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1.
Jennifer M. McKinley Patricia Warke Christopher. D. Lloyd Alastair H. Ruffell Bernard J. Smith 《地球表面变化过程与地形》2006,31(8):950-969
Geostatistical techniques for spatial prediction and spatial simulation have been used in an innovative application to the study of weathering of natural building stone. The study investigates the differences in the spatial variation of permeability characteristics between fine‐ and coarse‐grained Stanton Moor building sandstone. Non‐destructive permeability measurements, using an unsteady‐state Portable Probe Permeameter, were made on three adjacent faces of two cubic blocks representative of fine‐ to medium‐grained and medium‐ to coarse‐grained Stanton Moor Sandstone. The findings provide greater understanding in the investigation of the durability characteristics of the Stanton Moor Sandstone and show that the spatial distribution and variability of permeability is more important in predicting the overall strength and weathering properties than mean permeability and absolute minimum and maximum values. The results suggest that both primary textural characteristics (such as grain size) and extent of cementation appear to be important factors in determining the overall durability properties of Stanton Moor Sandstone as a building stone. Geostatistical analysis has been shown to be an important tool in the characterization of spatial variation for the investigation of weathering of building stones. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
2.
Differences in weathering response characteristics of fine‐ and coarse‐grained Stanton Moor sandstone samples were assessed in a laboratory weathering simulation experiment using a variable combination of salt weathering and freeze/thaw cycles. Preliminary analysis of permeability characteristics identified similar mean values for each type of Stanton sandstone but significant differences in the range of values between the two sample sets, with coarse‐grained samples of Stanton Moor sandstone displaying a restricted range of values in comparison to fine‐grained samples which showed much greater within‐block variation. Data indicated that the greater the range in initial permeability values, the greater the potential for salt and moisture ingress and retention and hence eventual disruption of the fabric of the stone. Experimental data also identified different stages in decay sequences, with significant structural change occurring during the initial preparatory stage before material breakdown and loss became apparent. Evidence suggests that relatively minor structural and mineralogical differences between samples of the same stone type can have a significant influence on weathering behaviour, resulting in distinct rates and patterns of breakdown. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
3.
Low impact surface hardness testing (Equotip) on porous surfaces – advances in methodology with implications for rock weathering and stone deterioration research 
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下载免费PDF全文 The Equotip surface hardness tester is becoming a popular method for rock and stone weathering research. In order to improve the reliability of Equotip for on‐site application this study tested four porous limestones under laboratory conditions. The range of stone porosity was chosen to represent likely porosities found in weathered limestones in the field. We consider several key issues: (i) its suitability for soft and porous stones; (ii) the type of probe required for specific on‐site applications; (iii) appropriate (non‐parametrical) statistical methods for Equotip data; (iv) sufficient sampling size. This study shows that the Equotip is suitable for soft and porous rock and stone. From the two tested probes the DL probe has some advantages over the D probe as it correlates slightly better with open porosity and allows for more controlled sampling in recessed areas and rough or curved areas. We show that appropriate sampling sizes and robust non‐parametric methods for subsequent data evaluation can produce meaningful measures of rock surface hardness derived from the Equotip. The novel Hybrid dynamic hardness, a combination of two measuring procedures [single impact method (SIM) and repeated impact method (RIM)], has been adapted and is based on median values to provide a more robust data evaluation. For the tested stones in this study we propose a sample size of 45 readings (for a confidence level of 95%). This approach can certainly be transferred to stone and rock with similar porosities and hardness. Our approach also allows for consistent comparisons to be made across a wide variety of studies in the fields of rock weathering and stone deterioration research. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
4.
Data describing sediment generation focusing on the temporal evolution of size gradation are required for the prediction of long‐term landform evolution. This paper presents such data for the salt weathering of a quartz‐chlorite schist obtained from the Ranger Uranium Mine in northern Australia. Rock fragment samples are subjected to three different climate regimes: (1) a dry season climate; (2) a wet season climate (both based on observations at the Ranger site); and (3) an oven‐drying sequence designed to test the sensitivity of the weathering process by exposing the rocks to more extreme temperatures. Two MgSO4 salt solutions are applied, one being typical of wet season runoff and the other a more concentrated solution. Salt solution is applied daily in the wet season experiments and once only at the beginning of the dry season experiments. Results of the experiments reveal four stages of weathering. The kinetics of each stage are described and related to the formation of sediment of different sizes. Wet season climate conditions are shown to produce greater moisture variability and lead to faster weathering rates. However, salt concentrations in the wet season are typically lower and so when climate is combined with observed salt concentrations, the dry and wet season experiments weather at approximately equal rates. Finally, small variations in rock properties were shown to have a large impact on weathering rates, leading to the conclusion that rock weathering experiments need to be carefully designed if results are to be used to help predict weathering behaviour at the landscape scale. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
5.
A laboratory simulation of salt weathering was used to ascertain the effects of sodium sulphate and sodium carbonate under ‘Negev’ conditions using a single immersion technique. Three main points were addressed: what are the grain size and textural characteristics of the debris liberated from limestones and a sandstone, what do scanning electron microscope observations of the weathered samples tell us about the decay processes involved, and how does the rate of debris liberation change during the course of 100 cycles? The grain size characteristics of the liberated debris tended to be multimodal and were related to the original petrological characteristics of the rock. Large amounts of fines were produced which are believed to be analogous to the ‘rock flour’ of arid areas. Blistering was also observed. Scanning electron microscope analysis revealed differences in the style of attack for different rock types and salt treatments, and revealed the pattern of salt crystallization in pores and the nature of cracking. The rate of debris liberation tended to decline or remain constant through time. The reasons for this remain obscure, but it is evident that diurnal cycles of temperature and humidity change can cause continuing rock weathering long after the initial input of salt to the rock has taken place. 相似文献
6.
D.N. Mottershead 《地球表面变化过程与地形》2000,25(10):1143-1159
Historic structures can be viewed as exposure trials of the stone of which they are constructed. As such, they represent a geomorphological weathering experiment. Several structures of Henrician (sixteenth century) and greater age on the coast of southwest England have been exposed to coastal salt weathering for 500–600 years. Long‐term weathering rates on five different rock groups are derived from careful study of weathering depths and forms. There is significant variation in weathering rate between five major rock groups. Rank ordering of weathering rate values reveals a durability order of these rock groups, which is confirmed by local juxtapositions. Controls on rock durability in the coastal weathering environment include both mechanical and mineralogical characteristics. Specific density, and combined quartz and muscovite content, are positively related to durability; high feldspar and chlorite content are associated with low durability. Copyright © 2000 John Wiley & Sons, Ltd. 相似文献
7.
Fire has long been recognized as an agent of rock weathering. Our understanding of the impact of fire on stone comes either from early anecdotal evidence, or from more recent laboratory simulation studies, using furnaces to simulate the effects of fire. This paper suggests that knowledge derived from simulated heating experiments is based on the pre‐conceptions of the experiment designer – when using a furnace to simulate fire, the operator decides on the maximum temperature and the duration of the experiment. These are key factors in determining the response of the stone to fire, and if these are removed from real‐world observations then knowledge based on these simulations must be questioned. To explore the differences between heating sandstone in a furnace and a real fire, sample blocks of Peakmoor Sandstone were subjected to different stress histories in combination (lime rendering and removal, furnace heating or fire, frost and salt weathering). Block response to furnace heating and fire is discussed, with emphasis placed on the non‐uniformity of the fire and of block response to fire in contrast to the uniform response to surface heating in a furnace. Subsequent response to salt weathering (by a 10% solution of sodium chloride and magnesium sulphate) was then monitored by weight loss. Blocks that had experienced fire showed a more unpredictable response to salt weathering than those that had undergone furnace heating – spalling of corners and rapid catastrophic weight loss were evidenced in blocks that had been subjected to fire, after periods of relative quiescence. An important physical side‐effect of the fire was soot accumulation, which created a waxy, relatively impermeable layer on some blocks. This layer repelled water and hindered salt ingress, but eventually detached when salt, able to enter the substrate through more permeable areas, concentrated and crystallized behind it, resulting in rapid weight loss and accelerated decay. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
8.
Rob Inkpen 《地球表面变化过程与地形》1995,20(9):783-793
Portland Stone and Monks Park limestone tablets were used to assess weathering loss over a two-year study. Procedures involved in preparing tablets for exposure, attaching them to the exposure frame and reweighing might have influenced weight changes measured. The impact of each stage in the above procedures was tested to assess how much weight loss was generated and how significant the loss was comparing the two stone types and the final loss sustained upon weathering. Although all the procedures seem to produce a statistically insignificant amount of weight loss, the two stone types do respond differently to the procedures. This suggests that stone properties may be important in determining the accuracy with which tablets can be used to assess spatial patterns of weathering. 相似文献
9.
M. A. Coombes L. A. Naylor R. C. Thompson L. Gómez‐Pujol R. J. Fairhurst 《地球表面变化过程与地形》2011,36(5):582-593
Microorganisms are a ubiquitous feature of most hard substrata on Earth and their role in the geomorphological alteration of rock and stone is widely recognized. The role of microorganisms in the modification of engineering materials introduced into the intertidal zone through the construction of hard coastal defences is less well understood. Here we use scanning electron microscopy (SEM) to examine microbial colonization and micro‐scale geomorphological features on experimental blocks of limestone, granite and marine concrete after eight months' exposure in the intertidal zone in Cornwall, UK. Significant differences in the occurrence of microbial growth features, and micro‐scale weathering and erosion features were observed between material types (ANOVA p < 0·000). Exposed limestone blocks were characterized by euendolithic borehole erosion (99% occurrence) within the upper 34·0 ± 12·3 µm of the surface. Beneath the zone of boring, inorganic weathering (chemical dissolution and salt action) had occurred to a depth of 125·0 ± 39·0 µm. Boring at the surface of concrete was less common (27% occurrence), while bio‐chemical crusting was abundant (94% occurrence, mean thickness 45·1 ± 27·7 µm). Crusts consisted of biological cells, salts and other chemical precipitates. Evidence of cryptoendolithic growth was also observed in limestone and concrete, beneath the upper zone of weathering. On granite, biological activity was restricted to thin epilithic films (<10 µm thickness) with some limited evidence of mechanical breakdown. Results presented here demonstrate the influence of substratum lithology, hardness and texture on the nature of early micro‐scale colonization, and the susceptibility of different engineering materials to organic weathering and erosion processes in the intertidal zone. The implications of differences in initial biogeomorphic responses of materials for long‐term rock weathering, ecology and engineering durability are discussed. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
10.
Two types of cavernous‐weathering features are exposed in the Oligocene Macigno Sandstone along 5 km of the Tuscan coast south of Livorno, Italy. Honeycomb cells (type 1 features) are typical closely spaced, more or less circular pits of centimetre scale that have been eroded 2 to 6 cm below the general surface of bedding planes or joints. ‘Aberrant honeycomb’ cells (type 2 features) are highly elongate, polygonal, or irregular ?at depressions of decimetre scale surrounded by walls rarely higher than 2 cm, some of which pass into long, free‐standing walls or tendrils. Thus, not all type 2 ‘honeycomb’ cells are fully enclosed. We measured the geometry of 551 honeycomb cells and examined various rock properties (microscopic texture and fabric, mineralogy, porosity, permeability, and chemical composition) to isolate factors that control the size, shape, distribution, and pattern of the honeycombs. Our goal was to narrow potential origins of the features and to understand their formation. The ubiquitous occurrence of sea salt in the honeycombs and scanning electron microscope evidence of physical weathering of silicates, especially micas, favours an origin for the honeycombs chie?y by salt weathering. Honeycombs do not form in siltstone, iron‐oxide‐impregnated sandstone, calcite‐cemented concretions, or in case‐hardened joints. Thus, salt weathering of type 1 and 2 honeycombs is not effective in very low permeability rocks. We propose for type 1 honeycombs that seawater is drawn into micropores of the sandstone and evolves into self‐organized diffusion cells (Turing patterns). Selective evaporation at the stationary nodes of diffusion cells, which form at the same site over time, leads to the precipitation of salt, then grains spall off, and pits are formed. The deepest pits (>40 mm) formed where Turing patterns consistently formed at the same sites. Although the walls are more porous and weathered than the host sandstone, they become selectively case hardened by an unidenti?ed component of low abundance. Initial honeycomb cell shape and gravity locally in?uenced type 1 honeycomb shapes. We suggest that type 2 honeycombs develop where diffusion‐controlled Turing patterns lead to case‐hardening along linear trends; gravity and rock fabric are important locally in in?uencing the orientation of the walls. Only type 2 cells are forming today, suggesting recent environmental changes. Gravity is not a fundamental control on honeycomb shape; in places it is a contributing factor. Pre‐existing depressions (quarry tool marks) have strongly in?uenced honeycomb shape locally. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
11.
Marie‐Françoise André Olivier Voldoire Erwan Roussel Franck Vautier Bruno Phalip Hang Peou 《地球表面变化过程与地形》2012,37(5):519-532
Comparative assessment of stone weathering intensities and bioclimatic conditions was conducted at four temples located in cleared and forested sites of the Angkor Park, based on similar protocols. Four thousand sculpted lotus petals carved in the same grey sandstone were categorized by using two customized scales of weathering intensity, and climate monitoring was conducted from December 2008 to November 2009. Whereas 70% of the sandstone lotus petals are almost completely destroyed by mechanical weathering in cleared areas, 74% of petals located in forested environments appear to be totally free of mechanical weathering and are only affected by superficial biochemical weathering. Ambient conditions are also contrasting, with the magnitude of the diurnal surface temperature and relative humidity ranges being three times higher at cleared sites than in wooded areas. As wetting–drying cycles are the driving force of sandstone decay at Angkor, causal links are suggested between weathering and climate regimes. In wooded areas, the microclimate is buffered by the forest and the associated lithobionts, which maintain constant humidity levels, reduce thermal stresses at the stone surface and induce a slow biochemical weathering regime. In cleared areas, direct exposure to sunshine and monsoon rains induces pronounced wetting–drying cycles conducive to swelling–shrinking movements and other potential processes, provoking the rapid mechanical decay of the sandstone. Even if local damage can be caused by tree roots, the forest cover and the associated lithobionts obviously play an overall protective role. Additionally, microtopographical factors related to architectural designs and post‐building events probably explain intra‐site and between site minor differences in the amount of sandstone decay, by influencing key factors such as the water residence time at the stone surface. Last, the contrasting weathering regimes in forested and cleared sites are but a trend, for besides overwhelming mechanical weathering, chemical weathering is also operative at cleared sites, as indicated by salt efflorescences and ferric oxidation. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
12.
George E. Mustoe 《地球表面变化过程与地形》2010,35(4):424-434
Honeycomb weathering occurs in two environments in Late Cretaceous and Eocene sandstone outcrops along the coastlines of south‐west Oregon and north‐west Washington, USA, and south‐west British Columbia, Canada. At these sites honeycomb weathering is found on subhorizontal rock surfaces in the intertidal zone, and on steep faces in the salt spray zone above the mean high tide level. In both environments, cavity development is initiated by salt weathering. In the intertidal zone, cavity shapes and sizes are primarily controlled by wetting/drying cycles, and the rate of development greatly diminishes when cavities reach a critical size where the amount of seawater left by receding tides is so great that evaporation no longer produces saturated solutions. Encrustations of algae or barnacles may also inhibit cavity enlargement. In the supratidal spray zone, honeycomb weathering results from a dynamic balance between the corrosive action of salt and the protective effects of endolithic microbes. Subtle environmental shifts may cause honeycomb cavity patterns to continue to develop, to become stable, or to coalesce to produce a barren surface. Cavity patterns produced by complex interactions between inorganic processes and biologic activity provide a geological model of ‘self‐organization’. Surface hardening is not a factor in honeycomb formation at these study sites. Salt weathering in coastal environments is an intermittently active process that requires particular wind and tidal conditions to provide a supply of salt water, and temperature and humidity conditions that cause evaporation. Under these conditions, salt residues may be detectable in honeycomb‐weathered rock, but absent at other times. Honeycomb weathering can form in only a few decades, but erosion rates are retarded in areas of the rock that contain cavity patterns relative to adjacent non‐honeycombed surfaces. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
13.
Recent developments in long term landform evolution modelling have created a new demand for quantitative salt weathering data, and in particular data describing the size distribution of the weathered rock fragments. To enable future development of rock breakdown models for use in landscape evolution and soil production models, laboratory work was undertaken to extend existing schist/salt weathering fragmentation studies to include an examination of the breakdown of sub‐millimetre quartz chlorite schist particles in a seasonally wet tropical climate. Laser particle sizing was used to assess the impact of different experimental procedures on the resulting particle size distribution. The results reveal that salt weathering under a range of realistic simulated tropical wet season conditions produces a significant degree of schist particle breakdown. The fragmentation of the schist is characterized by splitting of the larger fragments into mid‐sized product with finer material produced, possibly from the breakdown of mid‐sized fragments when weathering is more advanced. Salinity, the salt addition method and temperature were all found to affect weathering rates. Subtle differences in mineralogy also produce variations in weathering patterns and rates. It is also shown that an increase in drying temperature leads to accelerated weathering rates, however, the geometry of the fracture process is not significantly affected. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
14.
R. U. Cooke 《地球表面变化过程与地形》1979,4(4):347-359
The equipment and techniques being used at Bedford College, London to simulate salt weathering processes in deserts are described in the context of a general discussion of the nature of salt weathering processes and approaches to studying them. An experiment based on the equipment and techniques is described: it is designed to test the durability of three building stones in the presence of several different saline solutions under conditions of surface temperature and relative humidity that are considered typical of hot deserts. The experiment, the first of a series, shows that Na2SO4 is the most effective of the salts used, and that susceptibility of the rocks to weathering is related to such rock properties as porosity, microporosity and water absorption capacity. 相似文献
15.
Quantitative data on rock surface millimetre‐scale roughness are presented concerning the splash and spray geomorphologic domains of two coastal profiles developed on Mediterranean carbonate rocks. Differences of the roughness characteristics are attributed to rock properties, weathering agents and bioerosion. In the splash zone, roughness is related to sparsely distributed patterns of bioerosion, salt weathering and wave attack. In the spray zone, smooth surfaces seem to be the response to the solution processes that predominate, exerting a more homogenous influence on rock surface evolution. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
16.
Building sandstone surface modification by biofilm and iron precipitation: emerging block‐scale heterogeneity and system response 下载免费PDF全文
下载免费PDF全文 Stephen McCabe Daniel McAllister Patricia A. Warke Miguel Gomez‐Heras 《地球表面变化过程与地形》2015,40(1):112-122
Stone surfaces are sensitive to their environment. This means that they will often respond to exposure conditions by manifesting a change in surface characteristics. Such changes can be more than simply aesthetic, creating surface/subsurface heterogeneity in stone at the block scale, promoting stress gradients to be set up as surface response to, for example, temperature fluctuations, can diverge from subsurface response. This paper reports preliminary experiments investigating the potential of biofilms and iron precipitation as surface‐modifiers on stone, exploring the idea of block‐scale surface‐to‐depth heterogeneity, and investigating how physical alteration in the surface and near‐surface zone can have implications for subsurface response and potentially for long‐term decay patterns. Salt weathering simulations on fresh and surface‐modified stone suggest that even subtle surface modification can have significant implications for moisture uptake and retention, salt concentration and distribution from surface to depth, over the period of the experimental run. The accumulation of salt may increase the retention of moisture, by modifying vapour pressure differentials and the rate of evaporation. Temperature fluctuation experiments suggest that the presence of a biofilm can have an impact on energy transfer processes that occur at the stone surface (for example, buffering against temperature fluctuation), affecting surface‐to‐depth stress gradients. Ultimately, fresh and surface‐modified blocks mask different kinds of system, which respond to inputs differently because of different storage mechanisms, encouraging divergent behaviour between fresh and surface‐modified stone over time. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
17.
A. S. Goudie 《地球表面变化过程与地形》1999,24(8):715-724
A total of 21 different types of British and European Mesozoic limestones have been subjected to simulated salt weathering using sodium sulphate (Na2SO4) with the following aims: assessment of the relative durabilities of different types of limestone; assessment of the importance of modulus of elasticity and other factors in affecting durability; and assessment of the use of impulse excitation techniques to monitor changes in rock modulus of elasticity. The rocks showed a wide spectrum of durabilities; while rocks with high values of modulus of elasticity, lower water absorption capacities, high densities and low salt uptakes tended to be durable, there were anomalies, the explanation for which probably lies in their pore structures. Non-destructive testing techniques showed that, although the more durable rocks failed to lose weight or to show visual signs of disintegration, their modulus of elasticity values did tend to decline, indicating a loss in strength. Copyright © 1999 John Wiley & Sons, Ltd. 相似文献
18.
Martin A. Coombes 《地球表面变化过程与地形》2011,36(15):2114-2121
The wetting–drying and warming–cooling behaviours of rock and stone are known to influence the nature and rate of weathering. The way materials warm‐up and dry‐out also influences their suitability as biological substrata. While rock thermal behaviours have been measured under controlled laboratory conditions, previous experiments have largely been restricted to terrestrial simulations due to practical constraints. Where efforts have been made to simulate intertidal conditions, expansion and contraction of rocks or rates of breakdown (i.e. sediment production and weight loss) have been measured, while detailed observations of thermal and drying behaviours have rarely been made. A simple, semi‐automated procedure is described that enabled measurement of surface temperatures and desorption (evaporative water loss) for different material types (rock and concrete) under simulated semidiurnal tide conditions. Some preliminary results are presented illustrating the types of data that were obtained, and comparisons are made with temperature data collected on a rock platform in the UK to assess the ability of the procedure to adequately represent field conditions. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
19.
Five granites from NW Spain were subjected to two salt‐spray weathering tests under controlled atmospheric conditions. Granite samples were exposed to a sodium chloride solution in the first test and to a complex solution (sea water) in the second. Subsequent examination of the rocks by light and petrographic microscopy clearly demonstrated the development of different weathering morphologies in each test. The distribution of dissolved ions in samples taken at different depths from the weathered surfaces at the end of the experiments, and the changes in weight of the samples during the tests, also differed. In our opinion, these results were determined by the nature of the solution used; although sodium chloride is the predominant salt in sea water, the presence of other ions modifies its solubility, thereby varying the dynamics of mobility and precipitation and thus the weathering morphology that develops. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
20.
J. P. McGreevy 《地球表面变化过程与地形》1982,7(5):475-488
A laboratory experiment has been conducted to examine the effects of ‘frost and salt’ weathering (i.e. physical breakdown by the freezing of salt solutions) on a limestone. Results show that the presence of certain salts in solution can inhibit frost damage. These findings are in direct conflict with those presented by Goudie (1974) and, more recently, Williams and Robinson (1981). Comparison of the experimental methods used in each of these three studies suggests that opposing results can be explained in terms of the different experimental procedures which were employed. If salt supply is frequent and plentiful then it seems likely that rock breakdown will be enhanced-this is the case represented by the experiment of Williams and Robinson. Conversely if the salt supply is limited and the amounts of salt remain more or less constant then rock breakdown will be inhibited-the case of the present experimental study. Caution is therefore advocated when attempting to extrapolate laboratory-derived results to infer on the behaviour of rocks under natural conditions. Several environmental situations in which ‘frost and salt’ weathering may be a possibility are dsiscussed, but it is concluded that further field data, especially concerning temperature regimes and salt availability at and below rock surfaces in cold regions, would be necessary before more definite statements could be made about the efficacy of this process. 相似文献