首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 46 毫秒
1.
The comment of Green et al. debates the interpretation of the temperature of the H2O-saturated peridotite solidus and presence of silicate melt in the experiments of Till et al. (Contrib Mineral Petrol 163:669–688, 2012) at <1,000?°C. The criticisms presented in their comment do not invalidate any of the most compelling observations of Till et al. (Contrib Mineral Petrol 163:669–688, 2012) as discussed in the following response, including the changing minor element and Mg# composition of the solid phases with increasing temperature in our experiments with 14.5?wt% H2O at 3.2?GPa, as well as the results of our chlorite peridotite melting experiments with 0.7?wt% H2O. The point remains that Till et al. (Contrib Mineral Petrol 163:669–688, 2012) present data that call into question the H2O-saturated peridotite solidus temperature preferred by Green (Tectonophysics 13(1–4):47–71, 1972; Earth Planet Sci Lett 19(1):37–53, 1973; Can Miner 14:255–268, 1976); Millhollen et al. (J Geol 82(5):575–587, 1974); Mengel and Green (Stability of amphibole and phlogopite in metasomatized peridotite under water-saturated and water-undersaturated conditions, Geological Society of Australia Special Publication, Blackwell, pp 571-581, 1989); Wallace and Green (Mineral Petrol 44:1–19, 1991) and Green et al. (Nature 467(7314):448–451, 2010).  相似文献   

2.
Thermal equation of state of an Al-rich phase with Na1.13Mg1.51Al4.47Si1.62O12 composition has been derived from in situ X-ray diffraction experiments using synchrotron radiation and a multianvil apparatus at pressures up to 24 GPa and temperatures up to 1,900 K. The Al-rich phase exhibited a hexagonal symmetry throughout the present pressure–temperature conditions and the refined unit-cell parameters at ambient condition were: a=8.729(1) Å, c=2.7695(5) Å, V 0=182.77(6) Å3 (Z=1; formula weight=420.78 g/mol), yielding the zero-pressure density ρ0=3.823(1) g/cm3 . A least-square fitting of the pressure-volume-temperature data based on Anderson’s pressure scale of gold (Anderson et al. in J Appl Phys 65:1534–543, 1989) to high-temperature Birch-Murnaghan equation of state yielded the isothermal bulk modulus K 0=176(2) GPa, its pressure derivative K 0 ′ =4.9(3), temperature derivative (?K T /?T) P =?0.030(3) GPa K?1 and thermal expansivity α(T)=3.36(6)×10?5+7.2(1.9)×10?9 T, while those values of K 0=181.7(4) GPa, (?K T /?T) P =?0.020(2) GPa K?1 and α(T)=3.28(7)×10?5+3.0(9)×10?9 T were obtained when K 0 ′ was assumed to be 4.0. The estimated bulk density of subducting MORB becomes denser with increasing depth as compared with earlier estimates (Ono et al. in Phys Chem Miner 29:527–531 2002; Vanpeteghem et al. in Phys Earth Planet Inter 138:223–230 2003; Guignot and Andrault in Phys Earth Planet Inter 143–44:107–128 2004), although the difference is insignificant (<0.6%) when the proportions of the hexagonal phase in the MORB compositions (～20%) are taken into account.  相似文献   

3.
Polarized optical absorption spectra of natural olivine, Fa10Fo90, were measured before and after annealing/quenching experiments performed at 650, 800, 1,000 and 1,200°C under controlled oxygen fugacity. It was found that the annealing induces weak but definite changes in the olivine spectra. The intensity of the spin-allowed Z > X-polarized band at 9,560 cm?1 and shoulder at ～8,300 cm?1 attributed to Fe2+(M2), continuously decreases with annealing temperature, whereas a weaker band at ～11,600 cm?1 assigned to electronic spin-allowed transitions of Fe2+(M1), increases. This evidently shows that annealing treatments cause a redistribution of Fe2+ from M2 to M1. The fractionation increases with increasing temperature. This observation is in good correspondence with many diffraction structural studies of natural and synthetic olivines, as well as with recent Raman and Mössbauer investigations by Kolesov and Geiger (Mitt Österr Mineral Ges 149:48, 2004) and Morozov et al. (Eur J Mineral 17:495–500, 2005) evidencing a weak tendency of Fe to order into the M1 site with increasing temperature. However, this deduction is incompatible with the results of the in situ neutron power diffraction study of synthetic FeMgSiO4 by Redfern et al. (Phys Chem Minerals 27:630–637, 2000). Polarization properties of the UV absorption edge, attributed to ligand-to-metal charge-transfer transitions in Fe3+, changes from Y > X ? Z in natural samples to a weak Y ≥ X ≥ Z-pleochroism in annealed ones. This may be due to redistribution of a small content of Fe3+ among M1 and M2 structural sites.  相似文献   

4.
The trace element signatures of fluids were investigated by leaching experiments on natural samples of partly altered mafic igneous rocks recovered from the drilling site 1,256 of ODP Leg 206 on the Cocos plate (Central America). Experiments with ultrapure water were performed at 400 °C/0.4 GPa and 500 °C/0.7 GPa. Both fluids and residual solids were examined to obtain the partition coefficients (Dfluid/rock) of various trace elements. Element partition coefficients (Dfluid/rock) obtained at 500 °C/0.7 GPa are significantly lower compared to results obtained at 400 °C/0.4 GPa, which is in contrast to observations at higher pressures (2.2–6 GPa) and temperatures between 700 and 1,400 °C (Kessel et al. in Earth Planet Sci Lett 237: 873–892, 2005a; Spandler et al. in Chem Geol 239: 228–249, 2007). This finding may indicate a considerable pressure effect on the leaching processes and strongly divergent fluid–rock interactions in the upper part of a subduction zone at 0.4–0.7 GPa compared to deeper subduction areas with higher pressures. Furthermore, this may be interpreted as one of the earliest fractionation processes during the subduction of crustal material.  相似文献   

5.
Jakobsson (Contrib Miner Petrol 164(3):397–407, 2012) investigated a double capsule assembly for use in piston-cylinder experiments that would allow hydrous, high-temperature, and high-pressure experiments to be conducted under controlled oxygen fugacity conditions. Using a platinum outer capsule containing a metal oxide oxygen buffer (Ni–NiO or Co–CoO) and H2O, with an inner gold–palladium capsule containing hydrous melt, this study was able to compare the oxygen fugacity imposed by the outer capsule oxygen buffer with an oxygen fugacity estimated by the AuPdFe ternary system calibrated by Barr and Grove (Contrib Miner Petrol 160(5):631–643, 2010). H2O loss or gain, as well as iron loss to the capsule walls and carbon contamination, is often observed in piston-cylinder experiments and often go unexplained. Only a few have attempted to actually quantify various aspects of these changes (Brooker et al. in Am Miner 83(9–10):985–994, 1998; Truckenbrodt and Johannes in Am Miner 84:1333–1335, 1999). It was one of the goals of Jakobsson (Contrib Miner Petrol 164(3):397–407, 2012) to address these issues by using and testing the AuPdFe solution model of Barr and Grove (Contrib Miner Petrol 160(5):631–643, 2010), as well as to constrain the oxygen fugacity of the inner capsule. The oxygen fugacities of the analyzed melts were assumed to be equal to those of the solid Ni–NiO and Co–CoO buffers, which is incorrect since the melts are all undersaturated in H2O and the oxygen fugacities should therefore be lower than that of the buffer by 2 log $a_{{{\text{H}}_{ 2} {\text{O}}}}$ .  相似文献   

6.
A total of 163 free-field acceleration time histories recorded at epicentral distances of up to 200 km from 32 earthquakes with moment magnitudes ranging from M w 4.9 to 7.4 have been used to investigate the predictive capabilities of the local, regional, and next generation attenuation (NGA) ground-motion prediction equations and determine their applicability for northern Iran. Two different statistical approaches, namely the likelihood method (LH) of Scherbaum et al. (Bull Seismol Soc Am 94:341–348, 2004) and the average log-likelihood method (LLH) of Scherbaum et al. (Bull Seismol Soc Am 99:3234–3247, 2009), have been applied for evaluation of these models. The best-fitting models (considering both the LH and LLH results) over the entire frequency range of interest are those of Ghasemi et al. (Seismol 13:499–515, 2009a) and Soghrat et al. (Geophys J Int 188:645–679, 2012) among the local models, Abrahamson and Silva (Earthq Spectra 24:67–97, 2008) and Chiou and Youngs (Earthq Spectra 24:173–215, 2008) among the NGA models, and finally Akkar and Bommer (Seism Res Lett 81:195–206, 2010) among the regional models.  相似文献   

7.
The validity of the thermodynamic cBΩ model is tested in terms of the experimentally determined diffusion coefficients of He in a natural Fe-bearing olivine (Fo90) and a synthetic end-member forsterite (Mg2SiO4) over a broad temperature range (250–950 °C), as reported recently by Cherniak and Watson (Geochem Cosmochim Acta 84:269–279, 2012). The calculated activation enthalpies for each of the three crystallographic axes were found to be (134 ± 5), (137 ± 13) and (158 ± 4) kJ mol?1 for the [100], [010] and [001] directions in forsterite, and (141 ± 9) kJ mol?1 for the [010] direction in olivine, exhibiting a deviation of <1 % with the corresponding reported experimental values. Additional point defect parameters such as activation volume, activation entropy and activation Gibbs free energy were calculated as a function of temperature. The estimated activation volumes (3.2–3.9 ± 0.3 cm3 mol?1) of He diffusion in olivine are comparable with other reported results for hydrogen and tracer diffusion of Mg cations in olivine. The pressure dependence of He diffusion coefficients was also determined, based on single experimental diffusion measurements at 2.6 and 2.7 GPa along the [001] direction in forsterite at 400 and 650 °C.  相似文献   

8.
Growth rates of monomineralic, polycrystalline åkermanite (Ca2MgSi2O7) rims produced by solid-state reactions between monticellite (CaMgSiO4) and wollastonite (CaSiO3) single crystals were determined at 0.5 GPa dry argon pressure, 1,000–1,200°C and 5 min to 60 h, using an internally heated pressure vessel. Inert Pt-markers, initially placed at the monticellite–wollastonite interface, indicate symmetrical growth into both directions. This and mass balance considerations demonstrate that rim growth is controlled by transport of MgO. At 1,200°C and run durations between 5 min and 60 h, rim growth follows a parabolic rate law with rim widths ranging from 0.4 to 16.3 μm indicating diffusion-controlled rim growth. The effective bulk diffusion coefficient \( D_{\text{eff,MgO}}^{\text{Ak}} \) is calculated to 10?15.8±0.1 m2 s?1. Between 1,000°C and 1,200°C, the effective bulk diffusion coefficient follows an Arrhenius law with E a = 204 ± 18 kJ/mol and D 0 = 10?8.6±1.6 m2 s?1. Åkermanite grains display a palisade texture with elongation perpendicular to the reaction interface. At 1,200°C, average grain widths measured normal to elongation, increase with the square root of time and range from 0.4 to 5.4 μm leading to a successive decrease in the grain boundary area fraction, which, however, does not affect \( D_{\text{eff,MgO}}^{\text{Ak}} \) to a detectible extent. This implies that grain boundary diffusion only accounts for a minor fraction of the overall chemical mass transfer, and rim growth is essentially controlled by volume diffusion. This is corroborated by the agreement between our estimates of the effective MgO bulk diffusion coefficient and experimentally determined volume diffusion data for Mg and O in åkermanite from the literature. There is sharp contrast to the MgO–SiO2 binary system, where grain boundary diffusion controls rim growth.  相似文献   

9.
Melting experiments were conducted on a mica–clinopyroxenite xenolith brought up in a minette dyke in southern Alberta, Canada, near Milk River. Both the minettes and mica–clinopyroxenite xenoliths were studied by Buhlmann et al. (Can J Earth Sci 37:1629–1650, 2000), who hypothesized that the minettes formed by partial melting of a mantle source containing clinopyroxene + phlogopite ± olivine, at pressures ≥1.7 GPa. In liquidus experiments performed on the most primitive minette in our previous study (Funk and Luth in Contrib Mineral Petrol 164:999–1009, 2012), we found a multiple saturation point where olivine and orthopyroxene coexisted with liquid at 1.77 GPa and 1,350 °C. We argued that the minette originally formed by partial melting of clinopyroxene + phlogopite, but had re-equilibrated with a harzburgite during ascent. In the current study, we wanted to test both the source region hypothesis of Buhlmann et al. and our re-equilibration hypothesis by studying the near-solidus phase equilibria of a mica + clinopyroxene assemblage. We found the solidus for our xenolith has a steep slope in P–T space and lies at temperatures above those of a normal cratonic geotherm, implying that this mica–clinopyroxenite is stable in the cratonic mantle. Melting could occur at greater depths, where the solidus is extrapolated to cross the geotherm or must be induced either by raising the temperatures of the surrounding rocks or by introducing hydrous fluids into the source. Our melts are in equilibrium with clinopyroxene and olivine. The compositions of the liquids derived from melting this xenolith are similar to madupitic lamproites from the Leucite Hills, Wyoming, studied by Carmichael (Contrib Mineral Petrol 15:24–66, 1967) and Barton and Hamilton (Contrib Mineral Petrol 66:41–49, 1978; Contrib Mineral Petrol 69:133–142, 1979). Barton and Hamilton (Contrib Mineral Petrol 69:133–142, 1979) proposed that the madupitic lamproites may have come from a source containing mica and pyroxene. This study supports their hypothesis. The composition of the most primitive minette from southern Alberta lies between our experimental melt and a population of representative mantle orthopyroxenes. We conclude from our study that the Milk River minettes were likely derived from a source containing phlogopite, clinopyroxene and trace amounts of apatite, which formed olivine upon melting. During ascent, the melts changed composition by reacting with orthopyroxene.  相似文献   

10.
The crystal structures of natural jadeite, NaAlSi2O6, and synthetic kosmochlor, NaCrSi2O6, were studied at room temperature, under hydrostatic conditions, up to pressures of 30.4 (1) and 40.2 (1) GPa, respectively, using single-crystal synchrotron X-ray diffraction. Pressure–volume data have been fit to a third-order Birch–Murnaghan equation of state yielding V 0 = 402.5 (4) Å3, K 0 = 136 (3) GPa, and K 0 ′  = 3.3 (2) for jadeite and V 0 = 420.0 (3) Å3, K 0 = 123 (2) GPa and K 0 ′  = 3.61 (9) for kosmochlor. Both phases exhibit anisotropic compression with unit-strain axial ratios of 1.00:1.95:2.09 for jadeite at 30.4 (1) GPa and 1:00:2.15:2.43 for kosmochlor at 40.2 (1) GPa. Analysis of procrystal electron density distribution shows that the coordination of Na changes from 6 to 8 between 9.28 (Origlieri et al. in Am Mineral 88:1025–1032, 2003) and 18.5 (1) GPa in kosmochlor, which is also marked by a decrease in unit-strain anisotropy. Na in jadeite remains six-coordinated at 21.5 (1) GPa. Structure refinements indicate a change in the compression mechanism of kosmochlor at about 31 GPa in both the kinking of SiO4 tetrahedral chains and rate of tetrahedral compression. Below 31 GPa, the O3–O3–O3 chain extension angle and Si tetrahedral volume in kosmochlor decrease linearly with pressure, whereas above 31 GPa the kinking ceases and the rate of Si tetrahedral compression increases by greater than a factor of two. No evidence of phase transitions was observed over the studied pressure ranges.  相似文献   

11.
Despite a large number of studies of iron spin state in silicate perovskite at high pressure and high temperature, there is still disagreement regarding the type and P–T conditions of the transition, and whether Fe2+ or Fe3+ or both iron cations are involved. Recently, our group published results of a Mössbauer spectroscopy study of the iron behaviour in (Mg,Fe)(Si,Al)O3 perovskite at pressures up to 110 GPa (McCammon et al. 2008), where we suggested stabilization of the intermediate spin state for 8- to 12-fold coordinated ferrous iron ([8–12]Fe2+) in silicate perovskite above 30 GPa. In order to explore the behaviour in related systems, we performed a comparative Mössbauer spectroscopic study of silicate perovskite (Fe0.12Mg0.88SiO3) and majorite (with two compositions—Fe0.18Mg0.82SiO3 and Fe0.11Mg0.88SiO3) at pressures up to 81 GPa in the temperature range 296–800 K, which was mainly motivated by the fact that the oxygen environment of ferrous iron in majorite is quite similar to that in silicate perovskite. The [8–12]Fe2+ component, dominating the Mössbauer spectra of majorites, shows high quadrupole splitting (QS) values, about 3.6 mm s?1, in the entire studied P–T region (pressures to 58 GPa and 296–800 K). Decrease of the QS of this component with temperature at constant pressure can be described by the Huggins model with the energy splitting between low-energy e g levels of [8–12]Fe2+ equal to 1,500 (50) cm?1 for Fe0.18Mg0.82SiO3 and to 1,680 (70) cm?1 for Fe0.11Mg0.88SiO3. In contrast, for the silicate perovskite dominating Mössbauer component associated with [8–12]Fe2+ suggests the gradual change of the electronic properties. Namely, an additional spectral component with central shift close to that for high-spin [8–12]Fe2+ and QS about 3.7 mm s?1 appeared at ~35 (2) GPa, and the amount of the component increases with both pressure and temperature. The temperature dependence of QS of the component cannot be described in the framework of the Huggins model. Observed differences in the high-pressure high-temperature behaviour of [8–12]Fe2+ in the silicate perovskite and majorite phases provide additional arguments in favour of the gradual high-spin—intermediate-spin crossover in lower mantle perovskite, previously reported by McCammon et al. (2008) and Lin et al. (2008).  相似文献   

12.
Samples with eclogitic composition in the system CaO–FeO–Fe2O3–MgO–Al2O3–SiO2 were produced from various kinds of starting materials held in graphite-lined Pt capsules at a pressure of 2.5–3.0 GPa and temperatures of 800–1,300 °C using a piston-cylinder or Belt apparatus. Garnets and clinopyroxenes were characterized by analytical transmission electron microscopy and electron probe micro-analysis (EPMA). Fe3+/ΣFe ratios determined by electron energy-loss spectroscopy (EELS) decrease in clinopyroxene from 22.2 ± 3.4 % at 800 °C to 13.3 ± 5.4 % at 1,300 °C, while in garnet, they vary between 10.8 ± 1.5 and 15.4 ± 4.7 %, respectively. Temperature estimates according to Krogh (Contrib Mineral Petrol 99:44–48, 1988) reproduce the experimental temperature to ±60 °C without systematic deviations if total iron is used in the calculation. If only the Fe2+ content is used, which was obtained by combining EPMA and EELS results, the experimental temperature is underestimated by 33 °C on average at 800–1,200 °C and overestimated by 77 °C on average at 1,300 °C. These systematic deviations can be explained by the temperature-dependent ratio of Fe2+/ΣFe in garnet divided by that in clinopyroxene. Since the difference between the calculated and experimental temperature is relatively small, a Fe2+-based recalibration of the thermometer appears not to be necessary for the investigated system in the range of pressure, temperature and composition covered by the experiments of this study.  相似文献   

13.
Phenocryst assemblages of lavas from the long-lived Aucanquilcha Volcanic Cluster (AVC) have been probed to assess pressure and temperature conditions of pre-eruptive arc magmas. Andesite to dacite lavas of the AVC erupted throughout an 11-million-year, arc magmatic cycle in the central Andes in northern Chile. Phases targeted for thermobarometry include amphibole, plagioclase, pyroxenes, and Fe–Ti oxides. Overall, crystallization is documented over 1–7.5 kbar (~25 km) of pressure and ~680–1,110 °C of temperature. Pressure estimates range from ~1 to 5 kbar for amphiboles and from ~3 to 7.5 kbar for pyroxenes. Pyroxene temperatures are tightly clustered from ~1,000–1,100 °C, Fe–Ti oxide temperatures range from ~750–1,000 °C, and amphibole temperatures range from ~780–1,050 °C. Although slightly higher, these temperatures correspond well with previously published zircon temperatures ranging from ~670–900 °C. Two different Fe–Ti oxide thermometers (Andersen and Lindsley 1985; Ghiorso and Evans 2008) are compared and agree well. We also compare amphibole and amphibole–plagioclase thermobarometers (Ridolfi et al. 2010; Holland and Blundy 1994; Anderson and Smith 1995), the solutions from which do not agree well. In samples where we employ multiple thermometers, pyroxene temperature estimates are always highest, zircon temperature estimates are lowest, and Fe–Ti oxide and amphibole temperature estimates fall in between. Maximum Fe–Ti oxide and zircon temperatures are observed during the middle stage of AVC activity (~5–3 Ma), a time associated with increased eruption rates. Amphibole temperatures during this time are relatively restricted (~850–1,000 °C). The crystal record presented here offers a time-transgressive view of an evolving, multi-tiered subvolcanic reservoir. Some crystals in AVC lavas are likely to be true phenocrysts, but the diversity of crystallization temperatures and pressures recorded by phases in individual AVC lavas suggests erupting magma extensively reams and accumulates crystals from disparate levels of the middle to upper crust.  相似文献   

14.
Constraining magnitudes of mechanical and thermo-mechanical parameters of rocks and shear zones are the important goals in structural geology and tectonics (Talbot in J Struct Geol 21:949–957, 1999). Such parameters aid dynamic scaling of analogue tectonic models (Ramberg in Gravity, deformation and the Earth’s crust in theory, experiments and geological applications, 2nd edn. Academic Press, London, 1981), which are useful to unravel tectonics in further details (Schultz-Ela and Walsh in J Struct Geol 24:247–275, 2002). The channel flow extrusion of the Higher Himalayan Shear Zone (HHSZ, = Higher Himalaya) can be explained by a top-to-S/SW simple shear (i.e. the D2 deformation) in combination with a pressure gradient induced flow against gravity. Presuming its Newtonian incompressible rheology with parallel inclined boundaries, the viscosity (μ) of this shear zone along a part of the Himalayan chain through India, Nepal and Bhutan is estimated to vary widely between ~1016 and 1023 Pa s, and its Prandtl number (P r ) within ~1021–1028. The estimates utilized ranges of known thickness (6–58 km) of the HHSZ, that of its top subzone of ductile shear of normal shear sense (STDSU: 0.35–9.4 km), total rate of slip of its two boundaries (0.7–131 mm year?1), pressure gradient (0.02–6 kb km?1), density (2.2–3.1 g cm?3) and thermal diffusivity (0.5 × 10?6–2.1 × 10?6 m s?2) along the orogenic trend. Considering most of the parameters specifically for the Sutlej section (India), the calculated viscosity (μ) and the Prandtl number (P r ) of the HHSZ are deduced to be μ: ~1017–1023 Pa s and P r  ~ 1022–1028. The upper limits of the estimated viscosity ranges are broadly in conformity with a strong Tibetan mid-crust from where a part of the HHSZ rocks extruded. On the other hand, their complete ranges match with those for its constituent main rock types and partly with those for the superstructure and the infrastructure. The estimated mechanical and thermo-mechanical parameters of the HHSZ will help to build dynamically scaled analogue models for the Himalayan deformation of the D2–phase.  相似文献   

15.
Tertiary basalt is widespread in the area south of Wadi Hodein, south Eastern Desert, Egypt. It is the youngest unit in the basement rocks of the Central Eastern Desert classification of El Shazly (Proc 22nd Intl Geol Congr, New Delhi 10:88–101, 1964) and El Ramly (Ann Geol Surv Egypt II:1–17, 1972), traversed all the previous succession of the basement rocks as well as the Nubia Sandstone of Cretaceous age, forming sheets, small hills, ridges, and dikes. This Tertiary basalt is strongly associated with the opening of the Red Sea. Geologic, petrographic, and petrochemical studies as well as microprobe and X-ray analyses were performed on samples from Wadi Hodein Tertiary basalt. Field and petrographic studies classified the Tertiary basalt in south Wadi Hodein into porphyritic olivine basalt, plagiophyric basalt, and doleritic basalt. Opaque minerals (magnetite and ilmenite) constitute 6–7.5% of this basalt. Petrochemical studies and microprobe analyses reveal that they are low-TiO2 basalt with low uranium and thorium contents, classified as being basaltic andesite to andesite, originated from calc-alkaline magma, and developed in within-plate tectonic environment. Scanning electron microscopy shows that magnetite and ilmenite are the prevalent opaque minerals in this Tertiary basalt. Field radiometric measurements of the Tertiary basalt in south Wadi Hodein reveals low uranium and thorium contents. Uranium contents range from 0.5 to 0.9 ppm, while thorium contents range from 1.2 to 3.2 ppm. Fractional crystallization and mass balance modeling indicate that the most-silica low-TiO2 Tertiary basalt in south Wadi Hodein can be derived from the relatively less-silica low-TiO2 Tertiary basalt of south Quseir and Gabal Qatrani through fractional crystallization of plagioclase, olivine, augite, and titanomagnetite oxides. Tertiary basalts in south Wadi Hodein and south Quseir have nearly the same age, 25 Ma (Sherif, The Fifth International Conference on the Geology of Africa, 2007), 24 Ma (Meneisy and Abdel Aal, Ain Shams Sci Bull 25(24B): 163–176, 1984), and 27 Ma (El Shazly et al., Egypt J Geol 1975), respectively. Finally, the fractionation modeling and geochemical characteristics of these basalts suggested their origination from one basaltic magma emplaced in late Oligocene.  相似文献   

16.
Orthorhombic post-perovskite CaPtO3 is isostructural with post-perovskite MgSiO3, a deep-Earth phase stable only above 100 GPa. Energy-dispersive X-ray diffraction data (to 9.4 GPa and 1,024 K) for CaPtO3 have been combined with published isothermal and isobaric measurements to determine its P–V–T equation of state (EoS). A third-order Birch–Murnaghan EoS was used, with the volumetric thermal expansion coefficient (at atmospheric pressure) represented by α(T) = α0 + α1(T). The fitted parameters had values: isothermal incompressibility, $ K_{{T_{0} }} $  = 168.4(3) GPa; $ K_{{T_{0} }}^{\prime } $  = 4.48(3) (both at 298 K); $ \partial K_{{T_{0} }} /\partial T $  = ?0.032(3) GPa K?1; α0 = 2.32(2) × 10?5 K?1; α1 = 5.7(4) × 10?9 K?2. The volumetric isothermal Anderson–Grüneisen parameter, δ T , is 7.6(7) at 298 K. $ \partial K_{{T_{0} }} /\partial T $ for CaPtO3 is similar to that recently reported for CaIrO3, differing significantly from values found at high pressure for MgSiO3 post-perovskite (?0.0085(11) to ?0.024 GPa K?1). We also report axial P–V–T EoS of similar form, the first for any post-perovskite. Fitted to the cubes of the axes, these gave $ \partial K_{{aT_{0} }} /\partial T $  = ?0.038(4) GPa K?1; $ \partial K_{{bT_{0} }} /\partial T $  = ?0.021(2) GPa K?1; $ \partial K_{{cT_{0} }} /\partial T $  = ?0.026(5) GPa K?1, with δ T  = 8.9(9), 7.4(7) and 4.6(9) for a, b and c, respectively. Although $ K_{{T_{0} }} $ is lowest for the b-axis, its incompressibility is the least temperature dependent.  相似文献   

17.
Fe-Ti-oxides may reach hundreds ppm in I-type granitoids and close to microgranular mafic enclaves (MME) up to several thousands ppm. Western Carpathian I-type granitoids have magnetic susceptibility above 3?×?10?4 SI units, whereas S-type granites are lower. Associated MMEs reach up to 160?×?10?4 SI. The measurement of magnetic susceptibility in field appears a useful tool for regional mapping of I-type granites and searching enclaves. The increased contents of Fe-oxides around MME within host I-type granitoids are interpreted as result of hybridization with mafic magma. The hybridisation is manifested by occurrence of two Fe-Ti-oxide generations: (1) orthomagmatic titanomagnetite from pre-mixing stage, (2) late-magmatic magnetite of post-mixing stage. The titanomagnetites show composite textures with exsolved ilmenite. The oxybarometry (Sauerzapf et al. 2008; Ghiorso Evans 2009) yields temperatures 700?C750°C at fO2 about NNO, and 650?C700°C below FMQ, respectively. Post-mixing pure magnetites originated from early titanomagnetite, annite and anorthite associated with titanite and apatite. The late oxidation seems to be responsible for high magnetic susceptibility of metaluminous I-type tonalites. Both post- and pre- mixing Fe-Ti oxides are locally converted to hematite.  相似文献   

18.
The concentrations of uranium, iron and the major constituents were determined in groundwater samples from aquifer containing uranyl phosphate minerals (meta-autunite, meta-torbernite and torbernite) in the Köprüba?? area. Groundwater samples from wells located at shallow depths (0.5–6 m) show usually near neutral pH values (6.2–7.1) and oxidizing conditions (Eh = 119–275 mV). Electrical conductivity (EC) values of samples are between 87 and 329 μS/cm?1. They are mostly characterized by mixed cationic Ca dominating bicarbonate types. The main hydrogeochemical process is weathering of the silicates in the shallow groundwater system. All groundwater in the study area are considered undersaturated with respect to torbernite and autunite. PHREEQC predicted UO2(HPO4) 2 2? as the unique species. The excellent positive correlation coefficient (r = 0.99) between U and PO4 indicates the dissolved uranium in groundwater would be associated with the dissolution of uranyl phosphate minerals. The groundwater show U content in the range 1.71–70.45 μg/l but they are mostly lower than US EPA (2003) maximum contaminant level of 30 μg/l. This low U concentrations in oxic groundwater samples is attributed to the low solubility of U(VI) phosphate minerals under near neutral pH and low bicarbonate conditions. Iron closely associated with studied sediments, were also detected in groundwater. The maximum concentration of Fe in groundwater samples was 2837 μg/l, while the drinking water guidelines of Turkish (TSE 1997) and US EPA (2003) were suggested 200 and 300 μg/l, respectively. Furthermore, iron and uranium showed a significant correlation to each other with a correlation coefficient (r) of 0.94. This high correlation is probably related to the iron-rich sediments which contain also significant amounts of uranium mineralization. In addition to pH and bicarbonate controlling dissolution of uranyl phosphates, association of uranyl phosphates with iron (hydr) oxides seems to play important role in the amount of dissolved U in shallow groundwater.  相似文献   

19.
The growth rate of ringwoodite reaction rims between MgSiO3 perovskite and periclase was investigated at 22.5 GPa and 1,800 °C for 1–24 h using the Kawai-type high-pressure apparatus. The reaction was likely to proceed by a diffusion-controlled mechanism in which the dominant diffusion mechanism was grain-boundary diffusion. The reaction constant (the width of the ringwoodite reaction rim squared divided by time) determined from these experiments was between 1.3 × 10?15 and 5.6 × 10?15 m2/s. A Pt inert marker experiment indicated that the MgO component migrated faster than the SiO2 component in ringwoodite. Thus, either Mg or O having the slower diffusion rate controlled the reaction. Because previous diffusion studies have shown that diffusion rates of O are slower than those of Mg, O would be a rate-controlling element for ringwoodite formation from MgSiO3 perovskite and periclase. The growth rate appeared to be too fast to explain the observed topographic rise (~10 km) inside mantle plumes at the 660-km discontinuity.  相似文献   

20.
Tracing fractures under glacial drift commonly involves costly and often unfeasible (in populated areas) geophysical methods or outcrop surveys, often far from the area of interest. A hypothesis is tested, that the specific capacity data for wells penetrating through glacial drift into a bedrock aquifer display two statistical populations: assuming uniform well construction, the wells with high specific capacity penetrate transmissive fracture zones, while those with low specific capacity encounter non-fractured rock characterized by primary porosity. The hypothesis was tested on 617 wells drilled into the Pennsylvanian Sharon Sandstone, Geauga County, Ohio (USA). Hydraulic conductivity, calculated using the Cooper and Jacob (1946) approximation to Theis’ non-equilibrium radial flow equation, followed quasi-log-normal distribution (geometric mean 9.88?×?10?6 m/s). The lower values presumably correspond to primary porosity, and higher values correspond to bedrock fracture zones. The higher hydraulic conductivity followed two distinct orientations (N34°E, N44°W), corresponding with the regional fracture pattern of the Allegheny Plateau. A variogram showed that the wells within a kilometer of each other correlate and that wells penetrating the thicker glacial blanket have lower hydraulic conductivity and larger drawdown. Cooper and Jacob (1946) A generalized graphical method for evaluating formation constants and summarizing well-field history, Am. Geoph. Union Trans. 27/4:526–534.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号