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1.
The age of formation of the Lapstone Monocline has been long considered to be late Pliocene/early Pleistocene (the Kosciusko Uplift) but it is now generally thought to be much older. Palaeomagnetic data from haematite‐rich beds within the Hawkesbury Sandstone on and about the monocline indicate that it formed before the oldest haematite was introduced to these beds. The age of this oldest haematite is 15 ± 7 Ma. On the basis of these data, the age of the monocline is unlikely to be less than 8 Ma, probably exceeds 15 Ma, and could be older than 22 Ma.  相似文献   

2.
Sedimentary haematite ores of central Sweden give evidence of the existence of an oxidizing atmosphere about 2000 × 106 years ago. This is not consistent with Rankama's conclusions from the unoxidized condition of a diorite conglomerate in Finland. Therefore a (later) Pre-Cambrian conglomerate in northern Sweden has been examined for comparison. Where it is made up of dioritic material no proofs of oxidation can be found, but where the material is mainly iron-ore pebbles, magnetite ore is found to have been completely oxidized to haematite (martite) before being embedded as pebbles in the conglomerate.  相似文献   

3.
在磨矿中加入助磨剂是有效提高磨矿效率的一个重要途径,但在我国的研究还很少。对吉林某金矿的磨矿进行了助磨剂的试验研究,试验表明:在选定的条件下,选用二氧化锰、乙醇作为助磨剂可以使磨矿时间由120min缩短到90min左右,磨矿效率提高20%左右,而且环境污染小。本试验对其它矿山的磨矿作业也有很大的参考价值。  相似文献   

4.
Attempts at improving comminution machines generally have been directed towards increasing the performance efficiency, particularly increasing throughput rate and decreasing energy consumption. The latest and most successful new comminution technology has been the high-pressure grinding rolls (HPGR), which have proved to be highly efficient in energy consumption and to have a relatively high throughput rate at low steel consumption. Already used extensively in cement plants worldwide, the first HPGRs in the mineral industry were installed in plants processing diamond ores. They are now finding their way into the large-scale base-metal mining industry. Since feed constituents in natural ores vary in their physical properties such as hardness, plasticity and brittleness, the present paper is concerned with an investigation of the behavior of a heterogeneous feed as it passes through the HPGR. The effect of feed composition on operational parameters, the energy efficiency of comminution, and energy distribution among the feed components is addressed. Mineral particles with high hardness act as energy transfer agents in the roll gap and enhance the grinding of softer mineral particles in a mixed feed.  相似文献   

5.
In both nature and synthetic experiments, the common iron oxide haematite (α‐Fe2O3) can incorporate significant amounts of U into its crystal structure and retain radiogenic Pb over geological time. Haematite is a ubiquitous component of many ore deposit types and, therefore, represents a valuable hydrothermal mineral geochronometer, allowing direct constraints to be placed on the timing of ore formation and upgrading. However, to date, no suitable natural haematite reference material has been identified. Here, a synthetic haematite U‐Pb reference material (MR‐HFO) is characterised using LA‐ICP‐MS and ID‐TIMS. Centimetre‐scale ‘chips’ of synthesised α‐Fe2O3 were randomly microsampled via laser ablation‐extraction and analysed using ID‐TIMS. Reproducible U/Pb and Pb/Pb measurements were obtained across four separate chips (n = 13). Subsequently, an evaluation of the suitability MR‐HFO in constraining U‐Pb data via LA‐ICP‐MS is presented using a selection of natural samples ranging from Cenozoic to Proterozoic in age. The MR‐HFO normalised U‐Pb ratios are more concordant and ages more accurate versus the same LA‐ICP‐MS spot analyses normalised to zircon reference material, when compared with independently acquired ID‐TIMS data from the same natural haematite grains. Results establish MR‐HFO as a suitable reference material for LA‐ICP‐MS haematite U‐Pb geochronology.  相似文献   

6.
Authigenic iron and titanium oxides occur in three main textural varieties in the St. Bees Sandstone, a Triassic red bed succession in Cumbria. These are: (a) overgrowths of haematite, titaniferous haematite, anatase, and rutile which generally occur on detrital host grains of similar compositions. The overgrowths may occur as syntaxial rim cements or rhombohedral and prismatic projections and are always in optical continuity, (b) discrete crystals of anatase (including octahedrite) and haematite 10-40 μm in size occur in pore spaces, and (c) fine grained ( < 1 μm) pigmentary haematite occurs as grain coatings around detrital grains and in the interstitial matrix. The euhedral nature and pore-filling habit clearly indicate the authigenic origin of these iron- and titanium oxides. All three textural varieties are believed to have been precipitated from ground waters containing dissolved ferrous and titanium ions. These ions were derived from the intrastratal solution of detrital iron and titanium bearing grains including ferromagnesian silicates and iron-titanium oxides. The precipitation of iron oxides from migrating ground waters in the manner described here goes some way to explaining how thick, uniformly red successions can be formed.  相似文献   

7.
Authigenic iron and titanium oxides occur in three main textural varieties in the St. Bees Sandstone, a Triassic red bed succession in Cumbria. These are: (a) overgrowths of haematite, titaniferous haematite, anatase, and rutile which generally occur on detrital host grains of similar compositions. The overgrowths may occur as syntaxial rim cements or rhombohedral and prismatic projections and are always in optical continuity, (b) discrete crystals of anatase (including octahedrite) and haematite 10-40 μm in size occur in pore spaces, and (c) fine grained ( < 1 μm) pigmentary haematite occurs as grain coatings around detrital grains and in the interstitial matrix. The euhedral nature and pore-filling habit clearly indicate the authigenic origin of these iron- and titanium oxides. All three textural varieties are believed to have been precipitated from ground waters containing dissolved ferrous and titanium ions. These ions were derived from the intrastratal solution of detrital iron and titanium bearing grains including ferromagnesian silicates and iron-titanium oxides. The precipitation of iron oxides from migrating ground waters in the manner described here goes some way to explaining how thick, uniformly red successions can be formed.  相似文献   

8.
S. Malomo 《Chemical Geology》1987,60(1-4):101-109
The mineralogy and chemical composition of different laterite samples from Paraíba (NE Brazil) have been studied in order to improve our understanding of the laterite forming process. Determinations on size-fractionated samples of concretions and fines show that kaolinite (b-axis disordered form), haematite, goethite and quartz are the dominating minerals.

Laterisation process leads to the propagation of small-sized fractions (fines) into larger-sized ones (concretions). The propagation only involves the cementation of quartz and clay minerals by goethite and/or haematite and no segregation of alumina is involved. The larger sizes of the fines are similar in composition to the concretions, of which they are small-scale expressions.  相似文献   


9.
A new occurrence of (syenite-hosted) Vanadium bearing titaniferous magnetite ore body has been reported from Ganjang (26°09′35″ N: 93°20′ E), Karbi-Anglong, Northeastern India. The magnetite ore bodies have lumpy and sporadic occurrences within the host syenite pluton intrusive into gneissic country rocks. Ore microscopic studies reveal that magnetite is often associated with haematite and ilmenite depicting different textural patterns. Critical consideration of several elemental patterns suggests magmatic differentiation to be main ore-forming process. The ore body is suggested to have been formed as late stage segregation from a differentiating alkaline magma in a fluid enriched milieu.  相似文献   

10.
Grinding mills are commonly used in the Florida phosphate industry to reduce particle size. The corrosion of metallic grinding media and mill liner is a very serious problem, particularly under acidic conditions as encountered in the Florida phosphate fertilizer industry. A statistical Box–Behnken Design (BBD) of experiments was performed to evaluate the effects of individual operating variables and their interactions on the wear rate of high chromium alloy during phosphate grinding. The variables examined in this study included grinding time, solution pH, rotation speed, mill crop load, and solids percentage. The wear tests were conducted using a specially designed grinding mill whose electrochemical potential can be controlled. The most significant variables and optimum conditions were identified from statistical analysis of the experimental results using response surface methodology (RSM). It has been shown that solution pH had the most significant effect on the wear rate. The optimum process parameters for minimum wear rate were solution pH at 8.7, rotation speed at 61 rpm, solid percentage at 65% and crop load at 58%.  相似文献   

11.
This study deals with the effect of mechanical treatment, using vibrating mill, on the mineralogy and structure of apatite and associated gangue minerals (dolomite, calcite, quartz, pyrite and gypsum) in Abu-Tartour phosphate ore, Egypt. The evolution of mineralogy, crystallinity and deformation mechanism were evaluated with different techniques (XRD, DTA, TGA and FT-IR). Data obtained using these techniques give a good picture about the mechanochemical behavior of the different components in the ore. X-ray diffraction (XRD) indicated that the mineralogy has been changed quantitatively at short time grinding (30 min). After 45 min of grinding, the sample contained mainly carbonate apatite, quartz and pyrite. On the other hand, dolomite mineral disappeared, while calcite was partially transformed into aragonite. This transformation increased with increasing grinding time. Both Fourier Transform Infrared (FT-IR) and differential thermal analysis (DTA) analyses revealed that remarkable changes in the structural groups have occurred after 45 min of grinding. After 75 min of grinding, the carbonate in the apatite mineral partially decomposed and tricalcium phosphate formed instead. The formation of that simple form (tricalcium phosphate) may be another reason, besides surface area, for increasing the reactivity of phosphate ore by grinding. Scanning electron micrographs (SEM) revealed some idea about the grinding mechanisms of Abu-Tartour phosphate using vibrating mill. They indicate that the different minerals are ground differently. The apatite minerals are ground mostly by abrasion mechanism, while the carbonate minerals are ground mostly by compression. Also, these minerals are ground with different rates, where dolomite is ground faster than calcite, which are referred to the crystal lattice.  相似文献   

12.
A palaeomagnetic study of the Helmsdale granite (U/Pb-420 m.y., K/Ar-400 m.y.), northeast Scotland, has revealed a multicomponent remanence dominated by two characteristic axes of magnetization. The suggested oldest of these magnetizations, the direction of which is nearly horizontal and directed N-S, is thought to have been acquired in Upper Silurian-Lower Devonian times. The existence of this shallow direction of magnetization discounts a recent hypothesis of a ca. 2000 km sinistral offset along the Great Glen Fault. The second component of magnetization appears to be partly carried by haematite that apparently formed through disintegration of biotite and/or plagioclase. This secondary magnetization has a direction that can be associated with a Permian-early Mesozoic age. Similar overprinted magnetizations are characteristic features also in the Devonian sedimentary sequences north of Helmsdale.  相似文献   

13.
The effect of PSS (Sodium Polystyrene Sulphonate) and NSF (Naphthalene Sulphonate Formaldehyde Condensate) chemicals used to control the pulp rheology on the grindability of coals was studied. Zonguldak region bituminous coal and Istanbul region brown coal samples that high and low rank were used. Wet grinding tests with two coal samples were performed with or without PSS and NSF under constant grinding conditions: solid ratios ranged from 50% to 60% with 0–60 min grinding periods.In the present study, grinding conditions of coal with high pulp solid ratio were improved through the lowering of the viscosity of the coal by using the dispersing agents, PSS and NSF, during the grinding stage and evaluation were made by using the “efficiency factor”. It is possible to increase the amount of finely ground bituminous coal from Zonguldak by 20% and 16%, if optimum concentrations of PSS (0.3%) and NSF (0.7%) are used, respectively. Whereas, the increase in the case of finely ground lignite from Istanbul was 32% and 20%, respectively.  相似文献   

14.
Summary   Comminution (crushing and grinding) of rock materials is energy-intensive and expensive. Much effort has been directed to improve the efficiency of conventional milling practice, but relatively little attention has been given to the potential benefits of blast-induced (extrinsic) damage on comminution processes. The objective of this research is to investigate the effect of shock-induced “crack-like” damage on rock properties for three petrologically distinct rock materials under laboratory conditions. In order to evaluate the effect of shock-induced damage, a quantitative measure of rock damage is needed. Shock loading of rock material was accomplished with an explosively driven split Hopkinson pressure bar. Laboratory measurements show that the average uniaxial compressive strengths for damaged specimens are slightly lower than those for intact specimens. Based on damage mechanics, the scalar damage variable () was experimentally determined as the relative reduction in ultrasonic wave velocity of damaged versus intact rock. increases as the shock energy dissipated in rock material increases. A crack density was determined by confocal image analysis. Measurements following shock loading indicate that ultrasonic wave velocity in rock partially recovers with time. Ultrasonic wave velocity and confocal image analysis may be useful in quantitatively assessing the internal crack-like damage in rock materials.  相似文献   

15.
B. D. EVAMY 《Sedimentology》1963,2(2):164-170
A staining technique is described which detects variations in ferrous iron content within calcite and dolomite, whilst simultaneously differentiating the dolomite from the calcite. The application of this technique to a study of dedolomitisation is pre- sented.
Ferroan dolomite, in certain pyrite bearing limestones of the southern Jura, is shown to have been dedolomitised, that is replaced by calcite, while at the same time the pyrite content of the rock was oxidised to haematite. One of the oxidation products of the pyrite is considered to have caused the dedolomitisation.  相似文献   

16.
滑石的颗粒粒径、形貌、晶型等对其应用的实效性、终端产品的性能产生极大影响,目前主要研究其表面改性,而有关微观形貌及晶体结构研究较少。本文利用X射线荧光光谱、X射线衍射分析、红外光谱、粒度分析仪结合高分辨场发射扫描电镜(FE-SEM)技术对辽宁滑石粉在高强度机械力研磨作用下的微形貌和晶体结构变化特征进行系统研究。结果表明滑石粉原矿混合物中MgO与SiO2的分子个数比约为0.45,该数值明显低于纯滑石粉晶体中MgO与SiO2的分子个数比0.75。此类滑石为典型的单斜晶系,研磨作用使滑石粉由晶态转变为非晶态结构,其层状结构的有序化和键合作用发生了明显的变化。滑石粒度随研磨时间变化呈现减小-增大-减小的循环过程。研磨后粉体形貌存在差异,细化的小颗粒粉体因团聚而呈"准球体",且随着研磨的进行出现细化-团聚-细化的反复过程。此结论对于滑石的深加工与应用及其相关矿物粉体的研究具有一定的参考价值。  相似文献   

17.
为了探究不同温度下PDC切削齿性能,以适应不同的钎焊温度,并合理选用外形来提高效率,从影响金刚石复合片(PDC)质量的主要参数:耐磨性、磨削时间、平稳性、抗冲击韧性等出发,对不同厂家、不同外形的PDC在受热前后的性能进行试验,同时比较了平面片、微弧片和弧面片性能上的差异。结果表明:随着温度的升高,磨耗比呈现出降低的趋势;加热到750℃后,PDC磨耗比降低约30%~50%,磨削时间增加,进尺变慢;当温度达到800℃时,磨耗比小于10万,冲击功小于100 J;PDC切削齿对温度的敏感度不同,可根据不同温度下的性能对其分级,以满足不同的钎焊温度的焊接;对于不同外形的PDC,平面片磨削时间短,磨削效率高,而微弧片和弧面片磨耗比略低,磨削时间长,但冲击韧性大大提高。因此,在制造PDC钻头的过程中合理选择PDC形状,并将不同性能的PDC用于钻头的不同部位,能够有效提高PDC钻头的寿命。   相似文献   

18.
A new type of gold mineralisation containing minor amounts of platinum and palladium has been found proximal to the secondary redox interface located below the Cu-Ag Kupferschiefer orebody of the Polkowice-Sieroszowice mine in the south-western part of the Lubin-Sieroszowice district, Poland. This deposit can be classified as redbed-type gold. Our study shows that gold, platinum and palladium occur in secondary red-coloured sections of the basal Zechstein sedimentary rocks and in the uppermost Weissliegendes sandstone. Noble metal mineralisation occurs within an average interval of 0.22 m, which lies directly below the copper ores. The average grade of the horizon is 2.25 ppm Au, 0.138 ppm Pt and 0.082 ppm Pd with a metal content of several tens of tonnes of gold. A transition zone has been recognised between the gold-bearing horizon and the copper deposit. This transition zone is characterised by the presence of low grades of copper (<0.2 wt%) and elevated gold contents (>0.5 ppm). Native gold accompanied by electrum, mercury-bearing gold, haematite, covellite, chalcocite, bornite and chalcopyrite has been identified in the gold-bearing horizon. In some sections, Pd-arsenides, tetra-auricupride, Co-arsenides, clausthalite, tennantite, digenite, yarrowite, spionkopite and galena have also been noted.  相似文献   

19.
Incidence of high fluoride (F?) in groundwater (>1.5 mg/L) in two tribal belts of eastern India, one around Chukru in the Palamau district of Jharkhand and the other around Karlakot in the Nuapada district of Odisha, has been studied. The maximum concentration of F? in groundwater from dug wells and tube wells is 10.30 mg/L in Chukru and 4.62 mg/L in Karlakot. The groundwaters are mildly alkaline with pH ranges of 7.52–8.22 and 7.33–8.20 in Chukru and Karlakot, respectively. The F? concentration is positively correlated with pH, electrical conductivity and SO4 2? in both areas. The high F? in groundwater resulted mainly from dissolution of biotite and fluorapatite in quartzofeldspathic gneiss. The ionic dominance pattern (in meq/L) is mostly in the order Ca2+ > Na+ > Mg2+ > K+ among cations and HCO3 ? > SO4 2? > < Cl? > F? among anions in the Karlakot groundwater. Preliminary adsorption experiments were conducted on natural haematite iron ore and synthetic magnetite to evaluate their potential for F? removal from water. Effects of different parameters such as contact time, pH, adsorbent dose and initial F? concentration on the adsorption capacity of these materials were investigated. Strong dependence of F? removal on pH was observed for both the adsorbents. With natural haematite iron ore, the maximum F? removal of 66 % occurred at an initial pH of 3.2 for a solution with F? concentration of 3 mg/L, adsorbent dose of 7 g/L and overnight contact time. The haematite iron ore was observed to increase the pH of the F? solution. Adsorption equilibrium was not achieved with this adsorbent even after a contact time of 45.2 h. In the case of synthetic magnetite, 84 % F? removal was achieved after 2 min of contact time for a solution with F? concentration of 6 mg/L, adsorbent dose of 10 g/L and initial pH of 7. The results indicate high potential of both natural haematite iron ore and synthetic magnetite as adsorbents of F? in water.  相似文献   

20.
The main objective of this experimental study was to investigate the evolution of the mineral liberation characteristics of an ore undergoing grinding. Six samples of an iron ore containing hematite, magnetite and quartz have been tested. Mineral grade and liberation measurements have been performed with an image analyser on polished sections of particles from several discrete size intervals.For each product, the grade in iron oxides was increasing greatly with the fineness of the particles. Moreover, in each size interval down to 270 mesh, it was slightly decreasing as grinding proceeded. These behaviors are due to the fact that iron oxides were ground more easily than the siliceous gangue. The degree of liberation of the valuable minerals was evidently increasing with the particle fineness. Moreover, for each size interval coarser than 48 mesh, it has also shown a slight decrease with grinding. For finer sizes however, it appeared in practice invariant and independent of the grade or of the degree of grinding. These observations are of interest when considering that the grinding products tested were very different in fineness while corresponding to various modes of fragmentation.(jaw crushing, roll crushing and ball milling) and to an ore with a high tendency to break along the mineral grain boundaries.  相似文献   

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