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1.
Integrated petrographic and chemical analysis of zircon, garnet and rutile from ultrahigh‐temperature (UHT) granulites in the Anápolis–Itauçu Complex, Brazil, is used to constrain the significance of zircon ID‐TIMS U–Pb geochronological data. Chondrite‐normalized rare earth element (REE) profiles of zircon cores have positive‐sloping heavy‐REE patterns, commonly inferred to be magmatic, whereas unambiguous metamorphic grains and overgrowths have flat to slightly negatively sloping heavy‐REE patterns. However, in one sample, a core of zircon interpreted as having formed prior to garnet crystallization and a metamorphic zircon formed within microstructures involving garnet breakdown both display elevated heavy‐REE (and Y) with positive‐sloping patterns. DREE(zrc/grt) partition coefficients suggest an approximation to equilibrium between zircon and garnet cores, although progressive enrichment in heavy REE towards garnet rims occurs in two of the samples investigated. Titanium‐in‐zircon thermometry indicates zircon growth during both the prograde and post‐peak evolution, but not at peak temperatures of the UHT metamorphism. By contrast, zirconium‐in‐rutile thermometry of inclusions armoured by garnet records crystallization temperatures, based on the upper end of the interquartile range of the data, of ～890 to 870 °C and maximum temperature around 980 °C, indicating prograde and retrograde growth close to and after peak conditions. Rutile located in retrograde microstructures records crystallization temperatures of 850 to 820 °C. Rutile intergrown with ilmenite and included within orthopyroxene, which is associated with exsolved zircon, records temperatures ～760 °C, consistent with Ti‐in‐zircon crystallization temperatures. ID‐TIMS U–Pb geochronological data from two of the four samples investigated define upper intercept ages of 641.3 ± 8.4 Ma (MSWD 0.91) and 638.8 ± 2.5 Ma (MSWD 1.03) that correlate with periods of zircon growth along the prograde segment of the P–T path. Individual zircon U–Pb dates retrieved from all samples range from 649 to 634 Ma, indicating a maximum duration of c. 15 Myr for the UHT event. This period is interpreted as recording modest thickening of hot backarc lithosphere located behind the Arenópolis Arc at the edge of the São Francisco Craton consequent upon terminal collision of the Parána Block with the arc during the amalgamation of West Gondwana.  相似文献   

2.
Phase equilibria modelling, laser‐ablation split‐stream (LASS)‐ICP‐MS petrochronology and garnet trace‐element geochemistry are integrated to constrain the P–T–t history of the footwall of the Priest River metamorphic core complex, northern Idaho. Metapelitic, migmatitic gneisses of the Hauser Lake Gneiss contain the peak assemblage garnet + sillimanite + biotite ± muscovite + plagioclase + K‐feldspar ± rutile ± ilmenite + quartz. Interpreted P–T paths predict maximum pressures and peak metamorphic temperatures of ~9.6–10.3 kbar and ~785–790 °C. Monazite and xenotime 208Pb/232Th dates from porphyroblast inclusions indicate that metamorphism occurred at c. 74–54 Ma. Dates from HREE‐depleted monazite formed during prograde growth constrain peak metamorphism at c. 64 Ma near the centre of the complex, while dates from HREE‐enriched monazite constrain the timing of garnet breakdown during near‐isothermal decompression at c. 60–57 Ma. Near‐isothermal decompression to ~5.0–4.4 kbar was followed by cooling and further decompression. The youngest, HREE‐enriched monazite records leucosome crystallization at mid‐crustal levels c. 54–44 Ma. The northernmost sample records regional metamorphism during the emplacement of the Selkirk igneous complex (c. 94–81 Ma), Cretaceous–Tertiary metamorphism and limited Eocene exhumation. Similarities between the Priest River complex and other complexes of the northern North American Cordillera suggest shared regional metamorphic and exhumation histories; however, in contrast to complexes to the north, the Priest River contains less partial melt and no evidence for diapiric exhumation. Improved constraints on metamorphism, deformation, anatexis and exhumation provide greater insight into the initiation and evolution of metamorphic core complexes in the northern Cordillera, and in similar tectonic settings elsewhere.  相似文献   

3.
High‐pressure (HP) metagreywacke from the Namche Barwa Complex, Eastern Himalayan Syntaxis (EHS), consists of garnet, biotite, plagioclase, quartz, rutile and ilmenite with or without K‐feldspar, sillimanite, cordierite, spinel and orthopyroxene. Two types of metagreywacke are recognized: medium‐temperature (MT) and high‐temperature (HT) types. Garnet in the MT metagreywacke shows significant growth zoning and contains lower MgO than the weakly zoned garnet in the HT metagreywacke. Petrographic observations and phase equilibria modelling for four representative samples indicate that both types of metagreywacke experienced clockwise P–T paths subdivided into three stages: stage I is the pre‐peak prograde to pressure peak (Pmax) stage characterized by progressive increase in P–T conditions. The Pmax conditions are estimated using the garnet composition with maximum CaO, being 12.5–13.5 kbar and 685–725 °C for the MT metagreywacke, and 15–16 kbar and 825–835 °C for the HT one. Stage II is the post‐Pmax decompression with heating or near‐isothermal to Tmax stage and the Tmax conditions, constrained using the garnet compositions with maximum MgO, are 11 kbar and 760 °C for the MT metagreywacke, and ~12 kbar and 830–845 °C for the HT one. The modelled mineral assemblages at Tmax are garnet + biotite + K‐feldspar + rutile + plagioclase ± ilmenite in the presence of melt for both types of metagreywacke, consistent with the petrographic observations. Stage III is the post‐Tmax retrograde metamorphism, characterized by decompression and cooling. The modelling suggests that the melts with high Na/K ratios (1.7–5.2) have been produced during stages I and II, which could be responsible for the formation of sodium‐rich leucogranites. This study and previous results indicate that the Higher Himalayan Crystallines in the EHS consist of MT–HP and HT–HP metamorphic units separated by a speculated tectonic contact. Petrological and structural discontinuities within the EHS cannot be easily interpreted with ‘tectonic aneurysm’ model.  相似文献   

4.
Eclogites and related high‐P metamorphic rocks occur in the Zaili Range of the Northern Kyrgyz Tien‐Shan (Tianshan) Mountains, which are located in the south‐western segment of the Central Asian Orogenic Belt. Eclogites are preserved in the cores of garnet amphibolites and amphibolites that occur in the Aktyuz area as boudins and layers (up to 2000 m in length) within country rock gneisses. The textures and mineral chemistry of the Aktyuz eclogites, garnet amphibolites and country rock gneisses record three distinct metamorphic events (M1–M3). In the eclogites, the first MP–HT metamorphic event (M1) of amphibolite/epidote‐amphibolite facies conditions (560–650 °C, 4–10 kbar) is established from relict mineral assemblages of polyphase inclusions in the cores and mantles of garnet, i.e. Mg‐taramite + Fe‐staurolite + paragonite ± oligoclase (An<16) ± hematite. The eclogites also record the second HP‐LT metamorphism (M2) with a prograde stage passing through epidote‐blueschist facies conditions (330–570 °C, 8–16 kbar) to peak metamorphism in the eclogite facies (550–660 °C, 21–23 kbar) and subsequent retrograde metamorphism to epidote‐amphibolite facies conditions (545–565 °C and 10–11 kbar) that defines a clockwise P–T path. thermocalc (average P–T mode) calculations and other geothermobarometers have been applied for the estimation of P–T conditions. M3 is inferred from the garnet amphibolites and country rock gneisses. Garnet amphibolites that underwent this pervasive HP–HT metamorphism after the eclogite facies equilibrium have a peak metamorphic assemblage of garnet and pargasite. The prograde and peak metamorphic conditions of the garnet amphibolites are estimated to be 600–640 °C; 11–12 kbar and 675–735 °C and 14–15 kbar, respectively. Inclusion phases in porphyroblastic plagioclase in the country rock gneisses suggest a prograde stage of the epidote‐amphibolite facies (477 °C and 10 kbar). The peak mineral assemblage of the country rock gneisses of garnet, plagioclase (An11–16), phengite, biotite, quartz and rutile indicate 635–745 °C and 13–15 kbar. The P–T conditions estimated for the prograde, peak and retrograde stages in garnet amphibolite and country rock are similar, implying that the third metamorphic event in the garnet amphibolites was correlated with the metamorphism in the country rock gneisses. The eclogites also show evidence of the third metamorphic event with development of the prograde mineral assemblage pargasite, oligoclase and biotite after the retrograde epidote‐amphibolite facies metamorphism. The three metamorphic events occurred in distinct tectonic settings: (i) metamorphism along the hot hangingwall at the inception of subduction, (ii) subsequent subduction zone metamorphism of the oceanic plate and exhumation, and (iii) continent–continent collision and exhumation of the entire metamorphic sequences. These tectonic processes document the initial stage of closure of a palaeo‐ocean subduction to its completion by continent–continent collision.  相似文献   

5.
Polymetamorphic garnet micaschists from the Austroalpine Saualpe Eclogite Unit (Kärnten, Austria, Eastern Alps) display complex microstructural and mineral–chemical relationships. Automated scanning electron microscopy routines with energy dispersive X‐ray (EDX) spectral mapping were applied for monazite detection and garnet mineral–chemical characterization. When the Fe, Mg, Mn and Ca element wt% compositions are used as generic labels for garnet EDX spectra, complex zonations and porphyroblast generations can be resolved in complete thin sections for selective electron‐microprobe analyses. Two garnet porphyroblast generations and diverse monazite age populations have been revealed in low‐Ca and high‐Al‐metapelites. Garnet 1 has decreasing Mn, constant Ca and significantly increasing Mg from cores to rims. Geothermobarometry of garnet 1 assemblages signals a crystallization along a M1 prograde metamorphism at ~650 °C/6–8 kbar. Sporadic monazite 1 crystallization started at c. 320 Ma. Subsequent pervasive 300–250 Ma high‐Y and high‐Gd monazite 1 formation during decompression coincided with the intrusion of Permian and Early Triassic pegmatites. Monazite 1 crystallized along the margin of garnet 1. Coronas of apatite and allanite around the large 320–250 Ma monazite signal a retrogressive stage. These microstructures suggest a Carboniferous‐to‐Early‐Permian age for the prograde M1 event with garnet 1. Such a M1 event at an intermediate‐P/T gradient has not yet been described from the Saualpe, and preceded a Permo‐Triassic low‐P stage. The M2 event with garnet 2 postdates the corona formation around Permian monazite. Garnet 2 displays first increasing XCa at decreasing XMg, then increasing XCa and XMg, and finally decreasing XCa with increasing XMg, always at high Ca and Mg, and low Mn. This records a P–T evolution which passed through eclogite facies conditions and reached maximum temperatures at ~750 °C/14 kbar during decompression‐heating. A monazite 2 population (94–86 Ma) with lower Y and Gd contents crystallized at decreasing pressure during the Cretaceous (Eo‐Alpine) metamorphism M2 at a high‐P/T gradient. The Saualpe Eclogite Unit underwent two distinct clockwise metamorphic cycles at different P–T conditions, related to continental collisions under different thermal regimes. This led to a characteristic distribution pattern of monazite ages in this unit which is different from other Austroalpine basement areas.  相似文献   

6.
Garnet crystallization in metapelites from the Barrovian garnet and staurolite zones of the Lesser Himalayan Belt in Sikkim is modelled utilizing Gibbs free energy minimization, multi‐component diffusion theory and a simple nucleation and growth algorithm. The predicted mineral assemblages and garnet‐growth zoning match observations remarkably well for relatively tight, clockwise metamorphic P–T paths that are characterized by prograde gradients of ～30 °C kbar?1 for garnet‐zone rocks and ～20 °C kbar?1 for rocks from the staurolite zone. Estimates for peak metamorphic temperature increase up‐structure toward the Main Central Thrust. According to our calculations, garnet stopped growing at peak pressures, and protracted heating after peak pressure was absent or insignificant. Almost identical P–T paths for the samples studied and the metamorphic continuity of the Lesser Himalayan Belt support thermo‐mechanical models that favour tectonic inversion of a coherent package of Barrovian metamorphic rocks. Time‐scales associated with the metamorphism were too short for chemical diffusion to substantially modify garnet‐growth zoning in rocks from the garnet and staurolite zones. In general, the pressure of initial garnet growth decreases, and the temperature required for initial garnet growth was reached earlier, for rocks buried closer toward the MCT. Deviations from this overall trend can be explained by variations in bulk‐rock chemistry.  相似文献   

7.
An automated method for the calculation of P–T paths based on garnet zoning is presented and used to interpret zoning in metapelitic schist from the southern Canadian Cordillera. The approach adopted to reconstruct the P–T path is to match garnet compositions along a radial transect with predictions from thermodynamic forward models, while iteratively modifying the composition to account for fractional crystallization. The method is applied to a representative sample of garnet‐ and staurolite‐bearing schist from an amphibolite facies Barrovian belt in the southern Canadian Omineca belt. Garnet zoning in these schists is concentric and largely continuous from core to rim. Three zones are present, the first two of which coincide with sector‐zoned cores of garnet crystals. Similar zoning is developed in rocks that contain or lack staurolite, respectively, suggesting garnet growth was restricted to the initial part of the prograde P–T path prior to the development of staurolite. Growth zoning in large garnet crystals has not been significantly modified by diffusion. This interpretation is based on zoning characteristics of garnet crystals and is further supported by results of a forward model incorporating the effects of simultaneous fractional crystallization and intracrystalline diffusion. The P–T path calculated for this rock includes an initial, linear stage with a high dP/dT, and a later stage dominated by heating. The approach adopted in this study may have application to other garnet‐bearing rocks in which growth zoning is preserved.  相似文献   

8.
The P–T–t path of high‐P metamorphic rocks in subduction zones may reveal valuable information regarding the tectonic processes along convergent plate boundaries. Herein, we present a detailed petrological, pseudosection modelling and radiometric dating study of several amphibole schists of oceanic affinity from the Lhasa Block, Tibet. The amphibole schists experienced an overall clockwise P–T path that was marked by post‐Pmax heating–decompression and subsequent isothermal decompression following the attainment of peak high‐P and low‐T conditions (~490°C and 1.6 GPa). Pseudosection modelling shows that the amphibole schists underwent water‐unsaturated conditions during prograde metamorphism, and the stability field of the assemblage extends to lower temperatures and higher pressures within the water‐unsaturated condition relative to water‐saturated model along the prograde path. The high‐P amphibole schists were highly reduced during retrograde metamorphism. Precise evaluation of the ferric iron conditions determined from the different compositions of epidote inclusions in garnet and matrix epidote is crucial for a true P–T estimate by garnet isopleth thermobarometry. Lu–Hf isotope analyses on garnet size separates from a garnet‐bearing amphibole schist yield four two‐point garnet–whole‐rock isochron ages from 228.2 ± 1.2 Ma to 224.3 ± 1.2 Ma. These Lu–Hf dates are interpreted to constrain the period of garnet growth and approximate the timing of prograde metamorphism because of the low peak metamorphic temperature of the rock and the well‐preserved Mn/Lu growth zoning in garnet. The majority of zircon U–Pb dates provide no constraints on the timing of metamorphism; however, two concordant U–Pb dates of 222.4 ± 3.9 Ma and 223.3 ± 4.2 Ma were obtained from narrow and uncommon metamorphic rims. Coexistence of zircon and sphene in the samples implies that the metamorphic zircon growth was likely assisted by retrogression of rutile to sphene during exhumation. The near coincident radiometric dates of zircon U–Pb and garnet Lu–Hf indicate rapid burial and exhumation of the amphibole schists, suggesting a closure time of c. 224–223 Ma for the fossil ocean basin between the northern and southern Lhasa blocks.  相似文献   

9.
Garnet‐bearing ultramafic rocks including clinopyroxenite, wehrlite and websterite locally crop out in the Higashi‐akaishi peridotite of the Besshi region in the Cretaceous Sanbagawa metamorphic belt. These rock types occur within dunite as lenses, boudins or layers with a thickness ranging from a few centimetres to 1 metre. The wide and systematic variation of bulk‐rock composition and the overall layered structure imply that the ultramafic complex originated as a cumulate sequence. Garnet and other major silicates contain rare inclusions of edenitic amphibole, chlorite and magnetite, implying equilibrium at relatively low P–T conditions during prograde metamorphism. Orthopyroxene coexisting with garnet shows bell‐shaped Al zoning with a continuous decrease of Al from the core towards the rim, consistent with rims recording peak metamorphic conditions. Estimated P–T conditions using core and rim compositions of orthopyroxene are 1.5–2.4 GPa/700–800 °C and 2.9–3.8 GPa/700–810 °C, respectively, implying a high P/T gradient (> 3.1 GPa/100 °C) during prograde metamorphism. The presence of relatively low P–T conditions at an early stage of metamorphism and the steep P/T gradient together trace a concave upwards P–T path that shows increasing P/T with higher T, similar to P–T paths reported from other UHP metamorphic terranes. These results suggest either (1) down dragging of hydrated mantle cumulate parallel to the slab–wedge interface in the subduction zone by mechanical coupling with the subducting slab or (2) ocean floor metamorphism and/or serpentinization at early stage of subduction of oceanic lithosphere and ensuing HP–UHP prograde metamorphism.  相似文献   

10.
High‐P (HP) eclogite and associated garnet–omphacite granulite have recently been discovered in the Mulantou area, northeastern Hainan Island, South China. These rocks consist mainly of garnet, omphacite, hornblende, quartz and rutile/ilmenite, with or without zoisite and plagioclase. Textural relationships, mineral compositions and thermobarometric calculations demonstrate that the eclogite and garnet–omphacite granulite share the same three‐stage metamorphic evolution, with prograde, peak and retrograde P?T conditions of 620–680°C and 8.7–11.1 kbar, 820–860°C and 17.0–18.2 kbar, and 700–730°C and 7.1–8.5 kbar respectively. Sensitive high‐resolution ion microprobe U–Pb zircon dating, coupled with the identification of mineral inclusions in zircon, reveals the formation of mafic protoliths before 355 Ma, prograde metamorphism at c. 340–330 Ma, peak to retrograde metamorphism at c. 310–300 Ma, and subsequent pegmatite intrusion at 295 Ma. Trace element geochemistry shows that most of the rocks have a MORB affinity, with initial εNd values of +2.4 to +6.7. As with similar transitional eclogite–HP granulite facies rocks in the thickened root in the European Variscan orogen, the occurrence of relatively high P?T metamorphic rocks of oceanic origin in northeastern Hainan Island suggests Carboniferous oceanic subduction leading to collision of the Hainan continental block, or at least part of it, with the South China Block in the eastern Palaeo‐Tethyan tectonic domain.  相似文献   

11.
Interpretations based on quantitative phase diagrams in the system CaO–Na2O–K2O–TiO2–MnO–FeO–MgO–Al2O3–SiO2–H2O indicate that mineral assemblages, zonations and microstructures observed in migmatitic rocks from the Beit Bridge Complex (Messina area, Limpopo Belt) formed along a clockwise P–T path. That path displays a prograde P–T increase from 600 °C/7.0 kbar to 780 °C/9–10 kbar (pressure peak) and 820 °C/8 kbar (thermal peak), followed by a P–T decrease to 600 °C/4 kbar. The data used to construct the P–T path were derived from three samples of migmatitic gneiss from a restricted area, each of which has a distinct bulk composition: (1) a K, Al‐rich garnet–biotite–cordierite–sillimanite–K‐feldspar–plagioclase–quartz–graphite gneiss (2) a K‐poor, Al‐rich garnet–biotite–staurolite–cordierite–kyanite–sillimanite–plagioclase–quartz–rutile gneiss, and (3) a K, Al‐poor, Fe‐rich garnet–orthopyroxene–biotite–chlorite–plagioclase–quartz–rutile–ilmenite gneiss. Preservation of continuous prograde garnet growth zonation demonstrates that the pro‐ and retrograde P–T evolution of the gneisses must have been rapid, occurring during a single orogenic cycle. These petrological findings in combination with existing geochronological and structural data show that granulite facies metamorphism of the Beit Bridge metasedimentary rocks resulted from an orogenic event during the Palaeoproterozoic (c. 2.0 Ga), caused by oblique collision between the Kaapvaal and Zimbabwe Cratons. Abbreviations follow Kretz (1983 ).  相似文献   

12.
The Palaeo‐Mesoproterozoic metapelite granulites from northern Garo Hills, western Shillong‐Meghalaya Gneissic Complex (SMGC), northeast India, consist of resorbed garnet, cordierite and K‐feldspar porphyroblasts in a matrix comprising shape‐preferred aggregates of biotite±sillimanite+quartz that define the penetrative gneissic fabric. An earlier assemblage including biotite and sillimanite occurs as inclusions within the garnet and cordierite porphyroblasts. Staurolite within cordierite in samples without matrix sillimanite is interpreted to have formed by a reaction between the sillimanite inclusion and the host cordierite during retrogression. Accessory monazite occurs as inclusions within garnet as well as in the matrix, whereas accessory xenotime occurs only in the matrix. The monazite inclusions in garnet contain higher Ca, and lower Y and Th/U than the matrix monazite outside resorbed garnet rims. On the other hand, matrix monazite away from garnet contains low Ca and Y, and shows very high Th/U ratios. The low Th/U ratios (<10) of the Y‐poor garnet‐hosted monazite indicate subsolidus formation during an early stage of prograde metamorphism. A calculated P–T pseudosection in the MnCKFMASH‐PYCe system indicates that the garnet‐hosted monazite formed at <3 kbar/600 °C (Stage A). These P–T estimates extend backward the previously inferred prograde P–T path from peak anatectic conditions of 7–8 kbar/850 °C based on major mineral equilibria. Furthermore, the calculated P–T pseudosections indicate that cordierite–staurolite equilibrated at ~5.5 kbar/630 °C during retrograde metamorphism. Thus, the P–T path was counterclockwise. The Y‐rich matrix monazite outside garnet rims formed between ~3.2 kbar/650 °C and ~5 kbar/775 °C (Stage B) during prograde metamorphism. If the effect of bulk composition change due to open system behaviour during anatexis is considered, the P–T conditions may be lower for Stage A (<2 kbar/525 °C) and Stage B (~3 kbar/600 °C to ~3.5 kbar/660 °C). Prograde garnet growth occurred over the entire temperature range (550–850 °C), and Stage‐B monazite was perhaps initially entrapped in garnet. During post‐peak cooling, the Stage‐B monazite grains were released in the matrix by garnet dissolution. Furthermore, new matrix monazite (low Y and very high Th/U ≤80, ~8 kbar/850–800 °C, Stage C), some monazite outside garnet rims (high Y and intermediate Th/U ≤30, ~8 kbar/800–785 °C, Stage D), and matrix xenotime (<785 °C) formed through post‐peak crystallization of melt. Regardless of textural setting, all monazite populations show identical chemical ages (1630–1578 Ma, ±43 Ma). The lithological association (metapelite and mafic granulites), and metamorphic age and P–T path of the northern Garo Hills metapelites and those from the southern domain of the Central Indian Tectonic Zone (CITZ) are similar. The SMGC was initially aligned with the southern parts of CITZ and Chotanagpur Gneissic Complex of central/eastern India in an ENE direction, but was displaced ~350 km northward by sinistral movement along the north‐trending Eastern Indian Tectonic Zone in Neoproterozoic. The southern CITZ metapelites supposedly originated in a back‐arc associated with subducting oceanic lithosphere below the Southern Indian Block at c. 1.6 Ga during the initial stage of Indian shield assembly. It is inferred that the SMGC metapelites may also have originated contemporaneously with the southern CITZ metapelites in a similar back‐arc setting.  相似文献   

13.
Prograde P–T paths recorded by the chemistry of minerals of subduction‐related metamorphic rocks allow inference of tectonic processes at convergent margins. This paper elucidates the changing P–T conditions during garnet growth in pelitic schists of the Sambagawa metamorphic belt, which is a subduction related metamorphic belt in the south‐western part of Japan. Three types of chemical zoning patterns were observed in garnet: Ca‐rich normal zoning, Ca‐poor normal zoning and intrasectoral zoning. Petrological studies indicate that normally‐zoned garnet grains grew keeping surface chemical equilibrium with the matrix, in the stable mineral assemblage of garnet + muscovite + chlorite + plagioclase + paragonite + epidote + quartz ± biotite. Pressure and temperature histories were inversely calculated from the normally‐zoned garnet in this assemblage, applying the differential thermodynamic method (Gibbs' method) with the latest available thermodynamic data set for minerals. The deduced P–T paths indicate slight increase of temperature with increasing pressure throughout garnet growth, having an average dP/dT of 0.4–0.5 GPa/100 °C. Garnet started growing at around 470 °C and 0.6 GPa to achieve the thermal and baric peak condition near the rim (520 °C, 0.9 GPa). The high‐temperature condition at relatively low pressure (for subduction related metamorphism) suggests that heating occurred before or simultaneously with subduction.  相似文献   

14.
Eclogite, felsic orthogneiss and garnet–staurolite metapelite occur in a 5 km long profile in the area of Mi?dzygórze in the Orlica–?nie?nik dome (Bohemian Massif). Petrographic observations and mineral equilibria modelling, in the context of detailed structural work, are used to document the close juxtaposition of high‐pressure and medium‐pressure rocks. The structural succession in all lithologies shows an early shallow‐dipping fabric, S1, that is folded by upright folds and overprinted by a heterogeneously developed subvertical foliation, S2. Late recumbent folds associated with a weak shallow‐dipping axial‐plane cleavage, S3, occur locally. The S1 fabric in the eclogite is defined by alternation of garnet‐rich (grs = 22–29 mol.%) and omphacite‐rich (jd = 33–36 mol.%) layers with oriented muscovite (Si = 3.26–3.31 p.f.u.) and accessory kyanite, zoisite, rutile and quartz, indicating conditions of ～19–22 kbar and ～700–750 °C. The assemblage in the retrograde S2 fabric is formed by amphibole, plagioclase, biotite and relict rutile surrounded by ilmenite and sphene that is compatible with decompression and cooling from ～9 kbar and ～730 °C to 5–6 kbar and 600–650 °C. The S3 fabric contains in addition domains with albite, chlorite, K‐feldspar and magnetite indicating cooling to greenschist facies conditions. The metapelites are composed of garnet, staurolite, muscovite, biotite, quartz, ilmenite and chlorite. Chemical zoning of garnet cores that contain straight ilmenite and staurolite inclusion trails oriented perpendicular to the external S2 fabric indicates prograde growth, from ～5 kbar and ～520 °C to ～7 kbar and ～610 °C, during the formation of the S1 fabric. Inclusion trails parallel with the S2 fabric at garnet and staurolite rims are interpreted to be a continuation of the prograde path to ～7.5 and ～630 °C in the S2 fabric. Matrix chlorite parallel to the S2 foliation indicates that the subvertical fabric was still active below 550 °C. The axial planar S2 fabrics developed during upright folding are associated with retrogression of the eclogite under amphibolite facies conditions, and with prograde evolution in the metapelites, associated with their juxtaposition. The shared part of the eclogite and metapelite P–T paths during the development of the subvertical fabric reflects their exhumation together.  相似文献   

15.
Pelitic schists from contact aureoles surrounding mafic–ultramafic plutons in Westchester County, NY record a high‐P (~0.8 GPa) high‐T (~790 °C) contact overprint on a Taconic regional metamorphic assemblage (~0.5 GPa). The contact metamorphic assemblage of a pelitic sample in the innermost aureole of the Croton Falls pluton, a small (<10 km2) gabbroic body, consists of quartz–plagioclase–biotite–garnet–sillimanite–ilmenite–graphite–Zn‐rich Al‐spinel. Both K‐feldspar and muscovite are absent, and abundant biotite, plagioclase, sillimanite, quartz and ilmenite inclusions are found within subhedral garnet crystals. Unusually low bulk‐rock Na and K contents imply depletion of alkalic components and silica through anatexis and melt extraction during contact heating relative to typical metapelites outside the aureole. Thermobarometry on nearby samples lacking a contact overprint yields 620–640 °C and 0.5–0.6 GPa. In the aureole sample, WDS X‐ray chemical maps show distinct Ca‐enriched rims on both garnet and matrix plagioclase. Furthermore, biotite inclusions within garnet have significantly higher Mg concentration than matrix biotite. Thermobarometry using GASP and garnet–biotite Mg–Fe exchange equilibria on inclusions and adjacent garnet host interior to the high‐Ca rim zone yield ~0.5 ± 0.1 GPa and ~620 ± 50 °C. Pairs in the modified garnet rim zone yield ~0.9 ± 0.1 GPa and ~790 ± 50 °C. Thermocalc average P–T calculations yield similar results for core (~0.5 ± ~0.1 GPa, ~640 ± ~80 °C) and rim (~0.9 ± ~0.1 GPa, ~800 ± ~90 °C) equilibria. The core assemblages are interpreted to record the P–T conditions of peak metamorphism during the Taconic regional event whereas the rim compositions and matrix assemblages are interpreted to record the P–T conditions during the contact event. The high pressures deduced for this later event are interpreted to reflect loading due to the emplacement of Taconic allochthons in the northern Appalachians during the waning stages of regional metamorphism (after c. 465 Ma) and before contact metamorphism (c. 435 Ma). In the absence of contact metamorphism‐induced recrystallization, it is likely that this regional‐scale loading would remain cryptic or unrecorded.  相似文献   

16.
The zonal structure of prograde garnet in pelitic schists from the medium-grade garnet zone and the higher-grade albite-biotite zone was examined to investigate the evolution of prograde P–T paths of the Sanbagawa metamorphism. The garnet studied shows a bell-shaped chemical zoning of the spessartine component, which decreases in abundance from the core towards the rim. Almandine and pyrope contents and XMg [=Mg/(Mg+Fe2+)] increase monotonously outwards. The general scheme of the zonal structure for grossular content [XGrs=Ca/(Fe2++Mn+Mg+Ca)] can be summarized as: (1) XGrs increases outwards (inner segment) and reaches a maximum at an intermediate position between the crystal core and the rim, then decreases towards the outermost rim (outer segment) (2) the inner segment of garnet in the garnet zone samples tends to have a higher XGrs/XSps values for a given XSps than those in the albite–biotite zone samples (3) average XSps at the maximum XGrs position in the albite–biotite zone samples ranges from 0.02 to 0.12 and is lower than that in the garnet zone samples (0.13–0.32) (4) the maximum XGrs in the albite–biotite zone samples (0.34–0.39 on average) tends to be higher than that in the garnet zone samples (0.26–0.36), and (5) differences of XGrs between the maximum and rim in the albite–biotite zone samples are between 0.10 and 0.14 and higher than those in the garnet zone samples (< 0.11). These facts imply that albite–biotite zone materials (a) were recrystallized under lower dP/dT conditions at an early stage of the prograde metamorphism (b) began their exhumation under higher P–T conditions and (c) have been continuously heated during exhumation for a longer duration than the garnet zone materials. The systematic changes of prograde P–T paths can be interpreted as documenting the evolution of the Sanbagawa subduction zone.  相似文献   

17.
Northward subduction of the leading edge of the Indian continental margin to depths greater than 100 km during the early Eocene resulted in high‐pressure (HP) quartz‐eclogite to ultrahigh‐pressure (UHP) coesite–eclogite metamorphism at Tso Morari, Ladakh Himalaya, India. Integrated pressure–temperature–time determinations within petrographically well‐constrained settings for zircon‐ and/or monazite‐bearing assemblages in mafic eclogite boudins and host aluminous gneisses at Tso Morari uniquely document segments of both the prograde burial and retrograde exhumation path for HP/UHP units in this portion of the western Himalaya. Poikiloblastic cores and inclusion‐poor rims of compositionally zoned garnet in mafic eclogite were utilized with entrapped inclusions and matrix minerals for thermobarometric calculations and isochemical phase diagram construction, the latter thermodynamic modelling performed with and without the consideration of cation fractionation into garnet during prograde metamorphism. Analysis of the garnet cores document (M1) conditions of 21.5 ± 1.5 kbar and 535 ± 15 °C during early garnet growth and re‐equilibration. Sensitive high resolution ion microprobe (SHRIMP) U–Pb analysis of zircon inclusions in garnet cores yields a maximum age determination of 58.0 ± 2.2 Ma for M1. Peak HP/UHP (M2) conditions are constrained at 25.5–27.5 kbar and 630–645 °C using the assemblage garnet rim–omphacite–rutile–phengite–lawsonite–talc–quartz (coesite), with mineral compositional data and regional considerations consistent with the upper P–T bracket. A SHRIMP U–Pb age determination of 50.8 ± 1.4 Ma for HP/UHP metamorphism is given by M2 zircons analysed in the eclogitic matrix and that are encased in the garnet rim. Two garnet‐bearing assemblages from the Puga gneiss (host to the mafic eclogites) were utilized to constrain the subsequent decompression path. A non‐fractionated isochemical phase diagram for the assemblage phengite–garnet–biotite–plagioclase–quartz–melt documents a restricted (M3) P–T stability field centred on 12.5 ± 0.5 kbar and 690 ± 25 °C. A second non‐fractionated isochemical phase diagram calculated for the lower pressure assemblage garnet–cordierite–sillimanite–biotite–plagioclase–quartz–melt (M4) documents a narrow P–T stability field ranging between 7–8.4 kbar and 705–755 °C, which is consistent with independent multiequilibria P–T determinations. Th–Pb SHRIMP dating of monazite cores surrounded by allanite rims is interpreted to constrain the timing of the M4 equilibration to 45.3 ± 1.1 Ma. Coherently linking metamorphic conditions with petrographically constrained ages at Tso Morari provides an integrated context within which previously published petrological or geochronological results can be evaluated. The new composite path is similar to those published for the Kaghan UHP locality in northern Pakistan, although the calculated 12‐mm a?1 rate of post‐pressure peak decompression at Tso Morari would appear less extreme.  相似文献   

18.
Cathodoluminescence (CL) mapping of kyanite in high pressure, aluminous granulites from the central Grenville Province reveals internal structures that are linked to their metamorphic reaction history. In two samples, individual kyanite crystals are shown to be composite porphyroblasts comprising three distinct generations, defined by their CL intensity and Cr (±V, Ti, Fe and Ga) content, and each separated by resorbed interfaces. In contrast, a sub‐aluminous sample contains two types of kyanite, one as resorbed inclusions in garnet and another in the groundmass or replacing garnet. These textural variants of kyanite are interpreted within the framework of phase equilibria modelling. In P–T pseudosections, a first generation of kyanite, which is only present in the most aluminous samples, is potentially linked to staurolite breakdown, and its resorption is consistent with a subsequent increase in pressure. This kyanite represents the earliest remnant of prograde metamorphism identifiable in these rocks. The second generation, present in the porphyroblasts in the same samples and as inclusions in garnet in the sub‐aluminous sample, is interpreted to be the peritectic product of muscovite dehydration melting. Resorption of this kyanite is consistent with subsequent continuous dehydration melting of biotite, which is also inferred based on microstructural considerations. The final generation of kyanite, present as rims on the prograde kyanite porphyroblasts in aluminous samples and as part of the groundmass or replacing garnet in the sub‐aluminous rock, is interpreted to have grown during melt crystallization upon retrogression. The presence of retrograde kyanite implies that the melt crystallized over a wide range of temperatures, and provides an important constraint on the P–T conditions of the metamorphic peak and on the retrograde P–T path. CL mapping is crucial for identifying retrograde kyanite in aluminous samples, as it preferentially overgrows existing kyanite rather than replacing other prograde phases. The scarcity of kyanite in sub‐aluminous rocks allows retrograde kyanite to grow as discrete crystals that can be identified by optical microscopy. This work attests to the potential of unconventional tools such as CL imaging for deciphering the metamorphic history of rocks.  相似文献   

19.
High‐pressure basic granulites are widely distributed as enclaves and sheet‐like blocks in the Huaian TTG gneiss terrane in the Sanggan area of the Central Zone of the North China craton. Four stages of the metamorphic history have been recognised in mineral assemblages based on inclusion, exsolution and reaction textures integrated with garnet zonation patterns as revealed by compositional maps and compositional profiles. The P–T conditions for each metamorphic stage were obtained using thermodynamically and experimentally calibrated geothermobarometers. The low‐Ca core of growth‐zoned garnet, along with inclusion minerals, defines a prograde assemblage (M1) of garnet + clinopyroxene + plagioclase + quartz, yielding 700 °C and 10 kbar. The peak of metamorphism at about 750–870 °C and 11–14.5 kbar (M2) is defined by high‐Ca domains in garnet interiors and inclusion minerals of clinopyroxene, plagioclase and quartz. Kelyphites or coronas of orthopyroxene + plagioclase ± magnetite around garnet porphyroblasts indicate garnet breakdown reactions (M3) at conditions around 770–830 °C and 8.5–10.5 kbar. Garnet exsolution lamellae in clinopyroxene and kelyphites of amphibole + plagioclase around garnet formed during the cooling process at about 500–650 °C and 5.5–8 kbar (M4). These results help define a sequential P–T path containing prograde, near‐isothermal decompression (ITD) and near‐isobaric cooling (IBC) stages. The clockwise hybrid ITD and IBC P–T paths of the HP granulites in the Sanggan area imply a model of thickening followed by extension in a collisional environment. Furthermore, the relatively high‐pressures (6–14.5 kbar) of the four metamorphic stages and the geometry of the P–T paths suggest that the HP granulites, together with their host Huaian TTG gneisses, represent the lower plate in a crust thickened during collision. The corresponding upper‐plate might be the tectonically overlying Khondalite series, which was subjected to medium‐ to low‐pressure (MP/LP: 7–4 kbar) granulite facies metamorphism with a clockwise P–T path including an ITD segment. Both the HP and the MP/LP granulite facies events occurred contemporaneously at c. 1.90–1.85 Ga in a collisional environment created by the assembly process of the North China craton.  相似文献   

20.
The Sanbagawa metamorphic belt of southwest Japan is one of the type localities of subduction‐related high‐P metamorphism. However, variable pressure–temperature (P–T) paths and metabasic assemblages have been reported for eclogite units in the region, leading to uncertainty about the subduction zone paleo‐thermal structure and associated tectonometamorphic conditions. To analyse this variation, phase equilibria modelling was applied to the three main high‐P metabasic rock types documented in the region – glaucophane eclogite, barroisite eclogite and garnet blueschist – with modelling performed over a range of P, T, bulk rock H2O and bulk rock ferric iron conditions using thermocalc . All samples are calculated to share a common steep prograde P–T path to similar peak conditions of ～16–20 kbar and 560–610 °C. The results establish that regional assemblage variation is systematic, with the alternation in peak amphibole phase due to peak conditions overlapping the glaucophane–barroisite solvus, and bulk composition effects stabilizing blueschist v. eclogite facies assemblages at similar P–T conditions. Furthermore, the results reveal that a steep prograde P–T path is common to all eclogite units in the Sanbagawa belt, indicating that metamorphic conditions were consistent along strike. All localities are compatible with predictions made by a ridge approach model, which attributes eclogite facies metamorphism and exhumation of the Sanbagawa belt to the approach of a spreading ridge.  相似文献   

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