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1.
We have performed high-resolution spectral observations at mid-infrared wavelengths of C2H6 (12.16 μm), and C2H2 (13.45 μm) on Saturn. These emission features probe the stratosphere of the planet and provide information on the hydrocarbon photochemical processes taking place in that region of the atmosphere. The observations were performed using our cryogenic echelle spectrometer Celeste, in conjunction with the McMath-Pierce 1.5-m solar telescope in November and December 1994. We used Voyager IRIS CH4 observations (7.67 μm) to derive a temperature profile on the saturnian atmosphere for the region of the stratosphere. This profile was then used in conjunction with height-dependent volume mixing ratios of each hydrocarbon to determine global abundances for ethane and acetylene. Our ground-based measurements indicate abundances of for C2H6 (1.0 mbar pressure level), and for C2H2 (1.6 mbar pressure level). We also derived new mixing ratios from the Voyager mid-latitude IRIS observations; 8.6±0.9×10−6 for C2H6 (0.1-3.0 mbar pressure level), and 1.6±0.2×10−7 for C2H2 (2.0 mbar pressure level). 相似文献
2.
Darrell F. Strobel 《Icarus》2008,193(2):612-619
Hydrodynamic escape of N2 molecules from Pluto's atmosphere is calculated under the assumption of a high density, slow outflow expansion driven by solar EUV heating by N2 absorption, near-IR and UV heating by CH4 absorption, and CO cooling by rotational line emission as a function of solar activity. At 30 AU, the N2 escape rate varies from in the absence of heating, but driven by an upward thermal heat conduction flux from the stratosphere, for lower boundary temperatures varying from 70-100 K. With solar heating varying from solar minimum to solar maximum conditions and a calculated lower boundary temperature, 88.2 K, the N2 escape rate range is , respectively. LTE rotational line emission by CO reduces the net solar heat input by at most 35% and plays a minor role in lowering the calculated escape rates, but ensures that the lower boundary temperature can be calculated by radiative equilibrium with near-IR CH4 heating. While an upward thermal conduction heat flux at the lower boundary plays a fundamental role in the absence of heating, with solar heating it is downward at solar minimum, and is, at most, 13% of the integrated net heating rate over the range of solar activity. For the arrival of the New Horizons spacecraft at Pluto in July 2015, predictions are lower boundary temperature, T0∼81 K, and N2 escape rate , and peak thermospheric temperature ∼103 K at 1890 km, based on expected solar medium conditions. 相似文献
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Measurements of the vertical and latitudinal variations of temperature and C2H2 and C2H6 abundances in the stratosphere of Saturn can be used as stringent constraints on seasonal climate models, photochemical models, and dynamics. The summertime photochemical loss timescale for C2H6 in Saturn's middle and lower stratosphere (∼40-10,000 years, depending on altitude and latitude) is much greater than the atmospheric transport timescale; ethane observations may therefore be used to trace stratospheric dynamics. The shorter chemical lifetime for C2H2 (∼1-7 years depending on altitude and latitude) makes the acetylene abundance less sensitive to transport effects and more sensitive to insolation and seasonal effects. To obtain information on the temperature and hydrocarbon abundance distributions in Saturn's stratosphere, high-resolution spectral observations were obtained on September 13-14, 2002 UT at NASA's IRTF using the mid-infrared TEXES grating spectrograph. At the time of the observations, Saturn was at a LS≈270°, corresponding to Saturn's southern summer solstice. The observed spectra exhibit a strong increase in the strength of methane emission at 1230 cm−1 with increasing southern latitude. Line-by-line radiative transfer calculations indicate that a temperature increase in the stratosphere of ≈10 K from the equator to the south pole between 10 and 0.01 mbar is implied. Similar observations of acetylene and ethane were also recorded. We find the 1.16 mbar mixing ratio of C2H2 at −1° and −83° planetocentric latitude to be and , respectively. The C2H2 mixing ratio at 0.12 mbar is found to be at −1° planetocentric latitude and at −83° planetocentric latitude. The 2.3 mbar mixing ratio of C2H6 inferred from the data is and at −1° and −83° planetocentric latitude, respectively. Further observations, creating a time baseline, will be required to completely resolve the question of how much the latitudinal variations of C2H2 and C2H6 are affected by seasonal forcing and/or stratospheric circulation. 相似文献
5.
We report the detection of 13CH3D in Titan's stratosphere from Cassini/CIRS infrared spectra near 8.7 μm. Fitting simultaneously the ν6 bands of both 13CH3D and 12CH3D and the ν4 band of CH4, we derive a D/H ratio equal to and a 12C/13C ratio in deuterated methane of , consistent with that measured in normal methane. 相似文献
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We report laboratory studies on the 0.8 MeV proton irradiation of ices composed of sulfuric acid (H2SO4), sulfuric acid monohydrate (H2SO4·H2O), and sulfuric acid tetrahydrate (H2SO4·4H2O) between 10 and 180 K. Using infrared spectroscopy, we identify the main radiation products as H2O, SO2, (S2O3)x, H3O+, , and . At high radiation doses, we find that H2SO4 molecules are destroyed completely and that H2SO4·H2O is formed on subsequent warming. This hydrate is significantly more stable to radiolytic destruction than pure H2SO4, falling to an equilibrium relative abundance of 50% of its original value on prolonged irradiation. Unlike either pure H2SO4 or H2SO4·H2O, the loss of H2SO4·4H2O exhibits a strong temperature dependence, as the tetrahydrate is essentially unchanged at the highest irradiation temperatures and completely destroyed at the lowest ones, which we speculate is due to a combination of radiolytic destruction and amorphization. Furthermore, at the lower temperatures it is clear that irradiation causes the tetrahydrate spectrum to transition to one that closely resembles the monohydrate spectrum. Extrapolating our results to Europa’s surface, we speculate that the variations in SO2 concentrations observed in the chaotic terrains are a result of radiation processing of lower hydration states of sulfuric acid and that the monohydrate will remain stable on the surface over geological times, while the tetrahydrate will remain stable in the warmer regions but be destroyed in the colder regions, unless it can be reformed by other processes, such as thermal reactions induced by diurnal cycling. 相似文献
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In this paper we present the results of new experiments of ion irradiation of water ice deposited on top of a solid sulfurous residue to study the potential formation of SO2 at the interface ice/refractory material and discuss the possibility that this mechanism accounts for the sulfur dioxide ice detected on the surfaces of the Galilean satellites. In situ infrared spectroscopy was the used experimental technique. We have irradiated a thin film of H2O frost on a sulfurous layer with 200 keV of He+ at 80 K. The used sulfurous residue was obtained by irradiation of frozen SO2 at 16 K and it is used as a template of sulfur bearing solid materials. We have not found evidences of the efficient formation of SO2 after irradiation of H2O ice on top of the sulfurous residue. An upper limit to the production yield of SO2, of interface area for each 100 eV of energy absorbed in 1 cm3 of ice-covered residue, has been estimated. These results have relevance in the context of the surfaces of the icy Galilean satellites in which SO2 was detected. Our results show that radiolysis of mixtures of water ice and refractory sulfurous materials is not the primary formation mechanism responsible for the SO2 present on the surfaces of the Galilean satellites. 相似文献
11.
Jupiter exhibits bright H+3 auroral arcs at 3-4 microns that cool the hot (>1000 K) ionosphere above the ∼10−7 bar level through the infrared bands of this trace constituent. Below the 10−7 bar level significant cooling proceeds through infrared active bands of CH4, C2H2, and C2H6. We report the discovery of 3-micron line emission from these hydrocarbon species in spectra of the jovian south polar region obtained on April 18 and 20, 2006 (UT) with CGS4 on the United Kingdom Infrared Telescope. Estimated cooling rates through these molecules are 7.5×10−3, 1.4×10−3, and , respectively, for a total nearly half that of H+3. We derive a temperature of 450 ± 50 K in the 10−7-10−5 bar region from the C2H2 lines. 相似文献
12.
The contribution of exothermic ion and neutral chemistry to Titan's corona is studied. The production rates for fast neutrals N2, CH4, H, H2, 3CH2, CH3, C2H4, C2H5, C2H6, N(4S), NH, and HCN are determined using a coupled ion and neutral model of Titan's upper atmosphere. After production, the formation of the suprathermal particles is modeled using a two-stream simulation, as they travel simultaneously through a thermal mixture of N2, CH4, and H2. The resulting suprathermal fluxes, hot density profiles, and energy distributions are compared to the N2 and CH4 INMS exospheric data presented in [De La Haye, V., Waite Jr., J.H., Johnson, R.E., Yelle, R.V., Cravens, T.E., Luhmann, J.G., Kasprzak, W.T., Gell, D.A., Magee, B., Leblanc, F., Michael, M., Jurac, S., Robertson, I.P., 2007. J. Geophys. Res., doi:10.1029/2006JA012222, in press], and are found insufficient for producing the suprathermal populations measured. Global losses of nitrogen atoms and carbon atoms in all forms due to exothermic chemistry are estimated to be and . 相似文献
13.
We develop a parametric fit to the results of a detailed magnetohydrodynamic (MHD) study of the response of ion escape rates (O+, and ) to strongly varied solar forcing factors, as a way to efficiently extend the MHD results to different conditions. We then use this to develop a second, evolutionary model of solar forced ion escape. We treat the escape fluxes of ion species at Mars as proportional to the product of power laws of four factors - that of the EUV flux Reuv, the solar wind particle density Rρ, its velocity (squared) Rv2, and the interplanetary magnetic field pressure RB2, where forcing factors are expressed in units of the current epoch-averaged values. Our parametric model is: , where ?(i) is the escape flux of ion i. We base our study on the results of just six provided MHD model runs employing large forcing factor variations, and thus construct a successful, first-order parametric model of the MHD program. We perform a five-dimensional least squares fit of this power law model to the MHD results to derive the flux normalizations and the indices of the solar forcing factors. For O+, we obtain the values, 1.73 × 1024 s−1, 0.782, 0.251, 0.382, and 0.214, for ?0, α, β, γ, and δ, respectively. For , the corresponding values are 1.68 × 1024 s−1, −0.393, 0.798, 0.967, and 0.533. For , they are 8.66 × 1022 s−1, −0.427, 1.083, 1.214, and 0.690. The fit reproduces the MHD results to an average error of about 5%, suggesting that the power laws are broadly representative of the MHD model results. Our analysis of the MHD model shows that by itself an increase in REUV enhances O+ loss, but suppresses the escape of and , whereas increases in solar wind (i.e., in , and RB2, with Reuv constant) favors the escape of heavier ions more than light ions. The ratios of escaping ions detectable at Mars today can be predicted by this parametric fit as a function of the solar forcing factors. We also use the parametric model to compute escape rates over martian history. This second parametric model expresses ion escape functions of one variable (per ion), ?(i) = ?0(i)(t/t0)−ξ(i). The ξ(i) are linear combinations of the epoch-averaged ion escape sensitivities, which are seen to increase with ion mass. We integrate the and oxygen ion escape rates over time, and find that in the last 3.85 Gyr, Mars would have lost about mbars of , and of water (from O+ and ) from ion escape. 相似文献
14.
Analysis of Titan's neutral upper atmosphere from Cassini Ion Neutral Mass Spectrometer measurements
J. Cui R.V. Yelle V. Vuitton J.H. Waite Jr. W.T. Kasprzak D.A. Gell H.B. Niemann I.C.F. Müller-Wodarg N. Borggren G.G. Fletcher E.L. Patrick E. Raaen B.A. Magee 《Icarus》2009,200(2):581-615
In this paper we present an in-depth study of the distributions of various neutral species in Titan's upper atmosphere, between 950 and 1500 km for abundant species (N2, CH4, H2) and between 950 and 1200 km for other minor species. Our analysis is based on a large sample of Cassini/INMS (Ion Neutral Mass Spectrometer) measurements in the CSN (Closed Source Neutral) mode, obtained during 15 close flybys of Titan. To untangle the overlapping cracking patterns, we adopt Singular Value Decomposition (SVD) to determine simultaneously the densities of different species. Except for N2, CH4, H2 and 40Ar (as well as their isotopes), all species present density enhancements measured during the outbound legs. This can be interpreted as a result of wall effects, which could be either adsorption/desorption of these molecules or heterogeneous surface chemistry of the associated radicals on the chamber walls. In this paper, we provide both direct inbound measurements assuming ram pressure enhancement only and abundances corrected for wall adsorption/desorption based on a simple model to reproduce the observed time behavior. Among all minor species of photochemical interest, we have firm detections of C2H2, C2H4, C2H6, CH3C2H, C4H2, C6H6, CH3CN, HC3N, C2N2 and NH3 in Titan's upper atmosphere. Upper limits are given for other minor species.The globally averaged distributions of N2, CH4 and H2 are each modeled with the diffusion approximation. The N2 profile suggests an average thermospheric temperature of 151 K. The CH4 and H2 profiles constrain their fluxes to be and , referred to Titan's surface. Both fluxes are significantly higher than the Jeans escape values. The INMS data also suggest horizontal/diurnal variations of temperature and neutral gas distribution in Titan's thermosphere. The equatorial region, the ramside, as well as the nightside hemisphere of Titan appear to be warmer and present some evidence for the depletion of light species such as CH4. Meridional variations of some heavy species are also observed, with a trend of depletion toward the north pole. Though some of the above variations might be interpreted by either the solar-driven models or auroral-driven models, a physical scenario that reconciles all the observed horizontal/diurnal variations in a consistent way is still missing. With a careful evaluation of the effect of restricted sampling, some of the features shown in the INMS data are more likely to be observational biases. 相似文献
15.
In this work we report on new experiments of ion irradiation of water ice deposited on top of solid carbonaceous materials to study the production of CO2 at the interface ice/refractory material and discuss the possibility that this mechanism accounts for the quantity of CO2 ice detected on the surfaces of the Galilean satellites. The used experimental technique has been in situ infrared spectroscopy. We have irradiated thin films of H2O frost on carbonaceous layers with 200 keV of He+ and Ar+, and 30 keV of He+ at 16 and 80 K. The used carbonaceous layers have been asphaltite, a natural bitumen, and solid organic residues obtained by irradiation of frozen benzene. In both cases the results show that CO2 is produced very efficiently after irradiation obtaining a maximum quantity of the order of . These results are, also quantitatively similar, to those recently obtained for water ice deposited on amorphous carbon films [Mennella, V., Palumbo, M.E., Baratta, G.A., 2004. Formation of CO and CO2 molecules by ion irradiation of water ice covered hydrogenated carbon grains. Astrophys. J. 615, 1073-1080]. Thus we suggest that, whatever is the carbonaceous residue, CO2 will be produced efficiently by the studied process. These results have interest in the context of the surfaces of the icy Galilean satellites in which CO2 has been detected mainly trapped in the non-ice material, not in the pure water ice. We suggest that radiolysis of mixtures of water ice and refractory carbonaceous materials is the primary formation mechanism responsible for the CO2 formation on the surfaces of the Galilean satellites. 相似文献
16.
C.A. Nixon R.K. Achterberg B. Bézard P.G.J. Irwin R. de Kok D.E. Jennings F.M. Flasar 《Icarus》2008,195(2):778-791
We have analyzed infrared spectra of Titan recorded by the Cassini Composite Infrared Spectrometer (CIRS) to measure the isotopic ratio 12C/13C in each of three chemical species in Titan's stratosphere: CH4, C2H2 and C2H6. This is the first measurement of 12C/13C in any C2 molecule on Titan, and the first measurement of 12CH4/13CH4 (non-deuterated) on Titan by remote sensing. Our spectra cover five widely-spaced latitudes, 65° S to 71° N and we have searched for both latitude variability of 12C/13C within a given species, and also for differences between the 12C/13C in the three gases. For CH4 alone, we find (1-σ), essentially in agreement with the 12CH4/13CH4 measured by the Huygens Gas Chromatograph/Mass Spectrometer instrument (GCMS) [Niemann, H.B., and 17 colleagues, 2005. Nature 438, 779-784]: 82.3±1.0, and also with measured values in H13CN and 13CH3D by CIRS at lower precision [Bézard, B., Nixon, C., Kleiner, I., Jennings, D., 2007. Icarus 191, 397-400; Vinatier, S., Bézard, B., Nixon, C., 2007. Icarus 191, 712-721]. For the C2 species, we find in C2H2 and 89.8±7.3 in C2H6, a possible trend of increasingly value with molecular mass, although these values are both compatible with the Huygens GCMS value to within error bars. There are no convincing trends in latitude. Combining all fifteen measurements, we obtain a value of , also compatible with GCMS. Therefore, the evidence is mounting that 12C/13C is some 8% lower on Titan than on the Earth (88.9, inorganic standard), and lower than typical for the outer planets (88±7 [Sada, P.V., McCabe, G.H., Bjoraker, G.L., Jennings, D.E., Reuter, D.C., 1996. Astrophys. J. 472, 903-907]). There is no current model for this enrichment, and we discuss several mechanisms that may be at work. 相似文献
17.
Athena Coustenis Donald E. Jennings Yves Bénilan Sandrine Vinatier Gordon L. Bjoraker Ronald C. Carlson 《Icarus》2008,197(2):539-548
We report here the first detection of mono-deuterated acetylene (acetylene-d1, C2HD) in Titan's atmosphere from the presence of two of its emission bands at 678 and 519 cm−1 as observed in CIRS spectral averages of nadir and limb observations taken between July 2004 and mid-2007. By using new laboratory spectra for this molecule, we were able to derive its abundance at different locations over Titan's disk. We find the C2HD value () to be roughly constant with latitude from the South to about 45° N and then to increase slightly in the North, as is the case for C2H2. Fitting the 678 cm−1ν5 band simultaneously with the nearby C2H2 729 cm−1ν5 band, allows us to infer a D/H ratio in acetylene on Titan with an average of the modal values of 2.09±0.45×10−4 from the nadir observations, the uncertainties being mainly due to the vertical profile used for the fit of the acetylene band. Although still subject to significant uncertainty, this D/H ratio appears to be significantly larger than the one derived in methane from the CH3D band (upper limit of 1.5×10−4; Bézard, B., Nixon, C.A., Kleiner, I., Jennings, D.E., 2007. Icarus, 191, 397-400; Coustenis, A., Achterberg, R., Conrath, B., Jennings, D., Marten, A., Gautier, D., Bjoraker, G., Nixon, C., Romani, P., Carlson, R., Flasar, M., Samuelson, R.E., Teanby, N., Irwin, P., Bézard, B., Orton, G., Kunde, V., Abbas, M., Courtin, R., Fouchet, Th., Hubert, A., Lellouch, E., Mondellini, J., Taylor, F.W., Vinatier, S., 2007. Icarus 189, 35-62). From the analysis of limb data we infer D/H values of (at 54° S), (at 15° S), (at 54° N) and (at 80° N), which average to a mean value of 1.63±0.27×10−4. 相似文献
18.
Infrared spectra and radiation chemical behavior of N2-dominated ices relevant to the surfaces of Triton and Pluto are presented. This is the first systematic IR study of proton-irradiated N2-rich ices containing CH4 and CO. Experiments at 12 K show that HCN, HNC, and diazomethane (CH2N2) form in the solid phase, along with several radicals. NH3 is also identified in irradiated N2 + CH4 and N2 + CH4 + CO. We show that HCN and HNC are made in irradiated binary ice mixtures having initial N2/CH4 ratios from 100 to 4, and in three-component mixtures have an initial N2/(CH4 + CO) ratio of 50. HCN and HNC are not detected in N2-dominated ices when CH4 is replaced with C2H6, C2H2, or CH3OH.The intrinsic band strengths of HCN and HNC are measured and used to calculate G(HCN) and G(HNC) in irradiated N2 + CH4 and N2 + CH4 + CO ices. In addition, the HNC/HCN ratio is calculated to be ∼1 in both icy mixtures. These radiolysis results reveal, for the first time, solid-phase synthesis of both HCN and HNC in N2-rich ices containing CH4.We examine the evolution of spectral features due to acid-base reactions (acids such as HCN, HNC, and HNCO and a base, NH3) triggered by warming irradiated ices from 12 K to 30-35 K. We identify anions (OCN−, CN−, and N3−) in ices warmed to 35 K. These ions are expected to form and survive on the surfaces of Triton and Pluto. Our results have astrobiological implications since many of these products (HCN, HNC, HNCO, NH3, NH4OCN, and NH4CN) are involved in the syntheses of biomolecules such as amino acids and polypeptides. 相似文献
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To improve the scaling parameter controlling the impact crater formation in the strength regime, we conducted impact experiments on sintered snow targets with the dynamic strength continuously changed from 20 to 200 kPa, and the largest crater size formed on small icy satellites was considered by using the revised scaling parameter. Ice and snow projectiles were impacted on a snow surface with 36% porosity at an impact velocity from 31 m s−1 to 150 m s−1. The snow target was sintered at the temperature from −5 °C to −18 °C, and the snow dynamic strength was changed with the sintering duration at each temperature. We found that the mass ejected from the crater normalized by the projectile mass, πV, was related to the ratio of the dynamic strength to the impact pressure, , as follows: , where the impact pressure was indicated by P = ρtC0tvi/2 with the target density of ρt, when the impact velocity, vi, was much smaller than the bulk sound velocity C0t (typically 1.8 km s−1 in our targets). The ratio of the largest crater diameter to the diameter of the target body, dmax/D, was estimated by calculating the crater diameter at the impact condition for catastrophic disruption and then compared to the observed dmax/D of jovian and saturnian small satellites, in order to discuss the formation condition of these large dmax/D in the strength regime. 相似文献
20.
The existence of strong absorption bands of singly deuterated methane (CH3D) at wavelengths where normal methane (CH4) absorbs comparatively weakly could enable remote measurement of D/H ratios in methane ice on outer Solar System bodies. We performed laboratory transmission spectroscopy experiments, recording spectra at wavelengths from 1 to 6 μm to study CH3D bands at 2.47, 2.87, and 4.56 μm, wavelengths where ordinary methane absorption is weak. We report temperature-dependent absorption coefficients of these bands when the CH3D is diluted in CH4 ice and also when it is dissolved in N2 ice, and describe how these absorption coefficients can be combined with data from the literature to simulate arbitrary D/H ratio absorption coefficients for CH4 ice and for CH4 in N2 ice. We anticipate these results motivating new telescopic observations to measure D/H ratios in CH4 ice on Triton, Pluto, Eris, and Makemake. 相似文献