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1.
In order to assess the possible environmental impact of oily cuttings discharged during oil exploration activities, we studied the benthic foraminiferal faunas in a five-station, 4-km-long sampling transect around a cuttings disposal site at about 670 m depth offshore Angola (W Africa), where drilling activities started 1.5 years before sampling. Living (Rose Bengal stained) and dead foraminiferal faunas were sampled in March 2006. The faunal patterns mirror the spatial distribution of hydrocarbons, which are dispersed into a southeastern direction. Four different areas can be distinguished on the basis of the investigated faunal parameters (density, diversity and species composition of the living fauna, and comparison with subrecent dead faunas). The fauna at station S31, 300 m SE of the oil cuttings disposal site, appears to be clearly impacted: the faunal density and diversity are maximal, but evenness is minimal. Taxa sensitive to organic enrichment, such as Uvigerina peregrina, Cancris auriculus and Cribrostomoides subglobosus, have largely disappeared, whereas the low-oxygen-resistant taxon Chilostomella oolina and opportunistic buliminids and bolivinids attain relatively high densities. At station S32, 500 m SE of the disposal site, environmental impact is still perceptible. The faunal density is slightly increased, and U. peregrina, apparently the most sensitive species, is still almost absent. The faunas found at 1 and 1.8 km SE of the disposal site are apparently no longer impacted by the drill mud disposal. Faunal density and diversity are low, and the faunal composition is typical for a mesotrophic to eutrophic upper slope environment. Finally, Station S35, 2 km NW of the disposal site, contains an intermediate fauna, where both the low-oxygen-resistant C. oolina and the more sensitive taxa (U. peregrina, C. auriculus and C. subglobosus) are present. All taxa live close to the sediment–water interface here, indicating a reduced oxygen penetration into the sediment. Since the hydrocarbon concentration is low at this station, it appears that the faunal characteristics are the consequence of a slightly different environmental setting, and not due to a contamination with drill cuttings. Our data underline the large potential of benthic foraminifera as bio-indicators of anthropogenic enrichment in open marine settings, such as caused by the disposal of oily drill cuttings. The foraminiferal faunas react essentially by a density increase of a number of tolerant and/or opportunistic taxa, and a progressive disappearance of more sensitive taxa in the most impacted area. Rather surprisingly, large-sized taxa appear to be more sensitive than small-sized foraminiferal taxa.  相似文献   

2.
The distributions of benthic assemblages, heavy metals and organic carbon (Corg) in sediments were examined during a long-term study at a sewage sludge disposal site off the Mediterranean coast of Israel. The disposal of sewage sludge has a marked but localized, seasonally dependent, impact on the benthic assemblages and sediment quality. Elevated concentrations of Corg, Hg, Cd, Cu, Zn, Pb, and to a lesser degree Ni in the sediments were detected mostly northward of the sewage outfall, in the direction of the prevalent longshore current. High concentrations of Corg and metals were reflected by elevated populations of tolerant and opportunistic polychaetes in spring and by an azoic zone in fall. The impacted area extended mainly towards the north (up to ca. 4 km) and to a lesser extent south of the outfall (up to ca. 2.5 km). No evidence of increased accumulation of sewage sludge with time was found, nor of pollutants associated with it. Principal component analysis (PCA) grouped the anthropogenic metals and Corg with infaunal abundance for the spring surveys, while biotic diversity was negatively correlated with the pollutants. In the PCA of fall surveys, abundance was negatively correlated with the pollutants, decreasing with increased concentration of Corg and anthropogenic metals. We suggest that the seasonal pattern shown by infaunal abundance, anthropogenic metals and Corg is due to the stratification of the water column from spring to fall on one-hand and winter storms on the other. Winter storms resuspend and disperse the fine organic particles, sweeping the site clean of sludge; accumulation of sludge takes place throughout the quiescent periods of the year, when stratification is reestablished. The disposal site is dispersive and the spatial extent of the impacted area varies seasonally and interannually. This monitoring study, in addition to addressing specific questions about sewage sludge impact, represents an unusually large and unique set of long-term measurements that will serve as a basis to evaluate the site recovery following the cessation of disposal.  相似文献   

3.
Korean Geostationary Ocean Color Imager (GOCI) and Moderate Resolution Imaging Spectroradiometer (MODIS) Aqua observations of the variation in ocean color at the sea surface were utilized to monitor the impact of nutrient-rich sewage sludge disposal in the oligotrophic area of the Yellow Sea. MODIS revealed that algal blooms persisted in the spring annually at the dump site in the Yellow Sea since year 2000 to the present. A number of implications of using products of the satellite ocean color imagers were exploited here based on the measurements in the Yellow Sea. GOCI observes almost every hour during the daylight period, every day since June 2011. Therefore, GOCI provides a powerful tool to monitor waste disposal at sea in real time. Tracking of disposal activity from a large tanker was possible hour by hour from the GOCI timeseries images compared to MODIS. Smaller changes in the color of the ocean surface can be easily observed, as GOCI resolves images at smaller scales in space and time in comparison to polar orbiting satellites, e.g., MODIS. GOCI may be widely used to monitor various marine activities in the sea, including waste disposal activity from ships.  相似文献   

4.
Mercury speciation was performed in excess activated sewage sludge (ASS) and in marine sediments collected at the AAS disposal site off the Mediterranean coast of Israel in order to characterize the spatial and vertical distribution of different mercury species and assess their environmental impact. Total Hg (HgT) concentrations ranged between 0.19 and 1003ng/g at the polluted stations and 5.7 and 72.8ng/g at the background station, while the average concentration in ASS was 1181+/-273ng/g. Only at the polluted stations did HgT concentrations decrease exponentially with sediment depth, reaching background values at 16-20cm, the vertical distribution resulting from mixing of natural sediment with ASS solids and bioturbation by large populations of polycheates. Average Methyl Hg (MeHg) concentration in ASS was 39.7+/-7.1ng/g, ca. 3% of the HgT concentration, while the background concentrations ranged between 0.1 and 0.61ng/g. MeHg concentrations in surficial polluted sediments were 0.7-5.9ng/g (ca. 0.5% of the HgT) and decreased vertically, similar to HgT. A positive correlation between MeHg and Hg only at the polluted stations, higher MeHg concentrations at the surface of the sediment and not below the redoxline, and no seasonality in the concentrations suggest that the MeHg originated from the ASS and not from in situ methylation. By doing selective extractions, we found that ca. 80% of the total Hg in ASS and polluted sediments was strongly bound to amorphous organo-sulfur and to inorganic sulfide species that are not bioavailable. The fractions with potential bioaccessible Hg had maximal concentrations in the range in which biotic effects should be expected. Therefore, although no bioaccumulation was found in the biota in the area, the concentration in the polluted sediments are not negligible and should be carefully monitored.  相似文献   

5.
The anthropogenic contribution of trace metals to settling particulate matter (SPM) and surficial sediments was determined on the high-energy continental shelf adjacent to Sydney, Australia. Settling particulate matter and surficial sediment was collected in the vicinity of a major sewage outfall and at five control sites on the middle shelf (80-100 m water depth). Sediment traps were deployed on 10 occasions for up to 2 weeks during the summer and winter of 1995 and SPM was analyzed for Ag, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn. Cobalt, Fe, Mn and Ni act conservatively in SPM and in sediments regionally and are used as normalizing elements to determine anthropogenic enrichment. Surficial sediments and SPM are enriched in Ag, Cr, Cu, Pb and Zn near a major ocean outfall and at four of the five control sites, although sewage particles contribute < 5% of trace metals in the total sample. Silver is the most sensitive trace metal tracer for establishing the presence of sewage particulate matter. Sewage particulate matter flux near the outfall was estimated using a two end-member mixing model and is below 0.5 g m(-2) day(-1) during all deployment periods. The mean sewage particulate matter flux at sampling locations 30 km and 60 km north of the outfall are <0.13 g m(-2) day(-1) and <0.01 g m(-2) day(-1), respectively, indicating an efficient dispersal of anthropogenic material on this high energy continental shelf.  相似文献   

6.
A study was carried out to assess primary production and associated export flux in the coastal waters of the western Antarctic Peninsula at an oceanographic time-series site. New, i.e., exportable, primary production in the upper water-column was estimated in two ways; by nutrient deficit measurements, and by primary production rate measurements using separate 14C-labelled radioisotope and 15N-labelled stable isotope uptake incubations. The resulting average annual exportable primary production estimates at the time-series site from nutrient deficit and primary production rates were 13 and 16 mol C m−2, respectively. Regenerated primary production was measured using 15N-labelled ammonium and urea uptake, and was low throughout the sampling period.The exportable primary production measurements were compared with sediment trap flux measurements from 2 locations; the time-series site and at a site 40 km away in deeper water. Results showed ∼1% of the upper mixed layer exportable primary production was exported to traps at 200 m depth at the time-series site (total water column depth 520 m). The maximum particle flux rate to sediment traps at the deeper offshore site (total water column depth 820 m) was lower than the flux at the coastal time-series site. Flux of particulate organic carbon was similar throughout the spring–summer high flux period for both sites. Remineralisation of particulate organic matter predominantly occurred in the upper water-column (<200 m depth), with minimal remineralisation below 200 m, at both sites. This highly productive region on the Western Antarctic Peninsula is therefore best characterised as ‘high recycling, low export’.  相似文献   

7.
The results of four MAFF surveys (1975–1980) of the sediments in and around the sewage sludge dumping site in Liverpool Bay are presented. Sediments were analysed for particle size distribution, organic carbon concentrations and concentrations of Hg, Cd, Cu, Zn, Pb, Ni and Cr. Concentrations of organic carbon and metals were found to be elevated in the fine ( < 90 μm) fraction in areas associated with the major inputs of these substances to the bay—near the mouth of the Mersey, near the sewage sludge dumping site and at the dredged spoil dumping site.In an attempt to determine any temporal trends between surveys, stations were grouped into four 8×8 km areas from offshore of the dumping ground to the mouth of the Mersey. Changes in the metal concentrations in sediments in the square nearest the sewage sludge dumping site were larger than in the other squares including that nearest the Mersey. Comparison of temporal trends near the sewage sludge site with the quantities actually dumped showed a correlation between the two, consistent with sewage sludge dumping being a major contributor to the metal levels in fine sediments near the dumping ground.  相似文献   

8.
The diatom species composition of settling biogenic silica particles collected in sediment traps was compared with the underlying sediment to determine the preservation of the various diatom species and to investigate the potential of biogenic silica as an indicator for changes in paleo-upwelling intensity. During the Netherlands Indian Ocean Programme (NIOP), settling particles were collected at two sampling sites off Somalia (NW Indian Ocean) for 9 months, from June 1992 to February 1993. One sediment trap array was deployed on the Somali slope directly below one of the main upwelling gyres, and a second array, meant as a reference site to reflect pelagic sedimentation, was moored in the Somali Basin away from direct coastal upwelling influence. At both sites diatoms represented over 90% of the total opal microorganisms. On the Somali slope, total annual diatom flux was 12.6×109 valves m−2, 76% of which was collected during the 112 d of the southwest monsoon, with peak fluxes in October, the end of the upwelling season. In the Somali Basin, the total annual flux was lower, 4.8×109 valves m−2, and only 39% was collected during the SW monsoon period (98 d). At both sampling sites, a distinct seasonal diatom species succession of ‘pre-upwellers’, ‘upwellers’ and ‘oceanic species’ was apparent. Although only a small part of the diatom assemblage escaped dissolution at the sediment–water interface, two species, Thalassionema nitzschioides and Chaetoceros resting spores, were preserved in the sediment, indicating that they are resistant to dissolution at the sediment–water interface. Eighty one percent of the deposition of Thalassionema nitzschioides and 78% of the deposition of Chaetoceros occurred during the upwelling period. Since these two species are the dominant component of the diatom assemblage in the sediments, and thus determine the biogenic silica content, we conclude that this preserved biogenic silica reflects the upwelling in the surface layer of the water column. On the Somali Margin, variations in biogenic silica flux as inferred from sedimentary records can therefore be used as an indicator for changes in paleo-upwelling intensity.  相似文献   

9.
The impact of dredge spoil disposal on asymmetrical large-scale dunes has been studied at a disposal site in a shallow subtidal area of the outer Weser Estuary (German Bight, southeastern North Sea). Between June and December 1998, this site was used for the disposal of ~3×106 m3 dredge spoil. Repeated bathymetric surveys with a multibeam echosounder system reveal that the artificial supply of sediment provoked significant morphological changes in the dune field, including the infill of dune troughs and even the complete burial of individual dunes. However, even completely buried dunes began to regenerate within a few months. In addition, slow migration of the dunes toward the open sea was observed, indicating net seaward sediment transport in the survey area. Since the dumped sediment does not appear to have a persistent effect on the bedforms and, in all likelihood, will be exported from the estuarine system on medium- to long-term timescales, the investigated area constitutes a suitable disposal site.  相似文献   

10.
Three time-series sediment traps were deployed in the Japan Trench at 40°26′N, 144°28′E, from October 1994 to May 1995. The depths were approximately 1, 4.2 and 6.8 km and the water depth was 7150 m. There were large mass fluxes in spring at 1 and 4.2 km depths, whereas increased fluxes appeared from 27 December 1994 to 29 January 1995, at 4.2 and 6.8 km depths. The 1994 Sanriku-Oki earthquake (Mw=7.7) occurred on 28 December 1994, at 40°27′N, 143°43′E, adjacent to the study site. Distinct increases in non-biogenic material were observed at both 4.2 and 6.8 km just after the earthquake; the material seems to have originated from the surface sediments, though differing Mn/Al of particulate materials at the two depths imply a difference in their source areas. Analysis indicates that the main part of the increased particulate fluxes at 6.8 km depth derived from the sediment on the eastern slope of the Japan Trench.  相似文献   

11.
An extensive 234Th data set was collected at two sites in the North Pacific: ALOHA, an oligotrophic site near Hawaii, and K2, a mesotrophic HNLC site in the NW Pacific as part of the VERTIGO (VERtical Transport In the Global Ocean) study. Total 234Th:238U activity ratios near 1.0 indicated low particle fluxes at ALOHA, while 234Th:238U ～0.6 in the euphotic zone at K2 indicated higher particle export. However, spatial variability was large at both sites—even greater than seasonal variability as reported in prior studies. This variability in space and time confounds the use of single profiles of 234Th for sediment trap calibration purposes. At K2, there was a decrease in export flux and increase in 234Th activities over time associated with the declining phase of a summer diatom bloom, which required the use of non-steady state models for flux predictions. This variability in space and time confounds the use of single profiles of 234Th for sediment trap calibration purposes. High vertical resolution profiles show narrow layers (20–30 m) of excess 234Th below the deep chlorophyll maximum at K2 associated with particle remineralization resulting in a decrease in flux at depth that may be missed with standard sampling for 234Th and/or with sediment traps. Also, the application of 234Th as POC flux tracer relies on accurate sampling of particulate POC/234Th ratios and here the ratio is similar on sinking particles and mid-sized particles collected by in-situ filtration (>10–50 μm at ALOHA and >5–350 μm at K2). To further address variability in particle fluxes at K2, a simple model of the drawdown of 234Th and nutrients is used to demonstrate that while coupled during export, their ratios in the water column will vary with time and depth after export. Overall these 234Th data provide a detailed view into particle flux and remineralization in the North Pacific over time and space scales that are varying over days to weeks, and 10's–100's km at a resolution that is difficult to obtain with other methods.  相似文献   

12.
Sediment management is becoming a critical issue around the world, particularly where the development of Harbor facilities, the conservation of coastal environments and needs of tourism compete for sustainable use of sediment resources. In order to apply an Integrated Coastal Zone Management policy, new approaches for management of the dredged harbor material need to be considered by the scientific community and local stakeholders. The information contained in the Italian Ministry of the Environment Acts related to dredging of Carrara Harbor determined the sediment volume dredged between 1993 and 2008 (849,500 m3) and allows us to estimate an average rate of material dredged from the harbor mouth (10,000-13,000 m3/yr). Different management options were chosen by the authorities based on the contamination level of dredged sediment: nourishment (344,500 m3), offshore dumping (305,000 m3), disposal in landfill (10,000 m3) or in Confined Disposal Facilities (215,000 m3). The present study’s goal is to determine the sedimentary budget of the Apuo-Versilian coast and to use the result to guide a compensation strategy to reduce the sediment deficit caused by the disposal of sediments out of the sand-sharing system. In particular, the present study provides a detailed reference frame that can lead to adopt a compensation strategy to balance the eroding evolutionary trend of the coastline adjacent to shallow water dredging areas. The procedure described in the paper is a policy initiative based on scientific results and could provide a model for other jurisdictions developing their own sediment quantitative estimation within an ICZM approach and a sustainable development of sedimentary resource’s management.  相似文献   

13.
Apseudes latreillei (Milne-Edwards) is a common and abundant tanaid in soft-bottom communities from waters off East Atlantic and Mediterranean coasts. Its sensitivity to pollution is not clear despite being an abundant and widely distributed crustacean, since it has been reported as both a tolerant and sensitive species. This paper tests the sensitivity of A. latreillei to sewage discharges in fine-sand communities along the Castellon coast (W. Mediterranean). We analysed variation in tanaid populations between sites at varying distances from sewage outfalls with respect to population density, size distribution, sex ratio and their correlation with different abiotic factors of waste water and sediment. Results showed clearly that A. latreillei populations were affected by the presence of sewage outfalls, to such an extent that sewage disposal outlets produced a decrease in population density and changes in size spectra.  相似文献   

14.
This work aimed to evaluate, in vitro, the capability of roots of salt marsh plants to release strong Cu-complexing ligands and to ascertain whether Cu contamination would stimulate ligands' exudation or not. The sea rush Juncus maritimus and the sea-club rush Scirpus maritimus, both from the lower Douro river estuary (NW Portugal), were used. Plants were collected seasonally, four times a year in 2004, during low tide. After sampling, plant roots were washed for removal of adherent particles and immersed for 2 h in a solution that matched salinity (3) and pH (7.5) of the pore water from the same location and spiked with Cu2+ in the range 0–1600 nM to obtain plant exudates. In the final solutions as well as in sediment pore water total dissolved Zn and Cu, Cu-complexing ligand concentrations and the respective conditional stability constants (KCuL′) values were determined by voltammetry. This study demonstrated that plants are able to release, in a short period of time, relatively high amounts of strong Cu-complexing ligands (56–265 nmol groot−1), which differed among plants and sampling site but were independent of the season. Cu contamination did not stimulate exudation of Cu-complexing ligands. On the other hand, in media contaminated with Cu both plants accumulated relatively high amounts (29–83%) of the initially dissolved Cu, indicating that they have alternative internal mechanisms for Cu detoxification. Cu exchange between roots and medium (either accumulation in contaminated medium or release in the absence of Cu) was more intense for S. maritimus than for J. maritimus. It was observed that exudate solutions obtained in the absence of added Cu and sediment pore water (the densities of roots observed inside the salt marsh where comparable to those used in the in vitro experiments), displayed similarities in terms of total dissolved metals, Cu-complexing ligands concentrations, values of KCuL′ (12 < log KCuL′ < 14), as well as patterns of variation among seasons (only observed for Zn). These results are novel and point out that salt marsh plants may be the source at least partially of the strong organic ligands found in the sediment pore water in shallow marginal areas. The capability of salt marsh plants to release strong organic ligands into the environment, conjugated with their known capacity to oxidize anaerobic sediment around roots, indicate that these plants can play a role in controlling metal speciation in the water/sediment interface.  相似文献   

15.
《Marine Chemistry》2002,80(1):11-26
Profiles of particulate and dissolved 234Th (t1/2=24.1 days) in seawater and particulate 234Th collected in drifting traps were analyzed in the Barents Sea at five stations during the ALV3 cruise (from June 28 to July 12, 1999) along a transect from 78°15′N–34°09′E to 73°49′N–31°43′E. 234Th/238U disequilibrium was observed at all locations. 234Th data measured in suspended and trapped particles were used to calibrate the catchment efficiency of the sediment traps. Model-derived 234Th fluxes were similar to 234Th fluxes measured in sediment traps based on a steady-state 234Th model. This suggests that the sediment traps were not subject to large trapping efficiency problems (collection efficiency ranges from 70% to 100% for four traps). The export flux of particulate organic carbon (POC) can be calculated from the model-derived export flux of 234Th and the POC/234Th ratio. POC/234Th ratios measured in suspended and trapped particles were very different (52.0±9.9 and 5.3±2.2 μmol dpm−1, respectively). The agreement between calculated and measured POC fluxes when the POC/234Th ratio of trapped particles was used confirms that the POC/234Th ratio in trap particles is representative of sinking particles. Large discrepancies were observed between calculated and measured POC fluxes when the POC/234Th ratio of suspended particles was used. In the Barents Sea, vertical POC fluxes are higher than POC fluxes estimated in the central Arctic Ocean and the Beaufort Sea and lower than those calculated in the Northeast Water Polynya and the Chukchi Sea. We suggest that the latter fluxes may have been strongly overestimated, because they were based on high POC/234Th ratios measured on suspended particles. It seems that POC fluxes cannot be reliably derived from thorium budgets without measuring the POC/234Th ratio of sediment trap material or of large filtered particles.  相似文献   

16.
Disequilibrium between 234Th and 238U in water column profiles has been used to estimate the settling flux of Th (and, by proxy, of particulate organic carbon); yet potentially major non-steady-state influences on 234Th profiles are often not able to be considered in estimations of flux. We have compared temporal series of 234Th distributions in the upper water column at both coastal and deep-water sites in the northwestern Mediterranean Sea to coeval sediment trap records at the same sites. We have used sediment trap records of 234Th fluxes to predict temporal changes in water column 234Th deficits and have compared the predicted deficits to those measured to determine whether the time-evolution of the two coincide. At the coastal site (327 m water depth), trends in the two estimates of water column 234Th deficits are in fairly close agreement over the 1-month deployment during the spring bloom in 1999. In contrast, the pattern of water column 234Th deficits is poorly predicted by sediment trap records at the deep-water site (DYFAMED, 2300 m water depth) in both 2003 and 2005. In particular, the transition from a mesotrophic to an oligotrophic system, clearly seen in trap fluxes, is not evident in water column 234Th profiles, which show high-frequency variability. Allowing trapping efficiencies to vary from 100% does not reconcile the differences between trap and water column deficit observations; we conclude that substantial lateral and vertical advective influences must be invoked to account for the differences.Advective influences are potentially greater on 234Th fluxes derived from water column deficits relative to those obtained from traps because the calculation of deficits in open-ocean settings is dominated by the magnitude of the “dissolved” 234Th fraction. For observed current velocities of 5–20 cm s−1, in one radioactive mean-life of 234Th, the water column at the DYFAMED site can reflect 234Th scavenging produced tens to hundreds of kilometers away. In contrast, most of the 234Th flux collected in shallow sediment traps at the DFYFAMED site was in the fraction settling >200 m d−1; in effect the sediment trap can integrate the 234Th flux over distances 40-fold less than water column 234Th distributions. In some sense, sediment trap and water column sampling for 234Th provide complementary pictures of 234Th export. However, because the two methods can be dominated by different processes and are subject to different biases, their comparison must be treated with caution.  相似文献   

17.
This study was carried out at the Bahía Blanca Estuary, Argentina, at the seaward edge of a saltmarsh. The saltmarsh-mudflat boundary in the study area shows sediment deposits at a higher elevation immediately seaward of the saltmarsh edge. We compared field determinations of water velocity, bed shear stress, wind wave conditions and variations of the bed elevation in the mudflat and within the Spartina alterniflora canopy at the seaward edge of a saltmarsh, and we evaluated the relative role of vegetation in the observed morphology. A mud deposition event that raised bed elevation in more than 5 cm occurred during the study period, with TSS concentrations > 500 mg l−1, but simultaneous measurements performed on the bed levels confirmed that the sediments deposited did not originate from local resuspension within the edge of the canopy. In similar tidal cycles in terms of local wave activity and bed shear stresses at the sampling site, deposition occurred only with winds aligned with the azimuth of the Canal Principal, reaching a maximum fetch of more than 20 km in front of the sampling site.  相似文献   

18.
ABSTRACT

To investigate the uptake and depuration of polycyclic aromatic hydrocarbons associated with the Rena oil spill we sampled the surf clam Paphies subtriangulata at two open coast locations (6?km apart) just prior to oil coming ashore (7 October 2011), then at 1–3 week intervals for the next 4 months. Total polycyclic aromatic hydrocarbons (tPAH) increased at both sites from 1 to 96–124?µg?kg?1 (wet weight) by 18 October before declining to low levels (<4?µg?kg?1) by February 2012. Ongoing sampling throughout 2012–2014 included three additional sites to the north east (up to 30?km away) and a site 5?km to the south east revealing tPAH levels generally <10?µg?kg?1 except in October 2013 where levels ranged between 39–45?µg?kg?1 at all sites. A comparison of PAH component profiles with oil-contaminated beach sediment indicated that the high levels observed in surf clams between October–December 2011 were clearly associated with the Rena spill. However, the October 2013 peak had a PAH profile inconsistent with weathered Rena oil, suggesting an alternative source of contamination. Our results highlight the potential for P. subtriangulata as a PAH monitoring tool but recognise more study is needed to better quantify baseline levels and uptake and depuration dynamics.  相似文献   

19.
Stable carbon and nitrogen isotopic composition of zooplankton, suspended particulate organic matter (SPOM), and sinking particles collected using sediment traps were measured for samples obtained from the southeastern Bering Sea middle and outer shelf during 1997–1999. The quantity of material collected by the middle shelf sediment trap was greater in both spring and late summer and fall than in early and mid-summer. The δ15N of SPOM, sinking material and zooplankton showed greater inter-annual variability at the middle shelf site (M2) than at the outer shelf site (M3). Zooplankton and sinking organic matter collected by M2 sediment traps became more depleted in 15N from 1997 through 1999, associated with a change from unusually warm to unusually cold conditions. Suspended and sinking organic matter and zooplankton collected from M3 decreased only slightly in δ15N from 1998 to 1999. SPOM, zooplankton, and sediment trap samples collected at M2 were usually enriched in δ15N and δ13C over those from M3. However, in 1999 sediment trap samples from the middle shelf were enriched in 13C over M3 material, but the δ15N of samples from the two sites was similar. The geographic pattern could be explained greater productivity over the middle shelf, associated with either isotopically heavy nitrogen being regenerated from sediments, or with utilization of a greater fraction of the available inorganic nitrogen pool during most years.  相似文献   

20.
Seismic data from a 186 km-long refraction profile in the Santa Barbara Channel have been interpreted using several velocity inversion techniques. Data were obtained during two cruises in 1978 and 1979. Seismic arrivals from fifty explosions of between 1 and 300 lbs. of TNT were recorded by two ocean bottom seismometers, four permanent ocean bottom stations (University of Southern California), and much of the United States Geological Survey/California Institute of Technology southern California seismic network. Travel-time inversion gives a V p of 6.3 km sec-1 at 7.2 km depth above 7.2 km sec-1 at 14.4 km depth at the western end of the channel. At the eastern end, solutions suggest three sediment refractors overlying V p of 6.4 km sec-1 at 7.3 km depth, above 7.0 km sec-1 at 11.6 km depth, above mantle arrivals with V p of 8.3 km sec-1 at 21.8 km depth. The velocity structure determined by these methods suggests that the channel has a sedimentary fill of from 4 to 7 km and a layer of mafic plus ultramafic rock 14 to 17 km thick. The greatest thicknesses of sediments are restricted to east of Point Conception. The velocity data also suggest that the Franciscan formation may not be present beneath the channel. Rather, the crust here may represent a thickened portion of the Coast Range ophiolite.  相似文献   

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