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1.
Figeh watershed spring is one of the important groundwater aquifer, which is considered a major source for drinking waters of Damascus city and countryside. The origin identification and recharge estimates of groundwater are significant components of sustainable groundwater development in this Mountain karst aquifer of Figeh spring. During the period 2001–2009, monthly groundwater and precipitation samples were taken and the isotopic compositions of δ18O, δ2H, and chloride contents were analyzed to identify groundwater origins and to estimate recharge rates. The δ18O, δ2H of the groundwater show that the groundwater recharge is of meteoric origin. The chloride mass balance (CMB) method was used to quantify recharge rates of groundwater in the Mountain karst aquifer of Figeh spring. The recharge rate varies from 192 to 826 mm/year, which corresponds to 43 and 67% of the total annual rainfall. Recharge rates estimated by CMB were compared with values obtained from other methods and were found to be in good agreement. This study can be used to develop effective programs for groundwater management and development.  相似文献   

2.
 The Errachidia basin is composed of three superposed aquifers (Senonian, Turonian limestones and Infracenomanian). The Liassic limestone of the upper Atlas borders the northern part of the basin. The piezometric map of the Turonian aquifer displays a north-south flow, with an inflow area from the Atlas. This recharge hypothesis is demontrated by a discriminant analysis performed on chemical data: the majority of the spots are of sodium choride and hydrogenocarbonate types, while several boreholes are assigned to a calcium hydrogenocarbonate type Jurassic component. 18O measurements, using the Atlasic gradient δ18O=–4.18–0.0027 x elevation to estimate the recharge areas, confirm that the recharge area is the basin itself (<1100 m) on the Turonian outcrops, while in the confined part, the Turonian is recharged higher than 1400 m (corresponding to the Atlas). This contribution ranges from 56 to 85%, according to the situation versus the piezometric inflow area. The remainder represents infiltration and vertical leakage from the Senonian layers.  相似文献   

3.
Stable isotopes (δ18O, δ2H and 13C) and radioactivity (3H, 14C) have been used in conjunction with chemical data to evaluate the processes generating the chemical composition, reconstruct the origin of the water and groundwater residence time. The Aleppo basin is comprised of two main limestone aquifers: the first one is unconfined of Paleogene age and the second is confined of Upper Cretaceous age. The chemical data indicate that the dissolution of minerals and evaporation are the main processes controlling groundwater mineralization. The groundwater from the two aquifers is characterized by distinctive stable isotope signatures. This difference in water isotopes is interpreted in terms of difference origin and recharge period. Fresh and brackish shallow groundwater were mostly recharged during the Holocene period. The presence of 3H in several groundwater samples of this aquifer gives evidence that groundwater recharge is going on. Brackish water of the deep confined aquifer has depleted stable isotope composition and very low 14C activity that indicates recharge during the late Pleistocene cold period.  相似文献   

4.
Water in the fissured limestone and dolomite of the Turonian aquifer of Tunisia has been investigated using geochemical (major ions) and isotopic (δ18O, δ2H, 14C) data. To carry out a characterization of aquifer behaviour, 48 representative samples were collected at the end of the humid season. The evolution of chemical composition of groundwater from recharge areas to discharge areas is characterized by increasing sodium, chloride and sulphate contents as a result of leaching of evaporite rock. In the study, three distinct chemical trends in groundwater were identified. The major reactions responsible for the chemical evolution of groundwater in the investigated area fall into three categories: (1) calcite precipitation, (2) gypsum and halite dissolution, and (3) ion exchange. The stable isotope composition of water samples indicates large-scale interaction between the Continental Intercalaire and the Turonian aquifer and the presence of a young local component which probably enters the system via faults and/or fractures.  相似文献   

5.
In a semiarid region, the karst aquifer generally forms a large groundwater reservoir that can play an important role in regional water supply. But because of the specific physical properties of karst aquifers, they are vulnerable to pollution and anthropogenic impacts. Karst groundwater management strategies are vital. As representative of karst springs in a semiarid area, Niangziguan Springs is located in the east of Shanxi Province, China with an annual average rate of discharge of 10.34 m3/s (1956–2003) (Y. Liang, unpublished data). The Niangziguan Spring Basin covers an area of 7,394 km2 with an annual average precipitation of 535 mm (1958–2003) (Hao et al. in Carsologica Sinica 23(1):43–47, 2004). Over the past three decades, accelerated groundwater exploitation has caused water-table decline in the aquifer, reduction of the spring discharge, and deterioration of water quality. In this study, three protection zones were defined to ensure the quality and capacity of this resource. The confluence of the 11 spring systems and the discharge areas were defined as I protection zone, the recharge basin was II protection zone, and the slack water area where there is little surface recharge was the III protection zone. Management strategies for each zone were suggested and evaluated to provide a scientific foundation for sustainable utilization.  相似文献   

6.
The phreatic aquifer beneath the Pampean plain, in eastern central Argentina, constitutes a relevant source of water supply in the area. The objective of this work was to assess the significance of the cation exchange processes in the hydrochemical evolution of this aquifer, based on a study case located in the middle and upper basin of the El Pescado creek. Results indicate that Ca2+/Na+ exchange is the main process determining the evolution of groundwater from the recharge areas (Ca–HCO3) towards the local discharge areas (Na–HCO3), as well as representing a source of Na+ contribution to the water in the aquifer. This hydrochemical characteristic is central to the identification of local discharge areas within a plain environment which extends regionally. The ion exchange capacity of these discharge areas has environmental importance, due to its influence on groundwater quality and potential groundwater uses. These results may be applied to any aquifer sharing similar hydrogeological characteristics.  相似文献   

7.
The Guadalupe Valley aquifer is the only water source for one of the most important wine industries in Mexico, and also the main public water supply for the nearby city of Ensenada. This groundwater is monitored for major ion, N-NO3, P-PO4, Fe, As, Se, Mo, Cd, Cu, Pb, Zn and Sb concentrations, as well as TDS, pH, dissolved oxygen and temperature. High concentrations of N-NO3 (26 mg l−1), Se (70 μg l−1), Mo (18 μg l−1) and Cu (4.3 μg l−1) suggest that groundwater is being polluted by the use of fertilizers only in the western section of the aquifer, known as El Porvenir graben. Unlike the sites located near the main recharge area to the East of the aquifer, the water in El Porvenir graben has low tritium concentrations (<1.9 TU), indicating a pre-modern age, and thus longer water residence time. No significant variations in water quality (generally <10%) were detected throughout 2001–2002 in the aquifer, suggesting that reduced rainfall and recharge during this dry period did not significantly affect water quality. However, the wells nearest to the main recharge area in the Eastern aquifer show a slight but constant increase in TDS with time, probably as a result of the high (∼200 L S−1) uninterrupted extraction of water at this specific recharge site. Relatively high As concentrations for the aquifer (10.5 μg l−1) are only found near the northern limit of the basin associated with a geological fault.  相似文献   

8.
The objective of this study is to refine the understanding of recharge processes in watersheds representative for karstic semiarid areas by means of stable isotope analysis and hydrogeochemistry. The study focuses on the Granada aquifer system which is located in an intramontane basin bounded by high mountain ranges providing elevation differences of almost 2900 m. These altitude gradients lead to important temperature and precipitation gradients and provide excellent conditions for the application of stable isotopes of water whose composition depends mainly on temperature. Samples of rain, snow, surface water and groundwater were collected at 154 locations for stable isotope studies (δ18O, D) and, in the case of ground- and surface waters, also for major and minor ion analysis. Thirty-seven springs were sampled between 2 and 5 times from October 2004 to March 2005 along an altitudinal gradient from 552 masl in the Granada basin to 2156 masl in Sierra Nevada. Nine groundwater samples were taken from the discharge of operating wells in the Granada basin which are all located between 540 and 728 masl. The two main rivers were monitored every 2–3 weeks at three different altitudes. Rainfall being scarce during the sampling period, precipitation could only be sampled during four rainfall events. Calculated recharge altitudes of springs showed that source areas of mainly snowmelt recharge are generally located between 1600 and 2000 masl. The isotope compositions of spring water indicate water sources from the western Mediterranean as well as from the Atlantic without indicating a seasonal trend. The isotope pattern of the Quaternary aquifer reflects the spatial separation of different sources of recharge which occur mainly by bankfiltration of the main rivers. Isotopic signatures in the southeastern part of the aquifer indicate a considerable recharge contribution by subsurface flow discharged from the adjacent carbonate aquifer. No evaporation effects due to agricultural irrigation were detected.  相似文献   

9.
Stable isotopes (??2H, ??18O and ??13C) and radiocarbon (14C) have been used in conjunction with chemical data to evaluate recharge mechanisms and groundwater residence time, and to identify inter-aquifer mixing in the Djeffara multi-aquifer in semi-arid southeastern Tunisia. The southern part of this basin, the Djeffara of Medenine aquifer system, is comprised of two main aquifers of Triassic and Miocene sandstone. The Triassic aquifer presents two compartments; the first one (west of the Medenine fault system) is unconfined with a well-defined isotope fingerprint; the second compartment is deeper and confined. Multi-tracer results show groundwater of different origins, ages and salinities, and that tectonic features control groundwater flows. Fresh and brackish groundwater from the unconfined part of the Triassic aquifer was mostly recharged during the Holocene. The recharge rates of this aquifer, inferred by 14C ages, are variable and could reach 3.5?mm/year. Brackish water of the deep confined part of the Triassic aquifer has stable isotope composition and 14C content that indicates earlier recharge during late Pleistocene cold periods. Brackish to saline water of the Miocene aquifer presents variable isotope composition. Groundwater flowing through the Medenine fault system is mainly feeding the Miocene aquifer rather than the deep confined part of the Triassic aquifer.  相似文献   

10.
The water resources of the Essaouira coastal basin (west of Marrakesh) are characteristic of a semi-arid climate and are severely impacted by the climate in terms of quantity and quality. Considering the importance of the Essaouira aquifer in the groundwater supply of a vast region (nearly 1,200 km2), a research study was conducted in order to better understand groundwater evolution in this aquifer system. It is a coastal aquifer located on the Atlantic coastline, southern Morocco, and salinization problems have been reported. Covering the Palaeozoic bedrock, the sedimentary series range from the Triassic to the Quaternary. Besides the possibility of seawater intrusion problems, the geological structures delineate a syncline bordered by the Tidzi diapir (of Triassic age) outcropping to the east and south. This is a recharge area for the aquifer, whereas the main groundwater flow direction is from SE to NW towards the Atlantic Ocean. In spite of the occurrence of calcareous and dolomitic levels, all waters in the Essaouira basin are of the Na–Cl-type. Based on a range of experimental methodologies, combined with PCA and geochemical modelling, it was possible to identify the mineralization processes occurring in the groundwater system, and the importance of the water–rock interaction in the water chemistry. Scenarios were tested using a simple mass balance model through the PHREEQC programme. The reaction path was assumed to be such that waters observed at shallow depths evolved to more mineralized waters. An important contribution of water–rock interaction in groundwater mineralization was found, corroborating the influence of preferential recharge from the Tidzi diapir in the water’s signature. Anthropogenic contamination was also identified and could lead to serious problems with groundwater degradation in the near future, in a country with scarce water resources.  相似文献   

11.
The southwestern Chad basin is a semi-arid region with annual rainfall that is generally less than 500 mm and over 2,000 mm of evapotranspiration. Surface water in rivers is seasonal, and therefore groundwater is the perennial source of water supply for domestic and other purposes. Stable isotope has been measured for rainwater, surface water and groundwater samples in this region. The stable isotope data have been used to understand the inter-relationships between the rainwater, surface water, shallow and deep groundwater of this region. This is being used in a qualitative sense to demonstrate present day recharge to the groundwater. Stable isotope in rainwater for the region has an average value of –4‰ δ18O and –20‰ δ2H. Surface water samples from rivers and Lake Chad fall on the evaporation line of this average value. The Upper Zone aquifer water samples show stable isotope signal with a wide range of values indicating the complex character of the aquifer Zone with three distinguishable units. The wide range of values is attributable to waters from individual unit and/or mixture of waters of different units. The Middle and Lower aquifers Zones’ waters show similar stable isotopes values, probably indicating similarity in timing and/or mechanism of recharge. These are palaeowaters probably recharged under a climate that is different from today. The Upper Zone aquifer is presently being recharged as some of its waters show stable isotope compositions similar to those of average rainfall waters of the region.  相似文献   

12.
Aquifers within the Pampa del Tamarugal Basin (Atacama Desert, northern Chile) are the sole source of water for the coastal city of Iquique and the economically important mining industry. Despite this, the regional groundwater system remains poorly understood. Although it is widely accepted that aquifer recharge originates as precipitation in the Altiplano and Andean Cordillera to the east, there remains debate on whether recharge is driven primarily by near-surface groundwater flow in response to periodic flood events or by basal groundwater flux through deep-seated basin fractures. In addressing this debate, the present study quantifies spatial and temporal variability in regional-scale groundwater flow paths at 20.5°S latitude by combining a two-dimensional model of groundwater and heat flow with field observations and δ18O isotope values in surface water and groundwater. Results suggest that both previously proposed aquifer recharge mechanisms are likely influencing aquifers within the Pampa del Tamarugal Basin; however, each mechanism is operating on different spatial and temporal scales. Storm-driven flood events in the Altiplano readily transmit groundwater to the eastern Pampa del Tamarugal Basin through near-surface groundwater flow on short time scales, e.g., 100–101 years, but these effects are likely isolated to aquifers in the eastern third of the basin. In addition, this study illustrates a physical mechanism for groundwater originating in the eastern highlands to recharge aquifers and salars in the western Pampa del Tamarugal Basin over timescales of 104–105 years.  相似文献   

13.
Many cities around the world are developed at alluvial fans. With economic and industrial development and increase in population, quality and quantity of groundwater are often damaged by over-exploitation in these areas. In order to realistically assess these groundwater resources and their sustainability, it is vital to understand the recharge sources and hydrogeochemical evolution of groundwater in alluvial fans. In March 2006, groundwater and surface water were sampled for major element analysis and stable isotope (oxygen-18 and deuterium) compositions in Xinxiang, which is located at a complex alluvial fan system composed of a mountainous area, Taihang Mt. alluvial fan and Yellow River alluvial fan. In the Taihang mountainous area, the groundwater was recharged by precipitation and was characterized by Ca–HCO3 type water with depleted δ18O and δD (mean value of −8.8‰ δ18O). Along the flow path from the mountainous area to Taihang Mt. alluvial fan, the groundwater became geochemically complex (Ca–Na–Mg–HCO3–Cl–SO4 type), and heavier δ18O and δD were observed (around −8‰ δ18O). Before the surface water with mean δ18O of −8.7‰ recharged to groundwater, it underwent isotopic enrichment in Taihang Mt. alluvial fan. Chemical mixture and ion exchange are expected to be responsible for the chemical evolution of groundwater in Yellow River alluvial fan. Transferred water from the Yellow River is the main source of the groundwater in the Yellow River alluvial fan in the south of the study area, and stable isotopic compositions of the groundwater (mean value of −8.8‰ δ18O) were similar to those of transferred water (−8.9‰), increasing from the southern boundary of the study area to the distal end of the fan. The groundwater underwent chemical evolution from Ca–HCO3, Na–HCO3, to Na–SO4. A conceptual model, integrating stiff diagrams, is used to describe the spatial variation of recharge sources, chemical evolution, and groundwater flow paths in the complex alluvial fan aquifer system.  相似文献   

14.
The spatial and temporal changes of the composition of the groundwater from the springs along the Wadi Qilt stream running from the Jerusalem–Ramallah Mountains towards the Jericho Plain is studied during the hydrological year 2006/2007. The residence time and the intensity of recharge play an important role in controlling the chemical composition of spring water which mainly depends on distance from the main recharge area. A very important factor is the oxidation of organics derived from sewage and garbage resulting in variable dissolved CO2 and associated HCO3 − concentration. High CO2 yields lower pH values and thus under-saturation with respect to calcite and dolomite. Low CO2 concentrations result in over-saturation. Only at the beginning and at the end of the rainy season calcite saturation is achieved. The degradation of dissolved organic matter is a major source for increasing water hardness. Besides dissolution of carbonates dissolved species such as nitrate, chloride, and sulfate are leached from soil and aquifer rocks together with only small amounts of Mg. Mg not only originates from carbonates but also from Mg–Cl waters are leached from aquifer rocks. Leaching of Mg–Cl brines is particularly high at the beginning of the winter season and lowest at its end. Two zones of recharge are distinguishable. Zone 1 represented by Ein Fara and Ein Qilt is fed directly through the infiltration of meteoric water and surface runoff from the mountains along the eastern mountain slopes with little groundwater residence time and high flow rate. The second zone is near the western border of Jericho at the foothills, which is mainly fed by the under-groundwater flow from the eastern slopes with low surface infiltration rate. This zone shows higher groundwater residence time and slower flow rate than zone 1. Groundwater residence time and the flow rate within the aquifer systems are controlled by the geological structure of the aquifer, the amount of active recharge to the aquifer, and the recharge mechanism. The results of this study may be useful in increasing the efficiency of freshwater exploitation in the region. Some precautions, however, should be taken in future plans of artificial recharge of the aquifers or surface-water harvesting in the Wadi. Because of evaporation and associated groundwater deterioration, the runoff water should be artificially infiltrated in zones of Wadis with high storage capacity of aquifers. Natural infiltration along the Wadis lead to evaporation losses and less quality of groundwater.  相似文献   

15.
The Krishni–Yamuna interstream area is a micro-watershed in the Central Ganga Plain and a highly fertile track of Western Uttar Pradesh. The Sugarcane and wheat are the major crops of the area. Aquifers of Quaternary age form the major source of Irrigation and municipal water supplies. A detailed hydrogeological investigation was carried out in the study area with an objective to assess aquifer framework, groundwater quality and its resource potential. The hydrogeological cross section reveals occurrence of alternate layers of clay and sand. Aquifer broadly behaves as a single bodied aquifer down to the depth of 100 m bgl (metre below ground level) as the clay layers laterally pinch out. The depth to water in the area varies between 5 and 16.5 m bgl. The general groundwater flow direction is from NE to SW with few local variations. An attempt has been made to evaluate groundwater resources of the area. The water budget method focuses on the various components contributing to groundwater flow and groundwater storage changes. Changes in ground water storage can be attributed to rainfall recharge, irrigation return flow and ground water inflow to the basin minus baseflow (ground water discharge to streams or springs), evapotranspiration from ground water, pumping and ground water outflow from the basin. The recharge is obtained in the study area using Water table fluctuation and Tritium methods. The results of water balance study show that the total recharge in to the interstream region is of the order of 185.25 million m3 and discharge from the study area is of the order of 203.24 million m3, leaving a deficit balance of −17.99 million m3. Therefore, the present status of groundwater development in the present study area has acquired the declining trend. Thus, the hydrogeological analysis and water balance studies shows that the groundwater development has attained a critical state in the region.  相似文献   

16.
Integrated biostratigraphic (planktonic foraminifera, calcareous nannofossils), chemostratigraphic (bulk C and O isotopes) and compound-specific organic geochemical studies of a mid-Cretaceous pelagic carbonate—black shale succession of the Ionian Zone (western Greece), provide the first evidence for the Cenomanian–Turonian oceanic anoxic event (OAE2, ‘Bonarelli’ event) in mainland Greece. The event is manifested by the occurrence of a relatively thin (35 cm), yet exceptionally organic carbon-rich (44.5 wt% TOC), carbonate-free black shale, near the Cenomanian–Turonian boundary within the Vigla limestone formation (Berriasian–Turonian). Compared to the ‘Bonarelli’ black-shale interval from the type locality of OAE2 in Marche–Umbria, Italy, this black shale exhibits greatly reduced stratigraphic thickness, coupled with a considerable relative enrichment in TOC. Isotopically, enriched δ13C values for both bulk organic matter (−22.2‰) and specific organic compounds are up to 5‰ higher than those of underlying organic-rich strata of the Aptian-lower Albian Vigla Shale member, and thus compare very well with similar values of Cenomanian–Turonian black shale occurrences elsewhere. The relative predominance of bacterial hopanoids in the saturated, apolar lipid fraction of the OAE2 black shale of the Ionian Zone supports recent findings suggesting the abundance of N2-fixing cyanobacteria in Cretaceous oceans during the Cenomanian–Turonian and early Aptian oceanic anoxic events.  相似文献   

17.
The Minqin Basin is at the lower reach of the Shiyang River of Gansu province in northwest China. Dramatic decline in groundwater level has resulted from over-abstraction of groundwater since the late 1950s to satisfy increasing irrigation and other demands. Severe water shortage led to environmental degradation. To better understand the spatial–temporal variation of groundwater levels and to evaluate the groundwater resources in the region, a three-dimensional regional groundwater flow model was built and calibrated under transient condition. The MODFLOW program was used and the research area was discretized as a square network with cell size of 400 × 400 m. The model showed that the aquifer was under destructive stress, with a groundwater resource deficit of 260 million cubic meters per year (Mm3/year) on average. Since the inflow of surface water from the upstream basin has declined to about 100–150 Mm3/year in recent decades, the irrigation return flow had become the main recharge and accounted for 60.6% of total recharge; meanwhile, abstraction by pumping wells took 99.2% from the total groundwater discharge.  相似文献   

18.
 Long Lake, located near Lake Michigan within the dune-complexes of Indiana Dunes National Lakeshore, USA, was formed some time during the Pleistocene and Holocene epochs. A surficial aquifer underlies Long Lake, which is either a source or sink for the later. The hydrologic processes in the lakeshore and surrounding environs have been significantly altered during the agricultural, municipal, and industrial development of the region. Limited data suggest that the organisms of Long Lake have elevated levels of several contaminants. This study attempts to quantify seepage within the lake to assess the potential threat to groundwater quality. Seepage measurements and minipiezometric tests were used to determine seepage within the lake. Seepage measurements and minipiezometric tests suggest that water seeps out of Long Lake, thus recharging the groundwater that flows southwest away from the lake. There is a great deal of variability in the seepage rate, with a mean of 11.5×10–4±11.2×10–4 m d–1. The mean seepage rate of 0.3 m yr–1 for Long Lake is greater than the 0.2 m yr–1 recharge rate estimated for the drainage basin area. The Long Lake recharge volume of 2.5×105 m3 yr–1 is approximately 22% of the volume of the lake and is significant when compared to the total surface recharge volume of 4.8×105 m3 yr–1 to the upper aquifer of the drainage area. There is a potential for contamination of the groundwater system through seepage from the lake from contaminants derived from aerial depositions. Received: 16 August 1995 · Accepted: 18 September 1995  相似文献   

19.
The major ion hydrochemistry, sodium absorption ratio (SAR), sodium percentage, and isotopic signatures of Hammamet-Nabeul groundwaters were used to identify the processes that control the mineralization, irrigation suitability, and origin of different water bodies. This investigation highlights that groundwater mineralization is mainly influenced by water-rock interaction and pollution by the return flow of irrigation water. The comparison of groundwater quality with irrigation suitability standards proves that most parts of groundwater are unacceptable for irrigation and this long-term practice may result in a significant increase of the salinity and alkalinity in the soils. Based on isotopic signatures, the shallow aquifer groundwater samples were classified into (i) waters with depleted δ18O and δ2H contents, highlighting recharge by modern precipitation, and (ii) waters with enriched stable isotope contents, reflecting the significance of recharge by contaminated water derived from the return flow of evaporated irrigation waters. The deep-aquifer groundwater samples were also classified into (i) waters with relatively enriched isotope contents derived from modern recharge and mixed with shallow-aquifer groundwater and (ii) waters with depleted stable isotope contents reflecting a paleoclimatic origin. Tritium data permit to identify three origins of recharge, i.e., contemporaneous, post-nuclear, and pre-nuclear. Carbon-14 activities demonstrate the existence of old paleoclimatic recharge related to the Holocene and Late Pleistocene humid periods.  相似文献   

20.
 The aim of the study is to investigate the interaction between waters of Lake Girdev and groundwater in the allochthonous limestone units exposed in the area between Lake Girdev and Kazanpınarı Spring, southwestern Turkey. The features analyzed include the flow direction and apparent groundwater velocity, their relationship with Lake Girdev, and the effect of lithological and structural features on the groundwater circulation. The results of a fluorescein tracer test indicate that groundwater flows east-northeast and the apparent flow velocity ranges from 26.2 to 35.6 m h–1 between the injection site and various observation points. Tritium data suggest that the water of Lake Girdev and groundwater are probably similar in age, and oxygen-18 isotope data indicate that water derived from Lake Girdev is the main source of recharge to the aquifer. The aquifer is fed not only by Lake Girdev but also by rainfall percolating through allochthonous limestones; together, these provide the discharge of springs in Elmalı Polje. The permeability of the allochthonous limestone aquifer has been enhanced as a result of jointing and faulting. Received, June 1997 / Revised, June 1998, March 1999 / Accepted, July 1999  相似文献   

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