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1.
Meteoric waters from cold springs and streams outside of the 1912 eruptive deposits filling the Valley of Ten Thousand Smokes (VTTS) and in the upper parts of the two major rivers draining the 1912 deposits have similar chemical trends. Thermal springs issue in the mid-valley area along a 300-m lateral section of ash-flow tuff, and range in temperature from 21 to 29.8°C in early summer and from 15 to 17°C in mid-summer. Concentrations of major and minor chemical constituents in the thermal waters are nearly identical regardless of temperature. Waters in the downvalley parts of the rivers draining the 1912 deposits are mainly mixtures of cold meteoric waters and thermal waters of which the mid-valley thermal spring waters are representative. The weathering reactions of cold waters with the 1912 deposits appear to have stabilized and add only subordinate amounts of chemical constituents to the rivers relative to those contributed by the thermal waters. Isotopic data indicate that the mid-valley thermal spring waters are meteoric, but data is inconclusive regarding the heat source. The thermal waters could be either from a shallow part of a hydrothermal system beneath the 1912 vent region or from an incompletely cooled, welded tuff lens deep in the 1912 ash-flow sheet of the upper River Lethe area.Bicarbonate-sulfate waters resulting from interaction of near-surface waters and the cooling 1953–1968 southwest Trident plug issue from thermal springs south of Katmai Pass and near Mageik Creek, although the Mageik Creek spring waters are from a well-established, more deeply circulating hydrothermal system. Katmai caldera lake waters are a result of acid gases from vigorous drowned fumaroles dissolving in lake waters composed of snowmelt and precipitation.  相似文献   

2.
Thermal waters hosted by Menderes metamorphic rocks emerge along fault lineaments in the Simav geothermal area. Thermal springs and drilled wells are located in the Eynal, Çitgöl and Na a locations, which are part of the Simav geothermal field. Studies were carried out to obtain the main chemical and physical characteristics of thermal waters. These waters are used for heating of residences and greenhouses and for balneological purposes. Bottom temperatures of the drilled wells reach 163°C with total dissolved solids around 2225 mg/kg. Surface temperatures of thermal springs vary between 51°C and 90°C. All the thermal waters belong to Na–HCO3–SO4 facies. The cold groundwaters are Ca–Mg–HCO3 type. Dissolution of host rock and ion-exchange reactions in the reservoir of the geothermal system shift the Ca–Mg–HCO3 type cold groundwaters to the Na–HCO3–SO4 type thermal waters. Thermal waters are oversaturated at discharge temperatures for aragonite, calcite, quartz, chalcedony, magnesite and dolomite minerals giving rise to a carbonate-rich scale. Gypsum and anhydrite minerals are undersaturated with all of the thermal waters. Boiling during ascent of the thermal fluids produces steam and liquid waters resulting in an increase of the concentrations of the constituents in discharge waters. Steam fraction, y, of the thermal waters of which temperatures are above 100°C is between 0.075 and 0.119. Reservoir pH is much lower than pH measured in the liquid phase separated at atmospheric conditions, since the latter experienced heavy loss of acid gases, mainly CO2. Assessment of the various empirical chemical geothermometers and geochemical modelling suggest that reservoir temperatures vary between 175°C and 200°C.  相似文献   

3.
This paper presents chemical and isotopic data for thermal waters, gases and S deposits from Volcan Puracé (summit elevation 4600 m) in SW Colombia. Hot gas discharges from fumaroles in and around the summit crater, and thermal waters discharge from three areas on its flanks. The waters from all areas have D values of-75±1, indicating a single recharge area at high elevation on the volcano. Aircorrected values of3He/4He in thermal waters range from 3.8 to 6.7 RA, and approach those for crater fumarole gas (6.1–7.1 RA), indicating widespread addition of magmatic volatiles. An economic S deposit (El Vinagre) is being mined in the Rio Vinagre fault zone at 3600 m elevation. Sulfur isotopic data are consistent with a magmatic origin for S species in thermal waters and gases, and for the S ore deposit. Isotopic equilibration between S species may have occurred at 220±40°C, which overlaps possible equilibration temperatures (170±40°C) determined by a variety of other geothermometers for neutral thermal waters. Apparent CH4–CO2 equilibration temperatures for gases from thermal springs (400±50°C) and crater fumaroles (520±60°C) reflect higher temperatures deeper in the system. Hot magmatic gas ascending through the Rio Vinagre fault zone is though to have precipitated S and generated thermal waters by interaction with descending meteoric waters.  相似文献   

4.
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5.
The chemical composition and D/H, and ratios have been determined for the acid hot waters and volcanic gases discharging from Zaō volcano in Japan. The thermal springs in Zaō volcano issue acid sulfate-chloride type waters (Zaō) and acid sulfate type waters (Kamoshika). Gases emitted at Kamoshika fumaroles are rich in CO2, SO2 and N2, exclusive of H2O. Chloride concentrations and oxygen isotope data indicate that the Zaō thermal waters issue a fluid mixture from an acid thermal reservoir and meteoric waters from shallow aquifers. The waters in the Zaō volcanic system have slight isotopic shifts from the respective local meteoric values. The isotopic evidence indicates that most of the water in the system is meteoric in origin. Sulfates in Zaō acid sulfate-chloride waters with δ34S values of around +15‰, are enriched in 34S compared to Zaō H2S, while the acid sulfate waters at Kamoshika contain supergene light sulfate (δ34S = + 4‰) derived from volcanic sulfur dioxide from the volcanic exhalations. The sulfur species in Zaō acid waters are lighter in δ34S than those of other volcanic areas, reflecting the difference in total pressure.  相似文献   

6.
The occurrence of thermal/spa waters on Lesvos Island is related to the presence of a major faulting system. Thermal waters are the result of mixing of meteoric and infiltrating seawater at great depth, and their total salinity depends on the percentage of seawater in their composition. According to the diagrams of main elements, trace elements and environmental isotopes, most of the components that determine the chemical composition of thermal waters such as sodium, chloride and sulphates originate from seawaters. On the other hand, the concentration of calcium, magnesium, boron, lithium, etc., was affected by water–rock interaction under high temperature conditions. Moving towards the surface, thermal waters may become polluted by influx of recent seawater, allowing their chemical composition to become similar to that of seawater. The thermal waters of Lesvos Island present relatively high concentrations of ammonia and redox sensitive metals because they are hosted in a reducing environment. They also exhibit low nitrate concentrations due to their mixture with recent fresh water. Finally, they show increased radon concentrations, ranging from 20 to 60 kBq m?3 in the eastern and southern parts of the island, and about 230 kBq m?3 in the north, in the area of Eftalou–Argenos. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

7.
Subarctic water bodies are extremely vulnerable with respect to changes in the environmental characteristics, including an increase in temperature. The thermal effect of spent waters of power plants in water bodies of the Kola Peninsula was found to cause changes in communities comparable, within certain limits, with the effect of eutrophication. The most informative indices, characterizing the response of zooplankton community to the thermal impact of spent waters of the Kola NPP are determined for the case of Lake Imandra, the Kola Peninsula. The qualitative and quantitative characteristics of zooplankton are shown to have some specific features depending on the extent of the thermal pollution of the water body and to adequately reflect the difference between the conditions of zooplankton existence in its individual parts. The indicator role of zooplankton is evaluated, and the possibility to incorporate it in the monitoring system of water bodies is substantiated.  相似文献   

8.
Mineral and thermal water chemistry from the Azores archipelago was investigated in order to discriminate among hydrochemical facies and isotopic groups and identify the major geochemical processes that affect water composition. A systematic geochemical survey of mineral and thermal water chemistry was carried out, incorporating new data as well as results from the literature. The Azores are a volcanic archipelago consisting of nine islands and samples were collected at São Miguel, Graciosa, Faial, São Jorge, Pico and Flores islands. Hydrothermal manifestations show the effects of active volcanism on several islands. Discharges are mainly related to active Quaternary central volcanoes, of basaltic to trachytic composition, but also some springs are related to older dormant or extinct volcanoes.Multivariate analysis – principal component and cluster analysis – enables classification of water compositions into 4 groups and interpretation of processes affecting water compositions. Groups 1 and 2 discharge from perched-water bodies, and mostly correspond to Na–HCO3 and Na–HCO3–Cl type waters. These groups comprise of cold, thermal (27 °C–75 °C) and boiling waters (92.2 °C–93.2 °C), with a wide TDS range (77.3–27, 145.7 mg/L). Group 3 is made of samples of dominated Na–SO4 from very acid boiling pools (pH range of 2.02–2.27) which are fed by steam-heated perched-water bodies. Group 4 is representative of springs from the basal aquifer system and corresponds to Na–Cl type fluids, with compositions dominated by seawater.Results are used to further develop a conceptual model characterizing the geochemical evolution of the studied waters. Mineral and thermal waters discharging from perched-water bodies are of meteoric origin and chemically evolve by absorption of magmatic volatiles (CO2) and by a limited degree of rock leaching. Existing data also suggest mixture between cold waters and thermal water. Water chemistry from springs that discharge from the basal aquifer system evolves by mixing with seawater; although, processes such as absorption of magmatic volatiles (CO2), rock leaching and mixture with hydrothermal waters are not excluded by the data because the actual composition of these waters deviates from that expected considering only conservative mixing between fresh and seawater.  相似文献   

9.
Thermal and cold waters from Castellammare–Alcamo (Western Sicily-Italy) were collected between May 1994 and May 1995 and studied for their chemical and isotopic composition. During the same period, mean monthly samples of meteoric water were also collected and measured for their isotopic composition. The main purpose of this study was the characterization of the acquifers and, if possible, of their recharge areas. According to the results obtained, the acquifers were divided into three main groups: (a) selenitic waters, (b) cold carbonatic waters, and (c) deep thermal waters resulting from the mixing of the other two types. Besides a mixing process between carbonatic and selenitic waters, contamination processes of thermal waters by seawater take place during their ascent. The water temperature of the acquifer feeding the thermal springs was estimated by means of various geothermometers to range between 60°C and 97°C. Isotope data on rainwater samples show a wide seasonal variation of both δ and δD values. The fairly constant values of thermal waters through time and the lack of an apparent correlation with the isotopic values of rainwater suggest the existence of a deep circuit determining an almost complete homogenisation of the seasonal variations of the isotopic values.  相似文献   

10.
A geochemical study of thermal and cold springs, stream waters and gas emissions has been carried out in the Mt. Amiata geothermal region.The cold springs and stream waters do not seem to have received significant contribution from hot deep fluids. On the contrary, the thermal springs present complex and not clearly quantifiable interactions with the hot fluids of the main geothermal reservoir.The liquid-dominated systems in the Mt. Amiata area, like most of the high-enthalpy geothermal fields in the world, are characterized by saline, NaCl fluids. The nature of the reservoir rock (carbonatic and anhydritic), and its widespread occurrence in central Italy, favor a regional circulation of “Ca-sulfate” thermal waters, which discharge from its outcrop areas. Waters of this kind, which have been considered recharge waters of the known geothermal fields, dilute, disperse and react with the deep geothermal fluids in the Mt. Amiata area, preventing the use of the main chemical geothermometers for prospecting purposes. The temperatures obtained from the chemical geothermometers vary widely and are generally cooler than temperatures measured in producing wells.Other thermal anomalies in central Italy, apart from those already known, might be masked by the above-mentioned circulation. A better knowledge of deep-fluid chemistry could contribute to the calibration of specific geothermometers for waters from reservoirs in carbonatic rocks.  相似文献   

11.
Thermal waters in hydrothermal ponds, bathing pools and the brines of geothermal electric power plants commonly have a characteristic blue color. Although many researchers have assumed that the blue color is due to a colloidal suspension and/or absorption by dissolved ferrous iron or by water itself, there has been no specific effort to identify the physical nature of this phenomenon. We have tested, in synthetic and natural solutions, whether aqueous colloidal silica is responsible for the blue color. Aqueous colloidal silica is formed by silica polymerization in thermal waters of the neutral-chloride type which contain initially monomeric silica in concentrations up to three times above the solubilities of amorphous silica. The hue of the blue thermal waters in the pools tested agrees with that of a synthesized colloidal silica solution. Grain-size analyses of aqueous colloidal silica in the blue-colored thermal waters demonstrate that the color is caused by Rayleigh scattering from aqueous colloidal silica particles with diameters (0.1–0.45 μm) smaller than the wavelengths of visible radiation.  相似文献   

12.
Hui-Long  Xu  Jian-Wei  Shen Xue-Wu  Zhou 《Island Arc》2006,15(1):199-209
Abstract   Geothermal waters in the Niigata Sedimentary Basin, central Japan, are divided into four groups based on their chemical composition (i.e. Na-SO4-type, Na-SO4-Cl-type, Na-Cl-type and Na-Cl-HCO3-type). The Na-SO4-type geothermal water forms as a consequence of water–rock interaction and generally occurs in the outer part of the basin. The Na-Cl-type geothermal water is further subdivided into the original Na-Cl-type geopressured thermal water and the mixed Na-Cl-type geothermal water, in terms of its geochemical and isotopic composition. The original Na-Cl-type geopressured thermal water originates from a geopressured hydrothermal system containing the altered fossil formation waters that are sealed at depth. It moves up to the upper part of the depositional succession or the ground, and generally does not mix with groundwater that is of meteoric origin. This type of water is cooled by heat conduction. The concentration of Cl– in this type of thermal water is very similar to that in seawater. The δD and δ18O values are approximately constant and independent of temperature. The original Na-Cl-type geopressured thermal water is distributed mainly along anticlinal axes in folded Neogene formations. The mixed Na-Cl-type geothermal water is related to the expulsion activity of the geopressured hydrothermal system and occurs mostly along active faults. It is formed by shallow groundwater of meteoric origin being mixed with geopressured hydrothermal water when the geopressured hydrothermal system was expulsed along active faults by paroxysmal tectonic events.  相似文献   

13.
This paper examines groundwater hydrochemical characteristics during mixing between thermal and non-thermal groundwater in low-to-medium temperature geothermal fields. A case study is made of Daying and Qicun geothermal fields in the Xinzhou basin of Shanxi province, China. The two geothermal fields have similar flow patterns, with recharge sourced from precipitation in mountain areas heated through a deep cycle, before flowing into overlying Quaternary porous aquifers via fractures. Hydrochemical features of 60 ground- and surface water samples were examined in the context of hydrogeologic information. The average temperatures of the deep geothermal reservoirs are estimated to be 125 °C in Daying field, and 159 °C in Qicun field, based on Na–K–Mg geothermometry, while slightly lower estimates are obtained using silica geothermometers. Hydrochemical features of thermal water are distinct from cold water. Thermal groundwater is mainly Cl·SO4–Na type, with high TDS, while non-thermal groundwater is mostly HCO3–Ca·Mg and HCO3–Ca type in the Daying and Qicun regions, respectively. Hydrogeochemical processes are characterized by analyzing ion ratios in various waters. Higher contents of some minor elements in thermal waters, such as F, Si, B and Sr, are probably derived from extended water–rock interaction, and these elements can be regarded as indicators of flow paths and residence times. Mixing ratios between cold and thermal waters were estimated with Cl, Na, and B concentrations, using a mass balance approach. Mixing between ascending thermal waters and overlying cold waters is extensive. The proportion of water in the Quaternary aquifer derived from a deep thermal source is lower in Daying geothermal field than in Qicun field (5.3–7.3% vs. 6.3–49.3%). Mixing between thermal and non-thermal groundwater has been accelerated by groundwater exploitation practices and is enhanced near faults. Shallow groundwater composition has also been affected by irrigation with low-temperature thermal water.  相似文献   

14.
Based on geochemical studies we have updated our knowledge of the generation conditions and discharge of thermal waters on Shiashkotan Island. The thermal springs, which are abundant on the island, are surface expressions of the North Shiashkotan and Kuntomintar hydrothermal systems. The North Shiashkotan hydrothermal system shows the classical hydrochemical zonality. The discharge of the Kuntomintar hydrothermal system is confined within two thermal fields that are situated in the central and northeastern craters of the eponymous volcano. The high temperature of the gases that are issuing from Kuntomintar Volcano to the ground surface and the higher predictive ratios S/Cl, S/C, and CO2/H2 in its composition provide evidence of a possible renewal of its fumarole activity.  相似文献   

15.
Thermal waters of the Ömer–Gecek geothermal field, Turkey, with temperatures ranging from 32 to 92°C vary in chemical composition and TDS contents. They are generally enriched in Na–Cl–HCO3 and suggest deep water circulation. Silica and cation geothermometers applied to the Ömer–Gecek thermal waters yield reservoir temperatures of 75–155°C. The enthalpy–chloride mixing model, which approximates a reservoir temperature of 125°C for the Ömer–Gecek field, accounts for the diversity in the chemical composition and temperature of the waters by a combination of processes including boiling and conductive cooling of deep thermal water and mixing of the deep thermal water with cold water. It is also determined that the solubility of silica in most of the waters is controlled by the chalcedony phase. Equilibrium states of the Ömer–Gecek thermal waters studied by means of the Na–K–Mg triangular diagram, Na–K–Mg–Ca diagram, K–Mg–Ca geoindicator diagram, activity diagrams in the systems composed of Na2O–CaO–K2O–Al2O3–SiO2–CO2–H2O phases, log SI diagrams, and finally the alteration mineralogy indicate that most of the spring and low-temperature well waters in the area can be classified as shallow or mixed waters which are likely to be equilibrated with calcite, chalcedony and kaolinite at predicted temperature ranges similar to those calculated from the chemical geothermometers. It was also observed that mineral equilibrium in the Ömer–Gecek waters is largely controlled by CO2 concentrations.  相似文献   

16.
The gas composition of recent thermal waters is in perfect conformity with their geologictectonic positions. The composition of gas-liquid inclusions in the basic-hyperbasic xenoliths of basaltoid lavas depends on the depth from which xenoliths are supplied. (The depth is determined by using the methods of geological thermobarometers). By comparing available data we came to the conchision that the gas compositions of thermal waters reflect the depth of generation of deep fluid which heats them and depends on the penetration depth of the fluid-conducting fissure zones.  相似文献   

17.
Discharge areas of hydrothermal springs are known to be inhabited by diverse types of microorganisms including archaea, prokaryotes and eukaryotes. A total of 11 hydrothermal samples from the Rio Grande rift and the Valles caldera in New Mexico were analyzed to investigate the correlation between chemical and microbiological parameters of hydrothermal waters. The sampled fluids are categorized into three chemical groups: (I) steam-condensing acid sulfate waters, (II) deep geothermal and derivative waters and (III) thermal meteoric waters. Analyses of the microbial phospholipid fatty acids and denaturing gradient gel electrophoresis of DNA show that acid sulfate waters were populated by thermoacidophilic organisms and had high biomass content. Mineralized deep geothermal and derivative waters exhibited a high degree of microbial diversity, but had low biomass content. Thermal meteoric waters are low in total dissolved solids, and exhibit very low biomass content and microbial diversity. DNA sequences from several previously unknown microbial species were detected. The results of this study support the hypothesis that microbes can be used as tracers for specific types of subsurface environments.  相似文献   

18.
The chemical compositions of a total of 120 thermal water samples from four different tectonically distinct regions (Central, North, East and West Anatolia) of Turkey are presented and assessed in terms of geothermal energy potential of each region through the use of chemical geothermometers. Na–Ca–HCO3 type waters are the dominant water types in all the regions except that Na–Cl type waters are typical for the coastal areas of West Anatolia and for a few inland areas of West and Central Anatolia where deep water circulation exists. The discharge temperature of the springs ranges up to 100°C, and the bottom-hole temperatures in drilled wells up to 232°C. Geothermometry applications yield reservoir temperatures of about 125°C for Central Anatolia, 110°C for North Anatolia, 136°C for East Anatolia and 251°C for West Anatolia, the latter agreeing with some of the bottom hole temperatures measured in drilled wells. The results reveal that the highest geothermal energy potential in Turkey is associated with the West Anatolian extensional tectonics which provides a regional, deep-seated heat source and a widespread graben system allowing deep circulation of waters. The North Anatolian region, bounded to the south by the dextral North Anatolian Fault along which most of the geothermal sites are located, has the lowest energy potential, probably due to the restriction of the heat source to local magmatic activities confined to pull-apart basins. The East Anatolian region (undergoing contemporary compression) and the Central Anatolian region (where the compressional regime in the east is converted to the extensional regime in the west) have moderate energy potential. Although the recently active volcanoes suggest the presence, at depth, of still cooling magma chambers that are potential heat sources, the lack of well-developed fault systems is probably responsible for the comparatively low energy potential of these regions. Almost all the thermal waters of Turkey are saturated with respect to calcite and, hence, have a significant calcite scaling potential which is particularly high for West Anatolian waters.  相似文献   

19.
Book Reviews     
Abstract

The southeast of the Betic Cordilleras has long been recognized as an area with numerous geothermal anomalies of regional character. Many thermal springs appear related to currently tectonically active fault systems. Carbon dioxide and other gases in these waters have been mobilized through those fault systems. The great depth of these “slip-strike zones” affects the entire thickness of the lithosphere and leads to contrasting crustal domains of different natures and structures. In this area, the detrital aquifer of the Alto Guadalentín has thermal waters with high salinity and unusually high contents of CO2 gas. The utilization of Principal Components Analysis (PCA) in the hydrogeochemical study of this aquifer has revealed that the origin of the salinity of its waters is due essentially to processes of dissolution of the Miocene evaporite rocks, principally sulphate, and to the contribution of deep hydrothermal waters that show signs of endogenous CO2 contamination. To a lesser extent, infiltration waters also form an input, with elevated sulphate, chloride and nitrate content. Likewise, PCA has enabled the differentiation of distinct groups of water to which these processes have had a variable contribution.  相似文献   

20.
Thermal springs associated with normal faults in Utah have been analyzed for major cations and anions, and oxygen and hydrogen isotopes. Springs with measured temperatures averaging greater than 40°C are characterized by Na + K- and SO4 + Cl-rich waters containing 103 to 104 mg/l of dissolved solids. Lower temperature springs, averaging less than 40°C, are more enriched in Ca + Mg relative to Na + K. Chemical variations monitored through time in selected thermal springs are probably produced by mixing with non-thermal waters. During the summer months at times of maximum flow, selected hot springs exhibit their highest temperatures and maximum enrichments in most chemical constituents.Cation ratios and silica concentrations remain relatively constant through time for selected Utah thermal springs assuring the applicability of the geothermometer calculations regardless of the time of year. Geothermometer calculations utilizing either the quartz (no steam loss), chalcedony or Mg-corrected Na/K/Ca methods indicate that most thermal springs in Utah associated with normal faults have subsurface temperatures in the range of 25 to less than 120°C. This temperature range suggests fluid circulation is restricted to depths less than about three kilometers assuming an average thermal gradient of about 40°C/km.Thermodynamic calculations suggest that most thermal springs are oversaturated with respect to calcite, quartz, pyrophyllite, (Fe, Mg)-montmorillonite, microcline and hematite, and undersaturated with respect to anhydrite, gypsum, fluorite and anorthite. Chalcedony and cristobalite appear to be the only phases consistently at or near saturation in most waters. Theoretical evaluation of mixing on mineral saturation trends indicates that anhydrite and calcite become increasingly more undersaturated as cold, dilute groundwater mixes with a hot (150°C), NaCl-rich fluid. The evolution of these thermal waters issuing from faults appears to be one involving the dissolution of silicates such as feldspars and micas by CO2-enriched groundwaters that become more reactive with increasing temperature and/or time. Solution compositions plotted on mineral equilibrium diagrams trend from product phases such as kaolinite or montmorillonite toward reactant phases dominated by alkali feldspars.Isotopic compositions indicate that these springs are of local surface origin, either meteoric (low TDS, < 5000 mg/l) or connate ground water (high TDS, > 5000 mg/l). Deviations from the meteoric water line are the result of rock-water isotopic exchange, mixing or evaporation. Fluid source regions and residence times of selected thermal spring systems (Red Hill, Thermo) have been evaluated through the use of a σ D-contour map of central and western Utah. Ages for waters in these areas range from about 13 years to over 500 years. These estimates are comparable to those made for low-temperature hydrothermal systems in Iceland.  相似文献   

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