共查询到20条相似文献，搜索用时 46 毫秒
1.
B.L. Sidwell L.E. McKinney M.F. Bozeman P.C. Egbujor G.R. Eaton S.S. Eaton D.A. Netzel 《Geochimica et cosmochimica acta》1979,43(8):1337-1342
Electron paramagnetic resonance (EPR) reveals the presence of free radicals in raw shale, shale oil, and spent shale. Thirty-four samples of raw shale, and the spent shale and shale oil produced in the Fischer assay of these raw shale samples were studied. There is a significant correlation between the gallons per ton oil yield as estimated by Fischer assay and the spin density in the raw oil shale. However, the scatter in the data (due to uncertainties in sample preparation, Fischer assay results, and estimation of spins per gram of sample) limits the analytical utility of this finding. Sample preparation techniques affect the EPR signal. 相似文献
2.
Oil was first discovered in the Masila area of Yemen in the late 1990s, with about 90% of the reserves found in the Lower Qishn Clastic Member of the Qishn Formation. The porosity determinations of the Lower Qishn Clastic are relatively high and the permeability ranges from 103 to 374?md. This paper tries to evaluate the hydrocarbons in the porous zones encountered in the Lower Cretaceous formations, which were penetrated by the eight wells in the study area. The water saturation shows low values, while the hydrocarbon saturation is in a reverse relation, i.e., the hydrocarbon increases where the water saturation decreases. Different cross-plots such as Rho-PHIN, Rho-DTN, and M-N were used in lithological identification for the two studied formations (Saar and Qishn) in the studied wells. Formation evaluation and presentation forms of the obtained petrophysical parameters have frequently proven that the formations have high hydrocarbon saturation in this area and contain many pay zones. On of the main targets of this paper is to build a detailed 3D geological modeling of the Lower Cretaceous Sequence conducted through an integrated study. 相似文献
3.
The free, adsorbed and inclusion oils were recovered by sequential extraction from eleven oil and tar containing reservoir rocks in the Tazhong Uplift of Tarim Basin. The results of gas chromatography (GC) and GC–mass spectrometry analyses of these oil components and seven crude oils collected from this region reveal multiple oil charges derived from different source rocks for these oil reservoirs. The initially charged oils show strong predominance of even over odd n-alkanes in the range n-C12 to n-C20 and have ordinary maturities, while the later charged oils do not exhibit any predominance of n-alkanes and have high maturities. The adsorbed and inclusion oils of the reservoir rocks generally have high relative concentrations of gammacerane and C28 steranes, similar to the Cambrian-Lower Ordovician source rocks. In contrast, the free oils of these reservoir rocks generally have low relative concentrations of gammacerane and C28 steranes, similar to the Middle-Upper Ordovician source rocks. There are two interpretations of this result: (1) the initially charged oils are derived from the Cambrian-Lower Ordovician source rocks while the later charged oils are derived from the Middle-Upper Ordovician source rocks; and (2) both the initially and later charged oils are mainly derived from the Cambrian-Lower Ordovician source rocks but the later charged oils are contaminated by the oil components from the Silurian tar sandstones and the Middle-Upper Ordovician source rocks. 相似文献
4.
5.
Gas chromatography, palynomorph constituents, and maturation are analyzed for oil samples of the Campanian Khasib and Tannuma Formations in the wells of East Baghdad oil field for biomarker studies, while palynomorph constituents and their maturation, Rock Eval pyrolysis, total organic carbon (TOC) analysis are carried on for the Upper Jurassic and the Cretaceous Formations of core samples from the same wells for dating and evaluation of the source rocks. The gas chromatography of these oils have shown biomarkers of abundant ranges of n-alkanes of less than C22(C17–C21) with C19 and C18 peaks to suggest mainly liquid oil constituents of paraffinic hydrocarbons from marine algal source of restricted palaeoenvironments in the reservoir as well as low nonaromatic $ {\hbox{C}}_{15}^{+} $ peaks to indicate their slight degradation and water washing. Oil biomarkers of $ \Pr ./{\hbox{Ph}}{.} = {0}{.85,}{{\hbox{C}}_{31}}/{{\hbox{C}}_{30}} < 1.0 $ , location is in the triangle of C27–C29 sterane, C28/C29 of 0.6 sterane, oleanane of 0.01, and CPI = 1.0, could indicate anoxic marine environment with carbonate deposition of Upper Jurassic–Early Cretaceous source. The recorded palynomorph constituents in this oil and associated water are four miospore, seven dinoflagellates, and one Tasmanite species that could confirm affinity to the Upper most Jurassic–Lower Cretaceous Chia Gara and Ratawi Formations. The recorded palynomorphs from the reservoir oil (Khasib and Tannuma Formations) are of light brown color of $ {\hbox{TAI}} = 2.8 - 3.0 $ and comparable to the mature palynomorphs that belong to Chia Gara and Lower part of Ratawi Formations. Chia Gara Formation had generated and expelled high quantity of oil hydrocarbons according their TOC weight percent of 0.5–8.5 with ${S_2} = 2.5 - 18.5\,{\hbox{mg}}\,{\hbox{Hc/g}}\;{\hbox{rock}} $ , high hydrogen index of the range 150–450 mg Hc/g Rock, good petroleum potential of 4.5–23.5 mg Hc/g rock, mature ( $ {\hbox{TAI}} = 2.8 - 3.0 $ and $ {\hbox{T}}\max = 428 - 443{\hbox{C}} $ ), kerogen type II, and palynofacies parameters of up to 100 amorphous organic matters with algae deposited in dysoxic–anoxic to suboxic–anoxic basin, while the palynomorphs of the rocks of Khasib Formation are of amber yellow color of TAI = 2.0 with low TOC and hence not generated hydrocarbons. But, this last formation could be considered as oil reservoir only according their high porosity (15–23%) and permeability (20–45 mD) carbonate rocks with structural anticline closure trending NW-SE. That oil have generated and expelled during two phases; the first is during Early Palaeogene that accumulated in traps of the Cretaceous structural deformation, while the second is during Late Neogene’s. 相似文献
6.
7.
以长春岭油田C107区块扶余油层为例,综合应用岩心、录井、动态及测试等资料,按层次分析的思路对曲流河储层进行了构型分析。在井上单河道砂体识别的基础上,采用相控对比方法进行了单河道砂体的井间对比。基于现代沉积,提出了"S"型、同向式、背向式和切割式4类点坝砂体的组合模式,结合点坝砂体厚度特征以及与其紧邻废弃河道分布特征,在研究区识别出8个点坝砂体,单个点坝砂体面积在0.02～0.16km2。综合录井、岩心和测井等资料,在单井侧积层识别的基础上,结合对子井分析法,计算出侧积层的倾角为5°左右,侧积体的宽度为25～70m,建立了点坝砂体内部构型定量模式。应用曲流河构型分析成果,指导了热采动态分析。 相似文献
8.
9.
吉林油区大老爷府油田低阻油层成因及测井解释 总被引：6，自引：0，他引：6
在国内外研究低阻油层的基础上，结合大老爷府油田的生产实际，认为形成大老爷府油田低阻油层的主要原因有五个方面，针对低阻油层的测井特征，提出综合利用测井多参数信息模糊综合评判的方法识别低阻油层。 相似文献
10.
一个典型的寒武系油藏:塔里木盆地塔中62井油藏成因分析 总被引：32，自引：4，他引：28
塔里木盆地志留系沥青砂岩广泛发育,主要原因是来源于寒武系的原油在进入志留系储层后区域性的抬升剥蚀使油藏遭到严重破坏,但到目前为止,究竟是寒武系烃源岩还是中上奥陶统烃源岩或是两者都对现今的志留系沥青砂岩中的有机质有贡献还不清楚.对塔中62井原油的化学组成和油源的分析表明,其甾萜类组成具有寒武系烃源岩的组成特征,反映该油藏原油主要来源于寒武系.另一方面,塔中62井砂岩透镜体被泥岩圈闭,油藏具有较好的保存条件,且后期中上奥陶统生成的烃类难以充注进入油藏.塔中62井志留系油藏破坏作用较弱、保存较好,是塔里木盆地在志留系发现的第一例来源于寒武系的油藏. 相似文献
11.
F. Afkhami A. R. Karbassi T. Nasrabadi A. Vosoogh 《Environmental Earth Sciences》2013,70(3):1219-1224
The Ahvaz oil field located in southern Iran has been identified as a possible point of elemental pollution, since elevated levels of metallic pollution (As, Cd, Cr, Ni, Cu, Zn, Pb and V) have been introduced to the adjacent environment through the oil excavation activities. The concentration of metals Cr, Ni, Cu, Pb and Zn are far below all reference values while that of As, Cd and V are remarkably above limits. Enrichment factor (EF) reports the mean waste status to be enriched by all three elements As, Cd and V while the Igeo values manifest the strongly polluted condition for Cd and moderately polluted for As and V. In order to quantify the association of metal concentrations with various Acid soluble, reducible, oxidizable and pseudo-total phases and consequently to estimate the potential mobility of existent metallic pollution, the sequential chemical partitioning technique was used for the samples collected from clean soil, drilling mud and wastage pit. According to the results achieved by chemical partitioning analysis, Cd seems to be mobile. Similar conditions exist for V with relatively lower risk level. Regarding As, the potential mobility is estimated to be low as a remarkable portion of bulk concentration (more than 70 %) is accumulated in the pseudo-total phase. Paying attention to the bulk and partitioning concentrations of three enriched elements in the drilling mud, it is concluded that the main cause of wastage pit contamination may be attributed to the nature of drilling mud utilized in excavation activities. Additionally, the geological texture in different depths may also play a role in this scenario. 相似文献
12.
David Grigg 《GeoJournal》2001,53(2):163-172
In the last thirty years there has been a growing interest in the use of olive oil in cooking because of greater knowledge of Mediterranean foods and an awareness of the healthy virtues of a Mediterranean diet, and particularly olive oil. In spite of this the consumption of olive oil is negligible outside the Mediterranean region, where most of the world's olive oil is produced and consumed, and which provides nearly all exports and receives a majority of the imports. This seems to be due to the very demanding climatic requirements of the olive tree and the fact that virtually all olive trees are grown in a Mediterranean-type climate. Although the olive tree was taken to areas with a similar climate during the European expansion after 1492, it has never become an important part of the diet in the Americas, in spite of the role of Mediterranean populations settling in the continent. The very high cost of olive oil compared with oilseeds has made its penetration of non-Mediterranean markets very difficult, and indeed the consumption of olive oil has declined in the face of such competition even in some of the Mediterranean countries. 相似文献
13.
Although tight oil has great resource potential, studies of oil charging mechanisms in tight reservoirs are relatively few. Researchers have found that a force balance exists during oil charging, but quantitative analyses of conditions critical for tight oil charging are sparse. This study developed a formula to identify effective source rocks using oil expulsion intensity as the discrimination parameter based on quantitative expression of hydrocarbon-generation overpressure and force-balance conditions. Using this formula, critical oil expulsion intensity under conditions at various burial depths can be obtained. This method was applied in the tight reservoirs of the Jimusar Sag, Junggar Basin, China. The calculated critical oil expulsion intensity range was between 122.61 × 104 t/km2 and 620.01 × 104 t/km2. The distribution range of effective oil source rocks and total expelled oil can be determined on the basis of critical oil expulsion intensity at different burial depths. This method provides a new approach to predict favourable tight oil-bearing regions. 相似文献
14.
川中地区公山庙油田侏罗系大安寨段致密油资源潜力分析 总被引：2，自引：1，他引：1
公山庙油田侏罗系大安寨段油层孔隙度大多小于2％,渗透率一般小于0.05×10-3μm2,属于典型的致密油层.该油层平面上大面积分布,存在明显的“甜点”区;剖面上非均质性强,顶部大一亚段和底部大三亚段的厚层介壳灰岩为主力产油层,中部大一三亚段的介壳灰岩与页岩薄互层为次要产油层.构造、介壳灰岩及暗色泥岩厚度对致密油富集没有明显的控制作用,“甜点”主要分布在公山庙构造西侧斜坡区.通过对公山庙油田大安寨段沉积演化、烃源岩生烃条件、储层特征及油气分布规律的研究,结合生产井数据,运用容积法和产量递减拟合法分别计算可采资源量,预测公山庙油田大安寨段致密油可采资源量分别为338.11万t和155.74万t. 相似文献
15.
16.
Dr. Ali A. Al-Shamlan M. I. Ali El-Sayed Muayyad H. Khaiwka 《International Journal of Earth Sciences》1981,70(3):941-955
Six microfacies are defined on quantitative petrographic data in a carbonate/clastic sequence from the subsurface, oil producing Mauddud Formation of early Middle Cretaceous age. These are, in descending order of importance and abundance: (1) biomicritic wackestone-packstone, (2) argillaceous mudstone, (3) micritic mudstone, (4) glauconitic sandstone, (5)Orhitolina pelsparitic grainstone, and (6) argillaceous dolomite.Sedimentation took place during a marine transgression onto a very shallow, intertidal, restricted marine shelf lagoons. Facies variations appear to be related to depth and energy changes and proximity to areas of clastic deposition. These changes may have been controlled by slight tectonic events in the hinterland and changes in the rate of basin subsidence.
Zusammenfassung Auf der Grundlage quantitativer petrographischer Daten werden sechs Mikrofazies in einer karbonat/klastischen Folge aus der unter der ErdoberflÄche liegenden, ölliefernden Mauddud-Formation der frühen Mittelkreide definiert. In absteigender Reihenfolge der Bedeutung und HÄufigkeit sind dieses: (1) biomikritischer wackestone-packstone, (2) toniger Schlickstein, (3) unkritischer Schlickstein, (4) glaukonitischer Sandstein, (5) Orbitolina-führender pelsparitischer Grainstone und (6) toniger Dolomit.Die Sedimentation erfolgte wÄhrend einer marinen Transgression auf sehr flache, intertidale Lagunen eines begrenzten marinen Schelfs. Die Fazies-Variationen scheinen mit den Wechseln in Wassertiefe und Energie sowie der mit NÄhe von Gebieten mit klastischer Sedimentation zusammenzuhÄngen.Diese Wechsel könnten durch kleinere tektonische Ereignisse im Hinterland und durch VerÄnderungen der Absenkungsrate des Beckens ausgelöst worden sein.
Résumé Des données pétrographiques quantitatives permettent de définir six microfacies dans une série clasto-carbonatée d'âge crétacé inférieur du sous-sol de la région pé trolifère de Mauddud. Ce sont par ordre décroissant d'importance et d'abondance: (1) des wacstones-pacstone biomicritiques; (2) des argilites; (3) des argilites micritiques; (4) des grès glauconitiques; (5) des grainstone pelsparitiques à orbitolines; (6) des dolomies argileuses.La sédimentation se produisit au cours d'une transgression marine dans des lagunes très plates, intercotidales, d'une plate-forme continentale de faible étendue. Les variations de facies semblent Être dues à des changements de profondeur et d'énergie, ainsi qu'à la proximité de régions à sédimentation clastique.Ces changements pourraient résulter de légers mouvements tectoniques dans l'arrière-pays et de variations dans le degré de subsidence du bassin de sédimentation.
- Mauddud, ( ). : 1) ; 2) ; 3) ; 4) ; 5) , 6) . , . , , , . , .相似文献
17.
油页岩中的稀土元素（REE）研究不仅可以用于解决岩石地质成因,提供物质来源信息,而且可以对REE含量进行资源评价,有利于油页岩的综合开发利用,具有重要的理论和现实意义。本研究测试并分析了银额盆地巴格毛德凹陷中生界白垩系下统巴音戈壁组（K1b）巴格毛德油页岩REE地球化学特征,分析结果表明,油页岩中的REE总量（∑REE）为94．8×10^-6～178×10^-6,平均值为126×10^-6,低于其围岩的∑REE;轻、重稀土元素含量比值（∑LREE／∑HREE）为2．60～3．45,平均值为3．10。（La／Yb）w为0．57～1．02,平均值为0．89,表明油页岩中LREE、HREE分异不明显,LREE相对HREE富集,属于LREE低度富集型。Eu表现为明显负异常,Ce表现为微弱的正异常,表明了油页岩形成于还原的古湖泊环境。油页岩样品∑REE与其微量元素的聚类分析结果表明,油页岩中的REE主要来自陆源碎屑沉积。油页岩样品δCe与δEu、δCe与∑REE均无明显的相关关系,表明成岩作用对REE的影响十分有限,研究区油页岩的成岩阶段处于未成熟阶段。 相似文献
18.
Secondary hydrocarbon generation potential from heavy oil, oil sand and solid bitumen during the artificial maturation 总被引：1，自引：0，他引：1
Secondary hydrocarbon generation potentials from natural bitumen, oil sand and heavy oil, representing different residual oil accumulations, were determined by artificial maturation in a closed pyrolysis system. Simulated results indicate that their thermal behavior and reactivity are similar to those of kerogen, and that they can generate hydrocarbons once subjected to suitable geological processes. Overall differences in oil and gas generation potentials among the samples result from differences in the chemical structure of precursor components, physical compaction status, and mineral matrices. Hydrogen rich precursors, such as oil sand and heavy oil, have greater potential to generate hydrocarbons than hydrogen poor ones. Naturally compacted oil sand has slightly higher conversion efficiency than artificially compacted heavy oil as indicated by lower residual bitumen content. However, total gas and liquid oil recovery from oil sand is lower than from heavy oil due to the poor release of pyrolytic products from well compacted and cemented networks in the experiments. Mineral matrices of previous oil deposits also affect further hydrocarbon generation potential. Carbonate matrices inhibit total oil and gas generation, which consequently retains high gas potential at the postmature stage. Traditional oil generation models mainly consider the thermal alteration of kerogen; this study provides supplemental information for superimposed basins where previous oil accumulations may have been destroyed and reburied to serve as secondary sources of oil and gas. Consideration of previous oil residues as potential source rock allows better estimates of available oil resources and the risks associated with their exploration. 相似文献
19.
Gerald Manners 《Geoforum》1984,15(1):57-64
The growing importance, and some of the benefits and costs, of North Sea oil production are reviewed, particularly the direct and indirect employment effects of the resource's development. Some of the issues surrounding the rate at which the remaining reserves of oil could be exploited are then delineated: the scale of the reserves, the future worth of oil, the macro-economic effects of oil production and the issue of private vs public perspectives are summarised in turn to develop a view on the most appropriate attitude towards depletion policy. 相似文献
20.
Shai Ezra Shimon Feinstein Ithamar Pelly Dan Bauman Irena Miloslavsky 《Organic Geochemistry》2000,31(12)
Residual fuel oil spilled into the sea from the Eshkol power station on 8 February, 1998 contaminated about 9 km of the foreshore north of the Ashdod harbour. A study of the aliphatic, polycyclic alkane and polyaromatic hydrocarbon (PAH) composition of the spilled oil shows rapid weathering in the early stages followed by gradual slowdown after about three months. Weathering of isoprenoids and PAH compounds and variation in Pr/Ph ratio appear to occur almost contemporaneously with that of n-alkanes, at a relatively moderate level of degradation, when much of the >C20 n-alkane envelope is still well preserved. Depletion of various compounds in accordance with molecular size rather than molecular structure appears to imply that physical weathering processes, i.e. evaporation and perhaps flushing due to wave energy, might have played an important role in the degradation of the spilled residual fuel oil in this study case. 相似文献