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The Lavrion carbonate-hosted Pb-Ag-Zn deposit in southeast Attica, Greece, consisted of significant non-sulfide ore bodies. The polymetallic sulfide mineralization was subjected to supergene oxidation, giving rise to gossan. The principal non-sulfide minerals of past economic importance were smithsonite, goethite and hematite. The supergene mineral assemblages occupy secondary open spaces and occur as replacement pods within marble. Calamine and iron ore mainly filled open fractures. X-ray diffraction and scanning electron microscopy of samples of oxidized ore indicate complex gossan mineralogy depending on the hypogene mineralogy, the degree of oxidation and leaching of elements, and the local hydrologic conditions. Bulk chemical analysis of the samples indicated high ore-grade variability of the supergene mineralization. On multivariate cluster analysis of geochemical data the elements were classified into groups providing evidence for their differential mobilization during dissolution, transport and re-precipitation. The mode of occurrence, textures, mineralogy and geochemistry of the non-sulfide mineralization confirm that it is undoubtedly of supergene origin: the product of influx into open fractures in the country rock of highly acidic, metal-rich water resulting from the oxidation of pyrite-rich sulfide protore. Dissolution of carbonates led to opening of the fractures. Mineral deposition in the supergene ore took place under near-neutral to mildly acidic conditions. The supergene dissolution and re-precipitation of Fe and Zn in the host marble increased metal grades and separated iron and zinc from lead, thereby producing economically attractive deposits; it further contributed to minimization of pollution impact on both soil and ground water. 相似文献
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Sajjad Maghfouri Mohammad Reza Hosseinzadeh Abdorrahman Rajabi Flavien Choulet 《地学前缘(英文版)》2018,9(1):249-272
The numerous non-sulfide zinc ore deposits were the historical basis for the development of zinc mining in Iran.They include the Mehdiabad,Irankouh and Angouran world-class deposits,as well as the Zarigan and Haft-har deposits.These deposits were formed by supergene oxidation of primary sulfide minerals during the complex interplay of tectonic uplift,karst development,changes in the level of the water table,and weathering.Zn(Pb)carbonates,Zn-hydrosilicates and associated hydrated phases directly replace the primary ore bodies or fill cavities along fractures related to uplift tectonics.Direct replacement of primary sulfides is accompanied by distal precipitation of zinc non-sulfide minerals in cavities or internal sediments filling.The mineralogy of the non-sulfide mineralization in all six deposits is generally complex and consists of smithsonite,hydrozincite,and hemimorphite as the main economic minerals,accompanied by iron and manganese oxy-hydroxides and residual clays.Commonly,non-sulfide minerals in these deposits consist of two types of ore:red zinc ore(RZO),rich in Zn,Fe,Pb-(As)and white zinc ore(WZO),typically with very high zinc grades but low concentrations of iron and lead.Typical minerals of the RZO are Fe-oxyhydroxides,goethite,hematite,hemimorphite,smithsonite and/or hydrozincite and cerussite.Common minerals of the WZO are smithsonite or hydrozincite and only minor amounts of Fe-oxyhydroxides and hemimorphite. 相似文献
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陕西镇安二台子金铜矿床表生地球化学异常特征 总被引：4，自引：0，他引：4
为查明二台子金铜矿床的表生地球化学异常特征，采用土壤地球化学综合剖面的研究方法，对其进行了详细的分析研究。结果表明，区域上二台子金铜矿床的表生地球化学异常元素组合为Au-As-Sb-Hg-Cu，并表现出与原生异常在组合，含量等特征上的一致性。矿区内金、铜等成矿及指示元素在土壤中的不同层位产生了一定程度的富集。土壤和岩石样品的Au，As，Hg，Cu均密切相关。该矿床上覆的土壤及氧化矿石中的金主要以自然金相，水溶相和硫化物相形式存在，金的这种赋存相态特征可以作为寻找掩埋和隐伏金矿床的标志。 相似文献
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The Tethyan domain from China to Iran hosts many important sediment-hosted Pb–Zn deposits but most have been poorly documented. This study summarizes the salient features of these deposits and discusses the type of ore, tectonic setting, and important ore controls, on the basis of new geological observations and previous publications. The Tethyan domain is characterized by the young and extensive Himalayan–Tibetan and Zagros orogens that formed through collisions between the India/Arabia and Eurasia continents since the Late Cretaceous or early Cenozoic. Abundant Mississippi Valley-type (MVT) and subordinate clastic-dominated (CD, also known as SEDEX) Pb–Zn deposits occur in this domain, including in central and eastern Himalayan–Tibetan orogen in China, the Indian passive margin in southern Pakistan, and various tectonic units of Iran. Economically important deposits contain 0.1–21 Mt Pb + Zn and have total metal resources of ∼75 Mt with ∼48% being oxidized ores. All major deposits known in this domain are MVTs (i.e., the Jinding, Huoshaoyun, Mehdiabad, and Angouran deposits).Mississippi Valley-type Pb–Zn deposits occur in continental-collision-related fold-and-thrust belts and forelands, where deposits are mostly located on the margin of the Eurasian continent, with some in the Indian and Arabian continental margins. Clastic-dominated Pb–Zn deposits occur in central Iran and southern Pakistan, hosted by deep-water siliciclastic sequences of the early Cambrian rifted continental margin of Gondwana and the Jurassic passive continental margin of India, respectively. The youngest mineralized rocks and ages constrain that some important MVT deposits (e.g., the Jinding, Chaqupacha, and Angouran deposits) were formed after a main phase of regional compression, during a regional, large-scale strike-slip or crustal-extension stage in a continental collision setting. In sense of lithologic structure, important ore controls for MVT deposits include evaporite diapir structure, carbonate/evaporite dissolution–collapse structure, pre-existing barite, and porous dolostone. Much of the primary sulfide ore in this domain has been oxidized by supergene processes. This is particularly pronounced in the newly discovered Huoshaoyun deposit, where almost all sulfides have been oxidized to smithsonite and cerussite. An understanding of tectonic setting, ore controls, and supergene processes is essential in exploring for MVT deposits in this domain. 相似文献
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鄂东南地区斑岩型矿床是与中酸性浅成小侵入体有关。本文应用模糊数学的原理和方法,对小岩体以地球化学参数所反映的信息,采用F—FFS聚类法,建立模糊聚类识别模型,从而使小岩体含矿性得到评判,快速选择靶区。这对矿产勘查工作,无疑是具有实际意义的。 相似文献