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1.
铀矿石和固体环境样品用Na2O2,NaOH在650°C快速熔融后,用HCl中和到pH值近似为9,以Fe(OH)3载带210Po,调HCl酸度为0.2-0.4mol/L,用抗坏血酸保护镀片,在70°C时自镀3h,210Po的回收率可达97.8±1.4%。产生的硅胶不影响测量结果。  相似文献   

2.
冀东高级变质岩石的流体包裹体研究   总被引:5,自引:5,他引:5  
刘树文 《岩石学报》1995,11(4):375-385
冀东高级变质的石榴石斜长片麻岩、含或不含石榴石的角闪二辉斜长片麻岩、紫苏花岗岩、斜长角门岩等岩石中的流体包裹体主要有4类,按形成的先后顺序依次为:(1)H2O和CO2两液相包裹体,CO2的部分均一温度是-12℃,密度1.04g/cm3,H2O含量21%~39%(mole%),CO2含量50%~71%(mole%);(2)CO2液相包裹体,冰点温度-56℃~-61℃,均一温度-7.4℃~-35.1℃,CO2密度约为1.05g/cm3,CO2含量82.1%~98.4%(mole%),还有少量的CH4、N2和H2等组分;(3)H2O和CO2多相包裹体,CO2的部分均一温度7℃~28℃,CO2密度为0.64~0.93g/cm3,气相组分以CO2、CH4和CO为主,液相成分主要是H2O和CO2;(4)多世代盐水溶液包裹体,冰点温度-0.5℃~-20℃,盐度0.87%~22.8%(wt%),盐水密度0.7~1.05g/cm3,均一温度在150℃~200℃和约300℃,存在两个峰值。不同世代的流体包裹体记录了等密度降温的P-T路径。包裹体反映的变质作用早期降温过程流体的H2O/H2O+CO2(mole)比值降低,晚期升高  相似文献   

3.
对碘偶氮氯膦与铅显色反应及其应用   总被引:2,自引:0,他引:2  
杨敏思  王曙  陈刚莲 《岩矿测试》1995,14(4):292-294
研究了对碘偶氮氯膦(CPA-pI)与Pb ̄2+的显色反应。在pH5.8的(CH_2)_6N。-NO_3缓冲介质中,Pb ̄2+与CPA-pl形成1:2的蓝绿色配合物,在675nm处测定配合物的吸光度,其表现摩尔吸光系数为2.47×10 ̄4L.mol ̄-1·cm ̄-1Pb ̄2+浓度在0~1.16×10 ̄-5mol/L即0~2.4μml)符合比尔定律。试验了20余种共存离子的影响,经共沉淀结合巯基棉分离预处理试样溶液后,测定了硫精砂中微量Pb的含量。  相似文献   

4.
在熔融的2PbO.B2O3中(974K),用滴溶量热法测定了298K下由组分K2CO3和CaCO3形成的复碳酸盐K2Ca(CO3)2(它有胶方解石和碳钾钙石两种多型)和K2Ca2(CO3)3为-7.2±5.8kJ/mol。同时推算出了复碳酸盐生砀熵变ΔSt。假定具有序结构的胶方解石的ΔSt=0,则碳钾钙石的生成熵为40.9±5.1J/mol.K,K2Ca2(CO3)3为39.4±7.3J/mol.  相似文献   

5.
热液体系中Si的络合作用   总被引:1,自引:0,他引:1  
在不同温度、PH和硅浓度条件下,实验标定了Au-SiO以及Sn-SiO2之间的络合反应:Au^++H3SiO4^-之间的络合反应:Au^++H4SiO=AuH3SiO4 lgK=-1.65436+9611.21/T;Sn^4++4H3SiO4^-=Sn(H3SiO4)4;lgK200c=42.73。通过与Au-Cl、Au-HS以及Sn-OH络合物迁移能力的比较,表明在具地质意义的P睡EH条件下,A  相似文献   

6.
作者利用桂北太古代四堡群的变质岩和用化学试剂配制该变质岩的化学成分作为试料(加入纯锡粉末10mg),分别用纯水,C(KF)=0.3mol/L+C(Nacl)=0.1mol/L和C(H_3BO_3)=0.2mol/L水溶液作为反应介质,在200-50MPa压力和580-750℃温度的范围内进行实验,结果形成含锡黑云母花岗岩的造岩矿物──石英、正长石、奥-钠长石、黑云母和锡石。作者通过显微镜下油浸法测定和X射线分析,阐述这些造岩矿物的主要光学特征,并探讨它们共生的物理化学条件,为壳源重熔型花岗岩的形成提供了造岩矿物学的理论佐证.  相似文献   

7.
研究了二个三元体系Li+/CO2-3,B4O2-7H2O(1)和K+/CO2-3,B4O2-7H20(2)298K时的相平衡关系和平衡液相的物化性质(密度、折光密、粘度、电导率、pH值)。研究表明:这二个三元体系均属简单共饱型,无复盐或固溶体形成。体系(1)的两段溶解度曲线对应于无水Li2CO3和Li2B4O7·3H2O结晶区,体系(2)的两段溶解度曲线对应于K2CO3·3/2H2O和K2B4O7·4H2O结晶区。  相似文献   

8.
石门超大型雄黄矿床流体包裹体丰富。包裹体液相成分中富Na+、Cl-和K+、SO2-4,气相成分中H2O占绝对优势,少量CO2,成矿流体化学类型属Cl SO4 Na K型水。雄黄、雌黄形成于低温(180~90℃)、低压(20~5MPa)、浅成(175~700m)、弱酸性(pH:4.67、4.43)和弱还原(Eh:-0.265V)条件。流体包裹体氢氧同位素研究表明,成矿流体主要为古大气降水,并混有盆地建造水,大气降水下渗、循环、加热、淋滤形成了中-低盐度[w(NaCl):16.03%~4.27%],中等密度(0.863~1.065g/cm3),含矿地下热水。  相似文献   

9.
感耦等离子体发射光谱法测定原油中痕量铁镍铜钒   总被引:3,自引:0,他引:3  
系统地试验了用感耦等离子体发射光谱同时测定原油中痕量元素Fe、Ni、Cu和V的多种前处理方法,制定出H2SO4、HNO3分步炭化,500℃灰化,HCl+HNO3(VHCl∶VHNO3=1∶1)溶解灰分的最佳分解方案。该方法的检出限为1.0~6.0μg/L,精密度好,RSD(n=4)<4.6%,加标回收率为96.2%~111%。方法已应用于大庆、苏北、惠州等原油样品的分析。  相似文献   

10.
一种新型高效复合消毒剂:二氧化氯消毒剂虞承伟(地质矿产部山西省中心实验室)1ClO_2为强氧化剂在酸性条件下,ClO_2有很强的氧化性:ClO_2+4H ̄++5e=Cl ̄-+H_2O在水处理条件下(pH=7),ClO_2+e=,E_0=0.95V+2...  相似文献   

11.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

12.
Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931.  相似文献   

13.
PALEONTOLOGY     
正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.)  相似文献   

14.
正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.)  相似文献   

15.
正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.)  相似文献   

16.
PETROLOGY     
正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus.,  相似文献   

17.
正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an  相似文献   

18.
正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of  相似文献   

19.
正20140582 Fang Xisheng(Key Lab.of Marine Sedimentology and Environmental Geology,First Institute of Oceanography,State Oceanic Administration,Qingdao 266061,China);Shi Xuefa Mineralogy of Surface Sediment in the Eastern Area off the Ryukyu Islands and Its Geological Significance(Marine Geology Quaternary Geology,ISSN0256-1492,CN37  相似文献   

20.
正20141810 Bian Yumei(Geological Environmental Monitoring Center of Liaoning Province,Shenyang 110032,China);Zhang Jing Zoning Haicheng,Liaoning Province,by GeoHazard Risk and Geo-Hazard Assessment(Journal of Geological Hazards and Environment Preservation,ISSN1006-4362,CN51-1467/P,24(3),2013,p.5-9,2 illus.,tables,refs.)  相似文献   

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