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目前,我国金属矿床中见到铋硫盐矿物共46种,其中有8种未定名矿物。在PbS_Bi2S3系列矿物中,实验矿物学(L.L.Y.Chang)上已有的10种PbS-Bi2O3系列矿物,即由富硫铋铅矿→硫铋铅矿→针辉铋铅矿→柱辉铋铅矿→斜方辉铋铅矿→卡辉铋铅矿→辉铋铅矿→杂硫铅铋矿→斜方硫铋铅矿→柱硫铋铅矿,我国应有尽有外,还发现有4种PbS-Bi2S3的未定名的矿物。块辉铋铅银矿中暂定的3个亚各,我 辄全 相似文献
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本文在研究广西大厂矿田产出一组细密交生的锑-铋硫盐矿物共生组合基础上进行了矿物合成及元素代换实验。成功地合成了硫锑铋铁矿并确认了锑-铋不完全代换形成的辉铁锑矿-硫锑铋铁矿系列。 相似文献
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黑西哥FresnilloAg-Pb-Zn地区的SantoNino脉中,银含在螺状硫银矿及三个含银矿盐固溶体系列的矿物中,这些硫盐矿物是:浓红银矿、淡红银矿、硫锑铜银矿、硒硫铜银矿、黝铜矿及脆银矿。 相似文献
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对Ag_2S-Cu_2S-PbS-Bi_2S_3四元体系内铋硫盐矿物的类质同象取代类型的研究表明,它共有四种:配对取代Ag(Cu)+Bi=2Pb,简单取代Ag=Cu,Bi(Pb)=Cu和Cu原子填隙(以平衡Bi或Pb为Cu取代时电价差)。研究还给出了体系内10个重要固溶体的成分及结晶参数之间的关系。对这些固溶体及铜、银、铅铋硫盐矿物结构特征、共生和共生长关系研究表明,它们可以分成四个系列:块硫铋银矿、硫铋铅矿、辉铋矿-针硫铋铅矿、贺硫铋铜矿。 相似文献
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夏塞银多金属矿床中硫化物和硫盐系列矿物特征及其意义 总被引:4,自引:1,他引:3
夏塞矿主档是大型的热液脉型银多金属矿床,通过对大量矿石光(薄)片观察和电子探针分析表明,除主要(方铅矿、富铁闪锌矿)和次要(黄铁矿、毒砂、磁黄铁矿、黄铜矿等)硫化物外,硫盐毓硫物十分发育,主要有Cu-Sb-Ag硫盐(黝铜矿、含银黝铜矿和银黝铜矿)、Sb-Ag硫盐(深红银矿、辉锑银矿)、Pb-Sb硫盐(脆硫锑铅矿、硫锑铅矿)和Bi-Pb硫盐(斜方辉饿铅矿)。此外,尚有少(微)量黄锡矿、锡石、自然饿和银金矿等。银的硫盐硫物和硫化物(辉银矿)乃是获得银的主要工业矿物,这些硫盐毓矿物常与硫化物伴生,多沿方铅矿、富铁闪锌矿、黄铁矿等的解理、裂隙或粒间产出,这些研究结果不仅有助于了解矿化作用过程,而且为矿床评价,组分综合利用和选冶提供重要依据。 相似文献
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福建碧田矿床成因上是与燕山晚期次火山岩有关的,以银为主的大型铜金银矿床。该矿床产于燕山早期花岗岩中,在其铜矿石内发现了较多的锌砷黔铜矿、铋砷黝铜矿、铋锑黝铜矿、碲砷黝铜矿,针硫铋铅矿、硫铋铜矿、硫砷铜矿等硫盐矿物及少见的钨锡矿化物-硫锡铁铜矿,硫铁锡铜矿和硫钨锡铜矿。 相似文献
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碧田矿床是成因上与燕山晚期次火山岩有关的以银为主的大型铜金银矿床。金属矿物种类复杂,除常见的黄铁矿、黄铜矿、斑铜矿外,还有多种铜铋硫盐矿物(锌砷黝铜矿、铋砷黝铜矿、铋锑黝铜矿、针硫铋铅矿、硫铋铜矿)、钨锡硫化物(硫铁锡铜矿、硫钨锡铜矿)及多金属硫化物。金银矿物除辉银矿外,主要是Au-Ag系列的自然金、银金矿、金银矿及自然银。这些矿物形成于不同的物理化学条件下,大多数铜矿物、铜铋硫盐矿物和钨锡硫化物是在中高温(260—380℃)条件下、硫逸度较高(lgfS2=-8.74—-12.06)、流体盐度高并处于沸腾的状况下形成的;而多金属硫化物和金银矿物则主要是在中低温(120—260℃)条件下,硫逸度较低(lgfS2=-11.6—-19.5),流体盐度也较低的状况下形成的。 相似文献
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云南大硐厂铅锌矿床中的硫碲铋矿A 总被引:1,自引:0,他引:1
硫碲铋矿A产于云南省大硐厂铅锌矿床,与自然铋、辉铋铅矿共生。晶体呈柱状,粒度0.02 ̄0.3mm。反光显微镜下呈淡黄色,弱非均质性,反射率Rc′=52.4%,R0=48.8%(波长为540nm),显微压入硬度Hv=46 ̄72kg/mm^2。主要粉晶谱线:3.065(10),2.120(7),1.346(5),2.220(4)。三方晶系,空间群为D3d^5-R3↑-m,晶胞参数a=0.4241nm, 相似文献
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《Resource Geology》2018,68(3):209-226
Shin‐Otoyo, Suttsu, Teine, Date, Chitose, and Koryu are sites rich in precious and base metal Miocene–Pleistocene epithermal deposits, and located in southwestern Hokkaido, Japan. The deposits are predominantly hosted by the Green Tuff Formation of Middle Miocene age. Ore petrographic study of these deposits shows the occurrence of variable quantities of Cu–As–Sb–Ag–Bi–Pb–Te sulfosalt minerals. Determination of mineralogical and chemical compositions of the sulfosalt minerals was undertaken to elucidate the time and spatial changes of the sulfide‐sulfosalt minerals. Various types of sulfosalt minerals identified from gold–silver and base metal quartz–sulfide veins represented some sulfosalt mineralization phases, such as the Cu–Fe–Sn–S phase of mawsonite and stannite; Cu–(As,Sb)–S phase of tetrahedrite–tennantite and luzonite–famatinite series minerals; (Cu,Ag)–Bi–Pb–S phase of emplectite, pavonite, friedrichite, aikinite, and lillianite–gustavite series minerals; (Ag,Cu)–(As,Sb)–S phase of proustite–pyrargyrite and pearceite–polybasite series minerals; and Bi–Te–S phase of tetradymite and kawazulite minerals. There are some trends in the paragenetic sequence of sulfosalt mineralization in southwestern Hokkaido (in complete or partial) as follows: sulfide → Cu–Fe–Sn–S → (Cu,Ag)–Bi–Pb–S → (Bi–Te–S) → Cu–(As,Sb)–S → ([Ag,Cu]–[As,Sb]–S). The formation of sulfosalt minerals is characterized by the introduction of some elements such as Sn, Bi, and Te at an earlier stage and an increase or decrease of some elements such as As and Sb, followed by the introduction of Ag at the later stage of ore mineral paragenesis sequence. Mineral composition of the Chitose and Koryu deposits are slightly different from those of Shin‐Otoyo, Suttsu, Teine, and Date due to their lack of Sn (tin) and Bi (bismuth) mineralization. The variable concentrations and relationships are not simply with redistributed trace elements from the original sulfide minerals of chalcopyrite, pyrite, galena, and sphalerite. Some heavier elements were also introduced during the replacement reaction, which is consistent with the occurrence of their associated minerals. 相似文献
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锌-砷黝铜矿产于内蒙的某一铅锌矽卡岩矿床中,呈它形粒状集合体,粒径0.2-0.5mm,铅灰色,硬度HvHN=339-388kg/mm2。反射色呈灰蓝色微带绿色。均质性。其成分经电子探针分析(平均值)为:S 25.94,As 10.70,Cu 39.67,Zn 7.36,Sb 9.81,Bi 5.81,Ag 0.18,Fe 0.37(%),化学式为:(Cu10.02Age03)10.05(Zn1.81Fe0.11)1.82(As2.29Sb1.29Bi0.45)4.03S18。X射线分析:晶胞参数a=10.322,粉末衍射强线是2.98,1.82,1.56。 相似文献
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对Ag_2S-Cu_2S-PhS-Bi_2S_3四元体系500℃相图研究表明,整个体系相关系受十个组分范围变化大的固溶体和一个液相区控制。它们是:块硫铋银矿、铜银铅铋矿、硫铋铅矿、富硫铋铅矿、辉铋矿-针硫铋铅矿、方铅矿-杂硫铋银矿、硫铋铜矿和人工合成相CuBi_3S_5、Cu_3Bi_5S_8及新相“C”。此外体系内稳定的相是四元系端元相和辉铅铋矿。 相似文献
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