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1.
The lanthanide tetrad effect was investigated in a 5.4 m thick terra rossa profile overlying dolomite on the Yunnan-Guizhou Plateau, China. The results demonstrate that the chondrite-normalized rare earth element pattern of dolomite bedrock displays a W-type tetrad effect. The insoluble residue from the dolomite bedrock does not exhibit any significant tetrad effect. In contrast, some ferromanganese concretions and the terra rossa show tetrad effect. It is worth noting that the conjugate M- and W-types of the tetrad effect are observed in some terra rossa samples. The tetrad effect in the ferromanganese concretions and the terra rossa possibly originates from redistribution of dissolved rare earth elements during their downwards movement in the profile and not only from water/rock interaction. Within the dolomite weathering system, the ferromanganese concretions and surrounding terra rossa present similar correlations of Eu/Eu*, Y/Ho, Sm/Nd, Ce/Ce*, with the size of the tetrad effect. The ferromanganese concretions and the terra rossa with tetrad effect are characterized by a reduced, non-chondritic Y/Ho ratio. Also the Y/Ho ratio exhibits a clear negative correlation with the size of the tetrad effect in the ferromanganese concretions and the terra rossa. In addition, the Eu/Eu* tends to increase with increasing size of the tetrad effect in the ferromanganese concretions and the terra rossa, as does the Sm/Nd ratio. The regular variation for Eu/Eu*, Y/Ho and Sm/Nd is likely a result of the fractionation of rare earth elements and yttrium with the tetrad effect. On the other hand, the correlation of the Ce/Ce* with the size of the tetrad effect in the ferromanganese concretions and the terra rossa is random. This likely indicates that the Ce behavior within weathering system is mainly controlled by redox condition, rather than tetrad effect. Comparative study indicates that the correlations of Eu/Eu*, Y/Ho, Ce/Ce*, with the size of the tetrad effect in the ferromanganese concretions and the terra rossa, are not similar to those found in a highly evolved igneous system. Nevertheless, the correlation of Sm/Nd with the size of tetrad effect in weathering system is similar to that in igneous system. In general, it appears to indicate that the tetrad effect occurrence in granitic rocks is not associated with weathering.  相似文献   

2.
In this study, the mobilization, redistribution, and fractionation of trace and rare earth elements (REE) during chemical weathering in mid-ridge (A), near mountaintop (B), and valley (C) profiles (weak, weak to moderate, and moderate to intense chemical weathering stage, respectively), are characterized. Among the trace elements, U and V were depleted in the regolith in all three profiles, Sr, Nb, Ta, Zr, and Hf displayed slight gains or losses, and Th, Rb, Cs, and Sc remained immobile. Mn, Ba, Zn, Cu, and Cr were enriched at the regolith in profiles A and B, but depleted in profile C. Mn, Pb, and Co were also depleted in the saprock and fractured shale zones in profiles A and B and enriched in profile C. REEs were enriched in the regolith and depleted at the saprock zone in profiles A and B and depleted along profile C. Mobility of trace and REEs increased with increasing weathering intensity. Normalized REE patterns based on the parent shale revealed light REE (LREE) enrichment, middle REE (MREE), and heavy REE (HREE) depletion patterns. LREEs were less mobile compared with MREEs and HREEs, and this differentiation increased with increasing weathering degree. Positive Ce anomalies were higher in profile C than in profiles A and B. The Ce fractionated from other REE showed that Ce changed from trivalent to tetravalent (as CeO2) under oxidizing conditions. Minimal REE fractionation was observed in the saprock zone in profiles A and B. In contrast, more intense weathering in profile C resulted in preferential retention of LREE (especially Ce), leading to considerable LREE/MREE and LREE/HREE fractionation. (La/Yb)N and (La/Sm)N ratios displayed maximum values in the saprock zone within low pH values. Findings demonstrate that acidic solutions can mobilize REEs and result in leaching of REEs out of the highly acidic portions of the saprock material and transport downward into fractured shale. The overall behavior of elements in the three profiles suggests that solution pH, as well as the presence of primary and secondary minerals, play important roles in the mobilization and redistribution of trace elements and REEs during black shale chemical weathering.  相似文献   

3.
Fe-nodules occur within saprolites formed from weathering of granodioritic gneisses in the rain-shadow region of the Mysore Plateau adjacent to the Sahyadri Mountains in Southern India. These nodules and their host saprolites were studied for their geochemistry, including chemical speciation, to understand nodule formation and chemical redistribution processes during rock weathering. From their mode of occurrence, and mineralogical and geochemical data, we infer that the nodules originated by a two-stage process in which the initial extensive weathering of gneisses likely facilitated subsequent ferrolysis weathering and nodule formation. Nodules originated by precipitation of goethite, hematite and gibbsite along with several amorphous phases within the matrix of weathered gneisses. This is possible only under hydromorphic conditions, suggesting that parts of the plateau must have gone through a humid phase prior to the present aridity. In the saprolites, Al, Fe, and Ti become enriched because of the removal of Si, Ca, Na, and K. However within the nodule, Fe, Ti, Cr, and Ni are deposited after their chemical transport from the saprolite. Titanium, known for its immobile nature, was also mobilized and concentrated under the conditions of nodule formation. The most important elements in the nodule constitution are Fe, Al, Ti, and Mn, each having both crystalline and amorphous phases. Fe-Ti and Mn oxyhydroxides grain coatings in the saprolites and discrete amorphous Mn and Ti phases in the nodules seem to have scavenged trace elements from the weathering profile. REE were mobilized during weathering and nodule genesis in which Ce and Ti show a strong geochemical coherence. The enrichment of only HREE in saprolite, and both HREE and LREE with significant Ce in the nodule, indicate the control of evolving secondary minerals in the REE redistribution during rock weathering. Strong enrichment of Ce in the weathering profile and in nodules has important implications to the REE chemistry of river waters.  相似文献   

4.
This study presents bulk chemical compositions of the Tongmuling soil profile, which developed on dolostone, and the overlying strata covering the bedrock in the central Guizhou province (southern China). The chemical weathering characteristics of the studied profile were investigated and the inheritance relationships between the terra rossa and overlying strata were discussed. The results show that there is no remarkable variation in the major elements and weathering indices from the rock–soil interface to the topsoil, indicating that the studied profile was not typical for in situ crustal chemical weathering. The terra rossa were mainly composed of SiO2, Al2O3 and Fe2O3. Compared with the insoluble residues and overlying strata, the terra rossa are characterized by an enrichment of Y and Cs and depletion of Ba and Sr. The subsoil shows a notable Ce negative anomaly, characterized by heavy rare earth element enrichment (L/H = 1.55–3.74), whereas the topsoil shows a positive Ce anomaly with light rare earth element enrichment (L/H = 5.93–9.14). According to Laterite-forming capacity estimates, the terra rossa could not have only been formed from acid-insoluble residues from the bedrock; Al2O3 versus Fe2O3 and Nb plotted against Ta show significant positive correlations between the terra rossa and overlying strata. The Eu/Eu* versus GdN/YbN and ternary diagrams for Sc, Th, Zr, and Ta suggest that the overlying strata could also provide parent materials for the genesis of terra rossa.  相似文献   

5.
Major, trace and organic elements of a laterite profile developed on Neogene basalts in northern Hainan Island, South China were reported in this paper, the aim of which was to investigate element mobilization and re-distribution during extreme weathering. The results indicate that most of the elements have been mobilized and transferred downwards along the profile by aqueous solution. Organic matter (OM) can significantly improve the transport of insoluble elements. Among all the elements, Th is the least mobile. As for the general conservative elements during incipient chemical weathering, such as Fe, Ti, Zr, Hf, Nb and Ta, the removals are up to 20-40% in the upper profile. However, these elements behave as conservatively as Th in the lower profile. In the middle profile, oxic environment occurs, accompanied with significant OM decomposition. The Mn and Ce transferred downward are readily oxidized into insoluble Mn(IV) and Ce(IV) and precipitate in the oxic front. Important OM decomposition decreases the capacity of transfer of insoluble elements in aqueous solution. Consequently, Al significantly precipitates in the oxic front, and REEs, with the exception of Ce, precipitate largely in the OM-depleted layers. Co and U are also concentrated in the oxic front in association with Mn and Ce, respectively. However, Cr shows a negative correlation with Mn because its response to redox condition changes is reversed from that of Mn. Mn oxides/hydroxides, Fe oxides/hydroxides and secondary phosphate minerals other than clay minerals are potential hosts for REEs except for Ce in the profile; REEs with high concentrations in the profile seem closely associated with Mn oxides/hydroxides. Remarkable, highly correlated, Ce and Gd anomalies are observed in the profile. Ce anomalies are caused by Ce precipitation in the oxic environment and successive decomposition of organic matter. Gd anomalies are likely to have resulted from lower stability constants of Gd-OM complexes compared to those of neighboring REEs. The overall elemental behaviors in this profile suggest that organic matter plays a very important role in the mobilization and re-distribution of the elements during extreme weathering.  相似文献   

6.
Distribution of the major and trace elements in ferromanganese nodules, which are buried or exposed on the seafloor, and in host sediments was studied in ten concretion/sediment pairs by various physical and chemical methods. It has been established that, in addition to Fe and Mn, a limited number of the major and trace elements (P, Ca, Sr, Ba, Mo, Co, Zn, Ni, As, Pb, Sb, Tl, U, W, Y, and Ga included) is accumulated with a variable degree of intensity (relative to sediments) in the concretions. As compared to host sediments, the maximal content of Mn in concretions is 100 times higher, whereas maximal contents of all other elements listed above vary from more than one to 10–20 times. Manganese and, to a lesser extent, Ba and Sr are concentrated in the buried concretions. Other elements are primarily concentrated in concretions exposed on the sea-floor. The occurrence mode of concretions and compositional data on interstitial water suggest that metals in the concretions were derived from seawater and suspended particulates, in addition to sediments. Burial of concretions in the sediment pile is accompanied by the alteration of their composition, accumulation of Mn (relative to Fe), and loss of several associated metals.  相似文献   

7.
The purpose of this study was to determine and evaluate the geochemical characteristics of the limestone of the Upper Cretaceous Mortas Formation and related terra rossa in a 50 km2 area which is located 20 km south of the city of Seydisehir, Central Anatolia, by using data obtained from the ICP-MS analysis of randomly collected 42 samples of limestone and 18 samples of the terra rossa.The limestone of the Mortas Formation is composed of fossilliferous, gray-cream colored, medium to thick bedded, partially dolomitic carbonate rocks, and generally has dismicrite, intrapelmicrite composition. It includes the largest bauxite reservior in Turkey and has many occurences of terra rossa formation on it. According to mean distance, the Ba, Be, Hg, Mo, Nb, Sb and Th concentrations in the limestones overlying and underlying the bauxite deposits are different, but the main oxides, REE and other trace elements are same. In factor analysis, the first component reflects relative enrichment of clay against to CaO contents of the limestone, the second component corresponds to the degree of dolomitization. The PAAS-normalized REEs pattern for the Mortas Formation limestone samples illustrate similar main features as seawater.The terra rossa soils in the study area are considered to be highly weathered and weakly mature soil with respect to their generally low Al2O3 (21%), but high CaO (2%) contents, and their alteration indices. The element ratios in the terra rossa and limestone show that in the process of the transformation from limestone to terra rossa, Ba, Si, Ti, Al and Fe were enriched together by staying in-situ. Except Ce, all lanthanides show similar behavior, but the HREE, which were richer in limestone, were consumed fast relative to the LREE during soil formation. The association and the enrichment of Co, Cu, Cr, Ni and Pb as well as Ba, Zr, Ga, Nb and Rb in soil relative to the limestone are interpreted as being resulted from eolian transportation. Ca, Au, Hg, Sr, Se, Sb, Mo, Ag, U, Cd and Na were found to be the most mobile elements during pedogenic transformation. According to main oxide composition ratios of the limestone and terra rossa, the soils were described as representing a well washed soil completing the leaching and accumulation phase, but not totally completing the silicate weathering phase. In the processes of soil formation, 97.76% of the limestone was washed away; only 2.24% of limestone was deposited as soil. Therefore, 61 times mass reduction was realized.  相似文献   

8.
云贵高原碳酸盐岩风化壳的古地磁定年探讨   总被引：2，自引：0，他引：2  
云贵高原乃至中国残积型红土及红土性风化壳的形成年代是一个长期以来悬而未决的问题。本文以云贵高原厚度分别为9. 47m 和5. 4m的两个碳酸盐岩风化剖面为例,探讨了古地磁方法在碳酸盐岩风化剖面定年中的应用。古地磁定年结果初步表明,其发育时间在布容正极性世内,即两个风化壳剖面的发育年龄不会大于0. 78Ma B. P. 。此外,对古地磁方法应用于碳酸盐岩风化剖面定年中可能存在的问题进行了讨论,其中包括风化壳的成因、风化过程中的体积变化、母岩的岩石磁性、磁性载体矿物及其记录磁信号的稳定性等问题。   相似文献   

9.
The Mediterranean-type karst-bauxite deposit of Morta?, south Turkey, placed unconformably between Cenomanian and Senonian shallow marine limestones is built of massive (MB), oolithic (OB), breccia-bearing (BB) and earthy (EB) bauxite horizons, from top to bottom. The MB layer is enriched in Al and REE (except Ce) due to loss of Si, Na, K, Mg and P. REE are accumulated in the BB but depleted in the EB layers. The ferruginous OB lost LREE and gained in HREE probable due to scavenging by authigenic heavy minerals like rutile, anatase and titanite. Total REE contents in the bauxite profile display an increasing trend from bottom to top, while negative and maximum positive Ce anomalies characterize the upper and the lower parts of the profile, respectively. This unusual REE behavior is explicable by assuming mobilization of Ce(IV) either under reducing condition or chemical complexation under alkaline conditions in the top layer and scavenging of Ce by Al-Mg hydrosilicates and Ti-oxides and/or precipitation with authigenic REE minerals, especially of the bastnäsite group near the bedrock limestones. Similarity in chondrite normalized-REE patterns of the Seydi?ehir phyllites, bauxite and terra rossa samples and the presence of tridymite (?) in bauxites makes a felsic source rock most likely and reveal a close genetic relationship between the Seydi?ehir phyllites and the recent terra rossa occurrences. The REE patterns of the bauxites resemble those of the Katrangedi?i limestone despite variations in ΣREE. Field observations and geochemical data together with mass-balance calculations suggest that the Morta? deposit was derived from the Seydi?ehir phyllites and argillic phase within the Katrangedi?i limestone which in turn have Precambrian (?) felsic, probably granitic precursors.  相似文献   

10.
冯金良  朱立平 《中国岩溶》2005,24(4):270-275
通过与粉尘堆积,以及玄武岩和片麻杂岩风化剖面磁组构的对比,探讨了以贵州平坝白云岩之上红色粘土剖面磁组构特征及其成因指示意义。红色粘土的各向异性较弱,并且不具有明显的沉积磁组构;母岩的组构特征对红色粘土磁化率各向异性没有明显的控制“痕迹” ;红色粘土与粉尘堆积物之间磁组构特征的明显差异,表明它们在物源和形成机制方面是不同的;红色粘土磁化率及磁组构特征反映出红色粘土中磁性矿物的物质来源和成因具有一定的特殊性。   相似文献   

11.
黔中早石炭世九架炉组铝土矿含矿岩系富集Ti、Li、Sc、V、Ga、Nb、Ta、Zr、Hf、Th和稀土(REEs)等"三稀金属",具有成为独立矿床或伴生资源的潜力。这些元素大部分与九架炉组共有同一母岩,且富集程度受母岩的成分和风化作用控制。本研究选取九架炉组母岩乌当娄山关群白云岩和纳雍牛蹄塘组泥质白云岩的现代风化剖面为研究对象,研究元素在风化作用过程中的迁移特征及分布规律,进而为九架炉组微量元素的富集机制提供启示。研究获得以下认识:1)依据剖面结构、ZrHf、Nb-Ta、Y-Ho二元图特征及REE配分曲线和Eu/Eu*值的相似性表明研究区土层主要来源于基底或母岩的风化; 2)白云岩风化成土过程中Si、Fe、Cr、As、Sb、Ti、Nb、Ta、Zr、Hf、Th、REEs等元素化学性质相对稳定,富集程度较高,而Ca、Mg、Na、K、Sr、P、Mo、Cd等元素化学性质活泼,容易淋失亏损; 3)纳雍剖面REEs~(3+)和Ca~(2+)半径差与REEs富集系数相关性良好,表明碳酸盐岩风化过程中,含钙矿物磷灰石是稀土元素分配的重要控制因素; 4)九架炉组的母岩也是Ti、Li、Sc、V、Ga、Nb、Ta、Zr、Hf、Th等微量元素的主要物质来源,母岩风化过程中,这些微量元素首先在副矿物、黏土矿物、铝矿物及磷灰石等矿物相中初步富集,之后随风化碎屑物一起沉积形成微量元素超常富集地层; 5)纳雍剖面地表和地下水提供了部分P、Be、Zn、Sb、Pb、Y及REEs来源,指示水体迁入作用也是九架炉组REEs富集的重要原因。研究表明黔中九架炉组微量元素的来源较复杂,风化-沉积过程中,化学性质稳定的元素残留在风化碎屑物中并被搬运-沉积在负地形中,而化学性质活泼的元素首先被带入水体,在沉积-成岩过程中特定条件下发生二次富集作用(例如次生矿物的形成及吸附)形成微量元素富集的地层。  相似文献   

12.
Abstract. Rare earth, major and trace element geochemistry is reported for the Kunimiyama stratiform ferromanganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The deposit immediately overlies greenstones of mid-ocean ridge basalt (MORB) origin and underlies red chert. The ferromanganese ores exhibit remarkable enrichments in Fe, Mn, P, V, Co, Ni, Zn, Y and rare earth elements (excepting Ce) relative to continental crustal abundance. These enriched elements/ Fe ratios and Post-Archean Average Australian Shale-normalized REE patterns of the ferromanganese ores are generally analogous to those of modern hydrothermal ferromanganese plume fall-out precipitates deposited on MOR flanks. However in more detail, Mn and Ti enrichments in the ferromanganese ores are more striking than the modern counterpart, suggesting a significant contribution of hydrogenetic component in the Kunimiyama ores. Our results are consistent with the interpretation that the Kunimiyama ores were umber deposits that primarily formed by hydrothermal plume fall-out precipitation in the Panthalassa Ocean during the Early Permian and then accreted onto the proto-Japanese island arc during the Middle Jurassic. The presence of strong negative Ce anomaly in the Kunimiyama ores may indicate that the Early Permian Panthalassa seawater had a more striking negative Ce anomaly due to a more oxidizing oceanic condition than today.  相似文献   

13.
Mineralogy, major, trace and rare earth elements of a weathering profile developed on tertiary greenstone belt in the extreme North Cameroon are reported. The aim of which was to investigate mineralogical evolution and element mobilization and redistribution during weathering under dry tropical climate. The weathering profile consists of four main horizons: (1) a spheroidal weathering zone constituted by a corestone–shell complex, (2) a C horizon, (3) a Bw horizon and an Ah horizon. The results indicate that nontronite, a Fe-rich smectite, is the exclusive clay mineral formed in the exfoliated shells and the C horizon. It is associated with kaolinite in the upper horizons. The coexistence of these two clay minerals induced a decrease of CEC and pH which becomes neutral. The weathering index (WI) values reveal that weathering becomes more and more intensive from the corestone up to Bw horizon, which is the most weathered horizon in the weathering profile. Mass balance calculations, using Th as immobile element, indicate that Ti is quite mobile and that Al and Fe are relatively enriched at the bottom and strongly leached at the top of the profile. Alkalis and alkaline earth elements are strong leached through out the profile, except Ca which displays similar trend as Al and Fe. The same goes for LILE (Cs, Sr), TTE (Cr, Co, Ni) and HSFE (Y, Nb, Hf). In opposite, REE are depleted at the bottom and enriched in the upper horizons, with more enrichment for LREE than for HREE. It appears that weathering of greenstone belt causes a fractionation of HREE and induces a concentration of LREEs. Ce and Eu anomalies display opposite behaviour.  相似文献   

14.
碳酸盐岩风化形成的红土保存着喀斯特发展演化历史证据,同时也是喀斯特地区土壤研究的重要对象。文章选取云 南石林地区的两处典型碳酸盐岩剖面为研究对象,对主量元素,微量元素及稀土元素在风化层的迁移特征及分布规律进行 研究,为探究风化层的成因提供依据。结果显示：（1） 以Ti为参比元素的剖面迁移特征表明,两剖面的主量元素在成土过 程中有相似的迁移规律,多数表现为淋失;微量元素略有差异,富集淋失程度不一。（2） UCC 标准化蜘蛛图显示,相对于 基岩,风化层中的Ca和Sr均出现亏损;与UCC相比,Fe、Ti等元素轻微富集,Mg、Ca、Na、K、P等元素显示了强烈的亏 损特征。（3） 基岩与风化层的REE分布模式相似,但风化层的稀土相对富集,轻稀土元素间的分异较大而重稀土元素间的 分异较小,且SJC剖面的轻、重稀土元素比值大于QST剖面;稀土元素球粒陨石标准化后,SJC剖面的Eu为负异常,剖面 上部和下部出现Ce负异常;QST剖面Ce负异常,Eu明显负异常。（4） 元素含量变化和元素对Al-Ti、Al-Fe及Zr-Hf相关性 说明剖面上覆红土是下伏基岩风化的结果。研究结果显示,两个剖面的元素地球化学特征与基岩存在很好的继承性,风化 层是基岩原位风化的产物。  相似文献   

15.
The behaviour of major and trace elements have been studied along two serpentinite weathering profiles located in the Kongo-Nkamouna and Mang North sites of the Lomié ultramafic complex.The serpentinites are characterized by high SiO2 and MgO contents, very low trace, rare earth and platinum-group element contents. Lanthanide and PGE contents are higher in the Nkamouna sample than in Mang North. Normalized REE patterns according to the CI chondrites reveal that: (i) all REE are below chondrites abundances in the Mang North sample; (ii) the (La/Yb)N ratio value is higher in the Nkamouna sample (23.72) than in the Mang one (1.78), this confirms the slightly more weathered nature of the Nkamouna sample. Normalized PGE patterns according to the same CI chondrites reveal a negative Pt anomaly in the Mang sample. The Nkamouna sample is characterized by a flat normalized PGE pattern.All element contents increase highly from the parent rock to the coarse saprolite.In the weathering profiles, Fe2O3 contents decrease from the bottom to the top contrarily to Al2O3, SiO2 and TiO2. The contents of alkali and alkaline oxides are under detection limit.Concerning trace elements, Cr, Ni, Co, Cu, Zn and Sc decrease considerably from the bottom to the top while Zr, Th, U, Be, Sb, Sn, W, Ta, Sr, Rb, Hf, Y, Li, Ga, Nb and Pb increase towards the clayey surface soil. Chromium, Ni and Co contents are high in the weathered materials in particular in the saprolite zone and in the nodules.REE contents are high in the weathered materials, particularly in Nkamouna. Their concentrations decrease along both profiles. Light REE are more abundant than heavy REE. Normalized REE patterns according to the parent rock reveal positive Ce anomalies in all the weathered materials and negative Eu anomalies only at the bottom of the coarse saprolite (Nkamouna site). Positive Ce anomalies are higher in the nodular horizon of both profiles. An additional calculation method of lanthanide anomalies, using NASC data, confirms positive Ce anomalies ([Ce/Ce*]NASC = 1.15 to 60.68) in several weathered materials except in nodules ([Ce/Ce*]NASC = 0.76) of the upper nodular horizon (Nkamouna profile). The (La/Yb)N ratios values are lower in the Nkamouna profile than in Mang site.PGE are more abundant in the weathered materials than in the parent rock. The highest contents are obtained in the coarse saprolite and in the nodules. The elements with high contents along both profiles are Pt (63–70 ppb), Ru (49–52 ppb) and Ir (41 ppb). Normalized PGE patterns show positive Pt anomalies and negative Ru anomalies.The mass balance evaluation, using thorium as immobile element, reveals that:
– major elements have been depleted along the weathering profile, except for Fe, Mn and Ti that have been enriched even only in the coarse saprolite;
– all the trace elements have been depleted along both profiles, except for Cr, Co, Zn, Sc, Cu, Ba, Y, Ga, U and Nb that have been enriched in the coarse saprolite;
– rare earth elements have been abundantly accumulated in the coarse saprolite, before their depletion towards the top of the profiles;
– platinum-group elements have been abundantly accumulated in the coarse saprolite but have been depleted towards the clayey surface soil.
Moreover, from a pedogenetical point of view, this study shows that the weathering profiles are autochtonous, except in the upper part of the soils where some allochtonous materials are revealed by the presence of zircon grains.  相似文献   

16.
埃及西奈半岛西南部Um Bogma地区是埃及著名的金属与非金属矿产区,区内盛产锰铁矿、铜矿、铀矿、高岭石和石英砂等矿产,铀矿化与三水铝石体关系密切.通过详细的野外地质调查和室内分析鉴定,从三水铝石体和铀矿(化)体的时空分布、结构构造、矿物组成、化学成分、稀土元素及微量元素特征等方面,分析探讨了该地区三水铝石体与铀矿(化)体的内在联系,认为该地区广泛发育于石炭系Um Bogma组中的三水铝石体是红土化作用的结果,铀矿化与三水铝石体的关系十分密切,富含三水铝石、高岭石、蒙脱石等粘土矿物的三水铝石体是铀的良好聚集剂,在长期的表生风化过程中,从岩石活化淋滤出来的铀以微粒及超显微颗粒逐渐被三水铝石体所吸附而形成铀矿(化)体.  相似文献   

17.
Major, trace and organic elements of a South China were reported to investigate elements laterite profile developed on Neogene basalt on Hainan Island, mobilization and redistribution in tropical regions. The results indicate that strong acid environment and organic matter （OM） can remarkably improve the transfer of insoluble elements. Among all the elements, Th is the least mobile. As for the general conservative elements during incipient chemical weathering, such as Ti, Zr, Hf and Nb, the removals are up to 30%-40% in the upper profile. And for Fe, A1, Cu and Ni, that tend to be combined with secondary minerals and to be retained in temperate zone, they are re- moved from the upper profile, transferred downwards, and then precipitated in the lower profile. In addition, atmos- pheric inputs, including sea salt aerosols and dust, have a profound effect on the budgets of elements that are susceptible to leaching losses （e.g. K, Na and Sr）. Excluding the possibilities of groundwater and erosion, the remarkable increase of K, Na and Sr concentrations in the upper profile, together with dramatically upward increasing trends of the percentage changes of Sr/Th, K/Th and Na/Th ratios, show that atmospheric inputs, especially sea salt aerosols, contribute much extraneous seawater derived elements, such as K, Na and Sr to the soils. The overall elemental be- haviors in this profile suggest that organic matter and atmospheric inputs play a very important role in the mobiliza- tion and redistribution of elements during extreme weathering in tropical regions.  相似文献   

18.
The mineralogy and geochemistry data are presented for thirty-seven shales,four concretions,two carbonate sediments and seven lignites from the Marathousa coal field of the Megalopolis Basin in Greece.The argillaceous rocks consist of chlorite,illite,kaolinte,albite,quartz.opal-A,calcite and dolomite;the concretions of aragonite,gypsum and pyrite;and the carbonate rocks of calcite,quartz and illite.The mineral matter in the lignites consists of gypsum,quartz,albite,chlorite,illite,opal-A,dolomite,pyrite,and rarely calcite and kaolinite Athree-factor model explains the total variaition of major and trace elements in the argillaceous sediments.The first factor is an aluminosilicate factor and involves the following elements:Al,Si,Mg,Na,K,Ti,Mn,Nb,Y,Rb,Zn,Cu,Ni,Cr,Nband V,associated with chlorite,albite and illite.The second factor involves the elements Ca,Sr,Ba,Znand Sc and is related to carbonate lithology and mainly the carbonate concretions with gypsum.The third factor involves Fe and Ce with a weak association with Mn.The diagenesis of the Marathousa sediments and lignites was not very advanced as indicated by (a) the total thickness of the sequence (500m),(b) the presence of biogenic silica(opal-A) and (c) the age of the deposit(Pleistocene).FOr these reasons the rpresence of chlorite,illite and kaolinite in the sediments and lignite is due not to diagenetic reactions but to weathering of the flysch and metamorphic rocks at the edges of the Megalopolis Basin and transport of the weathering products(illite,chlorite,kaolinite)into the basin of deposition.The diagenetic minerals of the Marathousa sequence include pyrite,gypsum,dolomite and aragonite.  相似文献   

19.
Weathering of heavy metal enriched black shales may be one of the most important sources of environmental contamination in areas where black shales are distributed. Heavy metal release during weathering of the Lower Cambrian Black Shales (LCBS) in western Hunan, China, was investigated using traditional geochemical methods and the ICP-MS analytical technique. Concentrations of 16 heavy metals, 8 trace elements and P were measured for samples from selected weathering profiles at the Taiping vanadium ore mine (TP), the Matian phosphorous ore mine (MT), and Taojiang stone-coal mine (TJ). The results show that the bedrock at these three profiles is enriched with Sc, V, Cr, Co, Ni, Cu, Zn, Pb, Th, U, Mo, Cd, Sb, Tl, and P. Based on mass-balance calculation, the percentages of heavy metals released (in % loss) relative to immobile element Nb were estimated. The results show significant rates of release during weathering of: V, Cr, Co, Ni, Cu, Zn, U, Mo, Cd, Sn, Sb, and Tl for the TP profile; Sc, Cr, Mn, Co, Ni, Cu, Zn, Pb, Th, Cd, and Sn for the MT profile; and Sc, Mn, Co, Ni, Zn, Th, Cd, Sn, and Tl for the TJ profile. Among these heavy metals, Co, Ni, Zn, Cd, and Sn show very similar features of release from each of the three weathering profiles. The heavy metals released during weathering may affect the environment (especially topsoil and surface waters) and are possibly related to an observed high incidence of endemic diseases in the area.  相似文献   

20.
黔北白云岩红色风化壳元素地球化学特征   总被引：5，自引：3，他引：2  
李锐  高杰  张莉  李今今  季宏兵 《中国岩溶》2014,33(4):396-404
选取贵州高原喀斯特地区典型白云岩风化剖面作为研究对象,探讨了红土剖面元素迁移特征及其影响因素,为进一步认识红色风化壳元素地球化学特征提供依据。结果表明:（1）红土剖面中土壤样品（XPS-4~XPS-25）Fe、K、Mn常量元素及Co、Pb、Zn微量元素的分布曲线相对于其他元素靠近 UCC,元素Mg、Ca、Na、Ti和 Li、Cr、Ba、V 的数据点则显著偏离了上部陆壳的平均组成。（2）元素对协变分析得出Ti与Fe、Ba和V的积累特征一致,呈增加趋势;Ti与Mg呈反向变化特征。（3）以Ti为参比元素的剖面迁移特征表明,绝大部分元素的地球化学行为表现为迁移淋失,仅 Fe 、Cr和V 富集。K、Ba总体上呈迁出趋势,个别层段有轻微富集;Na和Co在风化原岩处有一个富集端点。元素在风化过程中的迁移聚集与土壤剖面的pH值和剖面结构变化、粘土矿物和有机质等的吸附有关。   相似文献   

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