and chemical neutralization (pH 3 to 7) within a shallow heterogeneous aquifer producing acid mine drainage (AMD) are examined at an abandoned surface coal mine in West Virginia. The aquifer is undergoing partial neutralization by mixing with alkalinity from a leaking sludge disposal pond, extending in preferential zones controlled by aquifer heterogeneity. Hydraulic heads interpolated from wells indicate leakage from a central alkaline (pH 7.1, 0.72 meq/L alkalinity) sludge pond is a principal source of recharge. Chemically-conservative sodium, added to AMD during treatment and leaked into the aquifer with the sludge, develops a dispersion plume over a restricted portion of the aquifer that correlates with pH, hydraulic head, and dissolved metals distributions. Concentrations of aluminum, iron, sulfate and acidity display higher concentrations downgradient from the pond as sludge alkalinity is consumed along flow paths. Before reaching springs, most dissolved iron is oxidized and hydrolyzed, likely precipitating in the aquifer as a ferric hydroxide or hydroxysulfate phase. The spatial pattern of iron and aluminum concentrations suggests accelerated oxidation caused by gas transport along the outer slopes of the spoil. Dissolved aluminum concentrations increase with total acidity, suggesting that dissolution of silicate minerals results from acidity released by iron hydrolysis. Neutralization reactions and higher pH are favored in more highly permeable portions of the spoil, where ferrihydrite and aluminum hydroxysulfate minerals (such as basaluminite) are supersaturated. In acid-producing zones at pH < 4.5, jurbanite is near equilibrium and an aluminum-sulfate phase with similar properties may limit aluminum concentrations, but become undersaturated in zones of advancing neutralization. At this particular site, ferrous iron produced by pyrite oxidation is almost completely oxidized over short transport distances, allowing hydrolysis of iron and aluminum should sufficient alkalinity be added to these acid waters.  相似文献   

9.
The water quality of shallow aquifers that have direct relationship to human heath and ecological safety has been seriously threatened by widespread dumping of industrial solid waste, urban and rural garbage. A garbage dump field with hydrogeological, environ-geological characteristics typical of the Beijing plain was selected for investigation. A hydrogeological model was constructed and the equations used to describe pollutant transport in one-dimensional (1D) steady, uniform groundwater flow to investigate the transport/diffusion processes. In addition to the coefficients for calculation, diffusion coefficient and other coefficients of the aquifer were obtained by conducting in situ diffusion experiments and sample tests. Velocity and scope of pollutant transport/diffusion process were calculated. Accordingly, the real pollution situation in the aquifer was evaluated through in situ drilling and sample testing. Transport/diffusion processes of pollutants within the aquifer abide by the solute equation applicable to 1D steady flow. The transport and diffusion dominate in the direction of groundwater flowing at a speed of about 120 m per year. Comparably, the lateral diffusive width is much smaller. Pollution degree decreases by the law of Y=1.08 exp(33.533/X), where Y is the distance from the garbage dump field and X is the overall pollution index.  相似文献   

10.
Knowledge of the transport behavior of radionuclides in groundwater is needed for both groundwater protection and remediation of abandoned uranium mines and milling sites. Dispersion, diffusion, mixing, recharge to the aquifer, and chemical interactions, as well as radioactive decay, should be taken into account to obtain reliable predictions on transport of primordial nuclides in groundwater. This paper demonstrates the need for carrying out rehabilitation strategies before closure of the Königstein in-situ leaching uranium mine near Dresden, Germany. Column experiments on drilling cores with uranium-enriched tap water provided data about the exchange behavior of uranium. Uranium breakthrough was observed after more than 20 pore volumes. This strong retardation is due to the exchange of positively charged uranium ions. The code TReAC is a 1-D, 2-D, and 3-D reactive transport code that was modified to take into account the radioactive decay of uranium and the most important daughter nuclides, and to include double-porosity flow. TReAC satisfactorily simulated the breakthrough curves of the column experiments and provided a first approximation of exchange parameters. Groundwater flow in the region of the Königstein mine was simulated using the FLOWPATH code. Reactive transport behavior was simulated with TReAC in one dimension along a 6000-m path line. Results show that uranium migration is relatively slow, but that due to decay of uranium, the concentration of radium along the flow path increases. Results are highly sensitive to the influence of double-porosity flow.  相似文献   

11.
Interest in artificially recharging selected shallow sands in South Louisiana with fresh water has been stimulated by the desire to retard contamination of municipal groundwater supplies by brackish water, to retard ground subsidence and decrease pumping lifts, and to develop emergency subsurface supplies of potable water for communities dependent on surface waters susceptible to contamination. Results of field experiments, laboratory work, and model calculations demonstrate that ion exchange reactions involving clays dispersed in aquifer sands can be expected to modify significantly the composition of waters injected into Gulf Coast sediments. As little as 0.1 weight percent smectite (montmorillonite) can remove, by exchange with absorbed Na, a significant fraction of the dissolved Ca and Mg present in the injected water. The hardness of the water is thus reduced, which may be a desirable modification in water quality. Exchange occurs as fast as the fluids can be pumped into or out of the aquifer, and the water-softening capacity of the aquifer can be restored by allowing sodium-rich native pore waters to sweep back over the dispersed clays. Each acre of an aquifer 50 feet thick and containing 0.1 wt % smectite could soften half a million gallons of injected Mississippi River water. Many individual Gulf Coast aquifers underlie tens of thousands of acres, and their potential softening capacity is thus enormous. Additional exchange processes involving adjacent aquitard shales presumably will operate over long-term periods. It is possible that Gulf Coast aquifers will be used at some point in the future as processing plants to treat injected water to improve its quality for a variety of municipal and industrial purposes.  相似文献   

12.
A numerical groundwater flow and mass transport model was developed to predict the extent of impact from methyl tertiary butyl ether (MTBE) release on a down-gradient drinking water well field. An MTBE incident in Pascoag, Rhode Island, was used as a case study and the plume’s past and future development was simulated using scenario analysis. The numerical code used was GeoSys/Rockflow, which permits a coupled flow and transport simulation as one object, thus alleviating the need for simulating the MTBE fate with separate flow and transport codes. The numerical model was built on available hydrogeological and chemical data as well as on GIS information of the site. By comparing the simulated results with observed field data, it was found that the model could provide reliable results even when the simulated aquifer was simplified to a two-dimensional flow and transport domain. Finally, the calibrated model was used for exploring a location that may be suitable for a new well field. Despite the model limitations associated with uncertainties of data and simplifying assumptions, numerical modeling of this MTBE contaminated site proved a useful tool and provided guidance for future municipal well field operation strategies and aquifer remediation alternatives.  相似文献   

13.
The impact of groundwater withdrawals on the interaction between multi-layered aquifers with different water qualities in the Viterbo geothermal area (central Italy) was studied. In this area, deep thermal waters are used to supply thermal spas and public pools. A shallow overlying aquifer carries cold and fresh water, used for irrigation and the local drinking-water supply. Starting with a conceptual hydrogeological model, two simplified numerical models were implemented: a steady-state flow model of the entire groundwater system, and a steady-state flow and heat transport model of a representative area, which included complex interactions between the aquifers. The impact of increased withdrawals associated with potential future development of the thermal aquifer must be considered in terms of the water temperature of the existing thermal sources. However, withdrawals from the shallow aquifer might also influence the discharge of thermal sources and quality of the water withdrawn from the shallow wells. The exploitation of the two aquifers is dependent on the hydraulic conductivity and thickness of the intervening aquitard, which maintains the delicate hydrogeological equilibrium. Effective methods to control this equilibrium include monitoring the vertical gradient between the two aquifers and the residual discharge of natural thermal springs.  相似文献   

14.
Steelmaking-coal waste rock placed in mountain catchments in the Elk Valley, British Columbia, Canada, drain constituents of interest (CIs) to surface water downgradient of the waste rock dumps. The role of groundwater in transporting CIs in the headwaters of mountain catchments is not well understood. This study characterizes the physical hydrogeology of a portion of a 10-km2 headwater catchment (West Line Creek) downgradient of a 2.7-km2 waste rock dump placed over a natural headwater valley-bottom groundwater system. The study site was instrumented with 13 monitoring wells. Drill core samples were collected to determine subsurface lithology and geotechnical properties. The groundwater system was characterized using field testing and water-level monitoring. The valley-bottom sediments were composed of unconsolidated glacial and meltwater successions (<64 m thick) deposited as a series of cut and fill structures overlying shale bedrock. An unconfined basal alluvial aquifer located above fractured bedrock was identified as the primary conduit for groundwater flow toward Line Creek (650 m from the toe of the dump). Discharge through the basal alluvial aquifer was estimated using the geometric mean hydraulic conductivity (±1 standard deviation). These calculations suggest groundwater discharge could account for approximately 15% (ranging from 2 to 60%) of the total water discharged from the watershed. The residence time from the base of the waste rock dump to Line Creek was estimated at <3 years. The groundwater system was defined as a snowmelt (i.e., nival) regime dominated by direct recharge (percolation of precipitation) across the catchment.  相似文献   

15.
地下水流动特征对水文地球化学特征具有重要控制作用, 研究分析了大同盆地地下水流动特征对高砷水迁移的影响.以山阴县桑干河南岸地下水试验场(SYFS)的监测数据为基础, 建立了河岸带三维非稳定地下水流模型.结果表明, 灌溉在很大程度上影响着地下水位动态变化.灌溉活动减慢了地下水埋深和水平地下水流速, 加速了不同岩性地层之间的垂向水量交换.粉土(L1、L2、L3和L4)、粘土1(L5)和砂1(L6)之间始终存在由上至下的垂向水量交换, 粘土2(L7)、砂2(L8)、粘土3(L9)和砂3(L10)以水平水量交换为主.灌溉水和大气降水从地表向下垂直入渗至含水层的过程中, 推动了地表和包气带沉积物中的砷逐渐向下迁移; 到达含水层后, 水平交换量占主导, 地下水在水平方向上频繁的水量交换促使As在含水层中发生水平迁移.   相似文献   

16.
 This study evaluates the geological, hydrogeological and hydrological conditions at the open waste dump site of the Van municipality in eastern Anatolia, Turkey. A geological map and a three-dimensional view of the project site have been prepared. All lithological units exposed at and near the dump site have been determined and their boundary relationships identified. Drainage basin characteristics of the dump site along with the water bearing properties of different lithological units have been assessed. For the rehabilitation of the existing dump site, material availability (clay as a liner, cap, and daily cover material; granular soil as a filter material) has been researched. Based on the geological, hydrogeological, morphological and hydrological conditions of the existing waste dump site, recommendations to minimize its environmental impact are presented. Received: 8 March 1999 · Accepted: 3 May 1999  相似文献   

17.
Geo-environmental assessment and geophysical investigations were carried out over the only functional municipal solid waste disposal site of the city of Addis Ababa, Ethiopia, known locally as Koshe. The accumulated wastes from Koshe have impact on the surrounding human and physical environment since the disposal site was not designed. The study deserves emphasis because the city of Addis Ababa currently obtains a considerable portion of its domestic water supply from a well field developed not much farther from and along a groundwater flow direction in relation to the waste disposal site. It was found out that the leachates from the site contain high concentration of biological oxygen demand, chemical oxygen demand, chloride and sulphate besides high concentration of cobalt, nickel and zinc in the surrounding soils. The geophysical results have mapped weak zones and near-vertical discontinuities that could potentially be conduits for the leachate from the wastes into the deep groundwater system. Further, a zone of potential leachate migration from the landfill was identified from the electrical models; the location of this zone is consistent with the predicted direction of groundwater flow across the site. The results further suggested that the open dump site tends to cause increasing amount of pollution on the surrounding soil, surface and ground waters. Furthermore, it was observed that the Koshe waste disposal site has grown beyond its capacity and the poor management of the open dump landfill has reduced the aesthetic value of the surrounding environments. The need to change/relocate the existing waste disposal site to a more suitable and technologically appropriate site is emphasized.  相似文献   

18.
The major ion hydrochemistry, sodium absorption ratio (SAR), sodium percentage, and isotopic signatures of Hammamet-Nabeul groundwaters were used to identify the processes that control the mineralization, irrigation suitability, and origin of different water bodies. This investigation highlights that groundwater mineralization is mainly influenced by water-rock interaction and pollution by the return flow of irrigation water. The comparison of groundwater quality with irrigation suitability standards proves that most parts of groundwater are unacceptable for irrigation and this long-term practice may result in a significant increase of the salinity and alkalinity in the soils. Based on isotopic signatures, the shallow aquifer groundwater samples were classified into (i) waters with depleted δ18O and δ2H contents, highlighting recharge by modern precipitation, and (ii) waters with enriched stable isotope contents, reflecting the significance of recharge by contaminated water derived from the return flow of evaporated irrigation waters. The deep-aquifer groundwater samples were also classified into (i) waters with relatively enriched isotope contents derived from modern recharge and mixed with shallow-aquifer groundwater and (ii) waters with depleted stable isotope contents reflecting a paleoclimatic origin. Tritium data permit to identify three origins of recharge, i.e., contemporaneous, post-nuclear, and pre-nuclear. Carbon-14 activities demonstrate the existence of old paleoclimatic recharge related to the Holocene and Late Pleistocene humid periods.  相似文献   

19.
《Applied Geochemistry》2004,19(3):261-271
The distribution of Rare Earth Elements (REE) was investigated in the acidic waters (lake and groundwater) of a lignite mining district (Germany). The Fe- and SO4-rich lake water (pH 2.7) displays high REE contents (e.g. La∼70 μg/l, Ce∼160 μg/l) and an enrichment of light REE (LREE) in the NASC normalised pattern. Considering the hydrodynamic model and geochemical data, the lake water composition may be calculated as a mixture of inflowing Quaternary and mining dump groundwaters. The groundwater of the dump aquifer is LREE enriched. Nevertheless, the leachates of dump sediments generally have low REE contents and display flat NASC normalised patterns. However, geochemical differences and REE pattern in undisturbed lignite (LREE enriched pattern and low water soluble REE contents) and the weathered lignite of the dumps (flat REE pattern and high water soluble REE contents) suggest that lignite is probably the main REE source rock for the lake water.  相似文献   

20.
In order to identify the origin of the main processes that affect the composition of groundwater in a karstic aquifer, a hydrogeochemical and isotopic study was carried out of water from numerous observation wells located in Sierra de Gador, a semiarid region in SE Spain. Several natural and anthropogenic tracers were used to calculate groundwater residence time within this complex aquifer system. Analysis of major ions enabled the principal geochemical processes occurring in the aquifer to be established, and the samples were classified into four distinctive solute groups according to this criterion. Dissolution of carbonate rocks determines the chemical composition of less mineralized water. In another group, the concurrent dissolution of dolomite and precipitation of calcite in gypsum-bearing carbonate aquifer, where the dissolution of relatively soluble gypsum controls the reaction, are the dominant processes. Marine intrusion results in highly mineralized waters and leads to base exchange reactions. The groundwater enrichment of minor and trace elements allowed classification of the samples into two classes that are linked to different flow patterns. One of these classes is influenced by a slow and/or deep regional flow, where the temperature is generally elevated. The influence of sulphate reduces by up to 40 % the barium concentration due to the barite precipitation. Isotope data (T, 14C) confirm the existence of recent local flows, and regional flow system, and ages of ground water may reach 8000 years. The importance of gypsum dissolution in this aquifer is proved by the δ34S content.  相似文献   

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