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1.
Chemical reactions and volatile supply through hypervelocity impacts may have played a key role for the origin and evolution of both planetary and satellite atmospheres. In this study, we evaluate the role of impact-induced N2 production from reduced nitrogen-bearing solids proposed to be contained in Titan’s crust, ammonium sulfate ((NH4)2SO4), for the replenishment of N2 to the atmosphere in Titan’s history. To investigate the conversion of (NH4)2SO4 into N2 by hypervelocity impacts, we measured gases released from (NH4)2SO4 that was exposed to hypervelocity impacts created by a laser gun. The sensitivity and accuracy of the measurements were enhanced by using an isotope labeling technique for the target. We obtained the efficiency of N2 production from (NH4)2SO4 as a function of peak shock pressure ranging from ∼8 to ∼45 GPa. Our results indicate that the initial and complete shock pressures for N2 degassing from (NH4)2SO4 are ∼10 and ∼25 GPa, respectively. These results suggest that cometary impacts on Titan (i.e., impact velocity vi > ∼8 km/s) produce N2 efficiently; whereas satellitesimal impacts during the accretion (i.e., vi < 4 km/s) produce N2 only inefficiently. Even when using the proposed small amount of (NH4)2SO4 content in the crust (∼4 wt.%) (Fortes, A.D. et al., 2007. Icarus 188, 139-153), the total amount of N2 provided through cometary impacts over 4.5 Ga reaches ∼2-6 times the present atmospheric N2 (i.e., ∼7 × 1020-2 × 1021 [mol]) based on the measured production efficiency and results of a hydrodynamic simulation of cometary impacts onto Titan. This implies that cometary impacts onto Titan’s crust have the potential to account for a large part of the present N2 through the atmospheric replenishment after the accretion.  相似文献   

2.
M.H. Moore  R.L. Hudson 《Icarus》2007,189(2):409-423
Spectra of Europa, Ganymede, and Callisto reveal surfaces dominated by frozen water, hydrated materials, and minor amounts of SO2, CO2, and H2O2. These icy moons undergo significant bombardment by jovian magnetospheric radiation (protons, electrons, and sulfur and oxygen ions) which alters their surface compositions. In order to understand radiation-induced changes on icy moons, we have measured the mid-infrared spectra of 0.8 MeV proton-irradiated SO2, H2S, and H2O-ice mixtures containing either SO2 or H2S. Samples with H2O/SO2 or H2O/H2S ratios in the 3-30 range have been irradiated at 86, 110, and 132 K, and the radiation half-lives of SO2 and H2S have been determined. New radiation products include the H2S2 molecule and HSO−3, HSO−4, and SO2−4 ions, all with spectral features that make them candidates for future laboratory work and, perhaps, astronomical observations. Spectra of both unirradiated and irradiated ices have been recorded as a function of temperature, to examine thermal stability and phase changes. The formation of hydrated sulfuric acid in irradiated ice mixtures has been observed, along with the thermal evolution of hydrates to form pure sulfuric acid. These laboratory studies provide fundamental information on likely processes affecting the outer icy shells of Europa, Ganymede, and Callisto.  相似文献   

3.
A.D. Fortes  I.G. Wood  L. Vo?adlo 《Icarus》2003,162(1):59-73
We present the first ab initio simulations of the low-pressure phase of ammonia dihydrate (NH3 · 2H2O), ADH I, a likely constituent of many volatile-rich solid bodies in the outer Solar System (e.g., Saturn’s moons). Ordered monoclinic (space group P21) and orthorhombic (space group P212121) variants of the experimentally observed cubic cell (space group P213) may be constructed, with fully ordered water molecule orientations that obey the ice rules. Our calculations show that the most stable structure at 0 K is orthorhombic (P212121), the monoclinic variants (P21) being energetically disfavored. We provisionally call this ordered orthorhombic phase ADH III. The, as-yet-unmeasured, bulk modulus, K0, is predicted to be 10.67−0.44+0.56 GPa at 0 K. Our results are also combined with literature data to arrive at a revised coefficient of volume thermal expansion, αv = 2.81 × 10−7 T1.39 (from 0-176 K), with the density at 0 K, ρ0 = 991.7(39) kg m−3. We also present a case, based on literature data, that argues for a gradual transformation from a paraelectrically disordered cubic structure (P213) to the proposed antiferroelectrically ordered orthorhombic structure (P212121) around 130-150 K (cf. ice III → IX), a temperature regime that applies to the surfaces and interiors of many medium-sized (radii ∼500-700 km) icy bodies.  相似文献   

4.
Chemistry on the icy surface of Europa is heavily influenced by the incident energetic particle flux from the jovian magnetosphere. The majority (>75%) of this energy is in the form of high energy electrons (extending to >10 MeV). We have simulated the electron irradiation environment of Europa with a vacuum system containing a high-energy electron gun for irradiation of ice samples formed on a gold mirror cooled with a cryostat. Pure water films of ∼2.6 μm thickness were grown at 100 K and then either cooled (to 80 K), warmed (to 120 K) or left at 100 K and subsequently irradiated with 10 keV electrons. The production of hydrogen peroxide (H2O2) was monitored by observation of the 2850 cm−1 (3.5 μm) band. Equilibrium concentrations of H2O2, in units of percent by number H2O2 relative to water, were found to be 0.043% (80 K), 0.029% (100 K), and 0.0063% (120 K). These values are 33%, 22%, and 5%, respectively, that of the reported surface concentration on the leading hemisphere of Europa (Carlson, R.W., Anderson, M.S., Johnson, R.E., Smythe, W.D., Hendrix, A.R., Barth, C.A., et al. [1999]. Science 283(5410), 2062-2064) and less than the equilibrium concentrations formed by ion irradiation. In addition to the ice film temperature, the current of electrons was varied between different experiments to determine the production and destruction of H2O2 as a function of both electron flux and ice temperature. Variation in current was found to have little effect on the results other than accelerating arrival at radiolytic equilibrium.  相似文献   

5.
To investigate the evolution of any processes on planetary surfaces in the outer Solar System, the rheological properties of non-water ices were studied by means of a sound velocity measurement system and a uniaxial deformation apparatus. A pulse transmission method was used to obtain longitudinal (Vp) and transverse (Vs) wave velocities through solid nitrogen and methane at temperatures ranging from 5 to 64 K and from 5 to 90 K, respectively. The measured velocities confirmed that the solid methane and solid nitrogen samples were non-porous polycrystalline samples without any cracks and bubbles inside. Compression tests at constant strain-rate were performed for solid nitrogen and methane at temperatures of 5-56 K and 5-77 K, respectively, at strain-rates of 10−4-10−2 s−1. Both brittle and ductile behavior was observed for solid nitrogen and methane under these conditions. The maximum strength of solid nitrogen was observed to be 9 MPa in the brittle failure mode, and that of solid methane was 10 MPa. These low strengths cannot support cantaloupe structures with the topographic undulation larger than several kilometers found on Triton’s surface, suggesting that other materials such as H2O ice could underlay solid methane and nitrogen and support these structures.  相似文献   

6.
The mid-infrared spectra of mixed vapor deposited ices of CO2 and H2O were studied as a function of both deposition temperature and warming from 15 to 100 K. The spectra of ices deposited at 15 K show marked changes on warming beginning at 60 K. These changes are consistent with CO2 segregating within the ice matrix into pure CO2 domains. Ices deposited at 60 and 70 K show a greater degree of segregation, as high as 90% for 1:4 CO2:H2O ice mixtures deposited at 70 K. As the ice is warmed above 80 K, preferential sublimation of the segregated CO2 is observed. The kinetics of the segregation process is also examined. The segregation of the CO2 as the ice is warmed corresponds to temperatures at which the structure of the water ice matrix changes from the high density amorphous phase to the low density amorphous phase. We show how these microstructural changes in the ice have a profound effect on the photochemistry induced by ultraviolet irradiation. These experimental results provide a framework in which observations of CO2 on the icy bodies of the outer Solar System can be considered.  相似文献   

7.
Sulfurous acid (H2SO3) has never been characterized or isolated on Earth. This is caused by the unfavorable conditions for H2SO3 within Earth's atmosphere due to the high temperatures, the high water content and the oxidizing environment. Kinetic investigations by means of transition state theory showed that the half-life of H2SO3 at 300 K is 1 day but at 100 K it is increased to 2.7 billion years. Natural conditions to form H2SO3 presumably require cryogenic SO2 or SO2/H2O mixtures and high energy proton irradiation at temperatures around 100 K. Such conditions can be found on the Jupiter moons Io and Europa. Therefore, we calculated IR-spectra of H2SO3 which we compared with Galileo's spectra of Io and Europa. From the available data we surmise that H2SO3 is present on Io and probably but to a smaller extent on Europa.  相似文献   

8.
Limb and nadir spectra acquired by Cassini/CIRS (Composite InfraRed Spectrometer) are analyzed in order to derive, for the first time, the meridional variations of diacetylene (C4H2) and methylacetylene (CH3C2H) mixing ratios in Saturn’s stratosphere, from 5 hPa up to 0.05 hPa and 80°S to 45°N. We find that the C4H2 and CH3C2H meridional distributions mimic that of acetylene (C2H2), exhibiting small-scale variations that are not present in photochemical model predictions. The most striking feature of the meridional distribution of both molecules is an asymmetry between mid-southern and mid-northern latitudes. The mid-southern latitudes are found depleted in hydrocarbons relative to their northern counterparts. In contrast, photochemical models predict similar abundances at north and south mid-latitudes. We favor a dynamical explanation for this asymmetry, with upwelling in the south and downwelling in the north, the latter coinciding with the region undergoing ring shadowing. The depletion in hydrocarbons at mid-southern latitudes could also result from chemical reactions with oxygen-bearing molecules.Poleward of 60°S, at 0.1 and 0.05 hPa, we find that the CH3C2H and C4H2 abundances increase dramatically. This behavior is in sharp contradiction with photochemical model predictions, which exhibit a strong decrease towards the south pole. Several processes could explain our observations, such as subsidence, a large vertical eddy diffusion coefficient at high altitudes, auroral chemistry that enhances CH3C2H and C4H2 production, or shielding from photolysis by aerosols or molecules produced from auroral chemistry. However, problems remain with all these hypotheses, including the lack of similar behavior at lower altitudes.Our derived mean mixing ratios at 0.5 hPa of (2.4 ± 0.3) × 10−10 for C4H2 and of (1.1 ± 0.3) × 10−9 for CH3C2H are compatible with the analysis of global-average ISO observations performed by Moses et al. (Moses, J.I., Bézard, B., Lellouch, E., Gladstone, G.R., Feuchtgruber, H., Allen, M. [2000a]. Icarus 143, 244-298). Finally, we provide values for the ratios [CH3C2H]/[C2H2] and [C4H2]/[C2H2] that can constrain the coupled chemistry of these hydrocarbons.  相似文献   

9.
We present a detailed study of an Iapetus mosaic of VIMS data with high spatial resolution (0.5 × 0.5° or ∼6.4 km/pixel). The spectra were taken in August 2007 and provide the highest VIMS spatial resolution data for this object during Cassini’s primary mission. We analyze this set of data using a statistical clustering approach to reduce the analysis of a large number of data (∼104 spectra from 0.35 to 5.10 μm) to the study of seven representative groups accounting for 99.6% of the surface covered by the original sample. We analyze the spectral absorption bands in the spectra of the different clusters indicative of different composition over the observed surface. We find coherence between the distribution of the clusters and the geographical features on the surface. We give special attention to the study of the water ice and CO2 bands. We find that CO2 is widespread over the entire surface being studied, including the bright and dark areas on Iapetus’ surface, and is probably trapped at the molecular level with other materials. The strength of the CO2 band in the areas where both, H2O- and carbon-bearing materials exist, gives support to the hypothesis that this volatile is formed on the surface of Iapetus as a product of irradiation of these two components. Finally, we also compare the Iapetus CO2 with that on other satellites confirming, that there are evident differences on the center, depth and width of the band on Iapetus and Phoebe, where CO2 has been suggested to be endogenous.  相似文献   

10.
C. Plainaki  A. Milillo  S. Orsini 《Icarus》2010,210(1):385-395
In this paper, we look at space weathering processes on the icy surface of Jupiter’s moon Europa. The heavy energetic ions of the jovian plasma (H+, O+, S+, C+) can erode the surface of Europa via ion sputtering (IS), ejecting up to 1000 H2O molecules per ion. UV photons impinging the Europa’s surface can also result in neutral atom release via photon-stimulated desorption (PSD) and chemical change (photolysis). In this work, we study the efficiency of the IS and PSD processes for ejecting water molecules, simulating the resulting neutral H2O density. We also estimate the contribution to the total neutral atom release by the Ion Backscattering (IBS) process. Moreover, we estimate the possibility of detecting the sputtered high energy atoms, in order to distinguish the action of the IS process from other surface release mechanisms. Our main results are: (1) The most significant sputtered-particle flux and the largest contribution to the neutral H2O density come from the incident S+ ions; (2) the H2O density produced via PSD is lower than that due to sputtering by ∼1.5 orders of magnitude; (3) in the energy range below 1 keV, the IBS can be considered negligible for the production of neutrals, whereas in the higher energy range it becomes the dominant neutral emission mechanism; (4) the total sputtering rate for Europa is 2.0 × 1027 H2O s−1; and (5) the fraction of escaping H2O via IS is 22% of the total sputtered population, while the escape fraction for H2O produced by PSD is 30% of the total PSD population. Since the PSD exosphere is lower than the IS one, the major agent for Europa’s surface total net erosion is IS on both the non-illuminated and illuminated side. Lastly, the exospheric neutral density, estimated from the Galileo electron density measurements appears to be higher than that calculated for H2O alone; this favors the scenario of the presence of O2 produced by radiolysis and photolysis.  相似文献   

11.
The vertical profile of H2SO4 vapor is calculated using current atmospheric and thermodynamic data. The atmospheric data include the H2O profiles observed at 70-112 km by the SOIR solar occultations, the SPICAV-UV profiles of the haze extinction at 220 nm, the VeRa temperature profiles, and a typical profile of eddy diffusion. The thermodynamic data are the saturated vapor pressures of H2O and H2SO4 and chemical potentials of these species in sulfuric acid solutions. The calculated concentration of sulfuric acid in the cloud droplets varies from 85% at 70 km to a minimum of 70% at 90 km and then gradually increasing to 90-100% at 110 km. The H2SO4 vapor mixing ratio is ∼10−12 at 70 and 110 km with a deep minimum of 3 × 10−18 at 88 km. The H2O-H2SO4 system matches the local thermodynamic equilibrium conditions up to 87 km. The column photolysis rate of H2SO4 is 1.6 × 105 cm−2 s−1 at 70 km and 23 cm−2 s−1 at 90 km. The calculated abundance of H2SO4 vapor at 90-110 km and its photolysis rate are smaller than those presented in the recent model by Zhang et al. (Zhang, X., Liang, M.C., Montmessin, F., Bertaux, J.L., Parkinson, C., Yung, Y.L. [2010]. Nat. Geosci. 3, 834-837) by factors of 106 and 109, respectively. Assumptions of 100% sulfuric acid, local thermodynamic equilibrium, too warm atmosphere, supersaturation of H2SO4 (impossible for a source of SOX), and cross sections for H2SO4·H2O (impossible above the pure H2SO4) are the main reasons of this huge difference. Significant differences and contradictions between the SPICAV-UV, SOIR, and ground-based submillimeter observations of SOX at 70-110 km are briefly discussed and some weaknesses are outlined. The possible source of high altitude SOX on Venus remains unclear and probably does not exist.  相似文献   

12.
Recent detection of methane (CH4) on Mars has generated interest in possible biological or geological sources, but the factors responsible for the reported variability are not understood. Here we explore one potential sink that might affect the seasonal cycling of CH4 on Mars - trapping in ices deposited on the surface. Our apparatus consisted of a high-vacuum chamber in which three different Mars ice analogs (water, carbon dioxide, and carbon dioxide clathrate hydrates) were deposited in the presence of CH4 gas. The ices were monitored for spectroscopic evidence of CH4 trapping using transmission Fourier-Transform Infrared (FT-IR) spectroscopy, and during subsequent sublimation of the ice films the vapor composition was measured using mass spectrometry (MS). Trapping of CH4 in water ice was confirmed at deposition temperatures <100 K which is consistent with previous work, thus validating the experimental methods. However, no trapping of CH4 was observed in the ice analogs studied at warmer temperatures (140 K for H2O and CO2 clathrate, 90 K for CO2 snow) with approximately 10 mTorr CH4 in the chamber. From experimental detection limits these results provide an upper limit of 0.02 for the atmosphere/ice trapping ratio of CH4. If it is assumed that the trapping mechanism is linear with CH4 partial pressure and can be extrapolated to Mars, this upper limit would indicate that less than 1% is expected to be trapped from the largest reported CH4 plume, and therefore does not represent a significant sink for CH4.  相似文献   

13.
We present new analysis of HST images of (47171) 1999 TC36 that confirm it as a triple system. Fits to the point-spread function (PSF) consistently show that the apparent primary is itself composed of two similar-sized components. The two central components, A1 and A2, can be consistently identified in each of nine epochs spread over 7 years of time. In each instance, the component separation, ranging from 0.023 ± 0.002 to 0.031 ± 0.003 arcsec, is roughly one half of the Hubble Space Telescope’s diffraction limit at 606 nm. The orbit of the central pair has a semi-major axis of a ∼ 867 km with a period of P ∼ 1.9 days. These orbital parameters yield a system mass that is consistent with Msys = 12.75 ± 0.06 × 1018 kg derived from the orbit of the more distant secondary, component B. The diameters of the three components are . The relative sizes of these components are more similar than in any other known multiple in the Solar System. Taken together, the diameters and system mass yield a bulk density of . HST photometry shows that component B is variable with an amplitude of ?0.17 ± 0.05 magnitudes. Components A1 and A2 do not show variability larger than 0.08 ± 0.03 magnitudes approximately consistent with the orientation of the mutual orbit plane and tidally distorted equilibrium shapes. The system has high specific angular momentum of J/J′ = 0.93, comparable to most of the known transneptunian binaries.  相似文献   

14.
Venus nightglow was observed at NASA IRTF using a high-resolution long-slit spectrograph CSHELL at LT = 21:30 and 4:00 on Venus. Variations of the O2 airglow at 1.27 μm and its rotational temperature are extracted from the observed spectra. The mean O2 nightglow is 0.57 MR at 21:30 at 35°S-35°N, and the temperature increases from 171 K near the equator to ∼200 K at ±35°. We have found a narrow window that covers the OH (1-0) P1(4.5) and (2-1) Q1(1.5) airglow lines. The detected line intensities are converted into the (1-0) and (2-1) band intensities of 7.2 ± 1.8 kR and <1.4 kR at 21:30 and 15.5 ± 2 kR and 4.7 ± 1 kR at 4:00. The f-component of the (1-0) P1(4.5) line has not been detected in either observation, possibly because of resonance quenching in CO2. The observed Earth’s OH (1-0) and (2-1) bands were 400 and 90 kR at 19:30 and 250 and 65 kR at 9:40, respectively. A photochemical model for the nighttime atmosphere at 80-130 km has been made. The model involves 61 reactions of 24 species, including odd hydrogen and chlorine chemistries, with fluxes of O, N, and H at 130 km as input parameters. To fit the OH vibrational distribution observed by VEX, quenching of OH (v > 3) in CO2 only to v ? 2 is assumed. According to the model, the nightside-mean O2 emission of 0.52 MR from the VEX and our observations requires an O flux of 2.9 × 1012 cm−2 s−1 which is 45% of the dayside production above 80 km. This makes questionable the nightside-mean O2 intensities of ∼1 MR from some observations. Bright nightglow patches are not ruled out; however, the mean nightglow is ∼0.5 MR as observed by VEX and supported by the model. The NO nightglow of 425 R needs an N flux of 1.2 × 109 cm−2 s−1, which is close to that from VTGCM at solar minimum. However, the dayside supply of N at solar maximum is half that required to explain the NO nightglow in the PV observations. The limited data on the OH nightglow variations from the VEX and our observations are in reasonable agreement with the model. The calculated intensities and peak altitudes of the O2, NO, and OH nightglow agree with the observations. Relationships for the nightglow intensities as functions of the O, N, and H fluxes are derived.  相似文献   

15.
Jeremy Bailey  Linda Ahlsved 《Icarus》2011,213(1):218-232
We have obtained spatially resolved spectra of Titan in the near-infrared J, H and K bands at a resolving power of ∼5000 using the near-infrared integral field spectrometer (NIFS) on the Gemini North 8 m telescope. Using recent data from the Cassini/Huygens mission on the atmospheric composition and surface and aerosol properties, we develop a multiple-scattering radiative transfer model for the Titan atmosphere. The Titan spectrum at these wavelengths is dominated by absorption due to methane with a series of strong absorption band systems separated by window regions where the surface of Titan can be seen. We use a line-by-line approach to derive the methane absorption coefficients. The methane spectrum is only accurately represented in standard line lists down to ∼2.1 μm. However, by making use of recent laboratory data and modeling of the methane spectrum we are able to construct a new line list that can be used down to 1.3 μm. The new line list allows us to generate spectra that are a good match to the observations at all wavelengths longer than 1.3 μm and allow us to model regions, such as the 1.55 μm window that could not be studied usefully with previous line lists such as HITRAN 2008. We point out the importance of the far-wing line shape of strong methane lines in determining the shape of the methane windows. Line shapes with Lorentzian, and sub-Lorentzian regions are needed to match the shape of the windows, but different shape parameters are needed for the 1.55 μm and 2 μm windows. After the methane lines are modeled our observations are sensitive to additional absorptions, and we use the data in the 1.55 μm region to determine a D/H ratio of 1.77 ± 0.20 × 10−4, and a CO mixing ratio of 50 ± 11 ppmv. In the 2 μm window we detect absorption features that can be identified with the ν5 + 3ν6 and 2ν3 + 2ν6 bands of CH3D.  相似文献   

16.
While CO, HCl, and HF, that were considered in the first part of this work, have distinct absorption lines in high-resolution spectra and were detected four decades ago, the lines of HDO, OCS, and SO2 are either very weak or blended by the telluric lines and have not been observed previously by ground-based infrared spectroscopy at the Venus cloud tops. The H2O abundance above the Venus clouds is typically below the detection limit of ground-based IR spectroscopy. However, the large D/H ratio on Venus facilitates observations of HDO. Converted to H2O with D/H ≈ 200, our observations at 2722 cm−1 in the Venus afternoon show a H2O mixing ratio of ∼1.2 ppm at latitudes between ±40° increasing to ±60° by a factor of 2. The observations in the early morning reveal the H2O mixing ratio that is almost constant at 2.9 ppm within latitudes of ±75°. The measured H2O mixing ratios refer to 74 km. The observed increase in H2O is explained by the lack of photochemical production of sulfuric acid in the night time. The recent observations at the P-branch of OCS at 4094 cm−1 confirm our detection of OCS. Four distributions of OCS along the disk of Venus at various latitudes and local times have been retrieved. Both regular and irregular components are present in the variations of OCS. The observed OCS mixing ratio at 65 km varies from ∼0.3 to 9 ppb with the mean value of ∼3 ppb. The OCS scale height is retrieved from the observed limb darkening and varies from 1 to 4 km with a mean value of half the atmospheric scale height. SO2 at the cloud tops has been detected for the first time by means of ground-based infrared spectroscopy. The SO2 lines look irregular in the observed spectra at 2476 cm−1. The SO2 abundances are retrieved by fitting by synthetic spectra, and two methods have been applied to determine uncertainties and detection limits in this fitting. The retrieved mean SO2 mixing ratio of 350 ± 50 ppb at 72 km favors a significant increase in SO2 above the clouds since the period of 1980-1995 that was observed by the SOIR occultations at Venus Express. Scale heights of OCS and SO2 may be similar, and the SO2/OCS ratio is ∼500 and may be rather stable at 65-70 km under varying conditions on Venus.  相似文献   

17.
The energy balance at the surface of an airless planetary body is strongly influenced by the bolometric Bond albedo and the surface thermal inertia. Both of these values may be calculated through the application of a thermal model to measured surface temperatures. The accuracy of either, though, increases if the value of the other is better constrained. In this study, we used the improved global bolometric Bond albedo map of Iapetus derived from Cassini VIMS and ISS and Voyager ISS data in conjunction with Cassini CIRS temperature data to reevaluate surface thermal inertia across Iapetus. Results showed the thermal inertia of the dark terrain varies between 11 and 14.8 J m−2 K−1 s−1/2 while the light material varies between 15 and 25 J m−2 K−1 s−1/2. Using an approximation to the thermal properties of the dark overburden derived from our thermal inertia results, we can implement our thermal model to provide estimates on the dark material thickness, which was found to lie between 7 cm and 16 cm. In order to develop an accurate global thermal model, a weighted function that approximates the surface thermal inertia across Iapetus was developed and verified via our measurements. The global bolometric Bond albedo map, surface thermal inertia map, and the thermal model are then used to synthesize global temperature maps that may be used to study the stability of volatiles.  相似文献   

18.
It has been suggested that inclusions of CO2 or CO2 clathrate hydrates may comprise a portion of the polar deposits on Mars. Here we present results from an experimental study in which CO2 molecules were trapped in water ice deposited from CO2/H2O atmospheres at temperatures relevant for the polar regions of Mars. Fourier-Transform Infrared spectroscopy was used to monitor the phase of the condensed ice, and temperature programmed desorption was used to quantify the ratio of species in the generated ice films. Our results show that when H2O ice is deposited at 140-165 K, CO2 is trapped in large quantities, greater than expected based on lower temperature studies in amorphous ice. The trapping occurs at pressures well below the condensation point for pure CO2 ice, and therefore this mechanism may allow for CO2 deposition at the poles during warmer periods. The amount of trapped CO2 varied from 3% to 16% by mass at 160 K, depending on the substrate studied. Substrates studied were a tetrahydrofuran (C4H8O) base clathrate and Fe-montmorillonite clay, an analog for Mars soil. Experimental evidence indicates that the ice structures are likely CO2 clathrate hydrates. These results have implications for the CO2 content, overall composition, and density of the polar deposits on Mars.  相似文献   

19.
This investigation uses linear mixture modeling employing cryogenic laboratory reference spectra to estimate surface compositions and water ice grain sizes of Europa’s ridged plains and smooth low albedo plains. Near-infrared spectra for 23 exposures of ridged plains materials are analyzed along with 11 spectra representing low albedo plains. Modeling indicates that these geologic units differ both in the relative abundance of non-ice hydrated species and in the abundance and grain sizes of water ice. The background ridged plains in our study area appear to consist predominantly of water ice (∼46%) with approximately equal amounts (on average) of hydrated sulfuric acid (∼27%) and hydrated salts (∼27%). The solutions for the smooth low albedo plains are dominated by hydrated salts (∼62%), with a relatively low mean abundance of water ice (∼10%), and an abundance of hydrated sulfuric acid similar to that found in ridged plains (∼27%). The model yields larger water ice grain sizes (100 μm versus 50-75 μm) in the ridged plains. The 1.5-μm water ice absorption band minimum is found at shorter wavelengths in the low albedo plains deposits than in the ridged plains (1.498 ± .003 μm versus 1.504 ± .001 μm). The 2.0-μm band minimum in the low albedo plains exhibits a somewhat larger blueshift (1.964 ± .006 μm versus 1.983 ± .006 μm for the ridged plains).The study area spans longitudes from 168° to 185°W, which includes Europa’s leading side-trailing side boundary. A well-defined spatial gradient of sulfuric acid hydrate abundance is found for both geologic units, with concentrations increasing in the direction of the trailing side apex. We associate this distribution with the exogenic effects of magnetospheric charged particle bombardment and associated chemical processing of surface materials (the radiolytic sulfur cycle). However, one family of low albedo plains exposures exhibits sulfuric acid hydrate abundances up to 33% lower than found for adjacent exposures, suggesting that these materials have undergone less processing, thus implying that these deposits may have been emplaced more recently.Modeling identifies high abundances (to 30%) of magnesium sulfate brines in the low albedo plains exposures. Our investigation marks the first spectroscopic identification of MgSO4 brine on Europa. We also find significantly higher abundances of sodium-bearing species (bloedite and mirabilite) in the low albedo plains. The results illuminate the role of radiolytic processes in modifying the surface composition of Europa, and may provide new constraints for models of the composition of Europa’s putative subsurface ocean.  相似文献   

20.
We have compiled a global geological map of Ganymede that represents the most recent understanding of the satellite based on Galileo mission results. This contribution builds on important previous accomplishments in the study of Ganymede utilizing Voyager data and incorporates the many new discoveries that were brought about by examination of Galileo data. We discuss the material properties of geological units defined utilizing a global mosaic of the surface with a nominal resolution of 1 km/pixel assembled by the USGS with the best available Voyager and Galileo regional coverage and high resolution imagery (100-200 m/pixel) of characteristic features and terrain types obtained by the Galileo spacecraft. We also use crater density measurements obtained from our mapping efforts to examine age relationships amongst the various defined units. These efforts have resulted in a more complete understanding of the major geological processes operating on Ganymede, especially the roles of cryovolcanic and tectonic processes in the formation of might materials. They have also clarified the characteristics of the geological units that comprise the satellite’s surface, the stratigraphic relationships of those geological units and structures, and the geological history inferred from those relationships. For instance, the characteristics and stratigraphic relationships of dark lineated material and reticulate material suggest they represent an intermediate stage between dark cratered material and light material units.  相似文献   

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