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1.
The formation of CO2 in the gas phase and on a polyaromatic hydrocarbon surface (coronene) via three possible pathways is investigated with density functional theory. Calculations show that the coronene surface catalyses the formation of CO2 on model grain surfaces. The addition of 3O to CO is activated by 2530 K in the gas phase. This barrier is lowered by 253 K for the Eley–Rideal mechanism and 952 K for the hot-atom mechanism on the surface of coronene. Alternative pathways for the formation of CO2 are the addition of 3O to the HCO radical, followed by dissociation of the HCO2 intermediate. The O + HCO addition is barrierless in the gas phase and on the surface and is more than sufficiently exothermic to subsequently cleave the H–C bond. The third mechanism, OH + CO addition followed by H removal from the energized HOCO intermediate, has a gas-phase exit barrier that is 1160 K lower than the entrance barrier. On the coronene surface, however, both barriers are almost equal. Because the HOCO intermediate can also be stabilized by energy dissipation to the surface, it is anticipated that for the surface reaction the adsorbed HOCO could be a long-lived intermediate. In this case, the stabilized HOCO intermediate could react, in a barrierless manner, with a hydrogen atom to form H2+ CO2, HCO2H, or H2O + CO.  相似文献   

2.
The Cepheus A star-forming region has been investigated through a multiline H2S and SO2 survey at millimetre wavelengths. Large-scale maps and high-resolution line profiles reveal the occurrence of several outflows. Cep A East is associated with multiple mass-loss processes: in particular, we detect a 0.6-pc jet-like structure which shows for the first time that the Cep A East young stellar objects are driving a collimated outflow moving towards the south.
The observed outflows show different clumps associated with definitely different H2S/SO2 integrated emission ratios, indicating that the gas chemistry in Cepheus A has been altered by the passage of shocks. H2S appears to be more abundant than SO2 in high-velocity clumps, in agreement with chemical models. However, we also find quite small H2S linewidths, suggestive of regions where the evaporated H2S molecules had enough time to slow down but not to freeze out on to dust grains. Finally, comparison between the line profiles indicates that the excitation conditions increase with the velocity, as expected for a propagation of collimated bow shocks.  相似文献   

3.
Recent laboratory experiments on interstellar dust analogues have shown that H2 formation on dust-grain surfaces is efficient in a range of grain temperatures below 20 K. These results indicate that surface processes may account for the observed H2 abundance in cold diffuse and dense clouds. However, high abundances of H2 have also been observed in warmer clouds, including photon-dominated regions (PDRs), where grain temperatures may reach 50 K, making the surface processes extremely inefficient. It was suggested that this apparent discrepancy can be resolved by chemisorption sites. However, recent experiments indicate that chemisorption processes may not be efficient at PDR temperatures. Here we consider the effect of grain porosity on H2 formation, and analyse it using a rate-equation model. It is found that porosity extends the efficiency of the recombination process to higher temperatures. This is because H atoms that desorb from the internal surfaces of the pores may re-adsorb many times and thus stay longer on the surface. However, this porosity-driven extension may enable efficient H2 formation in PDRs only if porosity also contributes to significant cooling of the grains, compared to non-porous grains.  相似文献   

4.
Long-slit spectra of the molecular outflow Herbig–Haro (HH) 46/47 have been taken in the J and K near-infrared bands. The observed H2 line emission confirms the existence of a bright and extended redshifted counter-jet outflow south-west of HH 46. In contrast with the optical appearance of this object, we show that this outflow seems to be composed of two different emission regions characterized by distinct heliocentric velocities. This implies an acceleration of the counter-jet.
The observed [Fe  ii ] emission suggests an average extinction of 7–9 visual magnitudes for the region associated with the counter-jet.
Through position–velocity diagrams, we show the existence of different morphologies for the H2 and [Fe  ii ] emission regions in the northern part of the HH 46/47 outflow. We have detected for the first time high-velocity (−250 km s−1) [Fe  ii ] emission in the region bridging HH 46 to HH 47A. The two strong peaks detected can be identified with the optical positions B8 and HH 47B.
The H2 excitation diagrams for the counter-jet shock suggest an excitation temperature for the gas of T ex≈2600 K . The lack of emission from the higher energy H2 lines, such as the 4–3 S(3) transition, suggests a thermal excitation scenario for the origin of the observed emission. Comparison of the H2 line ratios with various shock models yielded useful constraints about the geometry and type of these shocks. Planar shocks can be ruled out whereas curved or bow shocks (both J- and C-type) can be parametrized to fit our data.  相似文献   

5.
Anomalous molecular line profile shapes are the strongest indicators of the presence of the infall of gas that is associated with star formation. Such profiles are seen for well-known tracers, such as HCO+, CS and H2CO. In certain cases, optically thick emission lines with appropriate excitation criteria may possess the asymmetric double-peaked profiles that are characteristic of infall. However, recent interpretations of the HCO+ infall profile observed towards the protostellar infall candidate B335 have revealed a significant discrepancy between the inferred overall column density of the molecule and that which is predicted by standard dark cloud chemical modelling.
This paper presents a model for the source of the HCO+ emission excess. Observations have shown that, in low-mass star-forming regions, the collapse process is invariably accompanied by the presence of collimated outflows; we therefore propose the presence of an interface region around the outflow in which the chemistry is enriched by the action of jets. This hypothesis suggests that the line profiles of HCO+, as well as other molecular species, may require a more complex interpretation than can be provided by simple, chemically quiescent, spherically symmetric infall models.
The enhancement of HCO+ depends primarily on the presence of a shock-generated radiation field in the interface. Plausible estimates of the radiation intensity imply molecular abundances that are consistent with those observed. Further, high-resolution observations of an infall-outflow source show HCO+ emission morphology that is consistent with that predicted by this model.  相似文献   

6.
We suggest a new way to establish the relation between the electron temperature t 3 within the [O  iii ] zone and the electron temperature t 2 within the [O  ii ] zone in high-metallicity  (12 + log(O/H) > 8.25)  H  ii regions. The   t 2– t 3  diagram is constructed by applying our method to a sample of 372 H  ii regions. We find that the correlation between t 2 and t 3 is tight and can be approximated by a linear expression. The new   t 2– t 3  relation can be used to determine t 2 and accurate abundances in high-metallicity H  ii regions with a measured t 3. It can also be used in conjunction with the ff relation for the determination of t 3 and t 2 and oxygen abundances in high-metallicity H  ii regions, where the [O  iii ]λ4363 auroral line is not detected. The derived   t 2– t 3  relation is independent of photoionization models of H  ii regions.  相似文献   

7.
The pure rotational spectrum of homonuclear diatomic molecules in the interstellar medium is strongly forbidden, and no such spectrum has been detected. In regions of high excitation, vibrational emission may occur, as is widely detected in the case of H2 in interstellar shocks and photon-dominated regions. However, it is of considerable interest to know the abundance of homonuclear diatomics in quiescent regions. We propose that vibrational emission from homonuclear diatomic molecules in cold clouds may be detectable, where the excitation is mainly through collisions with non-thermal electrons arising from the cosmic-ray ionization of H2. As an example, we estimate the intensity of emission from N2 in cold, dark interstellar clouds. We show that such emission is at the limit of detectability with current technology. Other excitation mechanisms may also contribute and enhance this emission.  相似文献   

8.
A reliable estimate of the molecular gas content in galaxies plays a crucial role in determining their dynamical and star-forming properties. However, H2, the dominant molecular species, is difficult to observe directly, particularly in the regions where most molecular gas is thought to reside. Its mass is therefore commonly inferred by assuming a direct proportionality with the integrated intensity of the  12CO( J = 1 → 0)  emission line, using a CO-to-H2 conversion factor, X . Although a canonical value for X is used extensively in such estimates, there is increasing evidence, both theoretical and observational, that the conversion factor may vary by over an order of magnitude under conditions different from those of the local neighbourhood. In an effort to understand the influence of changing environmental conditions on the conversion factor, we derive theoretical estimates of X for a wide range of physical parameters using a photon-dominated region (PDR) time-dependent chemical model, benchmarking key results against those of an independent PDR code to ensure reliability. Based on these results, the sensitivity of the X factor to change in each physical parameter is interpreted in terms of the chemistry and physical processes within the cloud. In addition to confirming previous observationally derived trends, we find that the time-dependence of the chemistry, often neglected in such models, has a considerable influence on the value of the conversion factor.  相似文献   

9.
We present ISOPHOT observations of eight interstellar regions in the 60–200 μm wavelength range. The regions belong to mostly quiescent high-latitude clouds and have optical extinction peaks from   AV ∼1–6 mag  . From the 150- and 200-μm emission, we derived colour temperatures for the classical big grain component which show a clear trend of decreasing temperature with increasing 200-μm emission. The 200-μm emission per unit   AV   , however, does not drop at lower temperatures. This fact can be interpreted in terms of an increased far-infrared (FIR) emissivity of the big grains. We developed a two-component model including warm dust with the temperature of the diffuse interstellar medium (ISM) of   T = 17.5 K  , and cold dust with   T = 13.5 K  and FIR emissivity increased by a factor of >4. A mixture of the two components can reproduce the observed colour variations and the ratios   I 200/ AV   and  τ200/ AV   . The relative abundance of small grains with respect to the big grains shows significant variations from region to region at low column densities. However, in lines of sight of higher column density, our data indicate the disappearance of small grains, perhaps a signature of adsorption/coagulation of dust. The larger size and porous structure could also explain the increased FIR emissivity. Our results from eight independent regions suggest that these grains might be ubiquitous in the galactic ISM.  相似文献   

10.
We present measurements of several near-infrared emission lines from the nearby galaxy NGC 253. We have been able to measure four H2 lines across the circumnuclear starburst, from which we estimate the ortho- to para- ratio of excited H2 to be ∼2. This indicates that the bulk of the H2 emission arises from photodissociation regions (PDRs), rather than from shocks. This is the case across the entire region of active star formation.
As the H2 emission arises from PDRs, it is likely that the ratio of H2 to Brγ (the bright hydrogen recombination line) is a measure of the relative geometry of O and B stars and PDRs. Towards the nucleus of NGC 253 the geometry is deduced to be tightly clustered O and B stars in a few giant H  II regions that are encompassed by PDRs. Away from the nuclear region, the geometry becomes that of PDRs bathed in a relatively diffuse ultraviolet radiation field.
The rotation curves of 1–0 S(1) and Brγ suggest that the ionized gas is tracing a kinetic system different from that of the molecular gas in NGC 253, particularly away from the nucleus.  相似文献   

11.
To better understand the environment surrounding CO emission clumps in the Keyhole Nebula, we have made images of the region in H2 1–0 S(1) (2.122-μm) emission and polycyclic aromatic hydrocarbon (PAH) emission at 3.29 μm. Our results show that the H2 and PAH emission regions are morphologically similar, existing as several clumps, all of which correspond to CO emission clumps and dark optical features. The emission confirms the existence of photodissociation regions (PDRs) on the surface of the clumps. By comparing the velocity range of the CO emission with the optical appearance of the H2 and PAH emission, we present a model of the Keyhole Nebula whereby the most negative velocity clumps are in front of the ionization region, the clumps at intermediate velocities are in it and those which have the least negative velocities are at the far side. It may be that these clumps, which appear to have been swept up from molecular gas by the stellar winds from η  Car, are now being overrun by the ionization region and forming PDRs on their surfaces. These clumps comprise the last remnants of the ambient molecular cloud around η Car.  相似文献   

12.
Compact regions of enhanced HCO+ and NH3 emission have been detected close to a number of Herbig–Haro objects. An interpretation of these detections is the following: a transient clump within the molecular cloud has been irradiated by the shock that generates the Herbig–Haro object. The irradiation releases icy mantles from the grains within the transient clump and initiates a photochemistry. On the basis of this picture, we have developed an extensive chemical model which predicts that a wide range of species, other than NH3 and HCO+, should also be detectable. These include CH3OH, H2S, C3H4, H2CO, SO, SO2, H2CS and NS. The chemical effects should last ∼  104 yr  .  相似文献   

13.
The formation of H2 on a pristine olivine surface [forsterite (010)] is investigated computationally. Calculations show that the forsterite surface catalyzes H2 formation by providing chemisorption sites for H atoms. The chemisorption route allows for stepwise release of the reaction exothermicity and stronger coupling to the surface, which increases the efficiency of energy dissipation. This suggests that H2 formed on a pristine olivine surface should be much less rovibrationally excited than H2 formed on a graphite surface. Gas-phase H atoms impinging on the surface will first physisorb relatively strongly  ( E phys= 1240 K)  . The H atom can then migrate via desorption and re-adsorption, with a barrier equal to the adsorption energy. The barrier for a physisorbed H atom to become chemisorbed is equal to the physisorption energy, therefore there is almost no gas-phase barrier to chemisorption. An impinging gas-phase H atom can easily chemisorb  ( E chem= 12 200 K)  , creating a defect where a silicate O atom is protonated and a single electron resides on the surface above the adjacent magnesium ion. This defect directs any subsequent impinging H atoms to chemisorb strongly (39 800 K) on the surface electron site. The two adjacent chemisorbed atoms can subsequently recombine to form H2 via a barrier (5610 K) that is lower than the chemisorption energy of the second H atom. Alternatively, the adsorbed surface species can react with another incoming H atom to yield H2 and regenerate the surface electron site. This double chemisorption 'relay mechanism' catalyzes H2 formation on the olivine surface and is expected to attenuate the rovibrational excitation of H2 thus formed.  相似文献   

14.
The formation of molecular hydrogen  (H2)  in the interstellar medium takes place on the surfaces of dust grains. Hydrogen molecules play a role in gas-phase reactions that produce other molecules, some of which serve as coolants during gravitational collapse and star formation. Thus, the evaluation of the production rate of hydrogen molecules and its dependence on the physical conditions in the cloud are of great importance. Interstellar dust grains exhibit a broad size distribution in which the small grains capture most of the surface area. Recent studies have shown that the production efficiency strongly depends on the grain composition and temperature as well as on its size. In this paper, we present a formula that provides the total production rate of  H2  per unit volume in the cloud, taking into account the grain composition and temperature as well as the grain size distribution. The formula agrees very well with the master equation results. It shows that for a physically relevant range of grain temperatures, the production rate of  H2  is significantly enhanced due to their broad size distribution.  相似文献   

15.
A solid-state feature was detected at around 2175 cm−1 towards 30 embedded young stellar objects in spectra obtained using the Infrared Spectrometer and Array Camera at the European Southern Observatory Very Large Telescope. We present results from laboratory studies of CO adsorbed at the surface of zeolite wafers, where absorption bands were detected at 2177 and 2168 cm−1 (corresponding to CO chemisorbed at the zeolite surface) and 2130 cm−1 (corresponding to CO physisorbed at the zeolite surface), providing an excellent match to the observational data. We propose that the main carrier of the 2175-band is CO chemisorbed at bare surfaces of dust grains in the interstellar medium. This result provides the first direct evidence that gas–surface interactions do not have to result in the formation of ice mantles on interstellar dust. The strength of the 2175-band is estimated to be  ∼4 × 10−19 cm  molecule−1. The abundance of CO adsorbed at bare grain surfaces ranges from 0.06 to 0.16 relative to H2O ice, which is, at most, half of the abundance (relative to H2O ice) of CO residing in H2O-dominated ice environments. These findings imply that interstellar grains have a large (catalytically active) surface area, providing a refuge for interstellar species. Consequently, the potential exists for heterogeneous chemistry to occur involving CO molecules in unique surface chemistry pathways not currently considered in gas grain models of the interstellar medium.  相似文献   

16.
We have used the Australia Telescope Compact Array (ATCA) to make a sensitive  (5 σ ≃100 mJy)  search for maser emission from the 4765-MHz 2Π1/2   F =1→0  transition of OH. 55 star formation regions were searched and maser emission with a peak flux density in excess of 100 mJy was detected toward 14 sites, with 10 of these being new discoveries. In addition we observed the 4750-MHz 2Π1/2   F =1→1  transition towards a sample of star formation regions known to contain 1720-MHz OH masers, detecting marginal maser emission from G348.550−0.979. If confirmed this would be only the second maser discovered from this transition.
The occurrence of 4765-MHz OH maser emission accompanying 1720-MHz OH masers in a small number of well-studied star formation regions has led to a general perception in the literature that the two transitions favour similar physical conditions. Our search has found that the presence of the excited-state 6035-MHz OH transition is a much better predictor of 4765-MHz OH maser emission from the same region than 1720-MHz OH maser emission is. Combining our results with those of previous high-resolution observations of other OH transitions we have examined the published theoretical models of OH masers and find that none of them predicts any conditions in which the 1665-, 6035- and 4765-MHz transitions are inverted simultaneously.  相似文献   

17.
We have observed a large sample of compact planetary nebulae in the near-infrared to determine how the 21P–21S He  i line at 2.058 μm varies as a function of stellar effective temperature, T eff. The ratio of this line with H  i Br γ at 2.166 μm has often been used as a measure of the highest T eff present in a stellar cluster, and hence of whether there is a cut-off in the stellar initial mass function at high masses. However, recent photoionization modelling has revealed that the behaviour of this line is more complex than previously anticipated. Our work shows that in most aspects the photoionization models are correct. In particular, we confirm the weakening of the 21P–21S line as T eff increases beyond 40 000 K. However, in many cases the model underpredicts the observed ratio when we consider the detailed physical conditions in the individual planetary nebulae. Furthermore, there is evidence that there is still significant 21P–21S He  i line emission even in the planetary nebulae with very hot     central stars. It is clear from our work that this ratio cannot be considered as a reliable measure of effective temperature on its own.  相似文献   

18.
The photodissociation of surface species, caused by photons from the cosmic-ray-induced and background interstellar radiation fields, is incorporated into our combined gas-phase and grain-surface chemical models of quiescent dense interstellar cores. For the cores studied here, only cosmic-ray-induced photons are important. We find that photodissociation alters gas-phase and surface abundances mainly at large cloud ages (≳ 106–7 yr). The abundances of those surface species, such as H2O, that are readily reproduced on the surface following photodissociation are not strongly affected at any time. The abundances of surface species that are, on the other hand, reformed slowly via surface reactions possessing activation energy (e.g. CH3OH) are reduced, while the abundances of associated surface photoproducts (e.g. CO) increase. In the gas phase, inclusion of surface photodissociation tends to increase molecular abundances at late times, slightly improving the agreement with observation for TMC-1.  相似文献   

19.
The specific catalytic effect of a silica grain on the formation of methanol via the sequential addition of H atoms to CO adsorbed on the surface is investigated. A negatively charged defect on a siliceous edingtonite surface is found to reduce the gas phase barriers for the H + COads and H + H2C=Oads reactions by 770 and 399 K, respectively, when compared to the same reactions in the gas phase. The catalytic effect of negatively charged surface sites could also be applicable to the hydrogenation of other adsorbed unsaturated species. However, the activation energies on the surface defect are still too large (1150 and 2230 K) for CH3OH to form efficiently at 10–20 K in the interstellar medium via a classical mechanism. It is therefore suggested that quantum mechanical tunnelling through the activation barrier is required for these hydrogen addition reactions to proceed at such temperatures. The calculations show that because the adsorption energies of CO and H2C=O on the negatively charged defect are substantial, CH3OH may form efficiently during the warm-up period in star-forming regions.  相似文献   

20.
C18O J  = 2–1, C17O J  = 2–1 and [C  I ] 3P1–3P0 emission from the dense cold cloud B335 has been observed and modelled in order to determine the C/CO ratio. The observed ratio is compared with a prediction by Tarafdar who assumes a mechanism in which the CO dissociation is caused by photons of energy ∼ 13.8 eV. These were postulated by Sciama to result from the decay of dark matter neutrinos. Our value for the C/CO ratio sets an upper limit to the strength of the neutrino decay dissociation process, thus providing a significant datum for interstellar chemistry theory.  相似文献   

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