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1.
Although riparian zones are well known to reduce nitrogen (N) and phosphorus (P) runoff to streams, they also have the potential to affect greenhouse gas (CO2, N2O, and CH4) fluxes to the atmosphere. Following large storms, soil biogeochemical conditions often become more reduced, especially in oxbow depressions and side channels, which can lead to hot moments of greenhouse gas production. Here, we investigate the impact of the remnants of Hurricane Irene and Tropical Storm Lee on riparian zone hydrology (water table: WT), and biogeochemistry (oxidation‐reduction potential [ORP], dissolved oxygen [DO], NO3?, PO43?, CO2, N2O, CH4). Results indicate that large storms have the potential to reset WT levels for weeks to months. Overbank flooding at our site following Irene and Lee led to the infiltration of well‐oxygenated water at depth (higher DO and ORP) while promoting the development of anoxic conditions within soil aggregates near the soil surface (increased N2O and CH4 fluxes). A short‐term increase in CO2 emission was observed following Irene at our site where aerobic respiration was water‐limited. Over a 2‐year period, an oxbow depression exhibited higher WT, higher N2O and CH4 fluxes (hot moment), higher CO2 fluxes (seasonal), and lower NO3? concentrations (seasonal) than the rest of the riparian zone. However, neither Irene, nor Lee, nor the oxbow depression significantly impacted PO43?. Dissolved organic carbon, ORP, and DO data illustrate the time‐lag (>20 years) between the creation of an oxbow depression and the development of reducing conditions despite clear differences in riparian zone and oxbow WT dynamics.  相似文献   

2.
The spatial and temporal variability of groundwater–surface‐water (GW–SW) interactions was investigated in an intensively utilized salmon spawning riffle. Hydrochemical tracers, were used along with high‐resolution hydraulic head and temperature data to assess hyporheic dynamics. Surface and subsurface hydrochemistry were monitored at three locations where salmon spawning had been observed in previous years. Temperature and hydraulic head were monitored in three nests of three piezometers located to characterize the head, the run and the tail‐out of the riffle feature. Hydrochemical gradients between surface and subsurface water indicated increasing GW influence with depth into the hyporheic zone. Surface water was characterized by high dissolved oxygen (DO) concentrations, low alkalinity and conductivity. Hyporheic water was generally characterized by high levels of alkalinity and conductivity indicative of longer residence times, and low DO, indicative of reducing conditions. Hydrochemical and temperature gradients varied spatially over the riffle in response to changes in local GW–SW interactions at the depths investigated. Groundwater inputs dominated the head and tail of the riffle. The influence of SW increased in the area of accelerating flow and decreasing water depth through the run of the riffle. Temporal GW–SW interactions also varied in response to changing hydrological conditions. Gross changes in hyporheic hydrochemistry were observed at the weekly scale in response to changing flow conditions and surface water inputs to the hyporheic zone. During low flows, caused by freezing or dry weather, hyporheic hydrochemistry was dominated by GW inputs. During higher flows hyporheic hydrochemistry indicated that SW contributions increased. In addition, high‐resolution hydraulic head data indicated that rapid changes in GW–SW interactions occurred during hydrological events. The spatial, and possibly the temporal, variability of GW–SW interactions had a marked effect on the survival of salmon ova. It is concluded that hyporheic dynamics and their effect on stream ecology should be given increased consideration by fisheries and water resource managers. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

3.
Alan R. Hill 《水文研究》2012,26(20):3135-3146
The effect of preferential flow in soil pipes on nitrate retention in riparian zones is poorly understood. The characteristics of soil pipes and their influence on patterns of groundwater transport and nitrate dynamics were studied along four transects in a 1‐ to >3‐m deep layer of peat and marl overlying an oxic sand aquifer in a riparian zone in southern Ontario, Canada. The peat‐marl deposit, which consisted of several horizontal layers with large differences in bulk density, contained soil pipes that were generally 0.1 to 0.2 m in diameter and often extended vertically for 1 to >2 m. Springs that produced overland flow across the riparian area occurred at some sites where pipes extended to the peat surface. Concentrations of NO3?–N (20–30 mg L?1) and dissolved oxygen (DO) (4–6 mg L?1) observed in peat pipe systems and surface springs were similar to values in the underlying sand aquifer, indicating that preferential flow transported groundwater with limited nitrate depletion. Low NO3?–N concentrations of <5 mg L?1 and enriched δ15N values indicated that denitrification was restricted to small areas of the peat where pipes were absent. Groundwater DO concentrations declined rapidly to <2 mg L?1 in the peat matrix adjacent to pipes, whereas high NO3?–N concentrations of >15 mg L?1 extended over a larger zone. Low dissolved organic carbon values at these locations suggest that supplies of organic carbon were not sufficient to support high rates of denitrification, despite low DO conditions. These data indicate that it is important to develop a greater understanding of pipes in peat deposits, which function as sites where the transport of large fluxes of water with low biogeochemical reaction rates can limit the nitrate removal capacity of riparian zones. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

4.
邓焕广  张智博  刘涛  殷山红  董杰  张菊  姚昕 《湖泊科学》2019,31(4):1055-1063
为了解城市湖泊不同水生植被区水体温室气体的溶存浓度及其影响因素,于2015年4-11月按每月2次的频率采用顶空平衡法对聊城市铃铛湖典型植被区——菹草区、莲藕区和睡莲区表层水中CO2、CH4和N2O的溶存浓度进行监测,计算水中温室气体的饱和度和排放通量,并测定水温（T）、pH、溶解氧（DO）、叶绿素a及营养盐浓度等理化指标,以探究水体环境因子对温室气体溶存浓度的影响.结果表明,铃铛湖各植被区水体温室气体均处于过饱和状态,是大气温室气体的"源";莲藕区CH4浓度、饱和度和排放通量均显著高于菹草区,而各植被区N2O和CO2均无显著性差异;不同植被区湖水中DO、总氮（TN）、总磷（TP）和硝态氮（NO3--N）浓度具有显著差异,其中DO、TN和NO3--N浓度均表现为菹草区最高,莲藕区最低,而TP浓度则正好相反;各植被区温室气体浓度和水环境参数间的相关分析和多元回归分析的结果表明,水生植物可通过影响水体的理化性质对温室气体的产生和排放产生显著差异影响,在菹草区亚硝态氮（NO2--N）、NO3--N、T和DO是控制水体温室气体浓度的主要因子;睡莲区为TP和pH;莲藕区则为pH、NO2--N和DO.  相似文献   

5.
The spatial and temporal patterns of water quality in Kuwait Bay have been investigated using data from six stations between 2009 and 2011. The results showed that most of water quality parameters such as phosphorus (PO4), nitrate (NO3), dissolved oxygen (DO), and Total Suspended Solids (TSS) fluctuated over time and space. Based on Water Quality Index (WQI) data, six stations were significantly clustered into two main classes using cluster analysis, one group located in western side of the Bay, and other in eastern side. Three principal components are responsible for water quality variations in the Bay. The first component included DO and pH. The second included PO4, TSS and NO3, and the last component contained seawater temperature and turbidity. The spatial and temporal patterns of water quality in Kuwait Bay are mainly controlled by seasonal variations and discharges from point sources of pollution along Kuwait Bay’s coast as well as from Shatt Al-Arab River.  相似文献   

6.
Interactions of surface water and groundwater (SW–GW) play an important role in the physical, chemical, and ecological processes of riparian zones. The main objective of this study was to describe the two‐dimensional characteristics of riverbank SW–GW interactions and to quantify their influence factors. The SW–GW exchange fluxes for six sections (S1 to S6) of the Qinhuai River, China, were estimated using a heat tracing method, and field hydrogeological and thermodynamic parameters were obtained via inverse modelling. Global sensitivity analysis was performed to compare the effects of layered heterogeneity of hydraulic conductivity and river stage variation on SW–GW exchange. Under the condition of varied river stage, only the lateral exchange fluxes at S1 apparently decreased during the monitoring period, probably resulting from its relatively higher hydraulic conductivity. Meanwhile, the SW–GW exchanges for the other five sections were quite stable over time. The lateral exchange fluxes were higher than the vertical ones. The riverbank groundwater flow showed different spatial variation characteristics for the six sections, but most of the higher exchange fluxes occurred in the lower area of a section. The section with larger hydraulic conductivity has an apparent dynamic response to surface water and groundwater level differences, whereas lower permeabilities severely reduced the response of groundwater flow. The influence of boundary conditions on SW–GW interactions was restricted to a limited extent, and the impact extent will expand with the increase of peak water level and hydraulic conductivity. The SW–GW head difference was the main influence factors in SW–GW interactions, and the influence of both SW–GW head difference and hydraulic conductivity decreased with an increase of the distance from the surface water boundary. For each layer of riverbank sediment, its hydraulic conductivity had greater influence on its groundwater flow than the other layers, whereas it had negligible effects on its overlying/underlying layers. Consequently, the variations in river stage and hydraulic conductivity were the main factors influencing the spatial and temporal characteristics of riverbank groundwater flow, respectively.  相似文献   

7.
V. Chaplot  O. Ribolzi 《水文研究》2014,28(21):5354-5366
Dissolved organic carbon (DOC) is a key component of the global carbon cycle, but, to date, large uncertainties still exist on its source and fate in first‐order streams. In a 23 ha rangeland and steep‐slope headwater of South Africa, our aim was to quantify the contribution of overland flow (OF), soil water (SW) and ground water (GW) to DOC fluxes (DOCF), and to interpret the results in terms of DOC sources and fate. The average 2010–2011 DOC concentration (DOCC) at the catchment outlet was 4.7 mg C l?1 with a standard error of ±2.5 mg C l?1, which was significantly lower than in SW (15.2 ± 1.6 mg C l?1) and OF (11.9 ± 0.8 mg C l?1), but higher than in GW (2.3 ± 0.6 mg C l?1). Based on end‐member mixing using Si and Na concentration in the water compartments, the average SW contribution to DOCF was 66.4%, followed by OF (30.0%) and GW (3.6%). The resulting estimated DOCF at the catchment outlet was 8.05 g C m2 y?1. This was much higher than the observed value of 2.80 g C m2 y?1, meaning that 5.25 g C m2 y?1 or 65% of the DOC is lost during its downslope and/or downstream transport to the catchment outlet. Complementary investigations revealed that the DOCC in SW dropped from 15.2 ± 1.6 to 2.6 ± 0.3 mg C l?1 during its downslope transport to the river system, which corresponded to a net loss of 5.10 g C m2 y?1, or 97% of the catchment DOC losses. These results on DOC sources and potential fate in headwaters are expected to improve our understanding of the impact of hydrology on the global C‐cycle. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

8.
Spatial and seasonal variations in CO2 and CH4 concentrations in streamwater and adjacent soils were studied at three sites on Brocky Burn, a headwater stream draining a peatland catchment in upland Britain. Concentrations of both gases in the soil atmosphere were significantly higher in peat and riparian soils than in mineral soils. Peat and riparian soil CO2 concentrations varied seasonally, showing a positive correlation with air and soil temperature. Streamwater CO2 concentrations at the upper sampling site, which mostly drained deep peats, varied from 2·8 to 9·8 mg l?1 (2·5 to 11·9 times atmospheric saturation) and decreased markedly downstream. Temperature‐related seasonal variations in peat and riparian soil CO2 were reflected in the stream at the upper site, where 77% of biweekly variation was explained by an autoregressive model based on: (i) a negative log‐linear relationship with stream flow; (ii) a positive linear relationship with soil CO2 concentrations in the shallow riparian wells; and (iii) a negative linear relationship with soil CO2 concentrations in the shallow peat wells, with a significant 2‐week lag term. These relationships changed markedly downstream, with an apparent decrease in the soil–stream linkage and a switch to a positive relationship between stream flow and stream CO2. Streamwater CH4 concentrations also declined sharply downstream, but were much lower (<0·01 to 0·12 mg l?1) than those of CO2 and showed no seasonal variation, nor any relationship with soil atmospheric CH4 concentrations. However, stream CH4 was significantly correlated with stream flow at the upper site, which explained 57% of biweekly variations in dissolved concentrations. We conclude that stream CO2 can be a useful integrative measure of whole catchment respiration, but only at sites where the soil–stream linkage is strong. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

9.
Abstract

This study presents a new methodology for estimation of input data measurement-induced uncertainty in simulated dissolved oxygen (DO) and nitrate-nitrogen (NO3-N) concentrations using the Hydrological Simulation Program–FORTRAN (HSPF) model and data from the Amite River, USA. Simulation results show that: (1) a multiplying factor of 1.3 can be used to describe the maximum error in temperature measurements; similarly, a multiplying factor of 1.9 was estimated to accommodate the maximum of ±5% error in rainfall measurements; (2) the uncertainty in simulated DO concentration due to positive temperature measurement errors can be described with a normal distribution, N(0.062, 0.567); (3) the uncertainty in simulated NO3-N concentration due to rainfall measurement errors follows a generalized extreme value distribution; and (4) the probability density functions can be utilized to determine the measurement-induced uncertainty in simulated DO and NO3-N concentrations according to the risk level acceptable in water quality management.

Editor D. Koutsoyiannis

Citation Patil, A. and Deng, Z.-Q., 2012. Input data measurement-induced uncertainty in watershed modelling. Hydrological Sciences Journal, 57 (1), 118–133.  相似文献   

10.
三峡大坝上下游水质时空变化特征   总被引：6，自引：2，他引：4  
为探索三峡大坝上下游（坝上99.9 km、坝下63.0 km、全长162.9 km）水质时空变化特征,运用主成分分析和方差分析对2016年近坝段水质时空变化特征进行了分析.主成分分析表明,水文因子流量（Q）、气温（T）、水位（Z）和水质因子（水温（WT）、pH、电导率（EC）、溶解氧（DO）、悬浮物（SS）、高锰酸盐指数（CODMn）、硫酸盐（SO42-）、氟化物（F-）、总硬度（T-Hard）、硝态氮（NO3--N）、总氮（TN）和硒（Se））的变化主导着研究区域水质变化;各采样点主成分得分和双因素方差分析结果显示研究区域水质因子时间变化主要呈现出季节和不同水库运行时期的差异.消落期（2-5月）,T-Hard、F-、SO42-和EC是影响河流水质变化的主导因子;汛期（7-8月）,Q、SS、CODMn、NO3--N、TN和Se是影响河流水质变化的主导因子;T和WT主导着汛末（9月）河流水质变化,并引起了DO等理化特性的变化;高水位运行期（12月）,Cl-是影响河流水质变化的主导因子.现阶段,DO、有机污染物（CODMn）、无机盐（SO42-和F-）、营养盐类（NO3--N和TN）、类金属元素（Se）和水体的矿化程度（T-Hard）的变化主导着区域水质的变化,是三峡大坝近坝段水域水质的控制因子.方差分析表明,河流的理化特性（DO、pH和SS）、营养盐组分构成（NH3-N和NO3--N）、无机盐类（EC和Cl-）、石油类有机污染物及粪大肠菌群（FC）等指标在坝上与坝下断面存在显著性差异.气温、水温、降雨、含沙量的季节性影响因素和水库调度运行模式是影响近坝段水质时间差异的主要因子;空间差异主要受城区污染排放和三峡水库调度引起的坝上和坝下水文和水动力学条件差异影响.因此控制研究区域因人类活动等造成的外源性污染,并针对不同类污染物质的季节变化特征实施合理的水库运行方式是近坝段水质提升的关键.  相似文献   

11.
This paper presents a novel triple‐layer model, called VART DO‐3L, for simulation of spatial variations in dissolved oxygen (DO) in fine‐grained streams, characterized by a fluid mud (fluff or flocculent) layer (an advection‐dominated storage zone) as the interface between overlying stream water and relatively consolidated streambed sediment (a diffusion‐dominated storage zone). A global sensitivity analysis is conducted to investigate the sensitivity of VART DO‐3L model input parameters. Results of the sensitivity analysis indicate that the most sensitive parameter is the relative size of the advection‐dominated storage zones (As/A), followed by a lumped reaction term (R) for the flocculent layer, biological reaction rate (μo) in diffusive layer and biochemical oxygen demand concentration (L) in water column. In order to address uncertainty in model input parameters, Monte Carlo simulations are performed to sample parameter values and to produce various parameter combinations or cases. The VART DO‐3L model is applied to the Lower Amite River in Louisiana, USA, to simulate vertical and longitudinal variations in DO under the cases. In terms of longitudinal variation, the DO level decreases from 7.9 mg l at the Denham Springs station to about 2.89 mg l?1 at the Port Vincent station. In terms of vertical variation, the DO level drops rapidly from the overlying water column to the advection‐dominated storage zone and further to the diffusive layer. The DO level (CF) in the advective layer (flocculent layer) can reach as high as 40% of DO concentration (C) in the water column. The VART DO‐3L model may be applied to similar rivers for simulation of spatial variations in DO level. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

12.
From July 2003 to July 2004, samples were collected on Chongming Island east tidal flat every two months. The research showed that the nitrous oxide (N2O) production rate was very low in the water, Chongming east tidal flat (CM) sediment was the N2O source of the water. Sediment N2O natural production rate was between -0.08 and 1.74 μmolN·m-2·h-1. N2O natural production rate was higher in the summer. The difference of the N2O natural production rate in the different tidal flats, the correlation between the N2O natural production rate and the denitrification rate, and those with the temperature and DO indicate that middle tidal flat sediment denitrification was the main process of the N2O production, while in the low tidal flat sediment, the production of the N2O came from several processes of the nitrogen cycling. Tidal flat sediment denitrification reaction was stronger in summer and winter but relatively lower in the late autumn and early spring. Seasonal change of the sediment denitrification rate was wide, from 1.12 to 33.34 μmolN·m-2·h-1. Temperature, DO and the coactions of them had the prominent effect on the tidal flat sediment denitrification.  相似文献   

13.
This paper presents a novel method for assessing hyporheic water quality dynamics using advances in sensor technology. High‐resolution (15 min) dissolved oxygen (DO) and hydraulic head data were combined to assess groundwater–surface water (GW–SW) interactions in the hyporheic zone. DO concentrations varied at fine temporal and spatial scales, depending on the relative contributions of GW and SW. The effect of sample frequency on observed patterns of variability was assessed with reference to studies of the ecology of salmon spawning habitat. Conventional approaches fail to capture the full range of temporal variability in hyporheic water quality and demonstrate the need to reassess the interpretations of previous studies of the hyporheic zone. © Crown Copyright 2006. Reproduced with the permission of Her Majesty's Stationery Office. Published by John Wiley & Sons, Ltd.  相似文献   

14.
湖光岩玛珥湖水体中营养盐的时空分布特征及其影响因素   总被引：1，自引：0，他引：1  
湖光岩玛珥湖是世界上最大的玛珥湖,它几乎是封闭的,受外界的干扰小.目前有关玛珥湖的研究主要集中在古气候及生态环境研究方面,而有关玛珥湖营养盐在一年中的生物地球化学循环的研究较少,因此研究湖光岩玛珥湖营养盐的生物地球化学过程具有重要意义.于2015年10月-2016年9月对湖光岩玛珥湖全水柱的营养盐及其他相关参数进行逐月调查,分析营养盐的结构特征、垂直分布特征和时间变化情况,并讨论营养盐时空变化的影响因素.结果表明,湖光岩玛珥湖水中的无机氮（DIN）以铵态氮（NH4+-N）为主（>60%）,其次是硝态氧（NO3--N）,亚硝态氮（NO2--N）所占比利最低.湖光岩玛珥湖水中的硅酸盐（SiO32--Si）浓度较高,水体浮游植物生长受磷限制.冬季风期间,水体垂直混合较均匀,导致营养盐的垂直分布比较均匀;夏季风期间,水体层化,营养盐浓度在浅层水体较低,在深层水体较高.湖光岩玛珥湖表层水中的NO3--N、NH4+-N和SiO32--Si具有明显的时间变化规律：NO3--N浓度从10月-次年3月升高,从3-9月降低;NH4+-N浓度从10月-次年5月降低;SiO32--Si浓度从11月-次年5月降低,从5-9月持续升高.营养盐浓度的时间变化受有机质的矿化分解、水体的季节性混合、浮游植物的吸收、降雨的输入等多种因素的综合影响.  相似文献   

15.
Tree roots contribute to the resistance of riparian sediments to physical deformation and disintegration. Understanding reinforcement by roots requires information on root distributions within riparian soils and sediments. Continuous‐depth models or curves have been proposed to describe vertical root density variations, providing useful indicators of the types of function that may be appropriate to riparian trees, but have generally been estimated for terrestrial species or broad vegetation types rather than riparian species or environments. We investigated vertical distributions of roots >0.1 mm diameter of a single riparian tree species (Populus nigra L.) along the middle reaches of a single river (Tagliamento River, Italy), where Populus nigra dominates the riparian woodland. Root density (hundreds m?2) and root area ratio (RAR in cm2 m?2) were measured within 10 cm depth increments of 24 excavated bank profiles across nine sites. Sediment samples, extracted from distinct strata within the profiles, were analysed for moisture content, organic matter content and particle size. Statistical analyses identified two groups of wetter and drier profiles and five sediment types. Following loge‐transformation of root density and RAR, linear regression analysis explored their variation with depth and, using dummy variables, any additional influence of moisture and sediment type. Significant linear regression relationships were estimated between both root density and RAR and depth which explained only 15% and 8% of the variance in the data. Incorporating moisture and then sediment characteristics into the analysis increased the variance explained in root density to 29% and 36% and in RAR to 14% and 26%. We conclude that riparian tree root density and RAR are highly spatially variable and are poorly explained by depth alone. Complex riparian sedimentary structures and moisture conditions are important influences on root distributions and so need to be incorporated into assessments of the contribution of roots to river bank reinforcement. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

16.
Seasonal and diurnal variations in CH4 concentration in the water of the Don River and Taganrog Bay are examined, and two maximums are recognized in the seasonal variations. The diurnal variations are shown to be affected by the meteorological conditions.  相似文献   

17.
Mineralization of 14C‐radiolabled vinyl chloride ([1,2‐14C] VC) and cis‐dichloroethene ([1,2‐14C] cis‐DCE) under hypoxic (initial dissolved oxygen (DO) concentrations about 0.1 mg/L) and nominally anoxic (DO minimum detection limit = 0.01 mg/L) was examined in chloroethene‐exposed sediments from two groundwater and two surface water sites. The results show significant VC and dichloroethene (DCE) mineralization under hypoxic conditions. All the sample treatments exhibited pseudo‐first‐order kinetics for DCE and VC mineralization over an extended range of substrate concentrations. First‐order rates for VC mineralization were approximately 1 to 2 orders of magnitude higher in hypoxic groundwater sediment treatments and at least three times higher in hypoxic surface water sediment treatments than in the respective anoxic treatments. For VC, oxygen‐linked processes accounted for 65 to 85% of mineralization at DO concentrations below 0.1 mg/L, and 14CO2 was the only degradation product observed in VC treatments under hypoxic conditions. Because the lower detection limit for DO concentrations measured in the field is typically 0.1 to 0.5 mg/L, these results indicate that oxygen‐linked VC and DCE biodegradation can be significant under field conditions that appear anoxic. Furthermore, because rates of VC mineralization exceeded rates of DCE mineralization under hypoxic conditions, DCE accumulation without concomitant accumulation of VC may not be evidence of a DCE degradative “stall” in chloroethene plumes. Significantly, mineralization of VC above the level that could reasonably be attributed to residual DO contamination was also observed in several nominally anoxic (DO minimum detection limit = 0.01 mg/L) microcosm treatments.  相似文献   

18.
The relationship between solute concentrations and discharge can inform an integrated understanding of hydrological and biogeochemical processes at watershed scales. Recent work from multiple catchments has shown that there is typically little variation in concentration relative to large variations in discharge. This pattern has been described as chemostatic behavior. Pond Branch, a forested headwater catchment in Maryland, has been monitored for stream nitrate (NO3?) concentrations at weekly intervals for 14 years. In the growing season and autumn of 2011 a high‐frequency optical NO3? sensor was used to supplement the long‐term weekly data. In this watershed, long‐term weekly data show that NO3? concentrations decrease with increasing discharge whereas 6 months of 15‐minute sensor observed concentrations reveal a more chemostatic behavior. High‐frequency NO3? concentrations from the sensor collected during different storm events reveal variable concentration–discharge patterns highlighting the importance of high resolution data and ecohydrological drivers in controlling solute export for biologically reactive solutes such as NO3?.  相似文献   

19.
Three main reservoirs were identified that contribute to the shallow subsurface flow regime of a valley drained by a fourth‐order stream in Brittany (western France). (i) An upland flow that supplied a wetland area, mainly during the high‐water period. It has high N‐NO3? and average Cl? concentrations. (ii) A deep confined aquifer characterized by low nitrate and low chloride concentrations that supplied the floodplain via flow upwelling. (iii) An unconfined aquifer under the riparian zone with high Cl? and low N‐NO3? concentrations where biological processes removed groundwater nitrate. This aquifer collected the upland flow and supplied a relict channel that controlled drainage from the whole riparian zone. Patterns of N‐NO3? and Cl? concentrations along riparian transects, together with calculated high nitrate removal, indicate that removal occurred mainly at the hillslope–riparian zone interface (i.e. first few metres of wetland), whereas dilution occurred in lower parts of the transects, especially during low‐water periods and at the beginning of recharge periods. Stream flow was modelled as a mixture of water from the three reservoirs. An estimation of these contributions revealed that the deep aquifer contribution to stream flow averaged 37% throughout the study period, while the contribution of the unconfined reservoir below the riparian zone and hillslope flow was more variable (from ca 6 to 85%) relative to rainfall events and the level of the riparian water table. At the entire riparian zone scale, NO3? removal (probably from denitrification) appeared most effective in winter, despite higher estimated upland NO3? fluxes entering the riparian zone during this period. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

20.
Groundwater dynamics play an important role in runoff generation and hydrologic connectivity between hillslopes and streams. We monitored a network of 14 shallow groundwater (GW) wells in a 3.2 km2 experimental catchment in the Scottish Highlands. Wells were placed in three contrasting landscape units with different hydropedological characteristics and different topographic positions relative to the stream network, encompassing a catena sequence from freely draining podzols on steeper hillslopes to increasingly thick peats (histosols) in the valley bottom riparian zone. GW dynamics were characterized by statistical analyses of water table fluctuations, estimation of variabilities in lag times and hysteresis response in relation to streamflow. The three landscape units had distinct storage–discharge relationships and threshold responses with a certain GW level above which lateral flow dominates. Steeper hillslopes with freely draining podzols were characterized by GW fluctuations of around 150 cm in the underlying drift. GW usually showed peak response up to several hours after stream flow. During persistent wet periods the water table remained in the soil profile for short spells and connected shallow flow paths in the near surface horizons to the lower hillslopes. In the peaty gleys in the lower foot slopes, GW was characterized by a water table generally within 20 cm of the soil surface, though at some locations this could fall to 50 cm in extreme dry periods. GW responses were usually a few hours prior to the stream responses. In riparian peats, the water table was also usually less than 20 cm deep and responded several hours before the stream. These riparian peat soils remain at, or very near saturation with near‐continuous GW–surface water connectivity. In contrast, the steeper slopes remain disconnected for prolonged periods and need large recharge events to overcome storage thresholds. GW responses vary seasonally, and landscape controls on the spatial organization of GW dynamics are strongest at low flows and in small events. During wettest periods, limited storage and extensive saturation weaken such controls. This study demonstrated that montane catchments can have highly dynamic GW stores, which are important in generating both storm flows and baseflows. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

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