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1.
NASA’s Phoenix lander identified perchlorate and carbonate salts on Mars. Perchlorates are rare on Earth, and carbonates have largely been ignored on Mars following the discovery by NASA’s Mars Exploration Rovers of acidic precipitated minerals such as jarosite. In light of the Phoenix results, we updated the aqueous thermodynamic model FREZCHEM to include perchlorate chemistry. FREZCHEM models the Na-K-Mg-Ca-Fe(II)-Fe(III)-Al-H-Cl-Br-SO4-NO3-OH-HCO3-CO3-CO2-O2-CH4-Si-H2O system, with 95 solid phases. We added six perchlorate salts: NaClO4·H2O, NaClO4·2H2O, KClO4, Mg(ClO4)2·6H2O, Mg(ClO4)2·8H2O, and Ca(ClO4)2·6H2O. Modeled eutectic temperatures for Na, Mg, and Ca perchlorates ranged from 199 K (−74 °C) to 239 K (−34 °C) in agreement with experimental data.We applied FREZCHEM to the average solution chemistry measured by the Wet Chemistry Laboratory (WCL) experiment at the Phoenix site when soil was added to water. FREZCHEM was used to estimate and alkalinity concentrations that were missing from the WCL data. The amount of is low compared to estimates from elemental abundance made by other studies on Mars. In the charge-balanced solution, the dominant cations were Mg2+ and Na+ and the dominant anions were , and alkalinity. The abundance of calcite measured at the Phoenix site has been used to infer that the soil may have been subject to liquid water in the past, albeit not necessarily locally; so we used FREZCHEM to evaporate (at 280.65 K) and freeze (from 280.65 to 213.15 K) the WCL-measured solution to provide insight into salts that may have been in the soil. Salts that precipitated under both evaporation and freezing were calcite, hydromagnesite, gypsum, KClO4, and Mg(ClO4)2·8H2O. Epsomite (MgSO4·7H2O) and NaClO4·H2O were favored by evaporation at temperatures >0 °C, while meridianite (MgSO4·11H2O), MgCl2·12H2O, and NaClO4·2H2O were favored at subzero temperatures. Incongruent melting of such highly hydrated salts could be responsible for vug formation elsewhere on Mars.All K+ precipitated as insoluble KClO4 during both evaporation and freezing simulations, accounting for 15.8% of the total perchlorates. During evaporation, 35.8% of perchlorates precipitated with Na+ and 48.4% with Mg2+. During freezing, 58.4% precipitated with Na+ and 24.8% with Mg2+. Given its low eutectic temperature, the existence of Mg(ClO4)2 in either case allows for the possibility of liquid brines on Mars today. FREZCHEM also showed that Ca(ClO4)2 would likely not have precipitated at the Phoenix landing site due to the strong competing sinks for Ca as calcite and gypsum. Overall, these results help constrain the salt mineralogy of the soil. Differences between evaporites and cryogenites suggest ways to discriminate between evaporation and freezing during salt formation. Future efforts, such as sample return or in situ X-ray diffraction, may make such a determination possible. 相似文献
2.
In this paper we present the results of new experiments of ion irradiation of water ice deposited on top of a solid sulfurous residue to study the potential formation of SO2 at the interface ice/refractory material and discuss the possibility that this mechanism accounts for the sulfur dioxide ice detected on the surfaces of the Galilean satellites. In situ infrared spectroscopy was the used experimental technique. We have irradiated a thin film of H2O frost on a sulfurous layer with 200 keV of He+ at 80 K. The used sulfurous residue was obtained by irradiation of frozen SO2 at 16 K and it is used as a template of sulfur bearing solid materials. We have not found evidences of the efficient formation of SO2 after irradiation of H2O ice on top of the sulfurous residue. An upper limit to the production yield of SO2, of interface area for each 100 eV of energy absorbed in 1 cm3 of ice-covered residue, has been estimated. These results have relevance in the context of the surfaces of the icy Galilean satellites in which SO2 was detected. Our results show that radiolysis of mixtures of water ice and refractory sulfurous materials is not the primary formation mechanism responsible for the SO2 present on the surfaces of the Galilean satellites. 相似文献
3.
The objective of this work is to propose an automated unmixing technique for the analysis of 11-channel Mars Exploration Rover Panoramic Camera (MER/Pancam) spectra. Our approach is to provide a screening tool for identifying unique/distinct reflectance spectra. We demonstrate the utility of this unmixing technique in a study of the mineralogy of the bright salty soils exposed by the rover wheels in images of Gusev crater regions known as Paso Robles (Sols 400,426), Arad (Sol 721), and Tyrone (Sol 790). The unmixing algorithm is based on a novel derivation of the Nonnegative Matrix Factorization technique and includes added features that preclude the adverse effects of low abundance materials that would otherwise skew the unmixing. In order to create a full 11-channel spectrum out of the left and right eye stereo pairs, we also developed a new registration procedure that includes rectification and disparity calculation of the images. We identified two classes of endmember spectra for the bright soils imaged on Sols 426 and 790. One of these endmember classes is also observed for soils imaged on Sols 400 and 721 and has a unique spectral shape that is distinct from most iron oxide, sulfate and silicate spectra and differs from typical martian surface spectra. Instead, its unique spectral character resembles the spectral shape of the ferric sulfate minerals fibroferrite (Fe3+(SO4)(OH) · 5H2O) and ferricopiapite and the phosphate mineral ferristrunzite . The other endmember class is less consistent with specific minerals and is likely a mixture of altered volcanic material and some bright salts. Further analyses of data from Sols 400 and 790 using an anomaly detection algorithm as a tool for detecting low abundance materials additionally suggests the identification of the sulfate mineral paracoquimbite (Fe2(SO4)3 · 9H2O). This spectral study of Pancam images of the bright S- and P-enriched soils of Gusev crater identifies specific ferric sulfate and ferric phosphate minerals that are consistent with the unique spectral properties observed here in the 0.4-1 μm range. 相似文献
4.
Darrell F. Strobel 《Icarus》2008,193(2):588-594
The upper atmosphere of Titan is currently losing mass at a rate , by hydrodynamic escape as a high density, slow outward expansion driven principally by solar UV heating by CH4 absorption. The hydrodynamic mass loss is essentially CH4 and H2 escape. Their combined escape rates are restricted by power limitations from attaining their limiting rates (and limiting fluxes). Hence they must exhibit gravitational diffusive separation in the upper atmosphere with increasing mixing ratios to eventually become major constituents in the exosphere. A theoretical model with solar EUV heating by N2 absorption balanced by HCN rotational line cooling in the upper thermosphere yields densities and temperatures consistent with the Huygens Atmospheric Science Investigation (HASI) data [Fulchignoni, M., and 42 colleagues, 2005. Nature 438, 785-791], with a peak temperature of ∼185-190 K between 3500-3550 km. This model implies hydrodynamic escape rates of and , or some other combination with a higher H2 escape flux, much closer to its limiting value, at the expense of a slightly lower CH4 escape rate. Nonthermal escape processes are not required to account for the loss rates of CH4 and H2, inferred by the Cassini Ion Neutral Mass Spectrometer (INMS) measurements [Yelle, R.V., Borggren, N., de la Haye, V., Kasprzak, W.T., Niemann, H.B., Müller-Wodarg, I., Waite Jr., J.H., 2006. Icarus 182, 567-576]. 相似文献
5.
A global solution for the Mars static and seasonal gravity, Mars orientation, Phobos and Deimos masses, and Mars ephemeris 总被引：2，自引：0，他引：2
Alex S. Konopliv Charles F. Yoder E. Myles Standish Dah-Ning Yuan William L. Sjogren 《Icarus》2006,182(1):23-50
With the collection of six years of MGS tracking data and three years of Mars Odyssey tracking data, there has been a continual improvement in the JPL Mars gravity field determination. This includes the measurement of the seasonal changes in the gravity coefficients (e.g., , , , , , ) caused by the mass exchange between the polar ice caps and atmosphere. This paper describes the latest gravity field MGS95J to degree and order 95. The improvement comes from additional tracking data and the adoption of a more complete Mars orientation model with nutation, instead of the IAU 2000 model. Free wobble of the Mars' spin axis, i.e. polar motion, has been constrained to be less than 10 mas by looking at the temporal history of and . A strong annual signature is observed in , and this is a mixture of polar motion and ice mass redistribution. The Love number solution with a subset of Odyssey tracking data is consistent with the previous liquid outer core determination from MGS tracking data [Yoder et al., 2003. Science 300, 299-303], giving a combined solution of k2=0.152±0.009 using MGS and Odyssey tracking data. The solutions for the masses of the Mars' moons show consistency between MGS, Odyssey, and Viking data sets; Phobos GM=(7.16±0.005)×10−4 km3/s2 and Deimos GM=(0.98±0.07)×10−4 km3/s2. Average MGS orbit errors, determined from differences in the overlaps of orbit solutions, have been reduced to 10-cm in the radial direction and 1.5 m along the spacecraft velocity and normal to the orbit plane. Hence, the ranging to the MGS and Odyssey spacecraft has resulted in position measurements of the Mars system center-of-mass relative to the Earth to an accuracy of one meter, greatly reducing the Mars ephemeris errors by several orders of magnitude, and providing mass estimates for Asteroids 1 Ceres, 2 Pallas, 3 Juno, 4 Vesta, and 324 Bamberga. 相似文献
6.
Measurements of the vertical and latitudinal variations of temperature and C2H2 and C2H6 abundances in the stratosphere of Saturn can be used as stringent constraints on seasonal climate models, photochemical models, and dynamics. The summertime photochemical loss timescale for C2H6 in Saturn's middle and lower stratosphere (∼40-10,000 years, depending on altitude and latitude) is much greater than the atmospheric transport timescale; ethane observations may therefore be used to trace stratospheric dynamics. The shorter chemical lifetime for C2H2 (∼1-7 years depending on altitude and latitude) makes the acetylene abundance less sensitive to transport effects and more sensitive to insolation and seasonal effects. To obtain information on the temperature and hydrocarbon abundance distributions in Saturn's stratosphere, high-resolution spectral observations were obtained on September 13-14, 2002 UT at NASA's IRTF using the mid-infrared TEXES grating spectrograph. At the time of the observations, Saturn was at a LS≈270°, corresponding to Saturn's southern summer solstice. The observed spectra exhibit a strong increase in the strength of methane emission at 1230 cm−1 with increasing southern latitude. Line-by-line radiative transfer calculations indicate that a temperature increase in the stratosphere of ≈10 K from the equator to the south pole between 10 and 0.01 mbar is implied. Similar observations of acetylene and ethane were also recorded. We find the 1.16 mbar mixing ratio of C2H2 at −1° and −83° planetocentric latitude to be and , respectively. The C2H2 mixing ratio at 0.12 mbar is found to be at −1° planetocentric latitude and at −83° planetocentric latitude. The 2.3 mbar mixing ratio of C2H6 inferred from the data is and at −1° and −83° planetocentric latitude, respectively. Further observations, creating a time baseline, will be required to completely resolve the question of how much the latitudinal variations of C2H2 and C2H6 are affected by seasonal forcing and/or stratospheric circulation. 相似文献
7.
Darrell F. Strobel 《Icarus》2009,202(2):632-641
In Strobel [Strobel, D.F., 2008. Icarus, 193, 588-594] a mass loss rate from Titan's upper atmosphere, , was calculated for a single constituent, N2 atmosphere by hydrodynamic escape as a high density, slow outward expansion driven principally by solar UV heating due to CH4 absorption. It was estimated, but not proven, that the hydrodynamic mass loss is essentially CH4 and H2 escape. Here the individual conservation of momentum equations for the three major components of the upper atmosphere (N2, CH4, H2) are solved in the low Mach number limit and compared with Cassini Ion Neutral Mass Spectrometer (INMS) measurements to demonstrate that light gases (CH4, H2) preferentially escape over the heavy gas (N2). The lightest gas (H2) escapes with a flux 99% of its limiting flux, whereas CH4 is restricted to ?75% of its limiting flux because there is insufficient solar power to support escape at the limiting rate. The respective calculated H2 and CH4 escape rates are 9.2×1027 and 1.7×1027 s−1, for a total of . From the calculated densities, mean free paths of N2, CH4, H2, and macroscopic length scales, an extended region above the classic exobase is inferred where frequent collisions are still occurring and thermal heat conduction can deliver power to lift the escaping gas out of the gravitational potential well. In this region rapid acceleration of CH4 outflow occurs. With the thermal structure of Titan's thermosphere inferred from INMS data by Müller-Wodarg et al. [Müller-Wodarg, I.C.F., Yelle, R.V., Cui, J., Waite Jr., J.H., 2008. J. Geophys. Res. 113, doi:10.1029/2007JE003033. E10005], in combination with calculated temperature profiles that include sputter induced plasma heating at the exobase, it is concluded that on average that the integrated, globally average, orbit-averaged, plasma heating rate during the Cassini epoch does not exceed (). 相似文献
8.
9.
Data acquired by the Ion Neutral Mass Spectrometer (INMS) on the Cassini spacecraft during its close encounter with Titan on 26 October 2004 reveal the structure of its upper atmosphere. Altitude profiles of N2, CH4, and H2, inferred from INMS measurements, determine the temperature, vertical mixing rate, and escape flux from the upper atmosphere. The mean atmospheric temperature in the region sampled by the INMS is 149±3 K, where the variance is a consequence of local time variations in temperature. The CH4 mole fraction at 1174 km is 2.71±0.1%. The effects of diffusive separation are clearly seen in the data that we interpret as an eddy diffusion coefficient of , that, along with the measured CH4 mole fraction, implies a mole fraction in the stratosphere of 2.2±0.2%. The H2 distribution is affected primarily by upward flow and atmospheric escape. The H2 mole fraction at 1200 km is 4±1×10−3 and analysis of the altitude profile indicates an upward flux of , referred to the surface. If horizontal variations in temperature and H2 density are small, this upward flux also represents the escape flux from the atmosphere. The CH4 density exhibits significant horizontal variations that are likely an indication of dynamical processes in the upper atmosphere. 相似文献
10.
11.
Europa's surface is chemically altered by radiolysis from energetic charged particle bombardment. It has been suggested that hydrated sulfuric acid (H2SO4·nH2O) is a major surface species and is part of a radiolytic sulfur cycle, where a dynamic equilibrium exists between continuous production and destruction of sulfur polymers Sx, sulfur dioxide SO2, hydrogen sulfide H2S, and H2SO4·nH2O. We measured the rate of sulfate anion production for cyclo-octal sulfur grains in frozen water at temperatures, energies, and dose rates appropriate for Europa using energetic electrons. The measured rate is GMixture(SO42−)=fSulfur (r0/r)βG1 molecules (100 eV)−1, where fSulfur is the sulfur weight fraction, r is the grain radius, r0=50 μm, β≈1.9, and G1=0.4±0.1. Equilibrium column densities N are derived for Europa's surface and follow the ordering N(H2SO4) » N(S)>N(SO2)>N(H2S). The lifetime of a sulfur atom on Europa's surface for radiolysis to H2SO4 is τ(−S)=120(r/r0)β years. Rapid radiolytic processing hides the identity of the original source of the sulfurous material, but Iogenic plasma ion implantation and an acidic or salty ocean are candidate sources. Sulfate salts, if present, would be decomposed in <3800 years and be rapidly assimilated into the sulfur cycle. 相似文献
12.
We develop a parametric fit to the results of a detailed magnetohydrodynamic (MHD) study of the response of ion escape rates (O+, and ) to strongly varied solar forcing factors, as a way to efficiently extend the MHD results to different conditions. We then use this to develop a second, evolutionary model of solar forced ion escape. We treat the escape fluxes of ion species at Mars as proportional to the product of power laws of four factors - that of the EUV flux Reuv, the solar wind particle density Rρ, its velocity (squared) Rv2, and the interplanetary magnetic field pressure RB2, where forcing factors are expressed in units of the current epoch-averaged values. Our parametric model is: , where ?(i) is the escape flux of ion i. We base our study on the results of just six provided MHD model runs employing large forcing factor variations, and thus construct a successful, first-order parametric model of the MHD program. We perform a five-dimensional least squares fit of this power law model to the MHD results to derive the flux normalizations and the indices of the solar forcing factors. For O+, we obtain the values, 1.73 × 1024 s−1, 0.782, 0.251, 0.382, and 0.214, for ?0, α, β, γ, and δ, respectively. For , the corresponding values are 1.68 × 1024 s−1, −0.393, 0.798, 0.967, and 0.533. For , they are 8.66 × 1022 s−1, −0.427, 1.083, 1.214, and 0.690. The fit reproduces the MHD results to an average error of about 5%, suggesting that the power laws are broadly representative of the MHD model results. Our analysis of the MHD model shows that by itself an increase in REUV enhances O+ loss, but suppresses the escape of and , whereas increases in solar wind (i.e., in , and RB2, with Reuv constant) favors the escape of heavier ions more than light ions. The ratios of escaping ions detectable at Mars today can be predicted by this parametric fit as a function of the solar forcing factors. We also use the parametric model to compute escape rates over martian history. This second parametric model expresses ion escape functions of one variable (per ion), ?(i) = ?0(i)(t/t0)−ξ(i). The ξ(i) are linear combinations of the epoch-averaged ion escape sensitivities, which are seen to increase with ion mass. We integrate the and oxygen ion escape rates over time, and find that in the last 3.85 Gyr, Mars would have lost about mbars of , and of water (from O+ and ) from ion escape. 相似文献
13.
Analysis of Titan's neutral upper atmosphere from Cassini Ion Neutral Mass Spectrometer measurements
J. Cui R.V. Yelle V. Vuitton J.H. Waite Jr. W.T. Kasprzak D.A. Gell H.B. Niemann I.C.F. Müller-Wodarg N. Borggren G.G. Fletcher E.L. Patrick E. Raaen B.A. Magee 《Icarus》2009,200(2):581-615
In this paper we present an in-depth study of the distributions of various neutral species in Titan's upper atmosphere, between 950 and 1500 km for abundant species (N2, CH4, H2) and between 950 and 1200 km for other minor species. Our analysis is based on a large sample of Cassini/INMS (Ion Neutral Mass Spectrometer) measurements in the CSN (Closed Source Neutral) mode, obtained during 15 close flybys of Titan. To untangle the overlapping cracking patterns, we adopt Singular Value Decomposition (SVD) to determine simultaneously the densities of different species. Except for N2, CH4, H2 and 40Ar (as well as their isotopes), all species present density enhancements measured during the outbound legs. This can be interpreted as a result of wall effects, which could be either adsorption/desorption of these molecules or heterogeneous surface chemistry of the associated radicals on the chamber walls. In this paper, we provide both direct inbound measurements assuming ram pressure enhancement only and abundances corrected for wall adsorption/desorption based on a simple model to reproduce the observed time behavior. Among all minor species of photochemical interest, we have firm detections of C2H2, C2H4, C2H6, CH3C2H, C4H2, C6H6, CH3CN, HC3N, C2N2 and NH3 in Titan's upper atmosphere. Upper limits are given for other minor species.The globally averaged distributions of N2, CH4 and H2 are each modeled with the diffusion approximation. The N2 profile suggests an average thermospheric temperature of 151 K. The CH4 and H2 profiles constrain their fluxes to be and , referred to Titan's surface. Both fluxes are significantly higher than the Jeans escape values. The INMS data also suggest horizontal/diurnal variations of temperature and neutral gas distribution in Titan's thermosphere. The equatorial region, the ramside, as well as the nightside hemisphere of Titan appear to be warmer and present some evidence for the depletion of light species such as CH4. Meridional variations of some heavy species are also observed, with a trend of depletion toward the north pole. Though some of the above variations might be interpreted by either the solar-driven models or auroral-driven models, a physical scenario that reconciles all the observed horizontal/diurnal variations in a consistent way is still missing. With a careful evaluation of the effect of restricted sampling, some of the features shown in the INMS data are more likely to be observational biases. 相似文献
14.
15.
C.A. Nixon R.K. Achterberg B. Bézard P.G.J. Irwin R. de Kok D.E. Jennings F.M. Flasar 《Icarus》2008,195(2):778-791
We have analyzed infrared spectra of Titan recorded by the Cassini Composite Infrared Spectrometer (CIRS) to measure the isotopic ratio 12C/13C in each of three chemical species in Titan's stratosphere: CH4, C2H2 and C2H6. This is the first measurement of 12C/13C in any C2 molecule on Titan, and the first measurement of 12CH4/13CH4 (non-deuterated) on Titan by remote sensing. Our spectra cover five widely-spaced latitudes, 65° S to 71° N and we have searched for both latitude variability of 12C/13C within a given species, and also for differences between the 12C/13C in the three gases. For CH4 alone, we find (1-σ), essentially in agreement with the 12CH4/13CH4 measured by the Huygens Gas Chromatograph/Mass Spectrometer instrument (GCMS) [Niemann, H.B., and 17 colleagues, 2005. Nature 438, 779-784]: 82.3±1.0, and also with measured values in H13CN and 13CH3D by CIRS at lower precision [Bézard, B., Nixon, C., Kleiner, I., Jennings, D., 2007. Icarus 191, 397-400; Vinatier, S., Bézard, B., Nixon, C., 2007. Icarus 191, 712-721]. For the C2 species, we find in C2H2 and 89.8±7.3 in C2H6, a possible trend of increasingly value with molecular mass, although these values are both compatible with the Huygens GCMS value to within error bars. There are no convincing trends in latitude. Combining all fifteen measurements, we obtain a value of , also compatible with GCMS. Therefore, the evidence is mounting that 12C/13C is some 8% lower on Titan than on the Earth (88.9, inorganic standard), and lower than typical for the outer planets (88±7 [Sada, P.V., McCabe, G.H., Bjoraker, G.L., Jennings, D.E., Reuter, D.C., 1996. Astrophys. J. 472, 903-907]). There is no current model for this enrichment, and we discuss several mechanisms that may be at work. 相似文献
16.
Thomas K. Greathouse Matthew Richter Julianne Moses Therese Encrenaz Dan Jaffe 《Icarus》2011,214(2):606-621
Using TEXES, the Texas Echelon cross Echelle Spectrograph, mounted on the Gemini North 8-m telescope we have mapped the spatial variation of H2, CH4, C2H2 and C2H6 thermal-infrared emission of Neptune. These high-spectral-resolution, spatially resolved, thermal-infrared observations of Neptune offer a unique glimpse into the state of Neptune’s stratosphere in October 2007, LS = 275.4° just past Neptune’s southern summer solstice (LS = 270°). We use observations of the S(1) pure rotational line of molecular hydrogen and a portion of the ν4 band of methane to retrieve detailed information on Neptune’s stratospheric vertical and meridional thermal structure. We find global-average temperatures of 163.8 ± 0.8, 155.0 ± 0.9, and 123.8 ± 0.8 K at the 7.0 × 10−3-, 0.12-, and 2.1-mbar levels with no meridional variations within the errors. We then use the inferred temperatures to model the emission of C2H2 and C2H6 in order to derive stratospheric volume mixing ratios (hence forth, VMR) as a function of pressure and latitude. There is a subtle meridional variation of the C2H2 VMR at the 0.5-mbar level with the peak abundance found at −28° latitude, falling off to the north and south. However, the observations are consistent within error to a meridionally constant C2H2 VMR of at 0.5 mbar. We find that the VMR of C2H6 at 1-mbar peaks at the equator and falls by a factor of 1.6 at −70° latitude. However, a meridionally constant VMR of at the 1-mbar level for C2H6 is also statistically consistent with the retrievals. Temperature predictions from a radiative-seasonal climate model of Neptune that assumes the hydrocarbon abundances inferred in this paper are lower than the measured temperatures by 40 K at 7 × 10−3 mbar, 30 K at 0.12 mbar and 25 K at 2.1 mbar. The radiative-seasonal model also predicts meridional temperature variations on the order of 10 K from equator to pole, which are not observed. Assuming higher stratospheric CH4 abundance at the equator relative to the south pole would bring the meridional trends of the inferred temperatures and radiative-seasonal model into closer agreement.We have also retrieved observations of C2H4 emission from Neptune’s stratosphere using TEXES on the NASA Infrared Telescope Facility (IRTF) in June 2003, LS = 266°. Using the observations from the middle of the planet and an average of the middle three latitude temperature profiles from the 2007 observations (9.5° of LS later, the seasonal equivalent of 9.5 Earth days within Earth’s seasonal cycle), we infer a C2H4 VMR of at 1.5 × 10−3 mbar, a value that is 3.25 times that predicted by global-average photochemical models. 相似文献
17.
We have performed high-resolution spectral observations at mid-infrared wavelengths of C2H6 (12.16 μm), and C2H2 (13.45 μm) on Saturn. These emission features probe the stratosphere of the planet and provide information on the hydrocarbon photochemical processes taking place in that region of the atmosphere. The observations were performed using our cryogenic echelle spectrometer Celeste, in conjunction with the McMath-Pierce 1.5-m solar telescope in November and December 1994. We used Voyager IRIS CH4 observations (7.67 μm) to derive a temperature profile on the saturnian atmosphere for the region of the stratosphere. This profile was then used in conjunction with height-dependent volume mixing ratios of each hydrocarbon to determine global abundances for ethane and acetylene. Our ground-based measurements indicate abundances of for C2H6 (1.0 mbar pressure level), and for C2H2 (1.6 mbar pressure level). We also derived new mixing ratios from the Voyager mid-latitude IRIS observations; 8.6±0.9×10−6 for C2H6 (0.1-3.0 mbar pressure level), and 1.6±0.2×10−7 for C2H2 (2.0 mbar pressure level). 相似文献
18.
Vladimir A. Krasnopolsky 《Icarus》2011,215(1):197-203
The vertical profile of H2SO4 vapor is calculated using current atmospheric and thermodynamic data. The atmospheric data include the H2O profiles observed at 70-112 km by the SOIR solar occultations, the SPICAV-UV profiles of the haze extinction at 220 nm, the VeRa temperature profiles, and a typical profile of eddy diffusion. The thermodynamic data are the saturated vapor pressures of H2O and H2SO4 and chemical potentials of these species in sulfuric acid solutions. The calculated concentration of sulfuric acid in the cloud droplets varies from 85% at 70 km to a minimum of 70% at 90 km and then gradually increasing to 90-100% at 110 km. The H2SO4 vapor mixing ratio is ∼10−12 at 70 and 110 km with a deep minimum of 3 × 10−18 at 88 km. The H2O-H2SO4 system matches the local thermodynamic equilibrium conditions up to 87 km. The column photolysis rate of H2SO4 is 1.6 × 105 cm−2 s−1 at 70 km and 23 cm−2 s−1 at 90 km. The calculated abundance of H2SO4 vapor at 90-110 km and its photolysis rate are smaller than those presented in the recent model by Zhang et al. (Zhang, X., Liang, M.C., Montmessin, F., Bertaux, J.L., Parkinson, C., Yung, Y.L. [2010]. Nat. Geosci. 3, 834-837) by factors of 106 and 109, respectively. Assumptions of 100% sulfuric acid, local thermodynamic equilibrium, too warm atmosphere, supersaturation of H2SO4 (impossible for a source of SOX), and cross sections for H2SO4·H2O (impossible above the pure H2SO4) are the main reasons of this huge difference. Significant differences and contradictions between the SPICAV-UV, SOIR, and ground-based submillimeter observations of SOX at 70-110 km are briefly discussed and some weaknesses are outlined. The possible source of high altitude SOX on Venus remains unclear and probably does not exist. 相似文献
19.
Ultraviolet (UV) spectra of Saturn's aurora obtained with the Hubble Space Telescope Imaging Spectrograph (STIS), the Cassini Ultraviolet Imaging Spectrograph (UVIS) and the Far Ultraviolet Spectroscopic Explorer (FUSE) have been analyzed. Comparisons between the observed spectra and synthetic models of electron-excited H2 have been used to determine various auroral characteristics. Far ultraviolet (FUV: 1200-1700 Å) STIS and UVIS spectra exhibit, below 1400 Å, weak absorption due to methane, with a vertical column ranging between 1.4×1015 and . Using the low-latitude Moses et al. [Moses, J.I., Bézard, B., Lellouch, E., Feuchtgruber, H., Gladstone, G.R., Allen, M., 2000. Icarus, 143, 244-298] atmospheric model of Saturn and an electron energy-H2 column relationship, these methane columns are converted into the mean energy of the primary precipitating electrons, estimated to lie in the range 10-18 keV. This result is confirmed by the study of self-absorption with UVIS and FUSE extreme ultraviolet (EUV: 900-1200 Å) spectra. Below 1200 Å, it is seen that transitions connecting to the v″<2 vibrational levels of the H2 electronic ground state are partially self-absorbed by H2 molecules overlying the auroral emission. Because of its low spectral resolution (∼5.5 Å), the UVIS EUV spectrum we analyzed does not allow us to unequivocally determine reasonable ranges of temperatures and H2 columns. On the other hand, the high spectral resolution (∼0.2 Å) of the FUSE LiF1a and LiF2a EUV spectra we examined resolve the H2 rotational lines and makes it possible to determine the H2 temperature. The modeled spectrum best fitting the FUSE LiF1a observation reveals a temperature of 500 K and self-absorption by a H2 vertical column of . When converted to energy of precipitating electrons, this H2 column corresponds to primary electrons of ∼10 keV. The model that best fits the LiF2a spectrum is characterized by a temperature of 400 K and is not self-absorbed, making this segment ideal to determine the H2 temperature at the altitude of the auroral emission. The latter value is in agreement with temperatures obtained from infrared polar spectra. Self-absorption is detectable in the LiF2a segment for H2 columns exceeding , which sets the maximum mean energy determined from the FUSE observations to ∼15 keV. The total electron energy range of 10-18 keV deduced from FUV and EUV observations places the auroral emission peak between the 0.1 and 0.3 μbar pressure levels. These values should be seen as an upper limit, since most of the Voyager UVS spectra of Saturn's aurora examined by Sandel et al. [Sandel, B.R., Shemansky, D.E., Broadfoot, A.L., Holberg, J.B., Smith, G.R., 1982. Science 215, 548] do not exhibit methane absorption. The auroral H2 emission is thus likely located above but close to the methane homopause. The H2 auroral brightness in the 800-1700 Å bandwidth varies from 2.9 kR to 139 kR, comparable to values derived from FUV Faint Object Camera (FOC) and STIS images. 相似文献
20.
The contribution of exothermic ion and neutral chemistry to Titan's corona is studied. The production rates for fast neutrals N2, CH4, H, H2, 3CH2, CH3, C2H4, C2H5, C2H6, N(4S), NH, and HCN are determined using a coupled ion and neutral model of Titan's upper atmosphere. After production, the formation of the suprathermal particles is modeled using a two-stream simulation, as they travel simultaneously through a thermal mixture of N2, CH4, and H2. The resulting suprathermal fluxes, hot density profiles, and energy distributions are compared to the N2 and CH4 INMS exospheric data presented in [De La Haye, V., Waite Jr., J.H., Johnson, R.E., Yelle, R.V., Cravens, T.E., Luhmann, J.G., Kasprzak, W.T., Gell, D.A., Magee, B., Leblanc, F., Michael, M., Jurac, S., Robertson, I.P., 2007. J. Geophys. Res., doi:10.1029/2006JA012222, in press], and are found insufficient for producing the suprathermal populations measured. Global losses of nitrogen atoms and carbon atoms in all forms due to exothermic chemistry are estimated to be and . 相似文献