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1.
High As contents in groundwater were found in Rayen area and chosen for a detailed hydrogeochemical study. A total of 121 groundwater samples were collected from existing tube wells in the study areas in January 2012 and analyzed. Hydrogeochemical data of samples suggested that the groundwater is mostly Na–Cl type; also nearly 25.62 % of samples have arsenic concentrations above WHO permissible value (10 μg/l) for drinking waters with maximum concentration of aqueous arsenic up to 25,000 μg/l. The reducing conditions prevailing in the area and high arsenic concentration correlated with high bicarbonate and pH. Results show that arsenic is released into groundwater by two major phenomena: (1) through reduction of arsenic-bearing iron oxides/oxyhydroxides and Fe may be precipitated as iron sulfide when anoxic conditions prevail in the aquifer sediments and (2) transferring of As into the water system during water–acidic volcanic rock interactions.  相似文献   

2.
Hydrogeochemistry of the Saloum (Senegal) superficial coastal aquifer   总被引:1,自引:0,他引:1  
Seawater has entered and concentrated in the Saloum hydrologic system up to 100 km upstream, contaminating both the surface water and the superficial 'Continental terminal' (CT) groundwater resources, and large proportions of cultivated lands. In the areas affected by saltwater contamination, chloride concentrations as high as 3,195 mg/l have been measured in the groundwater samples collected from wells located in the vicinity of the Saloum River, making the water inadequate for drinking water purposes. This paper presents the results of a study designed to characterise the current extent of the saline groundwater and the mechanism of saline surface water body/fresh groundwater mixing in relation to the groundwater flow trends. It also describes the groundwater chemical and isotopic composition and geochemical processes controlling the chemical patterns. Four major water types occur in the study area, namely Na-rich saline groundwater, Ca-Na-rich saline groundwater, Na-dominant fresh groundwater and Ca-dominant fresh groundwater. A hydrogeochemical zonation of the aquifer, based on the presence of different water families and on the groundwater flow, led to the identification of the main processes controlling the groundwater chemistry. Cation exchange reactions on the kaolinite clay mineral, calcite dissolution in the eastern zone where calcite minerals have been identified, reverse cation exchange reactions in the saline-contaminated band along the Saloum River and, to a lesser extent, a gypsum dissolution are the predominant processes. Results of i18O and iD analysis in 15 groundwater samples compared with the local meteoric line indicate that the groundwater has been affected by evaporation, and the groundwater is isotopically lighter as the depth of water table increases. In this study, i18O data were used in conjunction with chloride data to identify the source of high chloride. Results show a departure of the contaminated water samples from the seawater mixing line, which indicates that other processes rather than mixing between modern seawater and native groundwater alone increase the chloride concentrations.  相似文献   

3.
The present study was carried out in the Mulaylih area which forms a part of Wadi Al Hamad in the Madinah Province of Saudi Arabia. Thirty groundwater samples from agricultural farms were collected and analyzed for various physio-chemical parameters including trace elements. The area is occupied by the Quaternary alluvium deposits which form shallow unconfined aquifers. Evaporation and ion exchange are the major processes which control the major ion chemistry of the area. The extreme aridity has results in high total dissolved solid values (average of 9793.47 mg/l). Trace element concentrations are low and are mainly attributed to geogenic sources (silicate weathering). Na-Cl groundwater type is the main hydrochemical facies found in the area. The waters are found to be oversaturated with calcite/aragonite and dolomite. The average nitrate concentration was found to be 134.10 mg/l and is much higher than the WHO recommended limit of 50 mg/l in drinking water. Their high values are mainly associated with the application of N-fertilizers on the agricultural farms. The average fluoride concentration in the study was found to be 1.54 mg/l. The relation between F and Cl and Cl and Na reveals that the fluoride concentrations are mainly attributed to geogenic sources. A comparison of the groundwater quality with the Saudi drinking water standards shows that the water is unfit for drinking. The high salinity and sodicity of the groundwater make it unfit for irrigation. Principal component analysis resulted in extraction of four principal components accounting for 79.5% of the total data variability and supports the fact that the natural hydrochemical processes (evaporation and ion exchange) control the overall groundwater chemistry.  相似文献   

4.
Groundwater quality assessment in southern parts of Tehran plain,Iran   总被引:1,自引:1,他引:0  
The hydrochemical characteristics of groundwater in the southern parts of Tehran Province are considered. Twenty-three sampling stations were selected and major anions/cations, electrical conductivity and pH were detected. Sulfate and chloride were found as major anions, while no specific dominant cation was determined. More than half of the samples were found to be unsuitable for drinking purposes, due to high concentrations of anions/cations. Regarding agricultural use, almost all samples were classified as having high-risk levels of salinity, while for alkali hazard considerable risks were observed in most cases. Generally, an increasing trend of salinity is observed from northwest to southeast of the study area. Such increase may be justified by the adjacency of the Iran central desert and salt lake to the southern boundaries of the study area. Extended use of sulfate-containing fertilizers may also play a key role in justifying the high sulfate concentration in comparison to other anions.  相似文献   

5.
Intensive agriculture by indiscriminate use of agrochemicals, sewage water, and polluted drain water has posed a serious threat to groundwater quality in some peri-urban areas of Delhi like Najafgarh block. The objective of the study was to determine the groundwater quality and to map their spatial variation in terms of suitability for irrigation and drinking purpose. Ordinary kriging method was used for preparation of thematic maps of groundwater quality parameters such as electrical conductivity, sodium adsorption ratio, bicarbonate, magnesium/calcium ratio, total dissolved solids, chloride, nitrate and hardness. Exponential semivariogram model was best fitted for all quality parameters except chloride and hardness, where spherical model fitted best. Pollution level was highest at south and south-eastern part of the study area. Better quality groundwater may be expected at the northern and western part. High salinity was due to high chloride concentration in the groundwater. Nitrate pollution level was found to be very alarming and need immediate interventions. High dissolved solids and hardness made the groundwater unsuitable for drinking. There were negligible sodium and bicarbonate hazard in the study area. The groundwater quality index was devised to analyse the combined impact of different quality parameters on irrigation and drinking purposes. The irrigation water quality index and drinking water quality index distribution maps delineated an area of 47.29 and 6.54 km2 suitable for irrigation and drinking, respectively. These safe zones were found as a small strip along the northern boundary and a very small pocket at the western side of the study area.  相似文献   

6.
A hydrogeochemical approach has been carried out in the Mio-Plio-Quaternary aquifer system of northern Sfax to investigate the geochemical evolution, the origin of groundwaters and their circulation patterns. The groundwater samples collected from different wells seem to be dominated by sodium chloride type to sulphate chloride type. Detail analysis of chemical data including the thermodynamic calculations was used to assess that the chemical evolution of groundwater is primarily controlled by water–rock interactions. The values of sodium absorption ratio and electrical conductivity of the groundwater were plotted in the US Salinity Laboratory diagram for irrigation water. Most of the water samples in northern Sfax fall in the fields of C4S1, C4S2 and C4S3 indicating very high salinity and medium to high sodium alkalinity hazard. Thus, groundwater quality is ranging between doubtful to unsuitable for irrigation uses under normal condition, and further action for salinity control is required in remediating such problem. Principal component analysis of geochemical data used in conjunction with bivariate diagrams of major elements indicates that groundwater mineralization is mainly controlled by (1) water–rock interaction processes, (2) anthropogenic process in relation with return flow of NO3-rich irrigation waters and (3) domestic discharges.  相似文献   

7.
The Cihanbeyli basin is located in the northern part of Konya in the Central Anatolian region, Turkey and is characterized by semi-arid climatic conditions and scarcity in water resources. The suitability of groundwater quality for drinking and agricultural purposes in the Cihanbeyli basin was assessed by measuring physicochemical parameters, including major cation and anion compositions, pH, total dissolved solid, electrical conductivity, and total hardness. For this purpose, 54 samples were collected from different sources viz. deep wells, shallow wells, and springs. Results from hydrochemical analyses reveal that groundwater is mostly affected by salty and gypsiferous lithologies. Evaporite minerals such as gypsum, anhydrite, and chloride salts make high contributions from the recharge areas (west, northwest, and southwest parts) toward the discharge area (central and eastern parts). High values of total dissolved solids in groundwater are associated with high concentrations of all major ions. A comparison of groundwater quality in relation to drinking water standards showed that most of the water samples are not suitable for drinking. Based on sodium absorption ratio values and percent sodium, salinity appears to be responsible for the poor groundwater quality, rendering most of the samples unsuitable for irrigation usage. It is concluded that evaporation and mineral dissolution are the main processes that determine major ion compositions.  相似文献   

8.
In this study, combining interpretations of conservative dissolved ions and environmental isotopes in water were used to investigate the main factors and mechanisms controlling groundwater salinization and hydrogeochemical processes in the Eastern Nile Delta, Egypt. Hydrogeochemical and isotopic study has been carried out for 61 water samples from the study area. Total dissolved solid (TDS) contents of groundwater are highly variable rising along flowpath from the south (410 mg/L) to the north (14,784 mg/L), implying significant deterioration and salinization of groundwater. Based on TDS and ionic ratios, groundwater samples were classified into three groups. In low-saline groups, water chemistry is greatly influenced by cation exchange, mineral dissolution/precipitation, anthropogenic pollutants and mixing with surface water. Whilst, in high-saline groups, water chemistry is affected by salt-water intrusion, reverse cation exchange and evaporation. The chemical constituents originating from saline water sources, reverse ion exchange and mineral dissolution are successfully differentiated using ionic delta and saturation index approaches. The δ18O–δ2H relationship plots on a typical evaporation line, suggesting potential evaporation of the recharging water prior to infiltration. Isotope evidence concludes that the groundwater have been considerably formed by mixing between depleted meteoric water recharged under different climatic conditions and recently infiltrating enriched surface water and excess of irrigation water. The δ18O data in conjunction with chloride concentrations provide firm evidence for impact of dissolution of marine-origin evaporite deposits, during past geologic periods, on groundwater salinity in the northern region. Moreover, the relation between 14C activities and Cl? concentration confirms this hypothesis.  相似文献   

9.
Coastal aquifers are considered as major sources for freshwater supply worldwide, especially in arid zones. The weak rainfall as well as the intensive extraction of groundwater from coastal aquifers reduce freshwater budget and create local water aquifer depression, causing both seawater intrusion and a threat to groundwater. This phenomenon was observed in the Jerba Island which is located in southeast Tunisia. Jerba??s unconfined aquifer shows high values of groundwater salinity reaching, locally, 17?g/l and a strong contrast between some zones of the aquifer. High pumping rates and weak recharge disturb the natural equilibrium between fresh and saline water causing water salinization in most areas of the island. This study aims at establishing the salinity map of the aquifer and identifying the origin of groundwater salinization. The salinity map shows that zones characterized by low groundwater salinity are located in the center of the study area. High groundwater salinities are observed near the coast and in some parts having low topographic and piezometric levels. Groundwater geochemical characterization, and Br/Cl and Na/Cl ratios suggest that the origin of abnormal salinity is seawater intrusion. Considering groundwater salinity values and Br concentrations, a seawater intrusion map is established. It shows that many areas of the unconfined aquifer are contaminated by mixed groundwater and seawater. The statistical analysis demonstrates that high mineralization of the groundwater is due to gypsum and carbonate dissolution coupled with the mixed groundwater and seawater in many areas.  相似文献   

10.
In order to mine lignite from the Neyveli opencast mines, about 200 km south of Madras, India, the Neyveli aquifer has been undergoing depressurisation continuously for almost three decades. To gain insight into the aquifer hydrodynamics, environmental-isotope and chloride measurements on selected groundwater samples were initiated two decades ago, and detailed studies were undertaken during 1985–91. This article demonstrates the effect of large-scale groundwater withdrawals on the hydrologic regime and the effects on environmental chloride and isotopic distributions. A feature common to both the radiocarbon and chloride data of 1991 is their marked variation in a small area between the recharge zone and the mine area where pumping is concentrated. Furthermore, an excellent correlation exists between the temporal increase in the apparent radiocarbon ages of groundwater sampled in 1991 and 1985 and the corresponding lowering of potentiometric levels. Isochlors based on 1991 and 1985 data also indicate a changed hydrologic regime. In certain areas, heavy withdrawals have resulted in increased groundwater salinity.  相似文献   

11.
吕晓立  刘景涛  周冰  朱亮 《中国地质》2020,47(6):1765-1775
以新疆塔城盆地80组地下水样品水化学组分测试结果为依据,结合区域地质、水文地质调查资料,研究塔城盆地地下水中铁、锰分布特征及其成因。结果表明,研究区浅层地下水中铁、锰浓度总体较低,局部超标,其空间分布特征基本一致。对比2017年发布的地下水质量标准,地下水中铁、锰超标率依次为25%和5%,深层承压水铁、锰含量均未超标。地下水中铁锰离子浓度受原生地质环境所控,同时叠加人类活动影响,城镇周边人口密集区尤其是排污沟渠附近地下水中耗氧量、溶解性总固体、铁、锰含量明显升高。地下水中铁锰超标连片区域呈条带状或斑块状分布于塔城盆地北部山区、中部冲积平原区以及南部低山丘陵区的铜钼成矿带,受人类活动影响,在塔城市、额敏县及其周边的地表水和地下水重污染区分布有地下水铁、锰重污染点,污染物特别是有机污染物排放所引起的还原环境促使地层中难溶的铁锰矿物的溶解释放。地层中,尤其是矿床及周边地层中高含量的铁锰是地下水中铁锰的重要来源,沉积层中富含丰富的有机质同时叠加人类活动输入所形成的还原条件是研究区地下水中铁、锰迁移和富集的主控因素。  相似文献   

12.
The current research has been conducted to evaluate groundwater aquifers qualitatively in the area located in the Western side of Qena city. The Quaternary aquifer represents the main groundwater source in the study area. It exists under unconfined to semiconfined conditions at depths varying between 4 m due North and 80 m in the South. The chemical analyses of the groundwater samples indicate that 77% of the total samples are fresh and 20% are brackish, while only 3% are saline. In addition, the iso-salinity contour map indicates that the salinity increases towards the central and northern parts of the study area. The total and permanent hardness increase as water salinity increases and vice versa in case of temporary hardness in the groundwater samples. The chemical water types and the ion ratios indicate meteoric origin of groundwater as well as the dissolution of terrestrial and marine salts. The contribution of recent recharge from the River Nile to a few groundwater wells in the study area varies from low to high. In addition, the most recharge sources are from the precipitation. Nitrate concentrations in groundwater increase towards the central and Northern areas significantly elevated in response to increasing anthropogenic land uses. Much of the solutes and physicochemical parameters in these waters are under the undesirable limits of World Health Organization (WHO) for drinking purpose, and a plot of sodium adsorption ratio versus EC shows that about 23% of the groundwater samples are good water quality, about 45% of groundwater samples are moderate quality, and 23% of the groundwater samples are intermediate water class, while the rest of samples (9%) are out of the range.  相似文献   

13.
Integrated hydrogeochemical and geophysical methods were used to study the salinity of groundwater aquifers along the coastal area of north Kelantan. For the hydrogeochemical investigation, analysis of major ion contents of the groundwater was conducted, and other chemical parameters such as pH and total dissolved solids were also determined. For the geophysical study, both geoelectrical resistivity soundings and reflection seismic surveys were conducted to determine the characteristics of the subsurface and groundwater contained within the aquifers. The pH values range from 6.2 to 6.8, indicating that the groundwater in the study area is slightly acidic. Low content of chloride suggests that the groundwater in the first aquifer is fresh, with an average concentration of about 15.8 mg/l and high geoelectrical resistivity (>45 ohm m). On the other hand, the groundwater in the second aquifer is brackish, with chloride concentration ranging from 500 mg/l to 3,600 mg/l and very low geoelectrical resistivity (<45 ohm m) as well as high concentration of total dissolved solids (>1,000 mg/l). The groundwater in the third aquifer is fresh, with chloride concentrations generally ranging from 2 mg/l to 210 mg/l and geoelectrical resistivity of greater than 45 ohm m. Fresh and saltwater interface in the first aquifer is generally located directly in the area of the coast, but, for the second aquifer, both hydrogeochemical and geoelectrical resistivity results indicate that the fresh water and saltwater interface is located as far as 6 km from the beach. The considerable chloride ion content initially suggests that the salinity of the groundwater in the second aquifer is probably caused by the intrusion of seawater. However, continuous monitoring of the chloride content of the second aquifer indicated no significant changes with time, from which it can be inferred that the salinity of the groundwater is not affected by seasonal seawater intrusion. Schoeller diagrams illustrate that sulphate concentrations of the groundwater of the second aquifer are relatively low compared to those of the recent seawater. Therefore, this result suggests that the brackish water in the second aquifer is probably from ancient seawater that was trapped within the sediments for a long period of time, rather than due to direct seawater intrusion.  相似文献   

14.
On the origin of oil-field water in the Biyang Depression of China   总被引:1,自引:0,他引:1  
We have surveyed groundwater samples collected from oil and gas reservoirs in the Biyang Depression of China and quantitatively analyzed the chemical features of those samples using the proportional coefficients. Three different proportional coefficients, namely the de-calcium–magnesium, the boron–calcium–magnesium, and the chloration coefficients have been calculated. These three coefficients reflect the strength of de-calcium–magnesium reaction, the trace elements concentrations, and the degree of diagenesis of the oil-field water, respectively. The concentrations of calcium and magnesium ions are found to be very low in the groundwater of the Biyang Depression. The concentration of anion in the oil-field groundwater changes greatly with the salinity of groundwater in the Biyang Depression. In low salinity oil field, bicarbonate is generally the dominating anion; but when salinity increases, sulfate gradually replaces bicarbonate to become the dominating anion. However, in high salinity oil field, chloride is the dominating anion. Bromine, iodine, and boron are found to be relatively rich in oil-field water of Biyang Depression. The results show that extensive dolomite deposited near the center of the depression was resulted from de-calcium–magnesium reaction, and the degree of diagenesis of the oil-field water and concentrations of trace elements increase with buried depth in the reservoir.  相似文献   

15.
Elevated salinity in groundwater (over 250?mg/l chloride) in a fractured chalk aquifer in the municipality of Greve, Denmark, has been attributed to seawater intrusion from the Baltic Sea, resulting in the closure of a number of wells nearest to the coastline. However, a recent study in eastern Denmark shows that the salinity could also be from ancient connate pore waters. Historical chemistry data from bulk-water samples collected from wells have been used to determine the source. The sample data were studied with respect to their historical changes and temporal trends in chloride, carbonate, sulfate, sodium, potassium, magnesium, and calcium. Wells in the southern third of the municipality are relatively low in sodium and carbonate and high in chloride and calcium/magnesium, indicating waters undergoing saline intrusion. Wells in the northern two-thirds of the municipality are high in carbonate and sodium, but low in chloride and calcium/magnesium, indicating a freshening of the aquifer. This is confirmed by the temporal trends in chloride, where chloride levels in the northern wells remain constant, whereas in the south, chloride increases as abstraction continues. Therefore close monitoring for seawater intrusion should be conducted in the southern third of the municipality.  相似文献   

16.
Hormozgan Province with arid climate is an important source of energy resources for Iran. This study investigates the results of hydrogeochemical investigation and its tectonic control in Hormozgan Province, Southern Iran. The chemical analysis of 158 groundwater samples was evaluated to determine the hydrogeochemical processes and ion concentration background in the region. Several NW-SE trending and NE-dipping basement reverse faults have intersected the area and have divided it into four tectonic terranes. Huge extension of Hormuz Formation in Zagros Foredeep tectonic terrane has increased the cations, Cl and SO4 concentration in groundwaters. HCO3 concentration in Sanandaj-Sirjan Zone and High Zagros is the result of silicate weathering or carbonates. Eighty-three percent of samples have negative CAI values in High Zagros, Sanandaj-Sirjan Zone, and eastern Zagros Fold Thrust Belt. The dominant hydrochemical facies of groundwater are Na-Mg-Ca-Cl (25.3% of samples) and Na-Mg-Cl (20.9% of samples). They are confined to the west of Main Zagros Reverse Fault and east of High Zagros Fault, respectively. The salt content of the groundwater indicates samples with very high salinity—as a result of Hormuz Formation—are mainly limited to the west of High Zagros Fault while samples with high to medium salinity are mainly limited to the east of this fault. Eastward increment of rock weathering is controlled with thrust faults activity of the area and southwestward migration of deformation front. Westward increment of evaporites is compatible with Hormuz Formation/salt dome density through the area.  相似文献   

17.
Integrated geoelectrical and hydrochemical surveys were used to investigate and delineate different types of groundwater in the Kuala Selangor alluvial aquifer. Previous hydrogeological borehole investigation showed that this aquifer contains several types of groundwater in relation to its salinity. The high salinity of the groundwater in some areas is believed to be due to either saltwater intrusion from the nearby sea or river infiltration during high tide season. The vertical electrical sounding (VES) method was employed to study and map the subsurface variation of resistivity in the area. For each sounding measurement, a total spread length of 300 m was obtained with a vertical depth penetration of about 60 to 75 m. Chemical analysis of the groundwater samples taken from both shallow and deep boreholes was carried out for the water quality determination. A total of 45 VES stations were succesfully established along three parallel roads with a direction almost perpendicular to the coastal line. The distance between stations varies from 1 to 2 km with a maximum length of about 60 km surveyed line. Results of the vertical electrical soundings as well as the hydrochemistry of the groundwater samples show that the soil and groundwater in the study area can be grouped into fresh and brackish water zones. The subsurface resisitivity sections derived from the VES study suggest that the area is dominated by brackish soil and groundwater zones, especially in the area towards the coast. This result appears to agree well with the groundwater pumped from boreholes scattered around in the area. Water drawn from boreholes near the coast showed higher salinity compared to the water pumped from inland boreholes. Chloride values greater than 250 mg/L are considered to represent the brackish zones whilst values less than 250 mg/L represents zones of fresh soil and groundwater.  相似文献   

18.
Panvel Basin of Raigarh district, Maharashtra, India is the study area for groundwater quality mapping using the Geographic Information System (GIS). The study area is typically covered by Deccan basaltic rock types of Cretaceous to Eocene age. Though the basin receives heavy rainfall, it frequently faces water scarcity problems as well as water quality problems in some specific areas. Hence, a GIS based groundwater quality mapping has been carried out in the region with the help of data generated from chemical analysis of water samples collected from the basin. Groundwater samples show quality exceedence in terms of chloride, hardness, TDS and salinity. These parameters indicate the level of quality of groundwater for drinking and irrigation purposes. Idrisi 32 GIS software was used for generation of various thematic maps and for spatial analysis and integration to produce the final groundwater quality map. The groundwater quality map shows fragments pictorially representing groundwater zones that are desirable and undesirable for drinking and irrigation purposes.  相似文献   

19.
煤系水矿化度是影响低煤阶煤层气生成、运移和成藏的重要因素之一。以新疆准噶尔盆地南缘地区为研究区,把研究区划分为8个水文地质单元,分析了研究区煤系水矿化度的分布特征及其对产甲烷菌生存的影响。以1 000 m埋深为例,估算了各个水文地质单元内煤系水的甲烷溶解度,据此分析评价了各水文地质单元溶解运移甲烷的能力。通过煤系水的矿化度分布、氯离子浓度和区域地质构造形态分析,综合判断区域内煤系水的大致流向。以准南地区硫磺沟水文地质单元为例,探讨了矿化度与煤层气富集成藏的关系。研究结果表明,研究区矿化度分布具有南北分带、东西分段的特征。后峡水文地质单元、玛纳斯河-呼图壁河水文地质单元的南部、硫磺沟水文地质单元的南端和阜康水文地质单元的西部地区矿化度有利于产甲烷菌的生存和产气。后峡水文地质单元溶解运移甲烷能力最强。地下水的流向大致由南向北,地表水的径流会使地下水流向发生偏转。指出了硫磺沟水文地质单元内高矿化度中心和低水位的汇水洼地是低煤阶煤层气富集成藏的地区。   相似文献   

20.
To understand the impact of the influence of treated wastewater, a study was undertaken in the downstream side of Wadi Hanifa in the southern part of Riyadh City in Saudi Arabia. Chemical elements from 17 groundwater samples, 9 surface water samples (treated wastewater), and 14 soil samples were analyzed. Water facies analyses showed that both groundwater and surface water belong to the SO4-Cl class. However, the groundwater is characterized by high salinity (average value of 3547 mg/l), which may be result of the greater rock-water interaction and limited rainfall recharge. The NO3 values are also high in the groundwater samples (average value of 40 mg/l) and are mainly attributed to the agricultural practices in the study area. The surface water samples (treated wastewater from the plant) shows an average salinity value of 1232 mg/l and is better suited for irrigation purposes. Heavy elements analyzed in the soil samples show high concentrations of all the elements except Mn and Ni as compared to their background concentration. Enrichment factor and index of geoaccumulation calculated from the soil samples indicate that they are severely enriched with respect to Cd and Se. The spatial distribution maps were prepared based on kriging interpolation technique to estimate the concentrations of the analyzed elements at unknown locations. The treated wastewater in the study area is better suited for agricultural and domestic activities as compared to groundwater.  相似文献   

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