Spatio‐temporal tracer variability in the glacier melt end‐member — How does it affect hydrograph separation results?          下载免费PDF全文

Jan Schmieder  Jakob Garvelmann  Thomas Marke  Ulrich Strasser 《水文研究》2018,32(12):1828-1843

Geochemical and isotopic tracers were often used in mixing models to estimate glacier melt contributions to streamflow, whereas the spatio‐temporal variability in the glacier melt tracer signature and its influence on tracer‐based hydrograph separation results received less attention. We present novel tracer data from a high‐elevation catchment (17 km², glacierized area: 34%) in the Oetztal Alps (Austria) and investigated the spatial, as well as the subdaily to monthly tracer variability of supraglacial meltwater and the temporal tracer variability of winter baseflow to infer groundwater dynamics. The streamflow tracer variability during winter baseflow conditions was small, and the glacier melt tracer variation was higher, especially at the end of the ablation period. We applied a three‐component mixing model with electrical conductivity and oxygen‐18. Hydrograph separation (groundwater, glacier melt, and rain) was performed for 6 single glacier melt‐induced days (i.e., 6 events) during the ablation period 2016 (July to September). Median fractions (±uncertainty) of groundwater, glacier melt, and rain for the events were estimated at 49±2%, 35±11%, and 16±11%, respectively. Minimum and maximum glacier melt fractions at the subdaily scale ranged between 2±5% and 76±11%, respectively. A sensitivity analysis showed that the intraseasonal glacier melt tracer variability had a marked effect on the estimated glacier melt contribution during events with large glacier melt fractions of streamflow. Intra‐daily and spatial variation of the glacier melt tracer signature played a negligible role in applying the mixing model. The results of this study (a) show the necessity to apply a multiple sampling approach in order to characterize the glacier melt end‐member and (b) reveal the importance of groundwater and rainfall–runoff dynamics in catchments with a glacial flow regime.  相似文献   

Hydrochemical evaluation of changing glacier meltwater contribution to stream discharge: Callejon de Huaylas,Peru / Evaluation hydrochimique de la contribution évolutive de la fonte glaciaire à l'écoulement fluvial: Callejon de Huaylas,Pérou     

《水文科学杂志》2013,58(6)

Abstract

Discharge measurements, precipitation observations and hydrochemical samples from catchments of the Callejon de Huaylas watershed draining the Cordillera Blanca to the Rio Santa, Peru, facilitate estimating the glacier meltwater contribution to streamflow over different spatial scales using water balance and end-member mixing computations. A monthly water balance of the Yanamarey Glacier catchment shows elevated annual discharge over December 2001–July 2004 compared to 1998–1999, with net glacier mass loss in all months. Glacial melt now accounts for an estimated 58% of annual mean discharge, 23% greater than 1998–1999. At Lake Querococha, below Yanamarey (3.4% glacierized), a hydrochemical end-member mixing model estimates that 50% of the streamflow is derived from the glacier catchment. Average concentrations from the Rio Santa leaving the Callejon de Huaylas (8% glacierized) are modelled as a mixture with 66% deriving from glacierized tributaries of the Cordillera Blanca as opposed to the non-glacierized Cordillera Negra end member.  相似文献   

Controls of streamflow generation in small catchments across the snow–rain transition in the Southern Sierra Nevada,California     

Fengjing Liu  Carolyn Hunsaker  Roger C. Bales 《水文研究》2013,27(14):1959-1972

Processes controlling streamflow generation were determined using geochemical tracers for water years 2004–2007 at eight headwater catchments at the Kings River Experimental Watersheds in southern Sierra Nevada. Four catchments are snow‐dominated, and four receive a mix of rain and snow. Results of diagnostic tools of mixing models indicate that Ca²⁺, Mg²⁺, K⁺ and Cl^? behaved conservatively in the streamflow at all catchments, reflecting mixing of three endmembers. Using endmember mixing analysis, the endmembers were determined to be snowmelt runoff (including rain on snow), subsurface flow and fall storm runoff. In seven of the eight catchments, streamflow was dominated by subsurface flow, with an average relative contribution (% of streamflow discharge) greater than 60%. Snowmelt runoff contributed less than 40%, and fall storm runoff less than 7% on average. Streamflow peaked 2–4 weeks earlier at mixed rain–snow than snow‐dominated catchments, but relative endmember contributions were not significantly different between the two groups of catchments. Both soil water in the unsaturated zone and regional groundwater were not significant contributors to streamflow. The contributions of snowmelt runoff and subsurface flow, when expressed as discharge, were linearly correlated with streamflow discharge (R² of 0.85–0.99). These results suggest that subsurface flow is generated from the soil–bedrock interface through preferential pathways and is not very sensitive to snow–rain proportions. Thus, a declining of the snow–rain ratio under a warming climate should not systematically affect the processes controlling the streamflow generation at these catchments. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

A comparison of streamflow,salt and water balances in adjacent farmland and forest catchments in south‐western Victoria,Australia          下载免费PDF全文

S. Michael Adelana  P. Evan Dresel  Peter Hekmeijer  Hanna Zydor  John A. Webb  Michael Reynolds  Matthew Ryan 《水文研究》2015,29(6):1630-1643

A study of the hydrologic effects of catchment change from pasture to plantation was carried out in Gatum, south‐western Victoria, Australia. This study describes the hydrologic characteristics of two adjacent catchments: one with 97% grassland and the other one with 62% Eucalyptus globulus plantations. Streamflow from both catchments was intermittent during the 20‐month study period. Monthly streamflow was always greater in the pasture‐dominated catchment compared with the plantation catchment because of lower evapotranspiration in the pasture‐based catchment. This difference in streamflow was also observed even during summer 2010/2011 when precipitation was 74% above average (1954–2012) summer rainfall. Streamflow peaks in the plantation‐based catchment were smaller than in the pasture‐dominated system. Flow duration curves show differences between the pasture and plantation‐dominated catchments and affect both high‐flow and low‐flow periods. Groundwater levels fell (up to 4.4 m) in the plantation catchment during the study period but rose (up to 3.2 m) in the pasture catchment. Higher evapotranspiration in the plantation catchment resulted in falling groundwater levels and greater disconnection of the groundwater system from the stream, resulting in lower baseflow contribution to streamflow. Salt export from each catchment increases with increasing flow and is higher at the pasture catchment, mainly because of the higher flow. Reduced salt loading to streams due to tree planting is generally considered environmentally beneficial in saline areas of south‐eastern Australia, but this benefit is offset by reduced total streamflow. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Determination of runoff components using path analysis and isotopic measurements in a glacier‐covered alpine catchment (upper Hailuogou Valley) in southwest China          下载免费PDF全文

Bing Xing  Zhongfang Liu  Guodong Liu  Jing Zhang 《水文研究》2015,29(14):3065-3073

Monitoring of stable water isotopes (δ¹⁸O and δ²H) at the watershed scales can improve our understanding of complex hydrology and hydroclimatology of the watershed, especially in remote regions. Previous studies that used tracers for hydrograph separation are largely based on end‐member mixing approach (EMMA), but one drawback of this approach is that at least two independent tracers are required for multi‐component separation. Here we introduce a new approach—path analysis, in combination with isotopic measurements to investigate the runoff generation in a glacier‐covered alpine catchment (upper Hailuogou Valley) in southwest China. This newly developed method can not only provide a multi‐component hydrograph separation with the aid of only one tracer but also determine the direct and indirect influence of sources on streamflow. Path analysis show that the majority of streamflow is dominated by ice/snow meltwater that represents about 63–78% of the total discharge, whereas precipitation and groundwater contribute approximately 19–39% and 2–4% of the streamflow discharge, respectively. These results are in good agreement with those derived from EMMA (using ¹⁸O and Cl^? as tracers), corroborating that our proposed approach is successful in hydrograph separation of the catchment. This approach may provide new opportunities for the hydrograph separation of catchment with sparse data and be of interest to catchment hydrologists who seek to understand the behaviour of hydrologic systems. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Interpretation of homogeneity in δ18O signatures of stream water in a nested sub-catchment system in north-east Scotland     

S. M. Dunn  J. R. Bacon  C. Soulsby  D. Tetzlaff  M. I. Stutter  S. Waldron  I. A. Malcolm 《水文研究》2008,22(24):4767-4782

The isotope hydrology of a set of nested sub-catchments in the north-east of Scotland has been studied to examine the mixing processes and residence times of water in the catchments. The measured δ¹⁸O in stream waters was found to be exceptionally uniform both temporally and spatially. Hydrochemical mixing analyses showed that groundwater contributes between 62 and 90% of the stream flow in all sub-catchments. Model analysis indicated that the δ¹⁸O in stream water is indicative of a highly mixed system in which near surface runoff appears to be mixed with groundwater, within the soil profile, before being released from the catchment. Small fluctuations in the stream water δ¹⁸O response are generated by a small proportion (<10%) of less-well mixed water in infiltration excess runoff during storm events. A comparative application of the model to a nearby catchment, which has a lower proportion of groundwater runoff, demonstrated contrasting behaviour, with significantly less mixing of waters occurring and a more distinct difference in the age of runoff generated by different flow paths. This highlighted that standard methods for characterization of mixing mechanisms are often insufficient and may not discriminate between systems that have retained quite distinct flow paths throughout catchment transit, and those which have been mixed at some stage. Model sensitivity analysis also indicated that the simulated mean residence time of water varies most strongly in response to different parameters compared with the δ¹⁸O response. This has implications for estimating water residence times from isotope data. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Understanding hydrological processes in glacierized catchments: Evidence and implications of highly variable isotopic and electrical conductivity data     

Giulia Zuecco  Luca Carturan  Fabrizio De Blasi  Roberto Seppi  Thomas Zanoner  Daniele Penna  Marco Borga  Alberto Carton  Giancarlo Dalla Fontana 《水文研究》2019,33(5):816-832

The spatial and temporal characterization of geochemical tracers over Alpine glacierized catchments is particularly difficult, but fundamental to quantify groundwater, glacier melt, and rain water contribution to stream runoff. In this study, we analysed the spatial and temporal variability of δ²H and electrical conductivity (EC) in various water sources during three ablation seasons in an 8.4‐km² glacierized catchment in the Italian Alps, in relation to snow cover and hydro‐meteorological conditions. Variations in the daily streamflow range due to melt‐induced runoff events were controlled by maximum daily air temperature and snow covered area in the catchment. Maximum daily streamflow decreased with increasing snow cover, and a threshold relation was found between maximum daily temperature and daily streamflow range. During melt‐induced runoff events, stream water EC decreased due to the contribution of glacier melt water to stream runoff. In this catchment, EC could be used to distinguish the contribution of subglacial flow (identified as an end member, enriched in EC) from glacier melt water to stream runoff, whereas spring water in the study area could not be considered as an end member. The isotopic composition of snow, glacier ice, and melt water was not significantly correlated with the sampling point elevation, and the spatial variability was more likely affected by postdepositional processes. The high spatial and temporal variability in the tracer signature of the end members (subglacial flow, rain water, glacier melt water, and residual winter snow), together with small daily variability in stream water δ²H dynamics, are problematic for the quantification of the contribution of the identified end members to stream runoff, and call for further research, possibly integrated with other natural or artificial tracers.  相似文献   

Identifying evaporation fractionation and streamflow components based on stable isotopes in the Kaidu River Basin with mountain–oasis system in north‐west China          下载免费PDF全文

Chen Haiyan  Chen Yaning  Li Weihong  Hao Xinming  Li Yupeng  Zhang Qifei 《水文研究》2018,32(15):2423-2434

Based on stable isotopes in stream water, groundwater, and meltwater in the Kaidu River Basin, NW China, we estimated the evaporation enrichment of stable oxygen isotopes in different types of water and separated the contribution of each streamflow component in river run‐off. Our results indicated that δ¹⁸O and δ²H in stream water did not vary with altitude regularly but with seasons, with low concentrations in spring and high concentrations in summer. However, the seasonal variations of δ¹⁸O and δ²H in groundwater were not as obvious. The mean evaporation enrichment was between 26% and 44% for δ¹⁸O. Of the various water types under investigation, we found glaciers were influenced the most, showing an evaporation enrichment of 44%, followed by oasis groundwater (37%), stream water (36%), and mountain groundwater (26%). Overall, meltwater and groundwater were the predominant streamflow components, with their contributions were governed by temperature, and varied both temporally and specially. In the oasis region, groundwater was the predominant contributor (64% in spring, 50% in summer, and 66% in autumn), whereas in the mountains, groundwater was the dominant in spring (53%) and autumn (51%), and meltwater contributed the most in summer (52%). Precipitation contributed less than 15% to the streamflow.  相似文献   

Solute provenance,transport and denudation in a high arctic glacierized catchment     

R. Hodgkins  M. Tranter  J. A. Dowdeswell 《水文研究》1997,11(14):1813-1832

Recent understanding of chemical weathering in glacierized catchments has been focused on mid-latitude, Alpine catchments; comparable studies from the high latitudes are currently lacking. This paper attempts to address this deficiency by examining solute provenance, transport and denudation in a glacierized catchment at 78°N in the Svalbard High Arctic archipelago. Representative samples of snow, glacier ice, winter proglacial icing and glacier meltwater were obtained from the catchment during spring and summer 1993 and analysed for major ion chemistry. Seasonal variations in the composition of glacier meltwater occur and are influenced by proglacial solute acquisition from the icing at the very start of the melt season, and subsequently by a period of discharge of concentrated snowmelt caused by snowpack elution; weathering within the ice-marginal channels that drain the glacier, particularly carbonation reactions, continues to furnish solute to meltwater when suspended sediment concentrations increase later in the melt season. Partitioning the solute flux into its various components (sea-salt, crustal, aerosol and atmospheric sources) shows that c. 25% of the total flux is sea salt derived, consistent with the maritime location of the glacier, and c. 71% is crustally derived. Estimated chemical denudation, 160 meq m⁻² a⁻¹ sea salt-corrected cation equivalent weathering rate, is somewhat low compared with other studied glacierized catchments (estimates in the range 450–1000 meq m⁻² a⁻¹), which is probably attributable to the relatively short melt season and low specific runoff in the High Arctic. A positive relationship was identified between discharge and CO₂ drawdown owing to carbonation reactions in turbid meltwater. © 1997 John Wiley & Sons, Ltd.  相似文献   

Isotope hydrology and water sources in a heavily urbanized stream     

Christian Marx  Dörthe Tetzlaff  Reinhard Hinkelmann  Chris Soulsby 《水文研究》2021,35(10):e14377

Complex networks of both natural and engineered flow paths control the hydrology of streams in major cities through spatio-temporal variations in connection and disconnection of diverse water sources. We used spatially extensive and temporally intensive sampling of water stable isotopes to disentangle the hydrological sources of the heavily urbanized Panke catchment (~220 km²) in the north of Berlin, Germany. The isotopic data enabled us to partition stream water sources across the catchment using a Bayesian mixing analysis. The upper part of the catchment streamflow is dominated by groundwater (~75%) from gravel aquifers. In dry summer periods, streamflow becomes intermittent in the upper catchment, possibly as a result of local groundwater abstractions. Storm drainage dominates the responses to precipitation events. Although such events can dramatically change the isotopic composition of the upper stream network, storm drainage only accounts for 10%–15% of annual streamflow. Moving downstream, subtle changes in sources and isotope signatures occur as catchment characteristics vary and the stream is affected by different tributaries. However, effluents from a wastewater treatment plant (WWTP), serving 700,000 people, dominate stream flow in the lower catchment (~90% of annual runoff) where urbanization effects are more dramatic. The associated increase in sealed surfaces downstream also reduces the relative contribution of groundwater to streamflow. The volume and isotopic composition of storm runoff is again dominated by urban drainage, though in the lower catchment, still only about 10% of annual runoff comes from storm drains. The study shows the potential of stable water isotopes as inexpensive tracers in urban catchments that can provide a more integrated understanding of the complex hydrology of major cities. This offers an important evidence base for guiding the plans to develop and re-develop urban catchments to protect, restore, and enhance their ecological and amenity value.  相似文献   

From precipitation to runoff: stable isotopic fractionation effect of glacier melting on a catchment scale          下载免费PDF全文

Shiqiao Zhou  Zheng Wang  Daniel R. Joswiak 《水文研究》2014,28(8):3341-3349

Stable isotope variability and fractionation associated with transformation of precipitation/accumulation to firn to glacial river water is critical in a variety of climatic, hydrological and paleoenvironmental studies. This paper documents the modification of stable isotopes in water from precipitation to glacier runoff in an alpine catchment located in the central Tibetan Plateau. Isotopic changes are observed by sampling firnpack profiles, glacier surface snow/ice, meltwater on the glacier surface and catchment river water at different times during a melt season. Results show the isotopic fractionation effects associated with glacier melt processes. The slope of the δD‐δ¹⁸O regression line and the deuterium excess values decreased from the initial precipitation to the melt‐impacted firnpack (slope from 9.3 to 8.5 and average d‐excess from 13.4‰ to 7.4‰). The slope of the δD‐δ¹⁸O line further decreased to 7.6 for the glacier runoff water. The glacier surface snow/ice from different locations, which produces the main runoff, had the same δD‐δ¹⁸O line slope but lower deuterium excess (by 3.9‰) compared to values observed in the firnpack profile during the melt season. The δD‐δ¹⁸O regression line for the river water exhibited a lower slope compared to the surface snow/ice samples, although they were closely located on the δD‐δ¹⁸O plot. Isotope values for the river and glacier surface meltwater showed little scatter around the δD‐δ¹⁸O regression line, although the samples were from different glaciers and were collected on different days. Results indicate a high consistency of isotopic fractionation in the δD‐δ¹⁸O relationships, as well as a general consistency and temporal covariation of meltwater isotope values at the catchment scale. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Bedrock geology controls on catchment storage,mixing, and release: A comparative analysis of 16 nested catchments          下载免费PDF全文

Laurent Pfister  Núria Martínez‐Carreras  Christophe Hissler  Julian Klaus  Gwenael E. Carrer  Mike K. Stewart  Jeffrey J. McDonnell 《水文研究》2017,31(10):1828-1845

The bedrock controls on catchment mixing, storage, and release have been actively studied in recent years. However, it has been difficult to find neighbouring catchments with sufficiently different and clean expressions of geology to do comparative analysis. Here, we present new data for 16 nested catchments (0.45 to 410 km²) in the Alzette River basin (Luxembourg) that span a range of clean and mixed expressions of schists, phyllites, sandstones, and quartzites to quantify the relationships between bedrock permeability and metrics of water storage and release. We examined 9 years' worth of precipitation and discharge data, and 6 years of fortnightly stable isotope data in streamflow, to explore how bedrock permeability controls (a) streamflow regime metrics, (b) catchment storage, and (c) isotope response and catchment mean transit time (MTT). We used annual and winter precipitation–run‐off ratios, as well as average summer and winter precipitation–run‐off ratios to characterise the streamflow regime in our 16 study catchments. Catchment storage was then used as a metric for catchment comparison. Water mixing potential of 11 catchments was quantified via the standard deviation in streamflow δD (σδD) and the amplitude ratio (A_S/A_P) of annual cycles of δ¹⁸O in streamflow and precipitation. Catchment MTT values were estimated via both stable isotope signature damping and hydraulic turnover calculations. In our 16 nested catchments, the variance in ratios of summer versus winter average run‐off was best explained by bedrock permeability. Whereas active storage (defined here as a measure of the observed maximum interannual variability in catchment storage) ranged from 107 to 373 mm, total catchment storage (defined as the maximum catchment storage connected to the stream network) extended up to ~1700 mm (±200 mm). Catchment bedrock permeability was strongly correlated with mixing proxies of σδD in streamflow and δ¹⁸O A_S/A_P ratios. Catchment MTT values ranged from 0.5 to 2 years, based on stable isotope signature damping, and from 0.5 to 10 years, based on hydraulic turnover.  相似文献   

Hydrologic functioning of the deep critical zone and contributions to streamflow in a high‐elevation catchment: Testing of multiple conceptual models     

Ravindra Dwivedi  Thomas Meixner  Jennifer C. McIntosh  P.A. Ty Ferr  Christopher J. Eastoe  Guo‐Yue Niu  Rebecca L. Minor  Greg A. Barron‐Gafford  Jon Chorover 《水文研究》2019,33(4):476-494

High‐elevation mountain catchments are often subject to large climatic and topographic gradients. Therefore, high‐density hydrogeochemical observations are needed to understand water sources to streamflow and the temporal and spatial behaviour of flow paths. These sources and flow paths vary seasonally, which dictates short‐term storage and the flux of water in the critical zone (CZ) and affect long‐term CZ evolution. This study utilizes multiyear observations of chemical compositions and water residence times from the Santa Catalina Mountains Critical Zone Observatory, Tucson, Arizona to develop and evaluate competing conceptual models of seasonal streamflow generation. These models were tested using endmember mixing analysis, baseflow recession analysis, and tritium model “ages” of various catchment water sources. A conceptual model involving four endmembers (precipitation, soil water, shallow, and deep groundwater) provided the best match to observations. On average, precipitation contributes 39–69% (55 ± 16%), soil water contributes 25–56% (41 ± 16%), shallow groundwater contributes 1–5% (3 ± 2%), and deep groundwater contributes ~0–3% (1 ± 1%) towards annual streamflow. The mixing space comprised two principal planes formed by (a) precipitation‐soil water‐deep groundwater (dry and summer monsoon season samples) and (b) precipitation‐soil water‐shallow groundwater (winter season samples). Groundwater contribution was most important during the wet winter season. During periods of high dynamic groundwater storage and increased hydrologic connectivity (i.e., spring snowmelt), stream water was more geochemically heterogeneous, that is, geochemical heterogeneity of stream water is storage‐dependent. Endmember mixing analysis and ³H model age results indicate that only 1.4 ± 0.3% of the long‐term annual precipitation becomes deep CZ groundwater flux that influences long‐term deep CZ development through both intercatchment and intracatchment deep groundwater flows.  相似文献   

Isotopic time series partitioning of streamflow components under regional climate change in the Urumqi River,northwest China     

Sun Congjian  Chen Yaning  Li Weihong  Li Xingong  Yang Yuhui 《水文科学杂志》2013,58(8):1443-1459

ABSTRACT

We investigated the isotopic composition of the Urumqi River and documented seasonal variability attributable to the mixing of various flow sources. Next, we applied these isotopic signals to partition the sources and studied their temporal variability in summer. The isotope hydrology separation results indicated that groundwater is the dominant streamflow source (approximately 62.7%) in the Urumqi River. Precipitation is an important source for the Urumqi River; approximately 19.1–20.7% of the runoff came from precipitation during summer and early autumn. In summer, approximately 21.1% of the runoff is derived from glacial meltwater. In summer, with the increasing distance to the glacier front, groundwater accounts for a larger and larger percentage of the river water, and the contributions of precipitation and glacial meltwater gradually diminish. Throughout 2012, the proportions of precipitation and glacial meltwater in the streamflow were 17.6% and 14.7%, respectively, and only 5% of the streamflow was derived from snowmelt.