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1.
The quenching rate kN2 of by N2 and the specific recombination rate α1D of O2+ leading to are re-examined in light of available laboratory and satellite data. Use of recent experimental values for the transition probabilities in a re-analysis of AE-C satellite 6300 Å airglow data results in a value for kN2 of 2.3 × 10?11 cm3s?1 at thermospheric temperatures, in excellent agreement with the laboratory measurements. This implies a value of JO2 = 1.5 × 10?6s?1 for the O2 photodissociation rate in the Schumann-Runge continuum. The specific recombination coefficient α1D = 2.1 × 10?7cm3s?1 is also in agreement with the laboratory value. Implications for the suggested reaction are discussed. 相似文献
2.
Measurements of N2+ and supporting data made on the Atmosphere Explorer-C satellite in the ionosphere are used to study the charge exchange process The equality k = (5 ± 1.7) × 10?10cm3s?1. This value lies close to the lower limit of experimental uncertainty of the rate coefficient determined in the laboratory. We have also investigated atomic oxygen quenching of O+(2D) and find that the rate coefficient is 2 × 10?11 cm3s?1 to within approximately a factor of two. 相似文献
3.
A major loss process for the metastable species, O+(2D), in the thermosphere is quenching by electrons .To date no laboratory measurement exists for the rate coefficient of this reaction. Thermospheric models involving this process have thus depended on a theoretically calculated value for the rate coefficient and its variation with electron temperature. Earlier studies of the O+(2D) ion based on the Atmosphere Explorer data gathered near solar minimum, could not quantify this process. However, Atmosphere Explorer measurements made during 1978 exhibit electron densities that are significantly enhanced over those occurring in 1974, due to the large increases that have occurred in the solar extreme ultraviolet flux. Under such conditions, for altitudes ? 280 km, the electron quenching process becomes the major loss mechanism for O+(2D), and the chemistry of the N+2 ion, from which the O+(2D) density is deduced, simplifies to well determined processes. We are thus able to use the in situ satellite measurements made during 1978 to derive the electron quenching rate coefficient. The results confirm the absolute magnitude of the theoretical calculation of the rate coefficient, given by the analytical expression k(Te) = 7.8 × 10?8 (Te/300)?0.5cm3s?1. There is an indication of a stronger temperature dependence, but the agreement is within the error of measurement. 相似文献
4.
Marcel Nicolet 《Planetary and Space Science》1984,32(7):871-880
The photodissociation of water vapour in the mesosphere depends on the absorption of solar radiation in the region (175–200 nm) of the O2 Schumann-Runge band system and also at H-Lyman alpha. The photodissociation products are OH + H, OH + H, O + 2H and H2 + O at Lyman alpha; the percentages for these four channels are 70, 8, 12 and 10%, respectively, but OH + H is the only channel between 175 and 200 nm. Such proportions lead to a production of H atoms corresponding to practically the total photodissociation of H2O, while the production of H2 molecules is only 10% of the H2O photodissociation by Lyman alpha.The photodissociation frequency (s?1) at Lyman alpha can be expressed by a simple formula where F10.7 cm is the solar radioflux at 10.7 cm and N the total number of O2 molecules (cm?2), and when the following conventional value is accepted for the Lyman alpha solar irradiance at the top of the Earth's atmosphere () qLyα,∞ = 3 × 1011 photons cm?2 s1?.The photodissociation frequency for the Schumann-Runge band region is also given for mesospheric conditions by a simple formula where JSRB,∞(H2O) = 1.2 × 10?6 and 1.4 × 10?6 s?1 for quiet and active sun conditions, respectively.The precision of both formulae is good, with an uncertainty less than 10%, but their accuracy depends on the accuracy of observational and experimental parameters such as the absolute solar irradiances, the variable transmittance of O2 and the H2O effective absorption cross sections. The various uncertainties are discussed. As an example, the absolute values deduced from the above formulae could be decreased by about 25-20% if the possible minimum values of the solar irradiances were used. 相似文献
5.
In this paper we confirm an earlier finding that the reaction constitutes a major source of OI 6300 Å dayglow. The rate coefficient for this reaction is found to be consistent with an auroral result, namely k1 ≈ 6 × 10?12cm3s?1. We correct an error in an earlier publication and demonstrate that reaction (1) is consistent with the laboratory determined quenching rate for the reaction where . Dissociative recombination of O+2 with electrons is found to be a major daytime source in summer above ～220 km. 相似文献
6.
V.A. Krasnopolsky 《Planetary and Space Science》1983,31(11):1363-1369
In an updating of energy characteristics of lightnings on Venus obtained from Venera-9 and -10 optical observations, the flash energy is given as 8 × 108 J and the mean energy release of lightnings is 1 erg cm?2 s which is 25 times as high as that on the Earth. Lightnings were observed in the cloud layer. The stroke rate in the near-surface atmosphere is less than 5 s?1 over the entire planet if the light energy of the stroke exceeds 4 × 105 J and less than 15 s?1 for (1–4) × 105 J.The average NO production due to lightnings equals 5 × 108 cm?2 s?1, the atomic nitrogen production is equal to 7 × 109 cm?2s?1,the N flux toward the nightside is 3.2 × 109 cm?2s?1, the number densities [N] = 3 × 107cm?3 and [NO] = 1.8 × 106cm?3 at 135 km. Almost all NO molecules in the upper atmosphere vanish interacting with N and the resulting NO flux at 90-80 km equals 5 × 105cm?2s?1, which is negligibly small as compared with lightning production. If the predissociation at 80–90 km is regarded as the single sink of NO, its mixing ratio, fNO, is 4 × 10?8, for the case of a surface sink fNO = 0.8 × 10?9 at 50 km. Excess amounts, , may exist in the thunderstorm region. 相似文献
7.
Iztok Čadež 《Planetary and Space Science》1983,31(8):843-848
The resonant electron impact quenching of metastable molecules might be important for understanding the phenomena in the upper atmosphere. In order to obtain information about the relative importance of this scattering event the resonant cross sections for electron scattering by metastable nitrogen in the state were calculated using the “boomerang” model and quenching rates for this state were evaluated for the altitudes of 130,170 and 210km. The obtained quenching rates are small (?5 × 10?3 s?1), even with respect to the radiative transition rate showing that under the considered conditions this process is unimportant for population of nitrogen state in the Earth's thermosphere. 相似文献
8.
Recent laboratory studies show that the quantum yield, , from O2+ dissociative recombination varies considerably with the degree r of vibrational excitation. However, the suggestion that the high values for deduced from airglow and auroral observations can be explained by invoking vibrational excitation, creates a number of problems. Firstly, the rapid vibrational deactivation of O2+ ions by collisions with O atoms will keep r too low to account for the magnitude of ; secondly, r varies considerably from one atmospheric source to another but its relative values (which should be reliable) do not co-vary with those of ; thirdly, because r increases markedly above the peak of the dissociative recombination layer, the fits which theorists have obtained to the observed volume emission rate profiles would have to be regarded as fortuitious. It is tentatively suggested that is higher in the airglow and aurora than in the laboratory plasma studied by Zipf (1980) because of the electron temperature dependence of the specific recombination coefficient for O2+(v' ? 3) ions.The repulsive state of O2 does not provide a suitable channel for the dissociative recombination. A possible alternative is the bound state with predissociation to the repulsive state. 相似文献
9.
K.M. Monahan W.T. Huntress A.L. Lane J.M. Ajello T.E. Burke P. Le Breton A. Williamson 《Planetary and Space Science》1974,22(1):143-149
The cross-section for dissociative photoionization of hydrogen by 584 Å radiation has been measured, yielding a value of 5 × 10?20 cm2. The process can be explained as a transition from the ground state to a continuum level of the ionized state of H2 The branching ratio for proton (H+) vs molecular ion (H2+) production at this energy is 8 × 10?3. This process is quite likely an important source of protons in the Jovian ionosphere near altitudes where peak ionization rates are found. 相似文献
10.
H. Böhringer M. Durup-Ferguson E.E. Ferguson D.W. Fahey 《Planetary and Space Science》1983,31(4):483-487
New experimental techniques have yielded several thermal energy vibrational quenching rate constants for O2+(v). Rates for quenching of O2+(v = 1) by O2, N2, Ar, CO2, H2, and CH4 are 3(?10), 2(?12), 1(?12), 1(?10), 2.5(?12), and 6(?10) cm3s?1 at 300 K. The quenching is somewhat faster for O2+(v = 2). The triatomic ions CO2+, NO2+, N2O+, SO2+, and H2O+ are all vibrationally deexcited with an efficiency greater than 10?3 in Ar or Ne collisions. A theoretical rationalization of the experimental results leads to the prediction that vibrational quenching in planetary atmospheres will generally be efficient, k > 1(?12) cm3s?1 for almost all ion and neutral gas pairs. 相似文献
11.
A mechanism has been proposed for uv-accelerated desorption from Fe2+ sites on mineral surfaces that satisfies kinetic constraints determined in the laboratory by Huguenin. The process is an integral step of the photochemical weathering mechanism for producing dust on Mars, and it now appears that it may play primary roles in stabilizing CO2 against dissociation by sunlight and in controlling the oxidation state of the atmosphere. We propose that adsorption occurs at octahedrally coordinated Fe2+ surface sites to form seven-coordinate transition-state complexes. These complexes acquire 16–18 kcal mole?1 of ligand field stabilization energy. During illumination (λ ≤ 0.35 μm), electrons are photoemitted from the surfaced Fe2+, temporarily oxidizing them to Fe3+. Fe3+ has no ligand field stabilization energy, and the complexes lose 16–18 kcal mole?1 of stabilization energy. This is a large fraction of the 19- to 28-kcal mole?1 activation energy for dissociating the complexes, and desorption should proceed spontaneously. The gases that were observed to undergo adsorption-photodesorption include O2, CO2, CO, H2O, N2, and Ar. Photodesorption can drive several catalytic reactions, one of which is the oxidation of CO to CO2. The rate of this reaction should be limited by the supply of CO and O2 to the surface to ～2 × 1012 cm?2 sec?1 (column photodissociation rate of CO2). By including this surface reaction in models of Martian atmospheric CO2 chemistry, CO2 can be stabilized against photodissociation with eddy diffusion coefficients of only 3 × 105?1 × 107 cm2 sec?1 below 40 km, raising to ～ 109 cm2 sec?1 at 140 km. Odd hydrogen is not needed to catalyze the oxidation of CO below 40 km, and odd hydrogen mixing ratios need only to be to depress ozone concentrations below the observed upper limit in equatorial regions. Another catalytic reaction that should be driven by photodesorption on Mars is . This is an important source of atmospheric O2, amounting to 7 × 1013?2 × 1017 O2 molecules cm?2 yr?1, and it could have a significant effect on atmospheric oxidation state. 相似文献
12.
Recent laboratory measurements of the deactivation rate constants for O(1S) have suggested that the dominant production mechanism for the green line in the nightglow is a two-step process. A similar mechanism involving energy transfer from an excited state of molecular oxygen is considered as a potential source of the OI (5577 Å) emission in the aurora. It is shown that the mechanism, , is consistent with auroral observations; the intermediate excited state has been tentatively identified as the O2(c1∑?u) state. For the proposed energy transfer mechanism to be the primary source of the auroral green line, the peak electron impact cross-section for O21 production must be approximately 2 × 10?17 cm2. 相似文献
13.
Vladimir A. Krasnopolsky 《Planetary and Space Science》2011,59(8):754-766
A scheme of excitation, quenching, and energy transfer processes in the oxygen nightglow on the Earth, Venus, and Mars has been developed based on the observed nightglow intensities and vertical profiles, measured reaction rate coefficients, and photochemical models of the nighttime atmospheres of the Venus and Mars. The scheme involves improved radiative lifetimes of some band systems, calculated yields of the seven electronic states of O2 in termolecular association, and rate coefficients of seven processes of electronic quenching of the Herzberg states of O2, which are evaluated by fitting to the nightglow observations. Electronic quenching of the vibrationally excited Herzberg states by O2 and N2 in the Earth's nightglow is a quarter of total collisional removal of the O2(A, A′) states and a dominant branch for the O2(c) state. The scheme supports the conclusion by Steadman and Thrush (1994) that the green line is excited by energy transfer from the O2(A3Σu+, v≥6) molecules, and the inferred rate coefficient of this transfer is 1.5×10−11 cm3 s−1. The O2 bands at 762 nm and 1.27 μm are excited directly, by quenching of the Herzberg states, and by energy transfer from the O2(5Πg) state. Quenching of the O2 band at 762 nm excites the band at 1.27 μm as well. Effective yield of the O2(a1Δg) state in termolecular association on Venus and Mars is ∼0.7. Quantitative assessments of all these processes have been made. A possible reaction of O2(c1Σu−)+CO is a very minor branch of recombination of CO2 on Venus and Mars. Night airglow on Mars is calculated for typical conditions of the nighttime atmosphere. The calculated vertical intensity of the O2 band at 1.27 μm is 13 kR, far below the recently reported detections. 相似文献
14.
The temperature dependence of the binary recombination coefficient, α2, for the reaction NO++NO2? → products has been obtained over the range 185–530 K. It is found that the corresponding mean cross section is described by the power law , and that α2 ? B · T?0.4. Data has also been obtained for two cluster ion recombination reactions which indicate that their recombination cross sections are only about 40% larger than for the parent ions at a given temperature, the cross sections for these reactions also apparently increasing with decreasing temperature. In the light of this data and by considering the most probable positive and negative ions existing at various altitudes up to 90km in the atmosphere, the most appropriate ionic recombination coefficients in various altitude ranges are deduced. Thus, between 30 and 90 km, where the recombination process is two-body, the coefficient varies over the narrow range 5–9 × 10?8 cm3s?1, while below 30 km the process is predominantly three-body with an effective two-body rate increasing rapidly to a maximum value ≈3 × 10?6 cm3s?1 in the troposphere, these deductions being based on published laboratory determinations of three-body recombination coefficients. 相似文献
15.
In March 1979, the spectrum of Venus was recorded in the far infrared from the G.P. Kuiper Airborne Observatory when the planet subtended a phase angle of 62°. The brightness temperature was observed to be 275°K near 110 cm?1, dropping to 230°K near 270 cm?1. Radiance calculations, using temperature and cloud structure formation from the Pioneer Venus mission and including gaseous absorption by the collision-induced dipole of CO2, yield results consistently brighter than the observations. Supplementing the spectral data, Pioneer Venus OIR data at similar phase angles provide the constraint that any additional infrared opacity must be contained in the upper cloud, H2SO4 to the Pioneer-measured upper cloud structure serves to reconcile the model spectrum and the observations, but cloud microphysics strongly indicates that such a high particle density haze is implausible. The atmospheric environment is reviewed with regard to the far infrared opacity and possible particle distribution modifications are discussed. We conclude that the most likely possibility for supplementing the far-infrared opacity is a population of large particles in the upper cloud with number densities less than 1 particle cm?3 which has remained undetected by in situ measurements. 相似文献
16.
The rates and altitudes for the dissociation of atmospheric constituents of Titan are calculated for solar UV, solar wind protons, interplanetary electrons, Saturn magnetospheric particles, and cosmic rays. The resulting integrated synthesis rates of organic products range from 102–103 g cm?2 over 4.5 × 109 years for high-energy particle sources to 1.3 × 104 g cm?2 for UV at , and to 5.0 × 105 g cm?2 if (acting primarily on C2H2, C2H4, and C4H2) is included. The production rate curves show no localized maxima corresponding to observed altitudes of Titan's hazes and clouds. For simple to moderately complex organic gases in the Titanian atmosphere, condensation occurs below the top of the main cloud deck at 2825 km. Such condensates comprise the principal cloud mass, with molecules of greater complexity condensing at higher altitudes. The scattering optical depths of the condensates of molecules produced in the Titanian mesosphere are as great as ～ 102/(particulate radius, μm) if column densities of condensed and gas phases are comparable. Visible condensation hazes of more complex organic compounds may occur at altitudes up to ～ 3060 km provided only that the abundance of organic products declines with molecular mass no faster than laboratory experiments indicate. Typical organics condensing at 2900 km have molecular masses = 100–150 Da. At current rates of production the integrated depth of precipitated organic liquids, ices, and tholins produced over 4.5 × 109 years ranges from a minimum ～ 100 m to kilometers if UV at is important. The organic nitrogen content of this layer is expected to be ～ 10?1?10?3 by mass. 相似文献
17.
Laboratory cross-section data on the excitation of the OII(2s 2p44P → 2s2 2p34S; λ834 Å) resonance transition and on the production of O+ and O2+ ions by electron impact on atomic oxygen are used to show that the ratio is nearly constant for incident electron energies > 50 eV. Under auroral conditions, the total electron-ion pair production rate from electron impact on O can be inferred from λ834 Å volume emission rate measurements using the result that . These findings, along with earlier work on the simultaneous ionization-excitation of the 1 Neg (0,0) band of N2+ and the 1 Neg (1, 0) band of O+2, allow the specific ionization rates for the principal atmospheric constituents (O+, O+2, N+2), for the multiply-ionized species (O2+, O2+2, N2+2), and for the dissociatively produced atomic ions to be inferred in aurora from remote satellite observations. 相似文献
18.
Measurements of the emission intensities of the 557.7 nm line and Herzberg bands and of O(3P) concentrations carried out on two coordinated rocket flights at South Uist during the night of 8/9 September 1975 are presented. An examination of the 557.7 nm emission and data on the basis of recent data on relevant rate coefficients has shown that the results can be interpreted on the basis of the Barth mechanism for the production of atoms but not the Chapman mechanism. Evidence is provided that the A3Σ+u state of O2 could be responsible for the production in the Barth mechanism. Values of the rate coefficients involved are deduced from a comparison of the 557.7 nm and Herzberg emission rates. 相似文献
19.
The calculated radiative lifetime of the metastable ion is 6.4 × 10?3s. Used in conjunction with the results of measurements by Erdman, Espy and Zipf this sets 1.3 × 10?18 cm2 as the upper limit to the cross section for the formation of in e - N2 collisions at 100eV which leaves the possibility that the process is responsible for the feature in auroras only just open. The cross section for the formation of in e — N collisions is large. However for this process to lead to the observed intensity of relative to the N:N2 abundance ratio would have to be as high as 1.6 × 10?2. 相似文献
20.
Kenneth Fox 《Icarus》1975,24(4):454-459
The basis for “quasipolar” absorption (QPA) by CH4 is the existence of a small electric dipole moment in its ground state. The integrated intensity αQPA at a temperature of 90K is calculated to be between 4.8 × 10?5 and 1.9 × 10?2 cm?2 atm?1. With an assumed mean pressure of 0.1 atm and a relative abundance of , it is estimated that the ratio of quasipolar to pressure-induced absorption (PIA) is 0.05 ? αQPA/αPIA ? 18 for the spectral range from 0 to 300 cm?1. This result suggests that quasipolar absorption may contribute to a weak, CH4-induced greenhouse in the atmosphere of Titan. 相似文献