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1.
Assessment of groundwater quality is an important aspect of water security, which is the key to ensure sustainable development. The objective of the study is to bring out an integrated approach for assessment of groundwater quality for drinking and irrigation purposes. Gogi region, Karnataka, India was chosen as the study area due to the effect of the presence of medium-grade uranium deposits. An integrated approach including the concentration of major ions, trace elements and uranium was employed to investigate the quality of groundwater. Totally, 367 groundwater samples were collected periodically from 52 wells distributes over the Gogi region and the parameters such as pH, electrical conductivity, total dissolved solids (TDS), Ca2+, Mg2+, Na+, K+, Cl?, SO4 2?, NO3 ?, Zn, Pb, Cu, and uranium of groundwater were analysed. Spatial distribution maps of various chemical constituents were prepared using geographic information system and its temporal variation was plotted in box and whisker plot. The analytical data were compared with Bureau of Indian Standards and World Health Organisation standards to determine drinking water quality and parameters such as salinity hazard, alkalinity hazard and percent sodium were estimated to assess the irrigation quality. Multivariate statistical analysis by cluster analysis was also performed which results in two groups consisting of wells with unsuitable water for drinking purposes. Groundwater in about 15% of the sampling wells were found to be unsuitable for domestic purpose based on TDS and about 17% were unsuitable based on uranium concentration. Finally, integration of spatial variation in TDS and uranium reveals that about 25% of the wells were unsuitable for domestic purposes. It is suggested that such an integrated approach needs to be formulated considering major ions, trace elements and radioactive elements for proper assessment of water quality. Implementation of managed aquifer recharge structures in the study area is suggested since it would potentially reduce the concentration of ions.  相似文献   

2.
Groundwater is of a paramount importance in arid areas, as it represents the main water resource to satisfy the different needs of the various sectors. Nevertheless, coastal aquifers are generally subjected to seawater intrusion and groundwater quality degradation. In this study, the groundwater quality of the coastal Jeffara aquifer (southeastern Tunisia) is evaluated to check its suitability for irrigation purposes. A total of 74 groundwater samples were collected and analyzed for various physical and chemical parameters, such as, electrical conductivity, pH, dissolved solids (TDS), Na, K, Ca, Mg, Cl, HCO3, and SO4. Sodium adsorption ratio, magnesium adsorption ratio, Sodium percentage, and permeability index were calculated based on the analytical results. The analytical results obtained show a strong mineralization of the water in the studied aquifer. TDS concentrations range from 3.40 to 18.84 g?L?1. Groundwater salinity was shown to be mainly controlled by sodium and chloride. The dominant hydrochemical facieses are Na–Cl–Ca–SO4, mainly as a result of mineral dissolution (halite and gypsum), infiltration of saline surface water, and seawater intrusion. Assessment of the groundwater quality of the different samples by various methods indicated that only 7% of the water, in the northwest of the study area, is considered suitable for irrigation purposes while 93% are characterized by fair to poor quality, and are therefore just suitable or unsuitable for irrigation purposes.  相似文献   

3.
In this study, combining interpretations of conservative dissolved ions and environmental isotopes in water were used to investigate the main factors and mechanisms controlling groundwater salinization and hydrogeochemical processes in the Eastern Nile Delta, Egypt. Hydrogeochemical and isotopic study has been carried out for 61 water samples from the study area. Total dissolved solid (TDS) contents of groundwater are highly variable rising along flowpath from the south (410 mg/L) to the north (14,784 mg/L), implying significant deterioration and salinization of groundwater. Based on TDS and ionic ratios, groundwater samples were classified into three groups. In low-saline groups, water chemistry is greatly influenced by cation exchange, mineral dissolution/precipitation, anthropogenic pollutants and mixing with surface water. Whilst, in high-saline groups, water chemistry is affected by salt-water intrusion, reverse cation exchange and evaporation. The chemical constituents originating from saline water sources, reverse ion exchange and mineral dissolution are successfully differentiated using ionic delta and saturation index approaches. The δ18O–δ2H relationship plots on a typical evaporation line, suggesting potential evaporation of the recharging water prior to infiltration. Isotope evidence concludes that the groundwater have been considerably formed by mixing between depleted meteoric water recharged under different climatic conditions and recently infiltrating enriched surface water and excess of irrigation water. The δ18O data in conjunction with chloride concentrations provide firm evidence for impact of dissolution of marine-origin evaporite deposits, during past geologic periods, on groundwater salinity in the northern region. Moreover, the relation between 14C activities and Cl? concentration confirms this hypothesis.  相似文献   

4.
Aquifer-based groundwater quality assessment offers critical insight into the major hydrochemical processes, and aids in making groundwater resources management decisions. The Texas Rolling Plains (TRP), spanning over 22 counties, is a major agro-ecological region in Texas from where highest groundwater nitrate (NO3 ?) levels in the state have been reported. In this study, we present a comparative assessment of major hydrochemical facies pertaining to NO3 ? contamination and a host of species such as sulfate (SO4 2?), chloride (Cl?), and total dissolved solids (TDS) in different water use classes in the Seymour and Blaine aquifers, underlying the TRP. Aquifer-stratified groundwater quality information from 1990 to 2010 was obtained from the Texas Water Development Board and aggregated over decadal scale. High groundwater salinization was found in the municipal water use class in the Blaine aquifer with about 100, 87 and 50 % of observations exceeding the secondary maximum contaminant level for TDS, SO4 2?, and Cl?, respectively in the 2000s (2000–2010). The NO3-contamination was more alarming in the Seymour aquifer with 82 and 61 % of observations, respectively, exceeding the maximum contaminant level (MCL) in the irrigation and municipal water use classes in the 2000s. Salinization was more influenced by SO4 2? and Cl? in the Blaine aquifer and by NO3 ? in the Seymour aquifer. High NO3 ? (>MCL) observations in the Seymour aquifer occurred in the Ca–HCO3 and Ca–Mg–HCO3 facies, the domains of fresh water recharge and anthropogenic influences (e.g., agricultural activities, waste disposal). High SO4 2?, Cl? and TDS observations in the Blaine aquifer dominated the Ca–Cl, Na–Cl, and mixed Ca(Mg)–SO4(Cl) facies indicating evaporite dissolution, mixing and solute exchange, and lack of fresh recharge.  相似文献   

5.
The carbonate aquifers of Lora and Mingo form part of the hydrogeological unit of Sierra de Estepa (SE Spain). By means of time series analysis and a 1D numerical groundwater model, groundwater exploitation was quantified and the mean annual recharge in both systems was estimated (2001–2004). During this period, the Lora and Mingo aquifers received an average groundwater recharge of 0.29 × 106 m3/year and 0.14 × 106 m3/year, respectively, whereas an average of 0.34 × 106 m3/year and 0.21 × 106 m3/year, respectively, was extracted. These conditions led to a conspicuous lowering of the water table in both systems. In addition, the analysis of the evolution of the main hydrogeochemical parameters of the groundwater showed that the increased pumping rates produced an increase in total dissolved solids, and chloride and sodium ions in both aquifers. In the case of the Lora aquifer, the only ion that presented decreased levels was nitrate. The results show that groundwater pumping in both aquifers should not exceed the mean annual recharge of 0.29 × 106 m3/year and 0.14 × 106 m3/year in the Lora and Mingo aquifers, respectively. Nevertheless, it would be advisable to reduce pumping rates to below these values in order to restore piezometric levels and improve groundwater quality for different uses in the future.  相似文献   

6.
The 1,750-km2 endorheic Honey Lake basin (California–Nevada, USA) was part of the 22,000-km2 Pleistocene Lake Lahontan pluvial lake system which existed between 5,000 and 40,000 years BP. The basin consists of two subbasins separated by a low elevation divide. Groundwater in the western subbasin has a maximum total dissolved solids (TDS) content of only ～1,300 mg/L; however eastern subbasin groundwater has a maximum TDS of ～46,000 mg/L. This TDS distribution is unexpected because 94% of surface water TDS loading is to the western subbasin. In situ reactions and upwelling thermal groundwater contributing to groundwater chemistry were modeled using NETPATH. The TDS difference between the subbasins is attributed to post-Lake Lahontan isostatic rebound about 13,000 years ago. Prior to rebound the subbasins did not exist and the low point of the basin was in the eastern area where hydraulic isolation from the larger Lake Lahontan and frequent desiccation of the basin surface water resulted in evaporite mineral deposition in accumulating sediments. After rebound, the terminal sink for most surface water shifted to the western subbasin. Although most closed basins have not been impacted by isostatic rebound, results of this investigation demonstrate how tectonic evolution can impact the distribution of soluble minerals accumulating in shallow basins.  相似文献   

7.
Groundwater pumped from the semi-confined Complex Terminal (CT) aquifer is an important production factor in irrigated oases agriculture in southern Tunisia. A rise in the groundwater salinity has been observed as a consequence of increasing abstraction from the aquifer during the last few decades. All sources of contamination were investigated using hydrochemical data available from the 1990s. Water samples were taken from wells tapping both the CT and the shallow aquifers and analyzed with regard to chemistry tracers. Hydrochemical and water quality data obtained through a sampling period (December 2010) and analysis program indicate that nitrate pollution can be a serious problem affecting groundwater due to the use of nitrogen (N) fertilizers–pesticides in agriculture. The concentration of nitrate in an groundwater-irrigated area in Gafsa oases basin was studied, where abstraction from an unconfined CT aquifer has increased threefold over 25 years to 34 million m3/year; groundwater levels are falling at up to 0.7 m/year; and groundwater is increasingly mineralised (TDS increase from 500 to 4,000 mg/L), with nitrate concentrations ranging from 16 to 320 mg/L.  相似文献   

8.
The future availability and sustainability of fresh groundwater resources in the South West district of the national capital territory (NCT) Delhi, India, have been projected. Due to a rapid decline in groundwater level and quality, the district has been required by the Government of India to regulate development of groundwater resources. Shallow groundwater is mostly saline and water resources in the area are limited. The methodology applied here involves microzonation of the district in terms of thickness of fresh groundwater and then quantification of present and future availability of freshwater in different freshwater zones, including tentative timescales. The calculation method has been aided by data on historic trends in water level at representative groundwater monitoring stations, located either in fresh groundwater zones or near to them. It is estimated that the presently available 481 million m3 of resources will be reduced to 374 million m3 by year 2007 and to 303 million m3 by the year 2012, and by the year 2022 the district will have only 176 million m3 of available fresh groundwater resources.  相似文献   

9.
Interactions between river water and groundwater have been used to help understand the movement of water and to evaluate water quality in the semi-arid area of the North China Plain (NCP). Stable isotopes, chlorofluorocarbons (CFCs) and hydrochemistry were used to study the influence of surface water from the Xiao River on regional groundwater. Using a mass balance approach based on chloride concentrations, hydrogen and oxygen isotope ratios, the average fraction of surface water recharging to groundwater was 50–60 %. CFC results indicated that the groundwater recharge age varied from 22.5 to 39.5 years. The vertical flow velocity of groundwater was estimated at about 1.8–3.5 m year?1. Nitrate concentrations in groundwater varied from 9.42 to 156.62 mg L?1, and exceeded 50 mg L?1 in most aquifers shallower than 80 m bordering the Xiao River. The δ 15N-NO3 data indicate that the major sources of nitrogen in groundwater are human sewage and animal excreta. Because groundwater is the main source of drinking water, there should be concern about public health related to the elevated nitrate concentrations in the NCP.  相似文献   

10.
Understanding the spatial distribution and variability of geochemical tracers is crucial for estimating groundwater influxes into a river and can contribute to better future water management strategies. Because of the much higher radon (222Rn) activities in groundwater compared to river water, 222Rn was used as the main tracer to estimate groundwater influxes to river discharge over a 323-km distance of the Big Sioux River, eastern South Dakota, USA; these influx estimates were compared to the estimates using Cl? concentrations. In the reaches overall, groundwater influxes using the 222Rn activity approach ranged between 0.3 and 6.4 m3/m/day (mean 1.8 m3/m/day) and the cumulative groundwater influx estimated during the study period was 3,982–146,594 m3/day (mean 40,568 m3/day), accounting for 0.2–41.9% (mean 12.5%) of the total river flow rate. The mean groundwater influx derived using the 222Rn activity approach was lower than that calculated based on Cl? concentration (35.6 m3/m/day) for most of the reaches. Based on the Cl? approach, groundwater accounted for 37.3% of the total river flow rate. The difference between the method estimates may be associated with minimal differences between groundwater and river Cl? concentrations. These assessments will provide a better understanding of estimates used for the allocation of water resources to sustain agricultural productivity in the basin. However, a more detailed sampling program is necessary for accurate influx estimation, and also to understand the influence of seasonal variation on groundwater influxes into the basin.  相似文献   

11.
The integration of the statistical approaches and GIS tools with the hydrogeological and geological contexts allowed the assessment of the processes that cause groundwater quality deterioration in the great important deltaic aquifer in the northeastern Tunisia (Medjerda Lower Valley Aquifer). The spatial variation of the groundwater parameters and the molar ratio (Cl?/Br?) were also used to determine the possible impacts from seawater intrusion and from the septic tank leachate. Sixty shallow groundwater samples were collected in 2014 and analyzed for major and trace ions over an area of about 1090 km2 to determine the suitability for drinking or agricultural purposes. The total dissolved solids (TDS) content ranges from 1005 to 19,254 mgl?1 with a mean value of 3477.18 mgl?1. The chemistry is dominated by the sodium–chloride waters (55%). Mapping of TDS, Cl?, Na+, SO42? and NO3? using kriging method shows a clear increase in salinity toward the coastline accompanied by Na+ and Cl? increase which may be related to seawater intrusion and halite dissolution. Locally, higher nitrate concentration is related to the agricultural activities inducing contribution of chemical fertilizers and irrigation with treated wastewater. The saturation indices indicate that all carbonate minerals tend to reach saturation equilibrium confirming water–rock interactions, while evaporitic minerals are still in sub-saturation state and may increase the salinity of the groundwater. The principal component analysis proves the occurrence of groundwater contamination principally by seawater intrusion in the factor I (74.15%) and secondary by an anthropogenic source in the factor II (10.35%).  相似文献   

12.
The Cuatrociénegas area is useful for the investigation of the effect of groundwater extraction in the Chihuahuan freshwater xeric ecoregion. It has been investigated at this time using a selection of geochemical indicators (major, minor and trace elements) and δ34S data, to characterize the origin of groundwater, the main geochemical processes and the mineral/groundwater interactions controlling the baseline geochemistry. The area is composed of limestones of Mesozoic age, with a composite thickness of about 500 m, overlaid by basin fill (poorly consolidated young sediments). Substantial water extraction and modification of natural discharges from the area along the last century have produced a detrimental impact on ecosystem structure and function. Water–rock interactions, mixing and evaporative processes dominate the baseline groundwater quality. Natural recharge is HCO3–Ca type in equilibrium with calcite, low salinity (TDS?<?500 mg/L), Cl? lower than 11 mg/L and average Li+ concentration of 0.005 mg/L. Along the groundwater flow systems, δ34S evidence and mass transfer calculations indicate that Cretaceous gypsum dissolution and dedolomitization reactions adjust water composition to the SO4–Ca type. The increase of water–rock interaction is reflected by Cl? values increase (average 68 mg/L), TDS up to about 1500 mg/L and an average Li+ concentration of 0.063 mg/L. Calculations with chemical geothermometers indicate that temperature at depth could be at maximum of 15–20 °C higher than field-measured temperature for pozas. After groundwater is discharged to the surface, chemical evolution continues; water evaporation, CO2 degassing and precipitation of minerals such as gypsum, calcite and kaolinite represent the final processes and reactions controlling water chemical composition.  相似文献   

13.
This paper gives an account of the assessment and quantification of the water balance and the hydrogeological processes related to lake–groundwater interaction in the Pampa Plain by using hydrogeochemical, isotopic and flow numerical modeling techniques. La Salada is a permanent shallow lake, with an area of 5.8 km2, located on the SE of Buenos Aires Province. A total of 29 lake water samples and 15 groundwater samples were collected for both hydrochemical analysis and environmental stable isotope determination. Water table depths were measured in wells closed to the lake. Groundwater samples appear grouped on the Local Meteoric Water Line, suggesting a well-mixed system and that rainfall is the main recharge source to the aquifer. Water evaporation process within La Salada is also corroborated by its isotopic composition. The model that best adjusts to La Salada Lake hydrochemical processes includes evaporation from groundwater, calcite precipitation with CO2 release and cationic exchange. The annual water balance terms for the lake basin indicates for each hydrological component the following values: 1.16 E08 m3 rainfall, 8.15 E07 m3 evapotranspiration, 1.90 E06 m3 runoff, 1.55 E07 m3 groundwater recharge, 6.01 E06 m3 groundwater discharge to the lake, 9.54 E06 m3 groundwater discharge to the river, 5.00 E05 m3 urban extraction and 4.90 E06 m3 lake evaporation. Integrated analysis of hydrochemical and isotopic information helped to calibrate the groundwater flow model, to validate the conceptual model and to quantitatively assess the basin water balance.  相似文献   

14.
应用对应分析方法处理地下水质资料,得出研究区地下水具有如下三种类型:(1)低矿化的弱碱性水;(2)相对高矿化的碱性甚至强碱性水;(3)介于上述两者之间。并由反馈信息得出,现有水质监测点似多了些。根据具体的水质特征,遵照反映不同水环境的监测点应保留、而反映相同或相似水环境的监测点应精简这一原则,对现有水质监测网作了优化分析。新的水质监测点数虽少于原有的,但只要定期的监测,仍能够反映原有水质监测网所能反映的主要信息。  相似文献   

15.
The Ordos Basin of China encompasses Shaanxi, Gansu, and Shanxi provinces, Ningxia and Inner Mongolia autonomous regions. It lacks significant surface water resources. Among the water-bearing formations, the Luohe formation, with an area of 1.32×105 km2, is the most prospective aquifer. Groundwater quality data collected at 211 boreholes drilled into the Luhe formation indicate a complex distribution of groundwater chemistry. The hydrochemical properties were used to study the recharge, runoff, and discharge conditions of the groundwater in Ordos Basin and to evaluate sustainable groundwater resources. In the northern part of the basin, the hydrochemistry types and the total dissolved solids (TDS) show a clear lateral transition from SEE to NWW, indicating that the groundwater gets recharge in the northwest region and discharges in the southeast region. In the southern part of the basin, maximum TDS occurs at the center of the Malian River valley, from which the TDS decreases radially. Therefore, the groundwater in the southern basin gets recharge from the southeast and southwest regions, and the Malian River valley is the discharge zone. As a result of this research, the areas with portable groundwater were delineated. They include most of the southeast region of the Sishili Ridge, east of the Ziwu Mountain, and the southwest corner of the basin. The TDS of the groundwater in these regions is less than 1 g/l, and the hydrochemistry type is either HCO3 or HCO3·SO4.  相似文献   

16.
Hydrogeochemical investigation of groundwater has been carried out in the coastal aquifers of southern Tamil Nadu, India. Seventy-nine dug well samples were collected and analyzed for various physicochemical parameters. The result of the geochemical analysis indicates the groundwater in the study area is slightly alkaline with moderate saline water. The cation and anion concentrations confirm most of the groundwater samples belong to the order of Na+ > Mg2+ > Ca2+ > K+ and Cl? > SO4 2? > HCO3 ?. Thereby three major hydrochemical facies (Ca–Cl, mixed Ca–Mg–Cl and Na–Cl) were identified. Based on the US Salinity diagram, majority of the samples fall under medium to very high salinity with low to high sodium hazard. The cross plot of Ca2+ + Mg2+ versus chloride shows 61 % of the samples fall under saline water category. Higher EC, TDS and Cl concentrations were observed from Tiruchendur to Koodankulam coastal zone. It indicates that these regions are significantly affected by saltwater contamination due to seawater intrusion, saltpan deposits, and beach placer mining activities.  相似文献   

17.
3H, δ13C and hydrochemical data were used to estimate the corrected groundwater age derived from conventional 14C age of dissolved inorganic carbon (DIC). The Middle-Upper Devonian aquifer system from the Baltic upland recharge area in eastern Lithuania towards the discharge area on the Baltic Sea coast in the west was considered. The concentration of total dissolved solids (TDS) in groundwater changes from 300 to 24,000  mg/L and increases downgradient towards the coast. The other major constituents have the same trend as the TDS. The hydrochemical facies of groundwater vary from an alkali-earth carbonates facies at the eastern upland area to an alkali-earth carbonate-sulfate and chloride facies at transit and discharge areas. Meteoric water percolating through the Quaternary and Devonian aquifers regulate the initial 14C activities of groundwater involving two main members of DIC: soil CO2 with modern 14C activity uptake and dissolution of 14C-free aquifer carbonates. Other sources of DIC are less common. 14C activity of DIC in the groundwater ranged from 60 to 108 pMC at the shallow depths. With an increase of the aquifers depth the dolomitization of aqueous solution and leakage of the “old” groundwater from lower aquifers take place, traced by lower activities (7–30 pMC).  相似文献   

18.
The present study was carried out in Singrauli area of the north India to know the water quality at selected sites. Physico-chemical parameters like pH, total dissolved solids (TDS), bicarbonate, hardness, calcium, magnesium, sodium, potassium, chloride, sulfate, copper, iron, cobalt, manganese, zinc, and chromium were analyzed in 27 water samples. Locations selected for sampling were based on the preliminary field survey carried out to understand the overall impact of mining and industrialization on the surface and groundwater resources of Singrauli. Base map, drainage map, and land use/land cover of the study area were prepared from Survey of India topographic map 63 L/12 on 1:50000 scale and satellite data of IRS P6 LISS III 4th May 2010. Land use were categorized into 15 categories out of which major area occupied by open forest covers 20.33 %, uncultivated land 20.25 %, cultivated land 12.60 %, dense forest 11.00 %, and other categories cover 35.82 %. The results obtained are compared with World Health Organisation standards for drinking water quality. The physico chemical analysis shows alkaline nature of water, soft to moderately soft, TDS and total alkalinity exceeds the desirable limit. The major ions in water like calcium, and magnesium are within desirable limits, and sulfate and potassium exceed in limit at some locations, whereas sodium and chloride show higher values. The minor ions like copper and zinc show values within desirable limits whereas iron, cobalt, and chromium show higher values than the desirable limits which deteriorate the quality of water.  相似文献   

19.
The Baiyu Mountain area has the most shortage of water in the Ordos Basin of China. The majority of the groundwater is in the Luohe water-bearing formation, which is characterized by high total dissolved solids (TDS). The concentration of TDS can be as high as 10.45 g/l, which makes the water unsuitable for either potable or irrigation purpose. The dominant ions in the groundwater are SO2–4·Cl–. The maximum concentrations of SO2–4 and Cl– are 3,170 and 3,830 mg/l, respectively. The areas with low TDS groundwater are in Jingbian and Zhidan counties. However, nitrogen pollution caused by human and agriculture activities is a significant threat to the protection of fresh water in these counties.  相似文献   

20.
Recognition of the temporal and spatial variations in groundwater levels and quality has become a prerequisite of formulating strategies for the sustainable development and utilization of water resources. In this study, data were obtained from 51 observation wells of depth to groundwater from 1999 to 2008 and 30 sampling wells of hydrochemical characteristics of groundwater in the Minqin oasis. The Kolomogorov–Semirnov test revealed that all data followed normal or log-normal distribution. A set of well-structured semivariograms also confirmed that the data had moderate (only for Mg2+ and K+) or strong spatial dependence. Based on spatial distribution, maps drawn using the ordinary Kriging interpolation method in different periods, the declining trend of the groundwater table was found to have been relieved since 2007, with the mean water table dropping 4.65 m from 1999 to 2008. Spatial comparison results further showed that the variations in groundwater levels in Baqu and Quanshan were more evident than those in Huqu, with mean decline rates of 0.64, 0.93, and 0.41 m/year, respectively. The mean value of total dissolved solids (TDS) was 3.34 g/L, and the groundwater in 76.2 % of the study area was brackish (TDS ≥ 1.0 g/L). From south to north, the groundwater types can be classified into three obvious zones based on the major ion distributions: SO4 2?–HCO3 ?–Na+–Ca2+ type in Baqu, SO4 2?–Na+–Ca2+ type in Quanshan, and SO4 2?–C1?–Na+ type in Huqu. TDS increased from the 1970 to 2005 and gradually decreased thereafter.  相似文献   

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