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为了研究岩体裂隙网络中矿物溶解-沉淀的变化规律及其对溶质运移的影响,联合矿物溶解-沉淀动力学模型、渗流模型和溶质运移模型建立了岩体裂隙网络矿物溶解-沉淀-迁移模型,经过水溶液络合物计算和矿物成分分析,对研究区域方解石溶解-沉淀作用及溶质运移进行了数值模拟。得出的结论主要有:(1)受裂隙网络分布的影响,溶质运移分布极不均匀,溶质主要通过连通的裂隙从上游向下游迁移;(2)考虑方解石的溶解-沉淀作用之后,在溶解区域溶质浓度增加,在沉淀区域溶质浓度减少;(3)通过对比分析,可知方解石溶解-沉淀受水溶液中CO23-浓度影响较大。 相似文献
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提高畦灌施肥地表水流与溶质运移数值模型的稳定性、收敛性及计算精度,有利于改善地面畦灌施肥系统的设计与评价工作.在利用隐-显混合时间格式对一维畦灌地表水流与溶质运移耦合模型中包含的各矢量项进行时间离散基础上,借助有限差分法、有限体积法和有限单元法分别对由隐时间格式生成的物理矢量线性近似式空间导数、物理矢量空间导数、溶质扩散矢量和地形矢量项进行空间离散,对最终形成的控制方程代数方程组进行数值求解,构建起基于混合数值解法的一维畦灌施肥地表水流与溶质运移耦合模型. 相似文献
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盐渍土壤中的物理化学作用对溶质运移具有重要影响.吸附和离子交换作用是土壤中常见的反应.利用室内土柱出流实验对这两种作用下的单组分和多组分溶质运移进行了探讨,用CXTFIT软件模拟了只考虑对流-弥散的常规溶质运移;用水文地球化学模拟软件PHREEQC进行了耦合吸附和离子交换反应的模拟.结果表明,土壤质地对单组分溶质的运移具有重要影响,而在多组分溶质运移中,组分之间的相互作用对溶质运移具有更为重要的影响,并且耦合物理化学作用的模拟精度更高. 相似文献
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PHREEQC在地下水溶质反应-运移模拟中的应用 总被引：7，自引：2，他引：7
由于地下水污染的加剧,对地下水中污染物运移规律的研究日益受到重视。地下水中的溶质在运移过程中伴随着溶质组分间的化学反应,因此需要建立地下水溶质运移与化学反应的耦合模型。PHREEQC是近年来发展起来的描述局部平衡反应、动态生物化学反应的水文地球化学模拟软件。本文利用该模拟软件对一维地下水流动过程中溶质离子交换反应和动态氧化还原反应进行了模拟。结果表明,PHREEQC能够成功地进行溶质运移情况下复杂水化学反应模拟,但对于复杂地下水流和溶质运动的情况,有必要耦合其它的地下水流动和溶质运移软件来共同完成。 相似文献
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波浪会促进海水中溶质向海底沉积物运移,但已有研究大多未考虑海床（海底沉积物）变形效应的影响。为揭示波浪作用下海床土变形对溶质运移过程的影响机制,构建了考虑海床土变形影响的溶质运移计算模型,对波浪作用下溶质向砂质海底沉积物中的运移过程进行模拟。结果表明:海床土变形会增大孔隙水流速,进而增大溶质纵向水动力弥散系数,增强溶质运移的机械弥散作用,促进溶质向沉积物中运移;考虑海床变形时的溶质最大纵向水动力弥散系数可达不考虑海床变形时的8.5倍,约为分子扩散系数的545倍;海床土剪切模量越小,土体变形效应越明显,对溶质运移过程的影响越大;海床土饱和度的降低,会进一步加速波浪作用下溶质向海底沉积物的运移过程。 相似文献
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利用算子分裂迎风均衡格式解对流为主溶质运移问题 总被引：2，自引：0，他引：2
水污染模拟问题是水流问题与溶质运移问题的耦合问题.各种常见的数值解法在以对流为主溶质运移问题的求解中都会遇到困难,如用有限单元法或有限差分法时,会产生数值弥散与过量这两类误差.引入算子分裂迎风均衡格式法求解对流为主的水污染模拟问题,较好地克服了数值弥散和数值解出现振荡问题,该格式具有良好的稳定性、单调性及守恒性特点. 相似文献
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土壤中水分和溶质运移一直是土壤-水环境系统中的研究热点,也是目前仍未得到很好解决的问题.将分形理论应用于土壤水分溶质运移机制的研究,探讨其领域中的众多复杂问题,是一种全新的思路和方法.在对土壤结构定量化的分形表征进行简要阐述的基础上,重点介绍了分形理论在水分特征曲线和水力传导度等土壤水分运动基本参数的分形模型、土壤水分运移过程模拟、土壤溶质运移的非费克现象、弥散度的尺度效应以及溶质运移机制研究方面所取得的一系列成果,并就分形理论今后在土壤水分、溶质运移研究中的应用作了展望. 相似文献
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不流动水与非平衡吸附作用对溶质在孔隙介质中的运移有很大影响,“两点-两区”模型是目前研究不流动水与非平衡吸附作用的较为完善和实用的模型。在溶质运移的“两点-两区”模型的基础上,同时考虑了土壤对溶质的平衡和非平衡吸附作用,开发了MIENESOR数值模型,并给出了基于有限差和有限元法联合的数值解,编制了相应的计算机程序。对MIENESOR数值模型的案例验算表明：该模型能很好地揭示溶质在包气带和含水层中运移的规律,所开发的计算机程序稳定性较强,可用于实际。 相似文献
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岩溶区地下水数值模拟研究进展 总被引：2，自引：2，他引：0
岩溶含水介质的不均一性导致岩溶地下水流动、溶质运移和热量迁移的数学模拟研究成为地下水模拟的难点。本文综述了岩溶区地下水流模拟的几种方法,重点阐述了等效多孔介质法、双重连续介质法和三重介质法的定义、发展过程和适用范围,并回顾了这几种方法的研究成果。从等效多孔介质法到三重介质法,模拟精度不断提高,适用范围也逐渐由大区域实际问题向小区域理论研究过渡。介绍了溶质运移模拟和热迁移模拟的研究方法及实例。溶质运移模拟以对流弥散方程为基础,其中尺度效应是溶质运移模拟的重点研究问题;热量迁移模拟应考虑地下热水密度变化对地下热水运动的影响。溶质运移模拟和热量迁移模拟往往是将迁移模型和已经调试成功的地下水流动模型相耦合,从而达到模拟溶质及热量迁移的目的。由于溶质运移和热量迁移的复杂性,现阶段水流模型多数处于等效多孔介质模型阶段。综合理论及实际应用,指出精确刻画裂隙及管道和注重基础数学算法是岩溶水数值模拟进步的关键。 相似文献
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A Fully Coupled Chemo-Poroelastic Analysis of Pore Pressure and Stress Distribution around a Wellbore in Water Active Rocks 总被引：1，自引：0，他引：1
Water active rocks consist of minerals that hold water in their crystalline structure and in pore spaces. Free water from
drilling fluid can be attracted by the formation depending on the potential differences between pore space and drilling fluid.
The fluid movement into the formation or out of the formation can lead to a change in effective stress, thus causing wellbore
failures. In all previous studies it is found that the solute transport from or to the formation is primarily controlled by
diffusion process and the effect of advection on solute transfer is negligible for a range of very low permeable shale formations
(>10−5 mD). In this study a range of permeable shale formations (10−5 to 10−3 mD) commonly encountered in drilling oil and gas wells are considered to investigate the solute transfer between drilling
fluid and formation due to advection. For this purpose a finite element model of fully coupled chemo-hydro-mechanical processes
was developed. Results of this study revealed that the solute transfer between the drilling fluid and the shale formation
is controlled primarily by permeability of the shale formations. For the range of shale formations studied here, there exists
a threshold permeability below which the solute transfer is dominated by diffusion process and above which by fluid in motion
(fluid flow). Results from the numerical experiments have shown that when the permeability of shales is greater than this
threshold permeability, the chemical potential gradient between the pore fluid and drilling fluid reaches equilibrium faster
than that when the permeability of shales is below this threshold value. Also it has been found that when advection is taken
into account, effective radial and tangential stresses decrease around the wellbore, particularly near the wellbore wall where
the solute concentration has reached near equilibrium. 相似文献
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在分析大区域地下水流数值模型构建缘起的前提下,系统论述了近年来地下水流数值模拟在大区域地下水资源评价、水文地质参数确定、地面沉降、溶质运移、海水入侵、盐渍化、风险评估、地下水管理及地表水与地下水的联合开发利用等方面的国内外研究应用现状;归纳、总结了目前大区域地下水流数值模型在灵敏度分析、裂隙和岩溶介质中模型建立、基于地下水流数值模拟的溶质运移模型建立、地下水流数值模型构建所需工作量等理论和方法研究及实际建模过程中存在的一些问题;展望了今后大区域地下水流数值拟在研究范围、模拟技术与方法以及与其它模型耦合等方面的发展趋势。 相似文献
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The migration of contaminant through soil is usually modeled using the advection‐dispersion equation and assumes that the porous media is stationary without introducing a constitutive equation to represent soil structure. Consequently, time‐dependent deformation induced by soil consolidation or physical remediation is not considered, despite the need to consider these variables during planning for the remediation of contaminated ground, the prediction of contaminated groundwater movement, and the design of engineered landfills. This study focuses on the numerical modeling of solute transfer during consolidation as a first step to resolve some of these issues. We combine a coupling theory‐based mass conservation law for soil‐fluid‐solute phases with finite element modeling to simulate solute transfer during deformation and groundwater convection. We also assessed the sensitivity of solute transfer to the initial boundary conditions. The modeling shows the migration of solute toward the ground surface as a result of ground settlement and the dissipation of excess pore water pressure. The form of solute transport is dependent on the ground conditions, including factors such as the loading schedule, contamination depth, and water content. The results indicate that an understanding of the interaction between coupling phases is essential in predicting solute transfer in ground deformation and could provide an appropriate approach to ground management for soil remediation. 相似文献
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A Lagrangian perturbation method is applied to develop a method of moments for reactive solute flux through a three-dimensional, nonstationary flow field. The flow nonstationarity may stem from medium nonstationarity, finite domain boundaries, and/or fluid pumping and injecting. The reactive solute flux is described as a space–time process where time refers to the solute flux breakthrough in a control plane at some distance downstream of the solute source and space refers to the transverse displacement distribution at the control plane. The analytically derived moments equations for solute transport in a nonstationary flow field are too complicated to solve analytically; therefore, a numerical finite difference method is implemented to obtain the solutions. This approach combines the stochastic model with the flexibility of the numerical method to boundary and initial conditions. The approach provides a tool to apply stochastic theory to reactive solute transport in complex subsurface environments. Several case studies have been conducted to investigate the influence of the physical and chemical heterogeneity of a medium on the reactive solute flux prediction in nonstationary flow field. It is found that both physical and chemical heterogeneity significantly affect solute transport behavior in a nonstationary flow field. The developed method is also applied to an environmental project for predicting solute flux in the saturated zone below the Yucca Mountain Project area, demonstrating the applicability of the method in practical environmental projects. 相似文献
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在地下水的相关研究中,农药和石油等地下水污染、土地盐碱化、海水入侵等诸多实际问题主要的研究方法都涉及地下水溶质迁移模拟. 相比地下水水流模拟的相对完善,对溶质迁移的模拟比较薄弱且迁移过程本身复杂性较高,目前地下水溶质迁移的研究工作还处在全面发展的阶段. 文中阐述了反映地下水溶质迁移机理和过程的数学模型,综述了溶质迁移模拟在地下水污染物防治、土地盐碱化、海水入侵、石油和放射性废物扩散等问题的诸多应用,归类了目前溶质迁移模拟所使用的对流迁移、对流-弥散模拟等主要数值方法,并对这些方法的优缺点和应用实例做了总结. 最后,分析了目前溶质迁移模拟中存在的不足,展望了未来在参数确定、裂隙介质运移机理和多相介质条件下运移模拟可能取得的突破. 相似文献
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The fate and movement of dissolved substances in soils and groundwater has generated considerable concern for the quality of the subsurface environment. Many analytical solutions for the partial differential equations that describe solute and pollutant movement exist. Numerical solutions are more general, and often more difficult to verify. In order to determine the model error, the examination of the ability of numerical methods compared to analytical methods is strongly recommended. The objective of the study is to make a comparison between numerical and analytical solution models for solute transport equation. In this study, the numerical solution calculated with the WAVE-model is compared with the analytical solution calculated with CXTFTT-model. The study scenarios considered variables such as compartment depth, applied flux at the top and soil dispersivity under steady-state conditions. The simulations depend on 27 solute infiltration scenarios. The solute concentrations were calculated with the WAVE-model and the CXTFIT-model for each scenario. The WAVE-model error was evaluated with three methods: absolute average maximum error, relative average maximum error and relative average area error. The study implied that the WAVE-model error increased with the increase of the compartment depth, decreasing soil dispersivity, and decrease in flux. The study leads to the recommendation to use compartment depth as thin as possible to minimise the WAVE-model error. Furthermore, it is more useful to use several numerical solution models, such as SWMS-2D model, to evaluate and examine the WAVE-model. 相似文献
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垃圾填埋场滤出液、入侵海水、核废物及生产生活废水等污染物随地下水的迁移威胁人类生存。地下水渗流的随机性导致溶质运移问题更加复杂。根据流网特点,利用流线与水头等势线对求解域进行离散,基于质量守恒原理建立流网单元内溶质浓度求解的隐式有限体积差分格式。基于多孔介质孔隙流速分布规律,利用蒙特卡洛法建立流管单元随机流速场进行溶质运移过程的数值模拟,最后根据数值模拟和模型试验的结果对比,验证了数值模拟方法的准确性。基于流网单元的数值模型中沿流线方向的物质交换由对流和扩散共同作用,而流管间的物质交换只有扩散作用,因此,可在不使用弥散系数下进行污染物运移的模拟。引入随机方法确定流管内流速为研究非均匀流场中染污物的优势迁移提供了新的思路。 相似文献