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1.
This paper presents new SHRIMP zircon U–Pb chronology, major and trace element, and Sr–Nd–Hf isotopic data of two Early Paleozoic granitic plutons (Yierba and North Kudi) from the western Kunlun orogen, in attempt to further constrain the Proto-Tethys evolution. SHRIMP zircon U–Pb dating shows that the Yierba pluton was emplaced in the Middle Cambrian (513?±?7 Ma) and the North Kudi pluton was emplaced in the Late Silurian (420.6?±?6.3 Ma). The Yierba pluton consists of quartz monzodiorite, quartz monzonite and granodiorite. These granitoids are metaluminous and potassic, with initial 87Sr/86Sr ratios of 0.7072–0.7096, εNd (T) of ?0.2 to ?1.6 and εHf (T) (in-situ zircon) of ?1.2. Elemental and isotopic data suggest that they were formed by partial melting of subducted sediments, with subsequent melts interacting with the overlying mantle wedge in an oceanic island arc setting in response to the intra-oceanic subduction of Proto-Tethys. The North Kudi pluton consists of syenogranite and alkali-feldspar granite. These granites are metaluminous to weakly peraluminous and potassic. They show an affinity of A1 subtype granite, with initial 87Sr/86Sr ratios of 0.7077–0.7101, εNd (T) of ?3.5 to ?4.0 and εHf (T) (in-situ zircon) of ?3.9. Elemental and isotopic data suggest that they were formed by partial melting of the Precambrian metamorphic basement at a shallow depth (<30 km) during the post-orogenic regime caused by Proto-Tethyan oceanic slab break-off. Our new data suggest that the subduction of the Proto-Tethyan oceanic crust was as early as Middle Cambrian (～513 Ma) and the final closure of Proto-Tethys was not later than Late Silurian (～421 Ma), most probably in Middle Silurian.  相似文献   

2.
The Middle Jurassic Barcroft mafic granodiorite and Late Cretaceous, ternary-minimum McAfee Creek Granite are important components of the igneous arc sited along the SW North American margin. Bulk-rock analyses of 11 samples of the metaluminous, I-type Barcroft comagmatic suite have an average δ18O value of 7.4±0.6‰ (all values±1σ). Four Barcroft specimens average εNd=?3.6±1.8, 87Sr/86Sr=0.707±0.001. The pluton consists of petrochemically gradational, Ca-amphibole-rich gabbro/diorite, granodiorite, metadiorite, and rare alaskite–aplite; for most of the pluton, oxygen isotope exchange of quartz, feldspar(s), biotite, and Ca-amphibole accompanied local deuteric alteration. Eight specimens of slightly peraluminous granitic rocks of the muscovite-bearing McAfee Creek series have an average δ18O of 8.6±0.5‰. Four McAfee-type samples average εNd=?7.8±1.7, 87Sr/86Sr=0.711±0.004. For both plutons, bulk-rock evidence of exchange with near-surface water is lacking, suggesting ~5–10 km cooling depths. Barcroft minerals exhibit regular oxygen isotopic partitioning from high to low δ18O in the sequence quartz>plagioclase>K-feldspar>>amphibole≥biotite. Along the SE margin of the pluton, quartz and biotite in Lower Cambrian quartzites are higher in δ18O, and show slightly larger fractionations than igneous analogues. Exchange with fluids derived from these heated, contact-metamorphosed country rocks increased bulk 18O/16O ratios of Barcroft border rocks (and constituent plagioclase+subsolidus tremolite–actinolite), especially of granitic dikes transecting the wall rocks. Oxygen isotope thermometry for seven Barcroft pluton quartz–amphibole and six quartz–biotite pairs indicate apparent subsolidus temperatures averaging 519±49 °C. Quartz–plagioclase pairs from two Barcroft granodiorites yield values of 519 and 515 °C. A quartz–biotite pair from a quartzite adjacent to the Barcroft pluton yields an apparent temperature of 511 °C, in agreement with estimates based on contact metamorphic parageneses. Except for its SE margin, Barcroft pluton silicates evidently exchanged oxygen isotopes under local deuteric conditions. Compatible with Ca-amphibole thermobarometric analyses, areal distributions for quartz–plagioclase, quartz–amphibole, and quartz–biotite pairs reveal that putative annealing temperatures are lowest in NE-trending axial portions of the Barcroft body, so it simply cooled inwards. Intrusion ~70 million years later by the McAfee Creek Granite had no discernable effect on δ18O values of Barcroft minerals and bulk rocks.  相似文献   

3.
The Upper Cretaceous Torul pluton, located in the Eastern Pontides, is of sub-alkaline affinity and displays features typical of volcanic arc granitoids. It is a composite pluton consisting of granodiorite, biotite hornblende monzogranite, quartz monzodiorite, quartz monzonite and hornblende biotite monzogranite. The oldest syenogranite (77.9 ± 0.3 Ma) and the youngest quartz diorite form small stocks within the pluton. Samples from the granodiorites, biotite hornblende monzogranites, quartz monzodiorites, quartz monzonites and hornblende biotite monzogranites have SiO2 between 57 and 68 wt% and display high-K calc-alkaline, metaluminous to peraluminous characteristics. Chondrite-normalized REE patterns are fractionated (Lacn/Lucn = 6.0?14.2) with pronounced negative Eu anomalies (Eu/Eu* = 0.59–0.84). Initial ?Nd(i) values vary between ?3.1 and ?4.1, initial 87Sr/86Sr values between 0.7058 and 0.7072, and δ18O values between +4.4 and +7.3‰. The quartz diorites are characterized by relatively high Mg-number of 36–38, low contents of Na2O (2.3–2.5 wt%) and SiO2 (52–55 wt%) and medium-K calc-alkaline, metaluminous composition. Chondrite-normalized REE patterns are relatively flat [(La/Yb)cn =  2.8–3.3; (Tb/Yb)cn =  1.2] and show small negative Eu anomalies (Eu/Eu* = 0.74–0.76). Compared to the other rock types, radiogenic isotope signatures of the quartz diorites show higher 87Sr/86Sr (0.7075–0.7079) and lower ?Nd(i) (–4.5 to –5.3). The syenogranites have high SiO2 (70–74 wt%) and display high-K calc-alkaline, peraluminous characteristics. Their REE patterns are characterized by higher Lacn/Lucn (12.9) and Eu/Eu* (0.76–0.77) values compared to the quartz diorites. Isotopic signatures of these rocks [?Nd(i) =  ?4.0 to ?3.3; 87Sr/86Sr(i) =  0.7034?0.7060; δ18 O =  + 4.9 to + 8.2] are largely similar to the other rock types but differ from that of the quartz diorites. Fractionation of plagioclase, hornblende, pyroxene and Fe–Ti oxides played an important role in the evolution of Torul granitoids. The crystallization temperatures of the melts ranged from 800 to 900°C as determined from zircon and apatite saturation thermometry. All these characteristics, combined with low K2O/Na2O, low Al2O3/(FeOT + MgO + TiO2), and low (Na2O + K2O)/(FeOT + MgO + TiO2) ratios suggest an origin through dehydration melting of mafic lower crustal source rocks.  相似文献   

4.
Oxygen isotope compositions of mineral separates were determined from two metaluminous granitoids (Emas and São Rafael plutons) from northeastern Brazil. The I-type Emas pluton has high δ18O (WR) values (11.5–11.8‰), whereas the São Rafael pluton has low δ18O (WR) values (7.5–8.1‰), but Sr and Nd are characteristics of S-type granitoids. Measured mineral–mineral fractionations suggest continuous sub-solidus inter-mineral isotope exchange among all minerals except zircon. There is a large and consistent quartz–epidote fractionation that gives apparent temperatures that are much lower than anticipated closure temperatures for epidote. Oxygen isotope fractionation between natural zircon and magmatic epidote is opposite to that predicted from theoretical determinations, as δ18O (epidote) <δ18O (zircon). An empirical calibration based on these results would suggests a closure T for oxygen in epidote of ~500 °C and Δ(qtz–epi) ~5.19 at 500 °C.  相似文献   

5.
Peralkaline syenite and granite dykes cut the Straumsvola nepheline syenite pluton in Western Dronning Maud Land, Antarctica. The average peralkalinity index (PI?=?molecular Al/[Na?+?K]) of the dykes is 1.20 (n?=?29) and manifests itself in the presence of the Zr silicates eudialyte, dalyite and vlasovite, and the Na–Ti silicate, narsarsukite. The dykes appear to have intruded during slow cooling of the nepheline syenite pluton, and the petrogenetic relationship of the dykes and the pluton cannot be related to closed-system processes at low pressure, given the thermal divide that exists between silica-undersaturated and oversaturated magmas. Major and trace element variations in the dykes are consistent with a combination of fractional crystallization of parental peralkaline magma of quartz trachyte composition, and internal mineral segregation prior to final solidification. The distribution of accessory minerals is consistent with late-stage crystallization of isolated melt pockets. The dykes give an Rb–Sr isochron age of 171?±?4.4 Ma, with variable initial 87Sr/86Sr ratio (0.7075?±?0.0032), and have an average ε Nd of ? 12.0. Quartz phenocrysts have δ18O values of 8.4–9.2‰, which are generally in O-isotope equilibrium with bulk rock. Differences in the δ18O values of quartz and aegirine (average Δquartz?aegirine = 3.5‰) suggest aegirine formation temperatures around 500 °C, lower than expected for a felsic magma, but consistent with poikilitic aegirine that indicates subsolidus growth. The negative ε Nd (< ? 10) and magma δ18O values averaging 8.6‰ (assuming Δquartz?magma = 0.6‰) are inconsistent with a magma produced by closed-system fractional crystallization of a mantle-derived magma. By contrast, the nepheline syenite magma had mantle-like δ18O values and much less negative ε Nd (average ??3.1, n?=?3). The country rock has similar δ18O values to the granite dykes (average 8.0‰, n?=?108); this means that models for the petrogenesis of the granites by assimilation are unfeasible, unless an unexposed high-δ18O contaminant is invoked. Instead, it is proposed that the peralkaline syenite and granite dykes formed by partial melting of alkali-metasomatised gneiss that surrounds the nepheline syenite, followed by fractional crystallization.  相似文献   

6.
Tourmalinization associated with peraluminous granitic intrusions in metapelitic host-rocks has been widely recorded in the Iberian Peninsula, given the importance of tourmaline as a tracer of granite magma evolution and potential indicator of Sn-W mineralizations. In the Penamacor-Monsanto granite pluton (Central Eastern Portugal, Central Iberian Zone), tourmaline occurs: (1) as accessory phase in two-mica granitic rocks, muscovite-granites and aplites, (2) in quartz (±mica)-tourmaline rocks (tourmalinites) in several exocontact locations, and (3) as a rare detrital phase in contact zone hornfels and metapelitic host-rocks. Electron microprobe and stable isotope (δ18O, δD, δ11B) data provide clear distinctions between tourmaline populations from these different settings: (a) schorl–oxyschorl tourmalines from granitic rocks have variable foititic component (X□ = 17–57 %) and Mg/(Mg + Fe) ratios (0.19–0.50 in two-mica granitic rocks, and 0.05–0.19 in the more differentiated muscovite-granite and aplites); granitic tourmalines have constant δ18O values (12.1 ± 0.1 ‰), with wider-ranging δD (?78.2 ± 4.7 ‰) and δ11B (?10.7 to ?9.0 ‰) values; (b) vein/breccia oxyschorl [Mg/(Mg + Fe) = 0.31–0.44] results from late, B- and Fe-enriched magma-derived fluids and is characterized by δ18O = 12.4 ‰, δD = ?29.5 ‰, and δ11B = ?9.3 ‰, while replacement tourmalines have more dravitic compositions [Mg/(Mg + Fe) = 0.26–0.64], close to that of detrital tourmaline in the surrounding metapelitic rocks, and yield relatively constant δ18O values (13.1–13.3 ‰), though wider-ranging δD (?58.5 to ?36.5 ‰) and δ11B (?10.2 to ?8.8 ‰) values; and (c) detrital tourmaline in contact rocks and regional host metasediments is mainly dravite [Mg/(Mg + Fe) = 0.35–0.78] and oxydravite [Mg/(Mg + Fe) = 0.51–0.58], respectively. Boron contents of the granitic rocks are low (<650 ppm) compared to the minimum B contents normally required for tourmaline saturation in granitic melts, implying loss of B and other volatiles to the surrounding host-rocks during the late-magmatic stages. This process was responsible for tourmalinization at the exocontact of the Penamacor-Monsanto pluton, either as direct tourmaline precipitation in cavities and fractures crossing the pluton margin (vein/breccia tourmalinites), or as replacement of mafic minerals (chlorite or biotite) in the host-rocks (replacement tourmalinites) along the exocontact of the granite. Thermometry based on 18O equilibrium fractionation between tourmaline and fluid indicates that a late, B-enriched magmatic aqueous fluid (av. δ18O ~12.1 ‰, at ~600 °C) precipitated the vein/breccia tourmaline (δ18O ~12.4 ‰) at ~500–550 °C, and later interacted with the cooler surrounding host-rocks to produce tourmaline at lower temperatures (400–450 °C), and an average δ18O ~13.2 ‰, closer to the values for the host-rock. Although B-metasomatism associated with some granitic plutons in the Iberian Peninsula seems to be relatively confined in space, extending integrated studies such as this to a larger number of granitic plutons may afford us a better understanding of Variscan magmatism and related mineralizations.  相似文献   

7.
In situ analysis reveals that eclogite-facies garnets are zoned in δ18O with lower values in the core and rims that are ~1.5 to 2.5 ‰ higher. This pattern is present in 9 out of 12 garnets analyzed by SIMS from four orogenic eclogite terranes, and correlates with an increase in the mole fraction of pyrope and Mg/Fe ratio from core to rim, indicating prograde garnet growth. At the maximum temperatures and the time-scales experienced by these garnets, calculated intragranular diffusion distances for oxygen are small (<5 μm), indicating that δ18O records primary growth zoning and not diffusive exchange. The oxygen isotope gradients are larger than could form due to temperature changes during closed-system mineral growth. Thus, gradients reflect the compositions of fluids infiltrating during prograde metamorphism. Values of δ18O in garnet cores range from ?1 to 15 ‰, likely preserving the composition of the eclogite protoliths. Two garnet cores from the Almenningen eclogite in the Western Gneiss Region, Norway, have δ18O ~?1 ‰ and are the first negative δ18O eclogites identified in the region. In contrast with orogenic eclogites, seven high δ18O garnets (>5 ‰) from two kimberlites are homogeneous in δ18O, possibly due to diffusive exchange, which is possible for prolonged periods at higher mantle temperatures. Homogeneity of δ18O in garnets outside the normal mantle range (5–6 ‰) may be common in kimberlitic samples.  相似文献   

8.
ABSTRACT

The Eastern Pontides orogenic belt in NE Turkey hosts numerous I-type plutons of Eocene epoch. Here, we report new U–Pb SHRIMP zircon ages and in situ zircon Lu-Hf isotopes along with bulk-rock geochemical and Sr-Nd-Pb-O isotope data from the Kemerlikda??, Ayd?ntepe and Pelitli plutons and mafic microgranular enclaves (MMEs) to constrain their parental melt source(s) and evolutionary processes. U-Pb SHRIMP zircon dating yielded crystallization ages between 45 and 44 Ma for the studied plutons and their MMEs. The plutons range from gabbro to granite and have I-type, medium to high-K calc-alkaline, and metaluminous to slightly peraluminous characteristics. On the primitive mantle-normalized multi-trace-element variations, the plutons and their MMEs are characterized by signi?cant enrichment in LILE/HFSE. Chondrite-normalized REE patterns of the plutons and their MMEs are close to each other and show moderate enrichment with variable negative Eu anomalies. The studied plutons have fairly homogeneous isotope composition (87Sr/86Sr(i) = 0.70502 to 0.70560; εNd(i) = +0.9 to – 1.4; δ18O = +5.0 to +8.7‰, εHf(i) = – 2.2 to +13.5). The MMEs show medium to high-K calc-alkaline and metaluminous character. Although the isotope signatures of the MMEs (87Sr/86Sr(i) = 0.70508 to 0.70542; εNd(i) = +0.9 to ?1.1; δ18O = +5.8 to +8.0, εHf(i) = +4.3 to +10.4) are very similar to those of the host rocks. Fractionation of plagioclase, amphibole, pyroxene and Fe-Ti oxides played an important role in the evolution of the plutons. The isotopic composition of the studied plutons and MMEs are similar to I-type plutons derived from mantle sources. The MMEs show incomplete magma mixing/mingling, representing small bodies of mafic parental magma. The parental magma(s) of the studied plutons were generated from the enriched lithospheric mantle and then modified by fractional crystallisation, and lesser assimilation and mixing/mingling in the crustal magma chambers.  相似文献   

9.
《International Geology Review》2012,54(16):1975-1991
Late Palaeozoic granites are widely distributed in the southeastern Beishan area, which is located in the central part of the southern Central Asian Orogenic Belt (CAOB). U–Pb zircon dates of five late Palaeozoic granitic plutons from the southeastern Beishan area yield Permian ages: 285 ± 2 Ma (Shuwojing and Western Shuwojing plutons), 269 ± 3 Ma (Jianquanzi and Jiuquandihongshan plutons), and 260 ± 1 Ma (Jiujing pluton). The early Permian Shuwojing pluton, an unfractionated calc-alkaline biotite monzogranite with slightly positive εNd(t) (+0.7 and +0.6) and low initial 87Sr/86Sr (0.70722 and 0.70712), and the early Permian Western Shuwojing pluton, a high-K calc-alkaline biotite granite with slightly negative εNd(t) (?0.2 and ?0.1) and low initial 87Sr/86Sr (0.70390 and 0.70919), are likely derived from a mixture of depleted (juvenile) mantle and upper continental crustal (or sedimentary) material. The mid-Permian Jianquanzi and Jiuquandihongshan monzogranites have highly fractionated potassium-rich calc-alkaline characteristics with negative εNd(t) (?4.3) and very high initial 87Sr/86Sr (0.71949), reflecting a continental crustal component. The compositionally diverse Jiujing pluton and the granodiorite and high-Sr monzogranite phases display adakite-like compositions with relatively low εNd(t) (?0.1 and ?2.2) and high initial 87Sr/86Sr (0.70822 and 0.70913). The Jiujing low-Sr monzogranite has higher initial 87Sr/86Sr (0.73464) and lower εNd(t) (?2.8), indicating a significant continental crustal component in its genesis. This work, combined with the regional geology and previous studies, suggest that the early to middle Permian southern Beishan plutons formed in a post-collisional environment, probably an intracontinental rift environment linked to asthenospheric upwelling in response to the break-off of a subducted slab. In the late Permian, the southern Beishan area was in a compressive tectonic regime and thickening of the continental crust resulted in the formation of the Jiujing adakite-like granite.  相似文献   

10.
ABSTRACT

Intrusive rocks are well-exposed in the south Birjand around the Koudakan is herein compared to previously studied outcrops along the middle Eocene to late Oligocene Eastern Iran Magmatic Belt. This pluton is composed mainly of monzonite, quartz-monzonite, and granite with high-K calc-alkaline to shoshonitic affinities. The U-Pb zircon geochronology from monzonite and quartz-monzonite reveals the crystallization ages of 40.96 ± 0.48 to 38.78 ± 0.78 Ma (Bartonian). The monzonite, quartz-monzonite, and granite rocks show similar REEs and trace element patterns, as well as limited variations in εNd(i) and 87Sr/86Sr(i) ratio, suggesting that they are a comagmatic intrusive suite. The chondrite and primitive mantle normalized rare earth and trace element patterns show enrichment in the light rare earth elements, K, Rb, Cs, Pb, Th, and U and depletion in heavy rare earth elements, Nb, Zr, and Ti. The εNd(i) and 87Sr/86Sr(i) values range from +1.32 to +1.68 and 0.7044 to 0.7047, respectively, identical to island-arc basalt composition. The whole-rock Nd model age (TDM) for the intrusive rocks range between 0.69 and 0.73 Ga. These geochemical and isotopic signatures indicate a subduction-related sub-continental lithospheric mantle source for these rocks. Our new geochemical, isotopic, and geochronological studies integrated with previously published data indicate that the middle Eocene to late Oligocene magmatism in eastern Iran was formed in a post-collisional tectonic environment. We suggest the northeastward subduction of the Neo-Tethys ocean beneath the Lut block and the eastward subduction of the Sistan ocean beneath the Afghan block caused mantle wedge to be metasomatized by slab components. At a later stage, a collision between the Lut and Afghan blocks was accompanied by the lithospheric delamination, and the subsequent asthenospheric upwelling led to the melting of the metasomatized sub-continental lithospheric mantle and the generation of middle Eocene to late Oligocene magmatism in the Eastern Iran Magmatic Belt.  相似文献   

11.
ABSTRACT

Subduction-related basaltic rocks in active continental margins should record information about the lithospheric mantle. Mafic rocks from the Qimantag region of the East Kunlun Orogenic Belt (EKOB), NW China, can be used to constrain the evolution of mantle sources. The Heishan basalts (445 Ma) and Xiarihamu gabbros (427 Ma) display distinct geochemical and isotopic features, with basalts yielding relatively lower Na2O+K2O (1.48–4.16 wt.%) and Mg# (0.50–0.57) than gabbros (Na2O+K2O = 2.96–4.07 wt.%, Mg# = 0.65–0.81). Although the basalts and gabbros show similar enrichment of LILE and depletion of HFSE, the gabbros have higher Th/Y and lower Sm/Th and Nb/U ratios than the basalts, indicative of derivation from a more enriched mantle source. The Heishan basalts have relatively positive εNd(t) values (+4.7 to +5.8) whereas the Xiarihamu gabbros have negative εNd(t) values ranging from ?5.5 to ?3.8. Crustal contamination played an insignificant role in the formation of the basalts and gabbros. Our data suggest that the basalts originated from a depleted mantle source, slightly enriched by subduction-related fluids, whereas the gabbros originated from an enriched mantle source. These findings support a subduction-related progressive lithospheric mantle enrichment model over ~20 Ma beneath the Qimantag region in the Early Palaeozoic.  相似文献   

12.
ABSTRACT

Eocene intermediate to felsic plutons of different sizes and compositions are widespread in the Eastern Pontides Orogenic Belt in northern Turkey. Of these, the Ta?l?k Tepe pluton in the Havza (Samsun) area is fine-to-medium-grained, with granular, porphyritic, and micrographic textures, and include mafic microgranular enclaves (MMEs). LA-ICP-MS U-Pb zircon dating yielded emplacement ages of 42.9 (± 1.4) and 40.5 (± 1.3) Ma for the host granodioritic pluton and the dioritic MMEs, respectively. Petrochemically, the host pluton has I-type, high-K calc-alkaline, and metaluminous-to-slightly peraluminous features (A/CNK = 0.95–1.06). The host pluton also shows geochemical features of adakite-like rocks with high SiO2 (67–68 wt%) and Al2O3 (15.5–16.0 wt%) content and Ba/La (17–23), Sr/Y (40.7–61.6), and LaN/YbN (14.4–23.7) ratios and low Y (8.2–9.9 ppm) and YbN (3.1–4.4) contents. Whole-rock major and trace element variations suggest that fractional crystallisation played a significant role in the pluton evolution. The N-MORB normalised trace element patterns of the pluton are similar to those of MMEs with enrichment in large-ion lithophile elements, Th and Ce, and negative Nb and Ti anomalies. Chondrite-normalised rare earth element plots show moderate-to-highly enriched concave patterns (LaN/LuN = 14.2–21.6) with insignificant negative Eu anomalies (EuN/Eu* = 0.86–1.14), all of which imply hornblende fractionation during magmatic evolution. The pluton samples have 87Sr/86Sr ratios of 0.704767 to 0.704927, 143Nd/144Nd ratios of 0.512767–0.512774, εNd values of (+2.52) – (+2.65), and δ18O values of 7.9–9.7‰. The isotopic compositions of the host pluton and MMEs are similar to I-type granitoids derived from mantle sources. The MMEs show incomplete magma mixing/mingling, representing small bodies of mafic parental magma. Combined with regional studies, these new data suggest that the parental magma of the studied adakite-like pluton was generated from the lithospheric mantle and then modified by fractional crystallisation and assimilation in a post-collisional setting.  相似文献   

13.
The oxygen isotope compositions of eclogite and amphibolite garnets from Franciscan Complex high-grade blocks and actinolite rinds encasing the blocks were determined to place constraints on their fluid histories. SIMS oxygen isotope analysis of single garnets from five eclogite blocks from three localities (Ring Mountain, Mount Hamilton, and Jenner Beach) shows an abrupt decrease in the δ18O value by ~1–3 ‰ from core to rim at a distance of ~120 ± 50 μm from the rim in nine out of the 12 garnets analyzed. In contrast, amphibolite garnets from one block (Ring Mountain) analyzed show a gradual increase in δ18O value from core to rim, implying a different history from that of the eclogite blocks. Values of δ18O in eclogite garnet cores range from 5.7 to 11.6 ‰, preserving the composition of the eclogite protolith. The abrupt decrease in the δ18O values of the garnet rims to values ranging from 3.2 to 11.2 ‰ suggests interaction with a lower δ18O fluid during the final stages of growth during eclogite facies metamorphism (450–600 °C). We hypothesize that this fluid is sourced from the serpentinized mantle wedge. High Mg, Ni, and Cr contents of actinolite rinds encasing the blocks also support interaction with ultramafic rock. Oxygen isotope thermometry using chlorite and phengite versus actinolite of rinds suggests temperatures of 185–240 °C at Ring Mountain and Mount Hamilton. Rind formation temperatures together with the lower δ18O garnet rims suggest that the blocks were in contact with ultramafic rock from the end of garnet growth through low-temperature retrogression. We suggest a tectonic model in which oceanic crust is subducted at the initiation of subduction and becomes embedded in the overlying mantle wedge. As subduction continues, metasomatic exchange between high-grade blocks and surrounding ultramafic rock is recorded in low δ18O garnet rims, and later as temperatures decrease, with rind formation.  相似文献   

14.
The Jiapigou gold belt (>150 t Au), one of the most important gold-producing districts in China, is located at the northeastern margin of the North China Craton. It is composed of 17 gold deposits with an average grade around 10 g/t Au. The deposits are hosted in Archean gneiss and TTG rocks, and are all in shear zones or fractures of varying orientations and magnitudes. The δ34S values of sulfide from ores are mainly between 2.7?‰ and 10?‰. The Pb isotope characteristics of ore sulfides are different from those of the Archean metamorphic rocks and Mesozoic granites and dikes, and indicate that they have different lead sources. The sulfur and lead isotope compositions imply that the ore-forming materials might originate from multiple, mainly deep sources. Fluid inclusions in pyrite have 3He/4He ratios of 0.6 to 2.5 Ra, whereas their 40Ar/36Ar ratios range from 1,444 to 9,805, indicating a dominantly mantle fluid with a negligible crustal component. δ18O values calculated from hydrothermal quartz are between ?0.2?‰ and +5.9?‰, and δD values of the fluids in the fluid inclusions in quartz are from ?70?‰ to ?96?‰. These ranges suggest dominantly magmatic water with a minor meteoric component. The noble gas isotopic data, along with the stable isotopic data, suggest that the ore-forming fluids have a dominantly mantle source with minor crustal addition.  相似文献   

15.
Oxygen isotope ratios have been determined using laser fluorination techniques on olivine and plagioclase phenocrysts and bulk glasses from the Reykjanes Ridge and Iceland. δ18O in Reykjanes Ridge olivines shows hyperbolic correlations with Sr-Nd-Pb isotope ratios that terminate at δ18O = +4.5‰ at compositions almost identical to those of moderately enriched lavas on the Reykjanes Peninsula, Iceland. Samples with low δ18O show no indication of contamination by oceanic crust such as elevated Cl/K, and are too deep to have been influenced by meteoric water hydrothermal systems. They cannot represent Icelandic melts contaminated in the crust and transferred laterally along the ridge since fissure systems are strongly oblique to the ridge axis. It follows that Icelandic mantle advected along the ridge has low δ18O. The hyperbolic 143Nd/144Nd-δ18O correlation appears to be more strongly curved than magma mixing trajectories and suggests that melt fractions are ∼4.5× greater and source Nd contents ∼9× greater in the mantle at 63°N compared with that at 60°N. Primitive lavas from the Reykjanes Peninsula show linear correlations between olivine δ18O and 143Nd/144Nd or 206Pb/204Pb, extending to δ18O of +4.3‰ at 143Nd/144Nd close to the lowest ratios observed in Icelandic magmas. These correlations cannot be produced by melt mixing or crustal contamination because these would yield strongly hyperbolic trajectories. Lower δ18O seen in more evolved samples from the Eastern Rift Zone may reflect crustal contamination, though there is some evidence of a mantle source with lower δ18O in eastern Iceland. It is very difficult to explain the low δ18O of enriched Icelandic mantle sources on current understanding of mantle and crustal oxygen isotopes. There is no obvious reason why such low-δ18O sources should not contribute to other ocean islands. No oceanic crustal lithologies exist that could produce the low-δ18O enriched sources by recycling into the mantle, and there is no evidence for changes in δ18O of ophiolite suites with time, nor of changes during high-P metamorphism. Low δ18O appears to be associated with high 3He/4He, and we speculate that this signature may be characteristic of the host mantle into which ocean crust was recycled.  相似文献   

16.
The paper presents the results of determinations of stable S and O isotopes of dissolved sulfates and O and H stable isotopes of waters from three ponds, that is, Marczakowe Do?y acid pond, Marczakowe Do?y fish pond and Podwi?niówka acid pit pond, located in the Holy Cross Mountains (south-central Poland). The δ34SV-CDT and δ18OV-SMOW of SO4 2? in waters of three ponds (n = 14) varied from ?16.2 to ?9.5 ‰ (mean of ?13.6 ‰) and from ?8.1 to ?3.2 ‰ (mean of ?4.8 ‰), respectively. The mean δ34S–SO4 2? values were closer to those of pyrite (mean of ?25.4 ‰) and efflorescent sulfate salts (mean of ?25.6 ‰), recorded previously in the Podwi?niówka quarry, than to sulfates derived from other anthropogenic or soil and bedrock sources. The SO4 2? ions formed by bacterially induced pyrite oxidation combined with bacterial (dissimilatory) dissolved sulfate reduction, and presumably with subordinate mineralization of carbon-bonded sulfur compounds, especially in both Marczakowe Do?y ponds. In addition, the comparison of δ18O–SO4 2? and δ18O–H2O values indicated that 75–100 % of sulfate oxygen was derived from water. Due to the largest size, the Podwi?niówka acid pit pond revealed distinct seasonal variations in both δ18O–H2O (?9.2 to ?1.6) and δD–H2O (?29.7 to ?71.3) values. The strong correlation coefficient (r 2 = 0.99) was noted between δ18O–H2O and δD–H2O values, which points to atmospheric precipitation as the only source of water. The sediments of both acid ponds display different mineral inventory: the Marczakowe Do?y acid pond sediment consists of schwertmannite and goethite, whereas Podwi?niówka acid pit pond sediment is composed of quartz, illite, chlorite and kaolinite with some admixture of jarosite reflecting a more acidic environment. Geochemical modeling of two acid ponds indicated that the saturation indices of schwertmannite and nanosized ε-Fe2O3 (Fe3+ oxide polymorph) were closest to thermodynamic equilibrium state with water, varying from ?1.44 to 3.05 and from ?3.42 to 6.04, respectively. This evidence matches well with the obtained mineralogical results.  相似文献   

17.
ABSTRACT

The Mesozoic tectonic transition from the Palaeo-Tethys tectonic regime to the Palaeo-Pacific tectonic regime in the eastern South China Block has long been debated. Geochemical and zircon U–Pb–Hf isotopic studies were conducted on the Dashuang complex in the eastern Zhejiang Province. The Dashuang complex consists mainly of quartz syenite in the northwestern part and quartz monzonite in the southeastern part. New laser ablation inductively coupled plasma mass spectrometry zircon U–Pb data show that the quartz syenite, the quartz monzonite, and its chilled margin (fine-grained granite) crystallized at 235 ± 4 Ma, 232 ± 3 Ma, and 230 ± 1 Ma, respectively. The Dashuang complex intrudes into the Chencai Group gneiss that postdated ~646 Ma and underwent anatexis at 443 ± 14 Ma. The quartz monzonite shows A-type granite affinity, characterized by high K2O + Na2O and Zr + Nb + Ce + Y, high FeOT/(MgO + FeOT) and Ga/Al ratios, an enrichment in light rare earth elements, and depletions in Ba, Sr, and Eu. The quartz monzonite has zircon εHf(t) values of ?14.2 to –11.9 and two-stage model ages of 1788–1922 Ma. Zircon εHf(t) values of the chilled margin (fine-grained granite) and wall rock (gneiss) are scattered (?18.2 to –6.3 and ?19.5 to 10.2). The corresponding two-stage model ages are 1482–2133 Ma and 1184–2471 Ma, respectively. The Dashuang complex was derived mainly from partial melting of Neoproterozoic clastic rocks in the Cathaysia Block. Geochemical data indicate that the quartz monzonite formed in a post-collision extensional environment. These results, considered with previous data, indicate that the transition from the Palaeo-Tethys to the Palaeo-Pacific tectonic regimes of the eastern South China Block occurred during the Late Triassic (225–215 Ma).  相似文献   

18.
We present high-precision iron and magnesium isotopic data for diverse mantle pyroxenite xenoliths collected from Hannuoba, North China Craton and provide the first combined iron and magnesium isotopic study of such rocks. Compositionally, these xenoliths range from Cr-diopside pyroxenites and Al-augite pyroxenites to garnet-bearing pyroxenites and are taken as physical evidence for different episodes of melt injection. Our results show that both Cr-diopside pyroxenites and Al-augite pyroxenites of cumulate origin display narrow ranges in iron and magnesium isotopic compositions (δ57Fe = ?0.01 to 0.09 with an average of 0.03 ± 0.08 (2SD, n = 6); δ26Mg = ? 0.28 to ?0.25 with an average of ?0.26 ± 0.03 (2SD, n = 3), respectively). These values are identical to those in the normal upper mantle and show equilibrium inter-mineral iron and magnesium isotope fractionation between coexisting mantle minerals. In contrast, the garnet-bearing pyroxenites, which are products of reactions between peridotites and silicate melts from an ancient subducted oceanic slab, exhibit larger iron isotopic variations, with δ57Fe ranging from 0.12 to 0.30. The δ57Fe values of minerals in these garnet-bearing pyroxenites also vary widely (?0.25 to 0.08 in olivines, ?0.04 to 0.25 in orthopyroxenes, ?0.07 to 0.31 in clinopyroxenes, 0.07 to 0.48 in spinels and 0.31–0.42 in garnets). In addition, the garnet-bearing pyroxenite shows light δ26Mg (?0.43) relative to the mantle. The δ26Mg of minerals in the garnet-bearing pyroxenite range from ?0.35 for olivine and orthopyroxene, to ?0.34 for clinopyroxene, 0.04 for spinel and ?0.68 for garnet. These measured values stand in marked contrast to calculated equilibrium iron and magnesium isotope fractionation between coexisting mantle minerals at mantle temperatures derived from theory, indicating disequilibrium isotope fractionation. Notably, one phlogopite clinopyroxenite with an apparent later metasomatic overprint has the heaviest δ57Fe (as high as 1.00) but the lightest δ26Mg (as low as ?1.50) values of all investigated samples. Overall, there appears to be a negative co-variation between δ57Fe and δ26Mg in the Hannuoba garnet-bearing pyroxenite and in the phlogopite clinopyroxenite xenoliths and minerals therein. These features may reflect kinetic isotopic fractionation due to iron and magnesium inter-diffusion during melt–rock interaction. Such processes play an important role in producing inter-mineral iron and magnesium isotopic disequilibrium and local iron and magnesium isotopic heterogeneity in the subcontinental mantle.  相似文献   

19.
The Early Cretaceous Shihu gold deposit is located in the northern segment of the Taihang Tectonic belt, which extends across the central part of the North China Craton. The deposit is hosted predominantly by the Archean metamorphic crystalline units, and is spatially and temporally related to quartz diorite porphyry present extensively throughout the gold deposit. We studied the geology, geochronology and stable isotopic geochemistry. Zircon U–Pb LA–ICP–MS ages of the quartz diorite porphyry at deposit range from 134 ± 1 to 131 ± 2 Ma, which are coeval and probably genetically related to the mineralization. The majority of the sulfides of the gold deposit have δ34S values ranging from ?1 to 2‰, which suggest an homogeneous magmatic source. In addition, the isotopic compositions of δ18Ofluid and δ18Dfluid vary from 2.1 to 7.0‰ and ?93 to ?65‰, respectively, suggesting that the magmatic fluids mingled with meteoric water. The Pb isotopic analyses reveal that both the ore‐forming materials and the quartz diorite porphyry originated from the lower crust and may have been mixed with mantle material. The 87Sr/86Sri and 143Nd/144Nd (143Nd/144Nd)i ratios for the quartz diorite porphyry demonstrate that there was mixing of two end‐member (crust and the mantle) isotopic compositions. These results suggest that the ore‐forming fluids and materials were derived from lower‐crustal melting induced by mantle processes. Processes associated with the formation of the Shihu gold deposit differ significantly from those that characterize orogenic gold deposits, and instead are representative of formation in an intracontinental tectonic environment.  相似文献   

20.
ABSTRACT

The magmatic generation for the Late Triassic–Early Jurassic (~215–200 Ma) and Early Cretaceous–Late Cretaceous (~108–79 Ma) post-collisional granites in the Sanjiang Tethys orogeny remain enigmatic. The Xiuwacu complex, located in the southern Yidun Terrane, consists of biotite granite with a weight mean 206Pb/238U age of 199.8 ± 2.5 Ma, aplite granite of 108.2 ± 2.3 Ma, monzogranite porphyry of 80.8 ± 1.0 Ma, and diorite enclaves of 79.2 ± 0.9 Ma and 77.9 ± 0.8 Ma. The Late Triassic biotite granites show I-type granite affinities, with high SiO2 contents, high Mg# values, high zircon δ18O values, and negative whole-rock ?Nd(t) values, indicating a predominant ancient crustal source with the input of juvenile materials. Their fractionated REE patterns and concave-upward middle-to-heavy REE patterns require garnet-bearing amphibolite as the melt source. The Cretaceous highly fractionated aplite granites and monzogranite porphyries have relatively high SiO2 contents, high (Na2O + K2O)/CaO ratios, high zircon δ18O values, and enriched whole-rock Sr–Nd isotopic signatures, suggesting that their parent magmas were likely originated from the ancient middle- to lower crust. Their significant negative Eu anomalies and obvious depletions in Nb, Sr, and Ti demonstrate that the Cretaceous granitic magmas had experienced more fractionation than the Late Triassic felsic magmas. The Late Cretaceous diorite enclaves show low SiO2 contents, high Mg# values, and high zircon δ18O values, suggesting that they were probably derived from the partial melting of subcontinental lithospheric mantle enriched by the Late Triassic subduction. The Late Triassic–Early Jurassic and Early Cretaceous–Late Cretaceous magmatism witnessed the post-collisional setting and intraplate extensional setting in response to the slab break-off and lithospheric-scale transtensional faulting, respectively. The partial melting of subduction-modified lithospheric mantle or/and residual sulphide cumulates within the lower crust during the origination of Late Cretaceous magmas could have provided metals for the formation of Xiuwacu deposit.  相似文献   

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