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1.
皖南地区花岗岩风化壳中稀土元素普遍富集，局部已成为矿床，其中，郎溪县姚村岩体风化壳富集程度较高。LA- ICP- MS锆石U- Pb定年表明，姚村花岗岩体的形成年龄为127.9±1.4 Ma，属于皖南地区燕山期晚期岩浆作用的产物。风化壳可细分为残坡积层（A）、强半风化层（C1）、过渡层（C2）、弱风化层（C3）和基岩（D）五层。稀土总量在纵向剖面上呈“波浪式”分布，各层稀土分布型式表现出对原岩的继承性。风化壳稀土配分型式与基岩一致， 富集LREE，轻重稀土分馏明显(La/Yb)N=15.6），但总含量明显更高。基岩∑REE为338×10-6，半风化层∑REE最高达642×10-6，富集约两倍。风化壳物质由风化残余主矿物（石英、钾长石、斜长石、黑云母）、黏土矿物（高岭石、埃洛石、伊利石、三水铝石等）和副矿物（锆石、磷灰石、榍石等）等组成。黏土矿物以伊利石含量最高，指示风化壳发育不成熟。REE与埃洛石含量明显正相关，与其他黏土矿物关系不明显。（含）稀土矿物（尤其是榍石）对风化壳中稀土元素的贡献量超过百分之五十，其次为斜长石，是风化壳中REE的重要来源。 相似文献
2.
皖南地区花岗岩风化壳中稀土元素普遍富集，局部已成为矿床，其中，郎溪县姚村岩体风化壳富集程度较高。LA- ICP- MS锆石U- Pb定年表明，姚村花岗岩体的形成年龄为127. 9±1. 4 Ma，属于皖南地区燕山期晚期岩浆作用的产物。风化壳可细分为残坡积层（A）、强半风化层（C1）、过渡层（C2）、弱半风化层（C3）和基岩（D） 5层。稀土总量在纵向剖面上呈“波浪式”分布，各层稀土分布型式表现出对原岩的继承性。风化壳稀土配分型式与基岩一致， 富集LREE，轻重稀土分馏明显\[(La/Yb)N=15. 6\]，但总含量明显更高。基岩∑REE为338×10-6，半风化层∑REE最高达642×10-6，富集约两倍。风化壳物质由风化残余主矿物（石英、钾长石、斜长石、黑云母）、黏土矿物（高岭石、埃洛石、伊利石、三水铝石等）和副矿物（锆石、磷灰石、榍石等）等组成。黏土矿物以伊利石含量最高，指示风化壳发育不成熟。REE与埃洛石含量明显正相关，与其他黏土矿物关系不明显。（含）稀土矿物（尤其是榍石）对风化壳中稀土元素的贡献量超过 50%，其次为斜长石，是风化壳中REE的重要来源。 相似文献
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Labrador has been covered by reconnaissance-scale geochemical surveys under the National Geochemical Reconnaissance program. Lake sediment and water were the chief sample media, but stream sediment and water were employed in the mountainous terrain of northern Labrador. The main objective of these surveys was mineral resource assessment, but the data are also relevant to geological and environmental studies, and would be most useful to the non-specialist if the data from the two drainage types could be combined to produce unified element distribution maps for the whole region.A comparison of stream and lake data for a 5,700-km2 area where both drainage types were sampled suggests that only the pH of the lake and stream waters are directly comparable, showing a common range and similar spatial distribution. Comparing the two types of sediment, most elements show obvious differences in either median content or range or both, indicating that stream and lake sediment are geochemically distinct media, and their element contents cannot be compared directly. The distribution patterns of Cu, Ni and U reflect similar bedrock features in both sediment types. In contrast, Co, F, Fe, Hg, Mn, V and Zn show little or no spatial correlation between stream and lake sediment, but are strongly intercorrelated in the stream sediment data set.The sediments collected from lakes in Labrador represent disturbed column, about 40 cm in length, of organic debris that accumulated over the past several hundred years. Metal accumulation in the sediment is largely through fixation from inflowing surface and groundwater by microorganisms, coprecipitation with hydrous Fe and Mn oxides, sorption by clay minerals and chemical and biochemical processes at and just below the sediment/water interface. The stream sediments in this study were collected from active sediment, and represent principally the mechanical-weathering products of bedrock, with variable amounts of organic matter and hydrous Fe and Mn oxides. Considering the difference in the two sediment types, it is probably not surprising that there is rather limited spatial correlation between the geochemistry of the two sediment types indicating that to a large extent each medium reflects a different facet of the bedrock geochemistry. Only for a few elements should the data sets be merged. The degree of spatial correlation for U, Ni and Cu increases as the data are generalized by averaging into larger blocks, suggesting that the combined data sets will be more successful in defining broad crustal geochemical features rather than local details. The implication of this study for international geochemical mapping is that geochemical patterns for many elements are strongly dependent on the sample medium chosen. Therefore, when it is necessary to change sample media in passing from one terrain type to another, a comparative study must be carried out to determine how the geochemistry of the different sample media compare spatially. 相似文献
4.
花岗岩类化学元素丰度研究是花岗岩类地球化学和地壳丰度研究的一项重要内容,一直为国际上所关注,并有很多学者先后发表了不同的花岗岩类化学成分和元素丰度的数据,但迄今为止世界上还没有花岗岩类地球化学图的出版。本文以中国56种元素花岗岩类地球化学图为基础,探讨了中国大陆花岗岩类各元素地球化学图所展示的多元素的区域分布特征、空间分布规律和分布模式。结果显示,花岗岩类各元素的空间分布模式与中国花岗岩类的分布和特征密切相关。花岗岩类地球化学图能够清晰地反映出花岗岩类化学成份的空间变化规律和特征。 相似文献
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利用1∶200 000地球化学数据,从整个成矿地球化学环境的角度出发,最大限度地开发、挖掘三十九种化学元素中每个元素以及元素组合所蕴含的矿化信息,为成矿远景区预测提供更加翔实的地球化学依据,是地球化学工作者的研究任务之一。MAPGIS功能强大,其地图库管理模块为多幅1∶200 000地球化学异常图的拼接提供了技术支持。这里论述了1∶200 000地球化学数据的特征和MAPGIS的地图库管理的功能,并记述了在实际工作中应用MAPGIS的地图库管理对多幅1∶200 000地球化学异常图的拼接,实现了对1∶200 000地球化学数据的另一种应用方式。 相似文献
8.
Environmental geochemistry has attracted increasing interest during the last decade. In Sweden, geochemical mapping is carried out with methods that allow the data to be used in environmental research, including sampling plant roots and mosses from streams, soils and bedrock. These three sample types form an integrated strategy in environmental research, as well as in geochemical exploration. However, one problem that becomes prominent in geochemical mapping is to distinguish the signals derived from natural sources from those derived from anthropogenic sources. So far, this has mostly been done by using different types of samples, for example, different soil horizons. This is both expensive and time-consuming.We are currently developing alternative statistical solutions to this problem. The method used here is PLSR (partial least squares regression analysis). In this paper, we present an initial discussion on the applicability of PLSR in differentiating anthropogenic anomalies from natural contents.PLSR performs a simultaneous, interdependent principal component analysis decomposition in both X- and Y-matrices, in such a way that the information in the Y-matrix is used directly as a guide for optimal decomposition of the X-matrix. PLSR thus performs a generalized multivariate regression of Y on X overcoming the multicollinearity problem of correlated X-variables. The advantage of PLSR is that it gives optimal prediction ability in a strict statistical sense.Bedrock geochemistry from different lithologies in the mapping area in southern Sweden (Y-matrix) is analyzed together with stream or soil data (X-matrix). By modelling the PLS-regression between these two data sets, separate multivariate geochemical models based on the different bedrock types were developed. This step is called the training or modelling stage of the multivariate calibration. These calibrated models are subsequently used for predicting new (X) geochemical samples and estimating the corresponding Y-variable values. Information is obtained on how much of the metal contents in each new geochemical sample correlate with the different modelled bedrock types.By computing the appropriate X-residuals, we obtain information on the anthropogenic impact that is also carried by these new samples. In this way, it is possible from one single geochemical survey to derive both conventional geochemical background data and anthropogenic data, both of which can be readily displayed as maps.The present study concerns development of data analysis methods. Examples of the applications of the methodology are presented using Pb and U. The results show the share of these contents in different sampling media that is derived from bedrock on the one hand, and from anthropogenic sources, on the other. 相似文献
9.
《Applied Geochemistry》2002,17(3):321-336
Mineralogical, petrographical, and geochemical studies of the weathering profile have been carried out at Omai Au mine, Guyana. The area is underlain by felsic to mafic volcanic and sedimentary rocks of the Barama-Mazaruni Supergroup, part of the Paleoproterozoic greenstone belts of the Guiana Shield. Tropical rainy climate has favoured extensive lateritization processes and formation of a deeply weathered regolith. The top of the weathering profile consists of lateritic gravel or is masked by the Pleistocene continental-deltaic Berbice Formation. Mineralogical composition of regolith consists mainly of kaolinite, goethite and quartz, and subordinately sericite, feldspar, hematite, pyrite, smectite, heavy minerals, and uncommon mineral phases (nacrite, ephesite, corrensite, guyanaite). A specific feature of the weathering profile at Omai is the preservation of fresh hydrothermal pyrite in the saprolith horizon. Chemical changes during the weathering processes depend on various physicochemical and structural parameters. Consequently, the depth should not be the principal criterion for comparison purposes of the geochemical behavior within the weathering profile, but rather an index that measures the degree of supergene alteration that has affected each analyzed sample, independently of the depth of sampling. Thus, the mineralogical index of alteration (MIA) can provide more accurate information about the behavior of major and trace elements in regolith as opposed to unweathered bedrock. It can also aid in establishing a quantitative relationship between intensity of weathering and mobility (leaching or accumulation) of each element in each analyzed sample. At Omai, some major and trace elements that are commonly considered as immobile (ex: TiO2, Zr, etc.) during weathering could become mobile in several rock types and cannot be used to calculate the mass and volume balance. In addition, due to higher “immobile element” ratios, the weathered felsic volcanic rocks plotted in identification diagrams are shifted towards more mafic rock types and a negative adjustment of ∼20 units is necessary for correct classification. In contrast, these elements could aid in defining the material source in sedimentary rocks affected by weathering. Generally, the rare-earth element (REE) patterns of the bedrock are preserved in the saprolith horizon. This can represent a potentially useful tool for geochemical exploration in tropical terrains. Strong negative Ce and Tb anomalies are displayed by weathered pillowed andesites, which are explained by the influence of the water/rock ratio. 相似文献
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Rico, Colorado is a small mountain community that was developed before the turn of the century around and near underground
lead-zinc-silver mines. Today, US regulatory concerns in such communities focus on the metal content, particularly of lead,
in community soils. This study integrates bedrock geology, surficial geology, mineralogy and geochemistry in order to define
the controls on metal distribution in Rico community soils. The principal constituents of concern are As, Pb, and Mn. The
results show that mining-related sources are discrete and localized whereas natural sources, including bedrock (mean Pb content
of 3 500 ppm), colluvium (mean Pb content of 1 410 ppm), and older alluvium (mean Pb content of 744 ppm) are wider spread
and are the principal sources of metals in Rico community soils. Historical mining sites like Rico should be expected to have
significant surficial expressions of mineralized bedrock. In these communities, it is important to accurately define the role
of all metal sources as a foundation for determining environmental liabilities, cleanup guidelines, and health risk assessments.
The application of geology and mineralogy in support of geochemical characterization is necessary to accurately define the
origin and distribution of both anthropogenic and natural metal sources at such sites.
Received: 27 December 1996 · Accepted: 21 February 1997 相似文献
11.
Weathering intensity changes due to climatic variability across tectonically stable portions of continental crust can generate a thick and extensive weathered cover, resulting in regolith-dominated terrains (RDTs). Mineral exploration in RDTs is challenging because of the lack of bedrock outcrop, and the difficulty of linking surface regolith geochemistry to the geology at depth. Complex weathering obscures the expression of the basement geochemistry in the regolith, and therefore the footprints of mineral systems are difficult to detect. The southeast of the Yilgarn Craton and the Albany–Fraser Orogen (AFO) in the south of Western Australia is an RDT that extends along the coastline and the Eucla basin.This study proposes a landscape evolution model of the AFO, driven by transgression–regression sea-level changes that resulted in the formation of numerous islands and development of estuarine zones. This model contrasts with the river system-dominated landscape evolution present in the Yilgarn Craton. This difference has significant implications for mineral exploration and geochemical interpretation of the regolith in this region.Weathering profiles developed “on inland” and “on island” are thicker and more mature than those developed in sea-inundated areas. Even if in the Yilgarn Craton local areas display reworking of weathering profiles and other complexities from Permian, non-marine Tertiary sediments and Quaternary fluvial and aeolian sediments, at a regional scale, if vertical geochemical mobility of elements has occurred, “on inland” and “on island” are more reliable for understanding geochemical anomaly-basement relationships, whereas the “marine inundated” areas require a more detailed investigation, because of the role of marine reworking of weathering profiles and possible mixture of sediments from different provenances.Landscape changes from the topographically high, dissected Yilgarn environment with thick saprolite development and uneven basement topography, to the nearly flat regions dominated by sand dunes and thin saprolite development at the coastline. These regions are the result of the erosional and depositional effects of successive sea-level transgression–regression cycles. Within this framework, the following four different regolith settings have been identified in a progressive change from Yilgarn Craton environments to the modern coastline: (1) Albany; (2) Kalgoorlie–Norseman; (3) Esperance; and (4) Neale.Mapping the palaeocoastlines, islands and estuarine zones, as well as the region of influence of marine limestones and sediments, can significantly improve the understanding of how surface geochemistry relates to the landscape, and how it links with the geology at depth, and therefore, how it may reflect the presence of mineral systems. Understanding the difference in the landscape evolution between the AFO and Yilgarn Craton is essential to properly calibrate mineral exploration protocols in both regions. 相似文献
12.
Stephen J. Barnes L. A. Fisher R. Anand T. Uemoto 《Australian Journal of Earth Sciences》2013,60(2):269-285
Large, high-quality multi-element geochemical datasets are becoming widely available in the exploration industry, and afford excellent opportunities to investigate geochemical processes. A dataset of over 2500 analyses of unweathered and variably weathered mafic and ultramafic rocks for over 50 elements has been collected by Gold Fields Ltd. in the auriferous Agnew-Lawlers area of the eastern Yilgarn Craton of Western Australia. This dataset is used to investigate changes in element abundances and inter-element ratios through varying degrees and styles of weathering in an area of thick regolith characterised by deep in situ weathering. Systematic interrogation of the data, using lithostratigraphic controls derived from regional mapping and geophysics, reveals that a suite of elements, including Ti, Al, Zr, Th, La, Sc and Nb, and to a lesser extent Cr and Ni, behave as essentially immobile components during saprolite formation. In some cases diagnostic element ratios persist into siliceous duricrust. Ratios of these elements are used as reliable discriminants of bedrock type, and delineate features such as cryptic layering within fractionated sills and subtle geochemical variants in a sequence of tholeiitic and komatiitic basalts. Mapping on the basis of discriminant element ratios greatly extends previous trace-element ratio-based schemes for rock type discrimination. The potential to determine several of these elements with adequate precision and accuracy using portable XRF technology opens a potentially useful technique for rapid geochemical bedrock mapping in residual terrains. 相似文献
13.
Old geochemical datasets from the Paraná Shield of southern Brazil have been integrated into a new geochemical database and the results are presented as a series of multipurpose geochemical maps. Although the 24 datasets retrieved were analysed by three different laboratories, the maps produced correlate surprisingly well with bedrock geological features.The retrieval of old geochemical exploration data sets for the purpose of generating maps showing element depletions and enrichments is a powerful tool with a wide range of applications: trace elements such as Zn, Cu and Mo can significantly affect crop productivity; areas with high abundances of harmful elements such as As and F can be delineated in order to identify public health hazards; heavy metals such as Cd, Pb and Hg can be measured in order to better constrain knowledge of chemical background levels for environmental monitoring. The integration and manipulation of different data sets can however be complicated by the heterogeneity in sampling and analytical procedures. 相似文献
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The Hill Country of Central Texas, USA, is undergoing rapid socioeconomic development, but environmental management of this
region is hampered by misconceptions about local bedrock, soils, terrain, and hydrologic processes. The Hill Country is underlain
mostly by Glen Rose Limestone (Lower Cretaceous) and exhibits a stepped terrain, which has been incorrectly attributed to
alternating hard and soft bedrock strata. Other characteristics mistakenly attributed to this landscape include thin soils
with scant water-retention capabilities, and rapid runoff as the dominant hydrologic process. This report presents new findings:
unweathered bedrock is well indurated, but interbeds exhibit variable weathering rates. Recessive slopes (“risers”) on this
stepped terrain result from rapid deterioration of strata having generally heterogeneous depositional fabrics (bioturbation
and irregular clay partings) in contrast to ledge-forming strata having homogeneous fabrics. A stony regolith is thus formed
beneath risers, providing porous and permeable ground that retards runoff and promotes the formation of moderately deep to
deep (two-tiered) regolith/soil zones. These surficial materials on local steep slopes compose important natural environmental
buffers; they support diverse biota and enhanced geochemical cycling of nutrients; they also exhibit significant water retention
and enhanced erosion abatement. Proper land management demands recognition of these attributes in the siting, design, and
construction of facilities. 相似文献
16.
Major and trace element concentrations were measured in bedrock, regolith and stream sediments from a first-order catchment developed entirely on grey shale in central Pennsylvania, USA. These elements can be classified into five major groups based on statistical data analysis. The presence of different elemental groups is due to the mineralogical origin, cycling processes, and geochemical properties of these elements during soil formation. A better understanding of the behaviors of these elements during chemical weathering would allow for their possible use as natural tracers in Critical Zone processes. 相似文献
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A geochemical baseline provides the means to distinguish between the pedogenic origin and the anthropogenic origin of the
trace element in the environmental compartments. We collected 271 soil samples representative of different parent rocks and
soil types from the whole territory of Hong Kong and analyzed the composition of clay mineralogy and the contents of 15 chemical
elements (Fe, Cd, As, etc.) for these samples. The baseline was predicted with the method of the normalization procedure combined
with the relative cumulative frequency curve. The result indicated that Fe was the best reference element for the normalization
procedure among the five potential reference elements (Fe, Al, Sc, Ti, and Mn), followed by Sc and Ti. A poor correlation
was found between Sc, Ti, and Cu. The predicted baseline was much lower than the A-value of the Dutch List used usually in screening the polluted soil of Hong Kong, implying that the extent of heavy metal
pollution might have been underestimated with respect to local lands. We also applied the cluster analysis to distinguish
the geochemical associations of the trace elements due to its importance to the baseline. Approximately three major associations
including the Fe–Mn-oxides related, Al oxides or Al-bearing-clay-mineralogy related and sulfide- related associations were
observed from the dendrogram. 相似文献
19.
This essay traces the development of geochemical exploration from its early beginnings in the modern era during the 1930s, concentrating especially in its application to deeply weathered terrain in the tropics and sub-tropics. Following promising results obtained in temperate regions in North America and Europe, test orientation surveys were conducted to see whether similar procedures were applicable in the tropics, where conventional geological prospecting was largely precluded due to the extensive cover of a deep lateritic regolith and consequent lack of outcrop. After initial work in Sierra Leone and Nigeria, the emphasis transferred to East Africa in the 1950s and 1960s, aimed principally at Cu exploration. Many of the basic principles for exploration in dominantly residual, free-draining terrain were quickly established in this period. Exploration in terrains with more complex weathering histories, however, raised a number of difficulties due to leaching and secondary concentrations of elements, problems in selecting and identifying appropriate sample media, and extensive transported overburden. These were encountered especially in more arid regions in Australia and Africa during exploration for Ni and Au during the 1970s and 1980s. This led to a change in approach, placing weathering and geochemical dispersion in the context of regolith and landscape evolution –a return to the early concept of landscape geochemistry. The 3D expression of mineralization in the landscape is depicted as empirical conceptual models, that account for both relict features and active processes, and portray element associations, dispersion mechanisms and host materials. They also indicate suitable sample media, sampling intervals and procedures for analysis and interpretation. 相似文献
20.
Vast parts of the Australian continent are prospective for precious and base metal mineralisation, but exploration is hindered by extensive cover of often deeply reaching regolith. New operational exploration methods are required that can help to characterise the cover and provide information about bedrock signatures. This paper shows how mineral mapping information from a combination of satellite multispectral Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) imagery and drill core hyperspectral profiling data (HyLogging™) can be used to unravel the regolith stratigraphy and to describe regional variations of regolith landforms, delivering important information for mineral exploration.The case study is located in the Neale tenements in the northeastern Albany–Fraser Orogen (Western Australia), which is prospective for Tropicana-style gold mineralisation. By interpretation of indicator minerals from hyperspectral drill hole logging data the regolith stratigraphy atop a metamorphic basement, comprising saprock, ferrugineous saprolite, kaolinitic saprolite, silcrete and transported cover, is recorded in cm-detail. Important mineralogical parameters extracted from the hyperspectral subsurface data and validated by XRD and FTIR, are 1) the abundance and type of iron oxides, 2) the abundance and crystallinity of kaolinite, 3) the abundance and composition of primary minerals, such as white mica, and 4) the abundance of quartz.The HyLogging™ data served as ground control points for mineral mapping information provided by CSIRO's ASTER Geoscience Products, which are a collection of mineral maps that highlight variations in the abundance, type or chemistry of selected mineral groups. Key ASTER Geoscience Products for regolith characterisation were the Ferric Oxide and AlOH abundance and composition images. The comparison of the surface with the subsurface data suggests three major different regolith landforms, including erosional, depositional and relict areas, which were used to generate a map showing transported versus relict and erosional areas. Erosional domains were mapped out in great detail, providing important information for exploration in saprolite dominated areas. Furthermore, source areas of transported material could be identified, which may help to understand the distribution of geochemical signatures collected during, for example, geochemical soil sampling projects. 相似文献