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Statistically secured relations between nutrient concentrations in the water and characteristics of the catchment areas can be proved for the storage reservoirs of the GDR. The o–PO4 concentration during the full overturn in spring shows a close relation to the population density of the catchment area. Existing differences of concentration between drinking-water and industrial-water storage reservoirs can be attributed to different degrees of worthiness of protection of the catchment areas and to differences of the water morphology. The NO3 concentration is closely correlated with the proportion of agriculturally used area in the catchment area. The mass ratio NO3–N: o–PO4–P mostly lies above the limiting range of the limitation of nitrogen (> 12: 1), so that phosphorus becomes the central quantity of a possible control of the trophic level. Especially for drinking-water storage reservoirs in the weakly eutrophic range the reduction of the P-load is necessary and it has a high trophy-improving effect here. 相似文献
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Excessive inputs of phosphorus and nitrogen are the main reasons of eutrophication of inland waters and coastal areas. Large efforts have been made to control phosphorus, but the measures to reduce nitrogen emissions failed at least partly. While it was possible to reduce nitrogen emissions from industry and municipal wastewater treatment plants, diffuse sources are showing only very minor decline. Examples of limnetic, marine and coastal systems are given to review the current knowledge about nitrogen transformation and the effects of nitrate in the environment. When N is the limiting nutrient in a particular water body, this does not necessarily mean that phytoplankton is controllable by NO3– removal. In systems with problems due to a high redox‐sensitive internal phosphorus load and under certain constraints, nitrate may be used as an ecotechnological measure to prevent anaerobic phosphorus release from sediments. Model simulations are used to demonstrate this. A schematic model of redox‐mediated temporal phosphorus storage in riverine lake sediments with short retention time is proposed. We conclude that while anthropogenic nitrogen emissions are a global problem, no fast and simple single solution exists. Additional nitrogen removal in wastewater treatment will have no effect, as long as diffuse sources and nitrate concentrations in groundwater remain at a high level. Emission reductions should be achieved in an integrated way, taking direct and indirect effects into account. In this sense, case by case decisions and a new definition of “sensitive areas” are required. 相似文献
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K.-E. Quentin 《洁净——土壤、空气、水》1988,16(4):385-396
Altogether 10… 20 kg/ha·a N from precipitation are introduced into the soil. The fertilization of the agriculturally used area increased from 50 to 120 kg/ha·a N between 1950 and 1982. The nitrogen concentration is theoretically increased by 0.4 mg/l due to infiltration of surface water and wastewaters. The data prove agriculture to the main source of the nitrate load of groundwater, especially in regions with predominantly intensive agricultural use there is delivered drinking water with nitrate concentrations of more than 50 mg/l. The fixing of the limit value for drinking water at 50 mg/l nitrate (value recommended by the EC: 25 mg/l) is justified by new findings. Since the technology of nitrate elimination from water is very expensive, mainly the preventing of too high nitrate concentrations should be aimed at by agricultural measures of ground-water protection. 相似文献
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J. Malý 《洁净——土壤、空气、水》1985,13(2):137-147
As the introduction, the advantages and drawbacks of a large number of phosphorus determination methods and digestion techniques for particulate matter, as e. g. sewage sludge, used in practice are described. The results of some investigations concerning the techniques of digestion as well as the further preparation of the extracts for the phosphorus determination proper are graphically and in tabular form represented and interpreted. The investigated photo-metric methods may be disturbed by iron and silicic-acid components. Advice about, and possibilities for avoiding such disturbances are given. In the case of the simultaneous application of the Kjeldahl digestion for the determination of nitrogen as well as of phosphorus there should be paid attention to possible disturbances by the selenium- or mercury-containing catalyst additives in the further processing of samples due to the formation of deposits. 相似文献
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Ground-water levels in the Upper Floridan aquifer beneath the southeastern coast of South Carolina have undergone pumpage-induced declines approaching 20 ft below sea level at the southern end of Hilton Head Island. This scenario suggests the potential exists for the inducement of recharge to the Upper Floridan aquifer across the island, which could affect the quality of water being pumped by wells. However, low radiocarbon concentrations in ground-water samples (0.5 to 1.4 ± 0.1 PMC) indicate that most of the water is relict ground water reflecting prepumpage ground-water flow conditions in the Upper Floridan aquifer. The isotopic data indicate long residence times and water-chemistry evolution more characteristic of ground-water recharge occurring farther inland prior to the commencement of pumpage in the late 1800s. Radiocarbon concentrations (as Percent Modern Carbon) and stable carbon isotope ratios (as δ13C in dissolved inorganic carbon) determined during this study and reported in other studies on and around Hilton Head Island varied in a systematic manner. Heavier δ13C values (–2.8 to –1.6 per mil) in ground water beneath southern Hilton Head Island reflect ground-water discharge from prepumpage flowpaths originating over 100 miles away, hence a depletion in radiocarbon concentration with corrected ground-water ages no younger than 16,000 yrs BP. In contrast, lighter δ13C values (–13.9 to –8.67 per mil) beneath the northern part of the island indicate recent recharge as a result of water-level declines, and recharge in areas off the island that have not changed as a result of pumpage (evidenced by enrichment in radiocarbon with corrected ground-water ages no older than 4,000 yrs BP). This suggests that the δ13C composition of ground water in the Upper Floridan aquifer is a useful indicator of mixing between ground waters from different sources, and can be used to delineate recharge-discharge patterns. This approach may be applicable to other aquifers of highly evolved ground-water chemistry in regional carbonate aquifer systems that may be receiving recent recharge. Moreover, this approach could prove useful in delineating the contribution of recent water being captured by pumped wells as part of wellhead protection programs designed to assess aquifer vulnerability from surficial contaminant sources. 相似文献
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U. Wegener 《洁净——土壤、空气、水》1983,11(3):279-293
Prerequisite to the nitrogen leaching from agricultural soils in spring is the ecologically optimum control of the first nitrogen fertilizer application. On the basis of investigations having been carried out for some years, a method for determining the optimum time of fertilization with the aid of phenological data is presented. The blossoming data of Anemone nemorosa proved to be a suitable sensitive indicator, their onset of blossoming is the optimum time for the first nitrogen application. In dependence on the height and variation of weather, in the subdued mountains this time is 90 … 116 d after the beginning of the year and corresponds to a temperaturetotal ≥ 5°C of 80 … 120°C or > 0°C: 160 … 230°C. Possibly, the leaf development of Alchemilla vulgaris or the first development of Poa pratensis are suitable as other bioindicators. The boundary conditions and disturbance variables of the bioindication are discussed. By the phenological date-determination of the beginning of fertilization the nitrogen losses can be reduced by 10 … 20% and the nitrate leaching can be considerably reduced especially in drinking-water protection areas. 相似文献
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Spatial variability of ocean fertilizing nutrients in the dust‐emitting ephemeral river catchments of Namibia 
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下载免费PDF全文 Research into global hot spots of dust emission has focused on exposed fine‐grained sediments in palaeo‐ or ephemeral dryland lake basins including Etosha (Namibia) and Makgadikgadi (Botswana) in southern Africa. Namibia's western ephemeral river valleys are also known to produce dust but have remained largely overlooked as a regionally significant source. Nutrient enrichment of valley sediments and proximity to the South Atlantic suggests aeolian dust could play an important role in ocean fertilization. The fertility of valley dust is dependent on fluvial sediments originating in the upper catchments on the Southern African Central Plateau. In this study we investigate climate, geology, vegetation and land use variability and how these may influence the nitrogen, phosphorus and iron availability in the catchments. We intensely sampled the Huab, Kuiseb and Tsauchab river systems to map the spatial distribution of nutrients from upper catchments to river termini. Samples were analysed for the bioavailable fractions of iron, nitrogen and phosphorus as well as total nitrogen and phosphorus. Results show that the lower valley reaches are sources of aeolian dust enriched in nutrients. Nitrogen levels correlate with precipitation and vegetation levels and phosphorus levels with geology. However, differences in upper catchment sediment nutrient levels were not representative of downstream nutrient differences between valleys. Rather, it is the hydrological and geomorphological processes of the ephemeral river systems that are key for producing the enriched sediments in the lower reaches. We demonstrate that the ephemeral river valleys of western Namibia are an extensive and enriched source of mineral dust that could play a critical role in marine productivity of the southern Atlantic. © 2017 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd. 相似文献
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The main objective of this study was to characterize the ecological conditions that prevail after the application of chicken, cow and pig manure. Three treatments, chicken, cow, pig manure and a control were assigned to aquadams in a completely randomized design and each treatment was replicated three times. The aquadams were fertilized 2 weeks before the fish were stocked. One hundred Oreochromis mossambicus (mean weight ±40 g) were stocked in each aquadam. Water physico-chemical parameters (temperature, dissolved oxygen, pH, electrical conductivity, salinity, turbidity, ammonia, nitrite, total alkalinity as calcium carbonate, and phosphorus) were determined once a week for the duration of the experiment. Zooplankton and phytoplankton in the different treatments were enumerated once every 2 weeks. The relationship between phytoplankton communities and the water physico-chemical parameters were evaluated using canonical correspondence analysis (CCA). The CCA indicated that the physico-chemical variables which best explain the distribution of phytoplankton were carbonate alkalinity, pH, phosphate, potassium, nitrogen and dissolved oxygen. Phytoplankton abundance was highest in chicken manure because the optimum nutrient conditions for the growth of phytoplankton were found in this treatment. Zooplankton abundance was also highest in the chicken manure treatment. The control was associated with one phytoplankton taxa, Chlorella. The numerical contribution of the different food items in the stomachs of O. mossambicus was determined. The diet of O. mossambicus was dominated by phytoplankton particularly Microcystis species. Total coliforms and Escherichia coli were used to assess the microbiological quality of the water in the different manure treatments. Chicken manure had the lowest total coliform and E. coli count. However, chicken manure had the highest Bacillus count. The implications of the microbial load in the chicken, cow and pig manure are discussed. 相似文献
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The performance of one pilot‐scale and two full‐scale membrane bioreactors (MBR) were evaluated based on the control of main operational parameters, composition of microbial community and pathogens concentration in the treated outlet. Plants were designed for 0.75 m3/day (A), 60 m3/day (B) and 30 m3/day (C). Inlet and outlet samples were monitored for chemical oxygen demand (COD), biological oxygen demand, total suspended solids, ammonia nitrogen concentration (NH4–N), nitrate nitrogen concentration, total Kjeldahl nitrogen, total phosphorus and phosphate phosphorus concentration concentrations. Plants showed good COD removal: 91.9% for Plant A, 97.8% for Plant B and 94.2% for Plant C. The targeted nitrogenous ion was NH4–N due to the requirements for outlet limits. NH4–N removal was moderate for Plant A (73.3%) and Plant B (86.1%) and excellent for Plant C (>99%). Excellent phosphorus removal was achieved by Plant A (average outlet concentration was 0.7 mg/L, efficiency 84.7%). Unsatisfactory results for phosphorus removal were achieved at the full‐scale plants due to operational problems. The dependency between the extracellular polymeric substances increase and decreasing mixed liquor volatile suspended solids for both lab and full‐scale plants was confirmed. Soluble microbial product concentrations were reduced by 65–68% after coagulant dosage for Plant A. Outlets from the MBR plants were monitored for the presence of pathogens (thermotolerant coliforms, Escherichia coli, intestinal Enterococci and culturable microorganisms at 22 and 37°C). The treated effluent from Plant A, B and C met Czech national legislation regarding reuse criteria (standards) for environment, irrigation and swimming purposes. Plants B and C were not able to achieve requirements for potable water and personal hygiene quality standards. 相似文献
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骆马湖营养盐收支 总被引：3，自引：0，他引：3
根据对骆马湖1998年度营养盐（氮,磷）收入和支出的研究,结果表明,入湖氮,磷量分别为15764．78t和1035．53t,其中通过河道入湖的氮磷量最大,其年入湖氮磷量分别为13598．05t和942．35t,分别占总来源量的86．3％和91．0％,氮,磷在骆马湖湖体中的滞留量和沉降量较,滞留量分别为1532．65t和221．63t,分别占总来源量的9．7％和21．4％,沉积量分别为205．47t和199．95吨,分别占总业源量的1．3％和19．3％,湖水氮,磷蓄积变化大,湖水浓度升高较快,氮磷负荷较大,年平均负荷量分别为总氮42．04％g/m^2和总磷2．76g/m,^2。 相似文献
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Torben A. Bonde 《Marine pollution bulletin》1994,29(6-12):450-454
The history and rationale of environmental regulation with respect to nutrient emissions from Danish agriculture is briefly outlined, while the current regulation is detailed through reference to and statement of actual paragraphs in statutory orders. The present regulations mainly concern nitrogen losses in the form of farm waste discharges, ammonia volatilization from animal manure and nitrate leaching from agricultural land. Being an important nutrient, phosphorus is only considered implicitly in the regulations. The main elements of the regulations include provisions for storage capacity of animal manure, livestock density on a farm basis, and mandatory submission of fertilizer and crop rotation plans to the authorities. The fertilizer plans and the resulting agricultural practices with respect to the use of both commercial fertilizers and animal manures must comply with normative fertilizer values, stated as a function of the yield expectation of agricultural crops, and minimum utilization efficiencies of animal manure. It is thus a violation of Danish laws and regulations to apply more fertilizer than indicated by the normative values in the statutory orders (and violation of the provisions may be punished by fines). The current regulations apply advisory and regulatory instruments. Financial instruments are not used. It is therefore important that where aspects of the common agricultural policy have a potential to reduce nutrient emissions, this potential is used to the full. 相似文献
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TOC Determinations in Ground Water 总被引：2，自引：0，他引：2
Michael J. Barcelona 《Ground water》1984,22(1):18-24
Determinations of total organic carbon (TOC) can provide valuable diagnostic evidence of the extent of ground-water contamination by organic compounds. The usefulness of conventional TOC results in monitoring efforts is limited by the bias introduced during the purging of inorganic carbon prior to analysis. A modified TOC procedure has been evaluated to permit the quantitation of the volatile organic carbon (VOC) fraction in water samples. The methodology consists of trapping the VOC in a manner analogous to commercial purge and trap instruments which are used for specific organic compound separations. The method has been found to be sensitive, accurate and reasonably precise for TOC determinations of standard solutions as well as on ground-water samples. Volatile organic carbon levels can range from 9–50% of the TOC in both uncontaminated and contaminated ground waters. The reporting of the volatile and nonvolatile fractions of the TOC will enhance both monitoring and research efforts, since it permits more complete characterization of the organic carbon content of ground-water samples. 相似文献
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Soil quality is more difficult to define than air and water quality but it has an impact especially on the latter. The export of soil-based nutrients to waters is of increasing concern. Policy aiming at preservation of soil quality can be either effect-orientated or source-orientated. Statutory measures for soil protection in the Netherlands originate from the Soil Protection Act (SPA), which came into force in January, 1987. The SPA still is a framework law which provides very general regulations only. Practical implementation is achieved by means of General Administrative Orders (GAO). The law offers a framework for measures and regulations to protect the properties of soil which constitute the conditions for proper soil functioning. The first GAO introduced was the ‘Decree on use of animal manure’, which became operational on 1 April 1987. During recent decades there has been a large increase of intensive animal husbandry in the Netherlands. This development led to a strong imbalance between minerals imported in the country in the form of feed and raw materials for feed production, and minerals exported by dairy and animal products. The minerals produced in manure and animal slurries are far exceeding the amounts needed for proper crop fertilization. Standards for the use of animal manure are based on the phosphate content but this results in the application of unacceptable amounts of nitrogen and heavy metals. Phosphate saturation of soil was safeguarded by introducing special regulations for P-saturated soils. However, this has not been successful on judicial basis, indicating the need for general environmental protection legislation, instead of the compartmental (air-water-soil) approach. 相似文献
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Robert Kreuzig 《洁净——土壤、空气、水》2010,38(8):697-705
Veterinary medicines and biocides are frequently applied in animal houses of livestock husbandry. Due to these application patterns, they reach liquid manure. So far these substances are not transformed during manure storage, they enter soil by the application of manure as organic fertilizer. Therefore, biodegradability of veterinary medicines and biocides in manure is in the focus of regulatory procedures of environmental risk assessment. Since the representative and reproducible sampling of manures from high volume tanks is considered impossible due to high matrix variabilities, the reference manure concept was developed to utilize liquid bovine and pig manures for reproducible laboratory testing. Accordingly, excrement samples of cattle and pigs individually kept at experimental and conventional animal houses were taken. Tap water was added to matrix characterized excrements in order to prepare bovine and pig reference manures of 10 and 5% dry substance contents, respectively. Subsequently, the long‐term transformation of selected 14C‐labeled test substances was investigated under strictly anaerobic conditions. The application of different batches of bovine or pig reference manures indicated that extrapolation of transformation rates within the same animal species was possible. However, results cannot be transferred from bovine to pig manure because of substance specific interactions with the different manure matrices. The dependency of metabolic dynamics on different dry substance contents (2.5, 5, 10%) was additionally investigated in both manure matrices. These tests clearly showed that the dry substance content of the reference manure is one of the most relevant factors affecting the transformation of veterinary medicines and biocides. In contrast to highly variable tank manures, the reference manure concept allows for the exact adjustment of this parameter to guarantee reproducible laboratory testing. 相似文献
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Thorsten Christian Rudolf J. Schneider Harald A. Frber Dirk Skutlarek Michael T. Meyer Heiner E. Goldbach 《洁净——土壤、空气、水》2003,31(1):36-44
In the last years more and more often detections of antimicrobially active compounds (“antibiotics”) in surface waters have been reported. As a possible input pathway in most cases municipal sewage has been discussed. But as an input from the realm of agriculture is conceivable as well, in this study it should be investigated if an input can occur via the pathway application of liquid manure on fields with the subsequent mechanisms surface run‐off/interflow, leaching, and drift. For this purpose a series of surface waters, soils, and liquid manures from North Rhine‐Westphalia (Northwestern Germany) were sampled and analyzed for up to 29 compounds by HPLC‐MS/MS. In each of the surface waters antibiotics could be detected. The highest concentrations were found in samples from spring (300 ng/L of erythromycin). Some of the substances detected (e.g., tylosin), as well as characteristics in the landscape suggest an input from agriculture in some particular cases. In the investigation of different liquid manure samples by a fast immunoassay method sulfadimidine could be detected in the range of 1…2 mg/kg. Soil that had been fertilized with this liquid manure showed a content of sulfadimidine extractable by accelerated solvent extraction (ASE) of 15 μg/kg dry weight even 7 months after the application. This indicates the high stability of some antibiotics in manure and soil. 相似文献
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Impacts of climate variability on water quality with best management practices in sub‐tropical climate of USA 下载免费PDF全文
下载免费PDF全文 Efficiency of non‐point source pollution control methods may be altered in future climate. This study investigated climate change impacts on sediment and nutrient transport, and efficiency of best management practices (BMPs), in the Upper Pearl River Watershed (UPRW) in Mississippi. The Soil and Water Assessment Tool was applied to the UPRW using observed flow, sediment and nutrient data. Water quality samples were collected at three US geological survey gauging stations. The model was successfully calibrated and validated for daily time steps (Nash Sutcliffe efficiency and coefficient of determination – R2 up to 0.7) using manual and automatic (sequential uncertainty fitting version 2) methods from February 2010 to May 2011. Future weather scenarios were simulated using the LARS‐WG model, a stochastic weather generator, with Community Climate System Model, global climate model, which was developed by the National Center for Atmospheric Research in the USA. On the basis of the Special Report on Emissions Scenarios A1B, A2 and B1 of the Intergovernmental Panel on Climate Change, climate change scenarios were simulated for the mid (2046–2065) and late (2080–2099) century. Effectiveness of four BMPs (Riparian buffer, stream fencing, sub‐surface manure applications and vegetative filter strips) on reducing sediment and nutrient were evaluated in current and future climate conditions. Results show that sediment, nitrogen and phosphorus loadings will be increased up to a maximum of 26.3%, 7.3% and 14.3%, respectively, in future climate conditions. Furthermore, the effectiveness of BMPs on sediment removal will be reduced in future climate conditions, and the efficiency of nitrogen removal will be increased, whereas phosphorus removal efficiency will remain unchanged. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献