共查询到18条相似文献，搜索用时 531 毫秒
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随着易选金矿资源的日益枯竭，难处理金矿则成了专家们研究的热点。作者对栾川潭头高硫难浸金精矿工艺矿物学进行了详细的研究，其难浸的原因是由于黄铁矿中存在着大量的晶格金，并发现交互连生金以及金包裹其他矿物的金的赋存状态，这是该金精矿的独有特征 相似文献
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招远、莱州地区金矿床黄铁矿的标型特征及黄铁矿中金的赋存状态的研究,采用了化学成分分析、电子探针成分分析、透射电镜分析、物相分析、晶胞参数测定、热电系数测定、比重硬度测定、粒度测定等多种物理化学手段。初步探讨了黄铁矿与金矿成矿的关系,并归纳出以下特征,可作为找矿标志:一是裂隙发育,结构疏松不规则的碎块状及五角十二面体、八面体、立方体黄铁矿含金高,与金关系密切。二是金矿中黄铁矿热电系数为正值,热电场为空穴型及电子—空穴型两种。三是金矿中黄铁矿晶胞参数大、比重低、硬度低、反射率低者含金量高。四是黄铁矿的主要成分S、Fe偏低,杂质元素Au、Ag、As、Sb、Bi、Co、Ni等微量元素较高,是含金黄铁矿成分特征。五是在金矿中黄铁矿是主要载金矿物,有80％以上的金与黄铁矿有关。查明金主要呈独立矿物赋存在黄铁矿中。另外在黄铁矿中还有可能存在微量固溶体金。 相似文献
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以山东平度旧店金矿床中金矿物作为研究对象,通过对金矿物的形态、物性、主成分及微量元素等特征的研究,认为旧店金矿中主要金矿物为银金矿、自然金,主要载金矿物为石英、黄铁矿、黄铜矿、方铅矿、闪锌矿等。金主要以银金矿形式产出,金银矿少量,自然金很少。金矿物赋存状态主要为裂隙金、包体金、晶隙金等,呈粒状、板状、针状产出,银金矿与石英、黄铁矿依存关系最为密切。旧店金矿金的成色集中在600～800之间,平均744.13,说明旧店金矿经历了中温成矿环境,且成矿时间较短,是以金石英多金属硫化物阶段为主成矿期。 相似文献
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云南富宁者桑金矿床位于我国滇黔桂"金三角"区域,是该区的大型卡林型金矿床之一。为了更为详细地了解卡林型金矿在富金矿石中的赋存状态以及地球化学特征,该文以者桑金矿床中几种不同类型赋金矿石:辉绿岩型矿石、泥质板岩或粉砂岩型矿石、泥灰岩型矿石的载金黄铁矿及毒砂为研究对象,进行矿物特征观察和地球化学特征分析。结果表明:辉绿岩型矿石中,破碎状毒砂、细粒自形毒砂、拉长菱形毒砂的尖端含金性较优;泥质板岩或粉砂岩型矿石中,脉状黄铁矿集合体、粗粒自形五角十二面体含金性较优;泥灰岩型矿石普遍含金,其中细粒菱形毒砂的含金性尤为显著。不同矿石类型中载金矿物的含金性与硅化、炭化、绢云母化等密切相关;黄铁矿w(Fe)、w(S)关系,黄铁矿、毒砂晶形特征以及微量元素Co/Ni关系,揭示者桑金矿床属中—低温热液成因;Au-As关系表明者桑金矿床金主要是以"不可见"形式的晶格金和纳米金赋存于赋金矿石中。 相似文献
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已有文献认为:空穴型黄铁矿的存在对金成矿有利。作者对二道沟金矿床的研究表明,金矿化程度不仅与黄铁矿的热电性有关,而且与黄铁矿的晶体形态关系十分密切。富矿体中黄铁矿晶体形态复杂,种类多并以五角十二面体为主,叶夫济科娃晶体形态得分值(XFeS_)高;含矿较贫或不含矿的岩体黄铁矿晶体形态简单,种类少并以立方体为主,叶夫济科娃晶体形态得分值(XFeS_2)低。 相似文献
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归来庄金矿金矿物主要为自然金、碲铜金矿和银金矿，多呈角粒状产出，粒间金较常见，属细粒—微细粒金。载金矿物以脉石英、黄铁矿、褐铁矿及方解石为主。二者标型特征表明：该金矿属浅成中低温热液型金矿床，泰山群变质岩系为其主要矿源层，并且有来自地球深部的金质参与成矿。文中提出了与金矿化相关的元素变化特征和宏观找矿标志。 相似文献
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在Ａｕ（Ⅲ）－Ｃｌ络合溶液和常温常压条件下，黄铁矿随时间（ｔ）变化对金吸附的动态实验表明：整个吸附过程明显分为两个阶段．前一个阶段是快速达到平衡的吸附过程，随着平衡的建立，金的沉淀速度迅速变小，随后即进入缓慢吸附阶段，溶液中金的浓度按指数函数关系衰减．不同粒度黄铁矿实验结果的横向比较显示，粒度越细，金的沉淀速度越快，沉淀金的总量也越多。 相似文献
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黄铁矿是重要的金属硫化物矿物,在多种矿床中均有产出,其标型特征对矿床成因、矿体空间分布等具有重要的指示意义。以扬子板块西缘攀西地区白草矿区黄铁矿为研究对象,利用矿相学、电子探针等分析方法来对比研究浸染状、致密块状、斑杂状、网脉状矿石中黄铁矿的标型元素特征。结果表明:白草矿区黄铁矿Fe、S平均含量(质量分数,下同)分别为46.030%、52.815%,介于岩浆成因与热液成因之间,根据矿石特征,黄铁矿以岩浆成因为主,并有少量热液作用参与;将白草矿区黄铁矿δFe-δS特征与金川等典型铜镍硫化物矿床黄铁矿对比,表明白草矿区黄铁矿为典型的岩浆熔离型;由于存在钒钛磁铁矿,Co/Ni值多小于5,说明钒钛磁铁矿与硫化物存在共生关系;岩浆内生成因黄铁矿S/Se值小于15000,白草矿区黄铁矿S/Se值为812~10466,显示白草矿区黄铁矿为岩浆内生成因;Se/Te值随温度降低而升高,显示上述4类矿石黄铁矿结晶顺序为浸染状矿石→致密块状矿石→斑杂状矿石→网脉状矿石;原始地幔标准化主量、微量元素蛛网图显示白草矿区黄铁矿兼具岩浆成因与热液成因。综上所述,攀西地区白草矿区黄铁矿成因主要以岩浆熔离作用为主,并含有少量热液作用。 相似文献
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水体中S2-与砷(As)的迁移富集密切相关, 但不同含水介质中其作用机理尚不明确。为了查明潜流带中常见含水介质河砂在S2-作用下对As的吸附特征, 设计并开展了As在河砂上的吸附动力学实验, 以及S2-作用下河砂对As的吸附实验, 结合PHREEQC模拟计算, XRD、SEM-EDS、XPS和FTIR等表征测试技术, 进一步识别其作用机理。结果表明: 固液比为25 g/L情况下, 河砂对As的吸附在200 h左右达到吸附平衡, 且对As(Ⅴ)的吸附量明显高于As(Ⅲ); 随着S2-浓度的增加, 河砂对As吸附能力逐渐减弱; 模拟及表征测试结果显示, 少量As被吸附在河砂表面, 主要与其表面的Fe、Al结合, 其中As(Ⅲ)的吸附可能还与Si-O键断裂后与S2-结合形成的SiS2有关。S2-对河砂吸附As的主要影响机理为: ①S2-的加入使得溶液pH值升高、Eh值降低, 从而抑制了As的吸附; ②添加S2-条件下河砂表面的Fe、Al等能与S和As形成AlAs、AlAsO4、FeS2及Fe4As2O11等化合物, 减少了河砂表面吸附As的活性位点。研究结果有助于丰富As-S作用机理, 以及As在地下水环境中迁移过程的认识。 相似文献
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盘子涧金矿地处山东胶东地区蓬莱—栖霞金成矿带南部,是典型的石英脉型金矿,Au品位高,目前对该矿床成矿流体来源的研究尚不深入。在详细的矿相学观察及黄铁矿显微结构研究基础上,对盘子涧金矿主成矿阶段(石英-黄铁矿(绢云母)阶段和金-石英-多金属硫化物阶段)的载金黄铁矿进行了流体包裹体He-Ar同位素组成分析。结果表明:盘子涧金矿载金黄铁矿中流体包裹体的3He丰度为(3.49~8.50)×10^-14 cm^3 STP·g^-1,4He丰度为(2.46~5.06)×10^-8 cm^3 STP·g^-1,3He/4He值为0.8 Ra^1.2 Ra(Ra为大气3He/4He值,Ra=1.39×10^-6),成矿流体表现出以富集地幔为主导的壳幔混合特征;40Ar丰度为(1.02~2.65)×10^-7 cm^3 STP·g^-1,40Ar/36Ar值为896.3~1724.1,是大气饱和水40Ar/36Ar值的2~3倍,与中国东北部幔源岩样品40Ar/36Ar值相近,推测成矿流体主要来源于富集地幔,成矿流体中存在着一定量的地壳放射性成因40Ar,表明地壳流体参与了成矿作用。综上所述,推断山东胶东地区盘子涧金矿成矿流体为以富集地幔流体为主导的壳幔混合流体。 相似文献
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Gaskova Olga L. Strakhovenko Vera D. Ermolaeva Nadezhda I. Zarubina Eugene Yu. Ovdina Ekaterina A. 《中国海洋湖沼学报》2017,35(4):956-966
The Kambala and Barchin brackish lakes(Baraba steppe,southern West Siberia) contain an organic-rich sapropel layer that was formed in oxygen-depleted waters.We measured the bulk sediment elemental composition,the water chemistry and determined the mineralogical composition and predominant biota species(Diatoms and Cyanobacteria in phytoplankton community respectively) in the lakes.The result indicates that the first lake has a siliceous type of sapropel and the second a carbonaceous one.A computer thermodynamic model was developed for chemical interaction in water-bottom sediment systems of the Kambala and Barchin Lakes.The surface sodium bicarbonate waters are supersaturated with respect to calcite,magnesite(or low Mg-calcite),quartz and chlorite with minor strontianite,apatite and goethite(pH8.9-9.3,Eh 0.3 V).Nevertheless,it is shown that during sapropel deposition,deep silt waters should be anoxic(Eh0 V).The virtual component CH_2O has been used to create an anoxic environment suitable for pyrite formation due to the biotic community impact and abiotic reduction.Thermodynamic calculation has shown that silt water is not necessarily euxinic(anoxic and sulfidic).Depending on Eh,sulfate sulfur can dominate in solution,causing the formation of gypsum together with pyrite.An attempt was made to find a reason for solution supersaturation with respect to Ca and Mg ions due to their complexation with humic acids. 相似文献
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Pang Yue Fan Dejiang Sun Xiaoxia Sun Xueshi Liu Ming Yang Zuosheng 《中国海洋大学学报(英文版)》2020,19(4):801-810
For a long time, most studies about pyrite have focused on sediments while only a few have focused on pyrite in water. In this study, a method that combines the scanning electron microscopy(SEM) and the energy dispersive X-ray spectrometry(EDS) was used to compare pyrite particles suspended in water to those in associated bottom sediments, both obtained from the mixing zone of the Yangtze Estuary. It was found that the pyrite particles in the two media have similar morphologies and size distributions. The particle morphology mainly includes two types, single crystal and aggregate, and the particle size mainly ranges from 0.5 to 2 μm. The pyrite particles in water exhibit an increase in relative content towards the sea, and their transport and deposit processes are mainly affected by hydrodynamic conditions. It is concluded that the pyrite particles in the suspended matter mainly derived from the resuspension of sediments, which are products of the early diagenesis. Precursor minerals may appear during the formation of pyrite, but are generally restricted by the diagenetic environment and local microenvironment. 相似文献
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本文围绕着减少或杜绝硫铁矿山火灾事故的发生,认真分析了硫铁矿山火灾事故发生的外因、内因,并针对各类原因提出了不同的预防措施。确认抓好火灾预防工作的重点是监测和发现内因火灾的苗头,重点介绍了内因火灾的识别方法、预防措施。 相似文献
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In order to understand the mechanism(s) of gold precipitation in the anorthosite- hosted Sangchon gold deposits in the Hadong area, Korea, chemical speciation and reaction path calculations were accomplished by geochemical modeling.The modeling consisted of three- step procedures: reaction with anorthosite, then the simple cooling of the reacted fluid,and finally the boiling of metalliferous fluid. The principal vein minerals of the Sangchon deposits consist of quartz, sericite,kaolinite, pyrite, galena, chalcopyrite, sphalerite and acanthite. The sulfide mineralization is typically zoned from pyrite (preferentially at vein margins) to galena and sphalerite (toward vein center). Electrum is intimately associated with pyrite + chalcopyrite and sphalerite. By comparing the results of modeling with the observed mineral assemblages and paragenesis,the most appropriate evolution path of ore fluids was suggested as follow: reaction of a single fluid with anorthosite at 300℃,then the isobaric cooling of the fluid at temperatures from 2500° to 100℃3 , and then the boiling and cooling of the fluid due to the decrease of pressure and temperature. Calculations also show that all of the observed alteration minerals formed due to fluid - anorthosite interaction at early period, whereas most of sulfides and electrum were precipitated mainly due to cooling.The abundance of gold in veins depends critically on the ratio of total base metals plus iron to sulfide in the aqueous phase,because gold is transported as Au(HS)2- whose solubility is very sensitive to the sulfide activity. Our results of geochemical modeling generally fit to the observed mineral assemblages and mineral composition, indicating the usefulness of numerical simulation for elucidating the genesis of gold deposits. 相似文献