The influence of pH on Mg/Ca ratios is negligible at ambient seawater pH (8.1 to 8.3). However, we observe a dominating pH control on shell Mg/Ca when the pH of seawater is lower than 8.0. Sr/Ca in G. ruber shows a significant positive correlation with average growth rate. Presumably, part of the variability in shell Sr/Ca in the geological record is linked to changes in growth rates of foraminifera as a response to changing environmental conditions.  相似文献   

12.
Loading effect of a self-consistent equilibrium ocean pole tide on the gravimetric parameters of the gravity pole tides at superconducting gravimeter stations     
Xiaodong Chen  Bernard Ducarme  Heping Sun  Jianqiao Xu   《Journal of Geodynamics》2008,45(4-5):201-207
The gravimetric parameters of the gravity pole tide are the amplitude factor δ, which is the ratio of gravity variations induced by polar motion for a real Earth to variations computed for a rigid one, and the phase difference κ between the observed and the rigid gravity pole tide. They can be estimated from the records of superconducting gravimeters (SGs). However, they are affected by the loading effect of the ocean pole tide. Recent results from TOPEX/Poseidon (TP) altimeter confirm that the ocean pole tide has a self-consistent equilibrium response. Accordingly, we calculate the gravity loading effects as well as their influence on the gravimetric parameters of gravity pole tide at all the 26 SG stations in the world on the assumption of a self-consistent equilibrium ocean pole tide model. The gravity loading effect is evaluated between 1 January 1997 and 31 December 2006. Numerical results show that the amplitude of the gravity loading effect reaches 10−9 m s−2, which is larger than the accuracy (10−10 m s−2) of a SG. The gravimetric factor δ is 1% larger at all SG stations. Then, the contribution of a self-consistent ocean pole tide to the pole tide gravimetric parameters cannot be ignored as it exceeds the current accuracy of the estimation of the pole tide gravity factors. For the nine stations studied in Ducarme et al. [Ducarme, B., Venedikov, A.P., Arnoso, J., et al., 2006. Global analysis of the GGP superconducting gravimeters network for the estimation of the pole tide gravimetric amplitude factor. J. Geodyn. 41, 334–344.], the mean of the modeled tidal factors δm = 1.1813 agrees very well with the result of a global analysis δCH = 1.1816 ± 0.0047 in that paper. On the other hand, the modeled phase difference κm varies from −0.273° to 0.351°. Comparing to the two main periods of the gravity pole tide, annual period and Chandler period, κm is too small to be considered. Therefore, The computed time difference κL induced by a self-consistent ocean pole tide produces a negligible effect on κm. It confirms the results of Ducarme et al., 2006, where no convincing time difference was found in the SG records.  相似文献   

13.
High-resolution garnet chronometry and the rates of metamorphic processes     
Kevin W. Burton  R. Keith O'Nions 《Earth and Planetary Science Letters》1991,107(3-4)
Garnets in an amphibolite-facies metasediment from Sulitjelma, North Norway yield precise and concordant SmNd, UPb and RbSr ages that relate directly to the pressure (P) and temperature (T) conditions of mineral growth. Differential mineral reaction between graphitic and non-graphitic layers within this sample preserves a record of theP-T and time (t) history experienced during Barrovian regional metamorphism. Garnets in graphitic layers grew during prograde metamorphism at462 ± 16°C and5.2 ± 0.5 kbar under conditions of lowaH2O, and yield indistinguishable147Sm143Nd and238U206Pb ages of434.1 ± 1.2 Ma and433.9 ± 1.0 Ma, respectively. In contrast, garnet growth in adjacent graphite-free layers did not occur untilP-T conditions of540 ± 18°C and8.0 ± 1.0 kbar were attained, with continued growth in response to minor heating and decompression with final matrix equilibration at544 ± 16°C and7.0 ± 1.0 kbar. The inclusion-free garnet rims in this assemblage record indistinguishable147Sm143Nd and238U206Pb ages of424.6 ± 1.2 Ma and423.4± 1.7 Ma, respectively. These results provide precise estimates for average heating and burial rates during prograde metamorphism of 8.6−4.4+7.5°C Ma−1 and 0.8−0.5+0.9 km Ma−1, respectively. Rb and Sr exchange between coexisting silicates in the graphite-free assemblage continued for some 37 Ma after the “peak” of metamorphism, and require an average cooling rate of about 4.0°C Ma−1 during uplift. These results illustrate a clear relationship between reaction history and the timing of mineral growth and provide definitive constraints on the rates of thermal and tectonic processes accompanying regional metamorphism.  相似文献   

14.
Imprinting chemical remanent magnetization in claystones at 95 °C     
C. Aubourg  J.P. Pozzi  D. Janots  L. Sahraoui   《Earth and Planetary Science Letters》2008,272(1-2):172-180
Thermal effects related to burial and hydrothermal alteration leads to chemical remanent magnetization (CRM). We present an experimental study of CRM production by heating claystones at 95 °C. A vertical magnetic field of 2 mT was applied to the claystones during heating and the evolution of the remanence during heating in air is monitored intermittently for up to four months. Solid fragments (9 to 26 g) of claystones are included in a Teflon holder that is placed in the oven under a controlled atmosphere. Newly formed grains acquire a CRM and a thermoviscous magnetization (TVRM), both being parallel to the applied magnetic field. CRM is related to the amount of newly formed grains that pass the critical volume during the reaction. To measure the acquired remanence, the claystones are first cooled in a zero magnetic field and then measured using a 2G SQUID magnetometer.In the frame of the research programme on the feasibility of radioactive waste disposal in a deep geological formation, we investigate the magnetic transformation of Mont Terri Lower Dogger claystones (Switzerland) due to thermal imprinting at 95 °C. We simulate the dehydration that occurs in the walls of galleries after excavation when interstitial water evaporates and rehydration when the galleries are refilled allowing water to move towards dehydrated zones. During dehydration, the remanence gains one order of magnitude at the beginning of the experiment and then it follows a linear rate of 0.23 ± 0.07 mA m− 1/day between 3 and 14 days. The magnetic susceptibility increases by a few percent. The increase of the remanence and of the magnetic susceptibility stops after 15 days. Mass monitoring indicates that interstitial water evaporates when remanence and magnetic susceptibility stabilizes. During rehydration, the remanence increases again whilst magnetic susceptibility drops by a few percent. After 20 days, the remanence during rehydration follows a rate of 0.42 ± 0.15 mA m− 1/day. By contrast, when rehydration takes place later, after 66 days, the rate is much lower (0.09 ± 0.04 mA m− 1/day). Low temperature investigation of magnetic properties indicates an initial magnetic assemblage of magnetite and pyrrhotite. Newly formed magnetite and hematite carry the remanence. We propose that magnetite is formed at the expense of pyrite. Hematite results from the progressive oxidation of newly formed magnetite. Our results suggest the possibility that any claystones that pass the oil window can be remagnetized due to the unique action of temperature.  相似文献   

15.
Glacial–interglacial sediment transport to the Meiji Drift,northwest Pacific Ocean: Evidence for timing of Beringian outwashing     
Sam VanLaningham  Nicklas G. Pisias  Robert A. Duncan  Peter D. Clift 《Earth and Planetary Science Letters》2009,277(1-2):64-72
A large sediment deposit known as the Meiji Drift, located in the northwestern Pacific Ocean, is thought to have formed from deep water exiting the Bering Sea, although no notable deep water forms there presently. We determine the terrigenous sources since 140 ka to the drift using bulk sediment 40Ar–39Ar and Nd isotopic analyses on the silt-sized (20–63 μm) terrigenous fraction from Ocean Drilling Program (ODP) Site 884 to reconstruct paleo-circulation patterns. There are large changes in both isotopic tracers, varying on glacial–interglacial cycles. During glacial intervals, bulk sediment 40Ar–39Ar ages range between 40 and 80 Ma, while Nd isotopic values range from εNd = ? 1 to + 2. During interglacial intervals, sediments become much younger and more radiogenic, with bulk sediment ages falling to 2–15 Ma and Nd isotopic values ranging between εNd = + 5 and + 9. These data and quantitative comparison to potential source rocks indicate that the young Kamchatkan and Aleutian Arcs, lying NW and NE of the Meiji Drift, contribute the majority of sediment during interglacials. Conversely, older source rocks, such as those drained by the Yukon River and northeast Russia are the dominant origin of sediments during glacials. Mixing model calculations suggest that as much as 35–45% of the sediment deposited in the Meiji Drift during glacials is from the Bering Sea. It remains unclear whether thermohaline-type circulation or focussing of Bering Sea flow lead to the glacial–interglacial sediment source changes observed here.  相似文献   

16.
Leaf breakdown in two tropical streams: Differences between single and mixed species packs     
Marcelo Moretti  Jos Francisco Gonalves Jr.  Marcos Callisto 《Limnologica》2007,37(3):250-258
We assessed leaf breakdown of five native riparian species from Brazilian Cerrado (Myrcia guyanensis, Ocotea sp., Miconia chartacea, Protium brasiliense, and Protium heptaphyllum), incubated in single and mixed species packs in two headwater streams with different physico-chemical properties in the Espinhaço Mountain range (Southeastern Brazil). Leaves were placed in plastic litter bags (15 cm×20 cm, 10 mm mesh size) and the experiments were carried out during the dry seasons of 2003 and 2004. Leaf nitrogen and phosphorus contents were similar in all species, but polyphenolic contents were different (P<0.001). M. guyanensis showed higher polyphenolics content (8.48% g−1 dry mass) and leaf toughness. Individually, higher breakdown rates were found in M. guyanensis at Indaiá stream (k=0.0063±0.0005 d−1) and in Ocotea sp. at Garcia stream (k=0.0088±0.0006 d−1). However, P. brasiliense and P. heptaphyllum showed lower breakdown rates at Indaiá and Garcia streams (Indaiá: k=0.0020±0.0002 and 0.0019±0.0001 d−1; Garcia: k=0.0042±0.0001 and 0.0040±0.0002 d−1). Single and mixed breakdown processes of each species were not statistically different on both streams. However, all species showed higher breakdown rates at Garcia stream (P<0.01). These results suggest that leaf breakdown is not altered when litter benthic patches are composed by a mixture of species in the same proportions that they occur on riparian leaf falls.  相似文献   

17.
Viscosity measurements of subliquidus magmas: Alkali olivine basalt from the Higashi-Matsuura district, Southwest Japan   总被引：3，自引：0，他引：3  
Hidemi Ishibashi  Hiroaki Sato 《Journal of Volcanology and Geothermal Research》2007,160(3-4):223-238
We carried out viscosity measurements and sampling of a crystal suspension derived from alkali olivine basalt from the Matsuura district, SW Japan, at subliquidus temperatures from 1230 °C to 1140 °C under 1 atm with NNO oxygen buffered conditions. Viscosity increased from 31 to 1235 Pa s with a decrease in temperature from 1230 to 1140 °C. On cooling, olivine first appeared at 1210 °C, followed by plagioclase at 1170 °C. The crystal content of the sample attained 31 vol.% at 1140 °C (plagioclase 22%, olivine 9%). Non-Newtonian behaviors, including thixotropy and shear thinning, were pronounced in the presence of tabular plagioclase crystals. The cause of such behavior is discussed in relation to shear-induced changes in melt–crystal textures. Relative viscosities, ηr (= ηs / ηm, where ηs and ηm are the viscosities of the suspension and the melt, respectively), were obtained by calculating melt viscosities from the melt composition and temperature at 1 atm using the equation proposed by Giordano and Dingwell [Giordano, D., Dingwell, D.B., 2003. Non-Arrhenian multicomponent melt viscosity: a model. Earth and Planetary Science Letters, 208, 337–349.]. The obtained relative viscosities are generally consistent with the Einstein–Roscoe relation, which represents ηr for suspensions that contain equant and equigranular crystals, even though the crystal suspension analyzed in the present experiments contained tabular plagioclase and granular olivine of various grain sizes. This consistency is attributed to the fact that the effect of crystal shape was counterbalanced by the effect of the dispersion of crystal size. The applicability of the Einstein–Roscoe equation with respect to crystal shape is discussed on the basis of the present experimental results. Our experiments and those of Sato [Sato, H., 2005. Viscosity measurement of subliquidus magmas: 1707 basalt of Fuji volcano. Journal of Mineralogical and Petrological Sciences, 100, 133–142.] show that the relationship between relative viscosity and crystal fraction is consistent with the Einstein–Roscoe relationship for axial ratios that are smaller than the critical value of 4–6.5, but discrepancies occur for higher ratios.  相似文献   

18.
Efficient trapping of organic carbon in sediments on the continental margin with high fluvial sediment input off southwestern Taiwan   总被引：2，自引：0，他引：2  
Shuh-Ji Kao  Fuh-Kwo Shiah  Chung-Ho Wang  Kon-Kee Liu   《Continental Shelf Research》2006,26(20):2520-2537
Accumulation rates of marine and terrigenous organic carbon in the continental margin sediments off southwestern Taiwan were estimated from the measured concentrations and isotopic compositions of total organic carbon (TOC) and previously reported sedimentation rates. Surficial sediments were collected from the study area spanning from the narrow shelf near the Kaoping River mouth to the deep slope with depths reaching almost 3000 m. The average sediment loading of Kaoping River is 17 Mt/yr, which yields high sediment accumulation rates ranging from 0.08 to 1.44 g cm−2 yr−1 in the continental margin. About half of the discharged sediments were deposited on the margin within 120 km of the river mouth. Carbon isotopic compositions of terrestrial and marine end-members of organic matter were determined, respectively, based on suspended particulate matter (SPM) collected from three major rivers in the southwestern Taiwan and from an offshore station. All samples were analyzed for the TOC content and its isotopic composition (δ13Corg). The SPM samples were also analyzed for the total nitrogen (TN) content. TOC content in marine sediments ranges from 0.45% to 1.35% with the highest values on the upper slope near the Kaoping River mouth. The TOC/TN ratio of the SPM samples from the offshore station is 6.8±0.6, almost identical to the Redfield ratio, indicating their predominantly marine origin; their δ13Corg values are also typically marine with a mean of −21.5±0.3‰. The riverine SPM samples exhibit typical terrestrial δ13Corg values around −25‰. The δ13Corg values of surficial sediments range from −24.8‰ to −21.2‰, showing a distribution pattern influenced by inputs from the Kaoping River. The relative contributions from marine and terrestrial sources to sedimentary organic carbon were determined by the isotope mixing model with end-member compositions derived from the riverine and marine SPM. High fluvial sediment inputs lead to efficient trapping of organic carbon over a wide range of water depth in this continental margin. The marine organic accumulation rate ranges from 1.6 to 70 g C m−2 yr−1 with an area weighted mean of 4.2 g C m−2 yr−1, which is on a par with the mean terrestrial contribution and accounts for 2.3% of mean primary production. The depth-dependent accumulation rate of marine organic carbon can be simulated with a function involving primary productivity and mineral accumulation rate, which may be applicable to other continental margins with high sedimentation rates. Away from the nearshore area, the content of terrigenous organic carbon in surficial sediments decreases with distance from the river mouth, indicating its degradation in marine environments.  相似文献   

19.
Respiratory adaptations to oxygen lack in three species of Glossiphoniidae (Hirudinea) in Lake Esrom, Denmark     
Bettina Pohle  Kirsten Hamburger   《Limnologica》2005,35(1-2):78-89
The weight-specific respiration rate (μl O2 mg−1 AFDW h−1) of three species of leech from Lake Esrom, Denmark, Glossiphonia concolor, G. complanata and Helobdella stagnalis was measured in a closed stirred chamber with a micro electrode. At declining oxygen concentration (mg O2 l−1) all three species expressed moderate ability to regulate respiration, in G. concolor and G. complanata down to 2 mg O2 l−1, in H. stagnalis down to 0.75 mg O2 l−1. Survival in anoxia was measured in closed bottles. The time to 50% survival (LD50) was 30 days in G. concolor at 20 °C and 30 and 4 days in H. stagnalis at 10 and 20 °C, respectively. The results were discussed in relation to habitat and spatial distribution of the three species in the lake.  相似文献   

20.
Oxygen diffusion rates in quartz exchanged with CO2     
Z.D. Sharp  B.J. Giletti  H.S. Yoder Jr. 《Earth and Planetary Science Letters》1991,107(2)
Oxygen self diffusion rates were determined in quartz samples exchanged with18O-enriched CO2 between 745 and 900°C and various pressures, and the diffusion profiles were measured using an ion microprobe. The activation energy (Q) and preexponential factor (D0) at P(CO2) = P(tot) = 100 bar, for diffusion parallel to the c-axis are 159 ( ± 13) kJ/g atom and 2.10 (+0.75/ −0.55) × 10−8 cm2/s. This rate is approximately 100 times slower than that obtained from hydrothermal experiments and 100 times faster than a previous 1-bar quartz-O2 exchange experiment. The oxygen diffusion rate measured at 0.6 bar, 888°C, and at 900°C in vacuum is in agreement with the previous 1-bar exchange experiments with18O2. The effect of higher CO2 pressures is small. At 900°C, the diffusion rate exchanged with CO2 is = 2.35 × 10−15 cm2/s at 100 bar, 2.24 × 10−15 cm2/s at 3.45 kbar and 8.13 × 10−15 cm2/s at 7.2 kbar.There is probably a diffusing species, other than oxygen, that enhances the oxygen diffusion rate in these quartz-CO2 systems, relative to that occurring at very low pressures or in a vacuum. The effect of this diffusing species, however, is not as strong as that associated with H2O. Preserved oxygen isotope fractionations between coexisting minerals in a slowly cooled, high-grade metamorphic terrane will vary depending upon whether a water-rich phase was present or not. Closure temperatures will be approximately 100°C higher in rocks where no water-rich phase was present during cooling. The measured fractionations between coexisting minerals in metamorphic rocks may potentially be used as a sensor of water presence during retrogression.  相似文献   

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1.
Hydrothermal emission of mantle helium appears to be directly related to magma production rate, but other processes can generate methane and hydrogen on mid-ocean ridges. In an on-going effort to characterize these processes in the South Atlantic, the flux and distribution of these gases were investigated in the vicinity of a powerful black smoker recently discovered at 8°17.9' S, 13°30.4' W. The vent lies on the shoulder of an oblique offset in the Mid-Atlantic Ridge and discharges high concentrations of methane and hydrogen. Measurements during expeditions in 2004 and 2006 show that the ratio of CH4 to 3He in the neutrally buoyant plume is quite high, 4 × 108. The CTD stations were accompanied by velocity measurements with lowered acoustic Doppler current profilers (LADCP), and from these data we estimate the methane transport to have been 0.5 mol s− 1 in a WSW-trending plume that seems to develop during the ebb tidal phase. This transport is an order of magnitude greater than the source of CH4 calculated from its concentration in the vent fluid and the rise height of the plume. From this range of methane fluxes, the source of 3He is estimated to be between 0.14 and 1.2 nmol s− 1. In either case, the 3He source is significantly lower than expected from the spreading rate of the Mid-Atlantic Ridge. From the inventory of methane in the rift valley adjacent to the vent, it appears that the average specific rate of oxidation is 2.6 to 23 yr− 1, corresponding to a turnover time between 140 and 16 days. Vertical profiles of methane in the surrounding region often exhibited Gaussian-like distributions, and the variances appear to increase with distance from the vent. Using a Gaussian plume model, we obtained a range of vertical eddy diffusivities between 0.009 and 0.08 m2m2 s− 1. These high values may be due to tidally driven internal waves across the promontory on which the vent is located.  相似文献   

2.
Records of the past neodymium (Nd) isotope composition of the deep ocean can resolve ambiguities in the interpretation of other tracers. We present the first Nd isotope data for sedimentary benthic foraminifera. Comparison of the ?Nd of core-top foraminifera from a depth transect on the Cape Basin side of the Walvis Ridge to published seawater data, and to the modern dissolved SiO2–?Nd trend of the deep Atlantic, suggests that benthic foraminifera represent a reliable archive of the deep water Nd isotope composition. Neodymium isotope values of benthic foraminifera from ODP Site 1264A (Angola Basin side of the Walvis Ridge) from the last 8 Ma agree with Fe–Mn oxide coatings from the same samples and are also broadly consistent with existing fish teeth data for the deep South Atlantic, yielding confidence in the preservation of the marine Nd isotope signal in all these archives. The marine origin of the Nd in the coatings is confirmed by their marine Sr isotope values. These important results allow application of the technique to down-core samples.The new ?Nd datasets, along with ancillary Cd/Ca and Nd/Ca ratios from the same foraminiferal samples, are interpreted in the context of debates on the Neogene history of North Atlantic Deep Water (NADW) export to the South Atlantic. In general, the ?Nd and δ13C records are closely correlated over the past 4.5 Ma. The Nd isotope data suggest strong NADW export from 8 to 5 Ma, consistent with one interpretation of published δ13C gradients. Where the ?Nd record differs from the nutrient-based records, changes in the pre-formed δ13C or Cd/Ca of southern-derived deep water might account for the difference. Maximum NADW-export for the entire record is suggested by all proxies at 3.5–4 Ma. Chemical conditions from 3 to 1 Ma are totally different, showing, on average, the lowest NADW export of the record. Modern-day values again imply NADW export that is about as strong as at any stage over the past 8 Ma.  相似文献   

3.
Pressure–volume–temperature relations have been measured to 32 GPa and 2073 K for natural magnesite (Mg0.975Fe0.015Mn0.006Ca0.004CO3) using synchrotron X-ray diffraction with a multianvil apparatus at the SPring-8 facility. A least-squares fit of the room-temperature compression data to a third-order Birch–Murnaghan equation of state (EOS) yielded K0 = 97.1 ± 0.5 GPa and K′ = 5.44 ± 0.07, with fixed V0 = 279.55 ± 0.02 Å3. Further analysis of the high-temperature compression data yielded the temperature derivative of the bulk modulus (∂KT/∂T)P = −0.013 ± 0.001 GPa/K and zero-pressure thermal expansion α = a0 + a1T with a0 = 4.03 (7) × 10−5 K−1 and a1 = 0.49 (10) × 10−8 K−2. The Anderson–Grüneisen parameter is estimated to be δT = 3.3. The analysis of axial compressibility and thermal expansivity indicates that the c-axis is over three times more compressible (KTc = 47 ± 1 GPa) than the a-axis (KTc = 157 ± 1 GPa), whereas the thermal expansion of the c-axis (a0 = 6.8 (2) × 10−5 K−1 and a1 = 2.2 (4) × 10−8 K−2) is greater than that of the a-axis (a0 = 2.7 (4) × 10−5 K−1 and a1 = −0.2 (2) × 10−8 K−2). The present thermal EOS enables us to accurately calculate the density of magnesite to the deep mantle conditions. Decarbonation of a subducting oceanic crust containing 2 wt.% magnesite would result in a 0.6% density reduction at 30 GPa and 1273 K. Using the new EOS parameters we performed thermodynamic calculations for magnesite decarbonation reactions at pressures to 20 GPa. We also estimated stability of magnesite-bearing assemblages in the lower mantle.  相似文献   

4.
A series of experiments and petrographic analyses have been run to determine the pre-eruption phase equilibria and ascent dynamics of dacitic lavas composing Black Butte, a dome complex on the flank of Mount Shasta, California. Major and trace element analyses indicate that the Black Butte magma shared a common parent with contemporaneously erupted magmas at the Shasta summit. The Black Butte lava phenocryst phase assemblage (20 v.%) consists of amphibole, plagioclase (core An77.5), and Fe–Ti oxides in a fine-grained (< 0.5 mm) groundmass of plagioclase, pyroxene, Fe–Ti oxides, amphibole, and cristobalite. The phenocryst assemblage and crystal compositions are reproduced experimentally between 890 °C and 910 °C, ≥ 300 MPa, XH2O = 1, and oxygen fugacity = NNO + 1. This study has quantified the extent of three crystallization processes occurring in the Black Butte dacite that can be used to discern ascent processes. Magma ascent rate was quantified using the widths of amphibole breakdown rims in natural samples, using an experimental calibration of rim development in a similar magma at relevant conditions. The majority of rims are 34 ± 10 μm thick, suggesting a time-integrated magma ascent rate of 0.004–0.006 m/s among all four dome lobes. This is comparable to values for effusive samples from the 1980 Mount St. Helens eruption and slightly faster than those estimated at Montserrat. A gap between the compositions of plagioclase phenocryst cores and microlites suggests that while phenocryst growth was continuous throughout ascent, microlite formation did not occur until significantly into ascent. The duration of crystallization is estimated using the magma reservoir depth and ascent rate, as determined from phase equilibria and amphibole rim widths, respectively. Textural analysis of the natural plagioclase crystals yields maximum growth rates of plagioclase phenocryst rims and groundmass microlites of 8.7 × 10− 8 and 2.5 × 10− 8 mm/s, respectively. These rates are comparable to values determined from time-sequenced samples of dacite erupted effusively from Mount St. Helens during 1980 and indicate that syneruptive crystallization processes were important during the Black Butte eruptive cycle.  相似文献   

5.
The Laccadive Ridge (L-R), trending roughly parallel to the west coast of India, is an intriguing segment of the northernmost Chagos-Laccadive Ridge (C-L-R) system. Although crustal nature and isostatic response of the southern C-L-R is well known, there are no similar studies on the L-R. In the present study, the isostatic response of the lithosphere beneath the L-R is estimated so as to characterize its crustal nature, total crustal as well as effective elastic plate thickness and mode of compensation. Twelve gravity and bathymetry profiles across the ridge were analyzed using linear transfer function and forward model techniques. The observed admittance function within the diagnostic waveband of 250 < λ > 80 km (0.025 < k > 0.080 km−1) fits well with (i) the Airy model whose average crustal thickness (Tc) and density are 17 ± 2 km and 2.7 × 103 kg m−3, respectively, and (ii) the thin plate flexure model of isostasy with an effective elastic plate thickness (Te) of 2–3 km. The estimated average crustal thickness and density are in good agreement with published seismic refraction results over the ridge. The results of the present study support an Airy model of isostasy for the L-R. The low Te value, in view of other published results in the study area, suggests stretched and loaded continental lithosphere of the L-R during the evolution of the western continental margin of India.  相似文献   

6.
We report results from an investigation of the geologic processes controlling hydrothermal activity along the previously-unstudied southern Mid-Atlantic Ridge (3–7°S). Our study employed the NOC (UK) deep-tow sidescan sonar instrument, TOBI, in concert with the WHOI (USA) autonomous underwater vehicle, ABE, to collect information concerning hydrothermal plume distributions in the water column co-registered with geologic investigations of the underlying seafloor. Two areas of high-temperature hydrothermal venting were identified. The first was situated in a non-transform discontinuity (NTD) between two adjacent second-order ridge-segments near 4°02′S, distant from any neovolcanic activity. This geologic setting is very similar to that of the ultramafic-hosted and tectonically-controlled Rainbow vent-site on the northern Mid-Atlantic Ridge. The second site was located at 4°48′S at the axial-summit centre of a second-order ridge-segment. There, high-temperature venting is hosted in an  18 km2 area of young lava flows which in some cases are observed to have flowed over and engulfed pre-existing chemosynthetic vent-fauna. In both appearance and extent, these lava flows are directly reminiscent of those emplaced in Winter 2005−06 at the East Pacific Rise, 9°50′N and reference to global seismic catalogues reveals that a swarm of large (M 4.6−5.6) seismic events was centred on the 5°S segment over a  24 h period in late June 2002, perhaps indicating the precise timing of this volcanic eruptive episode. Temperature measurements at one of the vents found directly adjacent to the fresh lava flows at 5°S MAR (Turtle Pits) have subsequently revealed vent-fluids that are actively phase separating under conditions very close to the Critical Point for seawater, at  3000 m depth and 407 °C: the hottest vent-fluids yet reported from anywhere along the global ridge crest.  相似文献   

7.
Samples dredged from 2 localities near the crest of the Valu Fa ridge, an active back-arc basin spreading centre in the Lau Basin, consist of highly vesicular lava fragments of andesitic composition. The samples are characterized by rare, euhedral An85 plagioclase phenocrysts in a hypocrystalline groundmass of An60 plagioclase laths, brown glass and rare subhedral clinopyroxene. Samples from within and, to a lesser extent, between the dredge hauls show remarkable isotopic and chemical homogeneity, with: 87Sr/86Sr − 0.70330 ± 2; 143Nd/144Nd − 0.51303 ± 2; 206Pb/204Pb − 18.65 ± 2; 207Pb/204Pb − 15.55 ± 1; 208Pb/204Pb − 38.34 ± 4; Sr − 165 ppm; Rb − 7 ppm; Cs − 0.17 ppm; K − 3300 to 4200 ppm; Ba − 96 ppm; and REE — LREE depleted with 12–18 × chondritic abundances. On Sr-Nd, Pb-Pb and Sr-Pb plots the volcanics lie just within or on the edge of the MORB fields, overlapping with island-arc volcanics from the Marianas and Tonga. Compared with MORB and ocean-island basalts, the samples show alkali-element enrichment relative to REE and higher Cs relative to Rb. The isotopic and geochemical characteristics of the Valu Fa Ridge volcanics clearly indicate a minor, but significant, slab-derived component in the back-arc basin mantle source.  相似文献   

8.
The nitrogen isotope geochemistry of 15 basaltic glasses has been investigated using stepped heating and high sensitivity static vacuum mass spectrometry. At low temperature (< 600°C) the glasses release small amounts of nitrogen with δ15NAIR, averaging −0.3‰, suggesting surficial adsorption of atmospheric nitrogen. At high temperature, usually with a maximum at 1000°C, indigenous nitrogen with a concentration ranging from 0.2 to 2.1 ppm is released. The δ15N values of this high temperature release show a wide range from −4.5‰ to +15.5‰. There is no correlation between N ppm and δ15N, and the samples apparently form 3 groups with distinctive δ15N. Six MORB glasses from the Mid-Atlantic Ridge, East Pacific Rise and Juan de Fuca Ridge define a group with δ15N = +7.5 ± 1.3‰. In contrast two Indian Ocean MORB glasses (Carlsberg Ridge and Gulf of Aden) gave negative δ15N averaging −3.2‰. Glasses from Loihi Seamount have high δ15N averaging +14.0 ± 1.0‰. Comparison of the δ15N data with the mantle models derived from helium and argon isotope studies suggests that the wide range in δ15N may reflect in part heterogeneities in the mantle related to its degassing history. It is possible, however, that magmatic degassing processes have also affected nitrogen isotopic compositions, and the data cannot yet be unambiguously interpreted in terms of source variations.  相似文献   

9.
The precise knowledge of the initial 26Al/27Al ratio [(26Al/27Al)0] is crucial if we are to use the very first solid objects formed in our Solar System, calcium–aluminum-rich inclusions (CAIs) as the “time zero” age-anchor and guide future work with other short-lived radio-chronometers in the early Solar System, as well as determining the inventory of heat budgets from radioactivities for early planetary differentiation. New high-precision multi-collector inductively-coupled plasma mass spectrometry (MC-ICP-MS) measurements of 27Al/24Mg ratios and Mg-isotopic compositions of nine whole-rock CAIs (six mineralogically characterized fragments and three micro-drilled inclusions) from the CV carbonaceous chondrite, Allende yield a well-defined 26Al–26Mg fossil isochron with an (26Al/27Al)0 of (5.23 ± 0.13) × 10− 5. Internal mineral isochrons obtained for three of these CAIs (A44A, AJEF, and A43) are consistent with the whole-rock CAI isochron. The mineral isochron of AJEF with (26Al/27Al)0 = (4.96 ± 0.25) × 10− 5, anchored to our precisely determined absolute 207Pb–206Pb age of 4567.60 ± 0.36 Ma for the same mineral separates, reinstate the “canonical” (26Al/27Al)0 of 5 × 10− 5 for the early Solar System. The uncertainty in (26Al/27Al)0 corresponds to a maximum time span of ± 20 Ka (thousand years), suggesting that the Allende CAI formation events were culminated within this time span. Although all Allende CAIs studied experienced multistage formation history, including melting and evaporation in the solar nebula and post-crystallization alteration likely on the asteroidal parent body, the 26Al–26Mg and U–Pb-isotopic systematics of the mineral separates and bulk CAIs behaved largely as closed-system since their formation. Our data do not support the “supra-canonical” 26Al/27Al ratio of individual minerals or their mixtures in CV CAIs, suggesting that the supra-canonical 26Al/27Al ratio in the CV CAIs may have resulted from post-crystallization inter-mineral redistribution of Mg isotopes within an individual inclusion. This redistribution must be volumetrically minor in order to satisfy the mass balance of the precisely defined bulk CAI and bulk mineral data obtained by MC-ICP-MS.The radiogenic 208Pb/206Pb ratio obtained as a by-product from the Pb–Pb age dating is used to estimate time-integrated 232Th/238U ratio (κ value) of CAIs. Limited κ variations among the minerals within a single CAI, contrasted by much larger variations among the bulk CAIs, suggest Th/U fractionation occurred prior to crystallization of igneous CAIs. If interpreted as primordial heterogeneity, the κ value can be used to calculate the mean age of the interstellar dust from which the CAIs condensed.  相似文献   

10.
Surface partial pressure of CO2 (pCO2), temperature, salinity, nutrients, and chlorophyll a were measured in the East China Sea (ECS; 31°30′–34°00′N to 124°00′–127°30′E) in August 2003 (summer), May 2004 (spring), October 2004 (early fall), and November 2005 (fall). The warm and saline Tsushima Warm Current was observed in the eastern part of the survey area during four cruises, and relatively low salinity waters due to outflow from the Changjiang (Yangtze River) were observed over the western part of the survey area. Surface pCO2 ranged from 236 to 445 μatm in spring and summer, and from 326 to 517 μatm in fall. Large pCO2 (values >400 μatm) occurred in the western part of the study area in spring and fall, and in the eastern part in summer. A positive linear correlation existed between surface pCO2 and temperature in the eastern part of the study area, where the Tsushima Warm Current dominates; this correlation suggests that temperature is the major factor controlling surface pCO2 distribution in that area. In the western part of the study area, however, the main controlling factor is different and seasonally complex. There is large transport in this region of Changjiang Diluted Water in summer, causing low salinity and low pCO2 values. The relationship between surface pCO2 and water stability suggests that the amount of mixing and/or upwelling of CO2-rich water might be the important process controlling surface pCO2 levels during spring and fall in this shallow region. Sea–air CO2 flux, based on the application of a Wanninkhof [1992. Relationship between wind speed and gas exchange over the ocean. Journal of Geophysical Research 97, 7373–7382] formula for gas transfer velocity and a set of monthly averaged satellite wind data, were −5.04±1.59, −2.52±1.81, 1.71±2.87, and 0.39±0.18 mmol m−2 d−1 in spring, summer, early fall, and fall, respectively, in the northern ECS. The ocean in this study area is therefore a carbon sink in spring and summer, but a weak source or in equilibrium with the atmosphere in fall. If the winter flux value is assumed to have been the mean of autumnal and vernal values, then the northern ECS absorbs about 0.013 Pg C annually. That result suggests that the northern ECS is a net sink for atmospheric CO2, a result consistent with previous studies.  相似文献   

11.
Mg/Ca and Sr/Ca ratios were determined on a single species of planktonic foraminiferan, Globigerinoides ruber (white), collected from the Gulf of Eilat and cultured in seawater at five different salinities (32 to 44), five temperatures (18 to 30 °C) and four pH values (7.9 to 8.4). The Mg/Ca-temperature calibration of cultured G. ruber (with an exponential slope of 8 ± 3%/°C) agrees well with previously published calibrations from core-tops and sediment traps. However, the dependence of Mg/Ca on salinity (with an exponential slope of 5 ± 3%/psu) is also significant and should be included in the calibration equation. With this purpose, we calculated a calibration equation for G. ruber dependent on both temperature and salinity within the 95% confidence limits:
Mg/Ca(mmol/mol)=exp[0.06(±0.02)*S(psu)+0.08(±0.02)*T(°C)−2.8(±1.0)],R2=0.95
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