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1.
The occurrence of fluoride in groundwaters can be influenced by many factors. In Korea, the fluoride-rich groundwaters are normally associated with rock types, especially granite and gneiss. In Gimcheon, high-fluoride groundwaters (up to a maximum of 2.15 mg/L) were observed with bimodal distribution of concentrations. The groundwater in this area showed relatively high concentrations of anthropogenic chemicals such as nitrate, chloride, and sulfate. Statistical analysis showed that fluoride is positively correlated with pH, alkalinity, sodium, and lithium, indicating that the interaction with granite is the main cause enriching its concentration. In Gimcheon, δ18O data of groundwater showed a negative correlation with nitrate and can be used as an indicator of groundwater age. The four samples of fluoride-rich groundwater were plotted in the light δD and δ18O region, showing that they were the result of long water–rock reaction. However, other groundwater with a low-fluoride concentration was evenly distributed throughout all δD and δ18O ranges and did not show a statistically significant correlation with nitrate, indicating possible mixing with another source of fluoride. Considering the influence from the surface on the geochemical characteristics of groundwater in this area, anthropogenic sources including phosphate fertilizer containing fluoride and pesticides may also have partly contributed to the concentrations of fluoride in the low-fluoride groundwater. The scattered distribution of fluoride-rich groundwater and the significant correlation with lithium suggest that pegmatite is the main rock type increasing fluoride concentration in this area.  相似文献   

2.
Fluoride in drinking water has both beneficial and detrimental effects on public health, and a narrow range between .6 and 1.5 mg/L is optimal for consumption. However, natural groundwater sources exceed these guidelines affecting the entire population. This study aims to assess the distribution and controlling factors of fluoride concentration in the Tamiraparani River basin, South India. A total of 124 groundwater samples were analyzed for their fluoride content and other hydrogeochemical parameters. The fluoride concentration in the study area varied from .01 to 1.67 mg/L, and the highest concentrations were measured in the northern and central parts of the study area, which is underlain by charnockites and hornblende biotite gneiss. The sampling indicated (as per the Bureau of Indian Standards) that 53.9% of the area has fluoride concentrations below levels that are protective of teeth from dental caries (<.6 mg/L). .1% of the area is considered to be at risk of dental fluorosis, and the remaining 46% of the area is considered to have fluoride levels at desirable to permissible limit in groundwater. The groundwater in the study area belongs to Ca–Mg–Cl–SO4 and Ca–Mg–HCO3 types. A positive correlation between fluoride and TDS, Na+, K+ and HCO3 ? indicates its geogenic origin, and positive loading between pH and fluoride shows that alkaline environment enhances the dissolution of fluoride-bearing minerals into the groundwater. An empirical Bayesian kriging model was applied to interpolate the fluoride concentration in the study area. This geostatistical model is found to be better than other kriging methods, and it yielded an average standard error of .332 and root-mean-square standardized value of .986.  相似文献   

3.
Groundwater samples were collected from Mettur taluk of Salem district, Tamilnadu, India for two different seasons (pre-monsoon and post-monsoon) and analyzed for fluoride ion along with other chemical parameters. The major litho units of the study area are Charnockites, peninsular gneiss, and calc gneiss of meta-sedimentary group. The fluoride concentration ranges from 0.1 to 2.8?mg/L and 0.4 to 4.0?mg/L during pre-monsoon (PRM) and post-monsoon (POM) seasons, respectively. Results showed that collected water samples were contaminated by the presence of fluoride ion. During PRM and POM, 21% and 56% of samples recorded higher fluoride when compared with Indian Drinking Water Standard (1?mg/L) and (9% and 35%) of samples recorded higher fluoride when compared with World Health Organization tolerance limit (1.5?mg/L). The ratio of Na/Ca indicates high sodium content in groundwater enhances the dissolution of fluoride at higher pH. Hydrogeochemical facies indicates water-rock interaction as main source for high fluoride in groundwater. A positive correlation between pH, Mg, and F indicates high alkaline nature of water promotes fluoride leaching from source rocks into ground water. Factor analysis indicates hydro-geochemical processes like weathering, ion exchange, and anthropogenic contributes to groundwater chemistry. The saturation index indicates dissolution and precipitation contributes fluoride dissolution along with mixing.  相似文献   

4.
An attempt has been made in Chinnar sub basin of Dharmapuri district, South India to isolate the geochemistry of uranium occurrences in groundwater. The geology of the area is mainly of charnockite and granite gneiss. Groundwater samples were collected for two different seasons post and pre monsoon in two different litho units (granite gneiss and charnockite) and analysed for major, minor and uranium concentrations. Higher uranium (18.45 μg L?1) has been recorded during pre monsoon season in granite gneiss with increasing pH. The saturation index calculation for the groundwater isolated minerals like uaraninite, coffinite, haiweeite and soddyite to be precipitating and uranium oxides like UO2.25, UO2.25beta, UO2.33beta as oversaturated. The Eh-pH diagram attempted represents solubility of uraninite within the pH range of 6.0 to 8.0. The study isolate uranium in groundwater of the study area is controlled by the presence of (U4O9) uranium oxide.  相似文献   

5.
Chemical characterization has been made of groundwater bodies at 294 locations in four village districts in north-central and northwestern Sri Lanka, with special focus on fluorine contamination. High fluoride contents in groundwater are becoming a major problem in the dry zone of Sri Lanka, and dental fluorosis and renal failures are widespread. Field measurements of temperature, pH, and electrical conductivity were made during sampling. Chemical analyses of the water samples were later made using atomic absorption spectroscopy, spectrophotometry, and titration. Fluoride concentrations in the study area vary from 0.01 to 4.34 mg/l, and depend on pH and the concentrations of Na, Ca, and HCO3 −. Basement rocks including hornblende biotite gneiss, biotite gneiss, and granitic gneiss seem to have contributed to the anomalous concentrations of fluoride in the groundwater. Longer residence time in aquifers within fractured crystalline bedrocks may enhance fluoride levels in the groundwater in these areas. In addition, elevated fluoride concentrations in shallow groundwater in intensive agricultural areas appear to be related to the leaching of fluoride from soils due to successive irrigation.  相似文献   

6.
Groundwater samples were collected from various localities of Mithi sub-district of the Thar Desert of Pakistan and analysed for fluoride ion along with other chemical parameters. The area is mainly covered by sand dunes and kaolin/granite at variable depths. Results showed that collected water samples were severely contaminated by the presence of fluoride ion and most of the samples have higher concentration than prescribed WHO standards (1.5 mg/l) for drinking water. Fluoride ion concentrations ranged between 0.09 and 11.63 mg/l with mean and median values of 3.64 and 3.44 mg/l, respectively, in this area whereas, distribution pattern showed high concentrations in the vicinity of Islamkot and Mithi towns. The content of F− has also been correlated with other major ions found in the groundwater of the study area. The positive correlation of F− with Na+ and HCO3 − showed that the water with high Na+ and HCO3 − stabilizes F− ions in the groundwater of the Thar Desert. The pH versus F− plots signifies high fluoride concentration at higher pH values, implying that alkaline environment favours the replacement of exchangeable OH− with F− in the groundwater of Mithi area. The saturation indices (SI) of fluorite (CaF2) and calcite (CaCO3) in the groundwater samples showed that most of the samples are oversaturated with respect to calcite whereas majority of samples have been found under saturated with respect to fluorite. The log TDS and Na/Na+Ca ratio reflected supremacy of weathering of rocks, which promotes the availability of fluoride ions in the groundwater. Piper diagram has been used to classify the hydrofacies. In the cation triangle, all samples are Na-type, while the anion triangle reflects major dominance of Cl-type with a minor influence of HCO3 − and SO4 −.  相似文献   

7.
Anomalous high fluoride concentration up to 7.59 mg/dm3 is found in groundwater from “La Victoria” area. This water is used to supply drinking water to Hermosillo City, Sonora. Geochemistry of groundwater, relationship between physicochemical parameters, hydrogeology and geologic setting were correlated to define the origin and the geochemical mechanisms of groundwater fluorine enrichment. High fluoride concentration is associated with high bicarbonates, pH and temperature, and it decreases toward the west and south of the area. Fluoride is in negative correlation to calcium concentration. Sodium sulphate facies of regional deep water flow are related to high fluoride concentration. High electric resistivity rocks associated with granites from the Sierra Bachoco basement might be the deep source of fluoride. Outcropping of Sierra Bachoco in the west causes upward regional flow. Groundwater of longer residence time can be pumped there. The anomalous area is restricted to “La Victoria” because calcareous paleozoic rocks outcrop to the south.  相似文献   

8.
This paper explores the influence of a fluorine-rich granite on fluoride concentration in a small boreal catchment in northern Europe. The materials include stream water and shallow groundwater sampled in spatial and temporal dimensions, and analytical data on fluoride and a number of ancillary variables. Fluoride increased strongly towards the lower reaches of the catchment—at the stream outlet the concentrations were up to 4.2 mg L−1 and 1.6–4.7 times higher than upstream. Additionally, fluoride concentrations were particularly high in groundwater and small surface-water bodies (including quarries) above or in direct contact with the granite and showed a strong inverse correlation with water discharge in the stream. Taken together, these data and patterns pin-point the granite intrusion as the ultimate source, explaining the abundance and distribution of dissolved fluoride within the catchment. The granite most likely deliver fluoride to the stream by three mechanisms: (1) weathering of the fine fraction of glacial deposits, derived from the granite and associated fluorine-rich greisen alterations, (2) large relative input of baseflow, partially originating in the granite and greisen, into the lower reaches during low flow in particular, and (3) water-conducting fractures or fracture zones running through the fluorine-rich granite and greisen.  相似文献   

9.
Late Proterozoic rocks of Tanol Formation in the Lesser Himalayas of Neelum Valley area are largely green schist to amphibolite facies rocks intruded by early Cambrian Jura granite gneiss and Jura granite representing Pan-African orogeny event in the area. These rocks are further intruded by pegmatites of acidic composition, aplites, and dolerite dykes. Based on field observations, texture, and petrographic character, three different categories of granite gneiss (i.e., highly porphyritic, coarse-grained two micas granite gneiss, medium-grained two micas granite gneiss, and leucocratic tourmaline-bearing muscovite granite gneiss), and granites (i.e., highly porphyritic coarse-grained two micas granite, medium-grained two micas granite, and leucocratic tourmaline-bearing coarse-grained muscovite granite) were classified. Thin section studies show that granite gneiss and granite are formed due to fractional crystallization, as revealed by zoning in plagioclase. The Al saturation index indicates that granite gneiss and granite are strongly peraluminous and S-type. Geochemical analysis shows that all granite gneisses are magnesian except one which is ferroan whereas all granites are ferroan except one which is magnesian. The CaO/Na2O ratio (>0.3) indicates that granitic melt of Jura granite gneiss and granite is pelite-psammite derived peraluminous granitic melt formed due to partial melting of Tanol Formation. The rare earth element (REE) patterns of the Jura granite and Jura granite gneiss indicate that granitic magma of Jura granite and Jura granite gneiss is formed due to partial melting of rocks that are similar in composition to that of upper continental crust.  相似文献   

10.
刘德玉  贾贵义  张伟  喻生波  魏玉涛 《地质论评》2021,67(6):67120008-67120008
疏勒河尾闾区是护卫敦煌绿洲及文化的生态安全屏障,但是对地下水化学的研究相对较少。本次研究在野外调查及采样测试的基础上,综合运用数理统计、Piper三线图、离子相关性分析、Gibbs图及离子比例系数等方法明确了疏勒河尾闾区的地下水化学特征,并对其成因进行了分析。结果表明：疏勒河尾闾区地下水水质总体呈弱碱性,具有高溶解性总固体及高硬度的特征,水化学类型主要为Cl-·SO2-4-Na+型。地下水水化学演化是由蒸发浓缩作用主导,同时风化溶解和阳离子交换共同作用的结果。地下水中的Ca2+及Mg2+主要来自于蒸发岩及硅酸盐的溶解,Na+主要来源于岩盐溶解。高氟水的形成与片麻岩中普遍存在的黑云母矿物、蒸发浓缩主导的水文地球化学作用以及地势低洼的地形条件有关。成果不仅丰富了疏勒河流域内的地下水化学研究,亦可为敦煌绿洲生态安全屏障区的保护与建设提供科学依据。  相似文献   

11.
疏勒河尾闾区是护卫敦煌绿洲及文化的生态安全屏障,但是对地下水化学的研究相对较少.本次研究在野外调查及采样测试的基础上,综合运用数理统计、Piper三线图、离子相关性分析、Gibbs图及离子比例系数等方法明确了疏勒河尾闾区的地下水化学特征,并对其成因进行了分析.结果表明:疏勒河尾闾区地下水水质总体呈弱碱性,具有高溶解性总...  相似文献   

12.
High fluoride groundwater with F− concentration up to 6.20 mg/L occurs in Taiyuan basin, northern China. The high fluoride groundwater zones are mainly located in the discharge areas, especially in places where shallow groundwater occurs (the groundwater depth is less than 4 m). Regional hydrogeochemical investigation indicates that processes including hydrolysis of silicate minerals, cation exchange, and evaporation should be responsible for the increase in average contents of major ions in groundwater from the recharge areas to the discharge areas. The concentration of F− in groundwater is positively correlated with that of HCO3− and Na+, indicating that groundwater with high HCO3− and Na+ contents help dissolve some fluoride-rich minerals. The water samples with high F− concentration generally have relatively higher pH value, implying that alkaline environment favors the replacement of exchangeable F− in fluoride-rich minerals by OH− in groundwater. In addition, the mixing of karst water along the western mountain front and the evaporation may also be important factors for the occurrence of high fluoride groundwater. The inverse geochemical modeling using PHREEQC supports the results of hydrogeochemical analyses. The modeling results show that in the recharge and flow-through area of the northern Taiyuan basin, interactions between groundwater and fluoride-rich minerals are the major factor for the increase of F− concentration, whereas in the discharge area of the northern basin, the evaporation as well as the mixing of karst water has greater contribution to the fluoride enrichment in groundwater.  相似文献   

13.
This study has been carried out in the granitic aquifer of Maheshwaram watershed, Telengana, India. In this study, groundwater sample data of 8 years were analyzed for the fluoride content with other chemical quality parameters. The correlation and factor analysis were employed to understand the mechanisms for fluoride (F) enrichment as well as the hydrochemistry of the area. These analyses addressed that the observed groundwater quality was due to water-rock interaction in the aquifer and fluoride is coming from the dissolution of fluorite and other silicate minerals like biotite and hornblende by the groundwater. Land use/land cover (LULC) study from 2002 to 2008 revealed there were significant positive changes in build-up land and negative changes in vegetation cover after 2003. The main agriculture (paddy) has been reduced to 0.97 km2 in 2008 from 2.39 km2 in 2003. The studied watershed has been characterized on the basis of F concentration into safe, transition, and unsafe groups following the WHO and BIS guidelines. The temporal variation of the three groups showed that 57.6% area of the watershed was in unsafe zone in 2000–2003, but 69.2% of the area became safe in 2006–2009. It has been found that F concentration reduced in 12.59% of the area (became safe from unsafe) accompanied by the reduction of paddy field area. After validation with present (2016) fluoride concentrations, it was found that 16.28% are vulnerable in near future. The results of this study showed that (a) the safe and unsafe zones of fluoride concentrations vary with time with the changes in other parameters associated with it like crop pattern and (b) vulnerable zone can be identified based on the susceptibility to change of safe and unsafe zones. Such studies are useful for planning and management purposes.  相似文献   

14.
The fluoride level in groundwater is controlled by the distribution of Ca2+ and SO42?, ionic strength and the presence of complex ions in its composition. In the study area, situated in the Ranga Reddy district, Andhra Pradesh, India, the concentrations of fluoride in the groundwater vary from 0.7 to 4.80 mg/l and from 0.4 to 4.20 mg/l during the pre- and post-monsoon seasons respectively. From the correlation coefficient studies, it is observed that fluoride is inversely related with Ca2+ and positively related with HCO3?, whereas the correlation coefficient between fluoride and other ions is very poor during both seasons. The difference in F? concentrations between pre- and post-monsoon seasons could be because the ionic concentrations in the groundwater during the post-monsoon period were generally less than their counterparts during the pre-monsoon period, because of dilution by rainwater. By contrast, the fluoride concentration in many places was relatively high during the post-monsoon period. This indicates contamination of groundwater from surface pollutants.  相似文献   

15.
The source of fluoride toxicity in Muteh area,Isfahan, Iran   总被引：1，自引：0，他引：1  
Endemic dental fluorosis has been observed in most inhabitants of three villages of Muteh area, located in northwest of Isfahan province, with mottled enamel related to high levels of fluoride in drinking water (1.8–2.2 ppm). Forty-seven groundwater samples from six villages were collected and fluoride concentrations along with physico-chemical parameters were analyzed. Fluoride concentration in this area varies from 0.2 to 9.2 mg/l with highest fluoride level at Muteh gold mine (Chahkhatun mine). Fluoride concentration positively correlates with pH and HCO3 − indicating that alkaline pH provides a suitable condition for leaching of fluoride from surrounding rocks. The district is mainly covered by three lithological units, namely, metamorphic and granite rocks, alluvial sediments, and carbonate rocks. Factor analysis shows that parameters can be classified into four components: electrical conductivity (EC), total dissolved solids (TDS), Cl−, Na+ and K+, pH and F−, SO4 2−and Mg2+, HCO3 − and Ca2 +. The groundwaters from the three geological units were compared using Mann–Whitney U test. The order of median fluoride concentration is: metamorphic and granite rocks > alluvial sediments > carbonate rocks. Hence, the fluoride content is most probably related to fluoride-bearing minerals such as amphibole and mica group minerals in metamorphic and granitic rocks. The concentration of fluoride in drinking water wells located near the metamorphic complex in Muteh area is above 2 ppm.  相似文献   

16.
The Karbi Anglong hills (erstwhile Mikir hills) in northeast India are detached and separated from the Meghalaya plateau by a NW-SE trending Kopili rift. The Karbi Anglong hills granitoids (KAHG) and its granite gneissic variants belong to Cambrian plutons formed during Pan-African orogenic cycle, which commonly intrude the basement granite gneisses and Shillong Group metasediments. The KAHG can be broadly classified into three major granitoid facies viz., coarse grained porphyritic granitoid, medium grained massive non-porphyritic granitoid, and granite gneiss, which share a common mineral assemblage of plagioclase-K-feldspar-quartz-biotite±hornblende-apatite-titanite-zircon-magnetite but differ greatly in mineral proportion and texture. Modal mineralogy of KAHG, granite gneiss and basement granite gneiss largely represents monzogranite and syenogranite. The magnetic susceptibility (MS) of the KAHG, granite gneiss and basement granite gneiss varies widely between 0.11×10-3 and 43.144×10-3 SI units, corresponding to ilmenite series (<3×10-3 SI; reduced type) and magnetite series (>3×10-3 SI; oxidized type) of granitoids respectively. The observed MS variations are most likely intrinsic to heterogeneous source regions, modal variations of orthomagnetic and ferromagnetic minerals, and tectonothermal and deformational processes that acted upon these rocks. The primary and re-equilibrated compositions of biotites from the KAHG, granite gneiss and basement granite gneiss suggest calcalkaline, metaluminous (I-type) nature of felsic host magma formed in a subduction or post-collisional to peraluminous (S-type) host magma originated in syn-collisional tectonic settings, which were evolved and stabilized between FMQ and NNO buffers typically corresponding to reducing and oxidising magma environments respectively.  相似文献   

17.
Water samples collected from dug wells and tube wells from the Kurunegala District of Sri Lanka have been studied for their major hydrogeochemical parameters to understand the chemical quality of water in the terrain. The region is composed of Precambrian metamorphic rocks where groundwater is only available in the regolith and along weak structural discontinuities. The study of the major chemical constituents of groundwater revealed several relationships with the aquifer lithology. Groundwater from mafic rocks have high dissolved solids, while quartzose metaclastic rocks yield water with low dissolved solids. The study area displays very low SO4 2− contents of the groundwater. The chloride content is higher in the dry regions and in terrains underlain by pink granite and marble/calc gneiss while areas with marble, as expected, show high concentrations of Ca and Mg ions. The waters in the region can be classified into non-dominant cations to Na + K dominant and Cl− and HCO3 − dominant types. Water from charnockite-bearing areas tends to have non-dominant cations and more CO3 2− + HCO3 − types. Effects such as soluble salts in the regolith, fracture intensity and climatic variations play a significant role in the behavior of the hydrogeochemistry in the area.  相似文献   

18.
Fluoride (F?) is an indispensable element for the human’s skeletal and dental health at prescribed levels and becomes lethal at higher levels. Spatial–temporal variability of F? and its geochemical control/association with other dissolved ions in groundwater in the Dindigul district of Tamilnadu (India) were conducted to describe the geochemical dynamics of F– in response to seasonal variability. High concentrations of fluoride (≥1.5 mg L?1) were observed in the northern region of the district. High levels of F? were observed in non-monsoon periods and low levels in monsoon, because of dilution by precipitation. Bicarbonate was well correlated with F? which explains that both ions were derived from the weathering. While F? has a very weak correlation with silica, this implies that the silicate weathering does not supply F? to the groundwater system. The F? pollution in Dindigul groundwaters is mainly driven by two factors: (1) the geogenic weathering inputs, the geology of this area mainly comprises fluoride bearing minerals (e.g. hornblende biotite gneiss and charnockite); (2) the anthropogenic inputs (agri-fertilizers and tannery waste). Further, F? in the study area is mainly attributed to geogenic sources during pre and postmonsoons and anthropogenic sources in monsoon periods.  相似文献   

19.
Distribution of fluoride in groundwater of Maku area, northwest of Iran   总被引：3，自引：0，他引：3  
High fluoride groundwater occurs in Maku area, in the north of West Azarbaijan province, northwest of Iran. Groundwater is the main source of drinking water for the area residents. Groundwater samples were collected from 72 selected points including 40 basaltic and 32 nonbasaltic springs and wells, in two stages, during June and August 2006. The areas with high fluoride concentrations have been identified, and the possible causes for its variation have been investigated. Regional hydrogeochemical investigation indicates that water-rock interaction is probably the main reason for the high concentration of ions in groundwater. The concentration of F− in groundwater is positively correlated with that of HCO3 − and Na+, indicating that groundwater with high HCO3 − and Na+ concentrations help to dissolve some fluoride-rich minerals. All of the water samples, collected from the basaltic areas do not meet the water quality standards for fluoride concentration and some other parameters. Hence, it is not suitable for consumption without any prior treatment. Inhabitants of the area that obtain their drinking water supplies from basaltic springs and wells are suffering from dental fluorosis. The population of the study area is at a high risk due to excessive fluoride intake especially when they are unaware of the amount of fluoride being ingested due to lack of awareness.  相似文献   

20.
Fluoride contamination in groundwater resources of Alleppey,southern India   总被引：1，自引：0，他引：1  
Alleppey is one of the thickly populated coastal towns of the Kerala state in southern India.Groundwater is the main source of drinking water for the 240,991 people living in this region.The groundwater is being extracted from a multi-layer aquifer system of unconsolidated to semi-consolidated sedimentary formations,which range in age from Recent to Tertiary.The public water distribution system uses dug and tube wells.Though there were reports on fluoride contamination,this study reports for the first time excess fluoride and excess salinity in the drinking water of the region.The quality parameters,like Electrical Conductivity(EC) ranges from 266 to 3900 μs/cm,the fluoride content ranges from 0.68 to2.88 mg/L,and the chloride ranges between the 5.7 to 1253 mg/L.The main water types are Na-HC03,NaCO_3 and Na-Cl.The aqueous concentrations of F~- and CO_3~(2-) show positive correlation whereas F~- and Ca~(2+) show negative correlation.The source of fluoride in the groundwater could be from dissolution of fluorapatite,which is a common mineral in the Tertiary sediments of the area.Long residence time,sediment-groundwater interaction and facies changes(Ca-HCO_3 to Na-HCO_3) during groundwater flow regime are the major factors responsible for the high fluoride content in the groundwater of the area.High strontium content and high EC in some of the wells indicate saline water intrusion that could be due to the excess pumping from the deeper aquifers of the area.The water quality index computation has revealed that 62%of groundwater belongs to poor quality and is not suitable for domestic purposes as per BIS and WHO standards.Since the groundwater is the only source of drinking water in the area,proper treatment strategies and regulating the groundwater extraction are required as the quality deterioration poses serious threat to human health.  相似文献   

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