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1.
Throughout the world, large caves in rocks (tafoni) are found, which originate from salt weathering. The mechanisms that control their development are poorly understood. The growth of tafoni has been studied with a model that describes how a rock surface, containing a small pit, disintegrates by salt crystallization during wetting/drying cycles. In the model the rock is mapped on a grid. The migration and crystallization of salts are simulated explicitly in the drying phase of a cycle. At the end of each wetting/drying cycle the amount of salt deposited at the grid nodes is evaluated and the shape of the rock surface is adjusted by removing nodes. The length of the drying period in a single cycle proved to be the key parameter. For short drying periods the amount of crystallized salt at the surface is proportional to the drying rate. Therefore, for short drying periods most salts are deposited at the more exterior parts of the rock surface. As a result, most damage will develop at these parts of the surface, which results in smooth surfaces. Due to the characteristics of the drying process for long drying periods, most salts accumulate at regions with low evaporation rates, which are the sheltered parts of the rock surface. These parts are not exposed to the wind or the sun. As a result, the pit grows and a tafone develops. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

2.
Tafoni are a type of cavernous weathering widespread around the world. Despite the extensive distribution of the tafoni, their genesis is not clear and is still a matter of debate, also because they occur in such different climatic conditions and on so many different types of substrate. Geomorphological characterization of more than 60 tafoni in three different Antarctic sites (two coastal and one inland) between 74 and 76° S with sampling of weathering products and salt occurrences are described together with thermal data (on different surfaces) and wind speed recorded in different periods of the year in a selected tafone close to the Italian Antarctic station. The aim of this present study is to provide further information to help understand the processes involved in the growth of tafoni in a cryotic environment, and the relationship of these processes to climate, with particular attention to the thermal regime and the role of wind. The new data presented in this paper suggest that there is no single key factor that drives the tafoni development, although thermal stress seems the most efficient process, particularly if we consider the short‐term fluctuations. The data also confirm that other thermal processes, such as freezing–thawing cycles and thermal shock, are not really effective for the development of tafoni in this area. The wind speed measured within the tafoni is half that recorded outside, thus favouring snow accumulation within the tafoni and therefore promoting salt crystallization. On the other hand, the wind effect on the thermal regime within the tafoni seems negligible. While both salt weathering and thermal stress appear active in this cryotic environment, these are azonal processes and are therefore active in other climatic areas where tafoni are widespread (such as the Mediterranean region). Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

3.
Tafoni are pits formed by non‐uniform weathering in otherwise uniform rock. Two equations have been proposed for the rate of development of tafoni, both based on 2000‐year‐old outcrops from the coast of Japan. We have taken tafoni measurements from the Meteor Crater, Arizona, and vicinity that extend the equations back at least 50 000 years. As reported in earlier studies, we found pit depth to be the best tafone parameter to measure. The size of the pit decreases significantly with increasing inclination of the rock surface; however, the size of the pit can vary greatly for other reasons. In some cases the measurements are statistically significantly different between two stations taken from contiguous areas of similar inclination and aspect in an apparently homogeneous bed. It is clear, however, that over tens of thousands of years tafoni enlarge significantly. Our data are generally log‐normal and all are markedly heteroscedastic. The 1991 equation proposed by Matsukura and Matsuoka does not fit our data. The 1996 equation proposed by Sunamura provides a better fit. We propose a sigmoidal equation D = b1 + e(b2+(b3/t)) where D is the depth, t is the age, and b1, b2 and b3 vary with lithology. This new equation fits our data far better than the earlier published equations. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

4.
Using a combination of field, laboratory and micromorphological evidence, this study examines tafoni (singular, tafone) in the El Chorro area of Andalucia, southern Spain, and makes inferences concerning the processes responsible for their formation. Twenty-five tafoni were randomly selected for field examination. The morphology of these cavernous rock domes is characterized by a helmet-shaped outer roof and an arched-shaped cavern, often with a partially overhanging visor; measurements of height, width and depth of the caverns revealed marked variations in size. The presence or absence of lichen cover, surface varnish, overhanging visor, cavern backwall stripes, rock flaking, weathering pits and cavern floor sediments was also noted. Surface hardness values, obtained using a Schmidt hammer, are relatively low but significantly higher on the outer roof of the tafoni than on the inner cavern walls. Analysis of sediment samples collected from the cavern backwalls and floors indicates predominantly sandy textures, alkaline pH values and some base cation enrichment. Micromorphological analysis of thin sections, prepared from undisturbed blocks, reveals large quantities of pore-filling cement, consisting mainly of calcite, mineral grains affected by weathering and pseudomorphic replacement, and dark, rounded nodules with a metallic appearance. In terms of their formation, different processes appear to act on different parts of the landform. On the outer roof surfaces, case hardening, resulting from near-surface cementation and surface varnish development, is dominant. On the inner cavern surfaces, however, core softening, resulting from granular disintegration and flaking, dominates. Exfoliation weathering, running water and wind deflation also appear to play an important role in tafone formation. A phased model of tafone evolution is proposed whereby the features pass through four phases of development–initiation, enlargement, amalgamation and degradation; in the study area there are examples of tafoni in each of these phases. Much of the evidence suggests that the tafoni are actively developing under current environmental conditions. © 1997 by John Wiley & Sons, Ltd.  相似文献   

5.
To describe temporal change in tafone development, an S‐shaped curve equation is proposed: Z = Zc [1 ? (n + 1) exp (? β t ) + n exp (? (1 + 1/n) β t )] , where Z is observed tafone depth, Zc is ultimate tafone depth, t is time, and n and β are constants. The applicability of this model is examined using tafone data selected from seven sites, which are categorized into three different salt‐weathering environments: a spray/splash‐dominant (occasionally wave‐affected) supra‐tidal zone, aerosol‐affected coastal regions, and inland desert areas. The results indicate that the equation can well describe tafone development in each of these environments. An investigation based on the values of n and β, determined through a best fit of the equation to the data, suggests that n characterizes site‐specific environmental conditions and β reflects the magnitude of factors controlling the recession mechanism of tafone surfaces. It is found that (1) the maximum rate of tafone growth dramatically decreases from supra‐tidal, through coastal, to desert environments, and (2) the growing mode of tafoni is different depending on the environmental settings. The erosional force to facilitate the development of tafoni at supra‐tidal sites is estimated to be about 400 times greater than that in the general coastal area. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

6.
Despite numerous investigations and theoretical models, tafoni weathering is still not fully understood largely because of limited data available on temperature, moisture and salt regimes. We investigated tafoni developed in granite in the Tafraoute region, Morocco, through an exploratory, two‐week multi‐method field campaign. Temperatures were measured with iButtons and by means of infrared thermography; moisture distribution and progress were captured with handheld moisture sensors and with drilled‐in iButtons. Salts were analysed in drill dust samples from different positions and rock depths. The results derived from very different techniques mutually support one another. Salts and moisture are concentrated near the base of the investigated tafoni, probably due to a saturated pore water body around the base of rock tors. Salts are accumulated close to the rock surface in tafoni, but not on the surrounding rock surfaces. A clear correlation was found between moisture and salt contents. Within a tafone, areas of higher humidity also display increased salt concentration near the surface. The temperature/humidity records allied with ionic analyses suggest that sodium sulfate dominates and is likely to undergo frequent phase changes from thenardite to mirabilite and vice versa. Two pathways of salt transport in and around tafoni are assumed based on the data: infiltration with rainfall on the top and around tors and boulders, and capillary rise from saturated pore water bodies to the surface. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

7.
Cavernous weathering (tafoni development) occurs on coastal slopes in greenschist bedrock at elevations up to 40 m above sea level. The freshly weathered surfaces of the cavern interiors are irregular in morphology, discordant to major rock structure, formed by substantially weakened rock and associated with granular weathering debris. The weathering debris contains soluble elements in proportions similar to those present in seawater, and the penetration of elements associated with sea salts into the weathering surface to estimated depths of at least 0·1–0·2 m is indicated by the presence of chlorine. Scanning electron microscopy and microprobe analyses suggest that rock breakdown occurs principally through limited chemical weathering at grain boundaries. The mechanism for the emplacement of marine salts within sheltered rock surfaces in the tafoni is postulated to be a combination of dry deposition under turbulent atmospheric conditions and wetting by coastal fog.  相似文献   

8.
Bedding‐parallel tafoni are well developed over much of the surface of the Tunnel Spring Tuff (Oligocene) exposed in 300‐m‐high Crystal Peak, an inselberg. The Tunnel Spring Tuff is a crudely stratified, non‐welded rhyolite ash‐flow tuff with > 30 per cent porosity. Clasts of Palaeozoic dolomite, limestone and quartzite make up 10 per cent of the tuff. The tafoni are remarkable because of their size (up to 20 m wide but rarely wider than 4 m), shape of the openings (spherical, arch‐like or crescent‐shaped) and abundance (up to 50 per cent of an outcrop face). They are actively forming today. Calcite is abundant (10 to 40 per cent by weight) in tafoni as an efflorescence in spalling flakes of tuff on their roofs and walls. Halite and gypsum generally make up less than 0·01 per cent of the efflorescence. The absence of corroded quartz and feldspar grains in spall fragments indicates that chemical weathering is unimportant in development of the tafoni. Calcite, aragonite, halite and gypsum dust from modern salt pans less than 20 km from Crystal Peak are potential sources of salt in the tuff, but the prevailing winds are in the wrong direction for significant amounts of these evaporite minerals to reach the inselberg. Calcite is the only evaporite mineral present in the tafoni in more than trace amounts, and this mineral is readily available within the tuff itself as a result of rock weathering. We propose that meteoric water containing carbonic acid infiltrates the tuff, dissolves carbonate clasts, and migrates to the steep flanks (>20°) of the peak through abundant megapores and micropores. There it evaporates and precipitates calcite. Crystallization pressure spalls off grains and sheets as the physical manifestation of salt weathering. The quasi‐uniform spacing of tafoni suggests that a self‐organization process is active in the water flow. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

9.
Historic structures can be viewed as exposure trials of the stone of which they are constructed. As such, they represent a geomorphological weathering experiment. Several structures of Henrician (sixteenth century) and greater age on the coast of southwest England have been exposed to coastal salt weathering for 500–600 years. Long‐term weathering rates on five different rock groups are derived from careful study of weathering depths and forms. There is significant variation in weathering rate between five major rock groups. Rank ordering of weathering rate values reveals a durability order of these rock groups, which is confirmed by local juxtapositions. Controls on rock durability in the coastal weathering environment include both mechanical and mineralogical characteristics. Specific density, and combined quartz and muscovite content, are positively related to durability; high feldspar and chlorite content are associated with low durability. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

10.
Honeycomb weathering has been observed in a Carboniferous sandstone at a coastal location near Ballycastle on the north coast of Northern Ireland. Specimens of this sandstone have been analysed by X-ray diffraction, scanning electron microscopy, and energy dispersive spectrometry. Results reveal that calcium sulphate (gypsum) is the only salt present and is found only at and immediately below the rock surface. SEM observations suggest that crystallization of salts in pores could easily dislodge quartz grains to promote granular disintegration, whilst etching of quartz grain surfaces attests to chemical weathering activity within the rock However, the reason for the development of the honeycomb pattern is not known.  相似文献   

11.
Papago Park, Arizona, is a pediment-inselberg complex that hosts a variety of well developed tafoni and alveolar weathering forms. The purpose of this paper is to analyse the nature of chemical weathering associated with the tafoni using backscatter electron microscopy (BSE) and quantitative wavelength dispersive X-ray analysis (WDS). Calcium-rich and iron-rich coatings occur on the outer shells of the tafoni. Calcium carbonate precipitation within mineral microfractures occurs on the underside of the tafoni. Chemical weathering of primary mineral grains provides a source of material found in the coatings. The WDS analyses show a near-complete lack of salt-forming elements. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

12.
Three dated structures up to 450 years in age display the effects of coastal weathering of the greenschist of which they are constructed. A variety of weathering forms is present. The various topographic surfaces of the structures create variation in weathering environments and consequent weathering processes and rates. Weathering is enhanced by direct exposure to salt-bearing spray and by humid conditions, and apparently limited by direct exposure to solar radiation. The maximum rates of weathering on the three surfaces approximate to 0·6 mm a−1 over this period, consistent with measured contemporary weathering rates for a natural surface formed by this rock type in a nearby coastal location. © 1997 by John Wiley & Sons, Ltd.  相似文献   

13.
Experiments are described in which chalk cubes were soaked in solutions of either sodium chloride, sodium sulphate, or magnesium sulphate at concentrations of 5·5 per cent and 12·5 per cent, or in a mixed solution of sodium chloride and sodium sulphate or in distilled water. After removal of excess liquid, the cubes were subjected to six freeze–thaw cycles with temperatures ranging from either +15 to ?10°C or +15 to ?30°C. The results confirm that frost weathering can be enhanced by the presence of certain salts, but the extent of weathering was much less than that previously reported for samples frozen totally immersed in the same liquids. Evidence is presented which suggests that salt crystallization is the major weathering process operative when non–immersed samples are frozen but a combination of frost and salt weathering operates when fully immersed samples are frozen.  相似文献   

14.
Soil‐covered upland landscapes constitute a critical part of the habitable world. Our understanding of how they evolve as a function of different climatic, tectonic and geological regimes is important across a wide range of disciplines and depends, in part, on understanding the links between chemical and physical weathering processes. Extensive previous work has shown that soil production rates decrease with increasing soil column thickness, but chemical weathering rates were not measured. Here we examine a granitic, soil‐mantled hillslope at Point Reyes, California, where soil production rates were determined using in situ produced cosmogenic nuclides (10Be and 26Al), and we quantify the extent as well as the rates of chemical weathering of the saprolite from beneath soil from across the landscape. We collected saprolite samples from the base of soil pits and analysed them for abrasion pH as well as for major and trace elements by X‐ray fluorescence spectroscopy, and for clay mineralogy by X‐ray diffraction spectroscopy. Our results show for the first time that chemical weathering rates decrease with increasing soil thickness and account for 13 to 51 per cent of total denudation. We also show that spatial variation in chemical weathering appears to be topographically controlled: weathering rate decreases with slope across the divergent ridge and increases with upslope contributing area in the convergent swale. Furthermore, to determine the best measure for the extent of saprolite weathering, we compared four different chemical weathering indices – the Vogt ratio, the chemical index of alteration (CIA), Parker's index, and the silicon–aluminium ratio – with saprolite pH. Measurements of the CIA were the most closely correlated with saprolite pH, showing that weathering intensity decreases linearly with an increase in saprolite pH from 4·7 to almost 7. Data presented here are among the first to couple directly rates of soil production and chemical weathering with how topography is likely to control weathering at a hillslope scale. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

15.
Two types of cavernous‐weathering features are exposed in the Oligocene Macigno Sandstone along 5 km of the Tuscan coast south of Livorno, Italy. Honeycomb cells (type 1 features) are typical closely spaced, more or less circular pits of centimetre scale that have been eroded 2 to 6 cm below the general surface of bedding planes or joints. ‘Aberrant honeycomb’ cells (type 2 features) are highly elongate, polygonal, or irregular ?at depressions of decimetre scale surrounded by walls rarely higher than 2 cm, some of which pass into long, free‐standing walls or tendrils. Thus, not all type 2 ‘honeycomb’ cells are fully enclosed. We measured the geometry of 551 honeycomb cells and examined various rock properties (microscopic texture and fabric, mineralogy, porosity, permeability, and chemical composition) to isolate factors that control the size, shape, distribution, and pattern of the honeycombs. Our goal was to narrow potential origins of the features and to understand their formation. The ubiquitous occurrence of sea salt in the honeycombs and scanning electron microscope evidence of physical weathering of silicates, especially micas, favours an origin for the honeycombs chie?y by salt weathering. Honeycombs do not form in siltstone, iron‐oxide‐impregnated sandstone, calcite‐cemented concretions, or in case‐hardened joints. Thus, salt weathering of type 1 and 2 honeycombs is not effective in very low permeability rocks. We propose for type 1 honeycombs that seawater is drawn into micropores of the sandstone and evolves into self‐organized diffusion cells (Turing patterns). Selective evaporation at the stationary nodes of diffusion cells, which form at the same site over time, leads to the precipitation of salt, then grains spall off, and pits are formed. The deepest pits (>40 mm) formed where Turing patterns consistently formed at the same sites. Although the walls are more porous and weathered than the host sandstone, they become selectively case hardened by an unidenti?ed component of low abundance. Initial honeycomb cell shape and gravity locally in?uenced type 1 honeycomb shapes. We suggest that type 2 honeycombs develop where diffusion‐controlled Turing patterns lead to case‐hardening along linear trends; gravity and rock fabric are important locally in in?uencing the orientation of the walls. Only type 2 cells are forming today, suggesting recent environmental changes. Gravity is not a fundamental control on honeycomb shape; in places it is a contributing factor. Pre‐existing depressions (quarry tool marks) have strongly in?uenced honeycomb shape locally. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

16.
Differences in chemical weathering extent and character are expected to exist across topographic escarpments due to spatial gradients of climatic and/or tectonic forcing. The passive margin escarpment of south‐eastern Australia has a debated but generally accepted model of propagation in which it retreated (within 40 Ma) to near its current position following rifting between Australia and New Zealand 85–100 Ma before present. We focus on this escarpment to quantify chemical weathering rates and processes and how they may provide insight into scarp evolution and retreat. We compare chemical weathering extents and rates above and below the escarpment using a mass balance approach coupling major and trace element analyses with previous measurements of denudation rates using cosmogenic nuclides (10Be and 26Al). We find a slight gradient in saprolite chemical weathering rate as a percentage of total weathering rate across the escarpment. The lowlands area, encompassing the region extending from the base of the escarpment to the coast, experiences a greater extent of chemical weathering than the highland region above the escarpment. Percents of denudation attributable to saprolite weathering average 57 ± 6% and 47 ± 7% at low and high sites respectively. Furthermore, the chemical index of alteration (CIA), a ratio of immobile to mobile oxides in granitic material that increases with weathering extent, have corresponding average values of 73·7 ± 3·9 and 65·5 ± 3·4, indicating lower extents of weathering above the escarpment. Finally, we quantify variations in the rates and extent of chemical weathering at the hillslope scale across the escarpment to suggest new insight into how climate differences and hillslope topography help drive landscape evolution, potentially overprinting longer term tectonic forcing. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

17.
Landscapes evolve in response to external forces, such as tectonics and climate, that influence surface processes of erosion and weathering. Internal feedbacks between erosion and weathering also play an integral role in regulating the landscapes response. Our understanding of these internal and external feedbacks is limited to a handful of field‐based studies, only a few of which have explicitly examined saprolite weathering. Here, we report rates of erosion and weathering in saprolite and soil to quantify how climate influences denudation, by focusing on an elevation transect in the western Sierra Nevada Mountains, California. We use an adapted mass balance approach and couple soil‐production rates from the cosmogenic radionuclide (CRN) 10Be with zirconium concentrations in rock, saprolite and soil. Our approach includes deep saprolite weathering and suggests that previous studies may have underestimated denudation rates across similar landscapes. Along the studied climate gradient, chemical weathering rates peak at middle elevations (1200–2000 m), averaging 112·3 ± 9·7 t km–2 y–1 compared to high and low elevation sites (46·8 ± 5·2 t km?2 y?1). Measured weathering rates follow similar patterns with climate as those of predicted silica fluxes, modeled using an Arrhenius temperature relationship and a linear relationship between flux and precipitation. Furthermore, chemical weathering and erosion are tightly correlated across our sites, and physical erosion rates increase with both saprolite weathering rates and intensity. Unexpectedly, saprolite and soil weathering intensities are inversely related, such that more weathered saprolites are overlain by weakly weathered soils. These data quantify exciting links between climate, weathering and erosion, and together suggest that climate controls chemical weathering via temperature and moisture control on chemical reaction rates. Our results also suggest that saprolite weathering reduces bedrock coherence, leading to faster rates of soil transport that, in turn, decrease material residence times in the soil column and limit soil weathering. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

18.
To try to resolve the conflicts surrounding the influence of salts on frost weathering, chalk cubes were immersed, separately, in solutions of sodium chloride, sodium sulphate, and magnesium sulphate at concentrations of 5·5 per cent and 12·5 per cent, in a mixed solution of sodium chloride and sodium sulphate, and in distilled water. The cubes were subjected to six freeze-thaw cycles with temperatures ranging from either +15 to — 10°C or + 15 to — 30°C. The results confirm that frost weathering can be enhanced by the presence of certain salts, but the degree of enhancement depends both on the concentration and type of salt and on the intensity of the freeze-thaw regime. Some, but not all, of the results can be explained by the phase changes that occur during the freezing of the salt solutions.  相似文献   

19.
Most hillslope studies examining the interplay between climate and earth surface processes tend to be biased towards eroding parts of landscapes. This limitation makes it difficult to assess how entire upland landscapes, which are mosaics of eroding and depositional areas, evolve physio‐chemically as a function of climate. Here we combine new soil geochemical data and published 10Be‐derived soil production rates to estimate variations in chemical weathering across two eroding‐to‐depositional hillslopes spanning a climate gradient in southeastern Australia. At the warmer and wetter Nunnock River (NR) site, rates of total soil (–3 to –14 g m‐2 yr‐1; negative sign indicates mass loss) and saprolite (–18 to –32 g m‐2 yr‐1) chemical weathering are uniform across the hillslope transect. Alternatively, the drier hillslope at Frog's Hollow (FH) is characterized by contrasting weathering patterns in eroding soils (–30 to –53 g m‐2 yr‐1) vs. depositional soils (+91 g m‐2 yr‐1; positive sign indicates mass addition). This difference partly reflects mineral grain size sorting as a result of upslope bioturbation coupled with water‐driven soil erosion, as well as greater vegetative productivity in moister depositional soils. Both of these processes are magnified in the drier climate. The data reveal the importance of linking the erosion–deposition continuum in hillslope weathering studies in order to fully capture the coupled roles of biota and erosion in driving the physical and chemical evolution of hillslopes. Our findings also highlight the potential limitations of applying current weathering models to landscapes where particle‐sorting erosion processes are active. Copyright © 2018 John Wiley & Sons, Ltd.  相似文献   

20.
Honeycomb weathering occurs in two environments in Late Cretaceous and Eocene sandstone outcrops along the coastlines of south‐west Oregon and north‐west Washington, USA, and south‐west British Columbia, Canada. At these sites honeycomb weathering is found on subhorizontal rock surfaces in the intertidal zone, and on steep faces in the salt spray zone above the mean high tide level. In both environments, cavity development is initiated by salt weathering. In the intertidal zone, cavity shapes and sizes are primarily controlled by wetting/drying cycles, and the rate of development greatly diminishes when cavities reach a critical size where the amount of seawater left by receding tides is so great that evaporation no longer produces saturated solutions. Encrustations of algae or barnacles may also inhibit cavity enlargement. In the supratidal spray zone, honeycomb weathering results from a dynamic balance between the corrosive action of salt and the protective effects of endolithic microbes. Subtle environmental shifts may cause honeycomb cavity patterns to continue to develop, to become stable, or to coalesce to produce a barren surface. Cavity patterns produced by complex interactions between inorganic processes and biologic activity provide a geological model of ‘self‐organization’. Surface hardening is not a factor in honeycomb formation at these study sites. Salt weathering in coastal environments is an intermittently active process that requires particular wind and tidal conditions to provide a supply of salt water, and temperature and humidity conditions that cause evaporation. Under these conditions, salt residues may be detectable in honeycomb‐weathered rock, but absent at other times. Honeycomb weathering can form in only a few decades, but erosion rates are retarded in areas of the rock that contain cavity patterns relative to adjacent non‐honeycombed surfaces. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

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