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1.
松辽盆地地下水动力场的形成与演化控制了地下水化学场的形成与分布,地下水化学分布特征又反映地下水动力场的演化结果。在地下水化学场的形成过程中,影响沉积盆地地下水化学性质的因素较多,这些因素对地下水化学性质的影响作用在垂向上具有阶段性,在平面上具有选择性。前者导致地下水化学性质的垂直分带性,从浅到深可以划分出:1)大气水下渗淡化带,2)近地表蒸发浓缩带,3)泥岩压实排水淡化带(C 1)—压滤浓缩带(C 2),4)粘土矿物脱水淡化带和5)渗滤浓缩带等5种水化学剖面单元类型。后者决定了地下水化学场的平面分区性:1)盆地边缘为大气水下渗淡化区,2)盆地中央为泥岩压实排水淡化区,3)越流区为过渡区,4)越流-蒸发区为浓缩区。在泥岩压实排水形成的离心流方向上,矿化度、Na +浓度、Cl -浓度和盐化系数升高,(CO 32-+HCO 3-、SO 42-浓度、钠氯系数(γNa +/γCl -)和脱硫系数(SO 42-/SO 42-+Cl -)降低。在大气水下渗向心流方向上,矿化度、离子浓度和钠氯系数、脱硫系数和盐化系数一致升高。 相似文献
2.
The aim of this study was to investigate the pollution parameters relating to surface and groundwaters and to establish an interaction between these for the area near Yerköy. Three characteristic facies were determined based on the results of hydrochemical analyses: (1) Na +-Cl - facies were greater the deeper the aquifer, (2) Na +-SO 42- facies were the greater portion of the shallow alluvium aquifer, and (3) Na +-HCO 3- (SO 42-) facies represented the western portion of the shallow alluvium aquifer. Based on field and laboratory observations it was found that the water of the River Delice is suitable for irrigation and domestic use whereas the water from the shallow aquifer is extremely saline and considered to have been polluted by local lithological units. Active groundwater circulation and dilution between the alluvium aquifer and the River Delice was observed. Because of the short residence time of the groundwater in this area, the hydrogeochemical concentration and the salinity were found to be low. The other portions of the alluvium aquifer bear higher concentrations of soluble ions. 相似文献
3.
Calorimetric and experimental data on AlF-bearing titanite are presented that yield thermodynamic properties of CaAlFSiO4, as well as activity-composition relations of binary titanite CaTiOSiO4-CaAlFSiO4. The heat capacity of synthetic CaAlFSiO4 was measured with differential scanning calorimetry between 170 and 850 K: CP=689.96-0.38647T+2911300T-2-8356.1T-0.5+0.00016179T2 Based on low-temperature heat capacity calculations with lattice vibrational theory (Debye model), the calorimetric entropy of CaAlFSiO4 can be expected to lie between 104.7 and 118.1 J mol-1 K-1. The temperature of the P21/a to A2/a phase change was determined calorimetrically for a titanite with XAl=0.09 (Ttransition=390 K). The decrease of the transition temperature at a rate of about 11 K per mol% CaAlFSiO4 is in good agreement with previous TEM investigations. The displacement of the reaction anorthite + fluorite = CaAlFSiO4 in the presence of CaTiOSiO4 was studied with high P-T experiments. Titanite behaves as a non-ideal, symmetrical solid-solution. The thermodynamic properties of CaAlFSiO4 consistent with a multi-site mixing model are: % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavTnhis1MBaeXatLxBI9gBam % XvP5wqSXMqHnxAJn0BKvguHDwzZbqegm0B1jxALjhiov2Daebbnrfi % fHhDYfgasaacH8srps0lbbf9q8WrFfeuY-Hhbbf9v8qqaqFr0xc9pk % 0xbba9q8WqFfea0-yr0RYxir-Jbba9q8aq0-yq-He9q8qqQ8frFve9 % Fve9Ff0dmeaabaqaciaacaGaaeqabaWaaeaaeaaakeaafaqaaiWaca % aabaGaeeyrauKaeeOBa4MaeeiDaqNaeeiAaGMaeeyyaeMaeeiBaWMa % eeiCaaNaeeyEaKNaeeiiaaIaee4Ba8MaeeOzayMaeeiiaaIaeeOzay % Maee4Ba8MaeeOCaiNaeeyBa0MaeeyyaeMaeeiDaqNaeeyAaKMaee4B % a8MaeeOBa4MaeeiiaaIaeeikaGIaeeyzauMaeeiBaWMaeeyzauMaee % yBa0MaeeyzauMaeeOBa4MaeeiDaqNaee4CamNaeeykaKIaeeiiaaIa % emizaq2aaSbaaSqaaiabdAgaMbqabaGccqWGibasdaahaaWcbeqaai % abicdaWaaaaOqaaiabg2da9iabgkHiTiabikdaYiabiEda3iabisda % 0iabicdaWiabc6caUiabiIda4iabgglaXkabiodaZiabc6caUiabic % daWiabbccaGiabbUgaRjabbQeakjabb2gaTjabb+gaVjabbYgaSnaa % CaaaleqabaGaeyOeI0IaeGymaedaaaGcbaGaee4uamLaeeiDaqNaee % yyaeMaeeOBa4MaeeizaqMaeeyyaeMaeeOCaiNaeeizaqMaeeiiaaIa % ee4CamNaeeiDaqNaeeyyaeMaeeiDaqNaeeyzauMaeeiiaaIaeeyzau % MaeeOBa4MaeeiDaqNaeeOCaiNaee4Ba8MaeeiCaaNaeeyEaKNaeeii % aaIaee4uam1aaWbaaSqabeaacqqGWaamaaaakeaacqqG9aqpcqqGXa % qmcqqGWaamcqqG0aancqqGUaGlcqqG5aqocqGHXcqScqqGXaqmcqqG % UaGlcqqGXaqmcqqGGaaicqqGkbGscqqGTbqBcqqGVbWBcqqGSbaBda % ahaaWcbeqaaiabgkHiTiabigdaXaaakiabbUealnaaCaaaleqabaGa % eyOeI0IaeGymaedaaaGcbaGaeeyta0KaeeyyaeMaeeOCaiNaee4zaC % MaeeyDauNaeeiBaWMaeeyzauMaee4CamNaeeiiaaIaeeiCaaNaeeyy % aeMaeeOCaiNaeeyyaeMaeeyBa0MaeeyzauMaeeiDaqNaeeyzauMaee % OCaiNaeeiiaaYaamWaaeaacqWGxbWvdaWgaaWcbaGaemisaG0aaWba % aWqabeaacqGHsislaaaaleqaaOGaeeivaqLaem4vaC1aaSbaaSqaai % abdohaZbqabaaakiaawUfacaGLDbaaaeaacqGH9aqpcqaIXaqmcqaI % ZaWmcqGGUaGlcqaI2aGncqGHXcqScqaIWaamcqGGUaGlcqaI0aanca % aMe8UaeeOsaOKaeeyBa0Maee4Ba8MaeeiBaW2aaWbaaSqabeaacqGH % sislcqaIXaqmaaaaaaaa!E403! |
| Enthalpy of formation (elements) df H0 |
|
|
amp; = - 2740.8 ±3.0kJmol - 1 |
| | Standard state entropy S0 |
|
|
amp; = 104.9 ±1.1 Jmol - 1 K - 1 |
| | Margules parameter [ WH- TWs ] | WV) was determined from the excess volume of mixing based on XRD measurements (214ᆦ J mol-1 kbar-1), as well as refined from the piston-cylinder experimental results (198뀺 J mol-1 kbar-1), demonstrating consistency between crystal structure data and thermodynamic properties. The stability of AlF-bearing titanite Ca(Ti,Al)(O,F)SiO4 was investigated by thermodynamic modelling in the system Ca-Al-Si-Ti-O-F-H-C and subsystems. The petrogenetic grids are in good agreement with natural mineral assemblages, in that very Al-rich titanite (XAl>0.65ǂ.15) is generally absent because it is either unstable with respect to other phases, or its stability field lies outside the P-T conditions realised on Earth. The grids explain both the predominant occurrence of natural Al-rich titanite at high metamorphic grade such as eclogite facies conditions, as well as its scarcity in blueschist facies rocks. Wide spacing of the Al-isopleths for titanite of many high-grade assemblages prevents their use as geobarometers or thermometers. The instability of end-member CaAlFSiO4 with respect to other phases in most assemblages modelled here is consistent with the hypothesis that the presence of structural stresses in the crystal lattice of CaAlFSiO4 influences its thermodynamic stability. The titanite structure is not well suited to accommodate Al and F instead of Ti and O, causing the relatively high Gibbs free energy of CaAlFSiO4, manifested in its standard state properties. Thus, the increasing amount of CaAlFSiO4 along the binary join is the reason why titanite with XAl>0.65ǂ.15 becomes unstable in most petrogenetic grids presented here. The compositional limit of natural titanite (XAlƸ.54) probably reflects the point beyond which the less stable end member begins to dominate the solid-solution, affecting both crystal structure and thermodynamic stability. 相似文献
4.
Diffusion of Zr and zircon solubility in hydrous, containing approximately 4.5 wt% H 2O, metaluminous granitic melts with halogens, either 0.35 wt% Cl (LCl) or 1.2 wt% F (MRF), and in a halogen-free melt (LCO) were measured at 1.0 GPa and temperatures between 1,050 and 1,400 °C in a piston-cylinder apparatus using the zircon dissolution technique. Arrhenius equations for Zr diffusion in each hydrous melt composition are, for LCO with 4.4ǂ.4 wt% H 2O: % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavP1wzZbItLDhis9wBH5garm % Wu51MyVXgaruWqVvNCPvMCG4uz3bqee0evGueE0jxyaibaieYlf9ir % Veeu0dXdh9vqqj-hEeeu0xXdbba9ev6pc9fs0-rqaqpepmKs4qpepe % I8kaL8kuc9pgc9q8qqaq-dhH6hb9hs0dXdHu6deP0u0-vr0-vr0db8 % meaabaqaciGacaGaaeaabaWaaeaaeaaakeaacqWGebarcqGH9aqpcq % aIYaGmcqGGUaGlcqaI4aaocqaI4aaocqGHXcqScqaIWaamcqGGUaGl % cqaIWaamcqaIZaWmcqWG4baEcqaIXaqmcqaIWaamdaahaaWcbeqaai % abgkHiTiabiIda4aaakiGbcwgaLjabcIha4jabcchaWnaabmaabaWa % aSaaaeaacqGHsislcqaIXaqmcqaI0aancqaIWaamcqGGUaGlcqaIXa % qmcqGHXcqScqaIZaWmcqaIZaWmcqGGUaGlcqaI5aqoaeaacqWGsbGu % cqWGubavaaaacaGLOaGaayzkaaaaaa!571F! D = 2.88 ±0.03 x10 - 8 exp( [( - 140.1 ±33.9)/( RT)] )D = 2.88 \pm 0.03x10^{ - 8} \exp \left( {{{ - 140.1 \pm 33.9} \over {RT}}} \right) , for LCl with 4.5ǂ.5 wt% H 2O: % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavP1wzZbItLDhis9wBH5garm % Wu51MyVXgaruWqVvNCPvMCG4uz3bqee0evGueE0jxyaibaieYlf9ir % Veeu0dXdh9vqqj-hEeeu0xXdbba9ev6pc9fs0-rqaqpepmKs4qpepe % I8kaL8kuc9pgc9q8qqaq-dhH6hb9hs0dXdHu6deP0u0-vr0-vr0db8 % meaabaqaciGacaGaaeaabaWaaeaaeaaakeaacqWGebarcqGH9aqpcq % aIYaGmcqGGUaGlcqaIZaWmcqaIZaWmcqGHXcqScqaIWaamcqGGUaGl % cqaIWaamcqaI1aqncqWG4baEcqaIXaqmcqaIWaamdaahaaWcbeqaai % abgkHiTiabisda0aaakiGbcwgaLjabcIha4jabcchaWnaabmaabaWa % aSaaaeaacqGHsislcqaIYaGmcqaI1aqncqaI0aancqGGUaGlcqaI4a % aocqGHXcqScqaI2aGncqaI0aancqGGUaGlcqaIXaqmaeaacqWGsbGu % cqWGubavaaaacaGLOaGaayzkaaaaaa!5719! D = 2.33 ±0.05 x10 - 4 exp( [( - 254.8 ±64.1)/( RT)] )D = 2.33 \pm 0.05x10^{ - 4} \exp \left( {{{ - 254.8 \pm 64.1} \over {RT}}} \right) and for MRF with 4.9ǂ.3 wt% H 2O: % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavP1wzZbItLDhis9wBH5garm % Wu51MyVXgaruWqVvNCPvMCG4uz3bqee0evGueE0jxyaibaieYlf9ir % Veeu0dXdh9vqqj-hEeeu0xXdbba9ev6pc9fs0-rqaqpepmKs4qpepe % I8kaL8kuc9pgc9q8qqaq-dhH6hb9hs0dXdHu6deP0u0-vr0-vr0db8 % meaabaqaciGacaGaaeaabaWaaeaaeaaakeaacqWGebarcqGH9aqpcq % aIYaGmcqGGUaGlcqaI1aqncqaI0aancqGHXcqScqaIWaamcqGGUaGl % cqaIWaamcqaIZaWmcqWG4baEcqaIXaqmcqaIWaamdaahaaWcbeqaai % abgkHiTiabiwda1aaakiGbcwgaLjabcIha4jabcchaWnaabmaabaWa % aSaaaeaacqGHsislcqaIYaGmcqaIYaGmcqaIZaWmcqGGUaGlcqaI4a % aocqGHXcqScqaIXaqmcqaI1aqncqGGUaGlcqaI1aqnaeaacqWGsbGu % cqWGubavaaaacaGLOaGaayzkaaaaaa!5715! D = 2.54 ±0.03 x10 - 5 exp( [( - 223.8 ±15.5)/( RT)] )D = 2.54 \pm 0.03x10^{ - 5} \exp \left( {{{ - 223.8 \pm 15.5} \over {RT}}} \right) . Solubilities determined by the dissolution technique were reversed for LCO +4.5ǂ.5 wt% H 2O by crystallization of a Zr-enriched glass of LCO composition at 1,200 and 1,050 °C at 1.0 GPa. The solubility data were used to calculate partition coefficients of Zr between zircon and hydrous melt, which are given by the following expressions: for LCO % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavP1wzZbItLDhis9wBH5garm % Wu51MyVXgaruWqVvNCPvMCG4uz3bqee0evGueE0jxyaibaieYlf9ir % Veeu0dXdh9vqqj-hEeeu0xXdbba9ev6pc9fs0-rqaqpepmKs4qpepe % I8kaL8kuc9pgc9q8qqaq-dhH6hb9hs0dXdHu6deP0u0-vr0-vr0db8 % meaabaqaciGacaGaaeaabaWaaeaaeaaakeaacyGGSbaBcqGGUbGBcq % WGebardaqhaaWcbaGaemOwaOLaemOCaihabaGaemOEaONaemyAaKMa % emOCaiNaem4yamMaem4Ba8MaemOBa4Maei4la8IaemyBa0Maemyzau % MaemiBaWMaemiDaqhaaOGaeyypa0JaeGymaeJaeiOla4IaeGOnayJa % eG4mamZaaeWaaeaadaWcaaqaaiabigdaXiabicdaWiabicdaWiabic % daWiabicdaWaqaaiabdsfaubaaaiaawIcacaGLPaaacqGHsislcqaI % 1aqncqGGUaGlcqaI4aaocqaI3aWnaaa!5924! ln DZrzircon/melt = 1.63( [10000/( T)] ) - 5.87\ln D_{Zr}^{zircon/melt} = 1.63\left( {{{10000} \over T}} \right) - 5.87 , for LCl % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavP1wzZbItLDhis9wBH5garm % Wu51MyVXgaruWqVvNCPvMCG4uz3bqee0evGueE0jxyaibaieYlf9ir % Veeu0dXdh9vqqj-hEeeu0xXdbba9ev6pc9fs0-rqaqpepmKs4qpepe % I8kaL8kuc9pgc9q8qqaq-dhH6hb9hs0dXdHu6deP0u0-vr0-vr0db8 % meaabaqaciGacaGaaeaabaWaaeaaeaaakeaacyGGSbaBcqGGUbGBcq % WGebardaqhaaWcbaGaemOwaOLaemOCaihabaGaemOEaONaemyAaKMa % emOCaiNaem4yamMaem4Ba8MaemOBa4Maei4la8IaemyBa0Maemyzau % MaemiBaWMaemiDaqhaaOGaeyypa0JaeGymaeJaeiOla4IaeGinaqJa % eG4naCZaaeWaaeaadaWcaaqaaiabigdaXiabicdaWiabicdaWiabic % daWiabicdaWaqaaiabdsfaubaaaiaawIcacaGLPaaacqGHsislcqaI % 0aancqGGUaGlcqaI3aWncqaI1aqnaaa!5920! ln DZrzircon/melt = 1.47( [10000/( T)] ) - 4.75\ln D_{Zr}^{zircon/melt} = 1.47\left( {{{10000} \over T}} \right) - 4.75 and, for MRF by % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavP1wzZbItLDhis9wBH5garm % Wu51MyVXgaruWqVvNCPvMCG4uz3bqee0evGueE0jxyaibaieYlf9ir % Veeu0dXdh9vqqj-hEeeu0xXdbba9ev6pc9fs0-rqaqpepmKs4qpepe % I8kaL8kuc9pgc9q8qqaq-dhH6hb9hs0dXdHu6deP0u0-vr0-vr0db8 % meaabaqaciGacaGaaeaabaWaaeaaeaaakeaacyGGSbaBcqGGUbGBcq % WGebardaqhaaWcbaGaemOwaOLaemOCaihabaGaemOEaONaemyAaKMa % emOCaiNaem4yamMaem4Ba8MaemOBa4Maei4la8IaemyBa0Maemyzau % MaemiBaWMaemiDaqhaaOGaeyypa0JaeGymaeJaeiOla4IaeGinaqJa % eG4naCZaaeWaaeaadaWcaaqaaiabigdaXiabicdaWiabicdaWiabic % daWiabicdaWaqaaiabdsfaubaaaiaawIcacaGLPaaacqGHsislcqaI % 0aancqGGUaGlcqaI5aqocqaIXaqmaaa!591C! ln DZrzircon/melt = 1.47( [10000/( T)] ) - 4.91\ln D_{Zr}^{zircon/melt} = 1.47\left( {{{10000} \over T}} \right) - 4.91 . Experiments on the same compositions, but with water contents down to 0.5 wt%, demonstrated reductions in both the diffusion coefficient of Zr and zircon solubility in the melt. The addition of halogens at the concentration levels studied to metaluminous melts has a small effect on either the diffusion of Zr in the melt, or the solubility of zircon at all water concentrations and temperatures investigated. At 800 °C, the calculated diffusion coefficient of Zr is lowest in LCl, 9᎒ -17 m 2 s -1, and is highest in LCO, 4᎒ -15 m 2 s -1. Extrapolation of the halogen-free solubility data to a magmatic temperature of 800 °C yields solubilities of approximately one-third of those directly measured in similar compositions, predicted by earlier studies of zircon dissolution and based upon analyses of natural rocks. This discrepancy is attributed to the higher oxygen fugacity of the experiments of this study compared with previous studies and nature, and the effect of oxygen fugacity on the structural role of iron in the melt, which, in turn, affects zircon solubility, but does not significantly affect Zr diffusion. 相似文献
5.
Multivariate analysis of physico-chemical and chemical data has enabled differentiation among groundwaters sourced from different lithological formations in the Atherton Tablelands region of north-eastern Australia. The main water resource is stored in basalt, although basement rocks such as granite and metamorphics also contain variable amounts of water. Groundwater in the basalt is mostly Mg-Ca-Na, HCO 3 type, with electrical conductivities less than 300 µS/cm and pH values from 6.5 to 8.5. Some of the other groundwater is quite similar, making the identification of hydrochemical facies difficult. Groundwater samples were grouped based on the results of a principal component factor analysis of the major dissolved constituents H 4SiO 4, Na +, Ca 2+, Mg 2+ and HCO 3-, as well as pH and electrical conductivity. Based on this differentiation it was possible to identify the likely host rocks of groundwaters from unidentified lithological units, define the basalt thickness and provide a better understanding of the groundwater resource. Principal component factor analysis has also been useful in identifying the likely hydrochemical processes controlling the composition of these groundwaters, including the production of weak acids in the soil layers, silicate mineral weathering, ion-exchange reactions, evapotranspiration and the leaching of ions from organic matter. Supplementary material to this paper can be obtained by using the Springer LINK server located at http://dx.doi.org/10.1007/s00254-002-0667-z. 相似文献
6.
Diffusion-controlled growth rates of polycrystalline enstatite reaction rims between forsterite and quartz were determined at 1,000 °C and 1 GPa in presence of traces of water. Iron-free, pure synthetic forsterite with normal oxygen and silicon isotopic compositions and quartz extremely enriched in 18O and 29Si were used as reactants. The relative mobility of 18O and 29Si in reactants and rims were determined by SIMS step scanning. The morphology of the rim shows that enstatite grows by a direct replacement of forsterite. Rim growth is modelled within a mass-conserving reference frame that implies advancement of reaction fronts from the initial forsterite-quartz interface in both directions. The isotopic compositions at the two reaction interfaces are controlled by the partial reactions Mg 2SiO 4=0.5 Mg 2Si 2O 6+MgO at the forsterite-enstatite, and MgO+SiO 2=0.5 Mg 2Si 2O 6 at the enstatite-quartz interface, implying that grain boundary diffusion of MgO is rate-controlling. Isotopic profiles show no silicon exchange across the propagating reaction interfaces. This propagation, controlled by MgO diffusion, is faster than the homogenisation of Si by self-diffusion behind the advancing fronts. From this, and using % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn % hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr % 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9 % vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x % fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamiramaaDa % aaleaacaWGtbGaamyAaiaacYcacaWGfbGaamOBaaqaaiaadAfacaWG % VbGaamiBaaaaaaa!3DD2! DSi,EnVolD_{Si,En}^{Vol} at dry conditions from the literature, results a % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn % hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr % 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9 % vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x % fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGabmirayaafa % Waa0baaSqaaiaadofacaWGPbGaaiilaiaadweacaWGUbaabaaaaOGa % eqiTdqgaaa!3CCD! D￠ Si,En dD'_{Si,En}^{} \delta value of 3᎒ -24 m 3 s -1 at 1,000 °C. The isotopic profiles for oxygen are more complex. They are interpreted as an interplay between the propagation of the interfaces, the homogenisation of the isotope concentrations by grain boundary self-diffusion of O within the rim, and the isotope exchange across the enstatite-quartz interface, which was open to 18O influx from quartz. Because of overlapping diffusion processes, boundary conditions are unstable and D´ Ox,En' cannot be quantified. Using measured rim growth rates, the grain boundary diffusivity D´ MgO' of MgO in iron-free enstatite is 8᎒ -22 m 3 s -1 at 1,000 °C and 1 GPa. Experiments with San Carlos olivine (fo 92) as reactant reveal lower rates by a factor of about 4. Our results show that isotope tracers in rim growth experiments allow identification of the actual interface reactions, recognition of the rate-controlling component and further calculation of D´ ' values for specific components. 相似文献
7.
Volume diffusion rates of Ce, Sm, Dy, and Yb have been measured in a natural pyrope-rich garnet single crystal (Py 71Alm 16Gr 13) at a pressure of 2.8 GPa and temperatures of 1,200-1,450 °C. Pieces of a single gem-quality pyrope megacryst were polished, coated with a thin layer of polycrystalline REE oxide, then annealed in a piston cylinder device for times between 2.6 and 90 h. Diffusion profiles in the annealed samples were measured by SIMS depth profiling. The dependence of diffusion rates on temperature can be described by the following Arrhenius equations (diffusion coefficients in m 2/s): % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavTnhis1MBaeXatLxBI9gBam % XvP5wqSXMqHnxAJn0BKvguHDwzZbqegm0B1jxALjhiov2DaeHbuLwB % Lnhiov2DGi1BTfMBaebbfv3ySLgzGueE0jxyaibaieYlf9irVeeu0d % Xdh9vqqj-hEeeu0xXdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9 % pgea0dXdar-Jb9hs0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaaca % qabeaadaabauaaaOqaauaabeqaeeaaaaqaaiGbcYgaSjabc+gaVjab % cEgaNnaaBaaaleaacqaIXaqmcqaIWaamaeqaaOGaemiraq0aaSbaaS % qaaiabbMfazjabbkgaIbqabaGccqGH9aqpcqGGOaakcqGHsislcqaI % 3aWncqGGUaGlcqaI3aWncqaIZaWmcqGHXcqScqaIWaamcqGGUaGlcq % aI5aqocqaI3aWncqGGPaqkcqGHsisldaqadaqaaiabiodaZiabisda % 0iabiodaZiabgglaXkabiodaZiabicdaWiaaysW7cqqGRbWAcqqGkb % GscaaMe8UaeeyBa0Maee4Ba8MaeeiBaW2aaWbaaSqabeaacqqGTaql % cqqGXaqmaaGccqGGVaWlcqaIYaGmcqGGUaGlcqaIZaWmcqaIWaamcq % aIZaWmcqWGsbGucqWGubavaiaawIcacaGLPaaaaeaacyGGSbaBcqGG % VbWBcqGGNbWzdaWgaaWcbaGaeGymaeJaeGimaadabeaakiabdseaen % aaBaaaleaacqqGebarcqqG5bqEaeqaaOGaeyypa0JaeiikaGIaeyOe % I0IaeGyoaKJaeiOla4IaeGimaaJaeGinaqJaeyySaeRaeGimaaJaei % Ola4IaeGyoaKJaeG4naCJaeiykaKIaeyOeI0YaaeWaaeaacqaIZaWm % cqaIWaamcqaIYaGmcqGHXcqScqaIZaWmcqaIWaamcaaMe8Uaee4AaS % MaeeOsaOKaaGjbVlabb2gaTjabb+gaVjabbYgaSnaaCaaaleqabaGa % eeyla0IaeeymaedaaOGaei4la8IaeGOmaiJaeiOla4IaeG4mamJaeG % imaaJaeG4mamJaemOuaiLaemivaqfacaGLOaGaayzkaaaabaGagiiB % aWMaei4Ba8Maei4zaC2aaSbaaSqaaiabigdaXiabicdaWaqabaGccq % WGebardaWgaaWcbaGaee4uamLaeeyBa0gabeaakiabg2da9iabcIca % OiabgkHiTiabiMda5iabc6caUiabikdaYiabigdaXiabgglaXkabic % daWiabc6caUiabiMda5iabiEda3iabcMcaPiabgkHiTmaabmaabaGa % eG4mamJaeGimaaJaeGimaaJaeyySaeRaeG4mamJaeGimaaJaaGjbVl % abbUgaRjabbQeakjaaysW7cqqGTbqBcqqGVbWBcqqGSbaBdaahaaWc % beqaaiabb2caTiabbgdaXaaakiabc+caViabikdaYiabc6caUiabio % daZiabicdaWiabiodaZiabdkfasjabdsfaubGaayjkaiaawMcaaaqa % aiGbcYgaSjabc+gaVjabcEgaNnaaBaaaleaacqaIXaqmcqaIWaamae % qaaOGaemiraq0aaSbaaSqaaiabboeadjabbwgaLbqabaGccqGH9aqp % cqGGOaakcqGHsislcqaI5aqocqGGUaGlcqaI3aWncqaI0aancqGHXc % qScqaIYaGmcqGGUaGlcqaI4aaocqaI0aancqGGPaqkcqGHsisldaqa % daqaaiabikdaYiabiIda4iabisda0iabgglaXkabiMda5iabigdaXi % aaysW7cqqGRbWAcqqGkbGscaaMe8UaeeyBa0Maee4Ba8MaeeiBaW2a % aWbaaSqabeaacqqGTaqlcqqGXaqmaaGccqGGVaWlcqaIYaGmcqGGUa % GlcqaIZaWmcqaIWaamcqaIZaWmcqWGsbGucqWGubavaiaawIcacaGL % Paaaaaaaaa!0C76!
| log10 DYb = ( - 7.73 ±0.97) - ( 343 ±30 kJ mol- 1 /2.303RT ) |
| | log10 DDy = ( - 9.04 ±0.97) - ( 302 ±30 kJ mol- 1 /2.303RT ) |
| | log10 DSm = ( - 9.21 ±0.97) - ( 300 ±30 kJ mol- 1 /2.303RT ) |
| | log10 DCe = ( - 9.74 ±2.84) - ( 284 ±91 &nbs\matrix{ {\log _{10} D_{{\rm Yb}} = ( - 7.73 \pm 0.97) - \left( {343 \pm 30\;{\rm kJ}\;{\rm mol}^{{\rm - 1}} /2.303RT} \right)} \cr {\log _{10} D_{{\rm Dy}} = ( - 9.04 \pm 0.97) - \left( {302 \pm 30\;{\rm kJ}\;{\rm mol}^{{\rm - 1}} /2.303RT} \right)} \cr {\log _{10} D_{{\rm Sm}} = ( - 9.21 \pm 0.97) - \left( {300 \pm 30\;{\rm kJ}\;{\rm mol}^{{\rm - 1}} /2.303RT} \right)} \cr {\log _{10} D_{{\rm Ce}} = ( - 9.74 \pm 2.84) - \left( {284 \pm 91\;{\rm kJ}\;{\rm mol}^{{\rm - 1}} /2.303RT} \right)} \cr } . There is no significant influence of ionic radius on diffusion rates; at each temperature the diffusion coefficients for Ce, Sm, Dy, and Yb are indistinguishable from each other within the measurement uncertainty. However, comparison with other diffusion data suggests that there is a strong influence of ionic charge on diffusion rates in garnet, with REE3+ diffusion rates more than two orders of magnitude slower than divalent cation diffusion rates. This implies that the Sm-Nd isotopic chronometer may close at significantly higher temperatures than thermometers based on divalent cation exchange, such as the garnet-biotite thermometer. REE diffusion rates in pyrope are similar to Yb and Dy diffusion rates in diopside at temperatures near the solidus of garnet lherzolite (~1,450 °C at 2.8 GPa), and are an order of magnitude faster than Nd, Ce, and La in high-Ca pyroxene at these conditions. At lower temperatures relevant to the lithospheric mantle and crust, REE diffusion rates in garnet are much faster than in high-Ca pyroxene, and closure temperatures for Nd isotopes in slowly-cooled garnets are ~200 °C lower than in high-Ca pyroxene. 相似文献
8.
Based on the analysis of element correlation, the Gibbs diagram, hydro-geochemical ion ratios, isoline maps of groundwater and soil, and change patterns of strontium content after normalization, the study examines water-rock interaction of shallow groundwater in Dingtao area. The results suggest that strontium in the study area mainly comes from water-rock interactions, and the strata interacting with groundwater are the top of Quaternary and Neogene. The element correlation analysis shows that the formation of strontium-rich groundwater is sufficiently affected by sulfate and carbonate. The Gibbs diagram suggests that the chemical composition of groundwater is mainly influenced by water-rock interactions, accompanied by evaporation crystallization. c(Ca 2++Mg 2+)/c(HCO 3-+SO 42-) reflects that the main reactions in the groundwater system is weathering dissolution of carbonate and sulfate, and ion exchange takes place. c(Na +)/c(Cl -) indicates that Na + in groundwater may have water-rock interactions with rocks it flows through. c(Cl -)/c(Ca 2+) indicates that the hydrodynamic condition in the pumping well is poor and the water circulation is slow. The study examines the macro isoline map change patterns, correlation curves of change of strontium content in groundwater and shallow soil, and correlation curves of change of strontium content in groundwater, shallow soil, and deep soil. The results suggest that the strontium content in the study area has the same change pattern in groundwater and in soil, which further indicates that strontium in the study area comes from water-rock interactions. 相似文献
9.
Conventional hydrochemical techniques and statistical analyses were applied to better understand the solute geochemistry and the hydrochemical process of shallow groundwater in the Qinghai Lake catchment. Shallow groundwater in the Qinghai Lake catchment is slightly alkaline, and is characterized by a high ion concentrations and low water temperature. The total dissolved solids (TDS) in most of the samples are <1,000?mg/L, i.e. fresh water and depend mainly on the concentration of SO 4 2?, Cl ? and Na +. Groundwater table is influenced directly by the residents?? groundwater consumption. Most of the groundwaters in the Qinghai Lake catchment belong to the Ca 2+(Na +) ?CHCO 3 ? type, while the Qinghai Lake, part of the Buha (BHR) and the Lake Side (LS) samples belong to the Na +?CCl ? type. The groundwater is oversaturated with respect to aragonite, calcite and dolomite, but not to magnesite and gypsum. Solutes are mainly derived from strong evaporite dissolution in Daotang, BHR and LS samples and from strong carbonate weathering in Hargai and Shaliu samples. Carbonate weathering is stronger than evaporite dissolution with weak silicate weathering in the Qinghai Lake catchment. Carbonate weathering, ion exchange reaction and precipitation are the major hydrogeochemical processes responsible for the solutes in the groundwater in the Qinghai Lake catchment. Most of the shallow groundwaters are suitable for drinking. More attention should be paid to the potential pollution of nitrate, chloride and sulfide in shallow groundwater in the future. 相似文献
10.
A survey on quality of groundwater was carried out for assessing the geochemical characteristics and controlling factors of chemical composition of groundwater in a part of Guntur district, Andhra Pradesh, India, where the area is underlain by Peninsular Gneissic Complex. The results of the groundwater chemistry show a variation in pH, EC, TDS, Ca 2+, Mg 2+, Na +, K +, HCO 3 ?, Cl ?, SO 4 2?, NO 3 ? and F ?. The chemical composition of groundwater is mainly characterized by Na +?HCO 3 ? facies. Hydrogeochemical type transits from Na +–Cl ?–HCO 3 ? to Na +–HCO 3 ?–Cl ? along the flow path. Graphical and binary diagrams, correlation coefficients and saturation indices clearly explain that the chemical composition of groundwater is mainly controlled by geogenic processes (rock weathering, mineral dissolution, ion exchange and evaporation) and anthropogenic sources (irrigation return flow, wastewater, agrochemicals and constructional activities). The principal component (PC) analysis transforms the chemical variables into four PCs, which account for 87% of the total variance of the groundwater chemistry. The PC I has high positive loadings of pH, HCO 3 ?, NO 3 ?, K +, Mg 2+ and F ?, attributing to mineral weathering and dissolution, and agrochemicals (nitrogen, phosphate and potash fertilizers). The PC II loadings are highly positive for Na +, TDS, Cl ? and F ?, representing the rock weathering, mineral dissolution, ion exchange, evaporation, irrigation return flow and phosphate fertilizers. The PC III shows high loading of Ca 2+, which is caused by mineral weathering and dissolution, and constructional activities. The PC IV has high positive loading of Mg 2+ and SO 4 2?, measuring the mineral weathering and dissolution, and soil amendments. The spatial distribution of PC scores explains that the geogenic processes are the primary contributors and man-made activities are the secondary factors responsible for modifications of groundwater chemistry. Further, geochemical modeling of groundwater also clearly confirms the water–rock interactions with respect to the phases of calcite, dolomite, fluorite, halite, gypsum, K-feldspar, albite and CO 2, which are the prime factors controlling the chemistry of groundwater, while the rate of reaction and intensity are influenced by climate and anthropogenic activities. The study helps as baseline information to assess the sources of factors controlling the chemical composition of groundwater and also in enhancing the groundwater quality management. 相似文献
11.
The chemical content of the Souss unconfined groundwater displays spatial variations in conductivity (between 400 and 6,000 µS cm -1). The chemical tracers (Cl -, SO 42-, Sr 2+, Br -), which characterize the different components of the groundwater, allowed the determination of the origin of water salinity. Cl - and SO 42-, reaching respectively 2,000 and 1,650 mg L -1, display localized salinity anomalies. Br -/Cl - ratio distinguishes marine-influenced impoverished zones versus the oceanic domain. Thus, salinity anomalies can be attributed: (1) downstream, to a currently existing salt-encroachment (with added waste water) and sedimentary palaeosalinity, (2) in the middle-Souss, to High Atlas evaporites and to irrigation water recycling. Sr 2+/Ca 2+ ratio (evaporites if >1), confirms the evaporitic origin of the anomalies along the right bank of oued Souss. Furthermore, it facilitates the distinction between the different aquifer contributions (Cretaceous, Jurassic and Triassic), and it highlights leakage from deep Turonian limestones in the groundwater recharge system. To the south, recharge is from the Anti Atlas (evaporite-free) waters. Oxygen-18 measurements confirm the groundwater recharge from the High and Anti Atlas as piezometric maps and chemical tracers suggested, plus from leakage from the Turonian and the marine aquifers. 相似文献
12.
Systematic hydrogeochemical survey has been carried out for understanding the sources of dissolved ions in the groundwaters
of the area occupied by Sarada river basin, Visakhapatnam district, Andhra Pradesh, India. Khondalites, charnockites and granite
gneisses and calc-granulites of Precambrians and alluvial deposits of Quaternaries underlie the study area. Groundwaters are
both fresh and brackish; the latter waters being a dominant. Most groundwaters are characterized by Na +:HCO 3− facies due to chemical weathering of the rocks. Enrichment of Na +, K +, Cl −, SO 42−, NO 3− and F − in some groundwater samples is caused by seawater intrusion, locally accompanied by ion-exchange, and anthropogenic activities,
resulting in an increase of brackish in the groundwaters. Based on the results of this hydrogeochemical study, suitable management
measures are recommended to solve the water quality problems. 相似文献
13.
A series of Fe and Mg partition experiments between plagioclase and silicate liquid were performed in the system SiO 2-Al 2O 3-Fe 2O 3-FeO-MgO-CaO-Na 2O under oxygen fugacities from below the IW buffer up to that of air. A thermodynamic model of plagioclase solid solution for the (CaAl,NaSi,KSi)(Fe 3+,Al 3+)Si 2O 8-Ca(Fe 2+,Mg)Si 3O 8 system is proposed and is calibrated by regression analysis based on new and previously reported experimental data of Fe and Mg partitioning between plagioclase and silicate liquid, and reported thermodynamic properties of end members, ternary feldspar and silicate liquid. Using the derived thermodynamic model, FeO t, MgO content and Mg/(Fe t+Mg) in plagioclase can be predicted from liquid composition with standard deviations of ǂ.34 wt% (relative error =9%) and ǂ.08 wt% (14%) and ǂ.7 (8%) respectively. Calculated Fe 3+-Al exchange chemical potentials of plagioclase, m Fe3 + ( Al )- 1 Pl{\rm \mu }_{{\rm Fe}^{{\rm 3 + }} \left( {{\rm Al}} \right)_{{\rm - 1}} }^{{\rm Pl}} agree with those calculated using reported thermodynamic models for multicomponent spinel, m Fe3 + ( Al )- 1 Sp{\rm \mu }_{{\rm Fe}^{{\rm 3 + }} \left( {{\rm Al}} \right)_{{\rm - 1}} }^{{\rm Sp}} and clinopyroxene, m Fe3 + ( Al )- 1 Cpx{\rm \mu }_{{\rm Fe}^{{\rm 3 + }} \left( {{\rm Al}} \right)_{{\rm - 1}} }^{{\rm Cpx}} . The FeO t content of plagioclase coexisting with spinel or clinopyroxene is affected by Fe 3+/(Fe 3++Al) and Mg/(Fe+Mg) of spinel or clinopyroxene and temperature, while it is independent of the anorthite content of plagioclase. Three oxygen barometers based on the proposed model are investigated. Although the oxygen fugacities predicted by the plagioclase-liquid oxygen barometer are scattered, this study found that plagioclase-spinel-clinopyroxene-oxygen and plagioclase-olivine-oxygen equilibria can be used as practical oxygen barometers. As a petrological application, prediction of plagioclase composition and f O2 are carried out for the Upper Zone of the Skaergaard intrusion. The estimated oxygen fugacities are well below QFM buffer and consistent with the estimation of oxidization states in previous studies. 相似文献
14.
The system Ca 2Al 3Si 3O 11(O/OH)-Ca 2Al 2FeSi 3O 11(O/OH), with emphasis on the Al-rich portion, was investigated by synthesis experiments at 0.5 and 2.0 GPa, 500-800 °C, using the technique of producing overgrowths on natural seed crystals. Electron microprobe analyses of overgrowths up to >100 µm wide have located the phase transition from clinozoisite to zoisite as a function of P-T-X ps and a miscibility gap in the clinozoisite solid solution. The experiments confirm a narrow, steep zoisite-clinozoisite two-phase loop in T-X ps section. Maximum and minimum iron contents in coexisting zoisite and clinozoisite are given by X pszo (max) = 1.9*10 - 4 T+ 3.1*10 - 2 P - 5.36*10 - 2{\rm X}_{{\rm ps}}^{{\rm zo}} {\rm (max) = 1}{\rm .9*10}^{ - 4} T{\rm + 3}{\rm .1*10}^{ - 2} P - {\rm 5}{\rm .36*10}^{ - 2} and X psczo (min) = (4.6 * 10 - 4 - 4 * 10 - 5 P) T + 3.82 * 10 - 2 P - 8.76 * 10 - 2{\rm X}_{{\rm ps}}^{{\rm czo}} {\rm (min)} = {\rm (4}{\rm .6} * {\rm 10}^{ - {\rm 4}} - 4 * {\rm 10}^{ - {\rm 5}} P{\rm )}T + {\rm 3}{\rm .82} * {\rm 10}^{ - {\rm 2}} P - {\rm 8}{\rm .76} * {\rm 10}^{ - {\rm 2}} (P in GPa, T in °C). The iron-free end member reaction clinozoisite = zoisite has equilibrium temperatures of 185ᇆ °C at 0.5 GPa and 0ᇆ °C at 2.0 GPa, with ( Hr0=2.8ǃ.3 kJ/mol and ( Sr0=4.5ǃ.4 J/mol2K. At 0.5 GPa, two clinozoisite modifications exist, which have compositions of clinozoisite I ~0.15 to 0.25 X ps and clinozoisite II >0.55 X ps. The upper thermal stability of clinozoisite I at 0.5 GPa lies slightly above 600 °C, whereas Fe-rich clinozoisite II is stable at 650 °C. The schematic phase relations between epidote minerals, grossular-andradite solid solutions and other phases in the system CaO-Al 2O 3-Fe 2O 3-SiO 2-H 2O are shown. 相似文献
15.
The least evolved Jurassic Ferrar tholeiites from southern Prince Albert Mountains (Antarctica) are characterized by the occurrence of orthopyroxene (opx), a mineralogical feature virtually absent in the tholeiites from the large igneous provinces of Karoo (South Africa) and Paraná (Brazil). Petrography suggests that opx is the early phase in the sequence of crystallization and mineral chemistry indicates that it is in equilibrium with the host rock. In general, MELTS modeling predicts that opx is the liquidus phase in the Ferrar tholeiites with MgO higher than ~7 wt% at P=1.5-5 kbar, H 2O=0-1 wt% and % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavTnhis1MBaeXatLxBI9gBae % bbnrfifHhDYfgasaacH8YjY-vipgYlH8Gipec8Eeeu0xXdbba9frFj % 0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs0dXdbPYxe9 % vr0-vr0-vqpWqaaeaabiGaaiaacaqabeaabaqaamaaaOqaaiabdAga % MTWaaSbaaeaacqqGpbWtaeqaaWWaaSbaaeaadaWgaaqaaiabikdaYa % qabaaabeaakiabg2da9iabbgfarjabbAeagjabb2eanjabgkHiTiab % igdaXiaaysW7cyGGSbaBcqGGVbWBcqGGNbWzaaa!381A! = QFM - 1 f_{\rm O} _{_2 } = {\rm QFM} - 1\;\log unit conditions. MELTS results also show that the early crystallization of opx is primarily controlled by high SiO 2 and high SiO 2/CaO, chemical characteristics typical of the Ferrar tholeiites, but not shown by the Karoo and Paraná analogs with similar MgO content. Major element geochemistry of the least evolved Ferrar tholeiite has been modeled through fractional crystallization and fractional crystallization coupled with crustal assimilation processes, starting from natural peridotite-derived experimental melts. Mass balance and MELTS modeling support the argument that theoretical magma compositions suitable to be primary to the least evolved Ferrar tholeiites are compatible with hydrous (H 2O=0.3-0.5 wt%) and anhydrous melts obtained at 10-15 kbar by high melting degrees (>25%) of fertile and depleted spinel lherzolites, respectively, and later contaminated by the high-grade metamorphic rocks from the Victoria Land crystalline basement. The genesis of primary Ferrar tholeiites does not necessarily reflect the generally assumed depleted source mantle being also compatible with a fertile one. 相似文献
16.
Groundwater samples collected from the East Bokaro coalfield of Jharkhand state, India during the dry and rainy seasons of the year 2012. Samples were analyzed for the assessment of groundwater quality in the study area. The results of the chemical analysis indicate that the pH values were found alkaline in nature during both the season. The major cations in groundwater was in the order of Na +>Ca 2+>Mg 2+>K + during the dry season while Ca 2+>Na +>Mg 2+>K + during the rainy season. The abundance of the major anions was of HCO 3->SO 42->Cl ->NO 3->F - did not change on the seasonal basis. The average NO 3-concentration was exceeded the desirable limit for drinking water as per Indian standard in the rainy season. Silicate weathering was inferred to be a dominant process, controlling the groundwater chemistry in both seasons, with lesser contributions by carbonate weathering and ion exchange. Leaching of salts from the unsaturated zone also has a major impact on groundwater quality during the rainy season. The water quality data indicate that groundwater is generally suitable for irrigation. However, higher salinity and residual sodium carbonate values at some sites may limit groundwater use and therefore an adequate drainage and water management plan for the study area is required. 相似文献
17.
Groundwaters were collected around the Spence porphyry copper deposit, Atacama Desert, northern Chile, to study water-porphyry copper ore bodies interaction and test hypotheses regarding transport of metals through thick overburden leading to the formation of soil geochemical anomalies. The deposit contains 400 Mt of 1% Cu and is completely buried by piedmont gravels of Miocene age. Groundwaters were recovered from the eastern up hydraulic gradient (upflow) margin of the Spence deposit, from within the deposit, and for two kilometers down flow from the deposit. Water table depths decrease from 90 m at the upflow margin to 30 m 1.5 km down flow. Groundwaters at the Spence deposit are compositionally variable with those upflow of the deposit characterized by relatively low salinities (900-7000 mg/L) and Na +-SO 42−-type compositions. These waters have compositions and stable isotope values similar to regional groundwaters recovered elsewhere in the Atacama Desert of Northern Chile. In contrast, groundwaters recovered within and down flow of the deposit range in salinity from 10,000 to 55,000 mg/L (one groundwater at 145,000 mg/L) and are dominantly Na +-Cl −-type waters. Dissolved sulfate values are, however, elevated compared to upflow waters, and δ 34S CDT decreases into the deposit (from >4‰ to 2‰), consistent with increasing influence of sulfur derived from oxidation of sulfide minerals within the deposit. The increase in salinity and conservative tracers (Cl −, Br −, Li +, and Na +) and the relationship between oxygen and hydrogen isotopes suggests that in addition to water-rock reactions within the deposit, most of the compositional variation can be explained by groundwater mixing (with perhaps a minor role for evaporation). A groundwater-mixing scenario implies a deeper, more saline groundwater source mixing with the less saline regional groundwater-flow system. Flow of deeper, more saline groundwater along pre-existing structures has important implications for geochemical exploration and metal-transport models. 相似文献
18.
The solubility mechanisms of H 2O in peralkaline sodium aluminosilicatequenched melts (anhydrous NBO/T = 0.5) have been studied withRaman spectroscopy as a function of Al/(Al + Si) (0–0–3)and H 2O content (0–7.5 wt.%). The coexisting structuralunits in the anhydrous quenched melts are TO2 (Q4), T2O5(Q3),and TO3 (Q2). In Al-free Na 2Si 4O 9 (NS4) melt, H 2O forms complexes with Na +(Na–OH bonds) and with Si 4+ (Si–OH bonds). MolecularH 2O is also detected. TO3 structural units are not detectedin this composition. In the H 2O concentration range between0 and 4 wt.%, there is an approximately 20% increase in NBO/Tresulting from the increased abundance ratio, T 2O 5/TO2. Withfurther increments in water activity, the NBO/T of hydrous NS4melt is reduced. The depolymerization results from hydroxylationof the silica tetrahedra, whereas polymerization is due to formationof complexes with Na–OH bonding. In Al-bearing compositions on the Na 2Si 4O 9–Na 2(NaAl) 4O 9–join, there is evidence for Al–OH bonding in additionto Na–OH and Si–OH bonds. Among these complexes,the relative abundance of those with Si–OH bonds diminisheswith increasing Al/(A1 + Si), whereas complexes with Al–OHand Na–OH bonds become more important. Complexes withNa–OH bonds dominate for H 2O4 wt.%, whereas complexeswith Al–OH dominate at higher water content. The threestructural units, TO 3, T 2O 5, and TO 2, were observed in bothanhydrous and hydrous peralkaline sodium aluminosilicate melts.Their abundance varies, however, with the H 2O concentrationin the melts. The NBO/T decreases to a minimum (a 30–50%lowering of NBO/T relative to anhydrous materials) for low H 2Ocontents (3–4 wt.% H 2O), and increases as the H 2O contentis increased further. 相似文献
19.
Pollution of groundwater by seawater intrusion poses a threat to sustainable agriculture in the coastal areas of Korea. Therefore, seawater intrusion monitoring stations were installed in eastern, western, and southern coastal areas and have been operated since 1998. In this study, groundwater chemistry data obtained from the seawater intrusion monitoring stations during the period from 2007 to 2009 were analyzed and evaluated. Groundwater was classified into fresh (<1,500 μS/cm), brackish (1,500–3,000 μS/cm), and saline (>3,000 μS/cm) according to EC levels. Among groundwater samples ( n = 233), 56, 7, and 37% were classified as the fresh, brackish, and saline, respectively. The major dissolved components of the brackish and saline groundwaters were enriched compared with those of the fresh groundwater. The enrichment of Na + and Cl − was especially noticeable due to seawater intrusion. Thus, the brackish and saline groundwaters were classified as Ca–Cl and Na–Cl types, while the fresh groundwater was classified as Na–HCO 3 and Ca–HCO 3 types. The groundwater included in the Na–Cl types indicated the effects of seawater mixing. Ca 2+, Mg 2+, Na +, K +, SO 4 2−, and Br − showed good correlations with Cl − of over r = 0.624. Of these components, the strong correlations of Mg 2+, SO 4 2−, and Br − with Cl − ( r ≥ 0.823) indicated a distinct mixing between fresh groundwater and seawater. The Ca/Cl and HCO 3/Cl ratios of the groundwaters gradually decreased and approached those of seawater. The Mg/Cl, Na/Cl, K/Cl, SO 4/Cl, and Br/Cl ratios of the groundwaters gradually decreased, and were similar to or lower than those of seawater, indicating that Mg 2+, Na +, K +, SO 4 2−, and Br −, as well as Cl − in the saline groundwater can be enriched by seawater mixing, while Ca 2+ and HCO 3 − are mainly released by weathering processes. The influence of seawater intrusion was evaluated using threshold values of Cl − and Br −, which were estimated as 80.5 and 0.54 mg/L, respectively. According to these criteria, 41–50% of the groundwaters were affected by seawater mixing. 相似文献
20.
A hydrological and geochemical investigation of the Prairie Flats surficial uranium deposit in Summerland, BC was undertaken to identify the principal controls on uranium deposition. A network of piezometers was installed and used to measure the hydraulic conductivities of the host sediments as well as the general flow direction and aqueous geochemistry of the resident groundwaters. Two hydrostratigraphic units were identified: a peat and clay unit overlying a sand and gravel unit. Measured hydraulic conductivities were on the order of 10 -7 and 10 -5 m/s, respectively, and the vertical hydraulic gradients indicate significant groundwater discharge upward into the peat and clay unit. Prairie Flats groundwaters are neutral to alkaline in pH, enriched in Ca 2+ and HCO 3-, and have dissolved uranium concentrations ranging from 10 to nearly 1,000 µg/l. Groundwater flow and geochemistry data were used to estimate the flux of uranium in groundwater at the site. A major fraction of the uranium is taken up by adsorption to organics. There is also evidence for subsequent desorption by the formation of soluble complexes with bicarbonate. Uranium that is not held by adsorption is most likely precipitated as uraninite, UO 2(c). Reducing conditions in the peat and clay unit (Eh<0.1 V) relative to the underlying sand and gravel unit (Eh>0.2 V) may explain the high concentrations of uranium nearer ground surface. The current flux of uranium into the flats is significantly smaller than that calculated from the size and age of the deposit, which may be an indication of changing rates of deposition in response to varying climatic and hydrogeologic conditions over time. 相似文献
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