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1.
In the coastal catchments of Shandong Province the water scarcity is aggravated due to saltwater intrusion, reducing the usability of water resources available. Such a situation calls for sustainable integrated water resources management (IWRM). The idea for the objectives and implementation of the IWRM are explained in this paper. The general objective of the planned project disscussed in the present study is to bring together German traditional expertise in water resources management and newer developments in the context of the European Water Framework Directive; the research efforts aim to relieve the desperate water scarcity situation in the costal area of Shandong Province.  相似文献   

2.
Zong  Tong  Han  Xiqiu  Liu  Jiqiang  Wang  Yejian  Qiu  Zhongyan  Yu  Xing 《中国海洋湖沼学报》2020,38(1):75-92
Fractional crystallization of basaltic magma at variable depths in?uences strongly the geochemical compositions of mid-ocean ridge basalts(MORBs), especially at slow-spreading mid-ocean ridges. The Carlsberg Ridge is a typical slow-spreading ridge located in the northwestern Indian Ocean. In this study, we conducted petrological, geochemical and modelling studies of MORBs collected along the Carlsberg Ridge from 57°–65°E to understand the fractional crystallization processes of magma and the controls on variations in MORB geochemistry. Our results show that the mantle sources beneath the Carlsberg Ridge are heterogeneous even on the local scale of a segment; such heterogeneity may be ubiquitous beneath the Carlsberg Ridge. Mantle heterogeneity may be caused by the enriched components resulting in the "DUPAL" anomaly, whereas the ef fect of pyroxenite on mantle heterogeneity is negligible. The parental melts experienced crystallization of olivine, plagioclase and clinopyroxene prior to eruption, which played a signi?cant role in the major and trace element variations in MORBs from the Carlsberg Ridge. The liquid lines of descent(LLDs), deduced from the forward modelling of three parental magma compositions using the Petrolog3 program at pressures between 1 atm and 10 kbar, demonstrate that clinopyroxene joined the olivine and plagioclase cotectic. The over-enrichment in highly incompatible elements relative to LLDs may be caused by the processes of replenishment-tapping-crystallization in magma chambers. The calculated crystallization pressures suggest that parental magmas beneath the Carlsberg Ridge experienced moderateto high-pressure crystallization and that crystallization beneath the slow-spreading Carlsberg Ridge may start at upper mantle depths.  相似文献   

3.
The environmental problems in the Bohai Sea have become more serious in the last decade. High nutrient concentration contributes much to it. A Sino-German cooperation program has been carried out to improve the understanding of the ecosystem by observations and modelling. A three-dimensional ecosystem model, coupled with a physical transport model, is adopted in this study. The simulation for the year 1982 is validated by the data collected in 1982/1983. The simulated annual mean nutrient concentrations are in good agreement with observations. The nutrient concentrations in the Bohai Sea, which are crucial to the algal growth, are high in winter and low in summer. There are depletion from spring to summer and eleva-tion from autumn to winter for nutrients. The nutrients‘ deple tion is a response to the consumption of the phytoplankton bloom in spring. Internal recycle and external compensation affect the nutrient cycle. Their contributions to the nutrient budgets are discussed based on the simulated results. Production and respiration are the most important sink and source of nutrients. The process of photosynthesis consumes 152 kilotons-P and 831.1 kilotons-N while respiration releases 94.5 kilotons-P and 516.6 kilotons-N in the same period. The remineralization of the detritus pool is an important source of nutrient regeneration. It can compensate 23 percent of the nutrient consumed by the production process. The inputs of phosphates and nitrogen from rivers are 0.55 and 52.7 kilotons respectively. The net nutrient budget is 3.05 kilotons-P and 31.6 kilotons-N.  相似文献   

4.
Correlations between estrogenic activity and DOC/UV260 ratio in wastewater treatment processes were investigated to propose a simple, reliable and comprehensive indicator for the presence of estrogenic substances. Contrary to this, when short-term bioassays such as the E-SCREEN, receptor binding and reporter gene expression assays are used for detecting estrogenic activity in the wastewater sample, they require a long time, at least a few days. The major factors contributing to the estrogenic activity were found to be 17β-estradiol (E2) and estrone (El). A good relationship between the DOC/ UV260 ratio and the concentration of estrogens (El and E2) in the effluent of the activated sludge process was found: the E2 concentration increased as the DOC/UV260 ratio increased while the E1 concentration decreased. The relative estrogenic activity and DOC/UV260 ratio showed a good correlation (R^2 = 0.84) for all sewage samples except the ozonized samples in the sewage treatment plants. This study shows that the estrogenic compounds are hard to be mineralized by the conventional biological processes. Advanced oxidation processes are required to further remove estrogenic substances in the secondary effluent. By analysis of DOC and UV260, the estrogenic activity in the wastewater can be rapidly estimated.  相似文献   

5.
A new kinetic spectrophotometric method has been developed for the determination of iron (Ⅲ). The method is based on the catalytic effect of iron (Ⅲ) on the oxidation of weak acid brilliant blue dye (RAWL) by KIO4 in acid medium. The advantages of the proposed method are that it is sensitive, accurate, rapid, inexpensive, can be operated under room temperature and has a large determination concentration range compared to other techniques. The obtained optimum conditions are pH 3.15, RAWL (200 mgL-1) 5.00mL, Potassium periodate solution (0.01 molL-1) 0.30mL, phenanthroline (0.02molL-1) 1.00mL, reaction temperature 25℃ and reaction time 7 miu. With this method iron could quantitively be determined in the range 0.00-0.02 mgL-1, the detection limit being 4.10×10-10mL-1. The relative standard deviations (RSD) in five replicate determinations for 3 μgL-1 and 5μgL-1 iron (Ⅲ) are 3.1% and 1.9%, respectively. The method has been applied to the determination of iron (Ⅲ) in tap water samples and seawater samples (from the South China Sea), the recovery rates being 98.0% and 100.5%, respectively.  相似文献   

6.
The α7 nicotinic acetylcholine receptors(nAChRs) are widely expressed in the central and peripheral nervous systems and are important drug targets for the treatment of neurological diseases. However, differentiation of the agonists and antagonists of the nAChR is difficult. In this study we aimed to develop a reliable and efficient computational approach for differentiation of the agonists from the antagonists of the nAChR based on a systematical analysis of 123 ligands(87 agonists, 12 partial agonists, and 24 antagonists) binding with the extracellular domain of the α7 n AChR chimera. Our results suggest that the ligand size and ligand binding affinity cannot differentiate the agonists from the antagonists of the nAChR. The ligand efficiency that considers both ligand binding affinity and size for the agonists is overall more left shifted in comparison to the antagonists, but the values of the ligand efficiency still cannot differentiate the agonists from the antagonists unless the values are either relatively high(more than-0.3 kcal mol-1) or relatively low(less than-0.45 kcal mol-1). Our results suggest that accurate prediction of the agonist or antagonist of the nAChR is challenging and the ligand innate configuration has to be considered as an extra for differentiation of the agonists from the antagonists of the nAChR.  相似文献   

7.
8.
Hydrothermal barite is a typical low-temperature mineral formed during the mixing of hydrothermal fluid and seawater. Because of its extremely low solubility, barite behaves as a close system after crystallization and preserves the geochemical fingerprint of hydrothermal fluid. In this study, the elemental contents and Sr isotope compositions of hydrothermal barites from the Yonaguni IV were determined using electron microprobe and LA-MC-ICP-MS respectively. On these bases, the fluid/sediment interaction during the hydrothermal circulation and physicochemical condition of barite crystallization were discussed. Results show that the 87 Sr/86 Sr values of hydrothermal barites from the Yonaguni IV are apparently higher than those of the seawater and associated volcanic rocks, indicating the sufficient interaction between the hydrothermal fluid and overlying sediment. Monomineral Sr abundance shows large variations, reflecting the changes in barite growth rate during the fluid mixing. The mineralization condition in the Yonaguni IV was unstable. During the crystallization of barite, hydrothermal fluid and seawater mixed in varying degrees, with the pro-portions of hydrothermal fluid varied from 36% to 72%. The calculated crystallization temperatures range from 109 to 220℃. Sediment plays a critical role during the mineralization process in the Yonaguni IV and incorporation of sediment component into hydrothermal system was prior to barite crystallization and sulfide mineralization.  相似文献   

9.
A multiple time scale perturbation method is used to discuss the Lagrangian residual current and residual transport on the basis of a weakly nonlinear dynamic model of shallow seas. The governing equations for the long-term variation of zero order " apparent concentration " (which is a linear combination of salinity , temperature of seawater and the concentration of any tracer which is conservative and passive ) and its mean value over tidal cycles are obtained for the system with single tidal constituent . and for the one with multi-constituents, winds and thermohaline. The equations for the two cases are in the same form and show this long-term variation resulted from the cumulative effect of residual convection and turbulent diffusion .The multiple time scale variation of current is caused by tides, winds, and the thermohaline and the nonlinear effects of the system. The derived set of governing field equations of the Lagrangian current for this multiple time scale system is also in the same form as  相似文献   

10.
Based on various patterns of groundwater and their abundance characters in south Liaodong Peninsula, the distribution, stage, pattern and characters of sea water intrusion in the serious sea water intrusion areas are analysed. The reasons to cause sea water intrusion are uneven precipitation, limited recharge of surface water, artificial overpumping, lithology and geological structure. It can provide scientific basis for reasonable utilization of limited water resource in line with the local conditions.  相似文献   

11.
为了研究多金属结核的成矿机理,对中国大洋第45航次在东太平洋CC区(Clarion-Clipperton zone)所获得的20枚多金属结核进行了主量、微量及铂族元素分析测试,并与其他区域不同类型的多金属结核进行了对比。结果表明,研究区多金属结核基本为混合型结核,其PGEs总质量分数(w(ΣPGE))为77.2×10-9~197×10-9,平均值为136×10-9,明显低于库克(Cook)岛海域典型的水成型结核的值(w(ΣPGE)=306×10-9);研究区结核球粒陨石标准化PGEs配分模式与水成型结核及富钴结壳非常相似,均呈现明显的Pt正异常及从Os到Pt逐渐富集、从Pt到Pd逐渐亏损的特征,结合海水的PGEs配分特征及前人研究结果,表明结核中PGEs应该直接来源于海水;研究区多金属结核w(ΣPGE)与w(Fe2O3)表现为正相关,与w(MnO)表现为负相关,而Cook岛海域水成型结核w(ΣPGEs)则与w(MnO)表现为正相关,与w(Fe2O3)表现为负相关,表明不同成因类型的多金属结核PGEs的赋存载体有所不同,水成型结核中PGEs主要赋存在锰矿物相中,而混合-成岩型结核则主要赋存在铁矿物相中,且成岩作用越强,结核富集PGEs的能力越低。研究成果对于东太平洋多金属结核成矿机理及其赋存载体研究有一定的指示意义。   相似文献   

12.
对中国小岩体型铜镍硫化物(铂族)矿床成矿地质体的岩体规模、岩石组合及岩石地球化学特征进行了综述,并与其他类型铜镍硫化物矿床特征进行了对比,最后总结出了铜镍硫化物矿床成矿地质体的判别标志特征。结果表明:铜镍硫化物(铂族)矿床成矿地质体的出露形态不规则,多以岩脉、岩墙或岩床形式出露,出露面积较小,多小于1km2;岩石组合多以二辉橄榄岩、橄榄岩、橄榄辉石岩、辉石岩、苏长岩、辉长岩、闪长岩为主,岩相分带明显,岩体基性程度由内向外、从下向上逐渐降低,形成"外酸内基"、"上酸下基"的特征;岩石主要为铁质拉斑玄武岩系列;配分模式和蛛网图显示,橄榄石中Ni含量较低,大离子亲石元素和轻稀土元素富集,高场强元素和重稀土元素亏损,过渡族元素呈现Cr、Ni相对亏损的"W"型模式,铂族元素配分模式呈现Pt、Pd含量较高的左倾,源区为幔源但具有壳源的混染。  相似文献   

13.
岩浆硫化物矿床勘查研究的趋势与小岩体成矿系统   总被引:3,自引:0,他引:3  
通过2009年西安Ni-Cu(Pt)岩浆矿床国际学术研讨会和近10年来的勘查研究现状,可以看出岩浆硫化物矿床勘查领域的发展趋势为:与大型层状岩体有关的铂族矿床仍然受到关注;Sudbury矿床的特殊性和不可参照性取得了共识;小岩体矿床是勘查研究的主流;通道成矿作用受到重视。以大型层状岩体Bushveld为例,介绍了其中的Merensky矿层、UG-2矿层和北翼接触带的Platreef矿床。由于中国没有发现这种大型层状岩体,因此应当重视那些中小型层状岩体中可能赋存的铂族矿床。迄今为止,除了Sudbury矿床这个特殊的实例之外,国内外所有具有经济意义的Ni-Cu矿床都寄生于小岩体中并自成一个成矿系统。这个小岩体成矿系统包含成矿背景、邻近深大断裂、原始岩浆、先导性岩浆成岩作用、继发性岩浆成矿作用以及深部熔离-分期贯入-终端岩浆房聚集成矿等。近10年的勘查实践进一步说明,这类小岩体矿床仍是中国今后的主要勘查研究方向。最后,介绍了Noril sk-Talnakh和Voisey s Bay矿床的深部熔离-通道成矿机制,这种机制增添了小岩体成矿作用的多样性;但是,其现存空间是开放性岩浆通道还是封闭性终端岩浆房,还有待更多的研究和实践。  相似文献   

14.
系统研究浙江下白垩统“永康群”、“横山组”火山—沉积岩系地层层序,岩石组合,古生物,火山岩同位素年龄和岩石化学、地球化学资料表明:浙江永康群中火山岩成岩时间在距今115~100Ma之间,属早白垩世晚期。火山岩具双峰式特征。大致以江山—上虞和景宁—宁海一线为界,分成衢州—诸暨、永康—宁波、文成—临海3个火山活动带,自西向东火山活动渐次增强,火山活动起始时间稍有后移。根据火山—沉积岩系岩石组合,古生物群特征,火山岩同位素年龄及古地磁资料,提出横山组、中截组、永康群和文成群是早白垩世晚期同一构造发展阶段的产物。  相似文献   

15.
金川铜镍硫化物矿床Hf同位素地球化学特征与岩浆源区   总被引:1,自引:0,他引:1  
金川铜镍硫化物矿床是中国最大镍资源基地,形成于新元古界超镁铁质小岩体中,围岩是古元古界白家嘴子组一套角闪岩相变质岩,矿床的成矿关键因素一直受到广泛关注。详细的地质填图发现岩体与围岩为侵入接触,呈岩席状产出,西南部为岩体顶部,东北部为岩体底部。通过SHRIMP锆石U-Pb年代学及Hf同位素研究,获得矿床中锆石年龄平均为(840±10)Ma,与前人获得的年龄(831.8±0.6)Ma在误差范围内一致,代表成岩年龄的锆石εHf(t)值主要集中在-8.52~-4.85;Hf模式年龄大于锆石U-Pb年龄,表明其岩浆源区受到过地壳物质的混染或来自于富集地幔。Hf-Sr-Nd-Pb-Os同位素研究发现,形成金川铜镍硫化物矿床的岩浆源区属于Ⅰ型富集地幔(EMⅠ),成岩成矿地质背景与陆内裂谷有关,这种特殊的构造环境与地幔源区可能对形成金川超大型铜镍硫化物矿床发挥了重要贡献。  相似文献   

16.
岩浆成矿系统的尺度效应   总被引:2,自引:0,他引:2  
小岩体成大矿理论强调了岩浆侵入体的几何尺度与内生金属成矿作用的有机联系,但这种联系的实质尚理解甚少。简要分析了岩浆成矿系统的基本问题,聚焦于侵入体几何尺度与几种关键控矿因素的内在联系。利用前人提出的固相线前锋迁移距离与冷却时间之间的函数关系估算了岩浆侵入体固结的时间尺度,发现小岩体的存活时间尺度与超大型矿床的形成时间尺度一致。基于斯托克定律的估算,含有暗色微粒包体的小岩体以岩浆快速上升为特征,符合流体中成矿金属溶解度与压力(P)、温度(T)正相关的实验结果。分析了岩浆产量与源区减压速率和所产生岩浆中挥发分含量之间的关系,提出大规模岩浆活动之后岩浆产量必然逐渐减少,因而流体-熔体比值逐渐增加。据此认为,超大型矿床可形成于紧接着大规模岩浆活动之后,并以长英质岩浆成矿系统为例将其称为岩基后成矿作用。因此,岩浆成矿系统的尺度效应是一种重要的地质效应,尺度效应分析支持小岩体成大矿理论。  相似文献   

17.
广州地区地下水咸化现象由来已久,通过透射电子显微镜对广州珠江三角洲地下水的咸化原因进行了研究,并评价了其咸化程度。通过研究广州地区地下水中的微粒特征,包括观察微粒的形貌、结晶程度和化学成分等特征,同时对比现代海水微粒特征,讨论了微粒特征用于地下水咸化原因探究和评价的可行性。研究发现,在咸化程度不同的样品中,微粒中Cl含量不同,没有咸化的样品中难以找到Cl元素,咸化程度越高,微粒中Cl含量可以越高。同时,在受到海水入侵的地下水微粒中发现了具有海洋来源含Sr、Ba等微量元素的微粒,这些微量元素在一定程度上可视为海水的示踪剂,说明该组地下水受到了不同程度的海水浸染。通过透射电子显微镜分析研究了地下水中的微粒,结果表明,该研究区地下水中的微粒继承了海水中的微粒特征,广州市地下水的咸化是由于海水入侵所致,因此,利用微粒特征用于海水入侵的判别分析和评价是可行的。类似地,该方法同样可用于水污染调查以及地下水找矿研究。   相似文献   

18.
经研究证明,前人建立的二郎坪群火神庙组确有少量的亚碱性双峰式火山岩。这些火山岩零星地分布在几个地区,走向不连续,出露宽度一般为数百米。构成该组主体的是一条规模宏伟的侵入岩带,其岩石组合为辉长岩-闪长岩-石英闪长岩-斜长花岗岩-花岗岩,总体上表现为正序岩浆演化序列。这些侵入岩普遍经历了三个阶段的变形变质作用,即第一阶段为韧性变形;第二阶段为静态重结晶;第三阶段为带状褶劈理,表现了复杂而漫长的构造演化史。  相似文献   

19.
新疆包古图斑岩铜矿中性复式岩体的同化混染作用   总被引:4,自引:0,他引:4  
包古图斑岩铜矿位于新疆西准噶尔地区东南部,是一大中型斑岩铜矿床,赋存于包古图中性复式岩体中。包古图中性复式岩体是由早期闪长岩株和晚期闪长玢岩脉组成,以前者为主;该岩体侵位于下石炭统包古图组酸性火山-沉积岩中。对包古图闪长岩株及其围岩进行岩相学、岩石主量和微量元素地球化学及Sm-Nd同位素地球化学等方面进行研究。结果表明:闪长岩株由(石英)闪长岩(含少量辉长岩)、似斑状(石英)闪长岩及少量斜长花岗斑岩组成;其岩石是由偏基性的中性岩浆结晶(分异)作用及岩浆与酸性围岩同化混染作用形成的。同化混染作用的程度不同,则形成不同的岩石:①岩浆直接结晶作用形成辉长岩;②岩浆结晶(分异)作用和少量同化混染作用形成(石英)闪长岩和似斑状(石英)闪长岩;③强烈的同化混染作用形成斜长花岗斑岩,斑岩基质主要由混入岩浆的围岩细碎屑经重结晶作用形成,斑晶是晚于基质结晶的"晚生斑晶"。总之,岩浆与围岩的同化混染作用是包古图岩体的重要成岩作用。  相似文献   

20.
为了更全面地表征潜江凹陷潜江组页岩油储层孔隙结构特征,系统选取了距物源不同距离的A井和B井多块页岩样品进行了分析测试,通过场发射扫描电镜、低温氮气吸附和高压压汞实验综合分析了页岩孔隙结构特征;通过对比抽提前后场发射扫描电镜图像、低温氮气吸附和高压压汞实验数据,进一步研究了页岩中滞留烃的赋存空间特征;通过对典型页岩样品的二次压汞实验,探讨了页岩中连通孔隙的孔径分布特征。结果显示:潜江凹陷潜江组页岩油储层孔隙大小为纳米-微米级,孔径2~180 nm的黏土矿物层间孔和白云石晶间孔是该区发育最主要的两种孔隙类型;A井页岩中的滞留烃主要赋存在孔径2~20 nm的黏土矿物层间孔中,滞留烃含量较低,连通孔径主要集中在3~15 nm范围内,B井页岩中的滞留烃赋存在孔径8~100 nm的白云石晶间孔中,滞留烃含量多,连通孔径主要分布在10~130 nm范围内;白云石和黏土矿物的存在都有利于页岩储层储集空间的发育,但远离物源的生物成因的白云石更有利于滞留烃的赋存和可动性。研究成果可以为潜江凹陷页岩油的勘探和开发提供一定的理论支撑。   相似文献   

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