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1.
Physical and hydraulic properties of sediment from two karst aquifers were measured to determine (1) the similarity of sediment between karst aquifer systems and (2) the importance of sediment in modeling flow through karst aquifers. The sediment from the two systems was similar in size and composition. Within both aquifers, the silt-sized sediment was composed primarily of quartz, with minor amounts of plagioclase and clays. Hydraulic conductivity of the sediment measured directly (falling-head test) ranged from 1.61×10−7 to 1.33×10−6 m s–1 and estimated using the Campbell equation ranged from 8.30×10−8 to 8.98×10−7 m s–1. These values of hydraulic conductivity fall within the span of hydraulic conductivities for carbonate rocks, indicating that the sediment and carbonate matrix could be represented as one mathematical unit in modeling flow through karst aquifers. Statistical agreement in the hydraulic conductivity values generated by the two methods indicates that the estimation technique could be used to calculate hydraulic conductivities; thus allowing karst scientist to collect bulk sediment samples instead of having to collect cores from within karst aquifers. Electronic Publication  相似文献   

2.
In situ feldspar dissolution rates in an aquifer   总被引：1，自引：0，他引：1  
In situ silicate dissolution rates within the saturated Navajo sandstone, at Black Mesa, Arizona were determined from elemental fluxes in the aquifer. The mass transfer between groundwater and mineral matrix along flow paths was calculated from inverse mass balance modeling. The reaction time is bound by 14C-based travel time. BET surface areas were measured with N2 gas adsorption. Dissolution rates for K-feldspar and plagioclase are 10−19 and 10−16 mol (feldspar) m−2 s−1, respectively, which are ∼105 times slower than laboratory experiment-derived rates under similar pH and temperature but at far from equilibrium conditions. The rates obtained in this study are consistent with the slower field rates found in numerous watershed and soil profile studies. However, these rates are from saturated aquifers, overcoming some concerns on estimated rates from unsaturated systems. The Navajo sandstone is a quartz-sandstone with a relatively simple and well-studied hydrogeology, groundwater geochemistry, and lithology, a large number of groundwater analyses and 14C groundwater ages, groundwater residence times up to ∼37 ky, groundwater pH from ∼8 to 10, and temperature from ∼15 to 35°C.  相似文献   

3.
We developed light requirements for eelgrass in the Pacific Northwest, USA, to evaluate the effects of short- and long-term reductions in irradiance reaching eelgrass, especially related to turbidity and overwater structures. Photosynthesis-irradiance experiments and depth distribution field studies indicated that eelgrass productivity was maximum at a photosynthetic photon flux density (PPFD) of about 350–550 μmol quanta m−2 s−1. Winter plants had approximately threefold greater net apparent primary productivity rate at the same irradiance as summer plants. Growth studies using artificial shading as well as field monitoring of light and eelgrass growth indicated that long-term survival required at least 3 mol quanta m−2 day−1 on average during spring and summer (i.e., May-September), and that growth was saturated above about 7 mol quanta m−2 day−1. We conclude that non-light-limited growth of eelgrass in the Pacific Northwest requires an average of at least 7 mol quanta m−2 day−1 during spring and summer and that long-term survival requires a minimum average of 3 mol quanta m−2 day−1.  相似文献   

4.
 Jurassic Ferrar rocks in Victoria Land (Antarctica) occur predominantly as basaltic or andesitic flows and sills. Both show characteristic petrographical and chemical variations, which can be related to in-situ differentiation processes. Such characteristics have been investigated at one flow (“Colonnade flow”) and one sill (“Thumb Point sill”) in the Prince Albert Mountains (Central Victoria Land) based on a statistical grain size analysis and the application of the crystal size distribution theory. A third magma body (“HiTi-unit”), which in previous literature was described as a flow, does not show clear similarities to either the flow or sill. Sill and flow are in-situ differentiated with accumulation of silicic residual melt in the latest cooled parts. For the flow this part is located in the lower half and for the sill in the upper third of their thickness. Thumb Point sill additionally shows an accumulation zone of olivine in the lower third. The position of the residual melt accumulation zone is an indicator for an origin as flow or sill. The HiTi-unit, by contrast, exhibits, only moderate petrographical and chemical variations. Growth and nucleation rates have been determined using, with some modifications, the CSD theory introduced by Marsh (1988). Growth rates of plagioclase for the flow vary from 10−11 to 10−10 cm/s and are comparable with literature values for basaltic lava lakes on Hawaii. Nucleation rates vary from 10−4 to 10−3 cm−3s−1, which are generally smaller than for Hawaiian basalts. Growth and nucleation rates for the sill cover a large range from 10−13 to 10−11 cm/s and 10−9 to 10−3 cm−3s−1, respectively. Systematic variations of these parameters with vertical position were obtained for the sill with its extensive differentiation history. Nucleation and growth rates are dependant on the mode of cooling. Nevertheless, small but significant differences between the flow and sill exist. Growth and nucleation rates of HiTi-unit (10−12 to 10−11 cm/s and 10−6 to 10−5 cm−3s−1) are intermediate between the flow and sill and thus do not allow a distinction of emplacement mode. Received: 6 December 1995 / Accepted: 3 May 1996  相似文献   

5.
Alaknanda and Bhagirathi (AB) river basins in the Himalayan region in India expose lithologies comprising mainly of granites, low–high-grade metamorphics, shales and carbonates which, in conjunction with the monsoon rains and glacial melt, control water chemistry and dissolved elemental flux rates. In the present study, we monitored two locations: (a) Srinagar on the Alaknanda river and (b) Maneri on the Bhagirathi river for daily variations in total suspended sediments, major ions and dissolved silica over one complete year (July 2004–June 2005). Based on long-term discharge data, discharge-weighted composition and dissolved elemental flux rates (with respect to Ca, Mg, HCO3, Si) of the river were estimated. The information thus obtained has substantially added up to the existing chemical data of these rivers and has refined the flux rates. Our high-frequency samples provide informations such as (a) water chemical compositions that show a large temporal and spatial variation and (b) carbonate lithology that controls water chemistry predominantly. The dissolution kinetics of various lithologies namely leucogranite, gneiss, quartzite, phyllite and shale of the AB river basins were studied through batch experiments at controlled temperature (25 and 5°C) and pH (8.4) condition. In laboratory, these lithologies undergo slow rates of dissolution (10−13 to 10−15 mol/m2 s), while field weathering rates based on dissolved elemental flux rates in the AB rivers are much higher (10−8 to 10−9 mol/m2 s). Extremely high physical weathering rates in AB rivers, which enhance chemical weathering significantly, mainly attribute this wide discrepancy in laboratory-derived rates of representative basin rocks and dissolved elemental fluxes in the field. However, laboratory-simulated experiments facilitate to quantify elemental release rates, understand the kinetics of the dissolution reactions, and compare their roles at individual level.  相似文献   

6.
Zakynthos, an island of 408 km2 in the Ionian Sea, is completely dependent on its groundwater resources for fulfilling the demands of the water supplies. The use of groundwater resources has become particularly intensive during the last decades because of the intense urbanization, the tourist development and the irrigated land expansion that took place. The main aquifers are developed in limestones (karstic), sandstones of neogene deposits (confined) and alluvial deposits (phreatic). This paper focuses on the assessment of their hydrogeological characteristics and the groundwater quality. For this investigation, groundwater level measurements, drilling data, pumping tests and chemical analyses of groundwater samples were used. The average annual consumption that is abstracted from the aquifer systems, is 4.9 × 106 m3 year−1. The exploitable groundwater reserves were estimated to be 3.3 × 106 m3 year−1. In the last decades, the total abstractions exceed the natural recharge, due to the tourist development; therefore the aquifer systems are not used safely. The results of chemical analyses showed a deterioration of the groundwater quality. According to the analyses the shallow alluvial aquifer and the confined aquifer are polluted by nitrates at concentrations in excess of 25 mg L−1. High sulphate concentrations might be related to the dissolution of gypsum. Seawater intrusion phenomena are recorded in coastal parts of aquifer systems. The increased Cl− concentrations in karstic aquifer indicate signs of overexploitation. Strengths, weaknesses, opportunities and threats (SWOT) analysis was applied in order to evaluate the SWOT of the groundwater resources. Moreover, some recommendations are made to assist the rational management that aim at improving the sustainability of the groundwater resources of Zakynthos Island.  相似文献   

7.
Denitrification rates along a salinity gradient in the eutrophic Neuse River Estuary, North Carolina, were quantified using membrane inlet mass spectrometry (MIMS) within short-term batch incubations. Denitrification rates within the system were highly variable, ranging from 0 to 275 μmol N m−2 h−1. Intrasite variability increased with salinity, but no significant differences were observed across the salinity gradient. Denitrification rates were positively correlated with sediment oxygen demand at the upstream sampling site where sediment organic carbon levels were lowest. This relationship was not observed in the more saline sampling sites. Denitrification rates were highest during winter. On an annual basis, denitrification accounted for 26% of the dissolved inorganic nitrogen and 12% of the total nitrogen supplied to the system.  相似文献   

8.
The Bou-Areg plain in the Mediterranean coast at the North-eastern of Morocco is characterized by a semi-arid climate. The aquifer consists of two sedimentary formations of Plio-quaternary age: the upper formation of fine silts and the lower one of coarse silts with sand and gravels. The aquifer is underlain by marly bedrock of Miocene age that dips toward the coastal lagoon of Bou-Areg. The hydrodynamic characteristics vary between 10−4 and 10−3 m/s; and transmissivities range between 10−4 and 10−1 m2/s. The general direction of flow is SW to NE, toward the lagoon. The aquifer is crossed by the river Selouane, which also ends in the lagoon. The groundwater is characterized by a high salinity that can reach 7.5 g/l. The highest values are observed in the upstream and in the downstream sectors of the aquifer. The temporal evolution of the physico-chemical parameters depends on the climatic conditions and piezometric variations. The analysis of the spatio-temporal distribution of the physico-chemical parameters suggests different sources of groundwater salinization: the seawater intrusion, the influence of marly gypsum-bearing terrains, and the influence of anthropogenic products as the agricultural fertilizers, which cause great nitrate concentrations that vary between 80 and 140 mg/l.  相似文献   

9.
Reactive tracer tests are performed to derive flow, transport and in situ biodegradation parameters. This paper describes the 3D simulation of a reactive tracer test using the transition probability geostatistical approach. Fifty different equally probable aquifer realizations were generated based on the geological information of 107 boreholes in an area of 62,500 m2. One realization was chosen for the reactive transport simulation based on the results of groundwater flow modeling and on particle tracking calculations for the site. Field velocities at the site vary between 0.4 and 3 m/d. The transport of the reactive tracers deuterium ring labeled toluene-d5 and fully deuterated toluene-d8 was simulated and first-order biodegradation rates of 0.017 d−1 for toluene-d5 and 0.012 d−1 for toluene-d8 were determined.  相似文献   

10.
Hydraulic properties of the crystalline basement   总被引：1，自引：1，他引：1  
Hydraulic tests in boreholes, up to 4.5 km deep, drilled into continental crystalline basement revealed hydraulic conductivity (K) values that range over nine log-units from 10−13−10−4 m s−1. However, K values for fractured basement to about 1 km depth are typically restricted to the range from 10−8 to 10−6 m s−1. New data from an extended injection test at the KTB research site (part of the Continental Deep Drilling Program in Germany) at 4 km depth provide K=5 10−8 m s−1. The summarized K-data show a very strong dependence on lithology and on the local deformation history of a particular area. In highly fractured regions, granite tends to be more pervious than gneiss. The fracture porosity is generally saturated with Na–Cl or Ca–Na–Cl type waters with salinities ranging from <1 to >100 g L−1. The basement permeability is well within the conditions for advective fluid and heat transport. Consequently, fluid pressure is hydrostatic and a Darcy flow mechanism is possible to a great depth. Topography-related hydraulic gradients in moderately conductive basement may result in characteristic advective flow rates of up to 100 L a−1 m−2 and lead to significant advective heat and solute transfer in the upper brittle crust. An erratum to this article can be found at  相似文献   

11.
Fluxes of carbon dioxide, water vapor, and heat were measured above crop canopy using the eddy covariance method during the 2008 maize growing season, over an agricultural field within an oasis located in the middle reaches of Heihe River basin, northwest China. The values for friction velocity, the Monin–Obukhov stability parameter, and energy balance closure indicated that the eddy covariance system at this study site provided reliable flux estimates. Results from measurements showed that the mean sensible heat flux was 70 W m−2 with a maximum value of 164 W m−2 (May) and a minimum value of 45 W m−2 (July) during the maize growing season. In contrast, the mean latent heat was 278 W m−2 with a maximum value of 383 W m−2 (July) and minimum of 101 W m−2 (May). The mean downward soil heat flux was 55 W m−2 with a maximum value of 127 W m−2 (May) and minimum of 49 W m−2 (July). The magnitude of mean daytime net CO2 uptake was −11.50 μmol m−2 s−1 with a maximum value of −28.32 μmol m−2 s−1 (18 and 19 July) and a minimum values of −0.32 μmol m−2 s−1 (18 and 19 May). Correlation was observed between daytime half-hourly carbon dioxide flux and canopy conductance. In addition, the relationship between carbon dioxide flux and photosynthetically active radiation for selected days during different stages of maize growing season indicated the carbon dioxide flux uptake by the canopy was controlled by actual photosynthetic activity related to the variation of green leaf area index for the different growing stages.  相似文献   

12.
To determine the removal of regenerated nitrogen by estuarine sediments, we compared sediment N2 fluxes to the stoichiometry of nutrient and O2 fluxes in cores collected in the Childs River, Cape Cod, Massachusetts. The difference between the annual PO4 3− (0.2 mol P m−2 yr−1) and NH4 + (1.6 mol N m−2 yr−1) flux and the Redfield N∶P ratio of 16 suggested an annual deficit of 1.5 mol N m−2 yr−1. Denitrification predicted from O2∶NH4 + flux ratios and measured as N2 flux suggested a nitrogen sink of roughly the same magnitude (1.4 mol N m−2 yr−1). Denitrification accounted for low N∶P ratios of benthic flux and removed 32–37% of nitrogen inputs entering the relatively highly nutrient loaded Childs River, despite a relatively brief residence time for freshwater in this system. Uptake of bottom water nitrate could only supply a fraction of the observed N2 flux. Removal of regenerated nitrogen by denitrification in this system appears to vary seasonally. Denitrification efficiency was inversely correlated with oxygen and ammonium flux and was lowest in summer. We investigated the effect of organic matter on denitrification by simulating phytoplankton deposition to cores incubated in the lab and by deploying chambers on bare and macroaglae covered sediments in the field. Organic matter addition to sediments increased N2 flux and did not alter denitrification efficiency. Increased N2 flux co-varied with O2 and NH4 + fluxes. N2 flux (261±60 μmol m−2 h−1) was lower in chambers deployed on macroalgal beds than deployed on bare sediments (458±70 μmol m−2 h−1), and O2 uptake rate was higher in chambers deployed on macroalgal beds (14.6±2.2 mmol m−2 h−1) than on bare sediments (9.6±1.5 mmol m−2 h−1). Macroalgal cover, which can retain nitrogen in the system, is a link between nutrient loading and denitrification. Decreased denitrification due to increasing macroalgal cover could create a positive feedback because decreasing denitrification would increase nitrogen availability and could increase macroalgae cover.  相似文献   

13.
To investigate the possible variations of Rn concentration in crystalline rocks as a function of flow conditions, a field study was carried out of a fractured aquifer in granite. The method is based on the in situ measurement of Rn in groundwater, aquifer tests for the determination of hydraulic characteristics of the aquifer and laboratory measurement of Rn exhalation rate from rocks. A simple crack model that simulates the Rn concentration in waters circulating in a fracture intersecting a borehole was also tested. The Rn concentrations in groundwaters from boreholes of the study site ranged from 192 to 1597 Bq L−1. The Rn exhalation rates of selected samples of granite and micaschist were determined from laboratory experiments. The results yielded fluxes varying from 0.5 to 1.3 mBq m−2 s−1 in granite and from 0.5 to 0.9 mBq m−2 s−1 in micaschists. Pumping tests were performed in the studied boreholes to estimate the transmissivity and calculate the equivalent hydraulic aperture of the fractures. Transmissivities ranged from 10−5 to 10−3 m2 s−1. Using the cubic law, hydraulic equivalent fracture apertures were calculated to be in the range of 0.5–2.3 mm.  相似文献   

14.
The high permeability of sediments and strong near-bottom currents cause seawater to infiltrate the surface layers of Middle Atlantic Bight shelf deposits. In this study, sandy sediment cores from 11 to 12 m water depth were percolated with filtered seawater on shipboard. Sedimentary oxygen consumption (SOC) increased non-linearly with pore water flow, approaching maximum rates of 120 mmol m−2 d−1 (May 2001) or 75 mmol m−2 d−1(July 2001). The addition of acetate to the inflowing water promptly enhanced the release of dissolved inorganic carbon (DIC) from the cores. DIC production rates were a linear function of acetate concentration, ranging from 100 to 300 mmol m−2 d−1 without substrate addition to 572 mmol m−2 d−1 with 100 mM acetate. The sediments also hydrolyzed a glucose pseudopolymer, and the liberated glucose prompted an increase of SOC. Our results suggest that decomposition rates of organic matter in permeable sands can exceed those of fine-grained, organic-rich deposits, when water currents cause advective interstitial flow, supplying the subsurface microbial community with degradable material and electron acceptors. We conclude that the highly permeable sand beds of the Middle Atlantic Bight are responsive within minutes to hours and efficiently operate as biocatalytical filters.  相似文献   

15.
The waters of the Seine river estuary, located in a highly anthropogenicized area in the northern part of France, are of poor microbiological quality; the concentrations of faecal bacteria usually exceed the European Union bathing and recreational water directives. The aim of the present study was to identify the main sources of the faecal pollution of the Seine estuary in order to help define priorities for management and sanitation efforts. Budgets of faecal coliform (FC) inputs to the estuary were established for various hydrological conditions. Main sources of FC were the outfalls of the treated effluents of the wastewater treatment plants (WWTPs) located along the estuary, the faecal bacteria brought in through the tributaries of the Seine estuary, and the faecal bacteria transported by the Seine river flow at the estuary entrance at Poses dam. In order to quantify these inputs, FC were enumerated during sampling campaigns conducted for various hydrological conditions in the Seine at the entrance of the estuary, in the tributaries close to their confluence with the estuary, and in the effluents of some WWTPs located along the estuary. The importance of the flux of FC transported by the Seine river flow at the estuary entrance at Poses dam decreased from 92% of the total FC input when the flow rate was high (717 m3 s−1) to 5% when flow rate was low (143 m3 s−1). The release of the domestic wastewaters of the large city of Paris located 120 km upstream from the entrance of the estuary was mainly responsible for this microbiological pollution. At low flow rates, the tributaries represent the most important source of FC (64–76% for flow rates of the Seine at Poses at approximately 150 m3 s−1), mainly from the Robec and Eure rivers. The treated wastewater of the WWTPs located along the estuary was the second source of FC for low flow conditions (19–30%); it was less important for high to intermediate flow rate conditions.  相似文献   

16.
Modeling of groundwater flow for Mujib aquifer, Jordan   总被引：4，自引：0，他引：4  
Jordan is an arid country with very limited water resources. Groundwater is the main source for its water supply. Mujib aquifer is located in the central part of Jordan and is a major source of drinking water for Amman, Madaba and Karak cities. High abstraction rates from Mujib aquifer during the previous years lead to a major decline in water levels and deterioration in groundwater quality. Therefore, proper groundwater management of Mujib aquifer is necessary; and groundwater flow modeling is essential for proper management. For this purpose, Modflow was used to build a groundwater flow model to simulate the behavior of the flow system under different stresses. The model was calibrated for steady state condition by matching observed and simulated initial head counter lines. Drawdown data for the period 1985–1995 were used to calibrate the transient model by matching simulated drawdown with the observed one. Then, the transient model was validated by using drawdown data for the period 1996–2002. The results of the calibrated model showed that the horizontal hydraulic conductivity of the B2/A7 aquifer ranges between 0.001 and 40m/d. Calibrated specific yield ranges from 0.0001 to 0.15. The water balance for the steady state condition of Mujib aquifer indicated that the total annual direct recharge is 20.4 × 106m3, the total annual inflow is 13.0 × 106 m3, springs discharge is 15.3 × 106 m3, and total annual outflow is 18.7 × 106 m3. Different scenarios were considered to predict aquifer system response under different conditions. The results of the sensitivity analysis show that the model is highly sensitive to horizontal hydraulic conductivity and anisotropy and with lower level to the recharge rates. Also the model is sensitive to specific yield  相似文献   

17.
Groundwater recharge by natural replenishment for the unconsolidated alluvial aquifer in Wadi Al-Yammaniyah is estimated on a daily basis instead of the conventional monthly basis The study reveals that during the two-year period (1978 and 1979), the estimated recharge in the area is about 40% of the total average annual rainfall of 155 mm Subsurface underflow estimated at 36×10−6 m3/yr from the Wadi Al-Yammaniyah aquifer occurs in the vicinity of Wadi Ash-Shamiyah A comparison of the recharge and extracted volumes of water from the aquifer indicates that there is a net increase of 10 million m3 and 38 million m3 of water in the storage for 1978 and 1979, respectively  相似文献   

18.
Two 14-day experiments conducted in the dry summer (July 2006) and wet winter (March 2007) seasons, respectively, examined tidal, wave-driven, and seasonal variability of submarine groundwater discharge (SGD) at Stinson Beach, CA, using natural radium tracers. Tide stage, tide range, breaker height, and season each explained a significant degree of radium variability in the surf zone. A mass balance of excess radium in the surf zone was used to estimate SGD for each season, confirming larger discharge rates during the wet season. Our results indicate median groundwater discharge rates of 6 to 8 L min−1 m−1 in July 2006 and 38 to 43 L min−1 m−1 in March 2007. SGD from 200 m of Stinson Beach in March 2007 contributed a flux of phosphate and dissolved inorganic nitrogen approximately equal to that associated with all local creeks and streams within 6 km of the study site at that time.  相似文献   

19.
Sulfate reduction rate (SRR) and pools of reduced inorganic sulfur, acid volatile sulfide (AVS), chromium reducible sulfur (CRS), and elemental sulfur (So), were studied from June 1990 till March 1992 at two locations on the Ballastplaat mudflat in the Scheldt estuary. The sediment composition at station A was mainly sand with low organic content whereas sediments at station B were dominated by silt and clay with high organic content. SRR was positively related to temperature; more pronounced at station B (Ea=190 kJ mol−1) than at station A (Ea=110 kJ mol−1). The maximum SRR values observed equalled 14 μmol cm−3 d−1 at station B and 1 μmol cm−3 d−1 at station A. AVS was the dominant radiolabelled end product of the sulfate reduction reaction, except in surface sediments where pyrite and So were more dominant. However, CRS was the predominant reduced inorganic sulfur pool in the sediments. Both AVS and CRS pools showed temporal variations out of phase with SRR. SRR peaked in summer, while the concentrations of AVS and CRS were highest in fall. The accumulation of AVS and CRS started late summer after depletion of oxidants, which had accumulated during winter and spring. The estimated annual SRR and thus sulfide production in the upper 15 cm of station B was of the order of 100 mol m−2 yr−1, and at station A of the order of 12 mol m−2 yr−1. The sulfur mass balance shows that only a very small fraction, if any, of the produced sulfide is retained as reduced inorganic sulfur in the sediment.  相似文献   

20.
In this study rates of oxygen, ammonium (NH4 +), nitrate (NO3 −), nitrite (NO2 −), and nitrous oxide (N2O) fluxes, nitrogen (N) fixation, nitrification, and denitrification were compared between two intertidal sites for which there is an abundant global literature, muddy and sandy sediments, and two sites representing the rocky intertidal zone where biogeochemical processes have scarcely been investigated. In almost all sites oxygen production rates greatly exceeded oxygen consumption rates. During daylight, NH4 + and NO3 − uptake rates together with ammonification could supply the different N requirements of the primary producer communities at all four sites; N assimilation by benthic or epilithic primary producers was the major process of dissolved inorganic nitrogen (DIN) removal; N fixation, nitrification, and denitrification were minor processes in the overall light DIN cycle. At night, distinct DIN cycling processes took place in the four environments, denitrification rates ranged from 9 ± 2 to 360 ± 30 μmol N2 m−2 h−1, accounting for 10–48% of the water column NO3 − uptake; nitrification rates varied from 0 to 1712 ± 666 μmol NH4 + m−2 h−1. A conceptual model of N cycle dynamics showed major differences between intertidal sediment and rocky sites in terms of the mean rates of DIN net fluxes and the processes involved, with rocky biofilm showing generally higher fluxes. Of particular significance, the intertidal rocky biofilms released 10 times the amount of N2O produced in intertidal sediments (up to 17 ± 6 μmol N2O m−2 h−1), representing the highest N2O release rates ever recorded for marine systems. The biogeochemical contributions of intertidal rocky substrata to estuarine and coastal processes warrant future detailed investigation.  相似文献   

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