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1.
矿物3CaO·3Al_2O_3·BaSO_4形成过程研究   总被引:1,自引:0,他引:1  
eoreanu等[1]研究CaOAl2O3Mx(SO4)Y[M=Mg2+、Sr2+、Ba2+、Zn2+、Fe2+、Fe3+、Al3]系统中,形成类似于矿物3CaO·3Al2O3·CaSO4(硫铝酸钙)的可能性时,报道合成了新矿物3CaO·3Al2O3·BaSO4(简写为3CA·BaSO4);部分学者[2,3]研究过它的胶凝性能等。在有关文献中,研究者制备研究用纯矿物的煅烧条件、获得样品的矿相组成不尽相同。如文献[1]在温度1400℃保温240min,制备的样品包括铝酸钙(CaO·Al2O3…  相似文献   

2.
1-(2-咪唑偶氮)-2-萘酚-4-磺酸与镍的显色反应郑恩铭,潘富友浙江省台州师专生化系临海3170001-(2-咪唑偶氮)-2-萘酚-4-磺酸(IANS)已用作光度法测定Cu ̄[1]、Zn ̄[2]及Cu和Zn的连续测定 ̄[3]。本文试验了IANS与...  相似文献   

3.
王鲜华  潘兆橹 《地质论评》1995,41(5):409-414
氟碳钙铈矿从1835年发现至今已有一百五十多年的历史。然而迄今还没有人深度用结构因子计算法成功测定其晶体结构,只有推测结构模型与部分原子位,本文第一次用结构因子计算法完成该矿物二级亚晶胞a'c'的结构测定。晶体简易化学式Ce2CaF2[CO3]3,a'c'亚晶胞空间群为P6322,晶胞参数a'=b'=0.4101nm(a=0.7104(1)nm,a'=1/√3a),c'=2.7901(4)nm,r  相似文献   

4.
合成了新的杂环偶氮变色酸类试剂———2[2′(6甲氧基苯并噻唑)偶氮]1,8二羟基萘3,6二磺酸,并系统探讨了在pH4.5的邻苯二甲酸氢钾NaOH介质中显色试剂与钛的显色反应特性。结果表明,在溴化十六烷基吡啶存在下,试剂与Ti(Ⅳ)形成2∶1的络合物,显色反应15min完全并至少稳定4h,最大吸收波长为670nm,表观摩尔吸光系数达1.67×105L·mol-1·cm-1,钛的质量浓度在0~400μg/L时符合比尔定律。用拟定的方法测定了硅砖等标准物质中的Ti(Ⅳ),所得结果与标准值的相对误差均小于4%,RSD(n=5)小于3.5%。  相似文献   

5.
偏岭石及其有关的变高岭石过去用一般鉴定结晶矿物的x射线衍射分析定为“非晶质”矿物;后来刘长龄用x射线衍射分析粉末照相高功率长时间拍照,见到有中、低强度的衍射线条(背景发暗).4~4.1(弥散)等多条(偏岭石);4.4及2.2等(变高岭石),二者有区别(灵敏度高的x射线衍射仪强度曲线分析也有不同(图1),而均属于准晶质或半晶质。今后再鉴定为“非晶质”矿物,不符合事实,显然是错误的。又偏岭石及变高岭石的光学性质等也不是“非晶质”,而具有强非均质性及2V[1][2].  相似文献   

6.
陶瓷釉矿物学特征的电子自旋共振(ESR)研究   总被引:2,自引:1,他引:1  
早在60年代初,Griscon等人[1]就曾用ESR方法对玻璃中的顺磁离子进行了研究。80年代初Canara等人[2]又用ESR方法研究了硅酸玻璃、釉熔块和陶瓷色料的波谱特征,发现发色元素Cr、Fe、Co等在釉料中的反应行为,石田等人[3]则研究了含铁高岭土和瓷胎中氧化铁的存在状态。80年代末蔡秀成等人[4]应用ESR方法探讨了景德镇传统“石灰碱釉”的油(煤)窑产品发黄机理。由此可见,用ESR方法研究铁瓷釉及瓷胎中顺磁杂质离子的存在形式,对提高陶瓷质量和呈色机理的探讨有着广阔的应用前景。1 样…  相似文献   

7.
2,4-二甲氧基苯基荧光酮光度法测定铍韩峭峰,杨问华,侯安新,陈晓明,陈伟中国地质大学化学系汉口4300302,4-二甲氧基苯基荧光酮(DMPF)已用于分光光度法测定微量Co ̄[1]、Al ̄[2]及化学发光法测定Co ̄[3]。本试验在CTMAB存在下...  相似文献   

8.
辽宁八家子三斜锰辉石的发现及其找矿意义   总被引:2,自引:0,他引:2  
在对辽宁建昌县八家子矿区吴家屯铅锌黄铁矿-硫锰矿矿床进行研究的过程中,首次发现三斜锰辉石,它与锰铝榴石、硫锰矿、黄铁矿等共生,主要产出在铅锌黄铁矿体、硫锰矿体和近矿矽卡岩中。该区的三斜锰辉石为玫瑰红色和暗红褐色,短柱状,两组解理,折射率Ng=1.749~1.753,Np=1.737~1.748,Nm=1.734~1.741;+2V=43°;DO=3.786~3.792;DC=3.79~3.83。化学成分除Si外主要为Mn和Fe,矿物化学式:(Ca0.27~0.43Mg0.43~0.57)0.75~1.00(Mn4.94~5.77Fe0.36~1.36)6.16~6.37[Si6.86~7O21]。晶体结构属三斜晶系,玫瑰红色三斜锰辉石的X射线衍射主要粉晶谱线:3.133(100),2.960(42),2.502(13),2.183(18),1.919(45)。矿物成因研究表明,三斜锰辉石主要为岩浆岩与含锰白云岩接触交代作用的产物,具明显的成因指示意义  相似文献   

9.
合成了新显色剂2(2咪唑偶氮)苯甲酸(简称IABA),分子式C10H8N4O2,分子量216.20,熔点213℃,各级酸离解常数pKa1为3.2,pKa2为9.8,研究了它的性质及其与钴显色反应的条件。在pH7的NH4Ac介质中,试剂与钴形成紫红色络合物,λmax为546nm,试剂的λmax为462nm,Δλ为84nm,Co2+与试剂络合比为1∶2,摩尔吸光系数1.61×104L·mol-1·cm-1,Co2+在0~0.8mg/L遵守比尔定律。所拟方法直接测定了工业废水及VB12中痕量钴,结果与原子吸收法相符,加标回收率为101.3%~102.2%,RSD(n=6)在2.0%~2.7%。  相似文献   

10.
刘福来 《岩石学报》1998,14(2):129-139
晋蒙交界孔兹岩系变质反应结构与矿物相转变机制研究结果表明,在麻粒岩相变质及其与之相伴随的重熔作用过程中,存在一类特殊的有熔体参与的变质反应,即未熔矿物与熔体之间的反应。结合天然块状岩石高温高压实验,确定研究区孔兹岩系熔体参与变质反应如下:①2Gt+(9SiO2+4Al2O3)熔体=3Crd;②Gt+(2SiO2+2Al2O3)熔体=Sp+Crd;③2Gt+(3SiO2)熔体=2Opx+Crd;④14Gt+(25SiO2+4H2O)熔体=4Cum+7Crd。这类熔体参与变质反应不仅受控于温压条件,而且与寄主岩石脱水熔融、长英质矿物部分熔融存在密切成因关系。该项理论与实验研究对于深化变质反应理论、探讨孔兹岩系矿物相转变成因机制及其动力学过程有着重要的意义。  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

13.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

14.
Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931.  相似文献   

15.
PALEONTOLOGY     
正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.)  相似文献   

16.
正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.)  相似文献   

17.
正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.)  相似文献   

18.
PETROLOGY     
正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus.,  相似文献   

19.
正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an  相似文献   

20.
正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of  相似文献   

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