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1.
Laboratory culturing experiments with living Globigerina bulloides indicate that Mg/Ca is primarily a function of seawater temperature and suggest that Mg/Ca of fossil specimens is an effective paleotemperature proxy. Using culturing results and a core-top Neogloboquadrina pachyderma calibration, we have estimated glacial–interglacial changes in sea surface temperature (SST) using planktonic Mg/Ca records from core RC11-120 in the Subantarctic Indian Ocean (43°S, 80°E) and core E11-2 in the Subantarctic Pacific Ocean (56°S, 115°W). Our results suggest that glacial SST was about 4°C cooler in the Subantarctic Indian Ocean and 2.5°C cooler in the Subantarctic Pacific. Comparison of SST and planktonic δ18O records indicates that changes in SST lead changes in δ18O by on average 1–3 kyr. The glacial–interglacial temperature change indicated by the Subantarctic Mg/Ca records suggests that temperature accounts for 40–60% of the foraminiferal δ18O change. We have used the Mg/Ca-based SST estimates and δ18O determinations to generate site-specific seawater δ18O records, which suggest that seawater δ18O was on average 1‰ more positive during glacial episodes compared with interglacial episodes.  相似文献   

2.
The meteorite ALH84001, a sample of the ancient martian crust, contains small quantities (1%) of strongly chemically zoned carbonate. High spatial resolution (10 μm) ion microprobe analyses show that the chemical zoning is strongly correlated with variations in oxygen isotope ratios. Early formed Ca,Fe-rich cores have δ18O 7‰ increasing to 22‰ SMOW in the more Mg-rich outer cores and magnesite rims. Isolated areas of ankerite appear to be isotopically lighter with δ18O 1‰. The large range in δ18O requires a significant range in either fluid isotopic composition, or temperature, or both, in the course of the deposition sequence. Our data are inconsistent with formation of the zoned carbonates by closed system Rayleigh fractionation. There is no unique interpretation of the oxygen data, but the recent observation of existence of Δ17O excesses in the carbonate appears to rule out models which involve high temperature isotopic exchange with silicate. Comparison with terrestrial analogues suggests that ALH84001 carbonates formed in a hydrothermal system with T<400°C, and which, at least in the early stages of formation, may have involved water with δ18O < 0‰ SMOW. The later stages of deposition probably occurred at temperatures below 150°C, a conclusion which does not preclude the co-existence of thermophilic bacteria; temperatures during earlier stages of deposition are less likely to have been hospitable to bacteria.  相似文献   

3.
High-precision 40Ar/39Ar ages for a series of proximal tuffs from the Toba super-volcano in Indonesia, and the Bishop Tuff and Lava Creek Tuff B in North America have been obtained. Core from Ocean Drilling Project Site 758 in the eastern equatorial Indian Ocean contains discrete tephra layers that we have geochemically correlated to the Young Toba Tuff (73.7 ± 0.3 ka), Middle Toba Tuff (502 ± 0.7 ka) and two eruptions (OTTA and OTTB) related to the Old Toba Tuff (792.4 ± 0.5 and 785.6 ± 0.7 ka, respectively) (40Ar/39Ar data reported as full external precision, 1 sigma). Within ODP 758 Termination IX is coincident with OTTB and hence this age tightly constrains the transition from Marine Isotope Stage 19–20 for the Indian Ocean. The core also preserves the location of the Australasian tektites, and the Matuyama-Brunhes boundary with Bayesian age-depth models used to determine the ages of these events, c. 786 and c. 784 ka, respectively. In North America, the Bishop Tuff (766.6 ± 0.4 ka) and Lava Creek Tuff B (627.0 ± 1.5 ka) have quantifiable stratigraphic relationships to the Matuyama-Brunhes boundary. Linear age-depth extrapolation, allowing for uncertainties associated with potential hiatuses in five different terrestrial sections, defines a geomagnetic reversal age of 789 ± 6 ka. Considering our data with respect to the previously published age data for the Matuyama-Brunhes boundary of Sagnotti et al. (2014), we suggest at the level of temporal resolution currently attainable using radioisotopic dating the last reversal of Earths geomagnetic field was isochronous. An overall Matuyama-Brunhes reversal age of 783.4 ± 0.6 ka is calculated, which allowing for inherent uncertainties in the astronomical dating approach, is indistinguishable from the LR04 stack age (780 ± 5 ka) for the geomagnetic boundary. Our high-precision age is 10 ± 2 ka older than the Matuyama-Brunhes boundary age of 773 ± 1 ka, as reported previously by Channell et al. (2010) for Atlantic Ocean records. As ODP 758 features in the LR04 marine stack, the high-precision 40Ar/39Ar ages determined here, as well as the Matuyama-Brunhes boundary age, can be used as temporally accurate and precise anchors for the Pleistocene time scale.  相似文献   

4.
Benthic foraminiferal magnesium/calcium ratios were determined on one hundred and forty core-top samples from the Atlantic Ocean, the Norwegian Sea, the Indian Ocean, the Arabian Sea and the Pacific Ocean, mostly at sites with bottom water temperatures below 5 °C. Mg/Ca ratios are consistently lower, by  0.2 mmol/mol, in samples cleaned using oxidative and reductive steps than using oxidative cleaning. Differences between Cibicidoides species have been identified: Mg/Ca of Cibicidoides robertsonianus > Cibicidoides kullenbergi > Cibicidoides wuellerstorfi. Comparison with bottom water temperatures support observations of lowered Mg/Ca of C. wuellerstorfi at temperature below  3 °C compared with values predicted by published calibrations and from other Cibicidoides species. Hydrographic data shows that carbonate ion saturation (Δ[CO32−]) decreases rapidly below this temperature. An empirical sensitivity of Δ[CO32−] on Mg/Ca has been established for C. wuellerstorfi of 0.0086 ± 0.0006 mmol/mol/μmol/kg. A novel application using modern temperatures and Last Glacial Maximum temperatures derived via pore fluid modelling supports a carbonate ion saturation state effect on Mg incorporation. This may significantly affect calculated δ18Oseawater obtained from foraminiferal δ18O and Mg/Ca temperature.  相似文献   

5.
The lack of temporal resolution and accurate chronology of Southern Ocean marine cores has hampered comparison of glacial millennial-scale oscillations between the Southern Ocean, Antarctic ice and other records from both hemispheres. In this study, glacial climate variability is investigated over the last 50 ka using a multi-proxy approach. A precise chrono-stratigraphy was developed on the high-sedimentation rate core MD94-103 (Indian Southern Ocean, 45°35′S 86°31′E, 3560 m water depth) by geomagnetic synchronization between the later core and NAPIS75, and 14C dates. High-resolution time-series of δ18O in planktonic foraminifera Globigerina bulloides and Neogloboquadrina pachyderma, and sea surface temperatures (SSTs) estimated from the alkenone UK′37 index and foraminifera assemblages have been generated. Temporal evolution of the two temperature proxy records is notably different during the last glacial period. While foraminifera data indicate a consistent cooling towards the last glacial maximum, anomalous warm glacial alkenone temperatures suggest a strong advection of warm “detrital” alkenones by surface waters of the Agulhas current. Superimposed to this general trend, during Heinrich events, foraminiferal SSTs point to warmer surface waters, while concurrent alkenone SSTs exhibit apparent coolings probably caused by enhanced local alkenone production. By analogy to modern observations, possible influence of ENSO-like conditions on the subantarctic Southern Ocean SSTs is discussed.  相似文献   

6.
The loess record in southern Tajikistan and correlation with Chinese loess   总被引：12，自引：0，他引：12  
In the present study, the Chashmanigar loess–soil sequence in southern Tajikistan is studied; this loess section has a paleomagnetic basal age of about 1.77 Myr. Magnetic susceptibility, color reflectance and grain size were systematically measured for closely spaced samples from the section. Paleosols consistently have a finer grain size distribution, higher magnetic susceptibility, redder color reflectance and lower dust sedimentation rate than loess horizons, suggesting a colder, drier and dustier environment during glacial periods than in interglacial periods. The grain size record was tuned to variations in obliquity and precession of the Earth’s orbit. The resulting magnetic susceptibility, grain size and color reflectance time series all show well-expressed astronomical periodicities during the Pleistocene. The mid-Pleistocene climate transition, characterized by a shift of dominant climatic periods from 41 kyr to 100 kyr at about 1.0–0.8 Myr, is clearly documented in these proxy records. Comparison of the Chashmanigar loess record with the Lingtai loess section in China and the ODP site 677 δ18O record shows that during the entire Pleistocene, the climate cycles recorded by the Central Asian loess can be well correlated to the Chinese loess and deep-sea oxygen isotope records. It is suggested that alternations of loess and soil horizons both in Central Asia and China could be basically forced by global ice volume variations, although different wind systems have controlled the Pleistocene loess transport and sedimentation in the two areas.  相似文献   

7.
New Hf isotope and trace element data on mid-ocean ridge basalts (MORB) from the Pacific Ocean basin are remarkably uniform (176Hf/177Hf≈0.28313–0.28326) and comparable to previously published data [Salters, Earth Planet. Sci. Lett. 141 (1996) 109–123; Patchett, Lithos 16 (1983) 47–51]. Atlantic MORB have 176Hf/177Hf ranging from 0.28302 to 0.28335 confirming the wide range originally identified by Patchett and Tatsumoto [Geophys. Res. Lett. 7 (1980) 1077–1080]. Indian MORB define an even wider range, from 0.28277 to 0.28337, but three exotic samples have very unradiogenic Hf isotope compositions. Their very low 176Hf/177Hf ratios, together with their trace element characteristics, require the presence of unusual plume-type material beneath the Indian ridge. All other Indian MORB have uniform Hf isotope compositions at about 0.2832, and define a small field displaced to the right of other MORB in Hf–Nd isotope space. The distinct nature of Indian MORB is best explained by the presence in Indian depleted mantle of old recycled oceanic crust and pelagic sediments. Sm/Hf ratios calculated from new high-precision rare earth element and Hf trace element data do not vary in MORB in the same way as in ocean island basalts (OIB): ratios are constant in OIB, but decrease with increasing Sm contents in MORB. The constancy of Sm/Hf in OIB is probably due to an overwhelming influence of residual garnet during melting. By contrast, the decrease of Sm/Hf in MORB is due to the effect of clinopyroxene in the residue of melting beneath ridges, an interpretation confirmed by quantitative modeling of melting. The relationship between Sm/Nd and Lu/Hf ratios in MORB does not require the presence of garnet in the residual mineralogy. The decoupling of Lu/Hf ratios and Hf isotope compositions – the so-called Hf paradox [Salters and Hart, EOS Trans. Am. Geophys. Union 70 (1989) 510] – can be explained by melting dominantly in the spinel field at shallow depths beneath mid-ocean ridges.  相似文献   

8.
DSDP Hole 504B is the deepest basement hole in the oceanic crust, penetrating through a 571.5 m pillow section, a 209 m lithologic transition zone, and 295 m into a sheeted dike complex. An oxygen isotopic profile through the upper crust at Site 504 is similar to that in many ophiolite complexes, where the extrusive section is enriched in18O relative to unaltered basalts, and the dike section is variably depleted and enriched. Basalts in the pillow section at Site 504 haveδ18O values generally ranging from +6.1 to +8.5‰ SMOW(mean= +7.0‰), although minor zeolite-rich samples range up to 12.7‰. Rocks depleted in18O appear abruptly at 624 m sub-basement in the lithologic transition from 100% pillows to 100% dikes, coinciding with the appearance of greenschist facies minerals in the rocks. Whole-rock values range to as low as +3.6‰, but the mean values for the lithologic transition zone and dike section are +5.8 and +5.4‰, respectively.

Oxygen and carbon isotopic data for secondary vein minerals combined with the whole rock data provide evidence for the former presence of two distinct circulation systems separated by a relatively sharp boundary at the top of the lithologic transition zone. The pillow section reacted with seawater at low temperatures (near 0°C up to a maximum of around 150°C) and relatively high water/rock mass ratios (10–100); water/rock ratios were greater and conditions were more oxidizing during submarine weathering of the uppermost 320 m than deeper in the pillow section. The transition zone and dikes were altered at much higher temperatures (up to about 350°C) and generally low water/rock mass ratios ( 1), and hydrothermal fluids probably contained mantle-derived CO2. Mixing of axial hydrothermal fluids upwelling through the dike section with cooler seawater circulating in the overlying pillow section resulted in a steep temperature gradient ( 2.5°C/m) across a 70 m interval at the top of the lithologic transition zone. Progressive reaction during axial hydrothermal metamorphism and later off-axis alteration led to the formation of albite- and Ca-zeolite-rich alteration halos around fractures. This enhanced the effects of cooling and18O enrichment of fluids, resulting in local increases inδ18O of rocks which had been previously depleted in18O during prior axial metamorphism.  相似文献   


9.
We provide two new determinations of the oxygen isotopic composition of seawater during the last glacial maximum (LGM). High-resolution oxygen isotopic measurements were made on interstitial waters from Ocean Drilling Program (ODP) Sites 1168 and 1170 in the southeast Indian Ocean sector of the Southern Ocean. We use a diffusion-advection numerical model to calculate the glacial-interglacial change in bottom-water δ18Osw from the pore water δ18O profiles; the first such determinations from this part of the oceans. Statistical analyses of the model runs indicate that Circumpolar Deep Water (CDW) δ18Osw changed by 1.0-1.1±0.15‰ since the last glacial maximum (LGM). Our results are consistent with a previous calculation from a South Atlantic Southern Ocean location (ODP Site 1093) also situated within CDW. The new values determined in this study, together with previous estimates, are converging on a global average Δδ18Osw of 1.0-1.1‰.Using the calculated bottom-water δ18Osw, we have extracted the temperature component from the benthic foraminiferal δ18O record at Sites 1168 and 1170. Since the LGM, bottom waters at these two sites warmed by 2.6 and 1.9°C, respectively. The absolute temperature estimates for the LGM (−0.5°C [Θ=−0.6°C] at Site 1168 and −0.2°C [Θ=−0.4°C] at Site 1170) are slightly warmer than those reported from previous studies using the same technique, but are consistent with more homogenous deep-ocean temperatures during the LGM relative to the modern.  相似文献   

10.
The tropical Indian Ocean circulation system includes the equatorial and near-equatorial circulations, the marginal sea circulation, and eddies. The dynamic processes of these circulation systems show significant multi-scale variability associated with the Indian Monsoon and the Indian Ocean dipole. This paper summarizes the research progress over recent years on the tropical Indian Ocean circulation system based on the large-scale hydrological observations and numerical simulations by the South China Sea Institute of Oceanology(SCSIO), Chinese Academy of Sciences. Results show that:(1) the wind-driven Kelvin and Rossby waves and eastern boundary-reflected Rossby waves regulate the formation and evolution of the Equatorial Undercurrent and the Equatorial Intermediate Current;(2) the equatorial wind-driven dynamics are the main factor controlling the inter-annual variability of the thermocline in the eastern Indian Ocean upwelling;(3) the equatorial waves transport large amounts of energy into the Bay of Bengal in forms of coastal Kelvin and reflected free Rossby waves. Several unresolved issues within the tropical Indian Ocean are discussed:(i) the potential effects of the momentum balance and the basin resonance on the variability of the equatorial circulation system, and(ii) the potential contribution of wind-driven dynamics to the life cycle of the eastern Indian Ocean upwelling. This paper also briefly introduces the international Indian Ocean investigation project of the SCSIO, which will advance the study of the multi-scale variability of the tropical Indian Ocean circulation system, and provide a theoretical and data basis to support marine environmental security for the countries around the Maritime Silk Road.  相似文献   

11.
An age model (Mark et al., 2017) for ODP 758 and the Matuyama-Brunhes boundary transition and Termination IX in the equatorial Indian Ocean is robust and accurate. No significant magnetic lock-in delay is evident at the depth of the Matuyama-Brunhes boundary and the study highlights that 40Ar/39Ar geochronology is critical for dissection of the Pleistocene at the highest levels of temporal precision and minimal model-dependence. Testing of leads and lags in global-scale climate response requires independently dated timescales to reveal the fine-detail recorded by the various climate archives.  相似文献   

12.
南印度洋副热带偶极模在ENSO事件中的作用   总被引：8，自引：0，他引：8       下载免费PDF全文
晏红明  李崇银  周文 《地球物理学报》2009,52(10):2436-2449
南印度洋副热带偶极模（Subtropical Dipole Pattern,SDP）是印度洋存在的另一种很明显的偶极型海温差异现象,在年际和年代际尺度上均有十分明显的表现.而目前有关印度洋海气相互作用的研究主要集中在赤道印度洋地区,针对南印度洋地区的工作还比较少,特别是有关南印度洋海温与ENSO（El NiDo-Southern Oscillation）事件关系的研究.本文初步探讨了年际尺度上南印度洋副热带偶极型海温变化差异与ENSO事件的关系,发现SDP与ENSO事件有密切的联系,SDP事件就像连接正负ENSO位相转换的一个中间环节,SDP事件前后期ENSO的位相刚好完全相反.进一步,本文通过分析SDP事件前后期海温、高低层风、低层辐合辐散、高空云量和辐射等的变化特征研究了南印度洋偶极型海温异常在ENSO事件中的作用,结果表明：SDP在ENSO事件中的作用不仅涉及海气相互作用的正负反馈过程,还与热带和副热带大气环流之间的相互作用有关,特别是与东南印度洋海温变化所引起的异常纬向风由赤道印度洋向赤道太平洋传播的过程等有十分直接的关系;同时,SDP对ENSO事件的影响在很大程度上还依赖于大尺度平均气流随季节的变换.  相似文献   

13.
通过对南海北部陆坡下部ODPl148站位沉积物中陆源矿物组分的含量、堆积速率、粒度、石英氧同位素及石英扫描电镜的分析,探讨南海沉积演化及其构造响应.结果显示,根据综合指标的变化特征可将南海海盆的沉积演化划分为5个阶段:扩张初期(34～28.5 Ma)、构造活动剧烈期(28.5～23 Ma)、构造活动减弱期(23～16....  相似文献   

14.
In a companion paper local transfer functions were estimated at Tecoman using earthquake and microtremor data. In this paper, the subsoil structure at this city is investigated using seismic refraction and cross-correlation of noise records as a case study. P- and S-wave refraction profiles were measured at five sites within the city. Standard analysis constrained only very shallow layers. The P-wave refraction deployment was also used to record ambient vibration. These data were processed using an extension of the SPAC (SPatial AutoCorrelation (Aki, 1957) [1]) method; cross-correlation is computed between station pairs and the results are inverted to obtain a phase velocity dispersion curve. Penetration depth was larger than that from the refraction experiments but the shear-wave velocity of the basement could not be determined. For this reason, additional microtremor measurements were made using broad band seismometers with a larger spacing between stations. The results allowed to constrain the shear-wave velocity of the basement. Site amplification computed for the final profiles compare well with observed ground motion amplification at Tecoman. The case of Tecoman illustrates that even a simple subsoil structure may require crossing data from different experiments to correctly constrain site effects.  相似文献   

15.
The Late Neogene witnessed various major paleoceanographic changes that culminated in intense Northern Hemisphere Glaciation (NHG). The cause and effects of these changes are still debated. We use a multiproxy approach to determine the relative timing of the closure of the Panama gateway, changes in Atlantic circulation, global cooling and ice sheet growth. Benthic foraminiferal Mg/Ca records from a Pacific and an Atlantic Site have been produced and are interpreted in terms of bottom water temperatures. These Mg-temperature records are combined with published benthic δ13C, δ18O and erosion records to reconstruct the flow of proto-North Atlantic Deep Water (proto-NADW) over the past 12 Ma. The results suggest that between 12.5 and 10.5 Ma, and again between about 8.5 and 6 Ma, a nutrient-depleted water mass that was colder (by 1–2°C) and fresher than the intervening deep water mass filled the Atlantic basin. This proto-NADW became warmer (by 1°C) and saltier between 6 and 5 Ma, coincident with the restriction of surface water flow through the Central American Seaway. The Mg-temperature records define a subsequent global cooling trend of 3.5°C between 5 Ma and today. Early NHG in the late Miocene was perhaps related to the formation of the relatively cold, fresh proto-NADW. The formation of the warmer and saltier proto-NADW in the early Pliocene may have initially limited Northern Hemisphere ice growth. However, the increased moisture released at high northern latitudes associated with formation of ‘warm’ proto-NADW, coupled with the global temperature decrease of deep (and hence polar surface) waters, likely helped initiate the intense NHG of the Plio–Pleistocene.  相似文献   

16.
Osmotically pumped fluid samplers were deployed in four deep-sea boreholes that were drilled during Ocean Drilling Program (ODP) Leg 168 on the eastern flank of the Juan de Fuca Ridge. Samplers were recovered from ODP Sites 1024 and 1027 and aliquots were analyzed for a variety of dissolved ions. Results from both of the samplers show a drastic change in the major ion composition within the first 20-40 days after the borehole was sealed at the seafloor followed by a more gradual change in composition. This gradual change ceased after 820 days at Site 1024 but continued throughout the 3-year deployment at Site 1027. We modeled this change in composition to estimate the flux of formation fluid through the open borehole. The rapid early change requires a flow of ∼1500 kg of formation fluid per day. The more gradual later change requires flow rates of 38 kg/day at Site 1024 and 17.5 kg/day at Site 1027. The latter fluxes require a minimum average specific discharge of meters to hundreds of meters per year through the surrounding basaltic matrix. Trace element data show surprisingly little contamination given the presence of steel casing, Li-organic-rich grease at each joint, cement, and drilling muds. Observed changes in trace element concentrations relative to those of bottom seawater provide a measure for the global significance of cool (23°C; ODP Site 1024) ridge flank hydrothermal systems relative to warm (64°C; Baby Bare and ODP Site 1027) hydrothermal systems and illustrate the importance of these cooler systems to global geochemical budgets.  相似文献   

17.
Tetsuji  Onoue  Hiroyoshi  Sano 《Island Arc》2007,16(1):173-190
Abstract   The Sambosan accretionary complex of southwest Japan was formed during the uppermost Jurassic to lowermost Cretaceous and consists of basaltic rocks, carbonates and siliceous rocks. The Sambosan oceanic rocks were grouped into four stratigraphic successions: (i) Middle Upper Triassic basaltic rock; (ii) Upper Triassic shallow-water limestone; (iii) limestone breccia; and (iv) Middle Middle Triassic to lower Upper Jurassic siliceous rock successions. The basaltic rocks have a geochemical affinity with oceanic island basalt of a normal hotspot origin. The shallow-water limestone, limestone breccia, and siliceous rock successions are interpreted to be sediments on the seamount-top, upper seamount-flank and surrounding ocean floor, respectively. Deposition of the radiolarian chert of the siliceous rock succession took place on the ocean floor in Late Anisian and continued until Middle Jurassic. Oceanic island basalt was erupted to form a seamount by an intraplate volcanism in Late Carnian. Late Triassic shallow-water carbonate sedimentation occurred at the top of this seamount. Accumulation of the radiolarian chert was temporally replaced by Late Carnian to Early Norian deep-water pelagic carbonate sedimentation. Biotic association and lithologic properties of the pelagic carbonates suggest that an enormous production and accumulation of calcareous planktonic biotas occurred in an open-ocean realm of the Panthalassa Ocean in Late Carnian through Early Norian. Upper Norian ribbon chert of the siliceous rock succession contains thin beds of limestone breccia displaced from the shallow-water buildup resting upon the seamount. The shallow-water limestone and siliceous rock successions are nearly coeval with one another and are laterally linked by displaced carbonates in the siliceous rock succession.  相似文献   

18.
Groundwater flow-paths through shallow-perch and deep-regional basaltic aquifers at the Golan Heights, Israel, are reconstructed by using groundwater chemical and isotopic compositions. Groundwater chemical composition, which changes gradually along flow-paths due to mineral dissolution and water–rock interaction, is used to distinguish between shallow-perched and deep-regional aquifers. Groundwater replenishment areas of several springs are identified based on the regional depletion in rainwater δ18O values as a function of elevation (−0.25‰ per 100 m). Tritium concentrations assist in distinguishing between pre-bomb and post-bomb recharged rainwater.

It was found that waters emerging through the larger springs are lower in δ18O than surrounding meteoric water and poor in tritium; thus, they are inferred to originate in high-elevation regions up to 20 km away from their discharge points and at least several decades ago. These results verify the numerically simulated groundwater flow field proposed in a previous study, which considered the geological configuration, water mass balance and hydraulic head spatial distribution.  相似文献   


19.
The response of a climate proxy against measured temperature, rainfall and atmospheric circulation patterns at sub-annual resolution is the ultimate test of proxy fidelity but very few data exist showing the level of correspondence between speleothem climate proxies and the instrumental climate record. Cave sites on the Gibraltar peninsula provide a unique opportunity to calibrate speleothem climate proxies with the longest known available precipitation isotopes and instrumental records. An actively growing speleothem sampled from New St. Michaels Cave in 2004 is composed of paired laminae consisting of light columnar calcite and a darker microsparitic calcite. Stable isotope analysis of samples micromilled in 100 μm steps at the equivalent of bi-monthly intervals reveals fabric-correlated annual cycles in carbon isotopes, oxygen isotopes and trace elements responding to seasonal changes in cave microclimate, hydrology and ventilation patterns. Calcite δ13C values reach a minimum in the light columnar fabric and evidence from trace element behaviour and cave monitoring indicates that this grows under cave ‘winter’ conditions of highest pCO2, whereas the dark microsparitic calcite, characterised by elevated δ13C and δ18O values grows under low ‘summer’ pCO2 conditions. Drip water δ13CDIC reaches a minimum in March–April, at which time the attenuated δ18O signal becomes most representative of winter precipitation. An age model based on cycle counting and the position of the 14C bomb carbon spike yields a precisely dated winter oxygen isotope proxy of cave seepage water for comparison with the GNIP and instrumental climate record for Gibraltar. The δ18O characteristics of calcite deposited from drip water representing winter precipitation for each year can be derived from the seasonally resolved record and allows reconstruction of the δ18O drip water representing winter precipitation for each year from 1951–2004. These data show an encouraging level of correspondence (r2 = 0.47) with the δ18O of rainfall falling each year between October and March and on a decadal scale the δ18O of reconstructed winter drip water mirrors secular change in mean winter temperatures.  相似文献   

20.
海洋含水合物沉积层的速度频散与衰减特征分析   总被引：3，自引：1，他引：2       下载免费PDF全文
随着水合物含量的增加,往往会引起纵、横波速度的增加,同时也会引起衰减的变化.针对含水合物沉积层的速度频散与衰减特征分析,有助于水合物含量的估计.本文以有效介质理论模型(EMT)为基础,研究了海洋未固结含水合物沉积层的纵、横波速度的非线性变化趋势.同时采用BISQ模型替代有效介质模型中的Gassmann方程,具体分析了全频带范围内海洋含水合物沉积层的速度频散与衰减特征.采用该模型,速度与衰减均随着水合物含量的增加而增加,且岩石孔隙度与泥质含量对衰减系数的影响较小.针对大洋钻探计划(ODP)164航次的实际数据,运用该模型方程计算采用声波测井数据(20kHz)与VSP数据(100Hz),分别获取了水合物稳定带的饱和度数据,平均在5%~7%之间,由于速度频散的影响,VSP估算结果要弱低于声波测井估算数据,均与实测保压取芯的甲烷含量数据、他人研究成果以及神经网络趋势预测结果均有着较好的一致性.对南海神狐海域三口钻位开展了水合物含量预测,与保压取芯结果有着较好的吻合关系.同时基于层剥离法提取该区域某地震测线BSR层的等效Q值,采用本文方法估算了该区域的等效天然气水合物含量15%~30%.数值模拟与实际应用结果表明:含水合物沉积层的速度频散与衰减特征均随着水合物含量的变化而变化,联合利用这一些变化特征,有助于天然气水合物含量的估计.  相似文献   

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