共查询到20条相似文献，搜索用时 46 毫秒
1.
《Journal of African Earth Sciences》2008,50(2-4):255-267
To improve the enrichment of the Thanetian marine phosphate ore deposit from the quarry of Bled El Hadba (Djebel Onk, Algeria) before its exploitation, we first conducted a joint study using different techniques for comparison. These studies reveal that magnetic minerals play a significant role within the matrix of the central productive unit which is squeezed between two other units. Magnetic separation procedures show that there are some positive correlations between magnetic susceptibility and grain size fraction (80–250 μm). These dolomite-rich fractions are more clearly separated. Different tools were used to characterize the magnetic minerals (X-ray, microprobe, differential scanning calorimetry, thermogravimetric and thermomagnetic analyses). They show correlations between magnetic phases and the presence of associated magnetic minerals within the matrix or included in the phosphate ore deposit. They enabled us to distinguish a series of magnetic minerals (magnetite, hematite, maghemite, goethite, ilmenite, pyrite, iron–titanium oxide and titanium oxide sulphate) and to determine that Fe and Ti are prevalent in the separated fractions, following the same variation as Mg. The phosphorous (phosphate) rate is higher in the non-magnetic material, especially in the layers that are rich in dolomitic carbonates (upper and lower units), which could be trapped within the dolomitic matrix, while Magnesium (dolomite) is more important in the magnetic fraction. The separation of phosphate elements and dolomite carbonates is effective and therefore the ore can be enriched through magnetic procedures. Comparison between products enriched by magnetic separation, flotation and calcination showed important differences, chemically, economically and technically speaking. 相似文献
2.
应用矿物磁测技术和X射线衍射研究氧化土中的磁性矿物 总被引：3，自引：2，他引：1
应用矿物磁测、Ｘ射线衍射和化学分析对氧化土的磁性矿物进行了研究。结果表明矿物磁测及磁分离技术与Ｘ射线衍射结合是鉴别土壤中磁性矿物的类型及其晶粒特征的有效方法,证明氧化土中的主要氧化铁矿物是赤铁矿和磁赤铁矿,针铁矿次之,磁铁矿偶见,其磁赤铁矿的含量可达１．６２％￣１．９２％。土壤中磁性矿物的晶粒特征多以超顺磁性和稳定单畴态存在,认为磁性矿物的成因是通过缓慢的成土化学作用产生的。 相似文献
3.
磁组构是由岩石中磁性矿物定向分布而产生的组构特征,因此磁组构分析是研究岩石组构常用的技术手段,它具有
见效快、灵敏度高、无损样品等特点,近年来得到广泛应用。然而在磁组构研究工作中钻取定向样品或定向手标本时,常
常会遇到天然样品含有裂缝且裂缝中充填大量近地表沉积物和自生矿物。本文针对辉绿岩裂缝充填物对其磁组构结果的影
响程度做了详细研究,选用160个含裂缝的辉绿岩岩芯定向样品,通过对比去除裂缝充填物前后的磁组构变化,发现实验
前后所有样品磁化率大小变化率平均值<1%,磁组构方向变化平均值<1°,因此认为辉绿岩裂缝物质对其磁组构影响甚微。
矿物学和岩石磁学分析表明裂隙充填物主要为石英、长石,以及少量赤铁矿、黄铁矿和绿泥石等表生矿物。而辉绿岩的携
磁矿物主要是亚铁磁性的磁铁矿,其磁化率强度约为同等质量裂缝填充物的30倍,致使辉绿岩中的裂隙充填物对磁组构的
影响很小。 相似文献
4.
An investigation of recovering finely divided mineral particles by centrifugal forces has been carried out.A theoretical analysis of the separation efficiency for various heavy minerals with density ranging between 5 and 19.3 g/cm3 against silica particles has been made initially. The size range considered in this study was 1–5 microns. The separation efficiency of these heavy minerals from silica was found to show typically a recovery over 95% with 80% purity.A system containing cassiterite and silica particles with 1–5 microns has been chosen as a model system in experiments. The experimental results were in good agreement with the theoretical predictions. Better separations were observed at higher pH's than pH 4 due to better dispersion of these minerals at the higher pH range. 相似文献
5.
Effects of various commonly used pretreatments such as desliming, ultrasonic scrubbing and leaching with dilute nitric, hydrofluoric and sodium hydroxide solutions on the electrokinetic properties of quartz in aqueous solutions are reported. The study showed that treatments with various reagents often used in mineral processing research in the past to clean minerals can affect, sometimes severly, the electrokinetic properties of quartz. The change in these properties during subsequent aging is also found to be governed by the type of treatment used. This study also shows the need in mineral research for standardization of mineral preparation techniques in order that the discrepancy in data reported for surface properties in literature can be minimized. 相似文献
6.
对马钢凹山铁矿区断层带中规模较大的粘土矿,采用化学分析、岩矿鉴定、Ｘ衍射分析、红外吸收光谱分析、差热分析、透射电镜及物理工艺性能等综合分析测试方法进行了研究,查明其岩石、矿石类型及６种类型矿石的物质组分和矿物特征、２组矿石样品的物理工艺性能,在此基础上,从选矿和提高矿石质量等方面提出了意见 相似文献
7.
Influence of sedimentary setting on the use of magnetic susceptibility: examples from the Devonian of Belgium 总被引：1，自引：0，他引：1
Bulk magnetic susceptibility measurements on sedimentological samples from all geological periods have been used widely in the last two decades for correlations and as a proxy for sea‐level variations. This paper explores the link between magnetic susceptibility, depositional setting and environmental parameters. These environmental parameters include distal–proximal transects, microfacies successions and fourth‐order trends on different carbonate platform types (platform, ramp, carbonate mound or atoll) during different Devonian stages (Eifelian, Givetian and Frasnian). Average magnetic susceptibility values over a distal–proximal‐trending facies succession vary markedly with depositional setting. On carbonate platforms, average magnetic susceptibility generally increases towards the top of shallowing‐upward sequences. On a distal–proximal transect, average magnetic susceptibility is intermediate for the deepest facies, decreases for the reef belts and increases to a maximum in the back‐reef zone. In ramps and atolls, magnetic susceptibility trends clearly differ; average magnetic susceptibility generally decreases towards the top of shallowing‐upward sequences and is highest in the deepest facies. The strong relationship between magnetic susceptibility, facies and sequences implies a strong environmental influence. However, the different responses in the different platform types suggest that sea‐level changes leading to variation in detrital input is not the only parameter controlling average magnetic susceptibility values. Other primary or secondary processes also probably influenced magnetic mineral distribution. Primary processes such as carbonate production and water agitation during deposition are probably key factors. When carbonate production is high, the proportion of magnetic minerals is diluted and the magnetic susceptibility signal decreases. High water agitation during deposition will also selectively remove magnetic minerals and will lead to low average magnetic susceptibility values. These parameters explain the lowest values observed on the reef platform, inner ramp and atoll crown, which are all in areas characterized by higher carbonate production and greater water agitation during deposition. The lowest values observed in the lagoon inside the atoll crown can be related to detrital isolation by the atoll crown. However, other parameters such as biogenic magnetite production or diagenesis can also influence the magnetic signal. Diagenesis can change magnetism by creating or destroying magnetic minerals. However, the influence of diagenesis probably is linked strongly to the primary facies (permeability, amount of clay or organic matter) and probably enhanced the primary signal. The complexity of the signal gives rise to correlation problems between different depositional settings. Thus, while magnetic susceptibility has the potential to be an important correlation tool, the results of this investigation indicate that it cannot be used without consideration of sedimentary processes and depositional environments and without strong biostratigraphical control. 相似文献
8.
过去一直被认为是烃源岩的长7段泥页岩,目前被证实可以作为页岩油储层,这就使得定量分析长7段岩石中各类黏土矿物含量变得十分重要。由于不同地区黏土矿物结晶程度存在差异,导致传统X衍射定量分析的行业标准并不具有普适性,因此要精确测量长7段黏土矿物含量,就需要针对研究区具体情况,实测一套符合该区情况的K因子。利用X衍射定量分析中的K因子法,以石英为内标物,求取长7段岩石中各类黏土矿物的K因子,进而计算出了各矿物的含量。此外,通过X荧光光谱矿物化学配平以及热重分析两种方法对相应样品进行了黏土矿物的定量和半定量分析,进一步验证了K因子的正确性,分析结果与利用K因子法获得的矿物含量具有较好的一致性。所求取的K因子,对今后该区域利用X射线衍射法定量分析黏土矿物含量提供了基础参数,从而可以促进判断页岩的岩性、对比不同岩性岩石中单矿物含量及变化关系等方面的研究。 相似文献
9.
《International Journal of Mineral Processing》2005,75(1-2):101-112
This study deals with the effect of mechanical treatment, using vibrating mill, on the mineralogy and structure of apatite and associated gangue minerals (dolomite, calcite, quartz, pyrite and gypsum) in Abu-Tartour phosphate ore, Egypt. The evolution of mineralogy, crystallinity and deformation mechanism were evaluated with different techniques (XRD, DTA, TGA and FT-IR). Data obtained using these techniques give a good picture about the mechanochemical behavior of the different components in the ore. X-ray diffraction (XRD) indicated that the mineralogy has been changed quantitatively at short time grinding (30 min). After 45 min of grinding, the sample contained mainly carbonate apatite, quartz and pyrite. On the other hand, dolomite mineral disappeared, while calcite was partially transformed into aragonite. This transformation increased with increasing grinding time. Both Fourier Transform Infrared (FT-IR) and differential thermal analysis (DTA) analyses revealed that remarkable changes in the structural groups have occurred after 45 min of grinding. After 75 min of grinding, the carbonate in the apatite mineral partially decomposed and tricalcium phosphate formed instead. The formation of that simple form (tricalcium phosphate) may be another reason, besides surface area, for increasing the reactivity of phosphate ore by grinding. Scanning electron micrographs (SEM) revealed some idea about the grinding mechanisms of Abu-Tartour phosphate using vibrating mill. They indicate that the different minerals are ground differently. The apatite minerals are ground mostly by abrasion mechanism, while the carbonate minerals are ground mostly by compression. Also, these minerals are ground with different rates, where dolomite is ground faster than calcite, which are referred to the crystal lattice. 相似文献
10.
11.
李国武 《矿物岩石地球化学通报》2021,40(2):337-358
矿物的晶体结构与晶体化学是矿物学的重要基础研究领域之一,21世纪以来,随着国家对地勘行业的重视,以及平面探测技术单晶衍射仪、微区、微量衍射等实验技术的应用与计算机软硬件能力的提高,我国矿物晶体结构与晶体化学研究得到飞速发展.矿物晶体结构测定与研究是伴随着新矿物的发现而发展的,新矿物的发现是矿物晶体结构研究的基石,又为新... 相似文献
12.
Industrial uranium orebodies have recently been found through in-depth uranium exploration in the Luohe Formation in the southwestern Ordos Basin, which is an important breakthrough in deep prospecting for sandstone-type uranium deposits. The composition, content and characteristics of clay minerals in the Luohe Formation in the Zhenyuan area were systematically studied by means of thin section identification, scanning electron microscopy, X-ray diffraction and altered mineral spectral scanning. Unlike the most important uranium-bearing rock series in the Zhiluo Formation in the northeast and southwest of the basin, the ore-bearing Luohe Formation sandstone has low contents of clay minerals while the clay mineral assemblages vary in different sand bodies. Among them, the main types of mudstone, oxidized sandstone, calcareous sandstone and mineralized sandstone are illite-smectite mixed-layer mineral and illite, followed by kaolinite and chlorite, the main types uranium-rich sandstone and gray-green sandstone are kaolinite and illite-smectite mixed-layer mineral, followed by illite and chlorite. Even though adsorption of clay minerals, such as chlorite, illite-smectite mixed-layer mineral, kaolinite, and illite may contribute to U enrichment and uranium mineral precipitation, no correlation between clays and uranium minerals have been observed, indicating that clay minerals are not the main factor affecting uranium enrichment during the deep metallogenic process. The study of clay minerals in the Luohe Formation sandstone demonstrated that there are at least two phases of chlorite and one phase of kaolinite in the study area, which respectively represent two phases of alkaline fluid and one phase of acid fluid activities, revealing a fluid phase transition of alkaline-acidic-alkaline. Therefore, the clay minerals can be used as an important indicator for uranium mineralization. © 2020, Science Press. All right reserved. 相似文献
13.
The anisotropy of magnetic susceptibility has been proven to be an excellent indicator for mineral fabrics and therefore deformation
in a rock or sediment. Low-field anisotropy is relatively rapid to measure so that a sufficient number of samples can be measured
to obtain a good statistical representation of the magnetic fabric. The physical properties of individual minerals that contribute
to the observed magnetic fabric include bulk susceptibility and intrinsic anisotropy of the mineral phase, its volume concentration,
and its degree of alignment. Several techniques have been developed to separate magnetic subfabrics arising from magnetization
types, i.e., ferrimagnetism, antiferromagnetism, paramagnetism, and diamagnetism. Susceptibility anisotropy can be measured
in low or high fields and at different temperatures in order to isolate a particular subfabric. Measuring the anisotropy of
a remanent magnetization can also isolate ferrimagnetic fabrics. A series of case studies are presented that exemplify the
value of isolating magnetic subfabrics in a geological context. It is particularly useful in rocks that carry a paramagnetic
and diamagnetic subfabric of similar magnitude, such that they negate one another. Further examples are provided for purely
paramagnetic subfabrics and cases where a ferrimagnetic subfabric is also identified. 相似文献
14.
萤石重晶石方解石共生非金属矿物分析方法研究 总被引：1，自引：0，他引：1
萤石、方解石、重晶石是自然界中普遍共生的非金属矿,具有十分重要的经济价值.目前对于该类共生矿物中不同矿物含量的分离测定,尚未建立较系统、准确的方法.本文通过条件试验,选用10％冰醋酸作为溶剂溶解分离方解石和萤石,硝酸-高氯酸溶解分离萤石和重晶石,制定了一套适用于方解石、萤石、重晶石共生矿物的分离分析方法流程.应用该实验流程对三类矿石组合样品及实际样品进行分析,内外检的测定结果准确可靠;对GBW 07250 ～ GBW 07254五个萤石国家一级标准物质和一个重晶石管理样品进行分析,方法精密度(RSD)＜0.4％,证明该方法流程也适用于萤石或重晶石含量较高的样品分析.与国家标准方法GB/T 5195.1-2006(萤石氟化钙含量测定)比较,本流程更加连续简便,可指导方解石、萤石、重晶石共生矿物资源评价、选矿及回收试验,有利于提高该类非金属矿物的综合利用价值. 相似文献
15.
铀矿床定年研究进展评述 总被引：8，自引：3，他引：5
往往由于铀矿物(沥青铀矿)颗粒细小、易蚀变成铀的次生矿物及多期铀矿化作用相互叠加等在组成和结构上的固有特点,通常难以用挑选铀矿物(沥青铀矿)样品溶样的传统定年方法精确确定其形成年龄。随着分析技术的不断更新和发展,对铀矿床成矿年代学的研究也不断深入。但受铀矿床中铀矿物U-Pb定年方法本身的制约,以及以往对铀矿物U-Pb定年体系中铀矿物样品要求认识的不足,常常导致获得的年龄无实际地质意义或无法获得理想的等时线年龄。本文针对铀矿化定年方法的发展历程进行了系统梳理和分析,评述了铀矿物定年的五种主要方法:(1)铀矿物U-Th-totalPb化学年龄;(2)铀矿物模式年龄;(3)铀矿物传统等时线年龄;(4)铀矿物矿伴生矿物年龄;(5)原位微区铀矿物U-Pb年龄。在此基础上,深入探讨了铀矿化作用定年研究中存在的问题和对应方案,期望促进未来铀矿床成矿年代学的发展。 相似文献
16.
磁学参数作为可靠的古气候和古环境指标, 能为全球环境变化、气候过程研究提供有价值的资料.对广西来宾铁桥剖面瓜德鲁普-乐平统界线地层进行详细岩石磁学研究, 结果表明, 铁桥剖面样品中主要磁性矿物是顺磁性矿物以及少量磁铁矿、赤铁矿.在瓜德鲁普-乐平统界线附近, 岩石磁学特征发生显著变化, 磁化率先增大再减小, 携磁矿物成分呈硬磁性矿物(赤铁矿)→软磁性矿物(磁铁矿)→硬磁性矿物(赤铁矿)的变化趋势, 这些转变仅在界线上下大约4m的岩层内完成, 与中二叠世晚期的海平面变化、古海水温度变化同步.中-晚二叠世之交碳酸盐岩磁学参数的变化显著, 反映磁性矿物在各圈层之间的运移和转换发生了转变, 这一转变起因于当时的气候环境变化.瓜德鲁普世晚期和乐平世早期, 海平面较高, 来宾地区物源少, 铁桥剖面的携磁矿物主要来自粉尘赤铁矿; 中-晚二叠世之交短暂的大规模海退作用使华南古陆面积大幅度增加, 同时陆生植物大规模灭绝, 地表侵蚀加剧, 来宾地区物源增多, 此时, 铁桥剖面的携磁矿物主要来源于河流输入的磁铁矿. 相似文献
17.
S. D. N. Lourenço Y. Saulick S. Zheng H. Kang D. Liu H. Lin T. Yao 《Acta Geotechnica》2018,13(1):1-14
Wettability is a fundamental property controlling the extent of wetting in flat and granular solids. In natural soils, wettability affects a wide variety of processes including infiltration, preferential flow and surface runoff. In mineral processing, wettability is paramount in enhancing the efficiency of separation of minerals from gangue. The manipulation of surface wettability is equally crucial in many industrial applications. For instance, superhydrophobic surfaces are those on which water drops roll off easily and as such are used for self-cleaning applications. Therefore, while wettability is strongly cross-disciplinary, its evolution has been discipline-specific with a direct extrapolation or transfer of concepts, approaches, and methods to ground engineering unlikely to remain valid. This paper synthesizes relevant aspects from surface chemistry, materials science, mining engineering, and soil science, and discusses their implications within the context of new granular materials that resist wetting, for use in barriers or ground improvement and, in unsaturated soils, where the effects of wettability have been documented. 相似文献
18.
依据承德地区大庙式钒钛磁铁矿床特征,通过人工重砂分离及单矿物化学分析并结合电子探针、岩矿鉴定结果查明了承德钒钛磁铁矿石中的含钒矿物主要是钛磁铁矿和磁铁矿,次要矿物是钛铁矿和硅酸盐;含钛矿物主要是钛铁矿、钛磁铁矿,次要矿物是金红石、榍石。根据承德钒钛磁铁矿石钒和铁呈正比的关系,选取代表性试样进行了钒钛物相分析项目的确定及溶剂选择的实验,最终确定了钒和钛物相分析测定流程。钒物相分析测定项目为磁铁矿和钛磁铁矿中的钒、钛铁矿中的钒、硅酸盐中的钒及总钒四项;钛物相分析测定项目为钛铁矿中的钛、磁铁矿和钛磁铁矿中的钛、金红石中的钛、硅酸盐中的钛及总钛五项。通过本方法测定的各种含钒和钛矿物含量占矿石中总钒和总钛含量的比例与人工重砂分析定量计算的各种含钒和钛矿物含量占矿石中总钒和总钛含量的比例是相互吻合的。对110件钒钛磁铁矿石样品进行了4种含钛矿物及3种含钒矿物物相分析,结果与实际地质成矿组分符合。本方法实现了钒钛磁铁矿中钒矿物和钛矿物的定量分离,确定了钒和钛物相联测分析流程,可以同时测定钒和钛矿物的含量。 相似文献
19.
电导度是溶液导电能力的相对尺度，电导度的大小能直接反映出成矿溶液的高低.实验证明，成矿溶液相对高浓渡聚集区，往往也是矿床的主矿体或富矿体赋存处.用电导度场替代浓度场，进而建立起电导度与矿体之间的定量对应关系，可以用于表达矿体的贫富，评价矿脉的工业价值，指示找矿远景区等.用金属矿物或半导体矿物的热电性来指导找矿，是近年业兴起的一种新的找矿方法.矿物的热电性大小或热导电类型等在不同的成矿环境、部位中表现不同.因此用矿物的热电性质可以对矿床的侵蚀面水平和矿化地段的远景作出评价.在黑龙江省西吉诺山铅、锌、铜、金普查区采用了成矿溶液电导度和矿物热电性等新技术、新方法，对普查区成矿远景及成矿有利地段进行了分析与预测.结果表明，前人入大量勘查工作的440线至500线一带并不是矿化中心位置，西吉诺山谱查区矿化中心可能位于500线以东至花岗斑岩体之间. 相似文献
20.
The mineralogy of the gossans of Rio Tinto and La Unión is studied. Special emphasis has been paid to the occurrence of jarosite group minerals because they constitute silver bearing material of technical importance. After granulometric separation of the fractions, magnetic separation was used to concentrate the jarosite-group minerals. Plumbojarosite, natrojarosite and argentojarosite were identified by X-ray diffraction techniques. The spatial deposition of jarosite, goethite and hematites has been studied in different samples and the sequence interpreted on the basis of the known literature. The silver content, as determined by SEM, indicates abundant silver deposition in an early phase of gossanization. The recovery in the industrial plant has been analyzed comparing the mineralogy of the whole one and the residues of flotation. This study reveals that the industrial process used today leaves unaltered the proportion of the jarosite minerals entering and leaving the plant.
Resumen En este trabajo se estudia la mineralogía del gossan de Rio Tinto y La Unión. Se hace enfasis especial en los minerales del grupo de la jarosita, por ser los principales portadores de plata y de importancia técnica. Para concentrar los minerales de la jarosita se realizó una separación magnética previa. Plumbojarosita, natrojarosita y argentojarosita se identificaron mediante difracción de rayos X. Se ha estudiado la deposición espacial de jarosita, goethita y hematites y se ha interpratado sus secuencias en base a la bibliografía que se conoce. La distribución del contenido en plata, realizada mediante S. E. M. a puesto de manifiesto que la deposición de plata es más abundante en la primera fase de gossanización. La recuperación de la plata en la planta industrial ha sido analizada comparando la mineralogía del todo uno y del residuo del proceso de flotación. En general el proceso de flotación no concentra la plata quedando practicamente inalterada la proporción de minerales de la jarosita que entran y salen de la planta de tratamiento.相似文献