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Sequential P extraction was combined with electron microscop and X-ray spectroscopy to characterise various P species and to study their transformation in settling seston and in recent sediment. During early diagenesis most of the particulate P formed in the water was redissolved. No net transformation into species that would resist dissolution was observed.It was shown that
•  the phosphorus (P) content and the P flux of settling particles varied seasonally over one order of magnitude
•  particles became enriched with reductant soluble P (BD-P) while settling through the hypolimnion
•  changes in BD-P were highly significantly correlated with changes in reductant soluble iron (BD-Fe)
•  bacteria oxidising Fe and Mn seemed to be mainly responsible for this increase in P concentration
•  other fractions including organic P did not change during sedimentation
•  most of the organic P and of the Fe bound P and 70% of TP was released from the sediment during early diagenesis
•  the sediment surface did not act as a trap for P migrating upwards from deeper sediment layers
•  CaCO3 sedimentation contributed little to P sedimentation but significantly to the permanent burial of P.
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6.
During a cruise on board RV Gauss in May/June 1988, joint investigations into organochlorine compounds, dissolved trace metals, petroleum hydrocarbons and basic hydrography were carried out at representative stations of the Baltic Monitoring Programme (BMP). The aim of the cruise was to study distribution patterns and — using previous data — to establish temporal trends if at all discernible.Each group of contaminants investigated showed specific characteristics, with differences even between compounds within the same group. The differences are due to:
–  - the partition of contaminants between dissolved and adsorbed form;
–  - the response to redox conditions;
–  - the influence of microbial decay, organic production or changes in speciation.
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7.
The elastic constants of sixteen garnet specimens of wide variety in chemical composition are accurately determined by means of the rectangular parallelpiped resonance method. The dependence of the elastic properties on chemical composition is analyzed using the present data and those for seven garnets investigated by other authors. The property Xi of a garnet solid solution i is given by a linear addition law in terms of the mole fraction nij of component j; Xi = ΣnijXj where the Xj's are the properties of the end-members j (j = pyrope, almandine, spessartine, grossular and andradite). The Xj's are determined for density ρ, bulk modulus K, and shear moduli Cs = (C11 ? C12)/2 and C44. No systematic deviation is observed from the linear addition law for the elastic moduli nor for other quantities such as the elastic wave velocities. The extrapolated elastic moduli (Mbar) of the end-members are:
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8.
The system Mg2SiO4MgOH2O was investigated at pressures between 85 and 160 kbar and at temperatures between 750 and 1200°C. In runs for a gel with Mg/Si ratio of 3 and with 4.0 wt.-percent H2O, a dense hydrous magnesian silicate, denoted phase B by Ringwood and Major, was found at pressures from about 100 kbar to at least 160 kbar in the whole temperature range studied. In the following table the crystallographic parameters and chemical formula of phase B, determined in this study, are compared with those of the other dense hydrous silicates in Mg2SiO4MgOH2O.
AlmandinePyropeSpessartineGrossularAndradite
K1.779 ± 0.0081.730 ± 0.0091.742 ± 0.0091.691 ± 0.0081.379 ± 0.017
Cs0.981 ± 0.0040.925 ± 0.0040.964 ± 0.0041.106 ± 0.0040.979 ± 0.007
C440.958 ± 0.0050.919 ± 0.0050.937 ± 0.0051.017 ± 0.0060.827 ± 0.010
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9.
The problem of fitting a probability distribution, here log-Pearson Type III distribution, to extreme floods is considered from the point of view of two numerical and three non-numerical criteria. The six techniques of fitting considered include classical techniques (maximum likelihood, moments of logarithms of flows) and new methods such as mixed moments and the generalized method of moments developed by two of the co-authors. The latter method consists of fitting the distribution using moments of different order, in particular the SAM method (Sundry Averages Method) uses the moments of order 0 (geometric mean), 1 (arithmetic mean), –1 (harmonic mean) and leads to a smaller variance of the parameters. The criteria used to select the method of parameter estimation are:
PhaseCompositionSpace groupCell parametersDensity (g cm?3)
abcβ
(Å)(Å)(Å)(°)
ChondroditeMg5Si2O10H2P21/c7.9144.75210.350108.713.06
ClinohumiteMg9Si4O18H2P21/c13.6954.74710.284100.643.14
Phase AMg7Si2O14H6P637.8609.5732.96
Phase BMg23Si8O42H6P21/c10.60014.09810.092104.053.32
–  - the two statistical criteria of mean square error and bias;
–  - the two computational criteria of program availability and ease of use;
–  - the user-related criterion of acceptability.
These criteria are transformed into value functions or fuzzy set membership functions and then three Multiple Criteria Decision Modelling (MCDM) techniques, namely, composite programming, ELECTRE, and MCQA, are applied to rank the estimation techniques.  相似文献   

10.
StochasticmodelofbedrockearthquakemotionanddeterminationofitsparametersDi-TaoNIU(牛荻涛)(Xi'anUniversityofArchitecturalSciencean...  相似文献   

11.
The Subvolcanic structure of the central dike swarm associated with the Miocene Otoge ring complex and the Shitara igneous complex, central Japan, has been reconstructed. The central dike swarm was supplied from several aligned magma reservoirs. Flow lineations observed at the margin of the dikes converge towards a region that is regarded as a magma reservoir about 1–2 km below present sea level. The minimum diameter of the magma reservoir corresponds to the width of the central dike swarm, estimated to be about 3–4 km. The inferred magma reservoir of the Otoge ring complex, may have a zoned structure, as suggested by the flow lineations of dikes and the arrangement of cone sheets. Felsic magma occupied the upper part, about 1–2 km below present sea level, and basic magma the lower part, deeper than 2 km. The centre of the Shitara igneous complex is interpreted to be composed of several other shallow magma reservoirs. The distribution pattern in plan view of the central dike swarm is summarized from the frequency of dikes (defined by the number of dikes per kilometre in the direction normal to the trend of the dike swarm) and the variations of the different properties of individual dikes along the dike swarm. It has a plane of symmetry normal to the dike swarm above the magma reservoir. The patterns critical to a general understanding of the dike formation are:
1.  A region of low dike frequency is present above the magma reservoir and a radial dike pattern occurs around the magma reservoir.
2.  From both sides of the magma reservoir, the axes of high dike frequency extend symmetrically along the central zone of the dike swarm.
3.  The number as well as the individual and total thickness of felsic dikes increases towards the magma reservoir.
4.  The number of basic dikes increases towards both sides of the magma reservoir, while the individual thicknesses of basic dikes increase with distance from the magma reservoir.
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12.
Based on published literature and the response to a questionnaire sent to geomagnetic field, ionospheric and magnetospheric researchers, several methods of choosing periods of quiet conditions based on geomagnetic records, as well as other observed parameters, have been identified. Caveats with respect to using geomagnetic indices to select quiet periods include the following:
1.  Geomagnetic disturbances are strongly local. Even if the data from all available observatories indicate quiet behavior, there is the distinct possibility that some other location, not sampled, may be disturbed.
2.  Geomagnetic indices are convenient but imperfect indicators of geomagnetic activity. Indices based on a quiet-day reference level have uncertainties comparable to the threshold value for quiet conditions. Indices representing average conditions during a 24-hr UT day may not be appropriate.
3.  Geomagnetic activity does not fully reflect the range of possible factors that influence the ionosphere or magnetosphere.
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13.
Two different models, a Physical Model and a Neural Net (NN), are used for the derivation of the Photosynthetically Available Radiation (PAR) from METEOSAT data in the German Bight; advantages and disadvantages of both models are discussed. The use of a NN for derivation of PAR should be preferred to the Physical Model because by construction, a NN can take the various processes determining PAR on a surface much better into account than a non-statistical model relying on averaged relations.
Kathrin SchillerEmail:
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14.
We examine the management of livestock diseases from the producers‘ perspective, incorporating information and incentive asymmetries between producers and regulators. Using a stochastic dynamic model, we examine responses to different policy options including indemnity payments, subsidies to report at-risk animals, monitoring, and regulatory approaches to decreasing infection risks when perverse incentives and multiple policies interact. This conceptual analysis illustrates the importance of designing efficient combinations of regulatory and incentive-based policies.
Ram RanjanEmail:
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15.
An approach to the simulation of spatial random fields is proposed. The target random field is specified by its covariance function which need not be homogeneous or Gaussian. The technique provided is based on an approximate Karhunen–Loève expansion of spatial random fields which can be readily realized. Such an approximate representation is obtained from a correction to the Rayleigh–Ritz method based on the dual Riesz basis theory. The resulting numerical projection procedure improves Rayleigh–Ritz algorithm in the approximation of second-order random fields. Simulations are developed to illustrate the convergence and accuracy of the method presented.
J. C. Ruiz-MolinaEmail:
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16.
The spontaneous and evoked activity of electroreceptors were electrophysiologically studied. The results are:
1.  The spontaneous discharge rate ranged from 15 to 85 imp/s with a mode of 50 imp/s for 126 organs of 18 animals.
2.  By analysis of periodic histograms and interspike interval histograms of responses to sinusoidal electric stimulations, the frequency response characteristic was determined. The frequency response curve shows a band pass type, the band width ranged from 5 Hz to 30 Hz and the best frequency is around 15 Hz.
3.  The thresholds of responses for 47 organs were measured by injection of sinusoidal current into the organs. The threshold values were less than 0.1nA (61μV/cm) for 35 organs (74%), and less than 0.01nA (6.1 μV/cm) for the rest of 9 organs (19%).
The Chinese version of this paper appeared in the Chinese edition ofActa Seismologica Sinica,13, 380–386, 1991.  相似文献   

17.
Time series measurements from light vessel and coastal stations in the transition area of the Kattegat and the Baltic Sea are analyzed for the period August 1975 to March 1976. The data consist of daily sampled salinities from different depth levels and daily means of sea levels, surface current, and wind, respectively. The purpose of this paper is to examine the dynamics of the mass- and salt-transport during a major salt water inflow.The principal conclusions of this paper are that
1)  the dynamics of the barotropic water exchange between the Kattegat and the Baltic Sea resembles that of a Helmholtz-resonator with a geostrophically controlled flow in the connecting channel;
2)  the water exchange is forced by both the east component of the windstress over the North Sea and the windstress component in 30o true over the Baltic Sea;
3)  the salinity in the upper layer of the Kattegat is governed by a permanent weak salt flux directed from the bottom to the surface layer and the outflow of less saline Baltic water into the upper layer of the Kattegat whereas the salinity of the Belt Sea is advected by the local currents along the main channel;
4)  the most favorable conditions for a major salt inflow are initially a mean sea level of the Baltic lowered by about 30 cm followed by west winds steadily increasing over the following several ten days. Moreover, the hitherto used definition of a major salt water inflow is discussed and an improved definition is proposed.
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18.
This paper, addresses the problem of novelty detection in the case that the observed data is a mixture of a known ‘background’ process contaminated with an unknown other process, which generates the outliers, or novel observations. The framework we describe here is quite general, employing univariate classification with incomplete information, based on knowledge of the distribution (the probability density function, pdf) of the data generated by the ‘background’ process. The relative proportion of this ‘background’ component (the priorbackground’ probability), the pdf and the prior probabilities of all other components are all assumed unknown. The main contribution is a new classification scheme that identifies the maximum proportion of observed data following the known ‘background’ distribution. The method exploits the Kolmogorov–Smirnov test to estimate the proportions, and afterwards data are Bayes optimally separated. Results, demonstrated with synthetic data, show that this approach can produce more reliable results than a standard novelty detection scheme. The classification algorithm is then applied to the problem of identifying outliers in the SIC2004 data set, in order to detect the radioactive release simulated in the ‘joker’ data set. We propose this method as a reliable means of novelty detection in the emergency situation which can also be used to identify outliers prior to the application of a more general automatic mapping algorithm.
Davide D’AlimonteEmail:
Dan Cornford (Corresponding author)Email:
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Extreme atmospheric events are intimately related to the statistics of atmospheric turbulent velocities. These, in turn, exhibit multifractal scaling, which is determining the nature of the asymptotic behavior of velocities, and whose parameter evaluation is therefore of great interest currently. We combine singular value decomposition techniques and wavelet transform analysis to generalize the multifractal formalism to vector-valued random fields. The so-called Tensorial Wavelet Transform Modulus Maxima (TWTMM) method is calibrated on synthetic self-similar 2D vector-valued multifractal measures and monofractal 3D vector-valued fractional Brownian fields. We report the results of some application of the TWTMM method to turbulent velocity and vorticity fields generated by direct numerical simulations of the incompressible Navier–Stokes equations. This study reveals the existence of an intimate relationship between the singularity spectra of these two vector fields which are found significantly more intermittent than previously estimated from longitudinal and transverse velocity increment statistics.
Alain ArneodoEmail:
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