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1.
A one-dimensional, time-dependent model of the neutral and ion composition of the middle atmosphere is used to study the processes controlling the production and loss of odd nitrogen species during particle ionization events. From consideration of the cross-sections for the relevant ionization and dissociation reactions we conclude that between 1.3 and 1.6 odd nitrogen atoms per ion pair are produced in the middle atmosphere. The value in the thermosphere is larger due to the role of atomic oxygen. The time-dependent mutual destruction of odd nitrogen by the reaction N(4S) +NO→ N2+O must be included and the assumption of a nitric oxide production normalized to the ionization rate is invalid. A simulation of the 1972 August solar proton event is presented. The calculated ozone depletion occurring during the event due to the increase in odd nitrogen agrees well with the measured ozone changes.  相似文献   

2.
S.C. Liu  T.M. Donahue 《Icarus》1976,28(2):231-246
It is shown that under present conditions the Jeans escape flux of hydrogen from Mars in the form of H and H2 is constrained to be the same as twice the non-thermal (McElroy, 1972) escape of O atoms. The mediation of the chemical chain that recombines CO2 plays an essential role in regulating the escape of hydrogen to match that of oxygen, confirming a mechanism postulated by McElroy and Donahue (1972). It is also shown that if the oxygen flux changes, a change in the O2 mixing ratio results and the consequence is to induce a large change in the odd hydrogen concentration, and consequently in H2 production and hydrogen escape. The effect is to stabilize the hydrogen escape flux at twice the O flux. It is shown that surface chemistry should not change the operation of this mechanism but has consequences for the eddy coefficient variation at low altitudes. There is a strong correlation between low humidity, large solar zenith angles and large O3 abundances. The effect of argon in a mixing ratio as large as 0.3 on these results is also investigated.  相似文献   

3.
In the mesosphere, water vapor photolysis is the major source of odd hydrogen (H, OH and HO2) under normal conditions. The odd hydrogen produced may then be converted to H2 by the reaction H + HO2→ H2 + O2. This process is responsible for the calculated decrease in the H2O mixing ratio and accompanying increase in the H2 mixing ratio with altitude in the upper mesosphere and lower thermosphere. Charged particle precipitation events are calculated to produce the same effect, particularly in the 70–85 km region, thus temporarily resulting in enhanced conversion of H2O to H2 following such an event. Since odd hydrogen is produced predominantly by water vapor photolysis at these altitudes, decreased odd hydrogen concentrations are also anticipated. Odd hydrogen processes dominate ozone destruction in this region, and so an increase in ozone may occur if odd hydrogen concentrations decrease. We have examined the calculated time behavior of these processes in a numerical model using the August 1972 solar proton event as an example, and we present calculations indicating what might be observed in future events.  相似文献   

4.
It is argued that ozone measurements made by Weeks et al. (1972) can be interpreted in terms of the enhanced ionization present. The conversion of O2+ ions to oxonium, H3O+ · (H2O)n, ions plus the dissociative recombination of these ions provides for an increased OH and/or H formation rate. The resulting enhanced OH and HO2 concentrations reduce the ambient atomic oxygen and hence ozone populations. The net excess H + OH formation rate is found to lie between one and two times the ionization production rate at altitudes where oxonium ions are the dominant positive ion species.  相似文献   

5.
Time variations in the solar flux between 1000 and 4000 Å induce changes in the concentrations of minor constituents in the upper stratosphere and mesosphere. The response of mesospheric ozone to variations in the Lyman α line over the course of several solar rotations may be of measurable magnitude. Large Lyman α fluxes lead to small O3 densities above 65 km due to the enhanced dissociation of H2O and resultant destruction of odd oxygen by odd hydrogen. An increase in continuum and Lyman α fluxes causes a slight enhancement in both the odd oxygen and hydrogen concentrations in the upper stratosphere.  相似文献   

6.
The efficiency with which critical ionization velocity (CIV) discharges can be generated in space experiments is affected by the altitude at which the experiments are conducted. At around 500 km higher plasma density enhances plasma lower hybrid instability, momentum coupling efficiency, and charge exchange which is needed for seed ionization. At higher altitudes where atomic hydrogen and helium become the dominant ambient neutral species, the conditions for CIV discharge may improve considerably because less energy is lost to atmospheric ionization, even though the ambient density is reduced.  相似文献   

7.
Through a line by line calculation, the contributions of the Schumann-Runge bands of the ordinary and isotopic oxygen to the photodissociation of these molecules at different altitudes have been calculated. The photodissociation rates are expressed analytically. Contribution of the satellite lines has been taken into account. Due to the broadening of the SR lines, this contribution is insignificant. Similarly, it is shown that the first and higher vibrational states of the initial molecular states contribute insignificantly to the dissociation rates. It is also shown that the main contribution to the odd oxygen production in the important ozone producing altitudes is from the low vibrational and high rotational quantum numbers. The effect of the temperature on dissociation rates has similarly been studied.Due to its selective absorption, the isotopic oxygen 16O18O produces at 70 km 10 times as much odd oxygen as would be produced if the isotope did not have selective absorption. At this altitude 6% of the odd oxygen produced is due to this isotope. Also, 1.45% of the odd oxygen produced per second in an atmospheric column is due to 16O18O. However, the excess odd oxygen produced is not enough to explain the excess amount of ozone observed in the atmosphere which cannot be accounted for in the photochemical models.The calculated dissociation rates for the isotope are in moderate agreement with similar rates obtained by Blake et al. (1984, J. geophys. Res.89, 7277), but are by an order of magnitude smaller than similar rates given by Cicerone and McCrumb (1980, Geophys. Res. Lett.7, 251).  相似文献   

8.
The behavior of mesospheric odd nitrogen species during and following relativistic and diffuse auroral precipitation events is simulated Below 75 km nitric oxide is enhanced in proportion to the ion pair production function associated with the electron precipitation and the length of the event. Nitrogen dioxide and nitric acid are also enhanced. At 65 Ian the percentage of odd nitrogen for N is 0.1%, HNO3 is 1.6%, NO2 is 15%, and NO is 83.3%. Between 75 and 85 km, NO is depleted during particle events due to the faster destruction of NO by N relative to the production of NO by N reacting with O2 Recovery of NO depends on transport from the lower thermosphere, where NO is produced in abundant amounts during particle events.  相似文献   

9.
The total photoelectron and secondary electron fluxes are calculated at different times and altitudes along the trajectory of Mars Global Surveyor passing through the nightside and dayside martian ionosphere. These results are compared with the electron reflectometer experiment on board Mars Global Surveyor. The calculated electron spectra are in good agreement with this measurement. However, the combined fluxes of proton and hydrogen atom as calculated by E. Kallio and P. Janhunen (2001, J. Geophys. Res.106, 5617-5634) were found to be 1-2 orders of magnitude smaller than the measured spectra. We have also calculated ionization rates and ion and electron densities due to solar EUV, X-ray, and electron-proton-hydrogen atom impacting with atmospheric gases of Mars at solar zenith angles of 75°, 105°, and 127°. In the vicinity of the dayside ionization peak, it is found that the ion production rate caused by the precipitation of proton-hydrogen atom is larger than the X-ray impact ionization rate while at all altitudes, the photoionization rate is always greater than either of the two. Moreover, X-rays contribute greatly to the photoelectron impact ionization rate as compared to the photoion production rate. The calculated electron densities are compared with radio occultation measurements made by Mars Global Surveyor, Viking 1, and Mars 5 spacecraft at these solar zenith angles. The dayside ionosphere produced by proton-hydrogen atom is smaller by an order of magnitude than that produced by solar EUV radiation. X-rays play a significant role in the dayside ionosphere of Mars at the altitude range 100-120 km. Solar wind electrons and protons provide a substantial source for the nightside ionosphere. These calculations are carried out for a solar minimum period using solar wind electron flux, photon flux, neutral densities, and temperatures under nearly the same areophysical conditions as the measurements.  相似文献   

10.
W.J. Borucki  R.C. Whitten  E. Barth 《Icarus》2006,181(2):527-544
The electrical conductivity and electrical charge on the aerosols in atmosphere of Titan are computed for altitudes between 0 and 400 km. Ionization of methane and nitrogen due to galactic cosmic rays (GCR) is important at night where these ions are converted to ion clusters such as CH+5CH4, C7H+7, C4H+7, and H4C7N+. The ubiquitous aerosols observed also play an important role in determining the charge distribution in the atmosphere. Because polycyclic aromatic hydrocarbons (PAHs) are expected in Titan's atmosphere and have been observed in the laboratory and found to be electrophilic, we consider the formation of negative ions. During the night, the very smallest molecular complexes accept free electrons to form negative ions. This results in a large reduction of the electron abundance both in the region between 150 and 350 km over that predicted when such aerosols are not considered. During the day time, ionization by photoemission from aerosols irradiated by solar ultraviolet (UV) radiation overwhelms the GCR-produced ionization. The presence of hydrocarbon and nitrile minor constituents substantially reduces the UV flux in the wavelength band from the cutoff of CH4 at 155 to 200 nm. These aerosols have such a low ionization potential that the bulk of the solar radiation at longer wavelengths is energetic enough to produce a photoionization rate sufficient to create an ionosphere even without galactic cosmic ray (GCR) bombardment. At altitudes below 60 km, the electron and positive ion abundances are influenced by the three-body recombination of ions and electrons. The addition of this reaction significantly reduces the predicted electron abundance over that previously predicted. Our calculations for the dayside show that the peaks of the charge distributions move to larger values as the altitude increases. This variation is the result of the increased UV flux present at the highest altitudes. Clearly, the situation is quite different than that for the night where the peak of the distribution for a particular size is nearly constant with altitude when negative ions are not present. The presence of very small aerosol particles (embryos) may cause the peak of the distribution to decrease from about 8 negative charges to as little as one negative charge or even zero charge. This dependence on altitude will require models of the aerosol formation to change their algorithms to better represent the effect of charged aerosols as a function of altitude. In particular, the charge state will be much higher than previously predicted and it will not be constant with altitude during the day time. Charging of aerosol particles, whether on the dayside or nightside, has a major influence on both the electron abundance and electrical conductivity. The predicted conductivities are within the measurement range of the HASI PWA instrument over most but not all, of the altitude range sampled.  相似文献   

11.
The effects of neutral air winds on the electron content (NT) and other parameters of the mid-latitude ionosphere have been modelled by means of mathematical solutions of the time-dependent continuity and momentum equations for oxygen and hydrogen ions. The geometry is chosen to represent a propagation path between a geosynchronous satellite and a ground station, and the computations are compared with results from slant path observations of the ATS-6 radio beacon made at Lancaster (U.K.) and Boulder, Colorado (U.S.A.).It is demonstrated that the electron content responds markedly to the magnitude and phase of the neutral air winds and that the effect induced by the wind on the electron content shows a consistent quantitative relationship with the wind velocity, especially during daytime. Reasonable variations in the phase and magnitude of the wind produce a range of daily electron content patterns which encompass the range of daily variations observed.The computations show that the wind gives rise to enhanced filling of the protonosphere. This shows as a depressed value of the shape factor (F), which by definition means that a greater fraction of the ionization is at higher altitudes. The depression of F is enhanced by a poleward wind and is suppressed or even superseded by an equatorward wind through changes of the electron density distribution with altitude.  相似文献   

12.
It has been shown that two concentric ionization zones of interstellar magnesium must exist around each star: internal, with a radius coinciding with that of the zone of hydrogen ionizationS H; and external, with a radius greater thanS H, by one order. Unlike interstellar hydrogen, interstellar magnesium is ionized throughout the Galaxy. It also transpires that the ionizing radiation of ordinary hot stars cannot provide for the observed high degree of ionization of interstellar magnesium. The discrepance can be eliminated by assuming the existence of circumstellar clouds or additional ionization sources of interstellar magnesium (X-ray background radiation, high-energy particles, etc.). Stars of the B5 and B0 class play the main role in the formation of ionization zones of interstellar magnesium; the contribution of O class stars is negligible (<1%).  相似文献   

13.
The ionization and dissociation of molecular hydrogen by the ultraviolet (UV) radiation of the parent star lead to the formation of hydrogen atoms with an excess of kinetic energy and, thus, are an important source of suprathermal hydrogen atoms in the upper atmosphere of exoplanet HD 209458b. Contemporary aeronomical models did not investigate these processes because they assumed the fast local thermalization of the hot atoms of hydrogen by elastic collisions. However, the kinetics and transfer of these atoms were not calculated in detail, because they require the solving of the Boltzmann equation for a nonthermal atom population. This work estimates the effect of the UV radiation of the parent star and the accompanying photocleacton flux on the production of the suprathermal fraction of atomic hydrogen in the H2 → H transition region. We also consider the formation of the escaping flux of Hatoms created by this effect in the upper atmosphere of HD 209458b. We calculate the production rate and energy spectrum of the hydrogen atoms with excess kinetic energy during the dissociation of H2. Using the numerical stochastic model created by Shematovich (2004) for a hot planetary corona, we investigate the molecular-scale kinetics and transfer of suprathermal hydrogen atoms in the upper atmosphere and the emergent flux of atoms evaporating from the atmosphere. The latter is estimated as 3.4 × 1012 cm−2 s−1 for a moderate stellar activity level of UV radiation, which leads to a planetary atmosphere evaporation rate of 3.4 × 109 g s−1 due to the process of the dissociation of H2. This estimate is close to the observational value of ∼1010 g s−1 for the rate of atmospheric loss of HD 209458b.  相似文献   

14.
Cosmic ray particles passing through dense lower atmosphere of Venus decay giving rise to various charged and neutral particles. The flux and degradation of dominant cascade particles namely neutrinos and pions are computed and ionization contributions at lower altitudes are estimated. Using the height profile of pion flux, the muon flux is computed and used to estimate ionization at lower altitudes. It is shown that cosmic ray produced ionization descends to much lower altitudes intercepting the thickness of Venus cloud deck. The dynamical features of Venus cloud deck are used to allow the likely charging and charge separation processes resulting into cloud-to-cloud lightning discharges.  相似文献   

15.
The cross-section for dissociative photoionization of hydrogen by 584 Å radiation has been measured, yielding a value of 5 × 10?20 cm2. The process can be explained as a transition from the X1 Σg+ ground state to a continuum level of the X2 Σg+ ionized state of H2 The branching ratio for proton (H+) vs molecular ion (H2+) production at this energy is 8 × 10?3. This process is quite likely an important source of protons in the Jovian ionosphere near altitudes where peak ionization rates are found.  相似文献   

16.
In the Earth's lower thermosphere and mesosphere, water vapor is photodissociated by absorption of Lyman alpha radiation. The hydrogen containing free radicals produced by this process lead to the formation of molecular hydrogen. Therefore, very small water vapor mixing ratios are expected at high altitudes, particularly in summer, when photolysis is especially rapid. We present one and two-dimensional model calculations regarding the distribution of H2O and H2 in the upper atmosphere.The ion chemistry of meteor ions in the lower thermosphere is also examined and it is shown that silicon ion densities can be used to infer water vapor concentrations near 100 km. The water vapor mixing ratios obtained are generally well below one part per million and are in good agreement with the model calculations.  相似文献   

17.
We calculated the ionization fraction for hydrogen and helium (He I) as a function of the redshift z by including the two-photon decays of high hydrogen and parahelium levels and the radiative transfer in the helium 23P1 ? 11S0 intercombination line. We show that this yields corrections of no more than a few percent to the ionization fraction for hydrogen and speeds up significantly the recombination for helium compared to the recent works by Seager et al. (1999, 2000), in which these effects were disregarded.  相似文献   

18.
Choosing an appropriate neutral-density model of martian atmosphere, the photoionization processes have been studied. Using relevant charge transfer and recombination reactions, the equilibrium electron-ion production rates have been computed for all species. The resultant electron-density profiles are compared with the ones measured experimentally by Viking 1 and 2. The theoretical electron-density profile compares well with the measured profiles at low altitudes, but shows rather large values at higher altitudes. The observed oscillation in the electrondensity profile at high altitudes is attributed to the variable nature of impact ionization produced by suprathermal charged particles of solar wind origin.  相似文献   

19.
The Ultraviolet Spectrometer Experiment on the MARINER 10 spacecraft measured the hydrogen Lyman α emmission resonantly scattered in the Venus exosphere at several viewing aspects during the encounter period. Venus encounter occurred at 17:01 GMT on 5 February 1974. Exospheric emissions above the planet's limb were measured and were analyzed with a spherically symmetric, single scattering, two-temperature model. On the sunlit hemisphere the emission profile was represented by an exospheric hydrogen atmosphere with Tc = 275±50 K and nc = 1.5 × 105 cm?3 and a non-thermal contribution represented by TH = 1250±100 K with nH = 500±100 cm?3. The observations of the dark limb showed that the spherically symmetric model used for the sunlit hemisphere was inappropriate for the analysis of the antisolar hemisphere. The density of the non-thermal component had increased at low altitudes, < 12,000 km, and decreased at high altitudes, > 20,000 km, by comparison. We conclude that the non-thermal source is on the sunward side of the planet. Analysis of the dark limb crossing suggests that the exospheric temperature on the dark side is <125 K if the exospheric density remains constant over the planet; upper limits are discussed. An additional source of Lyman α emission, 70 ± 15 R, was detected on the dark side of the planet and is believed to be a planetary albedo in contrast to multiple scattering from the sunlit side. Our analysis of the MARINER 10 data is consistent when applied to the MARINER 5 data.  相似文献   

20.
During the initial phase of magnetic storms with steep onset, the topside ionosphere shows enhancement of ionization above and depletion below a zone of unchanged ionization. During storms with a smoothly initiated disturbance, no enhancement of ionization is observed and depletion takes place at all altitudes.  相似文献   

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