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1.
The absolute cross-sections for the excitation of the 989 Å, 1027 Å, 7990 Å, 8446 Å, 1.1287 μm and 1.3164 μm multiplets of atomic oxygen by electron impact dissociation of O2 are reported. The radiative branching ratios for these transitions are calculated from these results and compared with the NBS compilation of Wiese et al. (1966) and the recent theoretical calculations of Pradhan and Saraph (1977). The cascade models of O+ radiative recombination and of electron-impact excitation of the OI(3S) state in the terrestrial airglow are discussed in the light of the laboratory measurements, and the effects of the resonant absorption of components of the λ 989 Å and λ. 1027 Å multiplets by the Birge-Hopfield band system of N2 are investigated. This process is shown to depend sensitively on the N2 vibrational temperature and to cause characteristic changes in the OI e.u.v. emission spectrum in auroras and in the sunlit F-region at high exospheric temperatures. It is also suggested that the λ 1027 Å radiation observed in auroral spectra is actually due to molecular nitrogen band emission that has been enhanced by entrapment effects and not to the excitation of the 2p 3P-3d 3D0 transition of atomic oxygen as believed previously.  相似文献   

2.
We have investigated the role of several ion-molecule reactions in the conversion of N2O5 to HNO3. In the proposed conversion, an N2O5 molecule would react with an H2O molecule clustered to an inert ion to produce two HNO3 molecules. Subsequent clustering of an H2O molecule to the inert ion would make the reaction catalytic. If such an ion-catalysed conversion of N2O5 to HNO3 occurs, it would probably play a role in the stratospheric chemistry at high latitudes in winter. In this paper we present reaction rate constant measurements made in a flowing afterglow apparatus for hydrated H3O+, H+(CH3CN)m (m = 1, 2, 3), and several negative ions reacting with N2O5. Slow rate constants were found for these ions for hydration levels that are predominant in the stratosphere. With the known stratospheric ion density, these slow rate constants preclude significant N2O5 conversion by ion-molecule reactions.  相似文献   

3.
This paper considers the classical method to determine the electron temperatures t 3,O, t 2,O and t 2,N from forbidden lines of the ions O++, O+, and N+, and investigates the influence of uncertainties in atomic data on the accuracy of the determined electron temperatures. The uncertainties in atomic data (the Einstein coefficients for spontaneous transitions and electron ionization cross-sections) are estimated as discrepancies between the values computed by various authors. The error in the electron temperature caused by uncertainties in the atomic data is found to increase with the growth in the electron temperature. At a temperature 10000 K, the errors in the electron temperatures t 3,O, t 2,N, and t 2,O do not exceed 1, 3, and 7%, respectively.  相似文献   

4.
Experimental results on fast ion collision with icy surfaces having astrophysical interest are presented. 252Cf fission fragments projectiles were used to induce ejection of ionized material from H2O, CO2, CO, NH3, N2, O2 and Ar ices; the secondary ions were identified by time-of-flight mass spectrometry. It is observed that all the bombarded frozen gas targets emit cluster ions which have the structure XnR±, where X is the neutral ice molecule and R± is either an atomic or a molecular ion. The shape of the positive or negative ion mass spectra is characterized by a decreasing yield as the emitted ion mass increases and is generally described by the sum of two exponential functions. The positive ion water ice spectrum is dominated by the series (H2O)nH3O+ and the negative ion spectrum by the series (H2O)nOH− and (H2O)nO−. The positive ion CO2 ice spectrum is characterized by R+ = C+, O+, CO+, O2+ or CO2+ and the negative one by R− = CO3−. The dominant series for ammonia ice correspond to R+ = NH4+ and to R− = NH2−. The oxygen series are better described by (O3)nOm+ secondary ions where m = 1, 2 or 3. Two positive ion series exist for N2 ice: (N2)nN2+ and (N2)nN+. For argon positive secondary ions, only the (Ar)nAr+ series was observed. Most of the detected molecular ions were formed by one-step reactions. Ice temperature was varied from ∼20 K to complete sublimation.  相似文献   

5.
Analysis of observed spectrograms is based on comparison with synthetic spectra. The O2(b1Σ+g?X3Σ?g Atm. (1,1) band in high latitude auroras observed from the ground is found to be the strongest in the Δv = 0 sequence. It is enhanced with altitude relative to the N2 1P(2, 0)and N+2 M(2,0) bands, but the O2 Atm. (2, 2) band has an unexpected low intensity. The range of rotational temperatures of the O2 Atm. bands varies from approx. 200 to above 500 K which indicates that the altitude of the centroid of the emission region varies from about 100 km to the F-region. The highest temperature is found in the midday aurora associated with the magnetospheric cusp. Conspicuous relative variations between the intensities of N2 and O2 spectra are documented, but a satisfactory explanation of the variety is not given. Deviations of the observed O2 Atm. band intensities from the vibrational intensity distribution predicted by Franck-Condor factors indicate that the excitation of the O2 Atm. bands in aurora is not mainly due to particle impact on O2, and the contribution due to energy transfer from hot O(1D) atoms has to be found in future research.  相似文献   

6.
The irregular galaxy M82 is known as the archetypal starburst galaxy. Its proximity (3.5 Mpc) makes this galaxy an ideal laboratory for studying the properties of its starburst. The detailed morphology of the [FeII] 1.644 μm and emission Paα (at 1.87 μm) is revealed by the NICMOS images. The peak of the 2.2 μm continuum brightness(evolved population) lies very close to the dynamical centre. Most of the Paα emission (which traces the young population) is distributed in a ring of star formation (with a `hole' lacking line emission at the centre of the galaxy). These observations support the scenario in which the starburst in M82 is propagating outwards. It has long been suggested that the [FeII] emission in starburst galaxies can be used as a measure of supernova (SN) activity. M82 shows a large number of radio supernova remnants (SNRs), approximately 50, lying in the plane of the galaxy. The comparison of the positions of the bright compact [FeII] emitting regions with the location of the radio SNRs shows that there is no one-to-one spatial correspondence between the two emissions, suggesting that the radio and [FeII] emissions trace two populations of SNRs with different ages. Young (a few hundred years) SNRs are best traced by their radio emission, whereas the [FeII] stage lasts for at least a few 104 yr. The compact [FeII] sources contribute only some 20 % of the total [FeII] emission observed in M82. However, much of the remaining unresolved [FeII] emission in the plane of the galaxy may arise from SNRs that expanded and merged into a general interstellar medium within a few 104 yr. Presumably, as much as 70% of the total extinction-corrected [FeII]1.644 μm in M82 is associated with SNRs. The extended and diffuse [FeII] component in M82 seems to be related with the superwind above and below the disc of the galaxy. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

7.
Fluorescence efficiencies of electrons in a large number of bands of the N2 First Positive and O2+ First Negative groups lying in the 4900–10,500 Å wavelength range have been investigated theoretically. The variation of transition moment with internuclear distance is taken into consideration. For the First Positive group of N2 the calculations are carried out at very low pressure as well as at 600 Torr. In general the present values are higher than the experimental values but in most of the cases fair agreement has been obtained. For the O2+ First Negative group no direct experimental data is available. However, the present ratio of the total efficiency in the O2+ First Negative group to the N2+ First Negative group is found to be in good agreement with the experimental intensity ratio.  相似文献   

8.
We analyze EUV spatially-resolved dayglow spectra obtained at 0.37 nm resolution by the UVIS instrument during the Cassini flyby of Venus on 24 June 1999, a period of high solar activity level. Emissions from OI, OII, NI, CI and CII and CO have been identified and their disc average intensity has been determined. They are generally somewhat brighter than those determined from the observations made with the HUT spectrograph at a lower activity level, We present the brightness distribution along the foot track of the UVIS slit of the OII 83.4 nm, OI 98.9 nm, Lyman-ß + OI 102.5 nm and NI 120.0 nm multiplets, and the CO C-X and B-X Hopfield-Birge bands. We make a detailed comparison of the intensities of the 834 nm, 989 nm, 120.0 nm multiplets and CO B-X band measured along the slit foot track on the disc with those predicted by an airglow model previously used to analyze Venus and Mars ultraviolet spectra. This model includes the treatment of multiple scattering for the optically thick OI, OII and NI multiplets. It is found that the observed intensity of the OII emission at 83.4 nm is higher than predicted by the model. An increase of the O+ ion density relative to the densities usually measured by Pioneer Venus brings the observations and the modeled values into better agreement. The calculated intensity variation of the CO B-X emission along the track of the UVIS slit is in fair agreement with the observations. The intensity of the OI 98.9 nm emission is well predicted by the model if resonance scattering of solar radiation by O atoms is included as a source. The calculated brightness of the NI 120 nm multiplet is larger than observed by a factor of ∼2-3 if photons from all sources encounter multiple scattering. The discrepancy reduces to 30-80% if the photon electron impact and photodissociation of N2 sources of N(4S) atoms are considered as optically thin. Overall, we find that the O, N2 and CO densities from the empirical VTS3 model provide satisfactory agreement between the calculated and the observed EUV airglow emissions.  相似文献   

9.
It is proposed that energy transfer from excited O2 contributes to the production of O(1S) in aurora. An analysis is presented of the OI5577 Å emission in an IBC II+ aurora between 90 and 130 km. The volume emission rate of the emission at these altitudes is consistent with the production rate of O(1S) by energy transfer to O(3P) from N2 in the A3Σ2+ state and O2 in the A3Σu+, C3Δc1Σu? states, the N2A state being populated by direct electron impact excitation and B → A cascade and the excited O2 states by direct excitation. Above the peak emission altitude (~105 km), energy transfer from N2A is the predominant production mechanism for O(1S). Below it, the contribution from quenching of the O2 states becomes significant.  相似文献   

10.
Laboratory cross-section data on the excitation of the OII(2s 2p44P → 2s2 2p34S; λ834 Å) resonance transition and on the production of O+ and O2+ ions by electron impact on atomic oxygen are used to show that the ratio σ(λ834 A?)σ(O+ + O2+) is nearly constant for incident electron energies > 50 eV. Under auroral conditions, the total electron-ion pair production rate from electron impact on O can be inferred from λ834 Å volume emission rate measurements using the result that η(O+ + O2+)$?8.4η(λ834 A?). These findings, along with earlier work on the simultaneous ionization-excitation of the 1 Neg (0,0) band of N2+ and the 1 Neg (1, 0) band of O+2, allow the specific ionization rates for the principal atmospheric constituents (O+, O+2, N+2), for the multiply-ionized species (O2+, O2+2, N2+2), and for the dissociatively produced atomic ions to be inferred in aurora from remote satellite observations.  相似文献   

11.
The evolution and variability of atmospheric ozone over geological time   总被引：1，自引：0，他引：1  
The rise of atmospheric O3 as a function of the evolution of O2 has been investigated using a one-dimensional steady-state photochemical model based on the chemistry and photochemistry of Ox(O3, O, O(1D)), N2O, NOx(NO, NO2, HNO3), H2O, and HOx(H, OH, HO2, H2O2) including the effect of vertical eddy transport on the species distribution. The total O3 column density was found to maximize for an O2 level of 10?1 present atmospheric level (PAL) and exceeded the present total O3 column by about 40%. For that level of O2, surface and tropospheric O3 densities exceeded those of the present atmosphere by about an order of magnitude. Surface and tropospheric OH densities of the paleoatmosphere exceeded those of the present atmosphere by orders of magnitude. We also found that in the O2-deficient paleoatmosphere, N2O (even at present atmospheric levels) produces much less NOx than it does in the present atmosphere.  相似文献   

12.
The nitrogen isotope ratio of middle atmosphere nitrogen oxide is predicted as a function of altitude. Nitrogen oxides originate photochemically either from stratospheric nitrous oxide reacting with O(1D) or in the mesosphere and thermosphere from direct dissociation of N2 and ionization-initiated reactions involving O2 and N2. During its formation process, N2O acquires a nitrogen isotopic composition of N isotopes different than N2. Photodissociation within the stratosphere also modifies the proportion of isotopes. Reaction of stratospheric NO with O3 produces NO2, which when photodissociated yields NO depleted in 15N relative to NO2 in laboratory air. The value of δ15NO in the stratosphere is −100‰. In the altitude region between 50 and 65 km, NO is transformed into NO2 and then returned to NO by reaction of NO2 with O and by NO2 photodissociation. These reactions determine the isotopic makeup of NO. Above 65 km, nitric oxide is produced by local ionization processes and gas phase photochemical reactions involving N2 and excited O2. These processes determine the isotopic composition of NO in the upper mesosphere and thermosphere. Here δ15NO is 0‰. Air transported into the mesosphere above 65 km will reflect the NO isotopic values of the region below, while mesospheric NO transported below 65 km will not be distinguishable from NO originating in the stratosphere.  相似文献   

13.
We extend the microscopic approach developed for proton energy deposition in N2 to the general case of proton bombardment of a polar atmosphere composed of N2, O2 and O. We calculate the volume emission rates of various N2+, O2, O2+ and OI emissions that would be encountered in a typical PCA event. Our results demonstrate that the ratios of I(5577)I(3914) and I(6300)I(3914) are strongly depe spectra considered.  相似文献   

14.
The vertical distribution of thermospheric temperature was measured from molecular rotational intensity distributions, in a rocket flight through the aurora at Fort Churchill, Canada. Both the N2+ (1NEG; 0–1) and O2 (ATM ; 0-0) bands were used and a stepping mask photometer was employed to locate each filter passband at seven points on each molecular band. The N2+ temperature follows the appropriate Jacchia (1971) model fairly closely at all altitudes but is higher in temperature by about 60 K. The O2 temperatures follow the model results more closely but one cannot be sure whether the differences between the two sets of measured temperatures are real.  相似文献   

15.
New experimental techniques have yielded several thermal energy vibrational quenching rate constants for O2+(v). Rates for quenching of O2+(v = 1) by O2, N2, Ar, CO2, H2, and CH4 are 3(?10), 2(?12), 1(?12), 1(?10), 2.5(?12), and 6(?10) cm3s?1 at 300 K. The quenching is somewhat faster for O2+(v = 2). The triatomic ions CO2+, NO2+, N2O+, SO2+, and H2O+ are all vibrationally deexcited with an efficiency greater than 10?3 in Ar or Ne collisions. A theoretical rationalization of the experimental results leads to the prediction that vibrational quenching in planetary atmospheres will generally be efficient, k > 1(?12) cm3s?1 for almost all ion and neutral gas pairs.  相似文献   

16.
Rate coefficients for the association reactions of NO+ ions with N2 and CO2, O2+ with N2, and N+ and N2+ with N2 have been determined as a function of gas temperature in a laboratory experiment employing a variable-temperature drift-tube apparatus. The measured rate coefficients were fitted to power laws of the form k = C (T300)x where the exponents x ranged from 2.2 to 4.3. The strong temperature dependence observed in the case of the reaction of NO+ with N2 (x = 4.3) supports the thesis by Arnold et al. (1979) that the temperature variability of D-region ion densities is a result of this reaction step in the ion clustering sequence.  相似文献   

17.
The high electron temperatures existing within SAR-arcs can result in enhanced vibrational excitation of atmospheric N2 molecules and, as a consequence, increase the rate coefficient of the reaction, O+ + N2 → NO+ + N. This results in a change in the relative abundance of O+ and NO++ in the SAR-arc region compared with that in the undisturbed ionosphere. Theoretical ion density profiles were computed by a triple ion analysis solving the mass, momentum and energy equations for O+, NO+ and O+2 ions self-consistently. Although the electron temperature dependence of the recombination rate of NO+ is not well known, the results show that for a range of expected recombination rates NO+ still remains the dominant ion up to ca. 320 km at night within a bright SAR-arc. Studies were also made of the relative importance of a downward O+ flux and an upward ion drift in maintaining the F-region under SAR-arc conditions. It was found that the upward drift caused a marked increase in the NO+/O+ transition altitude as high as 460 km at night. However, for typical drift speeds up to 50 m sec?1 the peak electron density was lower than experimental observations. The effect of a large, short-duration perpendicular electric field on the SAR-arc ion and electron density profiles was found to be small. In all cases considered the magnitude of the enhanced NO+ density as a result of vibrationally excited N2 molecules was sufficient to prevent the electron density within the night-time SAR-arc from becoming vanishingly small.  相似文献   

18.
The absolute reaction cross sections and reaction rate coefficients as a function of photoionisation energy for 25 ion-molecule reactions (charge transfer reactions except for one) have been measured between the most abundant species present as ions or neutral in the Mars, Venus and Earth ionospheres: O2, N2, NO, CO, Ar and CO2.This study shows the strong influence of electronic as well as vibrational internal energy on most ion-molecule reactions. In particular endothermic charge transfer reactions are driven by electronic excitation of O2+ and NO+ ions in their a4Πu and a3Σ+ metastable states, respectively. Moreover, it is shown that lifetimes of these metastable states are sufficient to survive the mean free path in the lowest part of ionospheres and therefore express their enhanced reactivity. The reactions of O2+ with NO as well as the reactions of CO2+ with NO, O2, CO and to a less extent N2 are driven by vibrational excitation. N2+ and CO+ reactions vary much less with photon energy than the other ones, except for the case of reactions with Ar. The effects of the molecular ion internal energy content on their reactivity must be included in the ionospheric models for most of the reactions investigated in the present work. It is also the case for the effect of collision energy on the CO++M reactions as we expect that a significant proportion of these CO+ could be produced with translational energy by dissociation of doubly charged CO22+, in particular in the Mars ionosphere. Recommended effective rate constant values are given as a function of VUV photon energy.  相似文献   

19.
Auroral ultraviolet spectra in the range 1200–3200 A have been obtained by the spectrometer onboard the OGO-4 satellite. Emissions of N2, H, O and N are readily identified. Atomic and molecular intensities are deduced from the comparison with a synthetic spectrum and compare reasonably well with some previous measurements and calculations. A feature at 2150 A is assigned to the (1-0) NO γ band. Taking into consideration the various excitation mechanisms of NO(A2σ) we propose that the energy transfer from N2 metastable molecules to oxygen accounts for the excitation of the NO γ bands. In particular, we suggest that the resonant reaction between O2 and highly metastable N2(W3Δ) molecules may be a major source of NO(A2σ).  相似文献   

20.
The quenching rate kN2 of O(1D) by N2 and the specific recombination rate α1D of O2+ leading to O(1D) are re-examined in light of available laboratory and satellite data. Use of recent experimental values for the O(1D) transition probabilities in a re-analysis of AE-C satellite 6300 Å airglow data results in a value for kN2 of 2.3 × 10?11 cm3s?1 at thermospheric temperatures, in excellent agreement with the laboratory measurements. This implies a value of JO2 = 1.5 × 10?6s?1 for the O2 photodissociation rate in the Schumann-Runge continuum. The specific recombination coefficient α1D = 2.1 × 10?7cm3s?1 is also in agreement with the laboratory value. Implications for the suggested N(2D) + O2 → O(1D) + NO reaction are discussed.  相似文献   

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