Particle size and abundance of HC₃N ice in Titan’s lower stratosphere at high northern latitudes     

C.M. Anderson  R.E. Samuelson  R.K. Achterberg 《Icarus》2010,207(2):914-922

Up to now, there has been no corroboration from Cassini CIRS of the Voyager IRIS-discovery of cyanoacetylene (HC₃N) ice in Titan’s thermal infrared spectrum. We report the first compelling spectral evidence from CIRS for the ν₆ HC₃N ice feature at 506 cm⁻¹ at latitudes 62°N and 70°N, from which we derive particle sizes and column abundances in Titan’s lower stratosphere. We find mean particle radii of 3.0 μm and 2.3 μm for condensed HC₃N at 62°N and 70°N, respectively, and corresponding ice phase molecular column abundances in the range 1-10 × 10¹⁶ mol cm⁻². Only upper limits for cloud abundances can be established at latitudes of 85°N, 55°N, 30°N, 10°N, and 15°S. Under the assumption that cloud tops coincide with the uppermost levels at which HC₃N vapor saturates, we infer geometric thicknesses for the clouds equivalent to 10-20 km or so, with tops at 165 km and 150 km at 70°N and 62°N, respectively.  相似文献   

Negative ion chemistry in Titan's upper atmosphere     

V. Vuitton  P. Lavvas  M. Galand  G.R. Lewis  A.J. Coates  J.-E. Wahlund 《Planetary and Space Science》2009,57(13):1558-662

The Electron Spectrometer (ELS), one of the sensors making up the Cassini Plasma Spectrometer (CAPS) revealed the existence of numerous negative ions in Titan's upper atmosphere. The observations at closest approach (∼1000 km) show evidence for negatively charged ions up to ∼10,000 amu/q, as well as two distinct peaks at 22±4 and 44±8 amu/q, and maybe a third one at 82±14 amu/q. We present the first ionospheric model of Titan including negative ion chemistry. We find that dissociative electron attachment to neutral molecules (mostly HCN) initiates the formation of negative ions. The negative charge is then transferred to more acidic molecules such as HC₃N, HC₅N or C₄H₂. Loss occurs through associative detachment with radicals (H and CH₃). We attribute the three low mass peaks observed by ELS to CN⁻, C₃N⁻/C₄H⁻ and C₅N⁻. These species are the first intermediates in the formation of the even larger negative ions observed by ELS, which are most likely the precursors to the aerosols observed at lower altitudes.  相似文献   

Anion chemistry on Titan: A possible route to large N-bearing hydrocarbons     

Ján Žabka  Claire Romanzin  Christian Alcaraz  Miroslav Polášek 《Icarus》2012,219(1):161-167

The reaction of CN^? with cyanoacetylene (HC₃N), has been studied as a function of the HC₃N pressure in a quadrupole tandem mass spectrometer. The mass spectra revealed the fast depletion of the CN^? parent ion and formation of larger anions of rapidly growing size. Most of the ions observed were found to belong to two series of products: (HC₃N)_x·C_2p+1N^? and (HC₃N)_x·C_2pN^? resulting from the sequential additions of HC₃N molecules and loss of HCN or HCCN molecules. The mechanism and energetics of the first two reaction steps are briefly discussed. The laboratory data are compared with those from the Cassini CAPS-ELS spectrometer. It is believed that the reactions observed could account for the growth of anions in Titan’s ionosphere.  相似文献   

Latitudinal variations of HCN, HC₃N, and C₂N₂ in Titan's stratosphere derived from Cassini CIRS data     

N.A. Teanby  P.G.J. Irwin  C.A. Nixon  B. Bézard  N.E. Bowles  L. Fletcher  F.W. Taylor 《Icarus》2006,181(1):243-255

Mid- and far-infrared spectra from the Composite InfraRed Spectrometer (CIRS) have been used to determine volume mixing ratios of nitriles in Titan's atmosphere. HCN, HC₃N, C₂H₂, and temperature were derived from 2.5 cm⁻¹ spectral resolution mid-IR mapping sequences taken during three flybys, which provide almost complete global coverage of Titan for latitudes south of 60° N. Three 0.5 cm⁻¹ spectral resolution far-IR observations were used to retrieve C₂N₂ and act as a check on the mid-IR results for HCN. Contribution functions peak at around 0.5-5 mbar for temperature and 0.1-10 mbar for the chemical species, well into the stratosphere. The retrieved mixing ratios of HCN, HC₃N, and C₂N₂ show a marked increase in abundance towards the north, whereas C₂H₂ remains relatively constant. Variations with longitude were much smaller and are consistent with high zonal wind speeds. For 90°-20° S the retrieved HCN abundance is fairly constant with a volume mixing ratio of around 1 × 10⁻⁷ at 3 mbar. More northerly latitudes indicate a steady increase, reaching around 4 × 10⁻⁷ at 60° N, where the data coverage stops. This variation is consistent with previous measurements and suggests subsidence over the northern (winter) pole at approximately 2 × 10⁻⁴ m s⁻¹. HC₃N displays a very sharp increase towards the north pole, where it has a mixing ratio of around 4 × 10⁻⁸ at 60° N at the 0.1-mbar level. The difference in gradient for the HCN and HC₃N latitude variations can be explained by HC₃N's much shorter photochemical lifetime, which prevents it from mixing with air at lower latitude. It is also consistent with a polar vortex which inhibits mixing of volatile rich air inside the vortex with that at lower latitudes. Only one observation was far enough north to detect significant amounts of C₂N₂, giving a value of around 9 × 10⁻¹⁰ at 50° N at the 3-mbar level.  相似文献   

Calculations of the thermochemistry of six reactions leading to ammonia formation in Titan's atmosphere     

Su-hong Ge  Xin-lu Cheng  Xiang-dong Yang  Wei Wang 《Icarus》2006,183(1):153-158

The thermochemical properties of the six reactions: (1) N₂+hν (solar EUV) → N⁺ + N(⁴S) + e⁻, (2) N⁺ + H₂ → NH⁺ + H, (3) NH⁺ + H₂ → NH⁺₂ + H, (4) NH⁺₂ + H₂ → NH⁺₃ + H, (5) NH⁺₃ + H₂ → NH⁺₄ + H, and (6) NH⁺₄ + e⁻ → NH₃ + H, were theoretically proposed by Atreya in 1986 and were cited in 2003 by Bernard who assumed that this chain reaction would lead to ammonia formation in Titan's atmosphere. The thermochemical properties of these six reactions have been calculated by means of the coupled cluster singles and doubles (CCSD) at the CCSD/cc-pvdz level, and the CCSD/6-311++g(3df,3pd) level, and G2 method. The geometries of the reactants and products of reactions have been optimized, the energies of reactions have been computed. The analysis of the results shows that: (I) The free energies of four reactions among these six reactions are negative. It means that these reactions, namely reactions (1)-(6) except reaction (2), can react spontaneously in Titan's low temperature environment. The converted temperatures of reactions (3) and (5) are 11881.7 and 4596.9 K, respectively. (II) Reaction (2) is an endothermic reaction, its converted temperature is 1797.6 K. When T<1797.6 K, reaction (2) cannot react forward spontaneously. The barrier of reaction (2) is 26.154 kcal mol⁻¹, which is probably too high to allow it to occur in the atmosphere of Titan. The rate for this reaction at 300 K has been calculated, and the value is k=4.16×¹⁰⁻⁷ s⁻¹. (III) The results of the three methods are more or less the same. So it is concluded that this chain reaction cannot be a pathway to lead to ammonia (gas phase) formation in Titan's atmosphere.  相似文献   

Condensed species in Titan's stratosphere: Confirmation of crystalline cyanoacetylene (HC₃N) and evidence for crystalline acetylene (C₂H₂) on Titan     

R.K. Khanna 《Icarus》2005,178(1):165-170

Infrared spectra of crystalline HC₃N and C₂H₂ were investigated at several temperatures between 15 and 150 K. The characteristics of the 505 and 753 cm⁻¹ bands of HC₃N are in complete agreement with the emission spectral data on Titan obtained by the Voyager IRIS instrument, thus confirming the identification of crystalline HC₃N on Titan. A composite spectrum in the 720-800 cm⁻¹ region, with contributions from HC₃N and C₂H₂ in crystalline phases, reproduces the Voyager emission data in that region, thus providing a suggestion for the identification of crystalline C₂H₂ on Titan.  相似文献   

Vertical profiles of HCN, HC₃N, and C₂H₂ in Titan's atmosphere derived from Cassini/CIRS data     

N.A. Teanby  P.G.J. Irwin  S. Vinatier  C.A. Nixon  S.B. Calcutt  L. Fletcher  F.W. Taylor 《Icarus》2007,186(2):364-384

Mid-infrared limb spectra in the range 600-1400 cm⁻¹ taken with the Composite InfraRed Spectrometer (CIRS) on-board the Cassini spacecraft were used to determine vertical profiles of HCN, HC₃N, C₂H₂, and temperature in Titan's atmosphere. Both high (0.5 cm⁻¹) and low (13.5 cm⁻¹) spectral resolution data were used. The 0.5 cm⁻¹ data gave profiles at four latitudes and the 13.5 cm⁻¹ data gave almost complete latitudinal coverage of the atmosphere. Both datasets were found to be consistent with each other. High temperatures in the upper stratosphere and mesosphere were observed at Titan's northern winter pole and were attributed to adiabatic heating in the subsiding branch of a meridional circulation cell. On the other hand, the lower stratosphere was much colder in the north than at the equator, which can be explained by the lack of solar radiation and increased IR emission from volatile enriched air. HC₃N had a vertical profile consistent with previous ground based observations at southern and equatorial latitudes, but was massively enriched near the north pole. This can also be explained in terms of subsidence at the winter pole. A boundary observed at 60° N between enriched and un-enriched air is consistent with a confining polar vortex at 60° N and HC₃N's short lifetime. In the far north, layers were observed in the HC₃N profile that were reminiscent of haze layers observed by Cassini's imaging cameras. HCN was also enriched over the north pole, which gives further evidence for subsidence. However, the atmospheric cross section obtained from 13.5 cm⁻¹ data indicated a HCN enriched layer at 200-250 km, extending into the southern hemisphere. This could be interpreted as advection of polar enriched air towards the south by a meridional circulation cell. This is observed for HCN but not for HC₃N due to HCN's longer photochemical lifetime. C₂H₂ appears to have a uniform abundance with altitude and is not significantly enriched in the north. This is consistent with observations from previous CIRS analysis that show increased abundances of nitriles and hydrocarbons but not C₂H₂ towards the north pole.  相似文献   

Deep Impact, Stardust-NExT and the behavior of Comet 9P/Tempel 1 from 1997 to 2010     

K.J. Meech  J. Pittichová  B. Yang  P. Candia  Y. Fernández  D. Polishook  G. Sarid 《Icarus》2011,213(1):323-344

We present observational data for Comet 9P/Tempel 1 taken from 1997 through 2010 in an international collaboration in support of the Deep Impact and Stardust-NExT missions. The data were obtained to characterize the nucleus prior to the Deep Impact 2005 encounter, and to enable us to understand the rotation state in order to make a time of arrival adjustment in February 2010 that would allow us to image at least 25% of the nucleus seen by the Deep Impact spacecraft to better than 80 m/pixel, and to image the crater made during the encounter, if possible. In total, ∼500 whole or partial nights were allocated to this project at 14 observatories worldwide, utilizing 25 telescopes. Seventy percent of these nights yielded useful data. The data were used to determine the linear phase coefficient for the comet in the R-band to be 0.045 ± 0.001 mag deg⁻¹ from 1° to 16°. Cometary activity was observed to begin inbound near r ∼ 4.0 AU and the activity ended near r ∼ 4.6 AU as seen from the heliocentric secular light curves, water-sublimation models and from dust dynamical modeling. The light curve exhibits a significant pre- and post-perihelion brightness and activity asymmetry. There was a secular decrease in activity between the 2000 and 2005 perihelion passages of ∼20%. The post-perihelion light curve cannot be easily explained by a simple decrease in solar insolation or observing geometry. CN emission was detected in the comet at 2.43 AU pre-perihelion, and by r = 2.24 AU emission from C₂ and C₃ were evident. In December 2004 the production rate of CN increased from 1.8 × 10²³ mol s⁻¹ to Q_CN = 2.75 × 10²³ mol s⁻¹ in early January 2005 and 9.3 × 10²⁴ mol s⁻¹ on June 6, 2005 at r = 1.53 AU.  相似文献   

New Millimeter Heterodyne Observations of Titan: Vertical Distributions of Nitriles HCN, HC₃N, CH₃CN, and the Isotopic Ratio N/N in Its Atmosphere     

A. MartenT. Hidayat  Y. BiraudR. Moreno 《Icarus》2002,158(2):532-544

High sensitivity observations were performed at 1.2- and 3-mm wavelengths with the IRAM 30-m telescope (Spain) between April 1996 and December 1999 to investigate the nitrile composition of Titan's stratosphere. A part of our dataset consists of high resolution spectra of HC¹⁴N taken at 88.6 GHz as well as spectra of HC¹⁵N recorded at 258.16 GHz. From a thorough analysis of both lines and with the help of appropriate radiative transfer calculations we show that the isotopic ratio ¹⁵N/¹⁴N is strongly enhanced compared to the terrestrial value. We propose that the range 3.9-4.5 should be considered as a basis for the enrichment factor. Five individual lines of HC₃N were measured at 39-kHz resolution using a frequency-switched technique. Several CH₃CN features were recorded at 78-kHz resolution in two transitions around 147.6 and 220.7 GHz. The high spectral resolution and the good signal-to-noise ratio affecting the spectra permit us to retrieve disk-averaged vertical profiles for HCN up to 450 km and for HC₃N and CH₃CN up to 500 km. Comparison of our inferred vertical profiles with relevant results of presently published photochemical models is presented. We show that the profiles of HCN and HC₃N predicted by various authors below 450-km altitude appear inconsistent with our new observations. We find that the three distributions present very different gradients of abundance below 200-km altitude down to the condensation levels around 80 km. In the upper stratosphere HC₃N and CH₃CN have approximately the same mixing ratio of about 4×10⁻⁸ at 450 km, at least one order of magnitude lower than that of HCN. In the same time, another nitrile HC₅N has been searched for by observing four transitions located between 109 and 221 GHz. As no spectral features could be detected after several hours of integration time, we propose an upper limit for the mixing ratio equal to 4×10⁻¹⁰ assuming a uniform distribution of this compound in the lower stratosphere.  相似文献   

Temperature-dependent photoabsorption cross-sections of cyanoacetylene and diacetylene in the mid- and vacuum-UV: Application to Titan's atmosphere     

T. Ferradaz  Y. Bénilan  M. Schwell  H.-W. Jochims 《Planetary and Space Science》2009,57(1):10-81

Cyanoacetylene (HC₃N) and diacetylene (C₄H₂) play an important role in the photochemistry of Titan's atmosphere, in part because of their strong absorption between 110 and 180 nm. Accurate photoabsorption cross-sections at temperatures representative of Titan's atmosphere are required to interprete Cassini observations and to calculate photolysis rates used in photochemical models. Using synchrotron radiation as a tunable vacuum ultraviolet (VUV) light source, we have measured absolute photoabsorption cross-sections of C₄H₂ and HC₃N with a spectral resolution of 0.05 nm in the region between 80 and 225 nm and at different temperatures between 173 and 295 K. The measured cross-sections are used to model transmission spectra of Titan atmosphere in the VUV.  相似文献   

Venus night airglow: Ground-based detection of OH, observations of O₂ emissions, and photochemical model     

Vladimir A. Krasnopolsky 《Icarus》2010,207(1):17-27

Venus nightglow was observed at NASA IRTF using a high-resolution long-slit spectrograph CSHELL at LT = 21:30 and 4:00 on Venus. Variations of the O₂ airglow at 1.27 μm and its rotational temperature are extracted from the observed spectra. The mean O₂ nightglow is 0.57 MR at 21:30 at 35°S-35°N, and the temperature increases from 171 K near the equator to ∼200 K at ±35°. We have found a narrow window that covers the OH (1-0) P1(4.5) and (2-1) Q1(1.5) airglow lines. The detected line intensities are converted into the (1-0) and (2-1) band intensities of 7.2 ± 1.8 kR and <1.4 kR at 21:30 and 15.5 ± 2 kR and 4.7 ± 1 kR at 4:00. The f-component of the (1-0) P1(4.5) line has not been detected in either observation, possibly because of resonance quenching in CO₂. The observed Earth’s OH (1-0) and (2-1) bands were 400 and 90 kR at 19:30 and 250 and 65 kR at 9:40, respectively. A photochemical model for the nighttime atmosphere at 80-130 km has been made. The model involves 61 reactions of 24 species, including odd hydrogen and chlorine chemistries, with fluxes of O, N, and H at 130 km as input parameters. To fit the OH vibrational distribution observed by VEX, quenching of OH (v > 3) in CO₂ only to v ? 2 is assumed. According to the model, the nightside-mean O₂ emission of 0.52 MR from the VEX and our observations requires an O flux of 2.9 × 10¹² cm⁻² s⁻¹ which is 45% of the dayside production above 80 km. This makes questionable the nightside-mean O₂ intensities of ∼1 MR from some observations. Bright nightglow patches are not ruled out; however, the mean nightglow is ∼0.5 MR as observed by VEX and supported by the model. The NO nightglow of 425 R needs an N flux of 1.2 × 10⁹ cm⁻² s⁻¹, which is close to that from VTGCM at solar minimum. However, the dayside supply of N at solar maximum is half that required to explain the NO nightglow in the PV observations. The limited data on the OH nightglow variations from the VEX and our observations are in reasonable agreement with the model. The calculated intensities and peak altitudes of the O₂, NO, and OH nightglow agree with the observations. Relationships for the nightglow intensities as functions of the O, N, and H fluxes are derived.  相似文献   

A New Formula for Computing Mean Neutron Exposure     

Feng-Hua Zhang  Gui-De Zhou  Bo Zhang 《Chinese Astronomy and Astrophysics》2008

We have investigated the characteristics of the distribution of neutron exposures (“DNE” hereafter) in the He-shell nucleosynthesis regions in the model of s-process nucleosynthesis in low-mass AGB (Asymptotic Giant Branch) stars in ¹³C radiatively burning conditions. The result indicates that although the DNE obtained with this model is still approximately exponential, like those of the previous convective s-process scenarios, the relation between the neutron exposure Δτ of each pulse and the mean neutron exposure τ₀ is no longer τ₀ = −Δτ/ln r, rather, it is now approximately τ0 = −Δτ/ ln{q[1.0020 + 0.6602(r − q) + 4.6125(r − q)²− 10.8962(r − q)³+ 13.9138(r − q)⁴]} (r is the overlap factor, q is the mass ratio of the ¹³C shell to the He shell). This formula unifies the stellar model of radiative s-process with the classical model from the angle of DNE.  相似文献   

An Observational Study of the Molecular Cloud Core Toward IRAS 23133+6050     

Min Wang  Ji YangTao Geng  Liu-bin Zhu 《Chinese Astronomy and Astrophysics》2008

This paper reports ¹³CO, C¹⁸O, HCO⁺ (J = 1−0) spectral observations toward IRAS 23133+6050 with the 13.7 m millimeter-wave telescope at Qinghai Station of PMO. Corresponding to the ¹³CO, C¹⁸O, HCO⁺ line emissions, the size of the observed molecular cloud core is 4.0 pc, 2.1 pc and 2.3 pc, the virial mass is 2.7 × 10³ M_⊙, 0.9 × 10³ M_⊙ and 2.3 × 10³ M_⊙, and the volume density of H₂ is 2.7 × 10³ cm⁻³, 5.1 × 10³ cm⁻³ and 4.6 × 10³ cm⁻³, respectively. Using the power-law function n(r) ∼r^−p, the spatial density distribution of the cloud core was analyzed, the obtained exponent p is respectively 1.75, 1.56 and 1.48 for the ¹³CO, C¹⁸O and HCO⁺ cores, and it is found that the density distribution becomes gradually flatter from the outer region to the inner region of the core. The HCO⁺ abundance is 4.6 × 10⁻¹⁰, one order of magnitude less than the value for dark clouds, and slightly less than that for giant molecular clouds. The ¹³CO/C¹⁸O relative abundance ratio is 12.2, comparable with the value 11.8 for dark clouds, and the value 9.0 ∼ 15.6 for giant molecular clouds. A ¹³CO bipolar outflow is found in this region. The IRAS far-infrared luminosity and the virial masses give the luminosity-mass ratios 18.1, 51.1 and 21.2 from the three lines.  相似文献   

IR band intensities of DC₃N and HC₃N: Implication for observations of Titan's atmosphere     

Yves Bénilan  Antoine Jolly  Jean-Claude Guillemin 《Planetary and Space Science》2006,54(6):635-640

We have obtained the infrared spectra and the corresponding absolute band intensities for two HC₃N isotopomers: DC₃N and HC₃¹⁵N. Our results for DC₃N are in good agreement with previous measurements except for the ν₂ and ν₃ stretching modes. For HC₃¹⁵N, this study is the first including intensity measurements.We have also studied the possible detection of these isotopomers in Titan's atmosphere using the CIRS spectrograph onboard the Cassini spacecraft. Our simulation of the expected spectra shows that for a signal-to-noise ratio better than 100, the ¹⁵N isotopomer of HC₃N could be detected. But, further study of HC₃N hot bands are needed since some of them overlap the HC₃¹⁵N Q-branch.  相似文献   

Methane evolution from UV-irradiated spacecraft materials under simulated martian conditions: Implications for the Mars Science Laboratory (MSL) mission     

Andrew C. Schuerger  Christian Clausen 《Icarus》2011,213(1):393-403

Fifteen organic and three inorganic compounds were tested for methane (CH₄) evolution under simulated martian conditions of 6.9 mbar; UVC (200-280 nm) flux of 4 W m⁻²; 20 °C; simulated optical depth of 0.1; and a Mars gas composition of CO₂ (95.3%), N₂ (2.7%), Ar (1.7%), O₂ (0.13%), and water vapor (0.03%). All three inorganic compounds (i.e., NaCl, CaCO₃, graphite) failed to evolve methane at the minimum detection level 0.5 ppm, or above. In contrast, all organic compounds evolved methane when exposed to UV irradiation under simulated martian conditions. The polycyclic aromatic hydrocarbon, pyrene, released the most methane per unit of time at 0.175 nmol CH₄ g⁻¹ h⁻¹, and a spectral reflectance target material used for the MER rovers and Phoenix lander released the least methane at 0.00065 nmol CH₄ cm⁻² h⁻¹. Methane was also released from UV-killed bacterial endospores of Bacillus subtilis. Although all organic compounds evolved methane when irradiated with UV photons under martian conditions, the concentrations of residual organics, biogenic signature molecules, and dead microbial cells should be relatively low on the exterior surfaces of the MSL rover, and, thus, not significant sources of methane contamination. In contrast, kapton tape was found to evolve methane at the rate of 0.00165 nmol CH₄ cm⁻² h⁻¹ (16.5 nmol m⁻² h⁻¹) under the UV and martian conditions tested. Although the evolution of methane from kapton tape was found to decline over time, the large amount of kapton tape used on the MSL rover (lower bound estimated at 3 m²) is likely to create a significant source of terrestrial methane contamination during the early part of the mission.  相似文献   

Kinematics of stellar populations with RAVE data     

Yüksel Karata? 《New Astronomy》2012,17(1):22-33

We study the kinematics of the Galactic thin and thick disk populations using stars from the RAVE survey’s second data release together with distance estimates from Breddels et al. (2010). The velocity distribution exhibits the expected moving groups present in the solar neighborhood. We separate thick and thin disk stars by applying the X (stellar-population) criterion of Schuster et al. (1993), which takes into account both kinematic and metallicity information. For 1906 thin disk and 110 thick disk stars classified in this way, we find a vertical velocity dispersion, mean rotational velocity and mean orbital eccentricity of (σ_W, 〈V_Φ〉, 〈e〉)_thin = (18 ± 0.3 km s⁻¹, 223 ± 0.4 km s⁻¹, 0.07 ± 0.07) and (σ_W, 〈V_Φ〉, 〈e〉)_thick = (35 ± 2 km s⁻¹, 163 ± 3 km s⁻¹, 0.31 ± 0.16), respectively. From the radial Jeans equation, we derive a thick disk scale length in the range 1.5-2.2 kpc, whose greatest uncertainty lies in the adopted form of the underlying potential. The shape of the orbital eccentricity distribution indicates that the thick disk stars in our sample most likely formed in situ with minor gas-rich mergers and/or radial migration being the most likely cause for their orbits. We further obtain mean metal abundances of 〈[M/H]〉_thin = +0.03 ± 0.17, and 〈[M/H]〉_thick = −0.51 ± 0.23, in good agreement with previous estimates. We estimate a radial metallicity gradient in the thin disk of −0.07 dex kpc⁻¹, which is larger than predicted by chemical evolution models where the disk grows inside-out from infalling gas. It is, however, consistent with models where significant migration of stars shapes the chemical signature of the disk, implying that radial migration might play at least part of a role in the thick disk’s formation.  相似文献   

Titan's aerosols: Comparison between our model and DISR findings     

A. Bar-Nun  V. Dimitrov 《Planetary and Space Science》2008,56(5):708-714

Our model [Dimitrov, V., Bar-Nun, A., 1999. A model of energy dependent agglomeration of hydrocarbon aerosol particles and implication to Titan's aerosol. J. Aerosol. Sci. 30(1), 35-49] describes the experimentally found polymerization of C₂H₂ and HCN to form aerosol embryos, their growth and adherence to form various aerosols objects [Bar-Nun, A., Kleinfeld, I., Ganor, E., 1988. Shape and optical properties of aerosols formed by photolysis of C₂H₂, C₂H₄ and HCN. J. Geophys. Res. 93, 8383-8387]. These loose fractal objects describe well the findings of DISR on the Huygens probe [Tomasko, M.G., Bézard, B., Doose, L., Engel, S., Karkoschka, E., 2008. Measurements of methane absorption by the descent imager/spectral radiometer (DISR) during its descent through Titan's atmosphere. Planet. Space Sci., this issue, doi:10.1016/j.pss.2007]. These include (1) various regular objects of R=(0.035-0.064)×10⁻⁶ m, as compared with DISR's 0.05×10⁻⁶ m; (2) diverse low and high fractal structures composed of random combinations of various regular and irregular objects; (3) the number density of fractal particles is 6.9×10⁶ m⁻³ at Z=100 km, as compared with DISR's finding of 5.0×10⁶ m⁻³ at Z=80 km; (4) the number of structural units per higher fractals in the atmosphere at Z∼100 km is (2400-2700), as compared with DISR's 3000, and their size being of R=(5.4-6.4)×10⁻⁶ m will satisfy this value and (5) condensation of CH₄ on the highly fractal structures could begin at the altitude where thin methane clouds were observed, filling somewhat the new open fractal structures.  相似文献   

The Unusual Absorption Line Spectrum of Quasar SDSS J2220+0109     

Ji Tuo  Zhou Hong-yan  Wang Ting-gui  Wang Hui-yuan 《Chinese Astronomy and Astrophysics》2013

We report the Balmer broad absorption lines (BALs) in the quasar SDSS J2220 + 0109 discovered from the SDSS data, and present a detailed analysis of the peculiar absorption line spectrum, including the He I* multiplet at λλ3189, 3889 arising from the metastable 2³s-state helium and the Balmer Hα and Hβ lines from the excited hydrogen H I of n = 2 level, which are rarely seen in quasar spectra, as well as many absorption lines arising from the excited Fe II* of the levels 7 955 cm⁻¹, 13 474 cm⁻¹ and 13 673 cm⁻¹ in the wavelength range 3100∼3300 Å. Ca II H, K absorption line doublets also clearly appear in the SDSS spectrum. All absorption lines show a similar blueshifted velocity structure of Δv ≈ − 1500 ∼ 0 km·s⁻¹ relative to the quasar's systematic redshift determined from the emission lines. Detailed analysis suggests that the Balmer absorption lines should arise from the partially ionized region with a column density of N_HI ≈ 10²¹ cm⁻² for an electron density of ne ∼ 10⁶ cm⁻³; and that the hydrogen n = 2 level may be populated via collisional excitation with Lyα pumping.  相似文献   

Minimum estimates of the amount and timing of gases released into the martian atmosphere from volcanic eruptions     

Robert A. Craddock  Ronald Greeley 《Icarus》2009,204(2):512-151

Volcanism has been a major process during most of the geologic history of Mars. Based on data collected from terrestrial basaltic eruptions, we assume that the volatile content of martian lavas was typically ∼0.5 wt.% water, ∼0.7 wt.% carbon dioxide, ∼0.14 wt.% sulfur dioxide, and contained several other important volatile constituents. From the geologic record of volcanism on Mars we find that during the late Noachian and through the Amazonian volcanic degassing contributed ∼0.8 bar to the martian atmosphere. Because most of the outgassing consisted of greenhouse gases (i.e., CO₂ and SO₂) warmer surface temperatures resulting from volcanic eruptions may have been possible. Our estimates suggest that ∼1.1 × 10²¹ g (∼8 ± 1 m m⁻²) of juvenile water were released by volcanism; slightly more than half the amount contained in the north polar cap and atmosphere. Estimates for released CO₂ (1.6 × 10²¹ g) suggests that a large reservoir of carbon dioxide is adsorbed in the martian regolith or alternatively ∼300 cm cm⁻² of carbonates may have formed, although these materials would not occur readily in the presence of excess SO₂. Up to ∼120 cm cm⁻² (2.2 × 10²⁰ g) of acid rain (H₂SO₄) may have precipitated onto the martian surface as the result of SO₂ degassing. The hydrogen flux resulting from volcanic outgassing may help explain the martian atmospheric D/H ratio. The amount of outgassed nitrogen (∼1.3 mbar) may also be capable of explaining the martian atmospheric ¹⁵N/¹⁴N ratio. Minor gas constituents (HF, HCl, and H₂S) could have formed hydroxyl salts on the surface resulting in the physical weathering of geologic materials. The amount of hydrogen fluoride emitted (1.82 × 10¹⁸ g) could be capable of dissolving a global layer of quartz sand ∼5 mm thick, possibly explaining why this mineral has not been positively identified in spectral observations. The estimates of volcanic outgassing presented here will be useful in understanding how the martian atmosphere evolved over time.  相似文献   

Titan’s atmosphere from ISO mid-infrared spectroscopy     

Athena Coustenis  A Salama  S Ott  T.h Encrenaz  H Feuchtgruber 《Icarus》2003,161(2):383-403

We have analyzed Titan observations performed by the Infrared Space Observatory (ISO) in the range 7-30 μm. The spectra obtained by three of the instruments on board the mission (the short wavelength spectrometer, the photometer, and the camera) were combined to provide new and more precise thermal and compositional knowledge of Titan’s stratosphere. With the high spectral resolution achieved by the SWS (much higher than that of the Voyager 1 IRIS spectrometer), we were able to detect and separate the contributions of most of the atmospheric gases present on Titan and to determine disk-averaged mole fractions. We have also tested existing vertical distributions for C₂H₂, HCN, C₂H₆, and CO₂ and inferred some information on the abundance of the first species as a function of altitude. From the CH₃D band at 1161 cm⁻¹ and for a CH₄ mole fraction assumed to be 1.9% in Titan’s stratosphere, we have obtained the monodeuterated methane-averaged abundance and retrieved a D/H isotopic ratio of 8.7−1.9+3.2 × 10⁻⁵. We discuss the implications of this value with respect to current evolutionary scenarios for Titan. The ν₅ band of HC₃N at 663 cm⁻¹ was observed for the first time in a disk-averaged spectrum. We have also obtained a first tentative detection of benzene at 674 cm⁻¹, where the fit of the ISO/SWS spectrum at R = 1980 is significantly improved when a constant mean mole fraction of 4 × 10⁻¹⁰ of C₆H₆ is incorporated into the atmospheric model. This corresponds to a column density of ∼ 2 × 10¹⁵ molecules cm⁻² above the 30-mbar level. We have also tested available vertical profiles for HC₃N and C₆H₆ and adjusted them to fit the data. Finally, we have inferred upper limits of a few 10⁻¹⁰ for a number of molecules proposed as likely candidates on Titan (such as allene, acetonitrile, propionitrile, and other more complex gases).  相似文献