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1.
Measurements of the [OI] 6300 Å twilight airglow during 1973 near Boulder, Colorado, show a strong dependence upon geomagnetic activity for the morning enhancement at solar depression angles where production of O1D) is due primarily to photodissociation of O2 and local photoelectron excitation. Analysis indicates that photodissociation is the dominant source; hence we infer a well defined magnetic dependence for the O2/N2 concentration ratio in the thermosphere. A seasonal variation in the twilight enhancement intensity is barely evident, in contrast with earlier observations made near solar maximum; the smaller variation is associated with a corresponding reduction in the seasonal variation of geomagnetic activity.  相似文献   

2.
Aircraft measurements of O2(1Δg) emission made over a 10-yr period provide information on the variation of ozone with latitude and season in the altitude region 50–90 km. Between 50 and 70 km there appears to be little variation (< ± 25%) whereas the abundance between 80 and 90 km exhibits a large seasonal change north of 30°N and much less at lower latitude. At mid and high latitude the column abundance above ～ 80 km changes from ? 1 × 1014 cm?2 in summer to about 3 × 1014 cm?2 in winter. There are occasional enhancements in both the day and twilight airglow which almost always occur in association with auroral activity or, at least, where such activity is statistically most likely. These enhancements appear to reflect a corresponding increase in the ozone mixing ratio in the upper stratosphere. While the gradient in ozone mixing ratio with latitude is generally small at altitudes between 50 and 90km there are occasions when a temporary latitude structure can be seen, particularly above 80 km.  相似文献   

3.
The Fabry-Perot interferometer on Dynamics Explorer 2 was used as a low sensitivity photometer to study the O2 Atmospheric A band during the daytime. A study of the brightness of the emission showed that the assumed source of O2(b1Σg+) in the thermosphere, O(1D), can account for the observed intensity up to about 250 km but with a significantly different scale height. This combined with an enhanced brightness above this altitude suggests an additional source for this emission.  相似文献   

4.
A major loss process for the metastable species, O+(2D), in the thermosphere is quenching by electrons
O+(2D) + e → O+(4S) + e
.To date no laboratory measurement exists for the rate coefficient of this reaction. Thermospheric models involving this process have thus depended on a theoretically calculated value for the rate coefficient and its variation with electron temperature. Earlier studies of the O+(2D) ion based on the Atmosphere Explorer data gathered near solar minimum, could not quantify this process. However, Atmosphere Explorer measurements made during 1978 exhibit electron densities that are significantly enhanced over those occurring in 1974, due to the large increases that have occurred in the solar extreme ultraviolet flux. Under such conditions, for altitudes ? 280 km, the electron quenching process becomes the major loss mechanism for O+(2D), and the chemistry of the N+2 ion, from which the O+(2D) density is deduced, simplifies to well determined processes. We are thus able to use the in situ satellite measurements made during 1978 to derive the electron quenching rate coefficient. The results confirm the absolute magnitude of the theoretical calculation of the rate coefficient, given by the analytical expression k(Te) = 7.8 × 10?8 (Te/300)?0.5cm3s?1. There is an indication of a stronger temperature dependence, but the agreement is within the error of measurement.  相似文献   

5.
It is proposed that energy transfer from excited O2 contributes to the production of O(1S) in aurora. An analysis is presented of the OI5577 Å emission in an IBC II+ aurora between 90 and 130 km. The volume emission rate of the emission at these altitudes is consistent with the production rate of O(1S) by energy transfer to O(3P) from N2 in the A3Σ2+ state and O2 in the A3Σu+, C3Δc1Σu? states, the N2A state being populated by direct electron impact excitation and B → A cascade and the excited O2 states by direct excitation. Above the peak emission altitude (~105 km), energy transfer from N2A is the predominant production mechanism for O(1S). Below it, the contribution from quenching of the O2 states becomes significant.  相似文献   

6.
Analysis of observed spectrograms is based on comparison with synthetic spectra. The O2(b1Σ+g?X3Σ?g Atm. (1,1) band in high latitude auroras observed from the ground is found to be the strongest in the Δv = 0 sequence. It is enhanced with altitude relative to the N2 1P(2, 0)and N+2 M(2,0) bands, but the O2 Atm. (2, 2) band has an unexpected low intensity. The range of rotational temperatures of the O2 Atm. bands varies from approx. 200 to above 500 K which indicates that the altitude of the centroid of the emission region varies from about 100 km to the F-region. The highest temperature is found in the midday aurora associated with the magnetospheric cusp. Conspicuous relative variations between the intensities of N2 and O2 spectra are documented, but a satisfactory explanation of the variety is not given. Deviations of the observed O2 Atm. band intensities from the vibrational intensity distribution predicted by Franck-Condor factors indicate that the excitation of the O2 Atm. bands in aurora is not mainly due to particle impact on O2, and the contribution due to energy transfer from hot O(1D) atoms has to be found in future research.  相似文献   

7.
Making use of the latest available semi-empirical atmospheric models, solar XUV radiations rates of photoionization and absorbed energy profiles have been graphically presented showing the latitudinal, seasonal and solar cycle variations. The photoionization limits of the major neutral constitutents of the terrestrial atmosphere O2, O, and N2 that occur at wavelengths 102.7, 91.2, and 79.6 nm, respectively have been quantified by showing the photoionization rates of O 2 + , O+, and N 2 + for different spectral groups both under quiet and different solar flare conditions. The variability of the photoionization efficiency parameter which is height-dependent, from winter to summer, for solar minimum to solar maximum for four significantly different latitudes under local noon conditions have been investigated during the solar cycle 21. More energy is required to produce an electron-ion pair in a denser atmosphere than in a thinner atmosphere and hence more energy is being deposited in the height range between 100–120 km which itself manifests in raising the electron gas temperatures higher than the neutral gas temperatures.  相似文献   

8.
The rate at which O(1S) is quenched in the atmosphere has been calculated as a function of altitude in the 75–115 km region. Recent measurements of the temperature-dependent O 2 quenching rate coefficient have been used, while for quenching by O(3P), an expression combining new theoretical and experimental results is employed. For the O(3P) altitude profile, the Jacchia (1971) model is chosen. The quenching profile shows a pronounced minimum quenching rate at about 87 km. It is concluded that different studies carried out on pulsating Type-B red aurorae, which extract an O(1S) quenching rate from the time lag between N 2+(B?X) emission and 5577-Åemission, can now be interpreted as indicating an altitude range for these aurorae of 84–89 km. This conclusion is in accord with observations made on artificial aurorae.  相似文献   

9.
This VIRTIS instrument on board Venus Express has collected spectrally resolved images of the Venus nightside limb that show the presence of the (0,0) band of the infrared atmospheric system of O2 at 1.27 μm. The emission is produced by three-body recombination of oxygen atoms created by photodissociation of CO2 on the dayside. It is consistently bright so that emission limb profiles can be extracted from the images. The vertical distribution of O2() may be derived following Abel inversion of the radiance limb profiles. Assuming photochemical equilibrium, it is combined with the CO2 vertical distribution to determine the atomic oxygen density. The uncertainties on the O density caused by the Abel inversion reach a few percent at the peak, increasing to about 50% near 120 km. We first analyze a case when the CO2 density was derived from a stellar occultation observed with the SPICAV spectrometer simultaneously with an image of the O2 limb airglow. In other cases, an average CO2 profile deduced from a series of ultraviolet stellar occultations is used to derive the O profile, leading to uncertainties on the O density less than 30%. It is found that the maximum O density is generally located between 94 and 115 km with a mean value of 104 km. It ranges from less than 1×1011 to about 5×1011 cm−3 with a global mean of 2.2×1011 cm−3. These values are in reasonable agreement with the VIRA midnight oxygen profile. The vertical O distribution is generally in good agreement with the oxygen profile calculated with a one-dimensional chemical-diffusive model. No statistical latitudinal dependence of the altitude of the oxygen peak is observed, but the maximum O density tends to decrease with increasing northern latitudes. The latitudinal distribution at a given time exhibits large variations in the O density profile and its vertical structure. The vertical oxygen distribution frequently shows multiple peaks possibly caused by waves or variations in the structure of turbulent transport. It is concluded that the O2 infrared night airglow is a powerful tool to map the distribution of atomic oxygen in the mesosphere between 90 and 115 km and improve future Venus reference atmosphere models.  相似文献   

10.
On 14 December 1971, during the maximum of the Geminid Meteor Shower, the positive ion composition was measured in the D- and E-regions above Sardinia. The payload was launched at 12:11 UT, and measurements were made between 68.5 and 152 km altitude. A magnetic sector type mass spectrometer with dual collector and a liquid helium cryopump was used. The instrument covered the mass range from 11 to 73 AMU and had a resolution at the 1 % level of M/ΔM = 60.In the E-region two distinct metal ion layers were observed, centred at 95 and 119 km, respectively. In the lower layer Fe+ and Mg+ were the most abundant metal ions, and in the upper layer Si+ was dominant. Si+ ions were conspicuously absent in the lower layer (Si+/Mg+ < 2 × 10−3). This particular behaviour of Si could be due to the inability of atomic oxygen to reduce SiO, whereas in the upper layer Si+ions might be formed directly by the charge rearrangement reaction SiO + O+ → Si++ O2. In addition, Na+, Al+, K+, Ca+, Ti+, Cr+, Ni+ and Co+ were also identified. The metal oxide ions AlO+ and SiO+ were detected, and probably also MgO+ and SiOH+. The concentrations of NO+ and O2+ show a deep minimum at the maximum of the lower metal ion layer. A very high neutral metal density of 6 × 107 cm−3 would be required to explain this feature as resulting from charge transfer reactions between the molecular and metal ions Such a high metal density is in contradiction to direct measurements and to cosmic dust influx rates. The isotopic ratios of Mg+, Si+, and of the major isotopes of Fe+ and Ni+ were measured, some of them with an accuracy of a few per cent (25Mg+/24Mg+ = 0.124 ± 0.006; 26Mg+/24Mg+ = 0.139 ± 0.008; 29Si+/28Si+ = 0.050 ± 0.004; 54Fe+/56Fe+ = 0.069 ± 0.005; 57Fe+/56Fe+ = 0.029 ± 0.004; 60Ni+/58Ni+ = 0.31 ± 0.12). The isotopic ratios agree within the experimental errors with the corresponding terrestrial ratios, thus giving evidence that these elements have the same isotopic composition in the Geminid meteors as in the Earth's crust, in chrondrites, and in lunar material.In the D-region the ions Na+H2O, Na+(H2O)2, NaO+ and NaOH+ were tentatively identified. Below 95 km altitude the relative abundances of the ions 32+, 33+ and 34+ deviate from the values expected for molecular oxygen isotopes. Their abundances can not be explained by the presence of S-ions only, and we conclude that HO2+ and H2O2+ are present.The ion density profiles of the major D-region constituents show some remarkable deviations from typical D-region conditions. These deviations are related to the winter anomaly in ionospheric absorption observed over Spain during the launch day, and our data represent the first ion composition measurements during such conditions. In particular, H+(H2O)2 is the major ion only up to 77 km, and at 80 km altitude the NO+ concentration exceeds the total water cluster ion density by almost two orders of magnitude. An increase of the mesospheric NO, O3 and O concentrations as well as of the O/H2O ratio could explain the observed ion profiles. The low NO+/O2+ ratios of approximately unity measured in the E-region are in agreement with a strong downward transport of NO and/or O into the mesosphere during the launch day. A simple four-ion model was used to interpret our D-region data. The calculated neutral NO concentration increases from about 2 × 107 cm−3 at 85 km to 5 × 107 cm−3 at 80 km. In addition, evidence for an increased O2+ production rate above 83 km was found, probably due to an enhanced O3 concentration. We conclude that our data strongly support vertical transport of minor neutral consituents as cause of the winter anomaly.  相似文献   

11.
W-H. IP  D.A. Mendis 《Icarus》1976,28(3):389-400
  相似文献   

12.
A simple vibrational relaxation model which reproduces the observed altitude integrated vibrational distribution of the Herzberg I bands in the nightglow is used to derive the altitude profiles of the individual vibrational levels at 1 km intervals in the 85–115 km height range. The possible errors associated with using rocket-borne photometer measurements of a limited number of bands in the O2(A3Σu+?X3Σg?) system to infer the total Herzberg I emission profile are assessed.  相似文献   

13.
A magnetic type mass spectrometer has been flown on two ESRO sounding rockets from ESRANGE (Kiruna 68°N) on February 25 and 26, 1970. The first launch was at sunset (16:33 UT) and the second the next morning, during sunrise (04:47 UT). For both flights the solar zenith angle was approximately 98°. The instrument was measuring simultaneously the neutral gas and positive ion composition and the total ion density. In this paper the results of the ion composition measurements are presented. For both flights the main ion constituents measured between approximately 110–220 km were O+, NO+ and O2+. Only at sunset were N+ and N2+ detected above 200 km. In spite of the identical solar UV-radiation, pronounced sunset/sunrise variations in the positive ion composition were found. The total ion densities at sunrise were between 5×103 and 5 × 104 ions cm?3 and therefore too high to be explained without a night-time ionization by precipitated particles. At sunrise the NO+ and O2+ profiles show a correlated wavelike structure with three pronounced almost equally spaced layers in the E-region. Only the highest layer is present in the O+ profile. Locally enhanced field aligned ionization originated by particle precipitation and an E × B instability are the most likely source for this structure. In the E- and lower F-regions the NO+O2+ ration increased overnight from values around 7 at sunset to 15 at sunrise, correlated with an increase of the local magnetic activity index K from 0+ to 2°. This could be explained if the NO density and magnetic activity are correlated.  相似文献   

14.
The Plasma Experiment for Planetary Exploration (PEPE) made detailed observations of the plasma environment of Comet 19P/Borrelly during the Deep Space 1 (DS1) flyby on September 22, 2001. Several distinct regions and boundaries have been identified on both inbound and outbound trajectories, including an upstream region of decelerated solar wind plasma and cometary ion pickup, the cometary bow shock, a sheath of heated and mixed solar wind and cometary ions, and a collisional inner coma dominated by cometary ions. All of these features were significantly offset to the north of the nucleus-Sun line, suggesting that the coma itself produces this offset, possibly because of well-collimated large dayside jets directed 8°-10° northward from the nucleus as observed by the DS1 MICAS camera. The maximum observed ion density was 1640 ion/cm3 at a distance of 2650 km from the nucleus while the flow speed dropped from 360 km/s in the solar wind to 8 km/s at closest approach. Preliminary analysis of PEPE mass spectra suggest that the ratio of CO+/H2O+ is lower than that observed with Giotto at 1P/Halley.  相似文献   

15.
The thickness of the peak of the ionosphere depends primarily on the temperature T n of the neutral gas, and corresponds approximately to an α-Chapman layer at a temperature of 0.87T n. The overall slab thickness, as given by Faraday rotation measurements, is then τ =0.22 n + 7km. Expansion of the topside ionosphere, and changes in the E-andFl-regions increase τ by about 20 km during the day in summer. Near solar minimum τ is increased by a lowering of the O +/H + transition height; if the neutral temperature T n is estimated, this height can be obtained from observed values of τ.Hourly values of slab thickness were determined over a period of 6 yr at 34°S and 42°S. Near solar maximum the night-time values were about 260 km in all seasons. The corresponding neutral temperatures agree with satellite drag values; they show a semiannual variation of 14 per cent and a seasonal change of 5 per cent. Daytime values of τ were about 230 km in winter and 320 km in summer, implying a seasonal change of 30 per cent in T n. Temperatures increase steadily throughout the day in all seasons, with a rapid post-sunset cooling in summer. Downwards movements produce a large peak in τ at 0600 hr in winter. A large upwards flux, equal to about 40 per cent of the maximum (limiting) value, reduces τ for several hours after sunrise in winter. The slab thickness increases near solar minimum showing a reduction of the O +/H + transition height to about 700 km in summer and 500 km in winter.  相似文献   

16.
The temporal response of ion and neutral densities to a geomagnetic storm has been investigated on a global scale with data from consecutive orbits of OGO-6 (>400km) for 4 days covering both magnetically quiet and disturbed conditions. The first response of the neutral atmosphere to the storm takes place in the H and He densities which start to decrease near the time of the storm sudden commencement. The maximum decreases in H and He were more than 40% of the normal density at high latitudes. A subsequent increase in O and N2 densities occurs about 8 hours later than the change in H and He densities, while the relative O and N2 density changes indicate a depletion of atomic oxygen in the lower thermosphere by more than a factor of two. The overall features of the change in the neutral atmosphere, especially the patterns of change for individual species, strongly support the physical picture that energy is deposited primarily at high latitudes during the storm, and the thermosphere structure changes through (1) heating of the lower thermosphere and (2) generation of large scale circulation in the atmosphere with upwelling at high latitudes and subsidence at the equator. The storm-time response of H+ occurs in two distinct regions separated by the low latitude boundary of the light ion trough. While on the poleward side of the boundary the H+ density decreases in a similar manner to the decrease in H density, on the equatorward side of the boundary the H+ decrease occurs about half a day later. It is shown that the decrease of H+ density is principally caused by the decrease in H density for both regions. The difference in H+ response between the two regions is interpreted as the difference in H+ dynamics outside and inside the plasmasphere. The O+ density shows an increase, the pattern of which is rather similar to that for O. Two possibilities for explaining the observed change in O+ density are suggested. One attributes the observed increase in O+ density to an increase in the plasma temperature during the storm. The other possibility is that the increase in the production rate of O+ due to an increase in O density exceeds the increase in the loss rate of O+ due to an increase in N2 density, especially around the time of sunrise. Hence the change in O+ density in the F-region may actually be controlled by the change in O density.  相似文献   

17.
An empirical model of thermospheric temperature (T∞T120, and s) and composition (H, He, N, O, N2, O2, and Ar) was derived from measurements of 8 satellites (AE-C, AE-E, AEROS-A, AEROS-B, ARIEL-3, ESRO-4, OGO-6, and SAN MARCO-3) and 4 incoherent scatter stations (Arecibo, Jicamarca, Millstone Hill, and St Santin). The altitude covered extends from 120 km up to about 600 km over the time period 1967 to 1976. The analytical framework used in the model resembles closely the MSIS setup: time independent terms, solar flux terms, geomagnetic activity (Kp) effect, annual (semiannual) and diurnal (semidiurnal, terdiurnal) variations, longitudinal terms, the U.T. effect, and corrections compensating for deviations from diffusive equilibrium at altitudes below 200 km. The model describes quiet to medium disturbed geomagnetic conditions (Kp ? 4) at solar fluxes (10.7cm) ranging from 60 to 180 × 10?22 Wm?2Hz?1. To get an impression of the accuracy presently obtained, the model is compared with MSIS, Jacchia (1977), and the models of Thuillier (T∞ and Engebretson (N). The best agreement is found for the temperature and the constituents He, O, and N2 with increasing deviations in the order of H, N, Ar, and O2.  相似文献   

18.
A coupled neutral-ionic photochemical model has been used to interpret the ionic composition of the Venusian dayside ionosphere measured by the orbiter retarding potential analyser (ORPA) experiment on board the NASA Pioneer-Venus orbiter spacecraft. The electron and ion temperatures also measured by the ORPA are used for calculating the plasma-diffusion coefficients and scale heights for ions. The neutral temperature profiles and the densities of neutral constituents, particularly CO2 and O, play key roles in the determination of the height profiles of the ionic constituents. All these quantities vary substantially in the Venusian thermosphere near the terminator; the models presented are representatives of the solar zenith angle ～65°. The predicted O2+ densities below ～200km agree particularly well with observations by the ORPA, but the model values are significantly less than those measured by the orbiter ion mass spectrometer (OIMS). Models predict much smaller densities than observed values for all molecular ions above ～200km. The reason for the turn-up trend of the concentration gradient of molecular ions observed at these heights by both ORPA and OIMS is unknown. One of the models can predict O+ ion densities above ～200km compatible with observations, if an effective vertical escape flux (φ108cm?2sec?1) is assumed at the ionopause. The neutral air density required to explain the observed ion composition is about 1.4 times larger than the values measured by the orbiter neutral mass spectrometer (ONMS).  相似文献   

19.
We have investigated the role of several ion-molecule reactions in the conversion of N2O5 to HNO3. In the proposed conversion, an N2O5 molecule would react with an H2O molecule clustered to an inert ion to produce two HNO3 molecules. Subsequent clustering of an H2O molecule to the inert ion would make the reaction catalytic. If such an ion-catalysed conversion of N2O5 to HNO3 occurs, it would probably play a role in the stratospheric chemistry at high latitudes in winter. In this paper we present reaction rate constant measurements made in a flowing afterglow apparatus for hydrated H3O+, H+(CH3CN)m (m = 1, 2, 3), and several negative ions reacting with N2O5. Slow rate constants were found for these ions for hydration levels that are predominant in the stratosphere. With the known stratospheric ion density, these slow rate constants preclude significant N2O5 conversion by ion-molecule reactions.  相似文献   

20.
This work presents model calculations of the diurnal airglow emissions from the OH Meinel bands and the O2 IR atmospheric band in the neutral atmosphere of Mars. A time-dependent photochemical model of the lower atmosphere below 80 km has been developed for this purpose. Special emphasis is placed on the nightglow emissions because of their potential to characterize the atomic oxygen profile in the 50-80 km region. Unlike on Earth, the OH Meinel emission rates are very sensitive to the details of the vibrational relaxation pathway. In the sudden death and collisional cascade limits, the maximum OH Meinel column intensities for emissions originating from a fixed upper vibrational level are calculated to be about 300 R, for transitions v′=9→v′?8, and 15,000 R, for transitions v′=1→v′=0, respectively. During the daytime the 1.27 μm emission from O2(), primarily formed from ozone photodissociation, is of the order of MegaRayleighs (MR). Due to the long radiative lifetime of O2(), a luminescent remnant of the dayglow extends to the dark side for about two hours. At night, excited molecular oxygen is expected to be produced through the three body reaction O + O + CO2. The column emission of this nighttime component of the airglow is estimated to amount to 25 kR. Both nightglow emissions, from the OH Meinel bands and the O2 IR atmospheric band, overlap in the 50-80 km region. Photodissociation of CO2 in the upper atmosphere and the subsequent transport of the atomic oxygen produced to the emitting layer are revealed as key factors in the nightglow emissions from these systems. The Mars 5 upper constraint for the product [H][O3] is revised on the basis of more recent values for the emission probabilities and collisional deactivation coefficients.  相似文献   

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