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1.
The gray crystalline hematite at Meridiani Planum first discovered by the Mars Global Surveyor Thermal Emission Spectrometer (MGS-TES) instrument occurs as spherules that have been interpreted as concretions. Analysis of the TES and mini-TES spectra shows that no 390 cm−1 feature is present in the characteristic martian hematite spectrum. Here, we incorporate the mid-IR optical constants of hematite into a simple Fresnel reflectance model to understand the effect of emission angle and crystal morphology on the presence or absence of the 390 cm−1 feature in an IR hematite spectrum. Based on the results we offer two models for the internal structure of the martian hematite spherules.  相似文献   

2.
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3.
We have determined the real and imaginary indices of refraction (n and k) for six iron oxide/oxyhydroxide phases—magnetite, maghemite, goethite, lepidocrocite, akaganéite, and ferrihydrite. A single crystal of magnetite was used to derive bulk n and k values from 100-2000 cm−1 (5-100 μm). Synthetic nanocrystalline samples of maghemite, goethite, lepidocrocite, akaganéite, and ferrihydrite were pressed into compact pellets used to determine bulk n and k values from 100-1200 cm−1 (8.33-100 μm). All values of n and k (the optical constants) were determined from specular reflectance spectra acquired at 2 cm−1 spectral sampling using classical Lorentz-Lorenz dispersion theory. In this paper, we present the optical constants of all six minerals and the oscillator parameters with which they were modeled. Use of these optical constants could aid in radiative transfer models of terrestrial dust as well as Mars, the Moon, and airless bodies in the Solar System.  相似文献   

4.
Ted L. Roush 《Icarus》2005,179(1):259-264
Optical constants are estimated from near-infrared reflectance spectra of the smectite clay montmorillonite using an iterative combination of particulate scattering theory and Kramers-Kronig analysis. The final results provide wavelength dependent imaginary indices of refraction similar to previous studies, but in addition produce wavelength dependent real indices of refraction, unlike most previous studies. A comparison of the values derived here to those previously reported for montmorillonite shows that the maxima absorption coefficient values from the two studies are in excellent agreement, and in other wavelength regions the two studies agree to within about a factor of two. This suggests that the approach presented can provide a reliable mechanism of estimating the wavelength dependence of both the real and imaginary indices for materials at visible and near-infrared wavelengths. The resulting near-infrared values are combined with mid-infrared values of the same sample to provide optical constants of montmorillonite over the 0.66-25 μm wavelength region.  相似文献   

5.
Temperature-influenced dynamics of small dust particles   总被引：1，自引：0，他引：1  
The motion of spherical dust particles under the action of gravity, electromagnetic radiation force and Lorentz force (LF) is studied theoretically for materials with temperature-dependent dielectric functions in the visible (VIS) spectral range. Even a weak variation of the optical constants with heliocentric distance may influence predominately a long-term dynamical behaviour of submicron-sized and small micron-sized dust grains. It is shown that the lifetime of carbonaceous or Si particles may change by several tens of per cent because of the temperature dependence of particle refractive indices. The orbital inclination is the most evident difference between the evolution of a dust particle with temperature-dependent optical properties and one without. While carbonaceous 2-μm-sized particles with optical constants independent of temperature may evolve in orbits with inclinations greater than an initial value, grains of the same size with variable refractive indices will be spread along orbits characterized with inclinations lower than the initial one. Here the temperature works as a separation factor for particles having slightly different temperature dependences of the optical constants.  相似文献   

6.
Abstract— Mössbauer studies of the samples from the Cretaceous‐Tertiary (K‐T) boundary layer at Gubbio, Italy show that iron appears mainly in two phases, magnetically ordered hematite and a paramagnetic silicate phase. The average particle size of hematite is estimated to be in the range of 16 to 27 nm from transmission electron micrographs and lack of a Morin transition. The hyperfine magnetic field at the iron nucleus is observed to be somewhat less than that of bulk hematite, which may be explained by collective magnetic excitation. Stepwise heating up to 1000°C shows a decomposition pattern of the paramagnetic phase, which suggests it to be a tri‐octahedral layer silicate. The iron‐bearing phases found in the bulk sedimentary K‐T boundary material are different from those found in the spherules separated from this material indicating that the redox conditions changed rapidly after the impact, becoming more oxidizing during the period these bulk phases were formed.  相似文献   

7.
Experiments to entrain dust with electrostatic and fluid-dynamic forces result in particulate clouds of aggregates rather than individual dust grains. This is explained within the framework of Griffith-flaw theory regarding the comminution/breakage of weak solids. Physical and electrical inhomogeneities in powders are equivalent to microcracks in solids insofar as they facilitate failure at stress risers. Electrical charging of powders induces bulk sample stresses similar to mechanical stresses experienced by strong solids, depending on the nature of the charging. A powder mass therefore “breaks” into clumps rather than separating into individual dust particles. This contrasts with the expectation that electrical forces on the Moon will eject a submicron population of dust from the regolith into the exosphere. A lunar regolith will contain physical and electrostatic inhomogeneities similar to those in most charged powders.  相似文献   

8.
Abstract— The origin of hematite detected in Martian surface materials is commonly attributed to weathering processes or aqueous precipitation. Here, we present a new hematite formation mechanism that requires neither water nor weathering. Glass‐rich basalts with Martian meteorite‐like chemistry (high FeO, low Al2O3) oxidized at high (700 and 900 °C) temperatures in air and CO2, respectively, form thin (<1 μm) hematite coatings on their outermost surfaces. Hematite is manifested macroscopically by development of magnetism and a gray, metallic sheen on the glass surface and microscopically by Fe enrichment at the glass surface observed in element maps. Visible and near‐infrared, thermal infrared, and Raman spectroscopy confirm that the Fe enrichment at the oxidized glass surfaces corresponds to hematite mineralization. Hematite formation on basaltic glass is enabled by a mechanism that induces migration of Fe2+ to the surface of an oxidizing glass and subsequent oxidation to form hematite. A natural example of the hematite formation mechanism is provided by a Hawaiian basalt hosting a gray, metallic sheen that corresponds to a thin hematite coating. Hematite coating development on the Hawaiian basalt demonstrates that Martian meteorite‐like FeO contents are not required for hematite coating formation on basalt glass and that such coatings form during initial extrusion of the glassy basalt flows. If gray hematite originating as coatings on glassy basalt flows is an important source of Martian hematite, which is feasible given the predominance of igneous features on Mars, then the requirement of water as an agent of hematite formation is eliminated.  相似文献   

9.
We apply the ballistic particle-cluster and cluster-cluster aggregation of spherical monomers identical in size and material composition to study the effect of the particle's shape and structure on the radiation pressure force acting on circumstellar dust particles. Furthermore, the influence of the material composition on the radiation pressure is investigated based on the assumption that the constituents of dust aggregates are composed of either silicate or carbon.We show that the ratio of radiation pressure to stellar gravity in the radial direction from a star is weaker for aggregates than for homogeneous spherical grains in the radius range of submicron or less. Therefore fluffy dust particles of submicron radius have a longer dynamical lifetime, compared to compact spherical particles. We also show that the nonradial component of the radiation pressure force can reach the same order of magnitude as the radial component of the radiation pressure reduced by stellar gravity for aggregates of submicron or less in size. This non-radial component of the radiation pressure may yield a component of random motion along the trajectories of the particles.  相似文献   

10.
We describe an algorithm that measures self-consistently the relative galaxy contribution in a sample of radio quasars from their optical spectra alone. This is based on a spectral fitting method which uses the size of the characteristic 4000 Å feature of elliptical galaxy spectral energy distributions. We apply this method to the Parkes half-Jansky flat-spectrum sample of Drinkwater et al. to determine whether emission from the host galaxy can significantly contribute to the very red optical to near-infrared colours observed. We find that at around 2σ confidence, most of the reddening in unresolved (mostly quasar-like) sources is unlikely to be the result of contamination by a red stellar component.  相似文献   

11.
Paul G. Lucey  Miriam A. Riner 《Icarus》2011,212(2):451-1125
Submicroscopic iron particles larger than about 50 nm, infused throughout mineral grains or glasses, are abundant in planetary materials altered by their environment such as shocked meteorites and lunar agglutinate glasses. Such particles darken their host material but do not redden their spectra but to date there has been no theoretical treatment of their optical effects. Using Mie theory, we modify the Hapke (2001) radiative transfer model of the effects of space weathering to include these effects. Comparison with laboratory measurements shows that the new treatment reproduces the relationship between submicroscopic iron size, abundance and reflectance. We apply this new model to near-IR spectra of Mercury recently obtained by the MESSENGER spacecraft and find that submicroscopic iron is much more abundant on Mercury than in lunar soils, with typical total submicroscopic iron abundances near 3.5 wt.% compared to about 0.5 wt.% for lunar soils We also find that the ratio of iron particles that darken but do not redden to the abundance of very small iron particles that impart the red slope to space weathered material is much larger than lunar (6 vs. 2). Both the total submicroscopic iron abundance and ratio of particle size fractions are consistent with the higher production of melt and vapor in micrometeorite impact on Mercury relative to the Moon (Cintala, 1992) that enables more accumulation of space weathering products before sequestration by regolith overturn. The radiative transfer model cannot directly constrain the abundance of opaque minerals on Mercury because of ambiguities between the darkening effects of opaques and submicroscopic iron particles larger than 50 nm, but assuming the opaques are the ultimate source of the submicroscopic iron, our results place a lower limit of 4-20 wt.% on opaque abundance on Mercury depending on the composition of the opaque phase and whether titanium metal also contributes to the space weathering effect.  相似文献   

12.
Abstract— We examined decomposition products of lepidocrocite, which were produced by heating the phase in air at temperatures up to 525 °C for 3 and 300 h, by x-ray diffraction (XRD), transmission electron microscopy (TEM), magnetic methods, and reflectance spectroscopy (visible and near-infrared (IR)). Single-crystal lepidocrocite particles dehydroxylated to polycrystalline particles of disordered maghemite that subsequently transformed to polycrystalline particles of hematite. Essentially pure maghemite was obtained at 265 and 223 °C for the 3 and 300 h heating experiments, respectively. Its saturation magnetization (Js) and mass specific susceptibility are ～50 Am2/kg and ～400 × 10?6 m3/kg, respectively. Because hematite is spectrally dominant, spectrally hematitic samples (i.e., a minimum near 860 nm and a maximum near 750 nm) also could be strongly magnetic (Js up to ～30 Am2/kg) from the masked maghemite component. Analyses by TEM showed that individual particles are polycrystalline with respect to both maghemite and hematite. The spectrally hematitic and magnetic Mh + Hm particles can satisfy the spectral and magnetic constraints for Martian surface materials over a wide range of values of Mh/(Mh + Hm) either as pure oxide powders or (within limits) as components of multiphase particles. These experiments are consistent with lepidocrocite as the precursor of Mh + Hm assemblages on Mars, but other phases (e.g., magnetite) that decompose to Mh and Hm are also possible precursors. Simulations done with a copy of the Mars Pathfinder magnet array showed that spectrally hematitic Mh + Hm powders having Js equal to 20.6 Am2/kg adhered to all five magnets.  相似文献   

13.
Abstract— The capability of modern methods to characterize ultra‐small samples is well established from analysis of interplanetary dust particles (IDPs), interstellar grains recovered from meteorites, and other materials requiring ultra‐sensitive analytical capabilities. Powerful analytical techniques are available that require, under favorable circumstances, single particles of only a few nanograms for entire suites of fairly comprehensive characterizations. A returned sample of > 1000 particles with total mass of just 1 μg permits comprehensive quantitative geochemical measurements that are impractical to carry out in situ by flight instruments. The main goal of this paper is to describe the state‐of‐the‐art in microanalysis of astromaterials. Given that we can analyze fantastically small quantities of asteroids and comets, etc., we have to ask ourselves, how representative are microscopic samples of bodies that measure a few to many kilometers across? With the Galileo flybys of Gaspra and Ida, it is now recognized that even very small airless bodies have indeed developed a particulate regolith. Acquiring a sample of the bulk regolith, a simple sampling strategy, provides two critical pieces of information about the body. Regolith samples are excellent bulk samples because they normally contain all the key components of the local environment, albeit in particulate form. Furthermore, because this fine fraction dominates remote measurements, regolith samples also provide information about surface alteration processes and are a key link to remote sensing of other bodies. Studies indicate that a statistically significant number of nanogram‐sized particles should be able to characterize the regolith of a primitive asteroid, although the presence of larger components (e.g., chondrules, calcium‐aluminum‐rich inclusions, large crystal fragments, etc.) within even primitive meteorites (e.g., Murchison) points out the limitations of using data obtained from nanogram‐sized samples to characterize entire primitive asteroids. However, the most important asteroidal geological processes have left their mark on the matrix, because this is the finest‐grained portion and therefore most sensitive to chemical and physical changes. Thus, the following information can be learned from this fine grain size fraction alone: (1) mineral paragenesis; (2) regolith processes; (3) bulk composition; (4) conditions of thermal and aqueous alteration (if any); (5) relationships to planets, comets, meteorites (via isotopic analyses, including O); (6) abundance of water and hydrated material; (7) abundance of organics; (8) history of volatile mobility; (9) presence and origin of presolar and/or interstellar material. Most of this information can be obtained even from dust samples from bodies for which nanogram‐sized samples are not truly representative. Future advances in sensitivity and accuracy of laboratory analytical techniques can be expected to enhance the science value of nano‐ to microgram‐sized samples even further. This highlights a key advantage of sample returns—that the most advanced analysis techniques can always be applied in the laboratory and that well‐preserved samples are available for future investigations.  相似文献   

14.
To compare the spectra of main-belt S-type asteroids and ordinary chondrites, we investigated the correlation between the reflectance peak position near 750 nm, the bend of the spectral curves in the 359–701 nm region, the linear gradient in the 359–853 nm range, and the absorption band position near 950 nm. In the diagrams of spectral parameters, the regions occupied by S-type asteroids and ordinary chondrites are separated. The modeling of the optical effect of maturation of ordinary-chondrite samples, which leads to variations in the meteorite spectral parameters, was carried out under the following conditions: (1) the increase of the concentration of reduced-iron grains (SMFe) in particles without any change in their size; (2) the increase/decrease of the size of particles at a constant concentration of SMFe in them; (3) we also examined different relations between the concentration and the size of SMFe in particles. But, under no conditions did we manage to bring into coincidence the asteroid and meteorite regions simultaneously in all spectral-parameter diagrams. Hence, the conclusion was made that the difference between the reflectance spectra of ordinary chondrites and those of large main-belt S-type asteroids is determined not only by space weathering of asteroidal surfaces but also by systematic differences in the material composition.  相似文献   

15.
Measurements of spectral emittance at wavelengths from 5 to 25 m were carried out for various particulate rocks and minerals (granite, calcite, talk) in dependence on particle size. The experimentally found variation of spectral features with particle size is discussed in terms of photon's mean free path and its dependence on particle size in the wavelength regions characterized by normal and anomalous dispersion, respectively. Moreover, a sample consisting of fine- and coarse-grained material was investigated in order to estimate the chance for mineral identification at conditions relevant to remote sensing of planetary objects. The mixture spectrum comprises characteristic features of both grain size fractions. This implies that the mineralogical composition of the fine-grained fraction also should be accessible by use of high-sensitive spectrometers.  相似文献   

16.
Visible-near infrared reflectance spectra for five particle size fractions of a Hawaiian palagonite (HWMK101) and a nontronite (ferruginous smectite, Clay Minerals Society source clay SWa-1) were measured under ambient, purged, and heated conditions to characterize the effects of surface and volume scattering on the relationship between absolute H2O content and the strength of the 3 μm absorption feature. Both materials were ground and dry sieved to particle sizes of <25, 25-45, 45-75, 75-125, and 125-250 μm. Particles of the bulk palagonite have an approximate bimodal distribution consisting of small, amorphous particles <5 μm in diameter mixed with crystalline and glass particles <1 mm in diameter, whereas the nontronite particles are polycrystalline aggregates. We find that band parameters value relating the strength of the 3 μm hydration feature to water content increase with particle size for a given water content, regardless of whether reflectance or single scattering albedo spectra are used. Spectra generally increase in reflectance as particle size decreases, a result of the relative increase in volume to surface scattering. Spectra of large particles are commonly saturated in the 3 μm region due to an increase in optical path length, making an accurate estimate of water content indeterminate until the samples dehydrate to the volume-scattering regime. We find that the presence of fines in several of the size fractions of palagonite cause their spectra to be representative of the finest fraction rather than the mean particle size. The nontronite spectra appear to be representative of an effective particle size within the range of the sieved size fractions. Many planetary surfaces are expected to have a large number of small particles which can dominate their spectral signature. Our results for particles <45 μm provide a reasonable model for estimating the H2O content of hydrated asteroids and regions of Mars.  相似文献   

17.
Oxygen isotope and chemical measurements were carried out on 25 samples of Libyan Desert Glass (LDG), 21 samples of sandstone, and 3 of sand from the same area. The δ18O of LDG samples range from 9.0‰ to 11.9‰ (Vienna Standard Mean Ocean Water [VSMOW]); some correlations between isotope data and typological features of the LDG samples are pointed out. The initial δ18O of a bulk parent material may be slightly increased by fusion due to the loss of isotopically light pore water with no isotope exchange with oxygen containing minerals. Accordingly, the δ18O of the bulk parent material of LDG may have been about 9.0 ± 1‰ (VSMOW). The measured bulk sandstone and sand samples have δ18O values ranging from 12.6‰ to 19.5‰ and are consequently ruled out as parent materials, matching the results of previous studies. However, separated quartz fractions have δ18O values compatible with the LDG values suggesting that the modern surface sand inherited quartz from the target material. This hypothesis fits previous findings of lechatelierite and baddeleyite in these materials. As the age of the parent material reported in previous studies is Pan‐African, we measured the δ18O values of bulk rock and quartz from intrusives of Pan‐African age and the results obtained were compatible with the LDG values. The main element abundances (Fe, Mg, Ca, K, Na) in our LDG samples conform to previous estimates; Fe, Mg, and K tend to be higher in heterogeneous samples with dark layers. The hypothesis of a low‐altitude airburst involving silica‐rich surface materials deriving from weathered intrusives of Pan‐African age, partially melted and blown over a huge surface by supersonic winds matches the results obtained.  相似文献   

18.
We report the room temperature infrared reflectance spectra of several lunar surface rocks in the form of polished slices or butt ends. The spectra were obtained over the frequency range 20-2000 cm–1 throughout the mid and far infrared (5-500µ) region of the electromagnetic spectrum where the fundamental internal and lattice vibrational modes of all minerals and rocks occur.Some fines samples were examined as pressed pellets and their reflectivities compared with the bulk samples. Several terrestrial minerals and rocks were also investigated. Kramers-Kronig analyses of these reflectance spectra were undertaken and the dispersion of the dielectric response ( and ) and the optical constants (n andk) have been determined over this frequency range. The low frequency and high frequency (infrared) dielectric constants were also calculated from the reflectance data.Raman light scattering measurements were made on all the samples supplied from the first three Apollo missions. Large background scattering proved to be the greatest experimental problem. Successful spectra in nearly all cases were obtained from small crystalline inclusions imbedded in the main ground mass. Some crystalline bulk rocks containing many very fine inclusions gave identifiable spectra and at least three different types were obtained.Supported by NASA Grant NGR 22-011-069 and by a Northeastern University Grant for Basic Research.  相似文献   

19.
The Chemical Analyser subsystem of the Cosmic Dust Analyser (CDA) aboard the Cassini spacecraft performs in situ measurements of the chemical composition of dust in space. The instrument records time-of-flight mass spectra of cations, extracted from the impact cloud that is created by high-velocity particle impacts onto the detector target. Thus, the spectra not only show signals of particle components but also of ions from the target material and target contamination. The aim of this work is to determine which non-particle ions are to be expected in the spectra obtained in space operation at Saturn.We present an analysis of the contamination state of the instrument's impact target. Beside investigations of the purity of the rhodium target surface, spectra from CDA calibration experiments at the dust accelerator facility are evaluated with regard to contamination signatures. Furthermore, contamination mass lines in spectra obtained by impacts of Jovian and Saturnian dust stream particles are analysed. Due to their small size and high speed, stream particle impacts predominantly produce ions from the target material and therefore the spectra are excellent probes of the contamination state of the target operating in space. With the exception of adsorbed hydrogen and carbon, the level of contamination is very low.Implications for CDA spectra of Saturnian E ring particle impacts are derived. The findings confirm the published interpretations. The low level of alkali metal contamination implies a significant sodium contribution in the composition of E ring ice particles. Additionally, ionisation thresholds for the occurrence of contamination mass lines can be utilised to set limits for the impact velocity.  相似文献   

20.
Reflectance spectroscopy in the infrared is a powerful tool to characterise the optical properties of analogue materials for Mars. In this work we present laboratory studies of four Martian analogues: calcite, montmordlonite, palagonite and andesite. Diffuse and specular reflectance and transmittance spectra in the IR are shown. The spectral effect produced by small grains clung to the larger ones is analysed for calcite. Significant variations in the diffuse reflectance spectrum, especially in the reststrahlen region, are observed. The diffuse reflectance spectra of the other materials show the shift of the reststrahlen features with Si content in the materials. Optical constants of andesite are retrieved, by using the Lorentz model, from the specular reflectance spectrum. These values are fundamental in performing modelling of the radiance coming from the planet Mars.  相似文献   

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