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1.
Changchengite occurs in chromite orebodies in dunite and in platinum placer deposits in chromite orebodies nearby. The mineral occurs as massive aggregates or veinlets on margins of iridisite (IrS2) and replaces it. Opaque. Lustre metallic. Colour steel-black. Streak black. Hm = 3.7. VHN20= 165 kg/ mm2. Isotropic. Cleavage none. Density 11.96 g/ cm3. Seven electron microprobe analyses give the following mean chemical results (wt. %): S 7.2, Cu 0.3, Te 0.4, Ir 41.2, Pt 2.8 and Bi 47.3 with total 99.1. The simplified formula is IrBiS. The strongest X-ray powder diffraction lines (hkl, d, I) are 210, 2.75 (70); 211, 2.51 (60); 311, 1.860 (100); 440. 1.090 (50) and 600, 1.027 (50). The X-ray powder diffraction pattern is similar to that of mayingite. After the diffraction data are indexed the mineral is determined to be cubic. The space group is P213 with a = 0.6164(4) nm, V = 0.2342 nm3 and Z = 4.  相似文献   

2.
Yixunite and damiaoite Were found in a cobalt- and copper-bearing platinum ore vein of a contact metasomatic deposit. The chief ore minerals are bornite, chalcopyrite, magnetite and carrollite. The platinum minerals include moncheite, sperrylite, daomanite, cobalt malanite and cooperite. Yixunite and damiaoite occur as immiscible globules, 1.0 to 2.0 mm in diameter. Yixunite is always in the central part of a globule. It is opaque with metallic lustre, bright white colour and black streak. HM = 5.8; VHN50 = 634 kg/mm2 (573-681 kg/ mm2); insoluble in HCl, HNO3, HF or H3PO4; no cleavage; no magnetism. Density is hard to measure because of small grain size. Calculated density = 18.21 g/cm3. Reflective colour is bright white with a yellowish tint. Isotropic. The mean analytical results (ranges) (%) are: Pt 82.8 (81.8-83.6), In 16.4(15.6-17.1) and total 99.2. The empirical formula (based on 4 atoms) is Pt2.993 In1.007 . The five strongest lines of X-ray diffraction (hkl, d,I) are 111, 2.30 (100); 200, 1.99 (  相似文献   

3.
Chengdeite occurs in chromite orebodies in dunite as well as in placers in their neighbourhood. The mineral occurs as granular aggregates in association with inaglyite and in some cases occurs as graphic intergrowths with native iridium. It is opaque with a metallic lustre, colour steel-black, streak black,HM = 5.2, VHN50=452 kg/mm2, cleavage not observed, fracture not observed, strongly magnetic. Its reflection colour is bright white with a yellowish tint. It has no internal reflection, bireflectance or pleochrism, and shows isotropism.Thirteen chemical analyses were carried out by means of the electron microprobe. The mean percentages of the data obtained in the 13 analyses ares S 0.001, Fe 7.9, Ni 0.03, Co 0.03, Cu 0.83, As 0.02, Rh 0.19, Pd 0.00, Os 0.06, Ir 88.5, Ft 2.2 and Pb 0.00. The simplified formula is Ir3Fe, which requires Ir 91.17 and Fe 8.83, the total being 100.00 (% ).Five strongest lines of X-ray powder diffraction (hkl, d, I)are: 111, 2.18 (80);200, 1.89 (60); 220, 1.34 (70);311, 1.142  相似文献   

4.
Voluminous platinum-group mineral(PGM) inclusions including erlichmanite(Os,Ru)S_2, laurite(Ru,Os)S_2, and irarsite(Ir,Os,Ru,Rh)As S, as well as native osmium Os(Ir) and inclusions of base metal sulphides(BMS), including millerite(NiS), heazlewoodite(Ni_3S_2), covellite(CuS) and digenite(Cu_3S_2), accompanied by native iron, have been identified in chromitites of the Zedang ophiolite, Tibet. The PGMs occur as both inclusions in magnesiochromite grains and as small interstitial granules between them; most are less than 10 μm in size and vary in shape from euhedral to anhedral. They occur either as single or composite(biphase or polyphase) grains composed solely of PGM, or PGM associated with silicate grains. Os-, Ir-, and Ru-rich PGMs are the common species and Pt-, Pd-, and Rh-rich varieties have not been identified. Sulfur fugacity and temperature appear to be the main factors that controlled the PGE mineralogy during crystallization of the host chromitite in the upper mantle. If the activity of chalcogenides(such as S, and As) is low, PGE clusters will remain suspended in the silicate melt until they can coalesce to form alloys. Under appropriate conditions of ?S_2 and ?O_2, PGE alloys might react with the melt to form sulfides-sulfarsenides. Thus, we suggest that the Os, Ir and Ru metallic clusters and alloys in the Zedang chromitites crystallized first under high temperature and low ?S_2, followed by crystallization of sulphides of the laurite-erlichmanite, solid-solution series as the magma cooled and ?S_2 increased. The abundance of primary BMS in the chromitites suggests that ?S_2 reached relatively high values during the final stages of magnesiochromite crystallization. The diversity of the PGE minerals, in combination with differences in the petrological characteristics of the magnesiochromites, suggest different degrees of partial melting, perhaps at different depths in the mantle. The estimated parental magma composition suggests formation in a suprasubduction zone environment, perhaps in a forearc.  相似文献   

5.
弓长岭富磁铁矿床成因的地球化学模型   总被引：4，自引：0，他引：4  
李曙光 《地球化学》1982,(2):113-121
Based upon geological and geochemical data on the genesis of Gongchangling rich magnetite deposit, it is suggested that the deposit is of multigenesis, and a three-stage geochemical model for the genesis of the deposit is proposed : (1) Depositional stage : the deposition of banded low-grade ores (magnetite-quartzite) was accompanied by high-grade magnetite (hematite)-siderite ores which are intercalated with magnetite-quartzites as lenses or stratoid shoots. (2) Metaamorphic stage: In response to metamorphism, siderite was decomposed into magnetite and graphite with decreasing fo2 and increasing PCO2. On the margin of magnetitc-siderite ores or within the thin intercalated layers where fO2, was high relative to PCO2 were formed graphite-free rich magnetite ores. (3) Hydrothermal stage: As a result of later hydrothermal process diffusive metasomatism between the shoots and host rocks anti silica leaching took place, thus giving rise to the rich magnetite ores of metasomatic type, and altered rocks.  相似文献   

6.
SEDEX-type lead-zinc deposits in the southern belt of the Xicheng Devonian basin, Gansu Province has been already identified. However, the sedimentary environment of the limestone and philite of the Xihanshui Group within which the lead-zinc deposits occur is littoral and shallow sea. This is different from those in the northern belt such as the Changba-Lijiagou lead-zinc deposits, which were formed in deep sea. The reef and bioclastic limestone are widespread in the southern belt. Particularly they are associated with lead-zinc ores and there are no striae and banding but massive or disseminated structures. It is discovered that the black chimney consists of sphalerite, ankerite, pyrite and galena, in which black, coarse and radial sphalerite occurs as irregularly veins or cylindricality with a width of 10-40 cm in the center, and it is surround by fine ankerite and minor celestite with ribbon structure. The immediate wall rock of the chimney, reef limestone, was unaltered and the outside reef and bioclastic limestone were intensively silicified. Those silicified reef and bioclastic limestone host disseminated lead-zinc ores of the Luoba and Bijiashan type. It is concluded that the exhalative system occurred in a shallow sea in the Givetian of the middle Devonian. Brine is boiled due to low pressure, and a great deal of lead and zinc was dispersed in the interface between the limestone and phyllite and formed a source bed. In the Triassic period, meta-hydrothermal fluids leached and extracted metals from the source bed, and then moved and mineralized in open space such as arches and inverse limbs of anticlines, and formed massive and vein ores such as the Jianyagou and Dengjiashan type deposits.  相似文献   

7.
Four types of apatite have been identified in the Ningwu region.The first type of apatite is widely distributed in the middle dark colored zones(i.e.iron ores) of individual deposits.The assemblage includes magnetite,apatite and actinolite(or diopside).The second type occurs within magnetite-apatite veins in the iron ores.The third type is seen in magnetite-apatite veins and (or) nodules in host rocks(i.e.gabbro-diorite porphyry or gabbro-diorite or pyroxene diorite).The fourth type occurs within apatite-pyrite-quartz veins filling fractures in the Xiangshan Group.Rare earth elements (REE) geochemistry of apatite of the four occurrences in porphyry iron deposits is presented.The REE distribution patterns of apatite are generally similar to those of apatites in the Kiruna-type iron ores,nelsonites.They are enriched in light REE,with pronounced negative Eu anomalies.The similarity of REE distribution patterns in apatites from various deposits in different locations in the world indicates a common process of formation for various ore types,e.g. immiscibility.Early magmatic apatites contain 3031.48-12080×10~(-6) REE.Later hydrothermal apatite contains 1958×10~(-6) REE,indicating that the later hydrothermal ore-forming solution contains lower REE.Although gabbro-diorite porphyry and apatite show similar REE patterns,gabbro-diorite porphyries have no europium anomalies or feeble positive or feeble negative europium anomalies, caused both by reduction environment of mantle source region and by fractionation and crystallization(immiscibility) under a high oxygen fugacity condition.Negative Eu anomalies of apatites were formed possibly due to acquisition of Eu~(2+) by earlier diopsite during ore magma cooling. The apatites in the Aoshan and Taishan iron deposits yield a narrow variation range of ~(87)Sr/~(86)Sr values from 0.7071 to 0.7073,similar to those of the volcanic and subvolcanic rocks,indicating that apatites were formed by liquid immiscibility and differentiation of intermediate and basic magmas.  相似文献   

8.
长江中下游地区内生铁铜矿床与膏盐的关系   总被引：12，自引：0，他引：12  
蔡本俊 《地球化学》1980,(2):193-199
A middle-Trlassic sequence of strata composed .of gypsumstlt beds has been reeognized in the middle-lower Yangtze Valley. The mineralization in the gypsum-salt beds is closely related to Yenshanian magmatism, During the Yenshanian, magmatic intrusion activities were very active across evaporite beds, occupying great space in gypsum-salt beds. The magmatie rocks and the alterated country rocks are characterized by alkali-eurichment and halogen-enrichment. Copper and iron ores mainly occur in the evaporite beds or overlying levels. The genesis of endogenic copper and iron ores is commonly considered to be the consequence of interaction of magma with the gypsumsalt beds, i.e. there exists a close genetic connection between evaporites, magmatism and copper-iron ores. These observed features are of great significance both in practice and theory.  相似文献   

9.
The Kengdenongshe deposit is a newly discovered large Au-Ag-Pb-Zn polymetallic deposit in the eastern Kunlun metallogenic belt, and the genetic relationship between Pb-Zn-rich ore bodies and Au-rich ore bodies in this deposit is controversial. Therefore, comparative studies of mineralization, alteration, and fluid inclusions in the two types of ore bodies were carried out with the statistical analysis of the correlation among ore-forming elements of Au, Ag, Pb and Zn. The results show that, from north to south, the mineralization changes gradually from Pb-Zn-rich to Au-rich with the wall-rock alteration from silicification-epidotization to baritization-marbleization-silicification. In addition, the structures of Pb-Zn-rich ores indicate a hydrothermal sedimentary origin with the late hydrothermal superposition, while those of Au-rich ores show features of hydrothermal origin. Besides, based on the study of fluid inclusions in this mining area, the ore-forming fluid of Pb-Zn-rich ores is low temperature (focus on 150-170°C) and low-medium salinity (1.74%-10.24% NaCleqv), while that of Au-rich ores displays low-medium temperature (manily 130-250°C) with low-medium salinity (0.35%-10.24% NaCleqv). Pb-Zn and Au-Ag show positive correlation (correlation coefficient r>0.25), but Au is poorly correlated with Pb and Zn (correlation coefficient r<0.15). However, to due to the late stage hydrothermal superimposition, Au is rather well correlated with Pb in high grade ores. In summary, there may exist two epochs of mineralization in the Kengdenongshe polymetallic deposit. The early one is Pb-Zn mineralization stage with characteristics of hydrothermal sedimentary origin, and the ore-forming fluid may be derived from the mixture of magmatic water and seawater. While the later one is Au mineralization stage, having characteristics of hydrothermal origin with subsequent hydrothermal superimpositions, and the ore-forming fluid is mainly derived from magmatic water that mixed with meteoric water. © 2018, Science Press. All right reserved.  相似文献   

10.
The Chagele is a typical Pb-Zn-Cu-Mo deposit located in the western Nyainqentanglha Pb-Zn-Ag-Fe-Cu metallogenic belt (NPMB) that immediately north of the Gangdese porphyry copper belt, Tibet. The deposit contains three ore types: the porphyry (Cu) Mo ores occur as thin veins hosted in the granite porphyry; the skarn (Cu) Pb-Zn type ores are of vein-type or lenticular-type mainly occurring in the external contact zone and interstratified crack zone; and the hydrothermal vein Pb-Zn type ores are controlled by the NNE-striking faults and situated in the structural fractured zones and the up walls of fault zones. The (Cu) Pb-Zn ores consist mainly of galena, sphalerite, chalcopyrite, pyrite, malachite, showing automorphic granular, hypautomorphic to allotriomorphic granular and metasomatic-relict textures, and exhibiting mainly veined, banded, disseminated and massive structures. Hydrothermal alteration includes skarnization, silicification and limonitization. The (Cu) Mo ores consists mainly of chalcopyrite and molybdenite, and minor pyrite. The (Cu) Mo ores are characterized by scaly texture, veinlet and massive structures. It has reserves of 0.38 Mt Pb, 0.6 Mt Zn and 110.1 t Ag, with average grade of 2.08%, 3.29% and 6.07 g/t, respectively, and is considered as a deposit with huge ore-prospecting potential in western of NPMB. However, the ore-forming material and genesis of the Chagele deposit are still not clear. This paper systematically investigated the H, O, S and Pb isotopes of the Chagele deposit and compared it with the other Pb-Zn (Cu-Mo) deposits in the middle-east segment of NPMB. Isotopic geochemical analyses showed that the fluids have δ18O values of -2.2‰ to 2.9‰ and δD values of -189‰ to -157‰, respectively, indicative of mixing between magmatic and meteoric waters. The bimodal distribution of δ34 S values for sulfides (-5.6‰ to -0.8‰, the average: -3.7‰ and 1.1‰ to 2.6‰, the average: 1.8‰) indicated that sulfur of the ores were derived from both wall rocks and magma, while the Cu-Mo orebodies was mainly derived from the granite porphyry. The sulfides have 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb values in ranges of 18.614 to 18.688, 15.657 to 15.747 and 38.988 to 39.269; similarly the granite porphyries have 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb values of 18.663 to 19.058, 15.643 to 15.664, and 39.002 to 39.559, respectively, implying that both of them were originated from the upper crust. The H-O-S-Pb isotopic characteristics of the Chagele deposit are similar to those of the Pb-Zn polymetallic deposits in the mid-east NPMB, suggesting that these deposits have similar ore-forming fluid and material sources. It can be concluded that the Chagele deposit is a typical porphyry type Mo deposit + skarn type-hydrothermal vein type of Cu-Pb-Zn deposit. Moreover, we argue that the mineralization is not only confined to the mid-east NPMB, the western segment of the belt with similar tectonic-magmatism also has high potential of ore mineralization. © 2018, Science Press. All right reserved.  相似文献   

11.
Summary We have conducted electron microprobe (EMP) analysis of 158 grains of platinum-group minerals (PGM; 0.1–1 mm in size) from 11 placer samples collected from Holocene fluvial placers and buried paleochannel placers at various localities in British Columbia. These grains principally comprise Pt-Fe-(Cu) alloy minerals: Fe-rich platinum [ΣPGE:(Fe + Cu + Ni) = 3.6–7.6], Pt3Fe-type alloy (isoferroplatinum or Fe-rich platinum), subordinate “Pt2Fe”-type alloy (probably, a compositional variant of Fe-rich platinum) and the tulameenite-tetraferroplatinum series. Less-abundant are iridium [Ir-dominant Ir-Os-(Pt) alloy] and osmium [Os-dominant Os-Ir-(Pt) alloy]. Ruthenium [Ru-dominant Ru-Ir-Os alloy] occurs as a single grain. One of these Pt-Fe alloy grains is unusually zoned; its core zone is: Pt74.0Fe20.4Cu1.9Ir1.5Rh1.1Pd1.0Os0.08Ru0.01Ni0.01 (in at%) [ΣPGE:(Fe + Cu + Ni) = 3.5], and its rim zone is: Pt78.5Fe15.5Cu1.7Ir1.5Rh1.4 Pd1.2Ni0.15Os0.06Ru<0.01 [ΣPGE:(Fe + Cu + Ni) = 4.8]. This zoning indicates late-stage removal of Fe and corresponding addition of Pt, probably as a result of interaction with a late fluid phase. Various combinations of minor elements: Ir-Rh, Rh-Pd, and Ir-Rh-Pd are observed in the analysed Pt-Fe-Cu alloys. However, the Ir-Pd pair appears to be prohibited because of crystallochemical factors. Minute PGM inclusions in Pt-Fe alloy grains, likely derived from the Tulameen complex, comprise: hongshiite (Pt1.04Pd0.02 Cu0.93), sperrylite (Pt0.93Ir0.03)Σ0.96(As2.02Sb0.01)Σ2.03, hollingworthite-platarsite (Rh0.74 Pt0.21Fe0.02Pd0.02Ir0.01)Σ1.00S0.91As1.10, cuprorhodsite-malanite (Cu0.91Fe0.03Ni<0.01)Σ0.95 (Rh1.06Pt0.89Ir<0.01)Σ1.95S4.10, a rare Te-rich isomertieite (Pd10.96Fe0.03)Σ10.99(Sb1.13 Te0.94)Σ2.07As1.93, and an unusual Pt-Pd-Rh antimonide [(Pt + Pd + Rh):(Sb + As) = 1.2–1.25], related to genkinite. This antimonide may exhibit a minor solid solution extending from genkinite toward stumpflite. In addition, 20 grains of diopside [Ca46.4–49.1Mg42.8–48.2Fe3.1–8.1; ≤0.59 wt% Cr2O3] and 20 grains of olivine [Fo86.8–91.5 Fa7.9–12.5], from a PGM-bearing placer located in the vicinity of the Tulameen complex, were analysed. The compositional ranges of these placer silicates are comparable to those of clinopyroxene and olivine in the olivine clinopyroxenite and dunite units of the Tulameen complex. The majority of the analysed placer PGM grains were probably derived from Alaskan-type source rocks, whereas an ophiolitic source, associated with the Atlin ophiolite complex, is suggested for the placer PGM deposits in the Atlin area, northern British Columbia. Authors’ addresses: Andrei Y. Barkov, Robert F. Martin, Department of Earth and Planetary Sciences, McGill University, 3450 University Street, Montreal, Quebec H3A 2A7, Canada; Michael E. Fleet, Department of Earth Sciences, University of Western Ontario, London, Ontario, N6A 5B7, Canada; Graham T. Nixon and Victor M. Levson, B.C. Geological Survey, Ministry of Energy, Mines and Petroleum Resources, PO Box 9320 Stn. Prov. Govt., Victoria, British Columbia V8W 9N3, Canada  相似文献   

12.
Lisiguangite, CuPtBiS3, is a new mineral species discovered in a PEG-bearing, Co-Cu sulfide vein in garnet pyroxenite of the Yanshan Mountains, Chengde Prefecture, Hebei Province, China. It is associated with chalcopyrite and bornite, galena, minor pyrite, carrolite, molybdenite and the platinum-group minerals daomanite (CuPtAsS2), Co-bearing malanite (Cu(Pt, Co)2S4) sperrylite, moncheite, cooperite and malyshevite (CuPdBiS3), rare damiaoite (Pt2In3) and yixunite (Pt3In). Lisiguangite occurs as idiomorphic crystals, tabular or lamellae (010) and elongated [100] or as aggregates, up to 2 mm long and 0.5 mm wide. The mineral is opaque, has lead-gray color, black streak and metallic luster. The mineral is non-fluorescent. The observed morphology displays the following forms: pinacoids {100}, {010}, {001}, and prism {110}. No twining is observed. The a:b:c ratio, calculated from unit-cell parameters, is 0.6010:1:0.3836. Cleavage: {010} perfect, {001} distinct, {100} may be visible. H Mohs: 21/2; VHN25=46.7-49.8 (mean 48.3) kg/mm2. Tenacity: brittle. Lisiguangite is bright white with a yellowish tint. In reflected light it shows neither internal reflections nor bireflectance or pleochroism. It has weak to moderate anisotropy (blue-greenish to brownish) and parallel-axial extinction. The reflectance values in air (and in oil) for R3, R4 and (imR3, imR4), at the standard Commission on Ore Mineralogy wavelengths are: 37.5, 35.7 (23.4, 22.3) at 470 nm; 38.6, 36.5 (23.6, 22.6) at 546 nm; 39.4, 37.5 (23.6, 22.7) at 589 nm and 40.3, 38.2 (23.7, 22.9) at 650 nm. The average of eight electron-microprobe analyses: Cu 12.98, Pt 30.04, Pd 2.69, Bi 37.65 and S 17.55, totaling 100.91%, corresponding to Cu1.10(Pt 0.83, Pd0.14)Σ0.97Bi0.97S2.96 based on six atoms apfu. The ideal formula is CuPtBiS3. The mineral is orthorhombic. Space group: P212121, a=7.7152(15)?,b=12.838(3)?, c=4.9248(10)?, V=487.80(17)?3, Z=4. The six strongest lines in the X-ray powder-diffraction pattern [d in ? (I) (h k l) are 6.40(30)(020), 3.24(80)(031), 3.03(100)(201), 2.27(40)(051), 2.14(50)(250), 1.865(60)(232).  相似文献   

13.
A new Cu-rich variety of lyonsite has been found from fumarolic sublimates of the Tolbachik volcano (Kamchatka, Russia). The empirical formula is Cu4.33Fe 2.37 3+ Ti0.26Al0.26Zn0.07(V5.85As0.07Mo0.07P0.01S0.01)O24. The crystal structure was studied on single crystal using synchrotron radiation, R = 0.0514. The mineral is orthorhombic, Pnma, a = 5.1736(7), b =10.8929(12), c = 18.220(2) Å, V = 1026.8(2) Å3, and Z = 2. The structural formula is (Cu0.6Ti0.3Al0.3Fe 0.2 3+ □0.6)Σ2Cu2(Fe 2.2 3+ Cu1.8)Σ4(V5.8As0.1Mo0.1)Σ6O24. It is proposed to recast the simplified formula of lyonsite as Cu3+x (Fe 4?2x 3+ Cu2x )(VO4)6, where 0 ≤ x ≤ 1.  相似文献   

14.
The coupled solubility of Au(cr) and Pt(cr) has been measured in acidic chloride solutions at 350–450°С and 0.5 and 1 kb using the autoclave technique with determination of dissolved metal contents after quenching. The constants of the reaction combining the dominant species of Au and Pt in high-temperature hydrothermal fluids (K(Au–Pt)) have been determined: 2 Au(cr) + PtCl42- = Pt(cr) + 2AuCl2-; log K(Au–Pt) =–1.02 ± 0.25 (450°С, 1 kb), 0.09 ± 0.15 (450°С, 0.5 kb), and –1.31 ± 0.20 (350°С, 1 kb). It has been established that the factors affecting the Au/Pt concentration ratio in hydrothermal fluids and precipitated ores are temperature, pressure, redox potential, and sulfur fugacity. An increase in temperature results in an increase in the Au/Pt concentration ratio (up to ~550°С at P = 1 kb). A decrease in pressure and redox potential leads to enrichment of fluid in Au. An increase in sulfur fugacity in the stability field of Pt sulfides results in increase in the Au/Pt concentration ratio. Native platinum is replaced by sulfide mineral in low-temperature systems enriched in Pt (relative to Au).  相似文献   

15.
A new mineral, jichengite ideally 3CuIr2S4·(Ni,Fe)9S8, was found as a constituent of placer concentrates at a branch of the Luanhe River, about 220 km NNE of Beijing. Its associated minerals are chromite, magnetite, ilmenite, zircon, native gold, iridium, ferrian platinum and osmium. The placer is distributed at places around ultrabasic rock, which hosts chromite orebodies, from which PGM originated. Jichengite occurs commonly as massive or granular aggregates. No perfect morphology of jichengite was observed. It is steel gray and opaque with metallic luster and black streak. It has a Mohs hardness of 5, VHN (d) μm 21.65, Hm 4.465, Hv = 268.1 N/um2. It is brittle and weakly magnetic. Cleavage {010} is rarely observed. No fracture was observed. Density could not be measured because of its too small grain size. Density (calc.) is 7.003 g/cm3. Reflect light is reddish-brown, without internal reflections. Anisotropism is distinct with grayish or yellowish white in crossed nicols and bluish violet-copper red in uncrossed nicols. Jichengite shows weak pleochroism and strong bireflectance. The reflectance values in air at the Standard Commission on Ore Mineralogy wavelengths are: 38.9, 34.3 at 470 nm, 38.9, 34.5 at 546 nm, 39.1, 35.3 at 590 nm, 39.2, 36.8 at 650 nm, parallel-axial extinction. The six strongest lines in the X-ray powder-diffraction pattern [d in ?, (I), (hkl)] are: 3.00 (100) (116), 2.80 (50) (205), 2.48. (50) (208), 1.916 (40) (2, 1, 10), 1.765 (60) (220), 1.753 (50) (2, 0, 16). Five chemical analyses carried out, yielding the following results: S 25.76 (25.49-5.97), Fe 10.03 (9.78-10.31), Co 0.78 (0.75-0.81), Ni 12.48 (12.32-12.85), Cu 4.77 (4.69-4.83), Ir 46.98(46.14-47.89), sum 100.80wt%, which produced a formula (Cu1.556Fe0.976)2.532(Ir5.063S10.126)·(Fe2.7451Ni4.404Co0.273)7.422S6.517. The ideal formula is X10Ir5S17.5, which was calculated by single crystal structure analyses, where X = Cu(II) + Fe(II) + Ni(II) + Co(II). The single crystal data were collected using a diffractometer with Mo Ka radiation and a graphite monochromate. The crystal system is trigonal with space group R3m and unit cell parameters a=7.0745(14) ?, c=34.267(10) ? (The superstructure not found), and the final R Indices [with 564 observed reflections, I>2sigma (I)] are R1=0.0495, wR2=0.1349. The specimens are deposited in the Geological Museum of China.  相似文献   

16.
Contents of Pt and Pd were determined in weakly mineralized rocks, ores, and flotation concentrates of the Aksug porphyry Cu-Mo deposit, northeastern Tuva. In all studied samples they are above the detection limits: Pt = 17–96 ppb and Pd = 9–924 ppb. These elements are unevenly distributed throughout the rocks and ores, with Pd/Pt varying from 0.5 to 37. Study of Pd-rich ores (up to 924 ppb, Pd/Pt = 37) on a JEOL JSM 5600 scanning electron microscope revealed finest (2–5 μm) merenskyite inclusions (25.20% Pd, 1.21% Pt, 72.31% Te) in chalcopyrite. The calculated crystallochemical formula of merenskyite from ores of the Aksug deposit is (Pd0.862Pt0.023Cu0.026Fe0.025)Te2.064. The merenskyite is associated with electrum (79.92% Au, 18.96% Ag), monazite, cobaltite, tennantite, and Sr-containing barite (4.6–18.0% Sr). Palladium mineralization occurs in massive chalcopyrite veinlets in zones of intensely propylitized rocks. The Devonian Aksug ore-bearing porphyry complex developed in the field of Early-Middle Cambrian intrusions of gabbro-diorite-plagiogranites associated with basalt-andesite effusions of island-arc complex. This might have led to high PGE contents in the Aksug rocks. The deposit formation proceeded with the participation of ore-bearing Cl-enriched fluids favoring the concentration and transport of PGE in porphyry copper systems.  相似文献   

17.
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18.
Auriacusite, ideally Fe3+Cu2+AsO4O, is a new arsenate mineral (IMA2009–037) and the Fe3+ analogue of olivenite, from the Black Pine mine, 14.5 km NW of Philipsburg, Granite Co., Montana, USA. It occurs lining quartz vughs and coating quartz crystals and is associated with segnitite, brochantite, malachite, tetrahedrite and pyrite. Auriacusite forms fibrous crystals up to about 5?µm in width and up to about 100?µm in length, which are intergrown to form fibrous mats. Individual crystals are a brownish golden yellow, whilst the fibrous mats are ochreous yellow. The crystals have a silky lustre and a brownish yellow streak. Mohs hardness is about 3 (estimated). The fracture is irregular and the tenacity is brittle. Auriacusite crystals are biaxial (+), with α?=?1.830(5), β?=?1.865(5) and γ?=?1.910(5), measured using white light, and with 2V meas.?=?83(3)º and 2V calc. = 84.6º. Orientation: X?=?a, Y?=?c, Z?=?b. Crystals are nonpleochroic or too weakly so to be observed. The empirical formula (based on 5 O atoms) is (Fe 1.33 3+ Cu0.85Zn0.03)Σ2.21(As0.51Sb0.27Si0.04?S0.02Te0.01)Σ0.85O5. Auriacusite is orthorhombic, space group Pnnm, a?=?8.6235(7), b?=?8.2757(7), c?=?5.9501(5) Å, V?=?424.63(6) Å3, Z?=?4. The five strongest lines in the powder X-ray diffraction pattern are [d obs in Å / (I) / hkl]: 4.884 / (100) / 101, 001; 2.991 / (92) / 220; 2.476 / (85) / 311; 2.416 / (83) / 022; 2.669 / (74) / 221. The crystal structure was solved from single-crystal X-ray diffraction data utilising synchrotron radiation and refined to R 1?=?0.1010 on the basis of 951 unique reflections with F o?>?4σF. Auriacusite is identified as a member of the olivenite group with Fe3+ replacing Zn2+ or Cu2+ in trigonal bipyramidal coordination. Evidence suggests that auriacusite is an intermediate member between olivenite and an as yet undescribed Fe3+Fe3+-dominant member. The name is derived from the Latin auri (golden yellow) and acus (needle), in reference to its colour and crystal morphology.  相似文献   

19.
Nineteen samples from the Kane Fracture Zone have been studied for sulfide mineralogy and analyzed for S, Se, platinum-group elements (PGE), and Au to assess the effect of refertilization processes on the PGE systematics of abyssal peridotites. The lherzolites show broadly chondritic PGE ratios and sulfide modal abundances (0.01 to 0.03 wt%) consistent with partial melting models, although the few pyroxene-hosted sulfide inclusions and in situ LAM-ICPMS analyses provide evidence for in situ mobilization of a Cu-Ni-rich sulfide partial melt. The most refractory harzburgites (spinel Cr# > 29) are almost devoid of magmatic sulfides and show uniformly low PdN/IrN (<0.5) for variable PtN/IrN (0.8 to 1.2). The compatible behavior of Os, Ir, Ru, Rh, and Pt reflects the presence of primary Os-Ru alloys. Some harzburgites displaying petrographic evidence for refertilization by incremental melts en route to the surface are enriched in sulfides (up to 0.1 wt%). Some of these sulfides are concentrated in small veinlets of clinopyroxene and spinel crystallized from these melts. These S-rich harzburgites display superchondritic PdN/IrN (up to 2.04) positively correlated with sulfide modal contents. It is concluded that refertilization processes resulting in precipitation of metasomatic sulfides may significantly enhance Pd concentrations of abyssal peridotites while marginally affecting Pt (PtN/IrN ≤ 1.24) and Rh (RhN/IrN ≤ 1.23) as well. When the effects of such processes are screened out, our database suggests PGE relative abundances in the DMM (Depleted MORB Mantle; MORB: Mid-Ocean Ridge) within the uncertainty range of chondritic meteorites, without evidence of superchondritic Pt/Ir and/or Rh/Ir ratios.  相似文献   

20.
The spin Hamiltonian (SH) parameters (g factors g x , g y and g z and the hyperfine structure constants A x , A y and A z ) and local structure for the rhombic Rh4+ and Ir4+ centers in TiO2 (rutile) are theoretically studied from the perturbation formulas of these parameters for a low spin (S = 1/2) d 5 ion under rhombically distorted octahedra. In the calculations, the ligand orbital and spin–orbit coupling contributions as well as the influence of the local lattice distortions are taken into account using the cluster approach. The local axial elongation ratios are found to be about 1.7 and 3 times, respectively, larger for the Rh4+ and Ir4+ centers than that (≈0.0075) for the host Ti4+ site in rutile, while the perpendicular distortion angles (≈−0.28° and −0.42°, respectively) are more than one order in magnitude smaller than the host value (≈−9.12°). This means that the impurity centers exhibit further elongations of the oxygen octahedra and much smaller perpendicular rhombic distortions as compared with those of the host Ti4+ site in TiO2. The above local lattice distortions can be mainly ascribed to the substitution of the host Ti4+ by the nd 5 impurities, which may induce different physical and chemical properties for the metal–ligand clusters. In addition, the influence of the Jahn–Teller effect on the local structure may not be completely excluded. The calculated SH parameters show reasonable agreement with the observed values.  相似文献   

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