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1.
The crystallinity and mineralogy of both the glauconite and the clay fraction of samples from six contemporary marine environments were investigated by X-ray diffraction. In those areas where glauconite is now forming, the mineralogy and the degree of crystallinity of both the glauconite pellets and the associated clay fraction are similar. In contrast, detrital and relic glauconites are observed to have mineralogies that are different from their clay fractions. No consistent relationship was observed between degree of crystallinity and color of the pellets. Further, only two classes of glauconite as defined by BURST (1958) were common: expandable, interlayered clays and two or more clay minerals in a mixed assemblage. Based on the clay fraction-glauconite similarities and other supporting evidence, glauconite on the Scotia Ridge is concluded to be authigenic. Glauconite from Santa Monica Bay, California and from the continental shelf off Morocco appear to be detrital. Glauconite pellets in the shelf sediments off Guinea and the southeastern Atlantic Shelf of the United States are both detrital and authigenic. The poor crystallinity exhibited by the Chatham Rise glauconite is in contrast to the well-crystallized associated clay fraction and indicates that they are not genetically related. However, the origin of this glauconite remains in doubt.  相似文献   

2.
F.G. Bell 《Engineering Geology》1994,36(3-4):257-266
The Lower Cretaceous in North Yorkshire is represented by a marine succession termed the Speeton Clay. The principal minerals in these clays consist of quartz, mica and clay minerals, although pyrite, glauconite and siderite are notable in some beds. The proportions of clay minerals change within the Speeton Clay and generally illite becomes more important in the younger horizons.

The Speeton Clay is a silty clay which generally has a high plasticity, the latter being influenced by the proportion of clay fraction present. All the clays tested were inactive although they would appear to have a potential for expansion. Neither the plasticity nor the moisture content were affected by depth.

In terms of its undrained shear strength, most of the Speeton Clay could be regarded as a stiff clay. It was also insensitive with generally a low slake-durability index. Its coefficients of volume compressibility were characteristic of overconsolidated and heavily overconsolidated days.  相似文献   


3.
The mineral composition and geochemistry of poppy-shaped ores, which represented river-bed alluvium and interore clay sediments formed in oxbow zones of the Lisakov deposit (northern Kazakhstan), are examined. Specific features of trace element distribution in oolitic ores, magnetic concentrate of oolites, interore clays, and fine clay fraction are analyzed.  相似文献   

4.
黏土矿物古气候意义研究的现状与展望   总被引：6，自引：1，他引：5  
系统地分析了利用海洋沉积物、古土壤、湖盆沉积物中黏土矿物进行古气候环境研究的现状、存在问题和发展趋势。海洋沉积物的物源范围广,影响因素复杂,其中的碎屑黏土矿物所指示的古气候参数只能用于解释母源区的气候变化,而只有自生黏土矿物才能指示沉积区的气候;古土壤形成于特定的地质背景条件下,尤其是发育于火山物质母岩之上的风化自生黏土矿物,可以准确地指示该区的古气候条件;湖盆沉积物的物源范围小,沉积物中的黏土矿物可以更有效地运用于古气候环境的分析。对于沉积物中黏土矿物来源的分析,可以借助晶体中cv空位和tv空位的精细结构特征进行判断;在风化改造的红土剖面研究中,因强烈的化学风化、淋滤和迁移,黏土矿物方法具有独特的优势。风化过程中形成的一些亚种或过渡性黏土矿物,以及同生沉积过程中形成的黏土矿物,对气候环境的变化更加敏感,应加强这方面的研究。此外,在造山带的气候环境演化研究中,自生黏土矿物稳定同位素可以更可靠地指示气候环境的变化。  相似文献   

5.
东海表层沉积物碎屑矿物组合分布特征及其物源环境指示   总被引：1，自引：1，他引：0  
张凯棣  李安春  董江  张晋 《沉积学报》2016,34(5):902-911
为进一步明确东海陆架区的沉积物物源及水动力环境,对研究区表层沉积物的碎屑矿物进行了鉴定分析。研究区共鉴定出49种重矿物、8种轻矿物。根据碎屑矿物的组合分布结合矿物形态特征,将东海陆架区划分为三个矿物区,内陆架矿物区、外陆架矿物区及虎皮礁矿物区。内陆架矿物区,动力分选是影响碎屑矿物分布的主要因素,物质来源相对单一,碎屑矿物主要来源于现代长江物质,闽浙沿岸近岸河流的输入,人类活动也对该区的矿物组成产生一定的影响;外陆架矿物区,重矿物分布的主控因素是长期的分选作用,主要是长江物质经后期改造形成,现代长江物质可从内陆架中北部扩散至124.5°E左右,此外外陆架东南部地形的变化也对碎屑矿物的分布起到一定控制作用;虎皮礁矿物区,有来自黄河、长江、火山物质的多重影响,且水动力环境相对复杂。  相似文献   

6.
Comparative investigations were made on the non-carbonate components of calcareous sediments of the upper chalk formation of the Hanover region.The mineral composition of the residues insoluble in 0.5 n HC1 has first been determined optically and by X-ray photographs and described. The quantitative analysis of the components contained was effected by microscopic counting using the phase contrast method up to the grain size of 2 u, and for the clay fractions proper by X-ray phase analyses.In addition to the minor components (feldspars, biotite, pyrite, marcasite, glauconite, heavy minerals and mikro-fossils) the residues contain quartz, muscovite, illite, montmorillonite and kaolinite.The calcareous sediments of the upper senon formation are specially characterized by the occurrence of authigenic heulandite crystals which could be analysed and described here for the first time. Moreover secondary crystallization of quartz, turmaline and albite could be observed in all the samples analysed.  相似文献   

7.
There are two general types of sedimentary glauconite in Recent ocean sediments: terrigenous-allogenic and authigenic glauconite. Recent sediments of the oceans contain mainly terrigenous-allogenic glauconite (shelf and continental slope) which is formed from ancient glauconite-bearing rocks on coasts, islands and the ocean floor. The age of terrigenous-allogenic glauconite ranges from 2 to 70 m.y. (8 samples from the Atlantic Ocean, 13 from the Pacific Ocean, 1 from the Indian Ocean). The area of terrigenous-allogenic glauconite distribution correlates very well with the area of distribution of glauconite-bearing rocks on land and does not correlate with the climate and bathymetry.Authigenic glauconite is seldom found in Recent ocean sediments. The sediments with authigenic glauconite form transition zones between sediments with organic carbon, H2S and sulphide near coasts and oxidized sediments of the ocean floor (red clay and others). The areas of authigenic glauconite distribution are not yet well known. The formation of authigenic glauconite occurs mainly during diagenesis of sediments by synthesis from interstitial solutions and/or alteration of clay minerals.  相似文献   

8.
The study of REE distribution in the clay fraction of sedimentary rocks from two coalfields made it possible to distinguish several types of REE distribution, which correlate with their mineral composition. It is shown that the REE fractionation was related to the mineral reconstruction of the primary clay fraction and some detrital minerals in the course of postsedimentary transformations of rocks during diagenesis, early catagenesis, and beginning of late catagenesis. These transformations were governed by several factors, such as the composition of sediments; hydrochemical features of accumulation environment; the chemical composition, dynamics, and feeding sources of pore solutions; the porosity and permeability of sediments and rocks; and the content of organic matter and its reaction ability.  相似文献   

9.
Stream-sediment and soil geochemical data from the Upper and Lower Coastal Plains of South Carolina (USA) were studied to determine relationships between soils and stream sediments. From multi-element associations, characteristic compositions were determined for both media. Primary associations of elements reflect mineralogy, including heavy minerals, carbonates and clays, and the effects of groundwater. The effects of groundwater on element concentrations are more evident in soils than stream sediments. A “winnowing index” was created using ratios of Th to Al that revealed differing erosional and depositional environments. Both soils and stream sediments from the Upper and Lower Coastal Plains show derivation from similar materials and subsequent similar multi-element relationships, but have some distinct differences. In the Lower Coastal Plain, soils have high values of elements concentrated in heavy minerals (Ce, Y, Th) that grade into high values of elements concentrated into finer-grain-size, lower-density materials, primarily comprised of carbonates and feldspar minerals (Mg, Ca, Na, K, Al). These gradational trends in mineralogy and geochemistry are inferred to reflect reworking of materials during marine transgressions and regressions. Upper Coastal Plain stream-sediment geochemistry shows a higher winnowing index relative to soil geochemistry. A comparison of the 4 media (Upper Coastal Plain soils and stream sediments and Lower Coastal Plain soils and stream sediments) shows that Upper Coastal Plain stream sediments have a higher winnowing index and a higher concentration of elements contained within heavy minerals, whereas Lower Coastal Plain stream sediments show a strong correlation between elements typically contained within clays. It is not possible to calculate a functional relationship between stream sediment–soil compositions for all elements due to the complex history of weathering, deposition, reworking and re-deposition. However, depending on the spatial separation of the stream-sediment and soil samples, some elements are more highly correlated than others.  相似文献   

10.
Upper Eocene detrital silica grains (chert and quartz) of the Hampshire Basin display alteration and replacement fabrics by glauconite. Silica grains have etched surfaces due to glauconitization which appear green in reflected light and thin section. Quartz grains were glauconitized by surface nucleation and replacement, which spreads from the margin with progressive glauconitization, replacing the quartz grain interior. Chert grains were glauconitized by surface replacement and nucleation internally along cracks and in pores. Different forms of glauconite are associated with the two minerals; glauconite associated with quartz is generally highly-evolved whereas glauconite associated with chert is of the evolved variety. This is interpreted as being due to different surface-reaction control mechanisms associated with the two forms of silica. There is no evidence to suggest that glauconite evolved in stages from a nascent form. Two crystalline morphological forms of glauconite are found associated with both quartz and chert. Glauconite growing within a confined space has a laminated morphology whilst glauconite occurring on the surface has a rosette morphology.  相似文献   

11.
Mineralogical and geochemical factors influencing the quality of the recharge water in the London Basin aquifer system (Tertiary Sands and Cretaceous Chalk) are identified, and phase associations for Fe (pyrite, glauconite, and smectite), Mn (carbonates, gypsum, and clays) and S (gypsum, pyrite, and organic matter) established. Concentrations of these elements vary considerably on a local scale, making basinwide predictions difficult. The oxidation of pyrite is a process of major significance, controlled to a certain extent by stratigraphic factors, particularly the thickness of clay cover to the aquifer sediments that controls access of air and surface water.  相似文献   

12.
To compare relative reaction rates of mineral dissolution in a mineralogically simple groundwater aquifer, we studied the controls on solute concentrations, Sr isotopes, and rare earth element and yttrium (REY) systematics in the Cape Cod aquifer. This aquifer comprises mostly carbonate-free Pleistocene sediments that are about 90% quartz with minor K-feldspar, plagioclase, glauconite, and Fe-oxides. Silica concentrations and pH in the groundwater increase systematically with increasing depth, while Sr isotopic ratios decrease. No clear relationship between 87Sr/86Sr and Sr concentration is observed. At all depths, the 87Sr/86Sr ratio of the groundwater is considerably lower than the Sr isotopic ratio of the bulk sediment or its K-feldspar component, but similar to that of a plagioclase-rich accessory separate obtained from the sediment. The Si-87Sr/86Sr-depth relationships are consistent with dissolution of accessory plagioclase. In addition, solutes such as Sr, Ca, and particularly K show concentration spikes superimposed on their respective general trends. The K-Sr-87Sr/86Sr systematics suggests that accessory glauconite is another major solute source to Cape Cod groundwater. Although the authigenic glauconite in the Cape Cod sediment is rich in Rb, it is low in in-grown radiogenic 87Sr because of its young Pleistocene age. The low 87Sr/86Sr ratios are consistent with equilibration of glauconite with seawater. The impact of glauconite is inferred to vary due to its variable abundance in the sediments. In the Cape Cod groundwater, the variation of REY concentrations with sampling depth resembles that of K and Rb, but differs from that of Ca and Sr. Shale-normalized REY patterns are light REY depleted, show negative Ce anomalies and super-chondritic Y/Ho ratios, but no Eu anomalies. REY input from feldspar, therefore, is insignificant compared to input from a K-Rb-bearing phase, inferred to be glauconite. These results emphasize that interpretation of groundwater chemistry, even in relatively simple aquifers, may be complicated by solute contributions from “exotic” accessory minerals such as glauconite. To detect such peculiarities, groundwater studies should combine the study of elemental concentration and isotopic composition of several solutes that show different geochemical behavior.  相似文献   

13.
Numerous previous studies indicate that several different authigenic aluminosilicates form in the oceans. In this study we show, using dissolved Al distributions in sediments and waters from the nearshore regions of the East China Sea, that the process of aluminosilicate formation probably begins rapidly upon contact of detrital clays with seawater. Statistical analyses of dissolved Al-Si-H+ relations in surface sediments indicate that the minerals forming in East China Sea sediments low in dissolved Fe are dioctahedral chlorites with an average composition EX0.91Mg0.77Al5.0Si2.7O10(OH)8 (where EX = exchangeable + 1 cation). This composition is also consistent with dissolved Al and Si measurements as a function of salinity in turbid overlying waters. Results suggest a dissolution—reprecipitation mechanism for clay mineral reconstitution. This mechanism can help to explain why different authigenic clays are found in different areas of the oceans. In the East China Sea the total amount of authigenic clays present must constitute a very minor fraction of the bottom sediments. Thus, the formation of these minerals has a relatively small impact upon dissolved Si distributions. Clay mineral reconstitution in nearshore regions may provide a mechanism for buffering sediments and overlying waters with respect to pH, as the composition of minerals formed should be a direct function of the H+ activity in the surrounding environment.  相似文献   

14.
关于东海现代沉积物中的海绿石,前人曾有过报道,但都限于一般性的描述。近年来我们对东海表层沉积物中的海绿石进行了较为系统的研究,工作范围为东经121°-129°,北纬26°30′-32°00′,样品233个。分别进行了镜下鉴定、透射电镜和扫描电镜观察,并以多晶X-射线衍射法,化学全分析、差热分析、红外吸收光谱和电子探针等方法进行较系统的矿物学研究。本文就东海表层沉积物中海绿石的矿物学特征,产状及分布进行阐述,并对其成因作了初步的探讨。  相似文献   

15.
Grain size and mineral composition of core sediments were used to investigate influences of various terrestrial and marine conditions, which have prevailed on the southwestern Black Sea shelf during the Holocene. Siliciclastic mud with small amounts of sand and gravel from nearby coastal hinterland is the principal sediment type, whereas sediments deposited near the shelf edge and the Istanbul Strait and off the Duru Lake （a paleo-river mouth） constitued large quantities of sand and gravel of both biogenic and terrigenic origin. Variable amounts of aragonite, 1 nmmicas, quartz, feldspars, calcite and dolomite constitute the dominant non-clay minerals in bulk sediments. The clay mineral assemblage in the 〈 2 μm fraction is made up of smectite, illite, kaolinite and chlorite. Aragonite and calcite are mainly derived from benthic accumulations, whereas feldspars （mainly plagioclase） and smectite reflect magmaticvolcanic provenance and the distribution of 1 nm-micas and chlorite correlate with nearby metamorphic sources onland. Nevertheless, grain size and mineral distribution generally indicate a combination of effects of wind and wave climate, longshore and offshore cyclonic currents, changing sea-level stands and nearby source rock and morphological conditions. It is also suggested that at least part of clay minerals could be derived from the northwesterly Danube River input.  相似文献   

16.
The Late Cretaceous sedimentary sequence in the Upper Benue Trough consists of seven formations. Outcrop samples from the type localities of these units were analysed by X-ray diffraction for their day mineral content. The composition and distribution of the clay minerals are influenced by tectonics, relief and water depth. Three main depositional phases are recognizable on the basis of clay mineral assemblages, two of which are associated with tectonic movements. The first phase, characterized by the presence of chlorite, illite, kaolinite and mixed-layer clays is common to Albian-Cenomanian sediments. This phase is succeeded by mixed-layer clays and smectite-rich, Turonian-Early Santonian sediments. The re-occurrence of chlorite and illite in association with kaolinite and mixed-layer clays in the Post-Santonian sediments constitutes the third depositional phase. These clay mineral assemblages are indicative of two periods of tectonism (Albian and Late Santonian) and an intervening Turonian-Early Santonian period of quiescence in the Upper Benue Trough.  相似文献   

17.
西沙群岛琛航岛碳酸盐沉积物X射线定量分析方法研究   总被引：1，自引：0，他引：1  
曲高生 《矿物学报》1990,10(4):360-369
利用X射线衍射分析技术测定碳酸盐沉积物中的矿物成分及其含量是目前研究碳酸盐最有效的方法。本文根据西沙琛航岛碳酸盐矿物组成的具体情况采用了“自清洗法”,用峰值强度测定方解石、白云石、文石和石英的含量,用方解石特征峰所在位置确定其MgCO_3含量,对西沙琛航岛碳酸盐沉积物进行了比较全面的定量分析测定,取得了较好的效果,从而对西沙群岛第四纪礁相沉积作用、白云岩化作用、地球化学、年代学、地层学等问题的解决提供了有价值的资料。  相似文献   

18.
The purpose of this paper is to characterize the materials developed in the middle Tajo River valley, Central Spain. These sediments are loess, the characterization of which has not been reported in the international bibliography. The sediments are related to the next geological context and their characterization is indispensable to locate the said material in the adequate environment. A few different methods have been employed in this study, such as the pipette method (for determining the grain size) and separation of the light and heavy minerals of the sand fraction by using bromoform. The mineralogical composition was determined by XRD and textural study was accomplished by SEM/EDX. The loessic materials are silt-clay or sandy-silt that are quite unstable. The mineralogical composition shows quartz, feldspar, calcite and clay minerals. Some samples show gypsum; this mineral and calcite present dissolution and stability problems. The heavy minerals starting from the sand fraction are tourmaline, zircon, garnet, staurolite, sillimanite and biotite associations. The studies carried out with SEM show that the quartz grain surfaces present etch pits typical of the wind-blown origin.  相似文献   

19.
We studied recent sedimentation in small saline and brackish lakes located in the Ol’khon region (western Baikal area) with arid and semiarid climate. The lakes belong to the Tazheran system; it is a series of compactly located closed shallow lakes, with a limited catchment area and different mineralization, under the same landscape, climatic, geologic, and geochemical conditions. Two complementary approaches are applied in the research: (1) a detailed study of individual lake and (2) a comparison of the entire series of lakes, which can be considered a natural model for studying the relationship between endogenic mineral formation and the geochemistry of lake waters. The lake waters and bottom sediments were studied by a set of modern methods of geochemistry, mineralogy, and crystal chemistry. The mineral component of the bottom sediments was analyzed by powder X-ray diffraction (XRD), IR spectroscopy, and electron microscopy. The lakes are characterized by predominant carbonate sedimentation; authigenic pyrite, smectite, chlorite, and illite are detected in assemblage with carbonate minerals in the bottom sediments. Carbonate phases have been identified, and their proportions have been determined in the samples by decomposition of the complex XRD profiles of carbonate minerals into peaks using the Pearson VII function. Mathematical modeling of the XRD profiles of carbonates has revealed that predominantly Mg-calcites with variable Mg content and excess-Ca dolomite accumulate in lake bottom sediments influenced by biogenic processes. Aragonite, monohydrocalcite, and rhodochrosite form in some lakes along with carbonates of the calcite-dolomite series. We show a dependence of the composition of the assemblages of the newly formed endogenic carbonate minerals and their crystallochemical characteristics on the chemical composition of lake waters.  相似文献   

20.
Siliciclastic sediments on the insular shelf of Puerto Rico are derived from a volcanic arc. The sands are feldspatholithic and subquartzose. They confirm predictions about sandstones of arc derivation in the following ways. The quartz content is low, usually less than 25 %. Feldspar is more abundant than quartz, but less so than lithic fragments. If mud rip-up clasts are excluded from the lithic suite, the ratio V/L (volcanic lithic grains to total unstable lithic grains) assumes values near 0.75. Most of the volcanic lithic grains have textures suggesting intermediate volcanics as source rocks. Ratios of plagioclase to total feldspar are high. Values of the parameter C/Q (stable lithic fragments to total lithic grains) are higher than expected for sandstones of volcanic provenance. Four compositionally and areally distinct assemblages of clay minerals are recognized. Clay suites characterized by major concentrations of both halloysite and smectite are found off the north-west coast. Sediments off the north-central and north-east coasts contain major concentrations of halloysite and lesser amounts of smectite, illite and chlorite. Major concentrations of kaolinite are present off the south-east coast. An assemblage of poorly crystallized smectite with lesser amounts of illite and chlorite occurs off the south-west and south-central coasts. Variation in the mineralogic composition of clays around the perimeter of the island reflects changes in the intensity of chemical weathering and the type of rock exposed in the immediate source area and, in instances, either early diagenetic alteration or, more likely, sorting within the clay fraction by currents on the shelf.  相似文献   

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