首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 46 毫秒
1.
The stability of subsurface Light Nonaqueous Phase Liquids (LNAPLs) is a key factor driving expectations for remedial measures at LNAPL sites. The conventional approach to resolving LNAPL stability has been to apply Darcy's Equation. This paper explores an alternative approach wherein single‐well tracer dilution tests with intermittent mixing are used to resolve LNAPL stability. As a first step, an implicit solution for single‐well intermittent mixing tracer dilution tests is derived. This includes key assumptions and limits on the allowable time between intermittent mixing events. Second, single‐well tracer dilution tests with intermittent mixing are conducted under conditions of known LNAPL flux. This includes a laboratory sand tank study and two field tests at active LNAPL recovery wells. Results from the sand tank studies indicate that LNAPL fluxes in wells can be transformed into formation fluxes using corrections for (1) LNAPL thicknesses in the well and formation and (2) convergence of flow to the well. Using the apparent convergence factor from the sand tank experiment, the average error between the known and measured LNAPL fluxes is 4%. Results from the field studies show nearly identical known and measured LNAPL fluxes at one well. At the second well the measured fluxes appear to exceed the known value by a factor of two. Agreement between the known and measured LNAPL fluxes, within a factor of two, indicates that single‐well tracer dilution tests with intermittent mixing can be a viable means of resolving LNAPL stability.  相似文献   

2.
  相似文献   

3.
Petroleum liquids, referred to as light non‐aqueous phase liquids (LNAPLs), are commonly found beneath petroleum facilities. Concerns with LNAPLs include migration into clean soils, migration beyond property boundaries, and discharges to surface water. Single‐well tracer dilution techniques were used to measure LNAPL fluxes through 50 wells at 7 field sites. A hydrophobic tracer was mixed into LNAPL in a well. Intensities of fluorescence associated with the tracer were measured over time using a spectrometer and a fiber optic cable. LNAPL fluxes were estimated using observed changes in the tracer concentrations over time. Measured LNAPL fluxes range from 0.006 to 2.6 m/year with a mean and median of 0.15 and 0.064 m/year, respectively. Measured LNAPL fluxes are two to four orders of magnitude smaller than a common groundwater flux of 30 m/year. Relationships between LNAPL fluxes and possible governing parameters were evaluated. Observed LNAPL fluxes are largely independent of LNAPL thickness in wells. Natural losses of LNAPL through dissolution, evaporation, and subsequent biodegradation, were estimated using a simple mass balance, measured LNAPL fluxes in wells, and an assumed stable LNAPL extent. The mean and median of the calculated loss rates were found to be 24.0 and 5.0 m3/ha/year, respectively. Mean and median losses are similar to values reported by others. Coupling observed LNAPL fluxes to observed rates of natural LNAPL depletion suggests that natural losses of LNAPL may be an important parameter controlling the overall extent of LNAPL bodies.  相似文献   

4.
Light nonaqueous phase liquid (LNAPL) tracer testing is a technique used to directly measure LNAPL flow in situ and evaluate LNAPL mobility and recoverability. The test method consists of adding a fluorescent oil‐soluble tracer to LNAPL within a well, isolating small volumes of LNAPL with known tracer concentrations for use as in‐well calibration standards, and measuring the rate of tracer concentration decline in the well over time. The test measures LNAPL flux through the well, which is directly related to LNAPL mobility and recoverability in the surrounding formation. Test results for a total of 29 wells at five sites are presented. Results from LNAPL tracer testing were comparable to results obtained through other methods, and the method offers a time‐averaged result measured over a relatively long period, in ambient conditions, and reflects the influences of heterogeneity and hydraulic changes. In some cases, tracer concentration decline followed unexpected patterns, and these data have led to a better understanding of test assumptions, mechanisms influencing tracer distribution, and options to improve test execution and data interpretation. Method improvements developed over the course of the field studies included refinement of pre‐test screening of LNAPL fluorescence and improvements to measurement equipment. Overall, the field studies confirmed the technical validity and usefulness of the LNAPL tracing technique to support LNAPL mobility and recoverability assessments.  相似文献   

5.
The objective of this study was to investigate whether 222Rn in groundwater can be used as a tracer for light non‐aqueous phase liquid (LNAPL) quantification at a field site treated by dual‐phase LNAPL removal. After the break of a pipeline, 5 ha of soil in the nature reserve Coussouls de Crau in southern France was contaminated by 5100 m3 of crude oil. Part of this oil seeped into the underlying gravel aquifer and formed a floating oil body of about 3.9 ha. The remediation consists of plume management by hydraulic groundwater barriers and LNAPL extraction in the source zone. 222Rn measurements were performed in 21 wells in and outside the source zone during 15 months. In uncontaminated groundwater, the radon activity was relatively constant and remained always >11 Bq/L. The variability of radon activity measurements in wells affected by the pump‐and‐skim system was consistent with the measurements in wells that were not impacted by the system. The mean activities in wells in the source zone were, in general, significantly lower than in wells upgradient of the source zone, owing to partitioning of 222Rn into the oil phase. The lowest activities were found in zones with high non‐aqueous phase liquid (NAPL) recovery. LNAPL saturations around each recovery well were furthermore calculated during a period of high groundwater level, using a laboratory‐determined crude oil–water partitioning coefficient of 38.5 ± 2.9. This yielded an estimated volume of residual crude oil of 309 ± 93 m3 below the capillary fringe. We find that 222Rn is a useful and cheap groundwater tracer for finding zones of good LNAPL recovery in an aquifer treated by dual‐phase LNAPL removal, but that quantification of NAPL saturation using Rn is highly uncertain.  相似文献   

6.
Recent research has demonstrated the use of in‐well heat tracer tests monitored by a fiber optic distributed temperature sensing (DTS) system to characterize borehole flow conditions in open bedrock boreholes. However, the accuracy of borehole flow rates determined from in‐well heat tracer tests has not been evaluated. The purpose of the research presented here is to determine whether borehole flow rates obtained using DTS‐monitored in‐well heat tracer tests are reasonable, and to evaluate the range of flow rates measureable with this method. To accomplish this, borehole flow rates measured using in‐well heat tracer tests are compared to borehole flow rates measured in the same boreholes using an impeller or heat pulse flowmeter. A comparison of flow rates measured using in‐well heat tracer tests to flow rates measured with an impeller flowmeter under the same conditions showed good agreement. A comparison of in‐well heat tracer test flow rate measurements to previously‐collected heat pulse flowmeter measurements indicates that the heat tracer test results produced borehole flow rates and flow profiles similar to those measured with the heat pulse flowmeter. The results of this study indicate that borehole flow rates determined from DTS‐monitored in‐well heat tracer tests are reasonable estimates of actual borehole flow rates. In addition, the range of borehole flow rates measurable by in‐well heat tracer tests spans from less than 10?1 m/min to approximately 101 m/min, overlapping the ranges typically measurable with an impeller flowmeter or a heat pulse flowmeter, making in‐well heat tracer testing a versatile borehole flow logging tool.  相似文献   

7.
Lost circulation, the inadvertent injection of drilling fluids into a highly permeable and/or fractured aquifer during rotary drilling, may result in collection of spurious information if the lost drilling fluids are not adequately purged before sampling the ground water. The purpose of this study was to determine whether removal of the volume of water lost during coring of a monitoring well in the carbonate Scotch Grove Formation (Silurian, east central Iowa) necessarily ensures collection of representative ground water samples. To monitor dilution of the ground water due to lost circulation, rhodamine dye was added to the drilling water and dye recovery was measured in samples collected during purging of five separate 5- to 10-foot intervals.
Circulation loss occurred in all five intervals, ranging from nearly 200 gallons in the upper permeable portion of the Scotch Grove to 25 gallons in the less permeable Buck Creek Member below. When the volume of water purged from the upper three intervals corresponded to the volume of water lost during coring, the purge water still contained 11 to 20 percent dyed drilling water. As purging continued, the proportion of drilling water in the samples decreased slowly. After purging more than 200 gallons of water, 86 to 98 percent of the dyed drilling water was recovered from the five test intervals. Four traditionally measured water quality parameters-pH, temperature, specific conductance, and dissolved oxygen — were less useful than the dye recovery for distinguishing drilling water from formation water in those zones in which the ground water quality was similar to the drilling water. These results indicate that the determination of the quantity of water to be purged prior to sampling must be based, at least in part, on aquifer lithology and hydraulic characteristics.  相似文献   

8.
A field tracer test was carried out in a light nonaqueous phase liquid (LNAPL) source zone using a well pattern consisting of one injection well surrounded by four extraction wells (5‐spot well pattern). Multilevel sampling was carried out in two observation wells located inside the test cell characterized by heterogeneous lithology. Tracer breakthrough curves showed relatively uniform flow within soil layers. A numerical flow and solute transport model was calibrated on hydraulic heads and tracer breakthrough curves. The model was used to estimate an average accessible porosity of 0.115 for the swept zone and an average longitudinal dispersivity of 0.55 m. The model was further used to optimize the relative effects of viscous forces versus capillary forces under realistic imposed hydraulic gradients and to establish optimal surfactant solution properties. Maximum capillary number (NCa) values between injection and extraction wells were obtained for an injection flow rate of 16 L/min, a total extraction flow rate of 20 L/min, and a surfactant solution with a viscosity of 0.005 Pa?s. The unconfined nature of the aquifer limited further flow rate or viscosity increases that would have led to unrealistic hydraulic gradients. An NCa range of 3.8 × 10?4 to 7.6 × 10?3 was obtained depending on the magnitude of the simulated LNAPL‐water interfacial tension reduction. Finally, surfactant and chase water slug sizing was optimized with a radial form of the simplified Ogata‐Banks analytical solution (Ogata and Banks 1961) so that injected concentrations could be maintained in the entire 5‐spot cell.  相似文献   

9.
A new tracer experiment (referred to as MADE‐5) was conducted at the well‐known Macrodispersion Experiment (MADE) site to investigate the influence of small‐scale mass‐transfer and dispersion processes on well‐to‐well transport. The test was performed under dipole forced‐gradient flow conditions and concentrations were monitored in an extraction well and in two multilevel sampler (MLS) wells located at 6, 1.5, and 3.75 m from the source, respectively. The shape of the breakthrough curve (BTC) measured at the extraction well is strongly asymmetric showing a rapidly arriving peak and an extensive late‐time tail. The BTCs measured at seven different depths in the two MLSs are radically different from one another in terms of shape, arrival times, and magnitude of the concentration peaks. All of these characteristics indicate the presence of a complex network of preferential flow pathways controlling solute transport at the test site. Field‐experimental data were also used to evaluate two transport models: a stochastic advection‐dispersion model (ADM) based on conditional multivariate Gaussian realizations of the hydraulic conductivity field and a dual‐domain single‐rate (DDSR) mass‐transfer model based on a deterministic reconstruction of the aquifer heterogeneity. Unlike the stochastic ADM realizations, the DDSR accurately predicted the magnitude of the concentration peak and its arrival time (within a 1.5% error). For the multilevel BTCs between the injection and extraction wells, neither model reproduced the observed values, indicating that a high‐resolution characterization of the aquifer heterogeneity at the subdecimeter scale would be needed to fully capture 3D transport details.  相似文献   

10.
To improve quantitative understanding of mixed‐land‐use impacts on nutrient yields, a nested‐scale experimental watershed study design (n = 5) was applied in a 303(d), clean water act impaired urbanizing watershed of the lower Missouri River Basin, USA. From 2010 to 2013, water samples (n = 858 sample days per site) were analysed for total inorganic nitrogen (TIN‐N), nitrite (NO2–N) nitrate (NO3–N), ammonia (NH3–N), and total phosphorus (TP‐P). Annual, seasonal, and monthly flow‐weighted concentrations (FWCs) and nutrient yields were estimated. Mean nutrient concentrations were highest where agricultural land use comprised 58% of the drainage area (NH3 = 0.111 mg/l; NO2 = 0.045 mg/l; NO3 = 0.684 mg/l, TIN = 0.840 mg/l; TP = 0.127 mg/l). Average TP‐P increased by 15% with 20% increased urban land use area. Highly variable annual precipitation was observed during the study with highest nutrient yields during 2010 (record setting wet year) and lowest nutrient yields during 2012 (extreme drought year). Annual TIN‐N and TP‐P yields exceeded 10.3 and 2.04 kg ha?1 yr?1 from the agricultural dominated headwaters. Mean annual NH3–N, NO2–N, NO3–N, TIN‐N, and TP‐P yields were 0.742, 0.400, 4.24, 5.38, and 0.979 kg ha?1 yr?1, respectively near the watershed outlet. Precipitation accounted for the majority of the explained variance in nutrient yields (R2 values from 0.68 to 0.85). Nutrient yields were also dependent on annual precipitation of the preceding year (R2 values from 0.87 to 0.91) thus enforcing the great complexity of variable mixed‐land‐use mediated source‐sink nutrient yield relationships. Study results better inform land managers and best management practices designed to mitigate nutrient pollution issues in mixed‐land‐use freshwater ecosystems. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

11.
Karst aquifers are susceptible to contamination by microorganisms, but relatively few studies have used bacteria as tracers. We demonstrate the utility of Escherichia coli enriched in the stable isotope nitrogen‐15 (15N) as a novel bacterial tracer. Nonpathogenic E. coli from two springs in central Kentucky were grown on 15N‐enriched media. Survival of E. coli and persistence of the isotopic signal were assessed in two sets of laboratory experiments conducted with sterilized spring water in dark microcosms at 14 °C. First, isotopically labeled bacteria survived for 130 d at concentrations within one log unit of the average initial value, and there was no significant difference in δ15N values from Day 1 to Day 130. Second, water samples with E. coli were inoculated with either of two different species of protozoa (Tetrahymena pyriformis or Colpoda steinii). During 7 d, δ15N values increased in T. pyriformis while bacterial populations decreased. In a field test, following a 2.1‐cm rainfall, 15N‐labeled E. coli, solutes (rhodamine WT dye and bromide), and latex microspheres were injected into a sinkhole approximately 530 m upgradient of a spring. Breakthrough of all tracers coincided, but microspheres were remobilized by subsequent storms, unlike other tracers. Enriched E. coli exhibited more tailing than solute tracers during the initial storm‐flow recession. These results indicate that 15N‐enriched E. coli is a viable tracer of bacterial transport in karst aquifers, although predation may attenuate the isotopic signal in systems that are not rapidly flushed.  相似文献   

12.
The impact of nonlinear flow phenomena on well response tests is still not completely understood today. With the present paper, a set of 10 well response tests is investigated. The tests were conducted in a fractured Devonian limestone formation close to the western national border of Germany. The test design incorporates a packer as well as different solid cylinders to initiate a series of slug‐injection and slug‐withdrawal tests by various initial displacements. Nonlinear response characteristics were observed in the course of the tests, which cannot be explained by tubing‐controlled flow inside the cased well. The analysis shows that the nonlinear response characteristics are likely to be either formation controlled according to non‐Darcian flow developing in a high‐conductivity fracture compartment of the tested limestone formation or a consequence of a severe well inefficiency caused by some sort of screen clogging. This inference is obtained from analyzing the data by a nonlinear well response test model, which differentiates between wellbore internal hydraulic head losses and a generalized rate‐dependent skin effect accounting for nonlinear flow processes in the vicinity of the well. The potential of identifying near‐well nonlinear flow by various displacement well response testing may indicate this methodology to be a valuable complement to modern high‐resolution borehole imaging techniques used when characterizing fractured reservoirs and the tightness of fractured reservoir cap rocks.  相似文献   

13.
  相似文献   

14.
Steady interface flow in heterogeneous aquifer systems is simulated with single‐density groundwater codes by using transformed values for the hydraulic conductivity and thickness of the aquifers and aquitards. For example, unconfined interface flow may be simulated with a transformed model by setting the base of the aquifer to sea level and by multiplying the hydraulic conductivity with 41 (for sea water density of 1025 kg/m3). Similar transformations are derived for unconfined interface flow with a finite aquifer base and for confined multi‐aquifer interface flow. The head and flow distribution are identical in the transformed and original model domains. The location of the interface is obtained through application of the Ghyben‐Herzberg formula. The transformed problem may be solved with a single‐density code that is able to simulate unconfined flow where the saturated thickness is a linear function of the head and, depending on the boundary conditions, the code needs to be able to simulate dry cells where the saturated thickness is zero. For multi‐aquifer interface flow, an additional requirement is that the code must be able to handle vertical leakage in situations where flow in an aquifer is unconfined while there is also flow in the aquifer directly above it. Specific examples and limitations are discussed for the application of the approach with MODFLOW. Comparisons between exact interface flow solutions and MODFLOW solutions of the transformed model domain show good agreement. The presented approach is an efficient alternative to running transient sea water intrusion models until steady state is reached.  相似文献   

15.
  相似文献   

16.
Optimization of groundwater and other subsurface resources requires analysis of multiple‐well systems. The usual modeling approach is to apply a linear flow equation (e.g., Darcy's law in confined aquifers). In such conditions, the composite response of a system of wells can be determined by summating responses of the individual wells (the principle of superposition). However, if the flow velocity increases, the nonlinear losses become important in the near‐well region and the principle of superposition is no longer valid. This article presents an alternative method for applying analytical solutions of non‐Darcy flow for a single‐ to multiple‐well systems. The method focuses on the response of the central injection well located in an array of equally spaced wells, as it is the well that exhibits the highest pressure change within the system. This critical well can be represented as a single well situated in the center of a closed square domain, the width of which is equal to the well spacing. It is hypothesized that a single well situated in a circular region of the equivalent plan area adequately represents such a system. A test case is presented and compared with a finite‐difference solution for the original problem, assuming that the flow is governed by the nonlinear Forchheimer equation.  相似文献   

17.
Magnetite is a natural component of many aquifers. Abiotic degradation of chlorinated solvents by magnetite can be an important mechanism for natural attenuation of these contaminants. The quantity of magnetite in aquifer materials can be estimated by measuring the magnetic susceptibility of the materials. This is most commonly done by determining the magnetic susceptibility of core samples in an analytical laboratory using a magnetic susceptibility meter. Unfortunately, the cost of acquiring core samples often makes an evaluation of abiotic degradation by magnetite economically unrealistic. Downhole sondes (probes) are available for the determination of magnetic susceptibility. In this study, a downhole sonde was evaluated as an affordable alternative to acquiring and analyzing core samples. The sonde was introduced into 10 monitoring wells. The data from the sonde were then compared to data from core samples that were collected from the same elevation as the sonde data. The core samples analyzed in the laboratory were used as the standard against which the sonde data were compared. The downhole sonde reported values that were similar to values reported on core samples. At most wells, the means of the two measurements could not be distinguished at the 95% confidence interval. When the means could be distinguished, they still agreed within a factor of two.  相似文献   

18.
A numerical model is proposed that describes the interaction between raindrops and water vapour near the planetary boundary layer to explain the “amount effect”. This model relates the intensity to the isotopic composition of precipitation. The model resolves raindrop sizes, and explicitly includes: (1) the isotopic equilibration time of raindrops that is drop‐size dependent; (2) raindrop transit times through the atmosphere; and (3) the evolution of the isotopic composition of vapour at various rain rates. At high rain rate, the precipitation through a layer is less equilibrated with the vapour because the isotopic equilibration time is long compared to the fast transit time, and there is a preponderance of large drops, which take longer to equilibrate. The δ18O of vapour in the lower atmosphere becomes lower as a result of the interaction with these raindrops of low δ18O, and the degree of depletion of 18O is higher when precipitation rates are high. The model reproduces time‐series observations of isotopic composition of precipitation in Japan, and a vapour replenishment rate is inferred by either advection or evaporation of about 5% of the precipitation rate. The results could be the basis for a new parameterization of the isotopic equilibration for different precipitation types and rates in General Circulation Models (GCMs). When the model is applied to a GCM, this parameterization is important for places where precipitation occurs at cold temperatures (<15 °C). Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

19.
In this article, we present a straightforward random walk model for fast evaluation of push‐pull tracer tests. By developing an adaptive algorithm, we overcome the problem of manually defining how many particles have to be used to simulate the transport problem. Beside this, we validate the random walk model by evaluating a push‐pull tracer test with drift phase and confirm the results with MT3DMS. The random walk model took less than 1% of computational time of MT3DMS, thus allowing a remarkable faster evaluation of push‐pull tracer tests.  相似文献   

20.
We have investigated non‐Darcian flow to a vertical fracture represented as an extended well using a linearization procedure and a finite difference method in this study. Approximate analytical solutions have been obtained with and without the consideration of fracture storage based on the linearization procedure. A numerical solution for such a non‐Darcian flow case has also been obtained with a finite difference method. We have compared the numerical solution with the approximate analytical solutions obtained by the linearization method and the Boltzmann transform. The results indicate that the linearized solution agrees generally well with the numerical solution at late times, and underestimates the dimensionless drawdown at early times, no matter if the fracture storage is considered or not. When the fracture storage is excluded, the Boltzmann transform solution overestimates the dimensionless drawdown during the entire pumping period. The dimensionless drawdowns in the fracture with fracture storage for different values of dimensionless non‐Darcian hydraulic conductivity β approach the same asymptotic value at early times. A larger β value results in a smaller dimensionless drawdown in both the fracture and the aquifer when the fracture storage is included. The dimensionless drawdown is approximately proportional to the square root of the dimensionless time at late times.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号